Vidyamandir Classes

JEE Advanced Final Practice Assignment

Inorganic Chemistry
SINGLE CHOICE QUESTIONS
1. During refining of pig iron by bessemerization process, which of the following impurity is oxidized last.
(A) Si (B) Mn (C) S (D) C

warm
2. PCl5  H 2 (g)  X  Y
If molecular weight of ‘X’ is greater than that of ‘Y’ then compound ‘X’ reacts with :
(A) H 2 O() (B) Cl2 gas (C) O2 gas (D) All

3. Incorrect statement for borax is :

(A) Its aqueous solution acts as buffer
(B) Its aqueous solution is used to determine strength of dil. HCl using phenolphthalein
(C) It is used as acidic flux in brazing
(D) H-bonding is present in borax
4. H2O2 acts as oxidizing agent with which of the following reagent :
(A) KMnO4 in basic medium (B) Fe2 (SO4 )3
(C) I2 in alkaline medium (D) HClO4

5. Milk of lime + SOCl 2 

 P  Q
Incorrect statement for compound‘P’ and ‘Q’ is :
(A) ‘Q’ produces observable change with hypo
(B) ‘P’ dissolves in excess of H2SO3
(C) ‘Q’ produces precipitate with aqueous solution of KF
(D) ‘P’ reacts with H2S gas in the presence of dilHCl
warm
6. K 4 [Fe(CN)6 ]  conc.H 2SO 4  products
Incorrect statement for products is :
(A) Gaseous product is used in Mond’s process
(B) Oxidation state of iron remains same
(C) One of the cations is derived from nonmetals
(D) Gaseous product obtained is acidic

7. 3HgO  HgCO3 (s)  2PbS(s)  Products
Incorrect statements about products is :
(A) One of the liberated gas can decolourize aqueous KMnO4 solution.
(B) Mercury is obtained in elemental state
(C) Lead is obtained in the form of PbO2
(D) PbS is roasted into PbO and SO2

8. Incorrect statement for complex ions [Mn(H 2 O) 6 ]2 and [MnBr4 ]2 is :

(A) Intensity of colour in [MnBr4 ]2 is less than [Mn(H 2 O)6 ]2 

(B) Both have same magnetic moment
(C) Stability : [Mn(H 2O)6 ]2  [MnBr4 ]2 

(D) Valence shell d- orbitals of Mn 2  are used in its hybridization in [Mn(H 2O)6 ]2

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9. When metal cation M forms homoleptic octahedral complex with following ligands, then for which ligand there
is maximum increase in entropy.
(A) NH3 (B) en (C) EDTA 4  (D) ox


10. Na(s)  H 2 (g)  P
180 C
P  BF3 
 Q   NaF
Incorrect statement for compound ‘Q’ is :
(A) Its thermal decomposition liberates H 2 gas
(B) It is an electron deficient compound
(C) Bond order of CO decreases when it reacts with ‘Q’
(D) Four hydrogen atoms can lie in a plane of molecule ‘Q’

11. In which oxyacid of phosphorus, both ‘P – P as well as ‘P – H’ bonds are present.

(A) H4P2O6 (B) H4P4O12 (C) H4P2O5 (D) None of these

12. Hydrolysis of which of the following compound does not produce gaseous product.
(A) Ca3P2 (B) CaH2 (C) Mg3N2 (D) CaO

13. H2O2 does not act as reductant with :

(A) Acidified KMnO4 solution (B) Ag2 O
(C) H2S gas (D) O3

14. Nitric oxide gas is evolved by :

(A) Zn + dilHNO3 (B) Mg + 2% HNO3
(C) Pb + Hot dilHNO3 (D) Hg + very dilute HNO3

15. XeF4 does not act as fluoride donor with :

(A) BF3 (B) SF6 (C) PF5 (D) CIF5

16. H3 BO3  Compound ' X '  Y
If product ‘Y’ produces green flame, then compound ‘X’ cannot be :
(A) HF (B) CH3OH in presence of conc. H2SO 4
(C) CoSO4 (D) All
17. Which of the following combination of reagents does not produce black precipitate :
(A) CuSO4soln. + PH3(g) (B) AgNO3 + warm soln. of Na2S2O3
(C) BiCl3 + KI (D) CdCl2 + KI soln.
18. Homoleptic carbonyl compound is not formed by :
(A) Cr (B) Fe (C) V (D) Zn

19. Select correct match :

Column I Column II

(P) Geometrical isomerism 1. [Cr(ox)(H 2 O) 2 (NH3 )2 ]Br

(Q) Hydrate isomerism 2. [Pt(ox)(H 2O) 4 ]Cl2

(R) Optical isomerism 3. [Co(NO2 )(SCN)(H2O)4 ]Br

(S) Ionisation isomerism 4. [IrBr(H 2 O)(NH3 )4 ]Br

Codes :
P Q R S P Q R S
(A) 4 2 1 3 (B) 3 4 1 2
(C) 4 3 1 2 (D) 3 4 2 1

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20. Select correct match :
Column I Column II

(P) Sn 1. Cupellation

(Q) Ag 2. Liquation

(R) Zn 3. Parke’s Process

(S) Pb 4. Distillation

Codes :
P Q R S P Q R S
(A) 2 1 4 3 (B) 2 3 1 4
(C) 2 1 3 4 (D) 4 3 1 2
21. Which of the following combination of reactants does not produce hydrogen gas :
Warm R .T
(A) Sn  NaOH 
 (B) NaH  H 2 O 
In the presence Warm
(C) PH3  O2  (D) K  NH3 (liquid) 

of P4 H 4

22. HOMO (Highest occupied M.O.) of which of the following diamagnetic molecular species is having  -bonding
character.
(A) C2 (B) N 22  (C) O22  (D) B22

