D and F Block Element Introduction

1. The d – block of the periodic table contains the elements of

the groups:

✓
A)3 – 12
B)1 – 12
C)4 – 13
D)13 – 18
1. The d – block of the periodic table contains the elements of
the groups:

A)3 – 12
B)1 – 12
C)4 – 13
D)13 – 18
 2. How many groups are there in d – block of the periodic
table?

✓
A)10
B)8
C)12
D)4
2. How many groups are there in d – block of the periodic
table?

A)10
B)8
C)12
D)4
3. How many periods are there in d – block of the periodic
table?

A)10
B)8
C)6
D)4
3. How many periods are there in d – block of the periodic
table?

A)10
B)8
C)6
✓
D)4
5. In d-block electrons are filled in ?

A)nd
✓
B)(n-1)d
C)(n-2)d
D)ns & np
5. In d-block electrons are filled in ?

A)nd
B)(n-1)d
C)(n-2)d
D)ns & np
 5. In which period f-block elements exists?

r
A)6 & 7
B)5 & 6
C)1 & 2
D)3 & 4
5. In which period f-block elements exists?

A)6 & 7
B)5 & 6
C)1 & 2
D)3 & 4
5. All f block elements belongs to which group ?

_
A)3
B)4
C)5
D)6
5. All f block elements belongs to which group ?

A)3
B)4
C)5
D)6
 5. Which of the following orbitals are progressively filled in
f – block elements?
GP tf
✓
→

A)4f and 5f
B)5f and 6f 9- P -
5f
C)3f and 4f
D)4f and 6f
5. Which of the following orbitals are progressively filled
in f – block elements?

A)4f and 5f
B)5f and 6f
C)3f and 4f
D)4f and 6f
6. The names transition metals and inner transition metals
are often used to refer to the elements of ______ and
_________ respectively.

A)s – block , d – block

B)d – block , f – block
C)f – block , d – block
D)p – block , f – block
6. The names transition metals and inner transition metals
are often used to refer to the elements of ______ and
_________ respectively.

A)s – block , d – block

B)d – block , f – block
C)f – block , d – block
D)p – block , f – block
 -4M€
8. The 3d series of the transition metals consist of element
from:

A) Y to Cd
-
B)Sc to Zn
C)La and Hf to Hg
D)Rf to Cn
8. The 3d series of the transition metals consist of element
from:

A) Y to Cd
B)Sc to Zn
C)La and Hf to Hg
D)Rf to Cn
 9. Elements Y to Cd belong to which series of the transition

-¥er
metals?

✓
A)4d
B)5d 4d series
C)3d
D)6d
9. Elements Y to Cd belong to which series of the transition
metals?

A)4d
B)5d
C)3d
D)6d
10. Elements La and Hf to Hg belong to which series of the
transition metals?

A)6d
B)5d
C)4d
D)3d
 10. Elements La and Hf to Hg belong to which series of the
transition metals?

A)6d
✓B)5d
C)4d
D)3d
12. How many series are there in periodic table for inner
-

transition metals?
-

A)2 (4f and 5f)

B)3 (4f and 6f)
C)2 (5f and 6f)
D)3 (5f , 6f and 7f)
 12. Which of the following is inner transitional metal?

✓
A)2 (4f and 5f)
B)3 (4f and 6f)
Gy7P_
tfsfseriess
C)2 (5f and 6f)
D)3 (5f , 6f and 7f)
 / GPen
13. The 4f series of consist of elements from:

A)Ce to Lu
B)Sc to Zn
C)Th to Lr
D)Rf to Cn
 13. The 4f series of consist of elements from:

La
✓
A)Ce to Lu 58-71 →

B)Sc to Zn
C)Th to Lr 90 -103 → Ac
D)Rf to Cn
14. Which of the following series consist of elements from
Th to Lr?
- _
Actinoid
A)4f
✓
B)5f
C)4d
D)5d
14. Which of the following series consist of elements from
Th to Lr?

A)4f
B)5f
C)4d
D)5d
 0
15. Which of the following matching is wrong?

A)Sc to Cu → Transition metals

B)Y to Ag → Transition metals
C)Ce to Lu → Inner transition metals
D)Th to Lr → Transition metals
it
15. Which of the following matching is wrong?

A)Sc to Zn → Transition metals

B)Rf to Cn → Transition metals
C)Ce to Lu → Inner transition metals
D)Th to Lr → Transition metals
16. The elements of 4f series is also known as:

A)Pnictogens
_
B)Lanthanoids
C)Actinoids
D)Halogens
16. The elements of 4f series is also known as:

A)Pnictogens
B)Lanthanoids
C)Actinoids
D)Halogens
17. The elements of 5f series of the inner transition metals
is also known as:

A)Actinoids
B)Lanthanoids
C)Transition metal
D)Halogens
 17. The elements of 5f series of the inner transition metals
is also known as:

✓
A)Actinoids
B)Lanthanoids
C)Transition metal
D)Halogens
18. Which of the following definition of transition metal is
correct according to IUPAC?

A)Metals which have incomplete d – subshell either in neutral

atom or in their ions
B)Metals which have complete d – subshell either in neutral
atom or in their ions
C)Metals which have incomplete f – subshell either in neutral
atom or in their ions
D)Metals which have complete f – subshell either in neutral
atom or in their ions
18. Which of the following definition of transition metal is
correct according to IUPAC?

r
A)Metals which have incomplete d – subshell either in neutral
atom or in their ions
B)Metals which have complete d – subshell either in neutral
atom or in their ions
C)Metals which have incomplete f – subshell either in neutral
atom or in their ions
D)Metals which have complete f – subshell either in neutral
atom or in their ions
19. Which of the following element(s) is not regarded as
Transition metals?

A)Hg
B)Cd
C)Zn
D)All of the above
19. Which of the following element(s) is not regarded as
Transition metals?

A)Hg
B)Cd
C)Zn

r
D)All of the above
20. Zn , Cd and Hg don’t regarded as transition metal
because:

_
A)They have full d10 configuration
B)They have full f14 configuration
C)They have half-filled d5 configuration
D)They have half-filled f7 configuration
20. Zn , Cd and Hg don’t regarded as transition metal
because:

A)They have full d10 configuration

B)They have full f14 configuration
C)They have half-filled d5 configuration
D)They have half-filled f7 configuration
 21. Zn , Cd and Hg belong to which group?

A)11
B)10
C)8
D)12
✓
21. Zn , Cd and Hg belong to which group?

A)11
B)10
C)8
D)12
25. What makes transition elements different from that of
-
the non – transition elements?
-

A)Partially filled p orbitals

B)Partly filled d or f orbitals
C)Both A and B
D)Fully filled d10 configuration
25. What makes transition elements different from that of
the non – transition elements?

A)Partially filled p orbitals

B)Partly filled d or f orbitals

?
C)Both A and B
D)Fully filled d10 configuration
26. How many of the given metals belong to the transition
metals series? Silver , Boron , Gold , Platinum , Iron , Copper
=

, Titanium , Aluminium , Tellurium , Selenium

- - -

A)6
B)8
C)4
D)5
26. How many of the given metals belong to the transition
metals series? Silver , Boron , Gold , Platinum , Iron , Copper
, Titanium , Aluminium , Tellurium , Selenium

A)6
r
B)8
C)4
D)5
27. Which of the following is/are precious metal?

A)Silver
B)Gold
C)Platinum

_
D)All of the above
27. Which of the following is/are precious metal?

A)Silver
B)Gold
C)Platinum
D)All of the above
 28. Why d-block elements are known as transitional
elements?

_
A)Because D-block lies b/w s & p-block
B)Because D-block lies b/w s & f-block
C) Because 3d e transition occurs in d-block
D)Both A & C
28. Why d-block elements are known as transitional
elements?

A)Because D-block lies b/w s & p-block

B)Because D-block lies b/w s & f-block
C) Because 3d e transition occurs in d-block
D)Both A & C
The Transition Elements ( d – block)
8.1 Position in the periodic table

8.2 Electronic Configuration of the

d – block elements
29. In which orbital last e occurs in d-block?

✓ ( n 1) of
-

A)Penultimate d-orbitals
B)Anti-penultimate d-orbitals ( penultimate
C)Last shell of d-orbitals
D)Outermost s-orbitals
( n -

2) f-
↳ antepenultimate
29. In which orbital last e occurs in d-block?

A)Penultimate d-orbitals
B)Anti-penultimate d-orbitals
C)Last shell of d-orbitals
D)Outermost s-orbitals
29. What is the general electronic configuration of d – block
elements? 1-10
"
( n 1) 9 ns
-

A)(n-1)d1-10 ns1-2
B)(n-1)d1-5 ns1-2
C)(n-1)d10 ns1-2
D)(n-1)d1-10 ns1-2
29. What is the general electronic configuration of d – block
elements?

r
A)(n-1)d1-10 ns1-2
B)(n-1)d1-5 ns1-2
C)(n-1)d10 ns1-2
D)(n-1)d1-10 ns1-2
30. How many e- can be accommodated by inner d orbitals d
-

– block elements?

A)1-10
B)1-5
C)10
D)1-8
30. How many e- can be accommodated by inner d orbitals d
– block elements?

r
A)1-10
B)1-5
C)10
D)1-8
31. The outermost ns orbital of d – block elements can
have:

A)1 or 2 e-
B)1 e-
C)2 e-
D)None of the above
 31. The outermost ns orbital of d – block elements can
have:

✓
A)1 or 2 e -

B)1 e-
C)2 e-
D)None of the above
 32. What is the outermost electronic configuration of Cr?

A)3d5 4s0
✓
B)3d5 4s1

C)3d4 4s2 3£ 4s
'

D)3d6 4s0
32. What is the outermost electronic configuration of Cr?

A)3d5 4s0
B)3d5 4s1
C)3d4 4s2
D)3d6 4s0
33. Why chromium has E.C 3d5 4s1 and not 3d4 4s2?

A)Energy gap between 3d and 4s orbital is small

B)Half-filled d5 configuration is more stable
C)Both A and B
D)None of the above
 33. Why chromium has E.C 3d5 4s1 and not 3d4 4s2?

A)Energy gap between 3d and 4s orbital is small

B)Half-filled d5 configuration is more stable
-C)Both A and B
D)None of the above
34. What is the outermost E.C of copper?

A)3d9 4s2
B)3d10 4s0
C)3d9 4s1
D)3d10 4s1
✓
34. What is the outermost E.C of copper?

A)3d9 4s2
B)3d10 4s0
C)3d9 4s1
D)3d10 4s1
 35. What is the general formula of E.C of outer orbitals of
Zn, Cd Hg and Cn?
-

✓
A)(n-1)d10 ns2
B)nd10 ns2
C)nd10 ns1
D)(n-1)d10 4s1
35. What is the general formula of E.C of outer orbitals of
Zn, Cd Hg and Cn?

A)(n-1)d10 ns2
B)nd10 ns2
C)nd10 ns1
D)(n-1)d10 4s1
36. Why Zn ,Cd, Hg is not a transitional element?

A)It has completely filled ground state and commen O.S.

B)It has unpaired electrone in outermost d-orbital
C)It has completely filled p-orbitals
D)None of these
 36. Why Zn ,Cd, Hg is not a transitional element?

