®

Chemistry : S-Block, Hydrogen & It's Compound

1. Which among the following hydrogen carbonate 8. On dissolving moderate amount of sodium metal
is not obtained in solid state :- in liquid NH3 at low temperature, which one of
the following does not occur
(1) Blue coloured solution is obtained
(1) NaHCO 3 (2) LiHCO3 (2) Na ions are formed in solution
(3) KHCO3 (4) None of the obove (3) Liquid NH3 becomes good conductor of
2. When sodium is dissolved in liq. NH3 the solution electricity
becomes blue due to presence of :- (4) Liquid NH3 remains diamagnetic
'Na' NH3 NH3
:-
(1) NH2– (1)
(2) NH4+ (2) Na
(3) Na+
(3) NH3
(4) Ammoniated electron
(4) NH3
3. Which of the following is least stable hydride :-
9. Alkali metals are powerful reducing agent
because :-
(1) CsH (2) NaH (3) LiH (4) KH
(1) They are metals
4. Photoelectric effect is maximum in :-
(2) They are monovalent
:-
(3) Their ionic radius are large
(1) Cs (2) Li (3) Na (4) K
(4) There IP are low
5. Li does not resemble with other alkali metals in
:-
following properties :
(1) Li2CO3 decomposes into oxides while other (1)
alkali metal carbonates are thermally stable (2)
(2) LiCl is predominantly covalent (3)
(3) Li3N is formed, when Li metal is heated with (4) IP
N2 gas 10. When Na and Li placed in dry air we get :-
(4) all are correct Na Li
Li : (1) NaOH, Na2O, Li2O
(1) Li2CO3 (2) Na2CO3, Na2O2, Li2O
(3) Na2O, Li3N, NH3
(2) LiCl (4) Na2O, Li2O, Li3N
(3) Li3N N2 11. Which element give dark red on flame test :-
:-
(4) (1) Sr (2) Li (3) Rb (4) Ca
6. The alkali metals which form normal oxide 12. When sodium is placed in moist air, finally change
peroxide as well as super oxides are :- into :-

:- :-
(1) Na, Li (2) K, Li (3) Li, Cs (4) K, Rb (1) NaOH (2) Na2O2 (3) Na2O (4)Na2CO3
7. Elements of group I give colour in Bunsen flame 13. Which one is correct :-
due to :-
(1) Low M. P. (2) Softness (1) MP Li < Na < K < Rb < Cs
(3) One valence electron(4) Low I. P. (2) BP Be > Mg > Ca > Sr > Br
I :- (3) density Li > K > Na > Rb > Cs
(1) (2) (4) density Ca < Mg < Be < Sr < Ba
(3) (4) I. P.
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Chemistry : S-Block, Hydrogen & It's Compound

14. The set of raw materials used in SOLVAY's 20. An orange solid (A) on heating gives a colourless
process are :- gas (y) and only a green residue (z), gas (y) on
SOLVAY's treatment with Mg produces a white solid
(1) NaCl, CaCO3, C, H2SO4 substance :-
(2) NaCl, CO2 (A) (y)
(3) NaOH, CO2 (z) , (y) Mg
(4) NaCl, NH3, CaCO3 :-
15. Hardest s-block metal is :- (1) Mg3N2 (2) MgO
s- :- (3) Mg2O3 (4) MgCl2
(1) Li (2) Na (3) Mg (4) Be 21. Which of the following reaction gives H2 gas :-
16. When MgCl2 . 6H2O is strongly heated, then it H2 :-
forms : (1) Zn + dil. H2SO4
MgCl2 . 6H2O : (2) Al + NaOH excess
(1) MgO (2) Mg(OH)2 (3) Zn + NaOH excess
(3) Mg(OH)Cl (4) MgCl2 (4) All of these
17. Identify the incorrect reaction involving Beryllium 22. Which is not obtained when metal carbides react
(Be) :- with H2O ?
Be :- H2O
(1) Be + H2 

