Professional Documents
Culture Documents
Chapter 08
Periodic Relationships Among the Elements
2. The law of octaves states that every eighth element has similar properties when arranged in
order of increasing
A. nuclear binding energy.
B. number of electrons.
C. number of neutrons.
D. atomic mass.
E. atomic number.
8-1
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
3. As opposed to early periodic tables based on the law of octaves, modern periodic tables
arrange the elements in order of increasing
A. nuclear binding energy.
B. number of neutrons.
C. atomic mass.
D. atomic number.
E. atomic size.
8-2
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
8-3
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
8. The alkali metal elements are found in _______ of the periodic table.
A. Group 1A
B. Group 2A
C. Group 3A
D. Period 7
E. Period 1
8-4
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
11. Which of the following elements is found as a monatomic species in its most stable form?
A. sulfur
B. oxygen
C. hydrogen
D. argon
E. phosphorus
12. Which of the following elements is found as a monatomic species in its most stable form?
A. nitrogen
B. neon
C. sulfur
D. chlorine
E. fluorine
13. Which of the following elements is found as a diatomic species in its most stable form?
A. bromine
B. neon
C. sulfur
D. xenon
E. phosphorus
8-5
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
14. Which of the following is the general electron configuration for the outermost electrons of
the elements in Group 5A?
A. ns2np6
B. ns2np5
C. ns2np4
D. ns2np3
E. ns2np1
15. Which of the following is the general electron configuration for the outermost electrons of
elements in the alkaline earth group?
A. ns1
B. ns2
C. ns2np4
D. ns2np5
E. ns2np6(n -1)d6
8-6
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
16. Which of the following is the general electron configuration for the outermost electrons of
the halogens?
A. ns2np6
B. ns2np5
C. ns2np6(n -1)d7
D. ns1
E. ns2np7
17. Which of the following is the general electron configuration for the outermost electrons of
the noble gases?
A. ns2np6
B. ns2np5
C. ns2np4
D. ns2np3
E. ns2
8-7
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
18. An element with the general electron configuration for its outermost electrons of ns2np1
would be in which element group?
A. 2A
B. 3A
C. 4A
D. 5A
E. 8A
19. In what row and group of the periodic table would you find the element with the electron
configuration [Kr]5s24d105p2?
A. row 4, group 4A
B. row 4, group 5A
C. row 5, group 4A
D. row 5, group 5A
E. none of the above
8-8
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
20. Consider the element with the electron configuration [Kr]5s24d7. This element is
A. a representative element.
B. a transition metal.
C. a nonmetal.
D. an actinide element.
E. a noble gas.
21. Consider the element with the electron configuration [Kr]5s24d105p5. This element is
A. a representative element
B. a transition metal
C. an alkali metal
D. an actinide element
E. a noble gas
8-9
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
22. Consider the element with the electron configuration [Xe]6s24f7. This element is
A. a representative element
B. a lanthanide element
C. a nonmetal
D. an actinide element
E. a noble gas
23. The representative elements are those with unfilled energy levels in which the "last
electron" was added to
A. an s orbital.
B. an s or p orbital.
C. a d orbital.
D. a p or d orbital.
E. an f orbital.
8-10
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
8-11
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
26. How many electrons does a sulfur atom need to fill its outermost s and p subshells?
A. 6
B. 8
C. 4
D. 2
E. 1
27. How many electrons does a nitrogen atom need to fill its outermost s and p subshells?
A. 5
B. 3
C. 1
D. 8
E. 0
28. How many electrons does a bromine atom need to fill its outermost s and p subshells?
A. 8
B. 7
C. 5
D. 3
E. 1
8-12
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
8-13
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
33. Concerning the electron configuration of fluorine, 1s22s22p5 which of the following
represents the core electrons only?
A. 1s2
B. 1s22s2
C. 1s22s22p5
D. 2s22p5
E. 2p5
8-14
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
34. Concerning the electron configuration of sulfur, 1s22s22p63s23p4, which of the following
represents the core electrons only?
A. 1s2
B. 1s22s2
C. 1s22s22p6
D. 1s22s22p63s2
E. 3s23p4
8-15
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
8-16
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
39. Which two electron configurations represent elements that would have similar chemical
properties?