-
A)It has completely filled ground state and commen O.S.
B)It has unpaired electrone in outermost d-orbital
C)It has completely filled p-orbitals
D)None of these
36. The properties such as various o.s. and colored ion is due
to:

A)Partly filled p orbitals

B)Partly filled d orbitals
C)Partly filled f orbitals
D)Fully filled d orbitals
 36. The properties such as various o.s. and coloured ion is due
to:
A)Partly filled p orbitals
✓B)Partly filled d orbitals
C)Partly filled f orbitals
D)Fully filled d orbitals
37. Which of the following properties is/are exhibited by
transition metals and their compound?

A)Catalytic property
B)Paramagnetic property
C)Ferromagnetic property
D)A & B both
✗
37. Which of the following properties is/are exhibited by
transition metals and their compound?

A)Catalytic property
B)Paramagnetic property
C)Ferromagnetic property
D)A & B both
8.3 General Properties of the
transition element
8.3.1 Physical Properties
38. Nearly all the transition elements display:

A)Metallic properties
B)Non- metallic properties
C)Metalloid properties
D)All of the above
 38. Nearly all the transition elements display:

-
A)Metallic properties
B)Non- metallic properties
C)Metalloid properties
D)All of the above
39. Transition elements exhibits:

A)High tensile strength-

B)Malleability
C)Ductility
=
D)All of the above
 39. Transition elements exhibits:

A)High tensile strength

B)Malleability
C)Ductility
✓ D)All of the above
40. Transition elements exhibits:

A)High thermal conductivity

B)High electrical conductivity
C)Metallic luster
D)All of the above
_
40. Transition elements exhibits:

A)High thermal conductivity

B)High electrical conductivity
C)Metallic luster
D)All of the above
¥
*
42. The transition metal are very hard and have low volatility
with the exception of:

A)Zu
*
B)Hg
C)Cd
D)All of the above
42. The transition metal are very hard and have low volatility
with the exception of:

A)Zu
An
B)Hg
C)Cd
D)All of the above
✗
43. The true statement regard transition metal is/are:
-

A)Very hard
B)Have low volatility} zn.ca Hg Exception
,

C)High melting point and boiling point

D)All of the above
 43. The true statement regard transition metal is/are:

A)Very hard
B)Have low volatility
C)High melting point and boiling point
D)All of the above
✓
44. The reasons for high melting and boiling point is
attributed to:

A)Involvement of greater number of e- from nd and ns e- in

the interatomic metallic bonding
B) Involvement of greater number of e- from (n-1)d and ns e-
in the interatomic metallic bonding
C)Involvement of greater number of e- from (n-2) and (n-1)s e-
in the interatomic metallic bonding
D)None of the above
 44. The reasons for high melting and boiling point is
attributed to:

A)Involvement of greater number of e- from nd and ns e- in

the interatomic metallic bonding
B) Involvement of greater number of e- from (n-1)d and ns e-
✓
in the interatomic metallic bonding
C)Involvement of greater number of e- from (n-2) and (n-1)s e-
in the interatomic metallic bonding
D)None of the above
45. Which of the following element has the highest melting
point?

A)Co
B)Zu
C)Ni
D)Cr
45. Which of the following element has the highest melting
point?

A)Co
B)Zu
C)Ni e-
unpaired
'
3d 54s → 6
D)Cr
✓
46. Which of the following element has exceptionally lowest
-

melting point?

A)Ni
B)Cr
C)Mn
D)Fe
 46. Which of the following element has exceptionally lowest
melting point?

¥
A)Ni
B)Cr
-C)Mn
D)Fe
47. Which of the following transitional element has the
lowest point in 4d series?
^

melting
A)Tc
B)Ru
C)Zr
D)Ag
47. Which of the following transitional element has the
lowest point in 4d series?

A)Tc
B)Ru
C)Zr
_
D)Ag
48. Which of the following metals shows anomalous values of
melting point in 3d and 4d series respectively?

r
A)Mn , Tc
B)Mn , Ru
C)Cr , Tc
D)Cr , Ru
48. Which of the following metals shows anomalous values of
melting point in 3d and 4d series respectively?

A)Mn , Tc
B)Mn , Ru
C)Cr , Tc
D)Cr , Ru
49. Which of the following statement is incorrect?
-

A)Mn and Tc have an abnormally low melting point

B)The transition metal have high enthalpies of atomization
C)Melting point of transition in any rows rises to a maximum
at d5 except for anomalous values of Mn and Tc and fall
regularly as the atomic number increases
D)Transition metal have generally low melting point
49. Which of the following statement is incorrect?

A)Mn and Tc have an abnormally low melting point

B)The transition metal have high enthalpies of atomization
C)Melting point of transition in any rows rises to a maximum
at d5 except for anomalous values of Mn and Tc and fall
regularly as the atomic number increases
D)Transition metal have generally low melting point
u
 PYO AMMI
50. The melting points of Au , Ag and Cu follow the order:

A)Cu > Ag > Au

B)Cu > Au > Ag
C)Au > Ag > Cu
D)Ag > Au > Cu
 50. The melting points of Au , Ag and Cu follow the order:

A)Cu > Ag > Au

✓B)Cu > Au > Ag
C)Au > Ag > Cu
D)Ag > Au > Cu
51. The melting point of transition metal is high because of:

A)Interatomic hydrogen bond formation

B)More no of valance e & hence more strong metallic bond
C)Their ability to form ionic bonds
D)All of the above
51. The melting point of transition metal is high because of:

A)Interatomic hydrogen bond formation

B)More no of valance e & hence more strong metallic bond
C)Their ability to form ionic bonds
D)All of the above
52. The metal with high melting point in 4d series is:
Cr -

A)Tc
→
B)Mo Mo
C)Cr →
D)W IN
 52. The metal with high melting point in 4d series is:

A)Tc
✓B)Mo
C)Cr
D)W
52. The highest M.P. among transition metal:

A)Mo car
B)Cr MO
C)W
✓ n
w
D)All of these
52. The highest M.P. among transition metal:

A)Mo
B)Cr
C)W
D)All of these
55. Which of the following statement is true regarding enthalpy
-

of atomization?
-

A)Metal of 2nd and 3rd transition series have greater enthalpies

of atomization than the corresponding element in the first
series
B)Metal of 1st and 3rd transition series have greater enthalpies
of atomization than the corresponding element in the second
series
C)Metal of 1st and 2nd transition series have greater enthalpies
of atomization than the corresponding element in the third
series
D)Metal of 2nd and 3rd transition series have lower enthalpies of
atomization than the corresponding element in the first
series
 55. Which of the following statement is true regarding enthalpy
of atomization? Crc MO < W ( MP order)
-8 f- F-

A)Metal of 2nd and 3rd transition series have greater enthalpies

✓of atomization than the corresponding element in the first
series
B)Metal of 1st and 3rd transition series have greater enthalpies
of atomization than the corresponding element in the second
series
C)Metal of 1st and 2nd transition series have greater enthalpies
of atomization than the corresponding element in the third
series
D)Metal of 2nd and 3rd transition series have lower enthalpies of
atomization than the corresponding element in the first
series
8.3.2 Variation in atomic and
ionic sizes of Transition metals
60. Which of the following is the correct size trend for the
series of transition metal?
_

A)3d < 4d ≈ 5d
B)4d < 3d ≈ 5d
C)5d > 4d > 3d
D)5d < 4d ≈ 3d
60. Which of the following is the correct size trend for the
series of transition metal?
- E-
-
A)3d < 4d ≈ 5d
B)4d < 3d ≈ 5d
C)5d > 4d > 3d
D)5d < 4d ≈ 3d
61. What is the reasons for the equal radii of element of third
(5d) series and the corresponding member of the second
series?

r
A)Lanthanoid contraction
B)Actinoid conctration
C)Baker – Nathan effect
D)Both A and C
61. What is the reasons for the equal radii of element of third
(5d) series and the corresponding member of the second
series?

A)Lanthanoid contraction
B)Actinoid conctration
C)Baker – Nathan effect
D)Both A and C
62. What is lanthenoid contraction?

-
A)Regular decrease in atomic radii due to filling of 4f before 3d
orbital

:
B)Regular increase in atomic radii due to filling of 4f before 3d
orbital
C)Regular decrease in atomic radii due to filling of 3d before 4f
orbital
D)Regular increase in atomic radii due to filling of 3d before 4f
orbital
62. What is lanthenoid contraction?

A)Regular decrease in atomic radii due to filling of 4f before 3d

orbital
B)Regular increase in atomic radii due to filling of 4f before 3d
orbital
C)Regular decrease in atomic radii due to filling of 3d before 4f
orbital
D)Regular increase in atomic radii due to filling of 3d before 4f
orbital
 63. The second and third d series exhibit similar radii due
- - -

to:
-
-

A)Actinoid contraction
-B)Lanthanoid contraction
C)Baker – Nathan effect
D)None of the above
63. The second and third d series exhibit similar radii due
to:

A)Actinoid contraction
B)Lanthanoid contraction
C)Baker – Nathan effect
D)None of the above
 64. Which of the following have similar radii and very
similar physical and chemical properties?

-
A)Zr and Hf
B)Ti and Zr
C)Ti and Hf
D)Cr and Mo
64. Which of the following have similar radii and very
similar physical and chemical properties?

A)Zr and Hf
B)Ti and Zr
C)Ti and Hf
D)Cr and Mo
65. The factor responsible for lanthanide contraction is:
-

A)Increase in effective nuclear charge due to pair shielding of

4f orbital e-
B)Increase in effective nuclear charge due to pair shielding of
3d orbital e-
C)Decrease in effective nuclear charge due to pair shielding
of 4f orbital e-
D)Decrease in effective nuclear charge due to pair shielding
of 3d orbital e-
65. The factor responsible for lanthanide contraction is:

✓
A)Increase in effective nuclear charge due to pair shielding of
4f orbital e-
B)Increase in effective nuclear charge due to pair shielding of
3d orbital e-
C)Decrease in effective nuclear charge due to pair shielding
of 4f orbital e-
D)Decrease in effective nuclear charge due to pair shielding
of 3d orbital e-
The reason for increase in density in transition elements is -
-

A)Decrease in metallic radius and increase in atomic mass

B)Decrease in metallic radius and decrease in atomic mass
C)Increase in metallic radius and decrease in atomic mass
D)Increase in metallic radius and increase in atomic mass
☆
The reason for increase in density in transition elements is -

A)Decrease in metallic radius and increase in atomic mass

B)Decrease in metallic radius and decrease in atomic mass
C)Increase in metallic radius and decrease in atomic mass
D)Increase in metallic radius and increase in atomic mass
67. The density from titanium (z = 22) to copper (z = 29)

-
A)Increases
B)Decreases
C)Remain equal
D)None of the above
67. The density from titanium (z = 22) to copper (z = 29)

A)Increases
B)Decreases
C)Remain equal
D)None of the above
8.3.3 Ionization Enthalpies
69. The increases in I.E from left to right in a given transition
-

series is due to:

-

A)Increase in effective nuclear charge & filling of inner d –

orbitals
B)Increase in effective nuclear charge & filling of inner d –
orbitals
C)Decrease in effective nuclear charge & filling of the inner f –
orbitals
D)Decrease in effective nuclear charge & filling of the inner d –
orbitals
69. The increases in I.E from left to right in a given transition
series is due to:

A)Increase in effective nuclear charge & filling of inner d –

=

orbitals
=

B)Increase in effective nuclear charge & filling of inner d –

orbitals
C)Decrease in effective nuclear charge & filling of the inner f –
orbitals
D)Decrease in effective nuclear charge & filling of the inner d –
orbitals
71. Which of the following successive I.E order is correct for 3d
series?