23. Correct order C – O bond order :

(A) CO  C2 O42   CO 2 (B) CO  CO2  C2 O42 
(C) CO 2  CO   C 2 O 42 (D) C2 O42   CO 2  CO

24. The set representing the correct order of ionic radius is :

(A) Na   Mg   Al3  Li   Be 2 (B) Na   Li   Mg 2   Al3  Be2 
(C) Na   Mg 2  Li   Al3  Be2  (D) Na   Mg 2   Li   Be 

25. The electronic configuration of four elements are

(I) [Kr]5s1 (II) [Rn]5f 14 6d1 7s 2 (III) [Ar]3d10 4s2 4p5 (IV) [Ar]3d 6 4s 2
Consider the following statements :
(i) I shows variable oxidation state
(ii) II is a d-block element
(iii) The compound formed between I and III is covalent
(iv) IV shows single oxidation state
Which statements is True (T) or false (F)
(A) FTFF (B) FTFT (C) FFTF (D) FFFF
26. Which of the following statements is correct regarding following process.
E. A. I.E. I.E I.E.
(i) Cl  Cl (ii) Cl 
 Cl (iii) Cl  Cl (iv) Cl 
 Cl2
(A) | I.E. of process (ii) | = |E.A. of process (i) |
(B) | I.E. of process (iii) | = | I.E. of process (ii) |
(C) | I.E. of process (iv) | = | E.A. of process (i) |
(D) | I.E. of process (iv) | = | I.E. of process (iii) |

27. Which of the following compounds does not have four equal bond lengths.
(A) ClF5 (B) XeOF4 (C) B2Cl4 (D) Be2Cl4

28. Number of geometrical isomers of complex ion [M(AA) b2cd]n± in which both ‘b’ monodentate ligands are
present at anti (trans) position of geometry.
(A) 1 (B) 2 (C) 3 (D) None of these

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29. Which charge on CO molecule would give its bond order > 3.0 ?
(A) +1 (B) +2 (C) –1 (D) Zero
30. Increasing order of strength of hydrogen bond in the following mentioned linkages is :
(i) O  H S (ii) S H  O (iii) F  H  F (iv) F H  O
(A) (i) < (ii) < (iv) < (iii) (B) (ii) < (i) < (iv) < (iii)
(C) (i) < (ii) < (iii) < (iv) (D) (ii) < (i) < (iii) < (iv)

31. Which of the following low spin complex has its magnetic moment = 2.8 B.M.
(A) [V(CN) 6 ]3 (B) [Ni(CN5 )]3 (C) [Cr(NH3 )6 ]2  (D) [Ni(en)3 ]2

32. Which of the following is not flexidentate legend ?

(A) CO32 (B) SCN  (C) S2 O32 (D) NO2

33. Consider the molecular formula of following complexes.

(i) CoCl3.6NH3 (ii) CoCl3. 5NH3 (iii) CoCl3.4NH3
If number of coordinated NH3 molecules in (i), (ii) and (iii) complexes respectively are 6, 5 and 4, then primary
valency of metal cation in (i), (ii) and (iii) respectively are :
(A) 6, 5, 4 (B) 3, 2, 1 (C) 0, 1, 2 (D) 3, 3, 3

34. Select the INCORRECT statements :

(A) B(CH3 )3 is a  bonded organometallic compound

(B) K[PtCl3 (2  C 2 H 4 )] is  bonded organometallic compound

(C) Vitamin B12 is a coordination compound of cobalt.
(D) RhCl(PPh3)3 (Named as Wilkinson catalyst) has sp3 hybridised central metal cation and is used for
Hydrogenation of alkenes.

35. On strongly heating, mixture of Cu2O and Cu2S gives :

(A) Cu + SO2 (B) Cu + SO3 (C) CuO + CuS (D) Cu2SO3

36. Polyphosphate are used as water softening agents because they :

(A) form soluble complexes with anionic species
(B) precipitate anionic species
(C) form soluble complexes with cationic species
(D) precipitate cationic species

37. Reduction of BaSO 4 with carbon gives :

(A) BaSO3 (B) BaS (C) BaS2O3 (D) Ba

38. MgBr2 and MgI2 are soluble in acetone because of :

(A) Their ionic nature (B) Their more covalent nature
(C) Their metallic nature (D) None of these

39. Which of the following is not responsible for colour of the compound
(A) Polarization (B) d-d transition
(C) Charge transfer spectra (D) Dipole moment

40. In which of the following molecule central atom has higher % s-character in its bond pair ?
(A) AsH3 (B) GeH 4 (C) P4 (D) H 2Se

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MULTIPLE CHOICE QUESTIONS
41. KO2 produces observable change with :
(A) Mg2+(aq) (B) Fe2+(aq) (C) Ba2+(aq) (D) Cr3+(aq)

42. Lowest Unoccupied Molecular Orbital (LUMO) of which of the following molecular species has centre of
symmetry :
(A) N2 (B) C2 (C) O2 (D) Li2

43. Correct statement(s) for complex compound CoBrCl2 2en is/are :

(A) It exhibits ionization isomerization
(B) One of the geometrical isomers exhibits optical activity
(C) All stereoisomers exhibit optical activity
(D) Its structural isomers can be distinguished by AgNO3 solution

44. Fe3 (aq)  Sn 2  (aq) 

PQ
If aqueous solution of cation ‘Q’ reacts with H2S gas, then which of the following reagent(s) can be used to
identify cation ‘P’ from its aqueous solution :
(A) dil. HNO3 (B) K3[Fe(CN)6] (C) Na2O2 (D) SO2gas

