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Introduction
The strong demand for alternatives to The Agilent B1500A Semiconductor
fossil fuel based energy sources and Device Analyzer is a well-known tool
growing environmental concerns have for evaluating the characteristics of
increased interest in solar cells as a semiconductor devices. However, it
long-term, exhaustless, environmen- can also be a very effective tool for
tally friendly and reliable energy tech- solar cell characterization since most
nology. Continuous efforts to develop solar cell measurements are the same
various types of solar cells are being as those for semiconductor devices,
made in order to produce solar cells such as current versus voltage (IV)
with improved efficiencies at a lower and capacitance versus voltage (CV)
cost, thereby taking advantage of the measurements. This application
vast amounts of free energy available note shows how the B1500A can be
from the sun. used to evaluate a variety of solar
cell types, from conventional devices
based on silicon to state-of-the-art
devices using more exotic materials.
Solar cell overview
The equivalent circuits used to model Although there are a variety of types for improvement the performance of
the DC and AC behavior of a solar of solar cells under development, the silicon-based solar cells is approach-
cell are different. Figure 1 shows the majority of solar cells fabricated today ing theoretical limits. In addition,
equivalent circuit models for these are silicon-based in single crystalline, the potential demand for solar cells
two cases. large-grained poly crystalline or amor- exceeds available manufacturing
phous forms. Silicon is an abundant capacity to produce the high quality,
The DC equivalent circuit, which material, highly stable and possessing pure silicon crystal lattices necessary
describes the static behavior of the a set of well-balanced electronic, for optimum solar cell efficiency.
solar cell, is commonly composed of physical and chemical properties that This has prompted the development
a current source, a pn junction diode are ideal for mass production. These of solar cells based on alternative
and a shunt resistor (Rsh) in parallel characteristics have made silicon the materials such as a Cu(In, Ga)Se2
along with a series resistor (Rs). The preferred material for microelectron- (CIGS) solar cell and a dye sensitized
current source models electron injec- ics and they also account for its solar cell (DSC) to improve conversion
tion from light. Rs is the total Ohmic predominance in solar cells. However, efficiency and reduce costs.
resistance of the solar cell, which although there is still some room
is essentially the bulk resistance.
Smaller Rs values equate to increased
solar cell efficiencies. Rsh accounts Solar cell Rs Solar cell rs
for stray currents, such as recombina- + +
tion currents and leakage currents
around the edge of devices. In this Rsh Load Cp rp Load
case a larger Rsh value equates to
– –
increased solar cell efficiency, since
it means that the stray currents are
reduced. DC equivalent circuit AC equivalent circuit
A three element model is used to Figure 1. Simplified equivalent circuit diagrams for modeling the DC and AC behavior
model the AC equivalent circuit. The of a solar cell
AC equivalent circuit consists of a
parallel capacitance (Cp), a parallel
resistance (rp) and a series resistance Category Type Challenges
(rs). The AC equivalent circuit can Single crystalline Development of the device structure
be used to describe the dynamic Silicon Polly crystalline Improvement of the crystal quality
behavior of the solar cell. Cp consists Amorphous Multiplying the junctions
of a transition capacitance (Ct) and a III-V
GaAsInP
diffusion capacitance (Cd) in parallel, Semiconductors
which are dependent on the applied II-VI CdTe/CdS Control of the band gap
Compound Semiconductors Cu2S/CdS
voltage. In addition, Cd also depends Multiplying the junctions
on the AC signal frequency. The rp Chalcopyrite
CIGS
resistor is the parallel combination of Semiconductors
Rsh and a dynamic resistance (Rd) that Pentacene Development of the device
also shows voltage dependence. Organic Phthalocyanine structure (Including multi-junction)
Merocyanine Development of the materials
Photochemical Dye sensitized Development of the materials
Table 1. Solar cell types and their associated challenges
2
Solar cell parameter extraction
Table 1 summarizes the various Table 2 lists the parameters that are solar cell generates its maximum
types of solar cells and the challeng- typically used to characterize solar power; the current and voltage in
es facing them. Of course, improving cells. this condition are defined as Imax and
energy conversion efficiency is the Vmax (respectively). The fill factor (FF)
over-riding challenge facing all of Parameters from IV and the conversion efficiency (η)
these solar cell types. Improved measurements are metrics used to characterize the
efficiency helps by both decreasing performance of the solar cell. The fill
the amount of expensive material Most solar cell parameters can be factor is defined as the ratio of Pmax
required for cell fabrication and by obtained from simple IV measure- divided by the product of Voc and Isc.