A)△iH0 (I) < △iH0 (II) < △iH0 (III)

B)△iH0 (III) = △iH0 (II) = △iH0 (I)
C)△iH0 (I) > △iH0 (II) > △iH0 (III)
D)None of the above
 71. Which of the following successive I.E order is correct for 3d
series?

_
A)△ H
i (I)
0 < △ i H0 (II) < △ H0 (III)
i
B)△iH0 (III) = △iH0 (II) = △iH0 (I)
C)△iH0 (I) > △iH0 (II) > △iH0 (III)
D)None of the above
72. From which orbitals e- is lost in d – block element to form
corresponding ions?

A)(n-1)d
B)nd
C)(n-1)s
D)ns
@
72. Which orbitals e- d – block element losses first to form
corresponding ions?

A)(n-1)d
B)nd
C)(n-1)s
D)ns
73. What happen when we move along the period in 3d series?
=
A)Nuclear charge increases from Sc to Zn
B)I.E increases only slightly
C)Atomic radii decreases less rapidly
D)All of the above
73. What happen when we move along the period in 3d series?

A)Nuclear charge increases from Sc to Zn

B)I.E increases only slightly
C)Atomic radii decreases less rapidly
✓
D)All of the above
 0
79. What is the outer shell electronic configuration of Mn+?

✓
A)3d5 4s1
Mn → 345452
B)3d4 4s2
3d 54s
'

C)3d4 4s1
Mnt →
D)3d5 4s2
79. What is the outer shell electronic configuration of Mn+?

A)3d5 4s1
B)3d4 4s2
C)3d4 4s1
D)3d5 4s2
 Cr → 395 Ysl
O
80. What is the outer shell configuration of Cr+?

A)3d5 4s1
cot → 345
✓B)3d5 4s0

C)3d4 4s2
D)3d5 4s2
80. What is the outer shell configuration of Cr+?

A)3d5 4s1
B)3d5 4s0
C)3d4 4s2
D)3d5 4s2
 81. Choose the correct statements from the following
-

✓
I) Mn+ has lower IE than Cr+ mnt ert
II)Mn+ has higher IE than Cr+
3d5ys1 { 3d
5

III)Fe2+ has lower IE than Mn2+

%IV)Fe2+ has higher IE than Mn2+

A)I & II ,
mn
395
1-2
>
Fetz
3d5
B)II & III
C)I & IV
D)II & IV
 81. Choose the correct statements from the following
I) Mn+ has lower IE than Cr+
II)Mn+ has higher IE than Cr+
III)Fe2+ has lower IE than Mn2+
IV)Fe2+ has higher IE than Mn2+

/
A)I & III
B)II & III
C)I & IV
D)II & IV
82. What is the outer shell Electronic configuration of Fe2+ and

3#
Mn2+ respectively?

¥
A)d6, d5
B)d5, d6
C)d5, d5
D)d4, d5
82. What is the outer shell Electronic configuration of Fe2+ and
Mn2+ respectively?

A)d6, d5
B)d5, d6
C)d5, d5
D)d4, d5
8.3.4 Oxidation State
84. The elements which give the greatest number of oxidation
states occur

A)in or near the middle of the series

B)at left of the series
C)at right of the series
D)all of these
84. The elements which give the greatest number of oxidation
states occur

-
A)in or near the middle of the series
B)at left of the series
C)at right of the series
D)all of these
85. Which of the following transition posses highest number of
oxidation?

A)Cr
B)Fe
C)Mn
D)Se
85. Which of the following transition posses highest number of
oxidation?

A)Cr
B)Fe
C)Mn_
D)Se
86. Manganese exhibits all the oxidation states from

A)+2 to +7_
B)+3 to +7
C)+1 to +6
D)+2 to +6
86. Manganese exhibits all the oxidation states from

A)+2 to +7
B)+3 to +7
C)+1 to +6
D)+2 to +6
87. The only oxidation state posses by scandium is

/
A)+3
B)+2
zn → ⊕
C)+4
⊕
-
I
D)+1
87. The only oxidation state posses by scandium is

A)+3
B)+2
C)+4
D)+1
88. The only oxidation state posses by Zinc is

r
A)+2
B)+3
C)+1
D)None of the above
88. The only oxidation state posses by Zinc is

A)+2
B)+3
C)+1
D)None of the above
89. Which of the following oxidation state is virtually unknown
for scandium?

A)+2
B)+3
C)Both A and B
D)None of the above
89. Which of the following oxidation state is virtually unknown
for scandium?

A)+2 r
B)+3
C)Both A and B
D)None of the above
 ≥
Ti → 3d ysz
90. Which one is more stable?
(22g
✓
A)Ti4+ inert gas

B)Ti2+ 302
C)Ti3+ 3432 lest
D)None of the above
90. Which one is more stable?

A)Ti4+
B)Ti2+
C)Ti3+
D)None of the above
92. Which of the following oxidation state are posses by
vanadium?

=
A)+2, +3, +4, +6
B)+2, +3, +4, +5
C)+1, +2, +3, +4
D)+3, +4, +5, +6
92. Which of the following oxidation state are posses by
vanadium?

A)+2, +3, +4, +6

B)+2, +3, +4, +5
C)+1, +2, +3, +4
D)+3, +4, +5, +6
 93. In the p – block, the lower oxidation states are favored by
the by the heavier member. This is due to –

_
A)Inert pair effect
B)Lanthanoid contraction
C)Mesomeric effect
D)Baker – Nathan effect
93. In the p – block, the lower oxidation states are favored by
the by the heavier member. This is due to –

A)Inert pair effect

B)Lanthanoid contraction
C)Mesomeric effect
D)Baker – Nathan effect
94. Which of the following oxidation state is/are favored by
heavier member of d – block elements?
_

A)Higher oxidation state

B)Lower oxidation state
C)Both A and B
D)None of the above
94. Which of the following oxidation state is/are favored by
heavier member of d – block elements?

r
A)Higher oxidation state
B)Lower oxidation state
C)Both A and B
D)None of the above
95. Which of the following oxidation state of group 6 is true
_

regarding?

A)Mo(VI) is more stable than Cr(VI)

B)W(VI) is more stable than Cr(VI)
C)Cr(VI) is more stable than Mo(VI) and W(VI)
D)Both A and B
95. Which of the following oxidation state of group 6 is true
regarding?
( 8+6 < motto < wtb

A)Mo(VI) is more stable than Cr(VI)

B)W(VI) is more stable than Cr(VI) }w
C)Cr(VI) is more stable than Mo(VI) and W(VI)
D)Both A and B
✓
96. Cr(VI) in the form of Dichromate in acidic medium act as

A)Strong reducing agent a÷:crᵗ3

B)Weak reducing agent
C)Weak oxidising agent ↳ Reduce
oxidizing agent
D)Strong oxidizing agent ↳
96. Cr(VI) in the form of Dichromate in acidic medium act as

A)Strong reducing agent

B)Weak reducing agent
C)Weak oxidising agent
D)Strong oxidizing agent
 97. The Cr(VI) in the form of dichromate act as a strong oxidising

#
agent because- 6
Crt
0g
A)Cr(VI) is more stable stable
B)Cr(VI) is less stable
+
C)Cr(VI) has electronic configuration 3d0 4s0
D)All of the above
97. The Cr(VI) in the form of dichromate act as a strong oxidising
agent because-

A)Cr(VI) is more stable

B)Cr(VI) is less stable
C)Cr(VI) has electronic configuration 3d0 4s0
D)All of the above
98. Which of the following don’t act as oxidizing agent?
MO
MO
A)MO3
#
" ☐
B)K2Cr2O7 → e.

C)WO3 ✗

( wt6→④
D)Both A and C
98. Which of the following don’t act as oxidizing agent?

A)MoO3
B)K2Cr2O7
C)WO3
D)Both A and C
99. Which of the following oxidation state is not posses by Iron?

A)+2 Feo
B)+3 few}
0
C)+5
D)+4
-
.
99. Which of the following oxidation state is not posses by Iron?

A)+2
B)+3
C)+5 x
D)+4
 100. What is the oxidation state of Nickel and iron in Ni(CO)4
and Fe(CO)5 respectively

A)0, 1
B)1, 0

tC)0, 0
D)0, -1
100. What is the oxidation state of Nickel and iron in Ni(CO)4
and Fe(CO)5 respectively

A)0, 1
B)1, 0
C)0, 0
D)0, -1
101.Which of the following oxidation state is not
exhibited by Titanium?

A)+1
B)+3
C)+4
D)+2
 101.Which of the following oxidation state is not
exhibited by Titanium?

_A)+1
B)+3
C)+4
D)+2
102.Which of the following oxidation state
is not posses by Co and Ni?

A)+4
B)+2
C)+3

O
D)+1
102.Which of the following oxidation state
is not posses by Co and Ni?

A)+4
B)+2
C)+3
D)+1
103.Which of the following is the highest
oxidation state posses by Mn?

A)+5
B)+8
C)+6
D)+7
103.Which of the following is the highest
oxidation state posses by Mn?

A)+5
B)+8
C)+6
D)+7
_
104. Which of the following is the most
common oxidation state posses by
Chromium?
↳ d5 4s
/

A)+3, +6
B)+3, +4
C)+4, +6
+2, +3
104. Which of the following is the most
common oxidation state posses by
Chromium?

r
A)+3, +6
B)+3, +4
C)+4, +6
+2, +3
105. The most common oxidation
state of Fe and Co is

=
A)+2, +3
B)+3, +4
C)+2, +3
D)+1, +2
105. The most common oxidation
state of Fe and Co is

A)+2, +3
B)+3, +4
C)+2, +3
D)+1, +2
106. The most common oxidation state of Ti
-

is

A)+2
B)+3
C)+4
D)+1
106. The most common oxidation state of Ti
is
t
A)+2
B)+3
C)+4
D)+1
107. The most common oxidation state of V
is

A)+2
¥20s
B)+5
C)+4
D)+3
 107. The most common oxidation state of V
is

A)+2
B)+5
✓

C)+4
D)+3
8.3.5 Trends in the M2+/M Standard
Electrode
108. Which of the following 3d element don't
-

have negative value of E°M2+ /M ?

-
.
.

A)Cu
④ + re → ④
B)Ti
C)Zn
D)Fe
108. Which of the following 3d element don't
-08

have negative value of E°M2+ /M ?

A)Cu
B)Ti
C)Zn
D)Fe
109. The unique behavior of Cu, having a
positive E° account for its
-

A)ability to liberate H2 from acids

B)inability to liberate H2 from acids
C)ability to liberate O2 from acids
D)inability to liberate O2 from acids
 109. The unique behavior of Cu, having a
positive E° account for its

A)ability to liberate H2 from acids

/B)inability to liberate H2 from acids

C)ability to liberate O2 from acids
D)inability to liberate O2 from acids
110. Which of the following acid can react
-

with Cu?
-

A)Hot concentrated Sulphuric acid

B)Hot concentrated Nitric acid
} oxidinj aid

C)Both A and B
D)None of the above
110. Which of the following acid can react
with Cu?