45. Complexes [Ni(dmg)2] and [Ni(NH3)6]2+ differ in following characteristics :

(A) Colour
(B) Stability
(C) Magnetic moment
(D) Maximum number of N-atoms that lie in a plane is equal to four

46. Which of the following process is/are common in the commercial extraction of lead and copper :
(A) Self reduction (B) Poling
(C) Electrolytic refining (D) Parke’s process

47. For reactions :

R .T.
SO 2 (g)  Cl2 (g)  X
warm
X  P4  Y  Z
Y  P4 O10   POCl3
Compounds ‘X’, ‘Y’ and ‘Z’ are :
(A) SO2Cl2 (B) PCl3 (C) SO2 (D) SOCl2

48. Pair(s) of co-ordination compounds that have different colour :

(A) [Ni(H 2 O)6 ]2  , [Ni(NH3 )6 ]2  (B) [NiCl4 ]2  , [CuCl4 ]3

(C) [Zn(NH3 )4 ]2 ,[Cd(CN)4 ]2  (D) Cis  [CoCl2 (NH3 )4 ]Cl, trans  [CoCl2 (NH 3 )4 ]Cl

49. Statement(s) which favour zinc metal to be used as solvent in Parke’s process.
(A) For any composition, zinc and lead do not attain a common melting point.
(B) Zinc can be recovered from zinc-silver layer by distillation
(C) Zinc is less denser than lead
(D) Silver is more soluble in lead than in zinc.

50. Which of the following combination(s) of reagents can produce halogen/pseudohalogen ?

(A) CaBr 2  conc. H 2SO4 (B) Fe3 (aq)  KI
(C) Cu 2  (aq)  KCN (D) CrO3  dilHBr

51. Correct statement(s) for complex compound [CoBr(NCS) (H2O) (NH3)3] (NO2)
(A) Its Ionization isomer is diamagnetic
(B) It has one pair of enantiomers
(C) In one of its optical isomers, Br  and NCS are at trans position
(D) It is less stable than [Co(en)3)3+.

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52. Which of the following stage(s) are involved in the extraction of blister copper from chalcopyrite :
(A) Bessemerization (B) Roasting
(C) Poling (D) Slag formation

53. Which of the following compound(s) on thermal decomposition produce residue that does not oxidize HCl acid ?
(A) K 2SO 4 .Cr2 (SO4 )2 24H 2 O (B) KMnO4
(C) FeSO4 .7H 2 O (D) 2CuCO3Cu(OH)2

54. Acidic character of HF increases appreciably on mixing it with :

(A) XeF2 (B) BF3 (C) PF5 (D) SiF4

55. Residue of metallic silver is obtained when, which of the following compounds is added into aqueous AgNO3
solution :
(A) H3PO2 (B) Adding Na2S2O 3 followed by warming
(C) Adding Na2SO3 followed by boiling (D) Addition Na2CO3followed by boiling

56. PCl5  Cu  X  Y
If aqueous solution of Y is acidic then correct statement(s) is/are :
(A) one of the hydrolysed product of ‘Y’ undergoes tautomerism
(B) On passing NH3 gas into solution of ‘X’ , its colour is intensified
(C) ‘X’ gives chocolate brown colour ppt with K4[Fe(CN)6]
(D) ‘X’ produces precipitates with NH4SCN

57. Blue colouration is observed in presence of starch for which of the following reaction(s) :
atm air
(A) I (aq)  H  (aq) 
 (B) I (aq)  Fe3 (aq) 

(C) IO3 (aq)  SO 2 (g) 
 (D) I (aq)  NO 2 (aq)  H  (aq) 

lim ited

58. Which of the following compound(s) can give precipitate with solution of chrome alum :
(A) BaCl2 (B) Na2CO3 (C) (NH4)2S (D) excess KOH


59. For reaction : Sn  2PCl5  X  2Y
Correct statement(s) is/are :
(A) HgCl2 changes to black residue with excess of X
(B) Oxyacid obtained from hydrolysis of Y, can undergo tautomeric change
(C) ‘X’ is soluble in excess of NaOH
(D) Y is polar and has plane of symmetry
60. Which of the following structure is planar ?
(A) Na 3 B3 O6 (B) I2 Cl6
(C) Sheet silicate (D) Inorganic graphite layer

61. Pair(s) of cations that can be separated by NH4OH solution.

(A) Pb2+(aq), Cu2+(aq) (B) Hg2+(aq), Ag+(aq)
3+ 2+
(C) Fe (aq), Mg (aq) (D) Ni2+(aq), Mn2+(aq)

KI excess
62. M n  (aq)  X 
 Y
KI
(coloured ppt)
colourless
solution 

Which of the following cation(s) respond to the above reaction ?

(A) Ag+(aq) (B) Pb2+(aq) (C) Bi3+(aq) (D) Hg2+(aq)

warm
63. Salt (solid) + conc. H 2 SO4  X
(Coloured gas)

If gas ‘X” undergoes disproportionation in NaOH solution, then which of the following salt(s) can respond to the
above reaction :
(A) NaCl (B) NaNO2 (C) NaNO3 (D) NaBr

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64. Select the correct order of periodic properties of species :
(A) Fe2   Fe3 : ionic radii (B) N  O : second ionization energy
(C) Cu  Zn : Atomic Radius (D) In  T : first ionization energy

65. Correct match is/are :

(A) AlN  MgO  MgF2 : Lattice energy
(B) N 2  N  O  O2 : Ionisation energy
(C) SF6  PF5  SiF4 : Lewis acidic character
(D) SiCl4  SiBr4  Sil4 : Electronegativity of Si