 BeH2 ?
(1) Al4C3 + H2O  CHCH
(2) Be + Cl2 

 BeCl2 (2) CaC2 + H2O  CHCH
(3) Be + 2HCl 
 BeCl2 + H2 (3) Mg2C3 + H2O  CH3CCH
(4) Be + 2NaOH  (4) Be2C + H2O  CH4
 Na2BeO2 + H2
23. Gas (X) on passing into lime water, it becomes
18. KO2 is used in space and submarines because
milky, on passing it in excess then milkiness
it :-
disappears. Gas (X) will be :-
(1) Absorbs CO2 and increase O2 concentration
(X)
(2) Absorbs moisture
(3) Absorbs CO2
(X) :-
(4) Produces ozone
(1) CO2 (2) H2S
KO2
(3) NO2 (4) All of these
:-
24. Which compound have strong affinity towards
(1) CO2 O2
CO2 :-
CO2
(2)
(1) BeO (2) K2O
(3) CO2
(3) H3PO4 (4) P4O6
(4)
25. Which of the following is not hygroscopic–
19. Which of the following reaction does not take
–
place:-
(1) NaCl (2) MgCl2
:-
(3) CaCl2 (4) LiCl
(1) Na + H O 
2  Cold   26. Electrolysis of aqueous solution of NaCl gives :-
(2) Mg + H2O 
 Hot   NaCl :-
(1) Na and Cl2
(3) Be + H2O 
 Steam 
(2) Na, Cl2 and H2
(4) Li + H2O 
 Hot   (3) NaOH and Cl2
(4) NaOH, Cl2 and H2
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Chemistry : S-Block, Hydrogen & It's Compound

27. Which given order is not correct :- 32. Incorrect match is :-
(1) BeF2 < MgF2 < CaF2 Water solubility (1) Permuitit  Hydrated silicates of Na and Al
(2) BeSO4 < MgSO4 < CaSO4Water solubility (2) Calgon  Sodium Hexameta phsophate
(3) Li2CO3>Na2CO3>K2CO3Thermal stability (3) BeH2,MgH2  Covalent polymeric hydride
(4) All of these (4) Hydrolith  electron deficient hydride
:- :-
(1) BeF2 < MgF2 < CaF2 (1)  Na Al
(2) BeSO4 < MgSO4 < CaSO4 (2) 
(3) Li2CO3 > Na2CO3 > K2CO3 (3) BeH2.MgH2 
(4) (4)  e–
28. Which is correct :- 33. Which is an example of electron-rich hydrides ?
(1) H2O2 oxidize Mn2+ in acidic medium
(2) HOCl reduce H2O2 in acidic medium (1) NaH
(3) Rxn of KMnO 4 with H2O2 in both (H+ ) (2) BH3
medium & (OH–) medium give O2 (3) NH3
(4) All (4) CH4
:- 34. Which combination is used in rocket fuel ?
(1) H 2O 2, Mn 2+
(1) liquid H2 + liquid O2
(2) HOCl, H 2O 2 (2) H2 + O2
(3) H2O + H2
(3) (H+) (OH–) KMnO4, H2O2 O2 (4) liquid H2 + O2
35. H2O2 + N2H4 can be used as :-
(4) (1) Antiseptic
29. Hydrogen is evolved by the action of cold dil (2) Oxidant
HNO3 on :- (3) Reductant
HNO3 :- (4) Rocket propellent
(1) Fe (2) Cu (3) Al (4) Mn H2O2 + N2H4 :-
30. Hard water when passed through ion exchange resin (1)
containing RCOOH group, becomes free from (2)
RCOOH (3)
(4)
(1) Cl– (2) SO4–2 (3) H3O (4) Ca+2 36. Temporary hardness of water due to presence of
31. Which is not a method to prepare H2O2 :-
(1) Oxidation of 2-ethyl Anthraquinol (1) CaCl2, MgSO4
(2) H2S2O7 
 Complete (2) Ca+2, Mg+2
Hydrolysis

(3) K+, CaCO3
(3) BaO2 . 8H2O  H H2 O
 (4) Ca(HCO3)2, Mg(HCO3)2
(4) K2S2O8 
Complete
Hydrolysis
 37. Which of the following is Ionic hydride ?
H2O2 :-
(1) 2-ethyl Anthraquinol (1) BeH2
(2) MgH2
(2) H2S2O7 
(3) NaH