A)Hot concentrated Sulphuric acid

B)Hot concentrated Nitric acid
C)Both A and B
D)None of the above
 111. Which of the following species reduced

HzÑ→ÉÑoy
during reaction of concentrated sulphuric
acid and Cu?
Cut

A)Cu

- B)H2SO4
C)H O
2

D)None of the above

111. Which of the following species reduced
during reaction of concentrated sulphuric
acid and Cu?

A)Cu
B)H2SO4
C)H2O
D)None of the above
115. The value of E°(M+2/M) for Mn, Ni and Zn are more
negative than expected from the trend. This is due to-

A)stable half-filled d sub-shell in Mn2+

B)the completely filled d10 configuration in Zn2+
C)Highest negative ∆hyd H° for Ni
D)All of the above
x
115. The value of E°(M+2/M) for Mn, Ni and Zn are more
negative than expected from the trend. This is due to-

A)stable half-filled d sub-shell in Mn2+

B)the completely filled d10 configuration in Zn2+
C)Highest negative ∆hyd H° for Ni
D)All of the above
116. Which of the following 3rd series element
has lowest value of E°M3+ /M2+ ?
-
-

A)Mn
B)Sc
C)Zn
D)Cr
 116. Which of the following 3rd series element
has lowest value of E°M3+ /M2+ ?

A)Mn

tB)Sc
C)Zn
D)Cr
117. The reason for the low value of E°M3+ /M2+ for Sc is-
- -
-

A)noble gas configuration of Sc3+

B)half filled configuration of Sc3+
C)colourless in it ionic form
D)both A and C
117. The reason for the low value of E°M3+ /M2+
for Sc is-
Stable instable

✓ inp
A)noble gas configuration of Sc3+
B)half filled configuration of Sc3+
C)colourless in it ionic form
D)both A and C
118. Which of the following metal has highest
I f

E°M3+ /M2+ value in the 3rd-series?

- -

A)Cr
B)Sc
C)Mn ¥
D)Cu
118. Which of the following metal has highest
E°M3+ /M2+ value in the 3rd-series?

A)Cr
B)Sc
C)Mn
D)Cu
 Unstable stable

119. The reason for highest E°M3+ /M2+ value of

-

•
Zn in its 3rd series is due to-

A)stable half filled d5 configuration of Zn2+

B)stable
✓ d10 configuration f Zn2+

C)colourless nature
D)None of the above
119. The reason for highest E°M3+ /M2+ value of
Zn in its 3rd series is due to-

A)stable half filled d5 configuration of Zn2+

B)stable d10 configuration f Zn2+
C)colourless nature
D)None of the above
 120. The comparatively high value of
E°M3+ /M2+ for Mn is due to-
Unstable stable

A)d5 configuration of Mn2+

-B)pink colour of Mn
C)low melting point of Mn
D)None of the above
120. The comparatively high value of
E°M3+ /M2+ for Mn is due to-

A)d5 configuration of Mn2+

B)pink colour of Mn
C)low melting point of Mn
D)None of the above
 121. The comparatively low value of E°M3+ /M2+ for Fe shows
the- stable Unstable
395 316

/A)extra stability of Fe3+ configuration i.e. d5

B)yellow colour of Fe 3+

C)both A and B
D)None of the above
121. The comparatively low value of E°M3+ /M2+ for Fe shows
the-

A)extra stability of Fe3+ configuration i.e. d5

B)yellow colour of Fe3+
C)both A and B
D)None of the above
8.3.7 Trend in stability of Higher
oxidation state
123. The highest halides exist for Ti, V and Cr is/are-

A)TiX3, VX3, CrX3 (X= F, Cl, Br, I)

B)TiX2, VF5, CrX2 (X= F, Cl)
C)TiX4, VF5, CrF6 (X= F, Cl, Br, I)
D)TiX4, VF5, CrF5 (X= F, Cl, Br, I)
123. The highest halides exist for Ti, V and Cr is/are-

A)TiX3, VX3, CrX3 (X= F, Cl, Br, I)

B)TiX2, VF5, CrX2 (X= F, Cl)
C)TiX4, VF5, CrF6 (X= F, Cl, Br, I)
D)TiX4, VF5, CrF5 (X= F, Cl, Br, I)
124. Which of the following compound is
known for Mn where its oxidation state is +7?

A)MF7
B)MnO3F
C)MnO2F3
D)MnOF5
124. Which of the following compound is
known for Mn where its oxidation state is +7?

A)MF7
B)MnO3F
C)MnO2F3
D)MnOF5
125. Which of the following trihalide does not
exist?

A)FeX3 (X= F, Cl, Br)

B)NiX3 (X= F, Cl, Br, I)
C)CoF3
D)MnF3
125. Which of the following trihalide does not
exist?

A)FeX3 (X= F, Cl, Br)

B)NiX3 (X= F, Cl, Br, I)
C)CoF3
D)MnF3
127. The reason for existence of higher covalent compound
VF5 and CrF6-

A)ability of 'F' to stablise the highest oxidation state due to

higher bond enthalpy term
B)ability of 'F' to destablise the highest oxidation state due to
higher bond enthalpy term
C)ability of 'F' to stablise the highest oxidation state due to
higher lattice energy
D)both A and C
127. The reason for existence of higher covalent compound
VF5 and CrF6-

A)ability of 'F' to stablise the highest oxidation state due to

higher bond enthalpy term
B)ability of 'F' to destablise the highest oxidation state due to
higher bond enthalpy term
C)ability of 'F' to stablise the highest oxidation state due to
higher lattice energy
D)both A and C
128. Choose the incorrect statement among the following.

A)The highest oxidation numbers are achieved in TiX4, VF5 and

CrF6 in the stable halides of 3rd series transition metals.
B)The +7 state for Mn is not represented in simple halides.
C)Beyond Mn no metal has a trihalide except FeX3 and CoF3.
D)The +7 state for Mn found in MnO2F3.
128. Choose the incorrect statement among the following.

A)The highest oxidation numbers are achieved in TiX4, VF5 and

CrF6 in the stable halides of 3rd series transition metals.
B)The +7 state for Mn is not represented in simple halides.
C)Beyond Mn no metal has a trihalide except FeX3 and CoF3.
D)The +7 state for Mn found in MnO2F3.
129. Which of the following halide of vanadium exist?

A)VCl5
B)VI5
C)VF5
D)VBr5
129. Which of the following halide of vanadium exist?

A)VCl5
B)VI5
C)VF5
D)VBr5
130. What product is obtain on hydrolysis
of halide of vanandium except VF5?

A)VOX3
B)VOX2
C)VOX
D)both A and C
130. What product is obtain on hydrolysis
of halide of vanandium except VF5?

A)VOX3
B)VOX2
C)VOX
D)both A and C
133. Which of the following copper halide is not
known?

A)CuI2
B)CuF2
C)CuCl2
D)CuBr2
133. Which of the following copper halide is
not known?

A)CuI2
B)CuF2
C)CuCl2
D)CuBr2
134. Why CuI2 is not known?

A)because Cu2+ oxidises I- to I2

B)because I- oxidises Cu2+ to Cu3+
C)because I- reduces Cu2+ to Cu+
D)both A and C
134. Why CuI2 is not known?

A)because Cu2+ oxidises I- to I2

B)because I- oxidises Cu2+ to Cu3+
C)because I- reduces Cu2+ to Cu+
D)both A and C
135. What is X in the given reaction.
Cu2+ + I- → X + I2

A)CuI2
B)Cu2I3
C)Cu2I2
D)CuI
135. What is X in the given reaction.
Cu2+ + I- → X + I2

A)CuI2
B)Cu2I3
C)Cu2I2
D)CuI
136. Choose the correct statement(s).

A)Many copper (I) compounds are unstable in aqueous

solution.
B)Copper (I) compounds undergo disproportionation.
C)2Cu+ → Cu2+ + Cu
D)All of the above
136. Choose the correct statement(s).

A)Many copper (I) compounds are unstable in aqueous

solution.
B)Copper (I) compounds undergo disproportionation.
C)2Cu+ → Cu2+ + Cu
D)All of the above
157. Which of the following halide is known for Zn?

A)ZnCl2
B)ZnI2
C)ZnBr2
D)All of the above
157. Which of the following halide is known for Zn?

A)ZnCl2
B)ZnI2
C)ZnBr2
D)All of the above
158. Which of the following Zinc fluoride exist?

A)ZnF2
B)ZnF
C)Zn2F2
D)Zn2F6
158. Which of the following Zinc fluoride exist?

A)ZnF2
B)ZnF
C)Zn2F2
D)Zn2F6
160. How many of the given halide is/are known for
chromium? X= F, Cl, Br, I
CrX2, CrX3, CrX4, CrF5, CrCl5, CrF6, CrCl6

A)5
B)4
C)1
D)2
160. How many of the given halide is/are known for
chromium? X= F, Cl, Br, I
CrX2, CrX3, CrX4, CrF5, CrCl5, CrF6, CrCl6

A)5
B)4
C)1
D)2
161. Which of the following halide exist for iron?
X=F, Cl, Br, I
Xˈ= F, Cl, Br

A)FeXˈ3
B)FeX2
C)both A and B
D)FeX
161. Which of the following halide exist for iron?
X=F, Cl, Br, I
Xˈ= F, Cl, Br

A)FeXˈ3
B)FeX2
C)both A and B
D)FeX
162. Which of the following halide doesn't exist for
manganese?
X=F, Cl, Br, I

A)MnF4
B)MnF
C)MnX2
D)MnX3
162. Which of the following halide doesn't exist for
manganese?
X=F, Cl, Br, I

A)MnF4
B)MnF
C)MnX2
D)MnX3
163. Which of the following halide doesn't known for
Titanium?
X= F, Cl, Br, I
Xˈ= F, Cl, Br

A)TiX4
B)TiX
C)TiX3
D)TiXˈ2
163. Which of the following halide doesn't known for
Titanium?
X= F, Cl, Br, I
Xˈ= F, Cl, Br

A)TiX4
B)TiX
C)TiX3
D)TiXˈ2
137. The stability of Cu2+(aq) rather than Cu+(aq) is due to-

A)more negative ∆hyd H° of Cu2+(aq) than Cu+(aq)

B)less negative ∆hyd H° of Cu+2(aq) than Cu+(aq)
C)more lattice energy of Cu2+ less than Cu+(aq)
D)more negative ∆hyd H° of Cu+(aq) than Cu2+(aq)
137. The stability of Cu2+(aq) rather than Cu+(aq) is due to-

A)more negative ∆hyd H° of Cu2+(aq) than Cu+(aq)

B)less negative ∆hyd H° of Cu+2(aq) than Cu+(aq)
C)more lattice energy of Cu2+ less than Cu+(aq)
D)more negative ∆hyd H° of Cu+(aq) than Cu2+(aq)
138. The highest oxidation number in the oxides SC2O3 to
Mn2O7 coincide with-

A)atomic number of corresponding metal

B)period number
C)group number
D)both B and C
138. The highest oxidation number in the oxides SC2O3 to
Mn2O7 coincide with-

A)atomic number of corresponding metal

B)period number
C)group number
D)both B and C
139. The higher oxides of Mn is-

A)Mn2O3
B)Mn2O7
C)Mn3O4
D)Mn3O7
139. The higher oxides of Mn is-

A)Mn2O3
B)Mn2O7
C)Mn3O4
D)Mn3O7
140. Which of the following is the only oxide known for Sc?

A)ScO
B)ScO2
C)Sc2O3
D)Sc3O7
140. Which of the following is the only oxide known for Sc?

A)ScO
B)ScO2
C)Sc2O3
D)Sc3O7
141. The higher oxide of Titanium is-

A)TiO
B)Ti2O3
C)TiO4
D)TiO4
141. The higher oxide of Titanium is-

A)TiO
B)Ti2O3
C)TiO4
D)TiO2
142. Which of the following oxide of Ti is not known?