66. Incorrect order of bond angle is :

(A) OCl2  SF2  AsH3  H 2Se (B) NH3  PF3  PH3  H 2 S
(C) XeO4  ClO 4  SO42   CF4 (D) N(SiH3 )3  NH3  NMe3

67. Which of the following order is/are Correct for the given properties indicated against each ?
(A) [Cr(NH3 )6 ]3  [Mn(CN) 6 ]3  [V(CO) 6 ] : Magnetic moment (spin only value)

(B) [Co(CN) 6 ]3  [Co(NH 3 )6 ]3  [Co(H 2O)6 ]3 : 0 values

(C) [Ni(CO)4  [Co(CO) 4 ]  [Fe(CO) 4 ]2  : CO bond order

3 4 2
(D) [Fe(CN)6 ]  [Co(CN) 6 ]  [Ni(NH 3 ) 6 ] : Effective atomic number of metal ion

68. For reaction : NaF  XeF4 

 P , the correct statement(s) for anionic part of compound ‘P’ is/are :
(A) Six atoms lie in a plane
(B) Non polar
(C) Non axial d-orbital used in hybridization of xenon has two xz and yz nodal plnes.
(D) All bonds are equivalent

69. Octahedral complex which neither show ionization nor hydrate isomerism :
(A) [Fe(H2O)5NH3]SO4 (B) [Fe(H2O)5Cl]SO4
(C) [Co(NH3)4SO4]Cl (D) [Fe(H2O)5Cl]Cl

70. Which of the following set of species correctly represent sp3 hybridization of central atom and tetrahedral
geometry ?
(A) ClO 4 ,SO42  , Diamond, [Zn(H2O)4]2+ (B) SiO 44  ,[PCl 4 ] , SiC, HClO 4
(C) Ni(CO)4, SnCl4, Graphite, Ice (D) P4, [PtCl4]2–, SiF4, [Be(gly)2]2+
roast in air heating without air
71. Consider the following steps : Cu 2S 
 products (X)  Pr oducts (Y)
Select Correct statement(s) :
(A) Self – reduction is involved in above step.

(B) Disproportionation reaction (Cu 2S  Cu  CuS) is involved in above step.
(C) Products (X) is a mixture of Cu2O and Cu2S
(D) Products (Y) is a mixture of Cu and SO2

72. The complex [Fe(H2O)5(NO)]2+ is formed in the brown ring test for nitrates when freshly prepared FeSO4 solution
is added to aqueous solution of NO3 followed by addition of conc. H2SO4. Select the correct statement about this
complex :
(A) Colour observed is due to charge transfer
(B) It has iron in +1 oxidation state and nitrosyl as NO+
(C) It has magnetic moment of 3.87 BM confirming three unpaired electrons in Fe
(D) CFSE value is equal to 0.8 0

73. Reaction involves an increases in bond length :

(A)  O 2
O2  (B)  O 2
O2  (C)  N 2
N 2  (D)  B22 
B2 

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excess NaOH solution Y Reagent
74. CrO2 Cl2 (vapour) 
 X  Z
(Coloured so ln .) (Coloured ppt)
then reagent (Y) can be :
(A) Sr(NO3 ) 2 (B) Pb(NO3 )2 (C) AgNO3 (D) Ba(NO3 )2
75.

According to the given Ellingham diagram the correct option(s) is/are :


(A) Above T3, reaction 3MgO  2Al 
 Al 2 O3  3Mg occurs
(B) Carbon reduction of MgO is faster than that of Al2O3 above T4 temperature
(C) Above T4, Mg metal is extracted in vapour phase by carbon reduction of MgO
(D) Carbides of Al and Mg formed above T4. On hydrolysis do not liberate C2H2.
76. Which of the following complex(es) has / have only two stereoisomers :
(A) [PdBrCl(NO2)NH3)]– (B) [Zn(SCN)(H2O)(Gly)]
(C) [Co(acac) 3] (D) [CrBr3(H2O)(en)]

77. In which of the following complex(es) unpaired electron is lying in d-orbital of valance shell of metal cation ?
(A) [Cu(en)2]2+ (B) Fe(CO)5 (C) [Co(CN)6]4– (D) [Cu(NO2)5]3–

78. During the production of steel from Haematite which of the following statements is/are correct.
(A) Fe2O3 is reduced to Fe by carbon in reduction zone of blast furnance.
(B) Impurities of impure iron are removed by oxidation using Bessemer’s converter.
(C) spiegeleisan is added to wrought iron
(D) Phosphorus impurities are converted into slag which is used as fertilizer

79. In which of the following reaction(s) H2O 2 acts reducing agent ?

(A) H 2 O2  Cr2 O72  (aq)  H  (aq) 
 Cr 3 (aq)  O2   H 2 O
(B) H 2 O2  Cr 3 (aq)  OH  (aq) 
 CrO 42  (aq)
(C) Ag 2 O  H 2O 2 
 2Ag  O2   H 2O
(D) H 2 O2  MnO4 (aq)  H  
 Mn 2 (aq)  O2 

[x] reagent
80. [(H 2 O)4 Co(O2 )2 Co(H 2O)4 ] (SO 4 )2 
 [(H 2 O)4 Co(O 2 ) 2 Co(H 2 O) 4 ](SO 4 )
(I) (II)

In both the complex, Co has t 62g e0g configuration. Which option is CORRECT ?
(A) Complex (I) is Paramagnetic (B) Complex (II) is Diamagnetic
(C) (X) is oxidizing agent (D) (X) is reducing agent

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MATCHING MATCH TYPE
81. Match the following :
Column-I (species) Column-II (Characteristics)

(A) XeF5 (P) Non-polar and planar

(B) MnO 4 (Q) Species having equal bond angle and bond length


(C) C H3 (R) Both axial d-orbitals are involved in hybridisation

(D) I2 Cl6 (S) All non-axial d-orbitals are involved in hybridisation

82.
Column-I (Compounds) Column-II (Characteristics)

(A) PH3 (P) Exists in gaseous state at room temperature

(B) B2H6 (Q) Reacts with aqueous CuSO4 solution
(C) NH3 (R) Molecule acts as lewis base
(D) H2S (S) On hydrolysis hydrogen gas is liberated.
(T) Can exhibit reducing character.