(1) 1s22s22p4 (2) 1s22s22p5 (3) [Ar]4s23d5 (4) [Ar]4s23d104p5
A. (1) and (2)
B. (1) and (3)
C. (2) and (3)
D. (2) and (4)
E. (3) and (4)
8-17
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
40. Which of the following make an isoelectronic pair: Cl–, O2–, F, Ca2+, Fe3+?
A. Ca2+ and Fe3+
B. O2– and F
C. F and Cl–
D. Cl– and Ca2+
E. None of the above.
8-18
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
42. Which one of the following is not isoelectronic with the others: Br–, Rb+, Se2–, Sr2+, Te2–?
A. Br–
B. Rb+
C. Se2–
D. Sr2+
E. Te2–
8-19
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
45. Which of the following is the electron configuration for the aluminum ion?
A. 1s22s22p63s2
B. 1s22s22p63s23p2
C. 1s22s22p63s23p1
D. 1s22s22p6
E. 1s22s22p63s23p4
8-20
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
46. Which of the following is the electron configuration for the bromide ion?
A. [Ar]
B. [Ar]4s23d104p7
C. [Kr]
D. [Kr]5s24d105p7
E. [Xe]
8-21
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
48. Which of the following is the electron configuration of the iron(III) ion?
A. [Ar]3d5
B. [Ar]4s13d5
C. [Ar]4s23d3
D. [Ar]3d6
E. [Ar]4s23d9
8-22
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
50. The sulfide ion, S2–, is isoelectronic with which one of the following?
A. O2–
B. F–
C. Na+
D. Al3+
E. K+
51. Which one of the following does not have [Kr] as its electronic configuration?
A. Se2–
B. Br–
C. Rb+
D. Y3+
E. Zn2+
8-23
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
52. Which one of the following does not have [Xe] as its electronic configuration?
A. Te2–
B. I–
C. Cs+
D. Ba2+
E. Sn4+
8-24
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
54. How many 3d electrons does the manganese(II) ion, Mn2+, have?
A. 3
B. 4
C. 5
D. 6
E. 7
8-25
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
56. Which of the following ground-state ions has the largest number of unpaired electrons?
A. Cr2+
B. Mn2+
C. Ni2+
D. Cu+
E. Co2+
8-26
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
58. The effective nuclear charge (Zeff) felt by the outermost electrons is the strongest for
which of the following elements?
A. B
B. C
C. N
D. O
E. F
59. The effective nuclear charge (Zeff) felt by the outermost electrons is the strongest for
which of the following elements?
A. Al
B. Si
C. P
D. S
E. Cl
8-27
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
60. Which of the atoms listed below has the smallest radius?
A. Al
B. P
C. As
D. Te
E. Na
61. Which of the atoms listed below has the largest radius?
A. Cl
B. I
C. P
D. Sb
E. Se
8-28
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
62. Which of the elements listed below has the greatest atomic radius?
A. B
B. Al
C. S
D. P
E. Si
63. Which one of the following ions has the largest radius?
A. Cl–
B. K+
C. S2–
D. Na+
E. O2–
8-29
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
64. Arrange the following ions in order of increasing ionic radius: K+, P3– , S2–, Cl– increasing
radius
A. K+ < Cl– < S2– < P3–
B. K+ < P3– < S2– < Cl–
C. P3– < S2– < Cl– < K+
D. Cl– < S2– < P3– < K+
E. Cl– < S2– < K+ < P3–
65. Arrange the following ions in order of decreasing ionic radius: Al3+, Mg2+, Na+, O2–
.decreasing radius
A. Al3+ > Mg2+ > O2– > Na+
B. Al3+ > Mg2+ > Na+ > O2–
C. Na+ > Mg2+ > Al3+ > O2–
D. O2– > Al3+ > Mg2+ > Na+
E. O2– > Na+ > Mg2+ > Al3+
8-30
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
66. For which of the following reactions is the enthalpy change equal to the second ionization
energy of nitrogen?
A. N2+(g) N3+(g) + e–
B. N2+(g) + e– N+(g)
C. N(g) N2+(g) + 2e–
D. N–(g) + e– N2–(g)
E. N+(g) N2+(g) + e–
67. For which of the following reactions is the enthalpy change equal to the third ionization
energy of vanadium?
