Name: HW # 6 (Chapter 7)

1- What element is represented by the following electron configuration

[Kr] 5s2 4d10 5p5?

2- How many orbitals are there in a subshell designated by the quantum numbers
[n = 3, ℓ = 2]?

3- What is the wavelength of light emitted (m) when an electron in a hydrogen atom
goes from n = 5 to n = 3?

4- Specify the subshell and the number electron for the given quantum numbers
[n = 4, mℓ = +1, ms = +1/2]?

Arrange the elements Ca, Sr, and Ba in order of increasing -5

)1st ionization energy, I.E. or I1(

6- Portions of orbital diagrams representing the ground state electron configurations of

certain elements are shown here. Which of them violate the Pauli Exclusion Principle?
Which violate Hund’s rule?
7- Which of the following pairs are isoelectronic with each other?
a) Ca2+ and Sr2+ b) S2− and Cl−
c) O2− and Mg2+ d) He and H+ e) I− and Kr

8- Which of the following is an isoelectronic series?

a- Na+, K+, Rb+, Cs+ b- K+, Ca2+, Ar, S2-

c- Na+, Mg2+, S2-, Cl- d- Li, Be, B, C

9- Give the set of four quantum numbers that could represent the last electron of the
17
Cl atom.
[n = 3, ℓ = 2, ml = 1 , ms = +1/2]
[n = 3, ℓ = 1, ml = 1, ms = +1/2]
[n = 3, ℓ = 2, ml = 1, ms = -1/2]
[n = 3, ℓ = 0, ml = 1, ms = -1/2]

10- Which of the following combinations of quantum numbers is not allowed?

[n = 4, ℓ = 3, mℓ = - 2 and ms = - ½]
[n = 4, ℓ = 2, mℓ = 0 and ms = ½]
[n = 2, ℓ = 1, mℓ = - 1and ms = ½]
[n = 2, ℓ = 2, mℓ = - 1 and ms = ½[

11- Which of the following combinations of quantum numbers is not allowed?

(n = 4, ℓ = 3, mℓ = - 3 and ms = 1/2)
(n = 3, ℓ = 2, mℓ = 1 and ms = - 1/2)
(n = 3, ℓ = 2, mℓ = - 3 and ms = 1/2)
(n = 4, ℓ = 2, mℓ = 0 and ms = 1/2)
12- Which of the following combinations of quantum numbers is not allowed?
(n = 0, ℓ = 1, mℓ = -1 and ms = 1/2)
(n = 3, ℓ = 2, mℓ = 1 and ms = - 1/2)
(n = 3, ℓ = 2, mℓ = - 1 and ms = 1/2)
(n = 4, ℓ = 2, mℓ = 0 and ms = 1/2)

13- What is the wavelength of light emitted (m) when an electron in a hydrogen
atom goes from n = 5 to n = 3?

14- Specify the subshell and the number electron for the given quantum numbers
[n = 4, mℓ = +1, ms = +1/2]?

15-What is the wavelength (in nm) of the W radiation if the energy required removing an
electron from the Hydrogen atom is 1.672 x 10-19 J?

16- What is the frequency (in Hz) emitted by a hydrogen atom by during transition n
from the n = 6 to n = 3 principal energy level?

17- The electron configuration of Cu2+ is -----------

13- The number of electrons in the 3dxy orbital is equal to --------------

14- - What is the de-Broglie wavelength (in m) of an electron travelling with a velocity of
10% of speed of light? (Mass of electron = 9.11 x1031- kg)

?Which of the following sets of quantum numbers is unacceptable -15

a- (n = 4, ℓ = 2, mℓ = -4, ms = +1/2) b- (n = 3, ℓ = 2, mℓ = -2, ms = +1/2)

c- (n = 3, ℓ = 0, mℓ = 0, ms = +1/2) d- (n = 4, ℓ = 1, mℓ = 1, ms = -1/2)
e- All are acceptable

16- Which of following atom has the lowest first ionization energy in its ground state?

a- Potassium b- Magnesium c- Aluminum

d- Lithium e- Neon

17-Order the elements S, Cl, Ca and F in terms of increasing atomic radii?

a- Ca, S, Cl, F b- Ca, F, S, Cl c- F, Cl, S, Ca

d- S, F, Cl, Ca e- F, S, Ca, Cl

18- Which one of the following pairs is isoelectronic?

a- Mn2+ and Ar
b- Zn2+ and Cu2+
c- Ca2+ and Ar
d- Cl- and S .

19- Arrange the following ions in order of increasing ionic radii [K+, P3-, S2-, Cl-]?

a- K+, Cl-, S2-, P3- b- K+, P3-, S2-, Cl- c- P3-, S2-, Cl-, K+
d- Cl-, S2-, P3-, K+ e- S2-, P2-, Cl-, K+

20- How much energy would be released as electron of H – atom moved from n = 4
to n = 3 energy level?
Useful Information
ΔE = Ef – Ei = [En = - 2.18 x 10-18 (1 /n2) = (hc/λ); c = 3.0 x 108 m/s and h = 6.626 x 10-
34
J.s
21- How much energy would be released as electron moved from n=5 to n=4 energy
level?

22- How much energy would be released as electron moved from n = 5 to n = 3

energy level?

23- What is the maximum number of orbitals described by the quantum number?
(n = 5)

24- What is the maximum number of orbitals described by quantum numbers n = 3

and ℓ = 2

25- What is the maximum number of orbitals described by quantum numbers?

(n = 4 and ℓ = 3)

26- What is the maximum number of orbitals described by quantum numbers?

(n = 3 and ℓ = 1)

27- How many orbitals in an atom can have the designation 4d?

The answer is ----------------------