(3) BaO2 . 8H2O  (4) NH3
H H2 O

(4) K2S2O8 
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Chemistry : S-Block, Hydrogen & It's Compound

38. Identify true and false statements : 42. Which of the following is known as syn-gas ?
(a) The compound sodium hexa meta phosphate
Na2[Na4(PO3)6] is called calgon. (1) CO + N2 (2) CO + H2O
(b) The formula of sodium zeolite which is used (3) CO2 + H2 (4) CO + H2
in permutit process for softening water is 43. In acidic medium, H2O2 acts as a reducing agent
Na2O.Al2O3.2SiO2.XH2O. in its reaction with :-
(c) Temporary hardness of water due to presence H2 O 2
of Ca(HCO3)2, Mg(HCO3)2.
(d) Hardness can be removed by passing through (1) FeSO4 (2) KMnO4
ion exchange resin. (3) MnO (4) K4[Fe(CN)6]
: 44. Which is least thermally stable?
(a) Na2[Na4(PO3)6] ?
(1) Li2CO3 (2) Na2CO3
(b) Na2O.Al2O3.2SiO2.XH2O
(3) K2CO3 (4) Rb2CO3
45. Which of the following does not give brown
coloured gas NO2, on heating :-
(c) Ca(HCO3)2, Mg(HCO3)2
NO2

(d)
(1) KNO3 (2) Cu(NO3)2
(1) T T F F (2) T F T F
(3) AgNO3 (4) LiNO3
(3) T T T T (4) T T T F
46. Which of the following metal reacts most
39. H2O2 is always stored in black bottles because:-
vigorously with water :-
(1) Highly unstable
(2) Enthalpy of decomposition is high
(3) Undergo autoxidation on prolonged standing
(4) None of these (1) Be (2) Li (3) Na (4) Fe
H2O2 47. Which is liquid at room temperature :-
:-
(1) (1) Na (2) Fr (3) Os (4) Ce
(2) 48. Alum is the name used for all double salts having
(3) composition M I2 SO 4 .M 2II  SO 4  3 .24H 2 O .
(4)
Where MI tends to
40. Which of the following reaction represent the use
of water gas reaction ?
M I2 SO 4 .M 2II  SO 4  3 .24H 2 O . MI
?
(1) CH 4(g )  H 2O (g )   CO (g)  H 2(g)
1270K
Ni (1) Li+, Cu+, Ag+ (2) Li+, NH4+, Na+
(3) Na+, K+, Rb+ (4) Ca2+, Mg2+, Sr2+
(2) CO(g)  H 2O(g)   CO2(g)  H 2(g)
673K
catalyst 49. What is the correct order of size in aqueous
medium of following ions :-
(3) C n H 2n 2  nH 2O (g ) 
1270K
Ni
 nCO  (2n  1)H 2

(4) CO(g)  2H2(g) Co


Catalyst
CH3OH(l )
(1) Cs+(aq) < Rb+(aq) < K+(aq) < Na+(aq)
41. In clark method chemical used is
(2) Na+(aq) < K+(aq) < Rb+(aq) < Cs+(aq)
(3) Na+ = K+ = Rb+ < Cs+(aq)
(1) NaOH (2) Na2CO3
(4) None of these
(3) CaCO3 (4) Ca(OH)2
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Chemistry : S-Block, Hydrogen & It's Compound