83.
Column-I (Metal) Column-II (Characteristics)

(A) Cu (P) Self reduction is used for commercial extraction.

(B) Hg (Q) CO gas can reduce metal oxide
(C) Zn (R) Metal sulphide is soluble in excess of KCN solution.
(D) Fe (S) Carbonate ore of meal is found
x
(T) M (aq) ion oxidizes KI solution into I2.

84.
Column-I (Observations) Column-II ( Compounds)

(A) Coloured fumes are evolved on warming with conc. H2SO4 (P) Na(NH4)HPO4.4H2O
(B) Ammonia gas is evolved on heating (Q) NH4I
(C) Precipitate is formed with AgNO3 solution (R) KBr
(D) Coloured residue is obtained on heating (S) Pb(NO3)2

(T) FeCl3  6H 2 O

85.
Column-I (complex compounds) Column-II (Type of isomerism)

(A) [Ir(NO2) (H2O)5]Br2 (P) Hydrate isomerism

(B) [CoBr(SCN) (en)2](NO2) (Q) Cis isomers are optically active
(C) [Cr(acac)(H2O)4] (NO3)2 (R) Trans isomer(s) is/are optical isomers
(D) [PtCl(ONO)(H2O)2(en)]Cl2 (S) Linkage isomerism
(T) Does not exhibit geometrical isomerism

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 Vidyamandir Classes
86.
Column-I Column-II
[process used for commercial extraction of pure metal] (Metals)
(A) Self reduction (P) Fe
(B) Carbon reduction (Q) Cu
(C) Distillation (R) Pb
(D) Bessemerization (S) Hg
(T) Zn

87.
Column-I (Observations) Column-II (Reagents)

(A) Precipitate with Pb(CH3COO)2 (P) CuSO4

(B) Formation of precipitate with KI (Q) FeCl3
(C) Complex formation with Na2S2O3 solution (R) AgNO3
(D) Liberation of gas with (Zn + NaOH) (S) Hg(NO3) 2
(T) BiCl3

88.
Column-I (Observations) Column-II (Salt)

(A) Conc. H2SO4 plays its two roles (P) NaBr

(B) Liberation of coloured gas/vapour with K2Cr2O7(s) + Hot conc. H2SO4 (Q) Na2S
(C) Acidified KMnO4 is decolourized (R) Na2C2O4
(D) Vapour/gas is evolved on warming with dil H2SO4 and MnO2 (S) NaCl
(T) NaI

89.
Column I (Compound) Column II (observations of Thermal decomposition)

(A) FeC2 O4 (P) Coloured metal oxide is obtained as residue

(B) Mg(NO3 )2 (Q) Metal cation is involved in redox reaction

(C) FeSO4 (R) Paramagnetic gas is evoved

(D) HgCO3  Hg(OH)2 (S) Metallic residue is obtained finally

(T) Acidic gas is evolved

90.
Column-I Column-II
(Same characteristic of given pair) (Pair of complexes)

(A) Geometry of complexes (P) [Cu(en) 2 ]2  and[Ni(dmg)2 ]

(B) Type of Hybridisation (Q) [NiF6 ]2  and [IrF6 ]3

(C) Low spin complex (R) [Co(CO)4 ] and[Fe(CO)4 ]2 

(D) Magnetic behaviour (S) [Ni(en)3 ]2  and[Cr(NH3 ) 6 ]2

(T) [CuCl5 ]3 and[MnBr5 ]3

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91.
Column-I Column-II
(A) [Co(NO3 )(OH)(H 2 O)2 (NH3 ) 2 ]Br (P) Linkage isomerism

(B) [Pt(SCN)2 (en)(Py) 2 ]C2O 4 (Q) Ionization isomerism

(C) [PtBr(SCN)(H2 O) (NH3 ) (Py)2 ]Br2 (R) Even numbered optical isomers

(D) [PdCl(S2O3 )(en) (NH3 )2 ]Cl (S) Trans-isomers are greater than cis-isomers

(T) Cis-isomers are greater than trans-isomers

92.
Column-I Column-II

(A) Diamagnetic gas is evolved on warming with conc. H2SO 4 (P) Br  (aq)

(B) Acidified solution of given ion turns (KI + starch) solution blue (Q) S2 O32 (aq)

(C) Reacts with Cl2 water (R) NO2 (aq)

(D) Ag+ Salt of given ion dissolves in excess NH3 solution (S) S2  (aq)

(T) C2 O42  (aq)

93.
Column-I Column-II
(A) Chemical change is observed with excess Na2O 2 (P) FeSO4
(B) Metal sulphide ppt is formed with (NH4)2 S solution (Q) Pb(NO3)2
(C) Precipitate is formed with excess NaOH (R) MnSO4
(D) White ppt is formed with BaCl2 solution (S) AgNO 3
(T) Cr2(SO4)3

94.
Column-I Column-II
(A) Purification by oxidation method (P) Fe
(B) Carbon reduction method applied for commercial extraction of metal (Q) Zn
(C) Froth floatation method (R) Cu
(D) Electrolytic refining method (S) Ag
(T) Al