A. V2+(g) V3+(g) + e–
B. V3+(g) + e– V2+(g)
C. V(g) V3+(g) + 3e–
D. V2–(g) + e– V3–(g)
E. V3+(g) V4+(g) + e–
8-31
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
68. Which of the elements listed below has the highest first ionization energy?
A. He
B. Ne
C. Ar
D. Kr
E. Xe
69. Which of the elements listed below has the highest first ionization energy?
A. C
B. Ge
C. P
D. O
E. Se
8-32
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
70. Which of the elements listed below has the smallest first ionization energy?
A. C
B. Ge
C. P
D. O
E. Se
71. Which of the following elements has the smallest first ionization energy?
A. Cl
B. Na
C. Be
D. K
E. As
8-33
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
72. Which of the following elements has the smallest ionization energy?
A. Li
B. Na
C. Be
D. K
E. Rb
73. Which element will display an unusually large jump in ionization energy values between
I3 and I4, its third and fourth ionization energies?
A. Na
B. Mg
C. Al
D. Si
E. P
8-34
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
74. For silicon atoms, which ionization energy will show an exceptionally large increase over
the preceding ionization energy?
A. 2nd
B. 3rd
C. 4th
D. 5th
E. 6th
75. For phosphorus atoms, which ionization energy will show an exceptionally large increase
over the previous ionization energy?
A. 2nd
B. 3rd
C. 4th
D. 5th
E. 6th
8-35
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
76.
Which of the elements listed below has the following pattern for its first six ionization energies? (I1 = first ionization energy,
I2 = second ionization energy, etc.)
A. Ca
B. Si
C. Al
D. Se
E. P
8-36
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
77. The successive ionization energies of a certain element are I1= 589.5 kJ/mol, I2 =1145
kJ/mol, I3= 4900 kJ/mol, I4 = 6500 kJ/mol, and I5 = 8100 kJ/mol. This pattern of ionization
energies suggests that the unknown element is
A. K
B. Si
C. As
D. Ca
E. S
78. The successive ionization energies of a certain element are I1= 577.9 kJ/mol, I2 = 1820
kJ/mol, I3= 2750 kJ/mol, I4 = 11,600 kJ/mol, and I5 = 14,800 kJ/mol. This pattern of
ionization energies suggests that the unknown element is
A. K
B. Al
C. Cl
D. Se
E. Kr
8-37
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
79. Which of the following elements has the greatest electron affinity (largest positive
value)?
A. Mg
B. Al
C. Si
D. P
E. S
80. Which of the following elements has the greatest electron affinity (largest positive
value)?
A. K
B. Br
C. As
D. Ar
E. I
8-38
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
81. Which of the following atoms has the greatest electron affinity (largest positive value)?
A. S
B. P
C. Ga
D. Li
E. Br
82. The first ionization energy of sodium is 495.9 kJ/mol. The energy change for the reaction
Na(s) Na+(g) + e– is therefore
A. 495.9 kJ/mol.
B. less than 495.9 kJ/mol.
C. greater than 495.9 kJ/mol.
D. is equal to the electron affinity of sodium.
E. is equal to the second ionization energy of sodium.
8-39
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
83. The first ionization energy of mercury is 1006 kJ/mol. The energy change for the reaction
Hg(l) Hg+(g) + e– is therefore
A. 1006 kJ/mol.
B. greater than 1006 kJ/mol.
C. less than 1006 kJ/mol.
D. is equal to the electron affinity of mercury.
E. is equal to the second ionization energy of mercury.
8-40
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
8-41
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
8-42
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
90. Which of the following reactants can be combined to produce hydrogen gas as a product?
A. N2O5(s) + H2O(l)
B. H2(g) + Cl2(g)
C. 2 F2(g) + 2H2O(l)
D. Mg(s) + 2H+(aq)
E. 2H2(g) + O2(g)
8-43
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
91. Which of the following reactants can be combined to produce a basic oxide as a product?
A. Cl2O7(l) + H2O(l)
B. P4O10(s) + 6H2O(l)
C. 4Li(s) + O2(g)
D. Al2O3(s) + 6HCl(aq)
E. MgO(s) + 2HCl(aq)
92. Which pair of elements from different groups resemble each other the most in their
chemical properties?
A. Be and B
B. Al and Si
C. Li and Be
D. Al and Be
E. Be and C
8-44
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
93. In a surprisingly large number of their properties, beryllium resembles aluminum and
boron resembles silicon. Such a relationship is called
A. amphoterism.
B. an allotropic relationship.
C. a diagonal relationship.
D. the periodic law.
E. an isoelectronic series.
94. Which of the following elements has the greatest metallic character?
A. Br
B. F
C. Ge
D. Mn
E. Sc
8-45
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
95. Which of the following elements has the greatest metallic character?
A. Br
B. Se
C. Ni
D. As
E. Si
96. Which of the following elements has the greatest metallic character?
A. Ca
B. Mg
C. Ba
D. As
E. Se
8-46
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
97. If the radius of atom X is greater than the radius of atom Y, then it is also likely that
A. X has a larger electron affinity than Y does.
B. X has a larger effective nuclear charge than Y does.
C. X has greater metallic character than Y does.
D. X has a larger first ionization energy than Y does.
E. X is a poorer conductor of electricity than Y when in the solid state.
8-47
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
8-48
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
8-49
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
8-50
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
8-51
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
iron
F.