50. The pair whose both species are used in antacid 56. When LiNO3 is heated, Products obtained are :
medicinal preparations is – LiNO3
(1) Li2O, NO2 (2) Li2O, NO2 + O2
– (3) LiNO2 + O2 (4) None of these
(1) NaHCO3 and Mg(OH)2 57. 'A' + H2O  NaOH ;
(2) Na2CO3 and Ca(HCO3)2
B 
H2 O
'A' 
O2
4000 C at 25 C
NaOH + O2
(3) Ca(HCO3)2 and Mg(OH)2
(4) Ca(OH)2 and NaHCO3 B is used for oxygenating in submarine. A and B
51. Which of the following is paramagnetic :- are :
:- B
(1) K 2 O (2) K2O2 (3) KO2 (4)Na2O A B
52. Compound having lowest melting point :- (1) Na2O2 and Na2O (2) Na2O and Na2O2
:- (3) Na2O2 and O2 (4) Na2O and O2
(1) LiCl (2) CsCl 58. Select the correct statement for alkali metal ions:-
(3) RbCl (4) KCl (1) Li+ show highest mobility in aqueous medium
53. Correct order of melting points & boiling point is:- (2) Cs+ show highest mobility in Molten phase
(M = Alkali metal) (3) Size of Li +(aq.) < Cs + (aq.) in aqueous
:- medium
(M = ) (4) Size of K+ > Na+ in gaseous phase
(1) MF > MBr > MI > MCl :-
(2) MF > MCl > MBr > Ml (1) Li+
(3) MI > MBr > MCI > MF
(4) MI > MBr > MF > MCl (2) Cs+
+
54. The stability order of oxide, peroxide and (3) Li (aq.) < Cs+ (aq.)
superoxide of alkaline metals is :- (4) K+ > Na+
(1) Normal oxide > Peroxide > Superoxide 59. Lithium chloride is highly soluble in :-
(2) Peroxide > Normal oxide > Superoxide :-
(3) Superoxide > Normal oxide > Peroxide (1) C6H6 (2) H2O
(4) None of these (3) D2O (4) All
60. The correct order of decreasing Thermal
stability:-
(1) > >
(2) > > (1) BeSO4 > MgSO4 > CaSO4 > SrSO4
(3) > > (2) SrSO4 > CaSO4 > MgSO4 > BeSO4
(4) (3) CaSO4 > SrSO4 > BeSO4 > MgSO4
55. Reaction given (4) MgSO4 > BeSO4 > CaSO4 > SrSO4
61. An element reacts with hydrogen to form a
Na2CO3 . 10H2O 
In open
 Na2CO3.H2O + 9H2O
air
compound A, which on treatement of water
The method is :- liberates hydrogen gas. The element can be :
(1) Efflorescence (2) Deliquescene (1) Chlorine (2) Selenium
(3) Dehydration (4) Hydration (3) Calcium (4) Nitrogen
A
Na2CO3 . 10H2O 
 Na2CO3.H2O + 9H2O A H2
:
:-
(1) (2)
(1) (2)
(3) (4)
(3) (4)
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Chemistry : S-Block, Hydrogen & It's Compound

62. Consider the following reaction sequence 66. Which one of the following is present as an
active ingredient in bleaching powder for
( )
bleaching action?
CaO + CO2 A B + CO2
H 2O ?
CO2
H2 O + D C (1) CaOCl2 (2) Ca(OCl)2
CO2 H2O (3) CaO2Cl (4) CaCl2
67. Which of the following compound on hydrolysis
E
give poisonous gas :-
Compounds D and E are respectively :-
D E (1) CCl4 (2) BiCl3 (3) SbCl3 (4) BCl3
(1) CaC2, CaO (2) Ca(HCO3)2, CaC2 68. Ionic hydrides reacts with water to give :-
(3) CaCO3, Ca(HCO3)2 (4) CaCO3, CaC2 (1) Acidic solution (2) Basic solution
63. Which one of the following pairs do not impart (3) Hydride ion (4) Proton
colour to flame :- :-
(1) (2)
:- (3) (4)
(1) BeCl2 & SrCl2 (2) CaCl2 & BaCl2 69. Which compound on electrolysis produces H2
(3) BeCl2 & MgCl2 (4) BaCl2 & SrCl2 gas at both electrode?
64. Correct option is :- (1)MgH2 (molten) (2)HCl (aq)
Compound Use (3) NaH(molten) (4) CaH2(aq)
(1) Gypsum rapid setting of cement H2
(2) K 2 O in submarines to purify air
(3) Zeolite catalyst & water softener (1)MgH2 (2)HCl
(3) NaH (4) CaH2
(4) All
70. D2O is preferred to H2O, as a moderator, in
:-
nuclear reactors because :-
Compound Use (1) D2O slows down fast neutrons better
(1) Gypsum Cement
(2) K 2 O (2) D2O has high specific heat
(3) Zeolite (3) D2O is cheaper
(4) None
(4) All D2O H2O
65. In during cement plasters water is sprinkled from :-
time to time. This helps in (1) D2O
(2) D2O
(1) Hydrating sand and gravel mixed with cement
(3) D2O
(2) Converting sand into sillicate
(4)
(3) Developing interlocking needle like crystals 71. Metallic hydrides are :-
of hydrated silicates (1) Also known as interstitial hydrides
(4) Keeping it cool (2) Are good conductor of electricity
, - (3) Have less density than their metals
:- (4) All are correct
(1) :-
(2) (1)
(3) (2)
(3)
(4) (4)
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Chemistry : S-Block, Hydrogen & It's Compound