A)TiO
B)TiO2
C)Ti3O5
D)Ti2O3
142. Which of the following oxide of Ti is not known?

A)TiO
B)TiO2
C)Ti3O5
D)Ti2O3
143. Among the given vanandium oxides, which one doesn't
exist?
VO3, V2O5, V2O4, V2O3, VO, VO4

A)VO3, V2O5
B)VO3, VO4
C)VO, V2O4
D)VO, V2O3
143. Among the given vanandium oxides, which one doesn't
exist?
VO3, V2O5, V2O4, V2O3, VO, VO4

A)VO3, V2O5
B)VO3, VO4
C)VO, V2O4
D)VO, V2O3
144. Which of the following is the highest oxide known for
chromium?

A)CrO5
B)CrO3
C)Cr2O3
D)CrO2
144. Which of the following is the highest oxide known for
chromium?

A)CrO5
B)CrO3
C)Cr2O3
D)CrO2
145. Which of the following manganese oxide is not known?

A)MnO
B)Mn3O4
C)MnO2
D)None of the above
145. Which of the following manganese oxide is not known?

A)MnO
B)Mn3O4
C)MnO2
D)None of the above
146. Which of following is the higher oxide known of Iron?

A)Fe3O4
B)FeO
C)Fe2O3
D)Fe2O5
146. Which of following is the higher oxide known of Iron?

A)Fe3O4
B)FeO
C)Fe2O3
D)Fe2O5
147. Ferrates (FeO42-) are generally formed in which
medium?

A)alkaline medium
B)acidic medium
C)neutral medium
D)both A and B
147. Ferrates (Fe0O42-) are generally formed in which
medium?

A)alkaline medium
B)acidic medium
C)neutral medium
D)both A and B
148. Ferrates readily decomposes to-

A)FeO and O2
B)Fe2O3 and O2
C)Fe3O4 and O2
D)FeO and Fe2O3
148. Ferrates readily decomposes to-

A)FeO and O2
B)Fe2O3 and O2
C)Fe3O4 and O2
D)FeO and Fe2O3
149. Which of the following is not a stable oxocations?

A)VO+
2

B)VO2+
3

C)VO2+
D)TiO2+
149. Which of the following is not a stable oxocatious?

A)VO+
2

B)VO2+
3

C)VO2+
D)TiO2+
150. Which of the following is highest Mn fluoride?

A)MnF2
B)MnF4
C)Mn2F6
D)MnF6
150. Which of the following is highest Mn fluoride?

A)MnF2
B)MnF4
C)Mn2F6
D)MnF6
151. Which of the following is regarding covalent oxide Mn2O7?

A)Mn is tetrahedrally surrounded by O's including a Mn-O-Mn bridge.

B)Mn is tetrahedrally surrounded by O's including a Mn-Mn bridge.
C)Mn is octahedrally surrounded by O's including Mn-O-Mn bridge
D)Mn is surrounded by 3 O's atom in a planar manner including Mn-
O-O-Mn bridge.
151. Which of the following is regarding covalent oxide Mn2O7?

A)Mn is tetrahedrally surrounded by O's including a Mn-O-Mn bridge.

B)Mn is tetrahedrally surrounded by O's including a Mn-Mn bridge.
C)Mn is octahedrally surrounded by O's including Mn-O-Mn bridge
D)Mn is surrounded by 3 O's atom in a planar manner including Mn-
O-O-Mn bridge.
153. Which of the following oxides is not known for
cobalt?

A)CoO
B)Co2O4
C)Co3O4
D)All of the above
153. Which of the following oxides is not known for
cobalt?

A)CoO
B)Co2O4
C)Co3O4
D)All of the above
154. The only simple oxide exist for Nickel is-

A)NiO
B)NiO2
C)Ni2O3
D)None
154. The only simple oxide exist for Nickel is-

A)NiO
B)NiO2
C)Ni2O3
D)None
155. Which of the following copper oxide doesn't exist?

A)CuO
B)Cu2O
C)both A and B
D)Cu2O3
155. Which of the following copper oxide doesn't exist?

A)CuO
B)Cu2O
C)both A and B
D)Cu2O3
156. The only simple oxide known for Zinc is-

A)Zn2O3
B)ZnO2
C)ZnO
D)Zn2O
156. The only simple oxide known for Zinc is-

A)Zn2O3
B)ZnO2
C)ZnO
D)Zn2O
8.3.8 Chemical reactivity and E°
Values
164. Which of the following transition metal don't react
with acids?

A)Cu
B)Fe
C)Co
D)Cr
164. Which of the following transition metal don't react
with acids?

A)Cu
B)Fe
C)Co
D)Cr
8.3.9 Magnetic Properties
170. Which substances are repelled by the applied field?

A)Paramagnetic
B)Diamagnetic
C)Ferrimagnetic
D)Ferromagnatism
170. Which substances are repelled by the applied field?

A)Paramagnetic
B)Diamagnetic
C)Ferrimagnetic
D)Ferromagnatism
171. Which of the following substances are attracted
toward the applied field?

A)Paramagnetic
B)Diamagnetic
C)Both A and B
D)None of the above
171. Which of the following substances are attracted
toward the applied field?

A)Paramagnetic
B)Diamagnetic
C)Both A and B
D)None of the above
172. Substances which attracted very strongly by applied
field is said to be-

A)Ferromagnetic
B)Diamagnetic
C)Paramagnetic
D)All of the above
172. Substances which attracted very strongly by applied
field is said to be-

A)Ferromagnetic
B)Diamagnetic
C)Paramagnetic
D)All of the above
173. Choose the incorrect statement(s).

A)Ferromagnetism is an extreme form of paramagnetism.

B)Ferromagnetism is an extreme form of diamegnatism.
C)Most of the transition metals are paramagetic.
D)Paramagnetism arises from the presence of unpaired.
173. Choose the incorrect statement(s).

A)Ferromagnetism is an extreme form of paramagnetism.

B)Ferromagnetism is an extreme form of diamagnatism.
C)Most of the transition metals are paramagetic.
D)Paramagnetism arises from the presence of unpaired.
174. The magnetic moment of unpaired e- is associated with

A)Spin angular momentum

B)Orbital angular momentum
C)Both A and B
D)None of the above
174. The magnetic moment of a unpaired e- is associated
with

A)Spin angular momentum

B)Orbital angular momentum
C)Both A and B
D)None of the above
176. What is the formula for calculating magnetic moment of
first series of transition metal?

A)𝑀 = 𝑋(𝑥 + 2)
B)𝑀 = 𝑥 𝑥 + 4
C)𝑀 = 𝑥+1 𝑥

1
D)𝑀 = 𝑥 𝑥 +
2
176. What is the formula for calculating magnetic moment of
first series of transition metal?

A)𝑀 = 𝑋(𝑥 + 2)
B)𝑀 = 𝑥 𝑥 + 4
C)𝑀 = 𝑥+1 𝑥

1
D)𝑀 = 𝑥 𝑥 +
2
177. Magnetic moment of a species is calculated in which
unit?

A)Decibel
B)Bohr Magnetons (BM)
C)Ampere
D)Joule
177. Magnetic moment of a species is calculated in which
unit?

A)Decibel
B)Bohr Magnetons (BM)
C)Ampere
D)Joule
178. What is the value of Magnetic moment of a species
having only one unpaired e-?

A)1.73 B.M.
B)2.84 B.M.
C)0 B.M.
D)3.87 B.M.
178. What is the value of Magnetic moment of a species
having only one unpaired e-?

A)1.73 B.M.
B)2.84 B.M.
C)0 B.M.
D)3.87 B.M.
179. Choose the incorrect statements(s) from the given statements.
A) Magnetic moment is determined by the number of unpaired e-s
B) Magnetic moment decreases with the increasing number of unpaired electrons.
C) Observed magnetic moment gives a useful indication about the number of
unpaired e-s present in the atom.
D) The Magnetic moment of a first series of transition metal calculated from 'Spin-
only' formula.
179. Choose the incorrect statements(s) from the given statements.

A) Magnetic moment is determined by the number of unpaired e-s

B) Magnetic moment decreases with the increasing number of unpaired electrons.
C) Observed magnetic moment gives a useful indication about the number of
unpaired e-s present in the atom.
D) The Magnetic moment of a first series of transition metal calculated from 'Spin-
only' formula.
180. Which is the magnetic moment (spin only) of Sc3+?

A)0 B.M.
B)1.73 B.M.
C)2.84 B.M.
D)3.87 B.M.
180. Which is the magnetic moment (spin only) of Sc3+?

A)0 B.M.
B)1.73 B.M.
C)2.84 B.M.
D)3.87 B.M.
181. How many of the given ins have spin only magnetic
moment value 1.73 B.M.?
Sc3+, Ti3+, Cu2+, Ti2+, V2+

A)2
B)4
C)5
D)1
181. How many of the given ins have spin only magnetic
moment value 1.73 B.M.?
Sc3+, Ti3+, Cu2+, Ti2+, V2+

A)2
B)4
C)5
D)1
182. Find out the value of Magnetic moment (spin only) of
Ti2+?

A)2.84 B.M.
B)0 B.M.
C)1.73 B.M.
D)490 B.M.
182. Find out the value of Magnetic moment (spin only) of
Ti2+?

A)2.84 B.M.
B)0 B.M.
C)1.73 B.M.
D)490 B.M.
183. If a element has Ec 3d3 than what would be the
magnetic moment (spin only)?

A)5.92 B.M.
B)3.87 B.M.
C)1.73 B.M.
D)2.84 B.M.
183. If a element has configuration 3d3 than what would
be the magnetic moment (spin only)?

A)5.92 B.M.
B)3.87 B.M.
C)1.73 B.M.
D)2.84 B.M.
184. What is the spin only magnetic moment value of Cr2+?

A)4.2 B.M.
B)4.9 B.M.
C)5.92 B.M.
D)2.84 B.M.
184. What is the spin only magnetic moment value of
Cr2+?

A)4.2 B.M.
B)4.9 B.M.
C)5.92 B.M.
D)2.84 B.M.
185. Which of the following ion has highest value of
Magnetic moment (spin only)?

A)Cr2+
B)Fe2+
C)Mn2+
D)CO2+
185. Which of the following ion has highest value of
Magnetic moment (spin only)?

A)Cr2+
B)Fe2+
C)Mn2+
D)CO2+
186. Which of the following pair have same magnetic
moment value (spin only)?

A)CO2+ & V2+

B)Zn2+ & Ti3+
C)Ni2+ & Mn2+
D)Sc3+ & Ti2+
186. Which of the following pair have same magnetic
moment value (spin only)?

A)CO2+ & V2+

B)Zn2+ & Ti3+
C)Ni2+ & Mn2+
D)Sc3+ & Ti2+
8.3.10 Formation of Coloured Ions
188. In which region frequency of absorbed light lies during
excitation of e- from lower energy to higher energy ?
A)UV region
B)Visible region
C)Near IR region
D)Far IR region
188. In which region frequency of absorbed light lies during
excitation of e- from lower energy to higher energy ?
A)UV region
B)Visible region
C)Near IR region
D)Far IR region
189. The frequency of the light absorbed is determined by-

A)nature of ligand
B)metal ion
C)both A and B
D)None of the above
189. The frequency of the light absorbed is determined by-

A)nature of ligand
B)metal ion
C)both A and B
D)None of the above
190. Which of the following ions is not colorless?