95.
Column-I Column-II

(A) Only three halogen atoms are lying in a plane (P) IO2 F2

(B) Fractional bond order is between central atom and oxygen atom (Q) XeO64

(C) p  d bond is present (R) POCl3

(D) d-orbital having no nodal plane is used in hybridization of central atom (S) CrO 2 F2

(T) SOF4

VMC | Chemistry 11 JEE Advanced Final Practice Assignment

 Vidyamandir Classes
96.
Column-I Column-II
(A) Undergoes complete hydrolysis with excess water (P) ClF5

(B) Can react with CsF (Q) BF3

(C) Molecule having only one type of bond angle (R) XeF6

(D) One of the final hydrolysed product reacts with silica present in glass (S) SF4

(T) SiF4

97.
Column-I Column-II
(A) Acid can undergo tautomeric change (P) H3PO3
(B) Undergoes disproportionation on heating (Q) HNO 2
(C) Changes colour of FeSO4 solution (R) H2SO3
(D) Decolourizes acidified KMnO4 solution (S) HClO4
(T) H2C2O4

SUBJECTIVE TYPE
98. Find out total number of C – Cu – C bond angle(s) in water soluble complex ‘P’ in following reaction

Cu 2 (aq)  KCN(aq)  water soluble complex (P)  Q
excess (Vapours)

99. Which of the following complex ions/compounds does/do NOT exhibit geometrical isomerism but exhibit optical
isomerism.
[Ni(dmg)2], [Ca(EDTA)2–, [Co(acac)Br4]2–, [Co(acac)3], [Zn(gly)2], [Pd(en)2]2+, [Be(bcac) (en)]+, [CrBr2(H2O) 4]+,
[IrBr2(CN) (NO2) (H2O) (NH3)]–.

100. In which of the following molecules or ions, dz2 orbital is used in bond formation.
[PlCl2(NH3)2], [CuCl5]3– , XeF4, ClF5,. [IrF6]3–, Fe(CO)5, [Zn(CN)4]2–, IO 2 F2

R.T.
101. For reaction : XeF6  OH  (aq) 
 Pr oducts
Find out the of sum of oxidation state of xenon atoms in products.

102. Consider the following reaction P4  KOH 

 PH3  X
How many P  H bonds are present in species X ?

103. Find the value of expression [X – Y] of lF5 molecle.

Where, X = total number of bond angle F  I  F , that are less than 90°.
Y = maximum number of atom(s) that lie in a plane having iodine atom,

104. Find out total number of species from the following which is/are tetrahedral w.r. to their respective central
atom/ion.
[NiCl2(PPh3)2], [AgF4]–, [Cd(CN)4]2–, [PtCl2(NH3)2], IF4+, [Ni(dmg)2], ClF4 , PCl4 , [Ag(S2O3)2]3–

105. Find out total number of compounds which are coloured :

Cu(BO2)2, NaCoPO4, Ag3PO4, Pb(OH)2, 2PbCO 3, Mg(NH4)PO4.6H2O, BiOI, ClO2, SnS, CdCl2

106. SO2, gas undergoes redox reaction with which of the following substance(s) or reagent(s)
Cl2(g), Fe2(SO4)3 soln., H2 S(g), FeSO4 soln., NalO3 soln., K2MnO4, (Al + NaOH soln.), (Zn + dil HCl), Cr2(SO4)3
solution.

VMC | Chemistry 12 JEE Advanced Final Practice Assignment

 Vidyamandir Classes
107. Find out total number of nonmetals from following which react with water.
N2, S8, F2, I2, P4, Br2, Boron, Si, Cl2

108. Find out maximum number of carbon atoms that can lie in a plane in [Cu(gly)2]

109. Find the number of species / molecules having at least four identical bond lengths.

XeO46  , H3 N NH 2 , TeCl4 , AsH 4 , XeF4 , N 2 O 4 , I2 Cl6 , B2 H6 , XeF5

110. NO3 (aq)  Zn  NaOH 

 [Zn(OH)4 ]2   X  (gas)

X(gas)  Mn 2 (aq)  H 2O 2   Y  (Brown ppt)

Oxidation state of Mn in brown ppt is ……..

111. From the following cations, find out total number of metal cation(s) which produce black sulphide on passing H2S
gas into their aqueous salt solution.
Hg2+(aq), Pb2+(aq), Cu2+(aq), Mn2+(aq), Fe2+(aq), Ni2+(aq), Co2+(aq), Fe3+(aq), Cd2+(aq)

112. Consider the complete hydrolysis of following compounds

complete
hydrolysis
Marshal’s acid + xH2O  
complete
hydrolysis
Xenonoxytetrafluoride + yH2O  
Then calculate the value of [x + y]

113. From the following given species, find out total number of species having partially filled HOMO (Highest
Occupied Molecular Orbital) of sigma character.
N 2 , N 2 , O 2 , C22  , B2 , H 2 , CO, NO, O 2

114. Find out number of geometrical isomers of complex ion [CrBrCl(NO2)2(en)]–, in which both NO2 ligands are
present at cis position of geometry.

115. A tetrahedron complex ion having molecular formula [M(CO)n]x± follows Sidwick’s rule of EAN and metal ‘M’
belongs to first transition series and 9th group. Find out number of unpaired electron(s) present in the carbonyl is :

750 atm ether

116. B2 O3  3H 2  2Al 
 ' X '  2BF3  6NaH
150C
Then maximum number of H atom(s) that can lie in same plane in compound ‘X’ is

117. Total number of compound(s) having ‘X – X’ linkage, (where X is 15th group element)
N2O4, N2O, P4O6, N2O3, N2H4, P4S10, N2O5, H4P2O6, H2N2O2.