72. Hydrogen gas is prepared by using C-coke 76. Which of the following reaction can give
and steam in presence of Fe 2O3/Cr 2O3 then hydrogen gas ?
process is known as :-
(1) Bosch process (2) Uyeno process (1) Zn + conc. H2SO4
(3) Lane process (4) None of these (2) Cu + dil. H2SO4
C-coke Fe2O3/Cr2O3 (3) Mn + HNO3 (1–2%)
:- (4) Pb + dil. HNO3
(1) (2) 77. Match the column.
(3) (4)
Column-I Column-II
73. Which of the following statement regarding
H2O2 is correct :- (i) Hydrogen (a) Used as air
peroxide purifier in
(1) It is prepared by electrolysis of dil.H2SO4
submarines
(2) The bleaching action of H2O2 is temporary
(ii) Calcium (b) Used for water
(3) It can be concentrated by boiling
sulphate softening
(4) the speed of decompositon of H2O2 can be hemihydrate
retarded by using urea.
(iii) Potassium (c) Antiseptic
H2O2 :- superoxide
(1) H2SO4
(iv) Calgon (d) Plaster of paris
(2) H2O2
(3)
(4) H2O2
Column-I Column-II

74. Which of the following statement is not correct :- (i) Hydrogen (a)
peroxide
(1) Hardness of water effects soap consumption.
(2) Temporary hardness is due to bicarbonates (ii) (b)
of Ca and Mg.
(3) Permanent hardness is due to soluble
(iii) (c)
sulphates, chlorides of Ca and Mg.
(4) Permanent hardness can be removed by
boiling watter. (iv) Calgon (d)
:-
(1) (i) (ii) (iii) (iv)
(2) Ca Mg (1) d c a b
(2) c d a b
(3) Ca Mg (3) c d b a
(4) d c b c
(4) 78. Which of the following incorrect ?
75. Which relation is incorrect ? (1) Ionic product D2O > H2O
(1) Molecular mass = H2O < D2O (2) Solubility of inorganic substances H2O >D2O
(2) Melting point = H2O < D2O (3) Mass D2O > H2O
(3) B.P. = H2O > D2O (4) Heat of fusion D2O > H2O
(4) Reactivily = H2O > D2O
(1) D2O > H2O
(1) = H2O < D2O
(2) H2O >D2O
(2) = H 2O < D 2 O
(3) D2 O > H 2 O
(3) = H2O > D2O
(4) D 2 O > H2 O
(4) = H 2 O > D2 O
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Chemistry : S-Block, Hydrogen & It's Compound

79. Which of the following is a true structure of 80. Very pure hydrogen (99.9%) can be made by
H 2O 2? which of the following processes ?
H2O2 (1) Reaction of metal hydrides with water
180° (2) Reaction of methane with steam
(1) (3) Mixing natural hydrocarbons of high molecular
H O O H weight
94° (4) Electrolysis of water
(2) H
O O (99.9%)
H ?
H (1)
(3) O O
H (2)
(3)
H
(4) O O (4)
H

Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. 2 4 1 1 4 4 4 4 4 4 1 4 4 4 4 1 1 1 3 1
Que. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
Ans. 4 1 1 2 1 4 4 3 4 4 2 4 3 1 4 4 3 3 3 4
Que. 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. 4 4 2 1 1 3 2 3 1 1 3 1 2 1 1 2 2 4 1 2
Que. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
Ans. 3 3 3 3 3 2 1 2 4 1 4 1 4 4 3 3 2 1 2 4