A)Sc3+
B)Ti4+
C)Zn2+
D)Ti3+
190. Which of the following ions is not colorless?

A)Sc3+
B)Ti4+
C)Zn2+
D)Ti3+
8.3.11 Formation of Complex
Compound
196. Which of the following is/are reason for complex
formation tendency of Transition metals?

A)Smaller size of the metal ions

B)High ionic charges
C)Availability of d-orbitals
D)All of the above
196. Which of the following is/are region for complex
formation tendency of Transition metals?

A)Smaller size of the metal ions

B)High ionic charges
C)Availability of d-orbitals
D)All of the above
8.3.12 Catalytic Properties
197. The catalytic activity of transition metal is due to-

A)ability to adopt multiple oxidation state

B)ability to form complexes
C)both A and B
D)None of the above
197. The catalytic activity of transition metal is due to-

A)ability to adopt multiple oxidation state

B)ability to form complexes
C)both A and B
D)None of the above
198. Which of the following is not correctly matched?

A)Contact process → Vanandium (V) Oxide

B)Haber's process → Finely divided Iron
C)Catalytic Hydrogenation → Nickel
D)Ostwald Process → MnO2
198. Which of the following is not correctly matched?

A)Contact process → Vanandium (V) Oxide

B)Haber's process → Finely divided Iron
C)Catalytic Hydrogenation → Nickel
D)Ostwald Process → MnO2
199. Transition metal itself act as an effective catalyst
because.

A)they can change their oxidation states

B)they have orbital
C)they posses metallic properties
D)they have high M.P. and b.p.
199. Transition metal itself act as an effective catalyst
because.

A)they can change their oxidation states

B)they have orbital
C)they posses metallic properties
D)they have high M.P. and b.p.
201. Which of the following ion catalyzes the given reaction?
2I − + S2 O2−
8 → I 2 + 2SO2−
4

A)Fe (III)
B)Mn (II)
C)Cr (III)
D)Sc (III)
201. Which of the following ion catelyses the given reaction?
2I − + S2 O2−
2 → I 2 + 2SO2−
4

A)Fe (III)
B)Mn (II)
C)Cr (III)
D)Sc (III)
8.3.13 Formation of Interstitial Compounds
202. Which atoms are trapped inside the crystal lattice of
metals to form interstitial compounds?

A)B , C , N
B)H , C , N
C)C , N , O
D)N , O , F
202. Which atoms are trapped inside the crystal lattice of
metals to form interstitial compounds?

A)B , C , N
B)H , C , N
C)C , N , O
D)N , O , F
203. The correct statement(s) regarding interstitial
compounds is/are:

A)They are usually non-stoichiometry

B)They are neither typically ionic nor covalent
C)H , C or N atoms are trapped inside the crystal lattice
D)All of the above
203. The correct statement(s) regarding interstitial
compounds is/are:

A)They are usually non-stoichiometry

B)They are neither typically ionic nor covalent
C)H , C or N atoms are trapped inside the crystal lattice
D)All of the above
204. Which of the following is not a interstitial compound?

A)Tic
B)NaH
C)VH0.56
D)Fe3H
204. Which of the following is not a interstitial compound?

A)Tic
B)NaH
C)VH0.56
D)Fe3H
205. Which of the following is/are interstitial compound?

A)Mn4N
B)TiH1.7
C)Fe3H
D)All of the above
205. Which of the following is/are interstitial compound?

A)Mn4N
B)TiH1.7
C)Fe3H
D)All of the above
206. I) They have high melting points, higher than those of pure metals.
II) They are very hard, some borides approach diamond in hardness.
III) They have low melting points, lower than those of pure metals.
IV) They retain metallic conductivity.
V) They are chemical inert.
VI) They are chemically reactive.
Of the given statements, which of the following statements is/are
correct?

A) I , II , IV , V
B)II , IV , V , VI
C)I , III , IV , V
D)II , IV , V , VI
206. I) They have high melting points, higher than those of pure metals.
II) They are very hard, some borides approach diamond in hardness.
III) They have low melting points, lower than those of pure metals.
IV) They retain metallic conductivity.
V) They are chemical inert.
VI) They are chemically reactive.
Of the given statements, which of the following statements is/are
correct?

A) I , II , IV , V
B)II , IV , V , VI
C)I , III , IV , V
D)II , IV , V , VI
8.3.14 Alloy Formation
207. Which of the following statements is/are correct
regarding alloy?

A)Alloy is a blends of metals

B)Alloy may be homogeneous solid solutions
C)Alloy are formed by atoms with metallic radii that are
within about 15% of each other
D)All of the above
207. Which of the following statements is/are correct
regarding alloy?

A)Alloy is a blends of metals

B)Alloy may be homogeneous solid solutions
C)Alloy are formed by atoms with metallic radii that are
within about 15% of each other
D)All of the above
208. Which of the following statement(s) is/are true
regarding alloy?

A)Alloy are readily formed by the transition metals

B)Alloy are hard
C)Alloy have often high melting point
D)All of the above
208. Which of the following statement(s) is/are true
regarding alloy?

A)Alloy are readily formed by the transition metals

B)Alloy are hard
C)Alloy have often high melting point
D)All of the above
209. Which of the following transition metals are
used in production of a variety of steels and
stainless steel?

A)Cr
B)V
C)Mo
D)All of the above
209. Which of the following transition metals are
used in production of a variety of steels and
stainless steel?

A)Cr
B)V
C)Mo
D)All of the above
210. Which of the following transition metals is not
used in production of a variety of steels and stainless
steel?

A)Mn
B)W
C)V
D)Zn
210. Which of the following transition metals is not
used in production of a variety of steels and stainless
steel?

A)Mn
B)W
C)V
D)Zn
211. Brass is an alloy of:

A)Copper + Zinc
B)Copper + Tin
C)Tin + Zinc
D)Copper + Aluminium
211. Brass is an alloy of:

A)Copper + Zinc
B)Copper + Tin
C)Tin + Zinc
D)Copper + Aluminium
212. Bronze is an alloy of:

A)Copper – Zinc
B)Copper – Tin
C)Tin – Zinc
D)Copper – Aluminium
212. Bronze is an alloy of:

A)Copper – Zinc
B)Copper – Tin
C)Tin – Zinc
D)Copper – Aluminium
213. Coin is an alloy of:

A)Copper – Zinc
B)Copper – Tin
C)Tin – Zinc
D)Copper – Aluminium
213. Coin is an alloy of:

A)Copper – Zinc
B)Copper – Tin
C)Tin – Zinc
D)Copper – Aluminium
214. Bell metal is an alloy of:

A)Cu + Sn + Fe
B)Cu + Sn + Zn
C)Sn + Zn + Fe
D)Cu + Fe + Al
214. Bell metal is an alloy of:

A)Cu + Sn + Fe
B)Cu + Sn + Zn
C)Sn + Zn + Fe
D)Cu + Fe + Al
215. Steel is an alloy of:

A)Fe (metal – Cr , Ni) + C (non – metal)

B)Fe (metal – Cr , Ni) + N (non – metal)
C)Cu + Sn + Fe
D)Cu + Sn + Zn
215. Steel is an alloy of:

A)Fe (metal – Cr , Ni) + C (non – metal)

B)Fe (metal – Cr , Ni) + N (non – metal)
C)Cu + Sn + Fe
D)Cu + Sn + Zn
8.4 Some Important
compounds of Transition
Elements
8.4.1 Oxides and Oxanion of
metals
216. Which of the following transition metal
don’t form MO oxides?

A)Sc
B)V
C)Ti
D)Mn
216. Which of the following transition metal
don’t form MO oxides?

A)Sc
+3¥
B)V
C)Ti
D)Mn
 217. What is the nature of MO type oxides
formed by transition metals?

⑤
'
A)Covalent
o
B)Ionic
✓C)Both A and B
D)None of the above
217. What is the nature of MO type oxides
formed by transition metals?

A)Covalent
B)Ionic
C)Both A and B
D)None of the above
218. Which of the following relation is correct
between oxidation number and ionic character of
transition metals oxides?

A)Oxidation number of a metal increases , ionic

character decreases
B)Oxidation number of a metal decreases , ionic
character decreases
C)Oxidation number of a metal increases , ionic
character increases
D)Both B and C
218. Which of the following relation is correct
between oxidation number and ionic character of
transition metals oxides?

↓
character decreases
↑
A)Oxidation number of a metal increases , ionic

B)Oxidation number of a metal decreases , ionic

character decreases
C)Oxidation number of a metal increases , ionic
character increases
D)Both B and C
 1- 7
219. Mn2O7 is a:

A)Covalent green oil

B)Covalent red oil
C)Covalent blue oil
D)Covalent pink oil
 219. Mn2O7 is a:

tA)Covalent green oil

B)Covalent red oil
C)Covalent blue oil
D)Covalent pink oil
220. Which of the following oxide(s) have low
melting point?

A)CrO3
B)V2O5
C)Both A and B
D)None of the above
 220. Which of the following oxide(s) have low
melting point?

A)CrO3
B)V2O5
C)Both A and B
vD)None of the above
221. Which of the following would be form when
Mn2O7 dissolve in water?

#
A)HMnO µÑn%y
4
B)H2MnO4
C)H3MnO4
D)Both A and B
221. Which of the following would be form when
Mn2O7 dissolve in water?

A)HMnO4
B)H2MnO4
C)H3MnO4
D)Both A and B
 1- 6

222. CrO3 dissolve in water to give an acid:

A)HCrO4
-B)H2CrO4
C)H2Cr2O7
D)Both A and C
222. CrO3 dissolve in water to give an acid:

A)HCrO4
B)H2CrO4
C)H2Cr2O7
D)Both A and C
 +7
223. HMnO4 is the hydride of:

A)MnO2
B)MnO
C)Mn2O7
-
D)Mn2O3
223. HMnO4 is the hydride of:

A)MnO2
B)MnO
C)Mn2O7
D)Mn2O3
 +5

224. What kind of oxide is V2O5?

A)Acidic
B)Amphoteric
C)Basic
D)Neutral
224. What kind of oxide is V2O5?

A)Acidic
B)Amphoteric
C)Basic
D)Neutral
225. Which of the following salts can be obtained from
V2O5?

A)VO3−
4
B)VO+
2
C)Both A and B
D)None of the above
225. Which of the following salts can
be obtained from V2O5?

A)VO3−
4
B)VO+
2
C)Both A and B
D)None of the above
 acidic Str 2 oxdn no

226. What is the basic strength order

of vanadium oxides?

A)V2O4 > V2O5 > V2O3

B)V2O3 > V2O5 > V2O4
C)V2O3 > V2O4 > V2O5
D)V2O5 > V2O5 > V2O4
 226. What is the basic strength order
of vanadium oxides?

A)V2O4 > V2O5 > V2O3

B)V2O3 > V2O5 > V2O4
C)V2O3 > V2O4 > V2O5
✓D)V O > V O > V O
2 5 2 5 2 4
228. Which of the following ion(s)
is/are obtained when V2O5 reacts with
alkalies?

A)VO3−
4
B)VO+
4
C)VO+
2
D)VO2+
 228. Which of the following ion(s)
is/are obtained when V2O5 reacts with
alkalies?

3−
A)
✓ 4 VO
B)VO+
C)VO+
4
2
arid
D)VO2+
 229. V2O5 reacts with acids to give:

+
u 2
A) VO
B)VO2+
C)VO+
4
D)None of the above
229. V2O5 reacts with acids to give:

A)VO+
2
B)VO2+
C)VO+
4
D)None of the above
 230. Which of the following oxide is
basic in nature?

