Q.

5 Complete the followingacid-base reactions and name the products:

(i) CH3CH2CH2NH2+ HCI

(ii) (C2H5)3N+ HCI
Q, 9. Convert:
(i) 3-Methylaniline into 3-nitrotoluene
(ii) Aniline into 1, 3, 5-tribromobenzene
Ilow will you convert
(J/Éthanoic acid to methanamine
(vÄ1ethanol to ethanoic acid
Y Ethanoic acid to propanoic acid
(v/ Nitromethane to dimethylamine
ii lexanenitrile to I-aminopentane
VEthanamine to methanamine
041ethanamine to ethanamine
(Y) Propanoic acid to ethanoic acid?
Bt2/KOH
Q. 8. Accomplish the followingconversions:
u Nitrobenzene to benzoic acid enzene to m-bromophenol
VMBenzoic acid to aniline (O—Anilineto 2, 4, 6-tribromofluorobenzene
2-phenylethanamine &Chlorobenzene to p-chloroaniline
U Benzyl chloride to
p-bromoaniline kö/'Benzamide to toluene
Aniline to
(if Aniline to benzyl alcohol
Give the structures ofA, В and С in the following reactions:
*aCN он- КаОН + Вп
(1 CH3CH21
Partia1 hydrolysis
Н20/Н+ хнз
2Yc6H5N2cl
cuCN
в
(iii СНзСН2Вг kCN LiAlH4 HN02
В
осс
FeJHCl NaN02+HCl Н2О/Н+
(&C6H5N02 273k д
уснзсоон NH3 NaOBr
в NaN02/HCl
Heat

(и
Fe,HCl нм» СбН50Н
C6H5N02
273k
в
Q. 11. Complete the f0110Mingreactions:
НЗРО: +
+ снсц + а)с.кон (ii) C6H5N2Cl +
(iiO + H2S04(conc.) C6HsN2Cl + С: НОН
сьнзхн: +
HBF4
(yii) C6HsX:Cl