resreor 01212020] FORM TP 2021005 & JANUARY 2031 CARIBBEAN EF AMUNATIONS COUNCIL CARIBE, AN SECO} ARY EDUCATION CERTIFICAT EXAMINATION CHEMISTRY Paper 02 ~ General Proficiency 2 hours aut 39 mines READ THE FOLLOWING INSTRUCTIONS CAREFULLY. | Write your answers in the spaces provided in this booklet Do NOT write fathe margins S$. Where appropriate. ALL WORKING MUST BE SHOWN in this booklet, 6. Youmay wse asilem. non-qwogrammble calculator to answer questions 7. ryou need to rewrite any answer and there isnot enough space ta do 59 om the ceriginal page, you must use the exia fined pagels) provided atthe Ick of this booklet, Remember ta draw a line through your original answer. 8. Ifyou use the extra page(s) you MUST write the questlon mumber clearly in the box provided at the top of the eaten page(s) and, where relevant, include the question part beside the answer ,__ Ging DO NOT TURN THIS PAGE. UNTIL YOU ARE TOLD TO DO SO. ‘Copyright © 2019 Caribbean Examinations Council, All rights reserved. mNANAAAEAE al L_sirmovesees Scanned with CamScannerSECTION A Auewer ALL sjucatlons, TEIN THIS AREA 30 mlautes on Question 1. Da NOT spend mors ved via the method The evmtecitration oF a swlation OF soaiain hysrenid b wilt a sion acid, The following pricedune was used. 1 (uNAAIOWH EoneeMteation} inte a styrofoam etn, Transtar 28 ers of NaOIL sol 2, Take the initial temperature of the 5 20 Nor way Add S em" of 1,50, (0,10 M) from the burette into the cup. Immediately slir the mixture and its temperature. Procedure, alding $ em! aliquots of H,SO, umil a toial of 30 em of H.SO, ) is added. (o.10 3 Figure | shows the thermometer readings ofthe acid-base resetions after the additions of 5 cm, 3 18 cmPand25 cm’ of H.S0,. B 5 ES RE Nor ae a7 Volume 25 cm? Volume 1$ em! g ‘Volume Sem’ = 31 ts =) Figure 1, Thermometer readings for acid-base reaction | u iS 2 2 | ‘GO ON TO THE NEXT PAGE = 01212020/1/CSEC 202) AL NNNHAMEAAT Scanned with CamScannerr 4 o Using the thermometer readings in Figure 1, on age S. complete Table | by recording the femperatures for ihe adkilions of 5 em, 1S 25 em’ of H,80,. TARLE Ie EXPERIMENTAL RESULTS Volume of H,S0, Adited (em) | Temperature (C) ° 0 s 2TS Pp | a 0 305 8 334 20 325 3 204, 30 t 260 (3 marks) (by wo Using the axes provided in Figure 2, on page 7, plot the graph of temperature against volume of acid added. (4 marks) Gi) Wy two lings of Fest fit throwsh the paints on the graph. one whee the temperature inereasing and the ether where the temperature is deeressing, (2 marks) (ii) On your graph, show the end point of the faction. Record the corresponding volume beh, 8 1s ‘ End point ofthe reaction = em? (2 marks) « _ Distinguish between a “strong acid” and a “weak acid’, a Shy add" fi Liotiged wen déssead, iq water. v¢ (tedion. GO ON TO THE NEXT PAGE ARNON _l Scanned with CamScanner” —| Te : i Volume of 11,80, (em) Figure 2, Teriperature against volume of H,SO, GO ON TO THE NEXT PAGE | Scanned with CamScanner 012120204/CSEC 2021 L Fsr * 1 ANa dep NS 0p) ee NaS ba) + 4,00 marks) (©) Calculate the number of {F11,S0, va inthe reaction ) melts, eo ls Teo " (Q marks) (0) Cates the suber of mols of NAOH in 25 moths Moke Chio= Bd ee BB Ned apo {Naot = aK 9: 216 cote 0007S raves “@imarks) te) e the concentration of NaOH, in mol dy? 0.990 1S nekes, 0-UV7S mots, gis ee ss oa marks) GO ON TO THE NEXT PAGE or212020n/CSEC 2021 L ee =! Scanned with CamScannerTr ee 7 (hy