reducing costs for the peripheral ments. Figure 2 shows the IV The conversion efficiency is defined
components, thereby lowering the characteristics of a typical solar cell as the ratio of Pmax to the product of
cost per Watt of the solar cell. IV under forward bias and illumination. the input light irradiance (E) and the
characterization, which will be dis- The short circuit current (Isc) is the solar cell surface area (Ac).
cussed later, is mandatory to evaluate current through the solar cell when
the parameters which describe the the voltage across the solar cell is
solar cell’s efficiency. zero. The open circuit voltage (Voc)
is the voltage across the solar cell
In addition to IV measurements, when the current through the solar
capacitance measurements and time cell is zero and it is the maximum
domain measurements are required voltage available from the solar cell.
to completely characterize solar cells. The maximum power point (Pmax)
Because traps in the bulk directly is the condition under which the
affect carrier recombination at the
interface and in the bulk, it is essen-
tial to characterize these traps so as IV measurement
to minimize their impact on solar cell Symbol Parameter Name Unit
performance. Capacitance measure- Isc Short circuit current A
ments are the main method to evalu- Jsc Short circuit current density A/cm2
ate traps in the bulk. Understanding Voc Open circuit voltage V
trap behavior is also important when Pmax Maximum power point W
studying multi-junction solar cells and Imax Current at maximum power point A
for controlling the solar cell band gap. Vmax Voltage at maximum power point V
To optimize solar cell performance it FF Fill factor —
is also important to know the carrier η Conversion efficiency %
diffusion length, because it is one of Rsh Shunt resistance Ω
the key parameters impacting solar Rs Series resistance Ω
cell efficiency. Time domain measure-
ment is the principal method used to Capacitance measurement
measure carrier diffusion length. Symbol Parameter Name Unit
Cp Parallel capacitance F
Nc Carrier density cm-3
Ndl Drive-level density cm-3
3
Although there are a variety of ∆Vsc ∆Vsc
Rsh = – ––––––
Isc ∆Isc
methods to estimate Rsh and Rs, one ∆Isc
of the most straightforward tech- Rs ∆Voc
Imax = – ––––––
niques is to measure the slope ∆Ioc
Pmax
of IV characteristics as shown in
∆Voc
Current
Figure 2. Unfortunately, the value of
Rs calculated using this method tends ∆Ioc
to be proportional to but larger than
the actual value.
Voltage Vmax Voc
To obtain more accurate estimates
of Rs, a series of forward biased Figure 2. Typical IV forward bias characteristics of a solar cell
IV measurements are made using
different values of input light irradi-
ance (please see Figure 3). First, Pmax
a forward-biased IV measurement Isc1
∆I
∆V
∆I
Voltage
,
4
Parameters from capacitance oscillating signal. The density that
measurements can be obtained using DLCP is also
called the drive level density (Ndl),
Capacitance measurements can be and it is defined as shown below
also used to evaluate the characteris- (please see Figure 6). (Note: In the
tics of solar cells. CV measurements, previous equation the subscripted
which are the most common capaci- symbols C1, C2, etc. have the units of
tance measurements, can be used to capacitance per volt, capacitance per
estimate the carrier density (Nc) using volt squared, etc.)
the following equation.
4.E+13 1.2E+15
Nc [cm-3]
shown below (please see Figure 5).
