Class 12 Physical Chemistry | Chemical Kinetics | Formulas

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Class 12 Physical Chemistry | Chemical Kinetics | Formulas

Chemical Kinetics
Formulas

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Class 12 Physical Chemistry | Chemical Kinetics | Formulas

A) Average rate & Instantaneous rate

R P
Δ[𝑅] Δ[𝑃] d[𝑅] d[𝑃]
rav = - = rinst = - =
Δ𝑡 Δ𝑡 d𝑡 d𝑡

A+B C
Δ[𝐴] Δ[𝐵] Δ[𝐶]
rav = - =- =
Δ𝑡 Δ𝑡 Δ𝑡

xA + yB zC
1 Δ[𝐴] 1 Δ[𝐵] 1 Δ[𝐶]
rav = - =- =
𝑥 Δ𝑡 𝑦 Δ𝑡 𝑧 Δ𝑡

B) Order of reaction & Units of k

1) Order of reaction = x + y
Rate = k [A]x [B]y

2) Units of k
𝑅𝑎𝑡𝑒 𝑅𝑎𝑡𝑒 𝑚𝑜𝑙 𝐿−1 𝑠 −1
k = [𝐴]x[𝐵]y = [𝑐𝑜𝑛𝑐]n = [𝑚𝑜𝑙 𝐿−1 ]n

C) Integrated rate equations

1) Zero order
[𝑅]𝑜 − [𝑅]
k=
𝑡
[𝑅]𝑜
t½ =
2𝑘

2) First order
2.303 [𝑅]𝑜
k= log
𝑡 [𝑅]

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Class 12 Physical Chemistry | Chemical Kinetics | Formulas

2.303 𝑝𝑖
k= log
𝑡 𝑝𝐴
0.693
t½ =
𝑘

D) Arrhenius Equation
1) k = A. e-Ea/RT

− 𝐸𝑎
2) log k = + log A
2.303 𝑅𝑇

𝑘2 𝐸𝑎 𝑇 −𝑇
2 1
3) log
𝑘1
= (
2.303 𝑅 𝑇 𝑇
)
1 2

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