Cateutate the concentration of NaOH, gain, given the matar mass of NAOH = 40 “Macs Conudlcaions tel ex Gatlahon x G7, 2 08 enlde "x #9 1:2. ade (i) State whether the reaetion that tonk place jn the styrofoam cup sas exothermic er end Blame he Tapas alo Wx last to te an ua G) State ONE sufety precaution which should have been taken during the experiment, Mae, Cubes | atex slows han, handling, ts nly Me vo (Hs) en oc + Week poste Ne tyewter . (mark) rh Ee Figen Ra Pa cay dha diy kas hak Hall a marks) Total 25 marks GOON TO THE NEXT PAGE 01212020/8/CSEC 2021 L ARRAAMERRAO | Scanned with CamScanner(8) Rand Sore i S ina rellective, eakourless sbi wits melting point of 382 (tine then Joby prepa 18s, (ii) (iv) Inthe space strong bonds an: cae ole fea ‘thet haw. al claw, sketch the siructure of R, using solid lines ¢ vibe 7 he exer as aky with a melting point 3425 *€ c slovoe Arar oe chute 4 (mark) Wel iid eps 4 ie hustical, “(@ marks) (mark) 0 show dotted lines («+ + © + +) to show weak bonds, 012120204/CSEC 2021 G marks) GO ON TO THE NEXT PAGE Scanned with CamScannerxn THIS AREA TEIN THIS ARE RITE TN NOT IR: ‘Donor Wi Do. TEIN THIS ARE DONOT WRITE MSAREA| 2 e e z cue 7 (9) Bypin why conducts elect bat S doesnot ced} is wv gad conductor becouse i Sly taben’ coded to Free, oats | deoad, lagec . ten tedcor (vm sady cache ated) bran, fe ateony sayalerdtt bond Mee Shee cies aa id, T. is white in colour with a meking point oF BOI °C, 1k conducts electricity Ww but notin the solid state ncbik ahatrons th) (i) eae the pe oF Boning edo doi, (1 mark) Gi) State ie appearayes that Solid is expected to have me ola’ (©) Solids, liquids and gases ure easily converted from one state tn another (Compare the arrangement of particles in solids with the arrangement of particles in tiquias, ¢ ———— Solid * aa by ace. chose Toyotas si a Wa atdecly fachio, ice (2 marks) (ii) When sotid iodine is heated. a pu which occurs and give ONE Site process Places: Suascenacon, Narusnasene.) Genme loured gas is observed. State the process Fonother compound! which undergoes the Total 1S marks GO ON TO THE NEXT PAGE L ie Scanned with CamScannera 1de | orm “structural i Se Iso, bat ipod eal ad a GI) Draw the fully displayed. ‘structure of 2-methylbutane, it ta 7 oe 7 c—c—H H 1 ! City HoH a met hudtone. ee (iti) Draw and namie ONE other structural isomer of CH, CHs | aq #-C—c_eiy H ? marke) GOON TO THE NEXT PAGE Ol212020VCSEC 2021 L =] Scanned with CamScanner[~ os. rent functional groups can be formed (i) What is the functional ne bfethanol, CL CHOW? Gi) Table 2 summarizes the conditions and produc le 2 by inserting the react displayed strueite of the products which would b {ype of product to be formed is given inthe table, TABLE 2: REACTIONS OF ETHANOL Reagent | con ms Product Structure 5 - Depending on the reagents and conditions of the “(i mark) of Wo reactions of ethanol ions and drawing the fully formed, Take note that the Msg i. Alene te celal. |, fe c. sh ~ ies c= i ae (2 marks) CH,COOH (2 marks) Soatin, CHa, fe \ EMal Ethovonle (2 marks) Total 15 marks GO ON TO THE NEXT PAGE 01212020//CSEC 2021 Scanned with CamScanneroe 7 SECTION B AnsmerALL questions, 4G) Atoms are the sinatiest particles of elements: however, they are made tp of three distinc substomic partictes (Complete Table 3 which shows the three subatomic parisles and their propentes TABLE 3: SUBATOMIC PARTICLES AND THEIR PROPERTIES Particle Mass | Charge 1 1Q40. | PRoENS 1 | + (4 marks) (Consider the notation of an torn of an unknown element 2A. Draw a labelled Sigsram to illuarate the fsation. arrangement and num a eae, tyre of ‘Subatomic particle in Element “A, 12020/CSEC 2021 Scanned with CamScannerr is 4 (0) Calelate the numberof ators in #0. gor esky [Relative atomic mins of Ca = 40) Avegadte’s constant 6.0-* 10") Ap *. G2 G-0x ang Vico et marks) The following observations were made by some students in a Home Economics elass Observation |: Cucumber slices release water when salt is added to them Observation 2; Peas swell when soaked in water, (i) Explain the chemical process that cam account far these ebservations. te waher onudl ealiov inti Cros de gate thay the. G boom sulk gular ang i) ae o ehtipe reek wher es. mv soaked in lo sitips Shdaky mark) ‘Total 15 marks GO ON TO THE NEXT PAGE | Scanned with CamScanner 1 212020,/CSEC 2021 Lr " 1 ALM Cand D: stil oon bh i aeoy " v0 PH et ap (Compound Ad (Compound C> (Compound Dy a co,+H,0 Figure3, Reaction scheme umber 162, La Renton [Sabet . weation Hadi ST eaten A iw | oiatros On - faditiow Viren oy mer Reaction 3 Reaction 4. GO ON TO THE NEXT PAGE _l Lane “ Scanned with CamScannerCT m | » Compound 18 sin Reaction U Su iitae ge genre: ek ReAeraan conderans: tiled ce Iso°c. Gms) Gi) Compound Ato Conmpound € vin Reaction 2 EAGENT: Booune Wee Te hl onthe Crone Select). . a ibn conto-re-nonks » fown cere Tite, ABSENCE OF at8¥ Geary (©) Given that R isan cthyt wroup, state the molecular formu! Compound A, Cyt. yi (Vomark) (ii) Hence, write a balanced chemical equatis Cale (9.260, (9): action 3, 0) +44, 019) (marks) ‘ompound B ‘Total 1S marks GO ON TO THE NEXT PAGE 01212020//CSEC 2021 Scanned with CamScannerr “ q 6 Some student inated the action of dilute hydrochtorie acid using a sample of solid sodiur hydrogen carbon ©) Oworihes ges that the rencion would yield a gaseous proce Devgrite a est ha owl he us vo kemiy te parcours tome Ten: as will heen fine ete C ubbled diico COs. Coch Dude” “(a marks) GD Asample the gos was collected in the Inharatocy by downward delivery. State the physiegt Property of the gas which supports this method of collection ats ig mace dence, tha (1 mark) ii) Write @ chemi Hf equation. including state symbols, for the reaction berween sodium hydrogen eather (marks) (0) Soe metals reat with dilate cid o produce a sltand a gaseous Product. Weite sn fone Equation forthe reaction of magnesium with dilute Toyoch lorie acid, HD) a) + at ep me re (2 marks) GOONTOTHE : 01212020./CSEC 202) NEXT PAGE L re Scanned with CamScannerSome no sulfite etter nile presence whale, Expt nat this Whunavae an dametiun, § at cencle afi aw galt , walecend amavaitey a, Erbin erassi rita fired q gee Nis, ri as f auld se hat tse doe ) ah ares rm phaete deslblt end. pede Gi) Phosphorus and silicon are two other use ul non-metals. List TWO uses of sificon and ONE use of phosphorus. ee sn conduttecs Teonsittocs. nclaly are important to the agricultural industry. Nite si marke iii) Swtfur is non-metal that hums in aicta produce a gas product that dissol¥es in ‘water 10 give a colourless solution. Identify the yas formed and! state the effet that he solution would have on blue litmus paper. CON MUTT BME defmaus: Tula sr RED. ‘@marks) ‘Total 15 marks END OF TEST IF YOU FINISH BEFORE TIME 1S CALLED, CHECK YOUR WORK ON THIS TEST. (01212020//CSEC 2021 | Scanned with CamScanner