2.E+13 1.0E+15
0.E+13 8.0E+14
-5.0 -4.0 -3.0 -2.0 -1.0 0 1.5 2.0 2.5 3.0
Voltage (V) W (µm)
where
C-AC Voltage plot Drive-level capacitance profile
163 1.8E+15
162
161 1.6E+15
Nc [cm-3]
Cp [nF]
5
Nyquist plot
Cole-Cole plot
A capacitance versus frequency (Cf) Cp-Frequency plot Complex impedance plot
measurement is helpful to understand 180 20
the dynamic behavior of solar cells as Dark
175 15
well. The results of a Cf measurement
Z'' [Ohm]
Cp [nF]
are often plotted as complex numbers 170 10
in the impedance plane where this
165 5
information is known by many names, Illuminated
such as Nyquist plots, Cole-Cole 160 0
1.E+03 1.E+04 1.E+05 0 10 20 30 40
plots, complex impedance plots, etc. Frequency (Hz) Z' [Ohm]
(please see Figure 7).
Figure 7. Cp-Frequency plot and Nyquist plot
Parameters from time domain
measurements
Voc
A variety of time domain measure-
ment methods are also being devel-
Voltage
oped to evaluate the recombination
parameters of solar cells, such as
minority carrier lifetime (τ), surface Voc τ
recombination velocity (S) and minor-
Dark
Illuminated
Forced current
is open circuit voltage decay (OCVD) τ
where the excitation is supplied
either electrically or optically (please Time
see Figure 8). In the electrical case
a constant current equal to Isc is Time
forced into the solar cell and the Optical excitation Electrical excitation
voltage decay across the solar cell is
Figure 8. Open circuit voltage decay measurement
observed after abruptly terminating
the current. In the optical case a
light pulse is used to stimulate the
solar cell instead of a current. For the
short circuit condition the current
flow across the solar cell is measured
after removing the light stimulus, and
this is called the short circuit current
decay (SCCD).
6
B1500A solar cell test switches (please see Figure 10). The
SMU not only has the capabilities to
The B1500A supports three types
of SMUs: a medium power SMU
capabilities force/measure voltage or current, but (MPSMU), a high power SMU
it also has a compliance feature that (HPSMU) and a high resolution SMU
The B1500A mainframe has ten slots limits the voltage or current output to (HRSMU). This allows you to select
available for modules and it supports prevent device damage. For example, the SMU appropriate for the type
a variety of module types. These when the SMU is in voltage source of device you are measuring. Table
include a source/monitor unit (SMU), mode you can specify a current 3 summarizes the different SMU
a multi-frequency capacitance compliance to prevent large currents capabilities, and Figure 11 shows the
measurement unit (MFCMU), a wave- from flowing into the device under amount of current/voltage that each
form generator/fast measurement test (DUT). SMU can force/measure.
unit (WGFMU) and a high-voltage
semiconductor pulse generator unit
–
(HV-SPGU). In addition, every B1500A A
mainframe includes a ground unit
(GNDU); the GNDU acts as an active SMU force
ground that always maintains a
potential of 0 V for current levels of
±4.2 A. Using these modules and the V
ground unit you can perform a wide Common –
variety of parametric test, from basic
IV and capacitance characterization
to ultra-fast IV time domain Figure 9. Simplified SMU equivalent circuit
measurements.