118. How many molecular species will produce O2 on reaction with water at room temperature.
CrO5, XeOF4, I2, XeF4, Br2, XeF2, Cl2, Na2O2, F2.

119. When Cl2 water is dropwise added into KI solution, initially brown colouration appears, further on adding excess
Cl2 water brown colouration disappears due to formation of colourless compound (X) predict oxidation state of
cental atom in compound (X).

120. Find out total number of ion(s)/compound(s) from the following, which can produce blue colour with starch
iodide solution.
Cu 2  (aq), HNO 2 , H 2S, Br2 , Fe3 (aq), H3 PO4 , Na 2 O 2 , H 3BO3 , Bi3 (aq)

121. Total number of molecular species which has/have open book like structure.
Na 2 O2 , S2 F2 , O 2 F2 , S2 O82  , P2 O74  , H 2 N 2 O 2 , S2 C 2 N 2 , C 2 N 2 , S4 O62 
|P  Q|
122. Consider thermal decomposition of following ammonium salts and calculate value of expression
2
(NH 4 )2 Cr2 O7 , NH 4 NO2 , NH 4 NO3 , NH 4 Cl, CH3 COONH 4 , NH 4 ClO4 , (NH 4 )2 S, (NH 4 )2 CO3 (NH 4 )2 C2 O4
Where : P : Total number of ammonium salts which liberates basic NH3 gas on thermal decomposition.
Q : Total number of ammonium salts which liberates neutral N2 gas on thermal decomposition.

VMC | Chemistry 13 JEE Advanced Final Practice Assignment

 Vidyamandir Classes
123. Consider the following reaction and predict the number of d-electrons in t2g set of d-orbitals in purple complex.
Na 2 [Fe(CN)5 NO]  Na 2S 
 purple complex

124. Total number of compounds, which contains only one peroxylinkage

PbO2, BaO2, H2O2, O2F2, O2[PtF6], H2S2O8, H2SO5,Na2O2, CrO5

Hydrolysis
125. NO2  xH 2 O 

Hydrolysis
ClO3  yH 2 O 

Then calculate the value of [x + y].

126. ClO 2  H 2 O 
x y
Calculate difference of oxidation states of chlorine atom in compounds x and y formed after hydrolysis.

 axb 
127. Consider P4O10 molecule and then calculate the value of expression  
 c 
Where
a = Total number of P – O– P bonds
b = Total number of  coordinate bonds
c = Total number of  dative bonds (back bonds)

128. The number of radicals which give coloured product on observation with conc. H2SO4.
CO32  , NO2 , Cl  , Br  , I  , NO 3 , PO34 , CrO 42 , SO 32

129. Calculate number of compound which contain direct single covalent bond (x –x) between same atoms.
P4O6, H2S2 O4, H2S2O5, H2S2O6, H2O2, H4P2O8, H4P2O7, H2SO5, H4P2O6.

130. When black iron sulphide is roasted in air, gas P is formed, further gas P on reaction with sufficient amount of Cl2
produces another compounds Q. Then find out difference in oxidation state between sulphur atoms in gas P and
compound Q.

131. Calculate sum of unpaired electrons in central metal ions of

Fe(CN)6 ]4  ,[FeF6 ]3 ,[Co(C 2O 4 )3 ]3 and [NiCl4 ]2 

132. Find total number of cations which form low spin and inner orbital octahedral complex on adding excess NH3
solution
Cu2+(aq), Co2+(aq), Ir3+(aq), Cr3+(aq), Fe3+(aq), Mn2+(aq), Ti3+(aq), Cd2+(aq). Ni2+(aq)

133. Find the number of compounds in which d orbital will take part in hybridization.
x2  y2
(1) [PtBrCl(NH3)(H2O)] (2) SF4 (3) [Cu(NH3)4]2+
(4) XeO3F2 (5) [RhCl(PPh3)3] (6) [Co(en)3]3+
(7) Fe(CO)5 (8) [Cu(NO2)5]3– (9) XeF4 (10) XeO64
134. Among following ligands, how many of them can get as  -acid ligand(s) with  -donating ability and accepting
back bond ability into its * M.O.
CO, C5 H5 , B3 N3 H6 , PMe3 , cyclopropyl, C2 H 4 , NO , F , O22 
135. Find the value of expression [x + y] for commercial extraction of following metals.
Ag, Zn, Hg, Cu, Fe, Mg, Pb, Al, Au
X : Number of metals commercially extracted by pyrometallurgy
Y : Number of metals during their extraction chemical leaching is used
136. Find the value of expression (x  y) for complexes
(A) Co2(CO)x (B) Fe(CO)2(NO)y
137. Find the total number of diamagnetic complex.
K3[Fe(CN)6], [Fe(EDTA))2–, Na3[Co(Ox)3], [Ni(H2O)6]Cl2, K2[Pt(CN)4], [Zn(NO2)4](NO3)2, K2[NiCl4],
[Pt(NH3)4]Cl2], [Ni(CO)4]

VMC | Chemistry 14 JEE Advanced Final Practice Assignment

 Vidyamandir Classes
138. Consider the following ligands and find the value of term (x + y)
SCN  , NO2 , gly, acac, bcac,S2 O32  , OH  , EDTA 4  , dmg
X = Number of ligands which form five membered ring with metal cation in respective complex compound.
Y = Number of ligands which form six membered ring with metal cation in respective complex compound.

139. Among the following sulphides, find the number of metal sulphides which are not soluble in yellow ammonium
sulphide (YAS).
CuS, Bi2S3, As2S3, SnS2, CdS, SnS, Sb2S3, PbS, Sb2S5

140. Among the following metals, the number of elements that release H2 gas on reaction with non oxidizing acid and
strong alkali solution.
Be, Al, Cu, Mg, Ca, Zn, Sn, Pb,, Fe

141. Predict the number of compounds that can give positive chromyl chloride test on reaction with solid K2Cr 2O7 and
few drops of conc. H2SO4.
CaCl2, NH4Cl, FeCl3, ZnCl2, AgCl, PbCl2, MnCl2, CuCl2, HgCl2.