beryllium
8-52
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
iron
F.
beryllium
109. The second ionization energy of Mg is ________ than its first ionization energy, and is
__________ than the second ionization energy of Na.
A. higher, higher
B. lower, higher
C. higher, lower
D. lower, lower
8-53
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
110. Consider the following reaction: 3Li + Z Li3Z. What is the formula for the compound
if we substitute sodium for lithium?
A. NaZ
B. Na2Z
C. NaZ2
D. Na3Z
E. NaZ3
111. Consider the following reaction: 3Li + Z Li3Z. What is the formula for the compound
if we substitute magnesium for lithium?
A. MgZ
B. Mg2Z
C. MgZ2
D. Mg3Z
E. Mg3Z2
8-54
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
112. Consider the following reaction 2A + 3F2 2AF3. What is the formula for the reaction
product if we substitute iodine for fluorine?
A. A2I3
B. A3I2
C. AI3
D. A3I
E. AI
113. Consider the following reaction 2A + 3F2 2AF3. What is the formula for the reaction
product if we substitute sulfur for fluorine?
A. A2S3
B. A3S2
C. AS3
D. A3S
E. AS
8-55
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
8-56
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
8-57
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
8-58
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
8-59
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
125. Concerning the electron configuration of F, 1s22s22p5, which, if any, is the configuration
for the valence shell electrons only?
A. 1s22s22p5
B. 2p5
C. 1s2
D. 2s22p5
E. None of the above
126. Concerning the electron configuration of S2-, 1s22s22p63s23p6, which, if any, is the
configuration for the valence shell electrons only?
A. 1s22s22p63s23p6
B. 2s22p63s23p6
C. 1s22s22p6
D. 3s23p6
E. None of the above
8-60
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
127. Select True or False: The Mg2+ ion is smaller than F–, even though they are
isoelectronic.
TRUE
128. Select True or False: An I- ion has a larger radius than an I atom.
TRUE
129. Select True or False: As the effective nuclear charge decreases, the electrons are pulled
closer to the nucleus and thus the radius of the atom decreases.
FALSE
8-61
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
130.
Given the following melting point data, what is a reasonable estimate of the melting point of potassium?
A. Around 100oC
B. Around 40oC
C. Around 190oC
D. Around 60oC
E. Around 20oC
131. Consider the following reaction: 3Li + Z Li3Z. What is a reasonable guess for the
identity of element Z?
A. Be
B. B
C. C
D. N
E. None of the above
8-62
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
132. Consider the following reaction 2A + 3F2 2AF3. What is a reasonable guess for the
identity element A?
A. Mg
B. Al
C. Si
D. P
E. None of the above
8-63
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
8-64
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
136. The following successive ionization energies correspond to an element in the third row
of the periodic table: I1 = 786.3 kJ/mol, I2 =1,580 kJ/mol, I3= 3,230 kJ/mol, I4 = 4,360 kJ/mol,
I5 = 16,000, and I6 = 20,000 kJ/mol. Based on this pattern of ionization energies, identify the
element.
A. Sulfur
B. Phosphorous
C. Silicon
D. Aluminum
E. None of the above
137. Select True or False: The group 5A elements have relatively small electron affinities
compared to the neighboring nonmetals in the corresponding rows.
TRUE
138. Select True or False: The radii of ions are always smaller than the radii of the
corresponding atoms of the same element.
FALSE
8-65
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
140. Select True or False: The electron configuration of the outermost electrons of atoms of
the halogen group is ns2np7.
FALSE
141. Select True or False: Amphoteric oxides exhibit both acidic and basic properties.
TRUE
8-66
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Chapter 08 - Periodic Relationships Among the Elements
142. Select True or False: For Mg atoms a very large jump in the magnitudes of the ionization
energies will occur between the second and the third ionization energies.
TRUE
143. Select True or False: In general the effective nuclear charge felt by the outermost
electrons of an element increases when moving across a period.
TRUE
144. Select True or False: Sodium ions are more reactive than sodium atoms.
FALSE
8-67
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.