IV measurement capabilities 60
40 Illuminated
As previously discussed, basic solar
cell parameters such as Isc, Jsc, Voc,
Current (mA)
20
Pmax, Imax, Vmax, FF, η, Rsh and Rs can
0
be determined from basic IV mea-
Dark
surements. The B1500A SMUs can -20
make IV measurements on solar cells
across all four quadrants as described -40
below. -60
-0.50 -0.25 0.00 0.25 0.50
SMUs are single-ended devices that Voltage (V)
combine a current source, a voltage
Figure 10. IV measurements made using an SMU
source, a current meter, a voltage
meter and several switches (please
see Figure 9). SMUs can evaluate
the IV characteristics of devices MPSMU HPSMU HRSMU
over all four quadrants, enabling the Maximum values to force/ Current 100 mA 1A 100 mA
measure(Absolute values) Voltage 100 V 200 V 100 V
measurement of both illuminated IV
characteristics and dark IV character- Minimum resolution to Current 10 fA 10 fA 1 fA
measure Voltage 0.5 μV 2 μV 0.5 μV
istics without requiring any external
Maximum power 2W 14 W 2W
Table 3. Comparison of SMU measurement capabilities
7
If your solar cells have short circuit Current (mA)
currents larger than 1 A or require Current (mA) 1000
voltages greater than 200 V, the MPSMU HPSMU
HRSMU 100 500
Agilent B1505A Power Device
50 125
Analyzer/Curve Tracer can be
20 50
used to evaluate your devices. The
B1505A supports a high current SMU -100 -40 -20 20 40 100 -200 -100 -40 -20 20 40 100 200
-20 Voltage (V) -50 Voltage (V)
(HCSMU) that can measure currents
-50 -125
of up to 20 A and a high voltage
-100 -500
SMU (HVSMU) that can measure
voltages of up to 3000 V. In addition, -1000
the B1505A also supports the HPSMU Figure 11. SMU current and voltage sourcing capabilities
and the MFCMU modules (the same
modules supported on the B1500A).
More detailed information about the
B1505A can be found in the B1505A
brochure (5990-4158EN).
Voltage
Current
Time
Figure 13. Comparison of the B1500A’s single and double sweep functions
8
Capacitance measurement used to evaluate the transient char- them. The WGFMU possesses a
capabilities acteristics of solar cells as described fast IV measurement capability that
above. The minimum sampling is synchronized with an arbitrary
Capacitance measurements charac- interval and the time stamp resolution linear waveform generation (ALWG)
terize the dynamic behavior of solar are both 100 μs, which is sufficient function (please see Figure 14).
cells. As previously discussed, the to evaluate the solar cells exhibiting The ALWG function enables you to
Mott-Schottky Plot, Nyquist plot and relatively slow transient responses to synthesize a variety of waveforms
DLCP are derived from capacitance changes in their condition. with 10 ns programmable resolution.
measurements and they can show The WGFMU has two modes, a PG
If the devices require IV measurement mode and a Fast IV mode, and Table 5
parameters such as the Nc and Ndl
at a sampling rate faster than 100 summarizes the functions and ranges
distribution over W.
μs, the B1500A’s WGFMU module of the WGFMU in both modes.
In addition to basic DC bias voltage is a possible option to evaluate
sweep capability, the B1500A’s
MFCMU also possesses frequency PG mode
WGFMU
sweep and AC bias voltage sweep
capabilities, which are required to
50 Ω V
evaluate the capacitance characteris-
tics of solar cells. Table 4 summarizes
the MFCMU’s supported measure- Arbitrary linear Output
ment ranges. In addition to eliminat- waveform
generator
ing the need for a separate external
capacitance meter, the B1500A’s A
MFCMU is completely integrated with V
its SMUs so that DC bias voltages up
to ±100 V can be applied to the solar
Fast IV mode
cell.
Figure 14. Simplified WGFMU circuit diagram
Time domain measurement
capabilities
Maximum Minimum Resolution
Time domain measurements can Frequency 5 MHz 1 kHz 1 mHz (Minimum)
be used to evaluate recombination Output signal level (rms) 250 mV 10 mV 1 mV
parameters such as τ, S and Ld. DC bias voltage 25 V -25 V 1 mV
(without SMU) (without SMU)
High-speed sampling capabilities are
100 V -100 V
required to make these types of time
(with SMU) (with SMU)
domain measurements. An oscil-
DC bias current 10 mA — —
loscope combined with some sort (50 Ω range)
of an IV converter is often used for
this purpose, although this involves Table 4. MFCMU measurement capabilities
integrating together a rack-and-stack
solution. Mode Function V force V measure I measure
The SMUs also have a time sampling ranges ranges ranges
function that enables you to make Fast IV V force / I measure -3 V to 3 V -5 V to 5 V 1 μA
voltage versus time (V-t) and current V force / V measure -5 V to 5 V -10 V to 10 V 10 μA
-10 V to 0 V 100 μA
versus time (I-t) sampling measure-
0 V to 10 V 1 μA
ments. The sampling function can be
10 μA
PG V force / V measure -3 V to 3 V -5 V to 5 V —
-5 V to 5 V
Table 5. WGFMU functions and measurement ranges
9
Software environment The B1500A mainframe has ten avail- external instruments, such as light
able slots, allowing you to make a sources and temperature chambers.