142. Determine the sum of molar coefficient of SO2 and KMnO4, when they react with each other in acidic medium.

143. Find the total number of ligands among the following species which can exhibit both ambidentate and
flexidentate character separately.
SCN  , CN  , NO 2 , S2O32  , SO32 , SO 42 , NO3 , NOS , OCN 

144. Among the following, the number of cation(s) that give precipitate with NaCl solution is
Ag+(aq), Cu2+(aq), Fe3+(aq), Mg2+(aq), K+(aq), Hg22+(aq), Pb2+(aq), Al3+(aq), Ca2+(aq)

145. Among the following, the number of compounds/ions having a linear structure is :
C3O 2 , N3 , (CN) 2 , I3 , IF2 , (SCN) 2 , O 3 , N 2 O, NH 2 .

146. Consider the following sequence of reaction

KMnO4  KOH(conc) 
 X  H 2 O  O2 ; X  H 2 O 
 Y  Z
Green light Dark
solution Pink Brown

Then calculate value of |P + Q – R| where, P, Q and R are oxidation states of central atoms of X, Y and Z
respectively.

147. Total number of  -acid (  -acceptor) ligands among given species is/are
NH 2 , CO, NO, PR 3 , C 2 H 4 , C6 H 6 , CN  , H 2 O, C5 H5 , H 

148. Calculate value of |x – y| where x and y are total number of maximum equivalent ‘Cr – O’ bonds in CrO5 and
Cr2 O72  ion respectively.

149. Total number of acidic radical(s) which does/do not give white precipitate with AgNO3 solution
SO32  (aq), S2 O32  (aq), C 2 O 42  (aq), I  (aq), PO 34 (aq), CrO 42  (aq) , NO2 (aq) , S2  (aq), MnO4 (aq)

150. Calculate value of |P – Q|, where

P : Sum of oxidation states of all sulphur atoms in tetrathionic acid
Q : Sum of oxidation states of all sulphur atoms in thiosulphuric acid

151. In electrolytic refining of impure copper containing impurities of Ag, Hg, Al, Zn, Au, Fe, Pt, Sn, Mg. Then find
out total number of metals present in anode mud in their elemental form.
152. How many of the following species would have C–O bond length longer than that of free CO molecules.
[V(CO) 6 ] , [Ti(CO)6 ]2  , BF3 (CO),[Sc(CO)6 ]3 , Ni(CO) 4 ,[Fe(CN)5 (CO)]3 , CO 2 , CO 32 , [Cr(CO) 6 ]

VMC | Chemistry 15 JEE Advanced Final Practice Assignment

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Answers Advanced Chemistry Assignment - 2 | Inorganic Chemistry

1 2 3 4 5 6 7 8 9 10 11 12
D D B C A D C A C C D D
13 14 15 16 17 18 19 20 21 22 23 24
C C B C D D A A C D B B
25 26 27 28 29 30 31 32 33 34 35 36
D A D A A B C B D D A C
37 38 39 40 41 42 43 44 45 46 47 48
B B D B ABD AB ABD ABC ABC ABC AC ABD
49 50 51 52 53 54 55 56 57 58 59 60
ABC ABCD ABCD ABCD ACD BCD AC ABCD ABCD ABC BCD ABD
61 62 63 64 65 66 67 68 69 70 71 72
ABD BD BCD BCD ABD CD ABC ABCD ACD AB ACD ABCD
73 74 75 76 77 78 79 80 81
BC ABCD ABCD BCD CD BCD ACD ABD A-PQR ; B-Q S ; C-PQ ; D-PR
82 83 84
A-PQRST ; B-PQST ; C-PQRT ;
A-PQRST ; B-PQ ; C-QRT ; D-QRST A-QRS ; B -PQ ; C-PQRT ; D-ST
D-PQRT
85 86 87
A -PQRT ; B -PRST ; C-PQRST ;
A-PST ; B-RS ; C-PT ; D-PQS A-QRS ; B-QPT ; C-ST ; D-PQ
D-RS
88 89 90
A-PQRT ; B-PST ; C-PQRST ; A-PQRST ; B-PQ RT ; C-QR ;
A-PT ; B-RT ; C-PQT ; D-QRST
D-PQRST D-QRST
91 92 93
A-QRS ; B-PQ RS ; C-PQT ; D-PQR A-PQST ; B-R ; C-PQRST ; D-PQRT A-PRST ; B-PQ RS ; C-PRS ; D-PQRST
94 95 96
A-PRS ; B-PQRST ; C-QT ;
A-PRS ; B-PQ ; C-QRS ; D-QRST A-PRT ; B-PQ ; C-PQRST ; D-PQT
D-PQRST
97 98 99 100 101 102 103 104 105
A-PQR ; B-PQT ; C-PQRS ; D-PQRT 6 3 6 8 2 4 3 6
106 107 108 109 110 111 112 113 114 115 116 117
7 3 4 7 4 3 4 2 3 0 4 6
118 119 120 121 122 123 124 125 126 127 128 129
5 5 5 5 1 6 5 2 2 6 5 7
130 131 132 133 134 135 136 137 138 139 140 141
2 7 2 7 3 8 4 6 6 4 5 6
142 143 144 145 146 147 148 149 150 151 152
7 2 3 5 9 7 2 4 6 4 7

VMC | Chemistry 16 JEE Advanced Final Practice Assignment