A)CrO
B)Cr2O3
C)V2O3
tD)Both A and C
230. Which of the following oxide is
basic in nature?

A)CrO
B)Cr2O3
C)V2O3
D)Both A and C
231. Which of the following oxide is
amphoteric in nature?

A)Cr2O3
B)CrO
C)V2O3
D)Both A and B
231. Which of the following oxide is
amphoteric in nature?
1-3
A)Cr2O3
oxide)
B)CrO Crt 20 (Basic
C)V2O3
D)Both A and B
Potassium Dichromate (K2Cr2O7)
232. Which of the following chemical is used in
leather industry?
-

A)K2Cr2O7
B)KMnO4
C)Na2Cr2O7
D)NaCl
232. Which of the following chemical is used in
leather industry?
-

A)K2Cr2O7
B)KMnO4
C)Na2Cr2O7
D)NaCl
234. Dichromate are generally
obtained from:

A)Chromate
B)Permanganate
C)Manganate
D)All of the above
 234. Dichromate are generally
obtained from:

A)Chromate
_B)Permanganate
C)Manganate
D)All of the above
 235. Which of the following chemical is fused
with chromate ore to obtained chromate? (M =
K or Na)
-

-A)M CO
2
B)NaCl
3

C)NaOH
D)Na2O
235. Which of the following chemical is fused
with chromate ore to obtained chromate? (M =
K or Na)

A)M2CO3
B)NaCl
C)NaOH
D)Na2O
 236. What is the chemical formula
of chromite ore?

A)FeCr2O4
-B)Na2Cr2O7
C)Fe2O3
D)Na2CrO4
236. What is the chemical formula
of chromite ore?

A)FeCr2O4
B)Na2Cr2O7
C)Fe2O3
D)Na2CrO4
237. Identify X and Y in the given reaction.
FeCr2O4 + X + O2 → Na2CrO4 + Y + CO2

A)Na2CO3 , FeO
B)Na2CO3 , Fe2O4
C)Na2CO3 , Fe2O3
D)None of the above
 237. Identify X and Y in the given reaction.
FeCr2O4 + X + O2 → Na2CrO4 + Y + CO2

A)Na2CO3 , FeO
B)Na2CO3 , Fe2O4
✓C)Na2CO3 , Fe2O3
D)None of the above
238. What is the yellow solution obtained on fusion
of chromite ore (FeCr2O4) with sodium carbonate in
free access of air?

A)Na2Cr2O7
B)Na2CrO4
t
C)Na2O + Cr2O3
D)None of the above
238. What is the yellow solution obtained on fusion
of chromite ore (FeCr2O4) with sodium carbonate in
free access of air?

A)Na2Cr2O7
B)Na2CrO4
C)Na2O + Cr2O3
D)None of the above
239. Which of the following chemical is used to
acidify sodium chromate to give a solution of
sodium dichromate?

A)HCl ↳ d

÷
B)HNO3
C)H2SO4
D)H3PO4
 239. Which of the following chemical is used to
acidify sodium chromate to give a solution of
sodium dichromate?

A)HCl
B)HNO3
vC)H2SO4
D)H3PO4
240. What is the colour of sodium
chromate solution?
-

am

Hunt
-

A)Orange
B)Red
C)Yellow
D)Brown golden an
240. What is the colour of sodium
chromate solution?

A)Orange
B)Red
C)Yellow
D)Brown
241. What is the colour of
Na2Cr2O7?

-
A)Orange
B)Yellow
C)Red
D)Pink
241. What is the colour of
Na2Cr2O7?

A)Orange
B)Yellow
C)Red
D)Pink
242. Which compound is crystallised when sodium
- -
=
chromate solution is acidified with Sulphuric acid?

A)Na2Cr2O7.3H2O
B)Na2Cr2O7.2H2O
C)Na2Cr2O7.5H2O
D)Na2Cr2O7.7H2O
242. Which compound is crystallised when sodium
chromate solution is acidified with Sulphuric acid?

A)Na2Cr2O7.3H2O
B)Na2Cr2O7.2H2O
C)Na2Cr2O7.5H2O
D)Na2Cr2O7.7H2O
243. What is the colour of the product (x) formed in the
given reaction?
Na2CrO4 + H+ → X + Na+ + H2O
yellow au 'd Maziarz
07
A)Yellow
B)Blue ¥
t
C)Orange
D)Green
243. What is the colour of the product (x) formed in the
given reaction?
Na2CrO4 + H+ → X + Na+ + H2O

A)Yellow
B)Blue
C)Orange
D)Green
244. What is the ‘X’ in the given reaction?
Na2Cr2O7 + KCl → K2Cr2O7 + X
Nacl
A)NaCl
B)HCl
C)KCl
D)KClO3
244. What is the ‘X’ in the given reaction?
Na2Cr2O7 + KCl → K2Cr2O7 + X

A)NaCl
B)HCl
C)KCl
D)KClO3
245. When an alkali is added to orange colour of
Potassium dichromate , it forms:

C d
A)Ferrochrome

÷
B)Chromyl chloride
C)Chromium Trioxide
D)Chromate
245. When an alkali is added to orange colour of
Potassium dichromate , it forms:

A)Ferrochrome
B)Chromyl chloride
C)Chromium Trioxide
D)Chromate
✓
246. When an acid is added to
chromate it forms:

A)Chromyl chloride C d
B)Chromium trioxide base
C)Chromium dioxide
-
D)Dichromate
246. When an acid is added to
chromate it forms:

A)Chromyl chloride
B)Chromium trioxide
C)Chromium dioxide
D)Dichromate
247. Identify products (x) and (y) in the
given reaction.
2−
Cr2O2−
7 + X → CrO 4 + Y
d- c-
A)H+ , H2O
B)H+ , O2
C)OH- , H2O
D)OH- , O2
 247. Identify products (x) and (y) in the
given reaction.
2−
Cr2O2−
7 + X → Cr 2 4 + Y
O

A)H+ , H2O
B)H+ , O2
C)OH- , H2O
✓D)OH- , O2
248. What is the oxidation state of chromium in
chromate and dichromate?

A) +6 , +7
B)+5 , +5
C)+3 , +6
D)+6 , +6
248. What is the oxidation state of chromium in
chromate and dichromate?

A) +6 , +7
B)+5 , +5
C)+3 , +6
D)+6 , +6
r
 249. Which is the correct geometry of
chromate ion?

A)Planar
B)T – shape
C)Tetrahedral
-D)Square planar
249. Which is the correct geometry of
chromate ion?

A)Planar
B)T – shape
C)Tetrahedral
D)Square planar
250. Which one is the correct shape of chromate ion?

A)

B)

C)

D) None of the above

250. Which one is the correct shape of chromate ion?
-2

A) Croy

B)
v

C)

D) None of the above

251. Choose the incorrect statement about structure

¥
°
of dichromate ion? - -
or
◦

✗
A)Dichromate ion consists of one planar and one
tetrahedral sharing one corner with Cr-O-O-Cr
=
bridge
B)Dichromate ion consists of two tetrahedral sharing
one corner with Cr-O-Cr bridge
C)The bridge Cr-O bond length is more than terminal
Cr-O bond length
D)Total number of terminal Cr-O bond is 6
251. Choose the incorrect statement about structure
of dichromate ion?

A)Dichromate ion consists of one planar and one

tetrahedral sharing one corner with Cr-O-O-Cr
bridge
B)Dichromate ion consists of two tetrahedral sharing
one corner with Cr-O-Cr bridge
C)The bridge Cr-O bond length is more than terminal
Cr-O bond length
D)Total number of terminal Cr-O bond is 6
 252. Sodium and potassium dichromate act as:

✓
A)Strong oxidising agent crtb -
arts
B)Weak oxidising agent
C)Strong reducing agent Unstable Stable
D)Weak reducing agent
Self
Reduce
252. Sodium and potassium dichromate act as:

A)Strong oxidising agent

B)Weak oxidising agent
C)Strong reducing agent
D)Weak reducing agent
253. Which of the following chemical is used
as a primary standard in volumetric
analysis?

A)KCl
B)K2Cr2O7
C)Na2Cr2O7
D)K2CrO4
 253. Which of the following chemical is used
as a primary standard in volumetric
analysis?

A)KCl
✓
B)K 2 Cr 2 O7
C)Na2Cr2O7
D)K2CrO4
254. In acidic solution the oxidising action of
dichromate ion can be represented as:

A)Cr2O2−
7 + 14H + 6e → 2Cr
+ - 3+ + 7O
2
B)Cr2O2−
7 + 14H + 6e → 2Cr
+ - 3+ + 7H O
2 2
C)Cr2O2−
7 + 14H + 6e → 2Cr
+ - 3+ + 7H
2
D)Cr2O2−
7 + 14H + 6e → 2Cr
+ - 3+ + 7H O
2

2min
254. In acidic solution the oxidising action of
dichromate ion can be represented as:

A)Cr2O2−
7 + 14H + 6e → 2Cr
+ - 3+ + 7O
2
B)Cr2O2−
7 + 14H + 6e → 2Cr
+ - 3+ + 7H O
2 2
C)Cr2O2−
7 + 14H + 6e → 2Cr
+ - 3+ + 7H
2
D)Cr2O2−
7 + 14H + 6e → 2Cr
+ - 3+ + 7H O
2
r
 255. Which of the following is not correct regarding
oxidising property of potassium dichromate? The
-

potassium dichromate oxidises:

-

I Iz
A)Iodides to Iodine - Z
so
S →
✓
B)Sulphides to Sulphurdioxide ✗
C)Tin(II) to Tin(IV)
D)Iron (II) to Iron(III)
255. Which of the following is not correct regarding
oxidising property of potassium dichromate? The
potassium dichromate oxidises:

A)Iodides to Iodine
B)Sulphides to Sulphurdioxide
C)Tin(II) to Tin(IV)
D)Iron (II) to Iron(III)
 256. I) Cr2O2−
7 + 14H + + 6Fe2+ → 2Cr3+ + 6Fe3+ + 7H O
2
II) Cr2O2−
7 + 14H + + 6I- → 2Cr3+ + 3I + 7H O
2 2
III) Cr2O2− + 14H 2 *
+ + 3H S → 2Cr3+ + 3SO + 7H O
7 2 2
IV) Cr2O2−7 + 14H + + 3Sn2+ → 2Cr3+ + 3Sn4+ + 7H O
2
Which of the following reaction is wrong?
=

✓A)III
B)II
C)I
D)IV
256. I) Cr2O2−
7 + 14H + + 6Fe2+ → 2Cr3+ + 6Fe3+ + 7H O
2
II) Cr2O2−
7 + 14H + + 6I- → 2Cr3+ + 3I + 7H O
2 2
III) Cr2O2−
7 + 14H + + 3H S → 2Cr3+ + 3SO + 7H O
2 2 2
IV) Cr2O2−7 + 14H + + 3Sn2+ → 2Cr3+ + 3Sn4+ + 7H O
2
Which of the following reaction is wrong?

A)III
B)II
C)I
D)IV
 257. What is the number of e- involve in the
reaction of dichromate and iodide?

A)3
B)6
a
C)4
D)5
257. What is the number of e- involve in the
reaction of dichromate and iodide?

A)3
B)6
C)4
D)5
Potassium Permanganate (KMnO4)
 258. Potassium permanganate is prepared by fusion
of _____ with an ____ and an oxidizing gent like____.