EasyEXPERT is a powerful software B1500A configuration with up to ten You can develop an automated mea-
environment resident on the B1500A. SMUs. You can operate all of these surement system using the B1500A
EasyEXPERT includes over 230 appli- SMUs in parallel when measuring as the system controller for a variety
solar cells to improve throughput. In of other instruments (please see
cation tests, conveniently organized
addition, B1500A can communicate Figure 16).
into logical categories. These applica-
through GPIB etc with the other
tion tests enable you to begin making
productive solar cell parametric
measurements immediately, eliminat- SCUU
ing the need to spend hours or days
learning how to set up the instrument
hardware. In addition, EasyEXPERT
SMU1
provides multiple data analysis fea-
tures, including the ability to plot two
or more sets of measurement data
on the same Y axis, the capability to SMU2
add multiple markers and pointers to
graphs to emphasize important data
points, and the ability to automati-
cally calculate parameters from the Hc
Hp
measurement results. All of the appli- Lp
Lc
cation tests are user-modifiable, so it
is easy to change them to meet the MFCMU
unique needs of your devices, such
Figure 15. Details of SCUU connections
as adding additional measurement
parameters or post-measurement
calculated parameters. B1500A
Additional measurement SMUs
capabilities GNDU
GPIB etc.
The SMU CMU Unify Unit (SCUU)
is useful if you need to make both
IV and capacitance measurements Light
(please see Figure 15). Because the source
SMUs and the MFCMU have different
connector types, it is inconvenient
and time-consuming to manually
change the cabling connections when
switching between IV measurements
and capacitance measurements. The
SCUU eliminates the need to manu-
ally change the cable connections. Measurement in parallel
The B1500A application note B1500-3
(5989-3608EN) explains the SCUU
operation in greater detail.
Chamber
10
Sample application tests
11
Solar Cell IV Rev makes a reverse
biased IV measurement and estimates
the solar cell Rsh from the slope of the
IV curve in the linear region.
12
Solar Cell Cp-Freq Log measures
solar cell capacitance versus AC
signal frequency to determine
the frequency dependency of the
capacitance. Measurement conditions
such as the start frequency, the stop
frequency and the applied voltage can
be specified.
13
Solar Cell DLCP also makes a
capacitance measurement while
changing both the DC bias and AC
bias voltages and estimates Ndl from
the result. After the measurement,
the profile distance dependency of Ndl
is shown. Measurement conditions
such as the start DC voltage, the stop
DC voltage, the step DC voltage, the
start value, the stop value and the
step value of the peak-to-peak voltage
of the AC signal, and the frequency of
the AC signal can be specified.
Conclusion
This application note has shown how the B1500A can be used to evaluate the
characteristics of solar cells. The B1500A has a variety of modules (SMUs,
MFCMU, WGFMU and HV-SPGU) that support all aspects of solar cell paramet-
ric test, from basic IV and capacitance characterization (such as CV, CVac and
Cf) to ultra-fast IV time domain measurements.
In addition to the over 230 application tests that are provided standard with
EasyEXPERT, sample application tests for solar cell evaluation are available
and can be downloaded from Agilent Web Site. This makes it easy to extract
the basic solar cell parameters without the need to spend lots of time develop-
ing test programs.
14
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