Class 12 Physical Chemistry | Electrochemistry | Formulas

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Class 12 Physical Chemistry | Electrochemistry | Formulas

Electrochemistry
Formulas

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Class 12 Physical Chemistry | Electrochemistry | Formulas

1) 𝐸𝑐𝑒𝑙𝑙 = 𝐸𝑐𝑎𝑡ℎ𝑜𝑑𝑒 - 𝐸𝑎𝑛𝑜𝑑𝑒

ɵ ɵ ɵ
2) 𝐸𝑐𝑒𝑙𝑙 = 𝐸𝑐𝑎𝑡ℎ𝑜𝑑𝑒 - 𝐸𝑎𝑛𝑜𝑑𝑒

3) Nernst Equation
ɵ 𝑅𝑇 1
a) E(Mn+/M) = E(𝑀 𝑛+ /M) - ln [𝑀𝑛+]
𝑛𝐹

ɵ 2.303 RT 1
E(Mn+/M) = E(𝑀 𝑛+ /M) - log [𝑀𝑛+]
nF

ɵ 0.059 1
E(Mn+/M) = E(𝑀 𝑛+ /M) - log [𝑀𝑛+]
n

ɵ 𝑅𝑇 [C]c [D]d
b) 𝐸𝑐𝑒𝑙𝑙 = 𝐸𝑐𝑒𝑙𝑙 - ln
𝑛𝐹 [A]a [B]b

ɵ 2.303 RT [C]c [D]d

𝐸𝑐𝑒𝑙𝑙 = 𝐸𝑐𝑒𝑙𝑙 - log
nF [A]a [B]b

ɵ 0.059 [C]c [D]d

𝐸𝑐𝑒𝑙𝑙 = 𝐸𝑐𝑒𝑙𝑙 - log
n [A]a [B]b

ɵ
4) Relationship between Kc & 𝐸𝑐𝑒𝑙𝑙
ɵ 2.303 RT
𝐸𝑐𝑒𝑙𝑙 = log Kc
nF
ɵ 0.059
𝐸𝑐𝑒𝑙𝑙 = log Kc
n

ɵ
5) ΔrGɵ = - nF𝐸𝑐𝑒𝑙𝑙
ΔrGɵ = - 2.303 RT logK

l l
6) R = ρ =
A κA

l
7) G* =
A
A
G=κ
l

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Class 12 Physical Chemistry | Electrochemistry | Formulas

κ
8) Λm =
c

9) Kohlrausch’s law of independent migration of ions:

Λom = ν+ λo+ + ν- λo-

Λm
α=
Λom

cα2
Ka =
(1-α)

10) Faraday’s law: Q = It

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