A)MnO2, alkaline metal hydroxide, HNO3

F-
B)MnO , alkali metal hydroxide, KNO
2 - 3

C)Mn2O7, alkaline metal hydroxide, HNO3

D)Mn2O7, alkali metal hydroxide, KNO3
258. Potassium permanganate is prepared by fusion
of _____ with an ____ and an oxidizing gent like____.

A)MnO2, alkaline metal hydroxide, HNO3

B)MnO2, alkali metal hydroxide, KNO3
C)Mn2O7, alkaline metal hydroxide, HNO3
D)Mn2O7, alkali metal hydroxide, KNO3
259. Which of the following compound is produced
by the fusion of MnO2 with an alkali metal hydroxide
and KNO3?

A)Dark green KMnO4

B)Dark green K2MnO4
C)Light green K2MnO4
D)Pale yellow K2MnO4
 259. Which of the following compound is produced
by the fusion of MnO2 with an alkali metal hydroxide
and KNO3?

A)Dark green KMnO4

B)Dark green K2MnO4
✓
C)Light green K2MnO4
D)Pale yellow K2MnO4
 +6
260. In which medium K2MnO4 disproportionate to
give permanganate?
7
Mnt
-

A)Neutral
B)Acidic }
C)Basic
D)Both A and B
260. In which medium K2MnO4 disproportionate to
give permanganate?

A)Neutral
B)Acidic
C)Basic
D)Both A and B
261. Identify M in the given reaction?
MnO2 + MOH + O2 → K2MnO4 + H2O
KOH
A)K
B)Mg
C)Ca
D)Ba
261. Identify M in the given reaction?
MnO2 + MOH + O2 → K2MnO4 + H2O

A)K
B)Mg
C)Ca
D)Ba
263. What can be X in the given reaction?
MnO42- + X → MnO−
4 + MnO2 + H2O

A)OH-
B)H+ ✓
C)Both A and B
D)None of the above
263. What can be X in the given reaction?
MnO42- + X → MnO−
4 + MnO2 + H2O

A)OH-
B)H+
C)Both A and B
D)None of the above
264. Commercially, Potassium permanganate is
prepared by the alkaline oxidative fusion of _____
followed by _____ of manganite (VI).

A)MnO2, electrolytic reduction

B)MnO2, electrolytic oxidation✓
C)Mn2O3, electrolytic reduction
Mn2O3, electrolytic oxidation
264. Commercially, Potassium permanganate is
prepared by the alkaline oxidative fusion of _____
followed by _____ of manganite (VI).

A)MnO2, electrolytic reduction

B)MnO2, electrolytic oxidation
C)Mn2O3, electrolytic reduction
Mn2O3, electrolytic oxidation
 265. When MnO2 is fused with KOH in presence of
air or KNO3, the product formed is

A)Purple colour KMnO4

_
B)Green colour K2MnO4
C)Colourless Mn3O4
D)Purple colour K2MnO4
265. When MnO2 is fused with KOH in presence of
air or KNO3, the product formed is

A)Purple colour KMnO4

B)Green colour K2MnO4
C)Colourless Mn3O4
D)Purple colour K2MnO4
 266.

what is (X) the above reaction

A)Colourless Mn3O4
B)Green colour K2MnO4
=
C)Purple colour KMnO4
D)Purple colour K2MnO4
 266.

what is (X) the above reaction

A)Colourless Mn3O4
B)Green colour K2MnO4
C)Purple colour KMnO4
D)Purple colour K2MnO4
 267.
What is the colour of (X) formed in the
above reaction?

A)Red
B)Pink
C)Purple
per magnate
D)Green
 267.
What is the colour of (X) formed in the
above reaction?

A)Red
B)Pink
C)Purple
D)Green
269. What is (X) in the given reaction?
+7
Mn2+ + S2 O2−
8 + 8H 2 O → MnO −
4 + X + H +

A)S2 O2−
3

B)S2 O2−
7

C)S2 O2−
4

D)S2 O2−
3
269. What is (X) in the given reaction?
Mn2+ + S2 O2−
8 + 8H 2 O → MnO −
4 + X + H +
-2
Szoy
A)S2 O2−
3

B)S2 O2−
7

C)S2 O2−
4
✓
D)S2 O2−
3
272. Which of the given compound is
isostructural with KMnO4?

=
A)K2Cr2O7
B)KClO4
C)KNO3
D)K2SO4
272. Which of the given compound is
isostructural with KMnO4?

A)K2Cr2O7
B)KClO4
C)KNO3
D)K2SO4
 273. The colour of potassium
permanganate crystals is –

r
A)Dark purple
B)Dark green
C)Dark yellow
D)Dark blue
273. The colour of potassium
permanganate crystals is –

A)Dark purple
B)Dark green
C)Dark yellow
D)Dark blue
274. The incorrect statement about
potassium permanganate is not very
soluble in water

A)Not very soluble in water

B)Decomposed at 513K
C)Readily soluble in water
D)Isostructured with KClO4
274. The incorrect statement about

:
potassium permanganate is not very
soluble in water

A)Not very soluble in water

B)Decomposed at 513K
C)Readily soluble in water
D)Isostructured with KClO4
275. Identify ‘X’ in the given reaction
2KMnO4 → K2MnO4 + X + O2

A)MnO
B)Mn2O3
C)Mn3O4
D)MnO2
275. Identify ‘X’ in the given reaction
2KMnO4 → K2MnO4 + X + O2

magnet minor _

A)MnO
B)Mn2O3
C)Mn3O4
D)MnO2
✓
276. A deep purple colour (A) compound on heating
decompound at 513 K to give a green (B) and brown
(C) colour compound along with oxygen. Name the A,
B, C

A)A = K2MnO4, B = KMnO4, C = MnO2

B)A = KMnO4, B = K2MnO4, C = Mn2O3
C)A = KMnO4, B = K2MnO4, C = MnO2 r
D)A = K2MnO4, B = KMnO4, C = Mn2O3
276. A deep purple colour (A) compound on heating
decompound at 513 K to give a green (B) and brown
(C) colour compound along with oxygen. Name the A,
B, C

A)A = K2MnO4, B = KMnO4, C = MnO2

B)A = KMnO4, B = K2MnO4, C = Mn2O3
C)A = KMnO4, B = K2MnO4, C = MnO2
D)A = K2MnO4, B = KMnO4, C = Mn2O3
279. What are the geometry magnate
and permanganate ion respectively?

A)Tetrahedral, Trigonal planar

B)Square planar, tetrahedral
C)Square planar, Square planar

v
D)Tetrahedral, Tetrahedral
279. What are the geometry magnate
and permanganate ion respectively?

A)Tetrahedral, Trigonal planar

B)Square planar, tetrahedral
C)Square planar, Square planar
D)Tetrahedral, Tetrahedral
280. In magnate and permanganate π – bonding take place
by the overlap of Mn =D

A)p – orbital of manganese and p – orbital of oxygen

B)p – orbital of oxygen and d – orbital of manganese
-
C)d – orbital of oxygen and d – orbital of manganese
D)p – orbital of manganese and d – orbital of oxygen
280. In magnate and permanganate π – bonding take place
by the overlap of

A)p – orbital of manganese and p – orbital of oxygen

B)p – orbital of oxygen and d – orbital of manganese
C)d – orbital of oxygen and d – orbital of manganese
D)p – orbital of manganese and d – orbital of oxygen
 281. What is the colour of magnate ion?

_
A)Green
B)Purple
C)Pink
D)Brown
281. What is the colour of magnate ion?

A)Green
B)Purple
C)Pink
D)Brown
282. The number of unpaired e- in magnate ion is
equal to -2

mnoy
A)0 mntb
B)2
C)3
↳ ①
D)1
✓
282. The number of unpaired e- in magnate ion is
equal to

A)0
B)2
C)3
D)1
 283. The green magnate is:

↳ d
'

✓ A)Paramagnetic
B)Diamagnetic
C)Ferromagnetic
D)Ferromagnetic
283. The green magnate is:

A)Paramagnetic
B)Diamagnetic
C)Ferromagnetic
D)Ferromagnetic
284. How many number of unpaired e- present in
permanganate ion?

KMDOY
A)1
B)2 mntt
✓
C)0
D)3
284. How many number of unpaired e- present in
permanganate ion?

A)1
B)2
C)0
D)3
 285. The permanganate ion is:

A)Paramagnetic

✓B)Diamagnetic
C)Ferromagnetic
D)Antiferromagnetic
285. The permanganate ion is:

A)Paramagnetic
B)Diamagnetic
C)Ferromagnetic
D)Antiferromagnetic
286. The correct structure of magnate ion is

/
A) B)

C) D)
286. The correct structure of magnate ion is

A) B)

C) D)
 O
O

Mn
Mn

287. The correct structure of permanganate is-

O -
O
-
O O
O
O

/
A) B)

C) D)
 O
O

Mn
Mn

287. The correct structure of permanganate is-

O -
O
-
O O
O
O

A) B)

C) D)
 289. Acidified magnate ions oxidized –
(I)Oxalates to carbon dioxide Ezo ,
-2
- Foz
(II)Iron (II) to iron (III) Fetz → Fet]

(III)Nitrites to nitrates NOI → NO-5

(IV)Iodides to iodates
-

I Iz
✗
→

of the given statements (I – IV), which of the following is

not true?

A) I B) IV
C) III D) II
289. Acidified magnate ions oxidized –
(I)Oxalates to carbon dioxide
(II)Iron (II) to iron (III)
(III)Nitrites to nitrates
(IV)Iodides to iodates
of the given statements (I – IV), which of the following is
not true?

A) I B) IV
C) III D) II
291. Acidified KMnO4 oxidises hydrogen sulphide to

Has"→ so
A)Sulphur dioxide
B)Sulphur Trioxide
C)Sulphur
D)Both A and C
291. Acidified KMnO4 oxidises hydrogen sulphide to

A)Sulphur dioxide
B)Sulphur Trioxide
C)Sulphur
D)Both A and C
292. Which of the following oxidized to sulphate or
-

sulphuric acid by acidified KMnO4?

-
-

A)SO2−
3

B)S2-
C)Both A and B
D)None of the above
292. Which of the following oxidized to sulphate or
sulphuric acid by acidified KMnO4?

5052
-2

A)SO2− - soy
✓ 3

B)S2-
C)Both A and B
D)None of the above
293. Which of the following compound oxidized to
sulphuric acid by acidified KMnO4?
-2
503-2 _ soy
A)H2S
B)H2SO3
42503 →
Hzsoy
✓
C)H2SO5
D)None of these
293. Which of the following compound oxidized to
sulphuric acid by acidified KMnO4?

A)H2S
B)H2SO3
C)H2SO5
D)None of these
295. Which of the following regent can oxidized iodide
-

to iodate?
-

A)Acidified KMnO4
B)Alkaline KMnO4
C)Neutral KMnO4
D)Both B and C
 295. Which of the following regent can oxidized iodide
to iodate?

A)Acidified KMnO4
B)Alkaline KMnO4
C)Neutral KMnO4 }
-D)Both B and C
300. Why permanganate titrations are not done with HCl?
'
ci -420

A)Hydrochloric acid is oxidized to chloric

B)Hydrochloric reduced to chloric
C)Hydrochloric acid is costly
D)None of the above
300. Why permanganate titrations are not done with HCl?

A)Hydrochloric acid is oxidized to chloric

B)Hydrochloric reduced to chloric
C)Hydrochloric acid is costly
D)None of the above