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    16 views12 pages

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    Ngọc Đào

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    NGi dung CATtech-5 ee 1. Gidi thigu 2. Thiét bi phan ting tang cé dinh bi phan Ung tang si Thiét bi phan tng xtc tac Catalytic reactors 1. Gidi thigu 2, Thiét bj phan ng xuc tac tang 6 dinh ‘Thiét bj phan tng: Catalytic fixed-bed/packed-bed reactor ~ Gin doan (batch reactor) ~ Ban lign tue ( semi-bateh reactor) eae ie = Lign tue QJ + CSTR (Continuous Stirred Tank Resetor): Tht bj th dang Kimiy oa + PER (Plug Flow Reactor): Tht bi dang dng 2. Thiét bi phan tng xuc tac tang c6 dinh La thiét bj don cid, phé bién nt Dong vu chét (chi, King) thd qua tng xéc tac 6 inh Xo te xp torg tang nay c6 thé la ty y (randomly) hay co tatty ¥ Hinh dang hat: edu tr, wong, Rich thuée: 2-10 mm 86 gdm thn thét dp sudt (pressure drop) > sti dng wie tac 6 cfu tric: vi ds monolith Lang eveng qua tin trao a8 nig: day a vén a8 quan trong ac bist 461 voi cac phn ng tba nhist hay thu nhiet Ion (IaHP>0) ova. 5 plo acta stove Figure 18. The empratre edna psked bed resco oramenater- teraction crests rail movement o eat and matter Xtic tac sdp xép ty do (random packing) 2. Thiét bi phan tng xuc tac tang c6 dinh ‘Hinh dang cia chat xic tic Dang sép xép tydo (random packing) Dong lau chatthuting & ché d9 chay réixoay (turbulance) Qua tinh tryén knbi ben ngoai pore S66, ruybn khbi ‘rong pore s@ ls qua tinh trayén khél king che. 26 din mht cba chdt xtc ta thueng cao hon kh > luw {profile vé nhist 4 git bé mat chat xis tac (noi din ra pha ting) va ddng ki (not do nhigt dB). ‘Thié: bj doan nhigt (adiabatic) | 2. Thiét bi phan ting xuc tac tng cé dinn oy, 2. Thiét bi phan ting xuc tac tng cé dinn oy, ‘Hinh dang cia chat xdc tic ‘Hinh dang cia chat xic tic Xic tc sdp xép trét tyr (Monolith) Dang monolith: Thuong ding trong xii tc xu ly méi zs trvdng: lt lugng dong lon, > tén that dp i suét nho . Y Sy truyén nhiét va truyén khéi bén ngoai la khéng ché. BREE. ¥ Dang khi thuong 6 ché d6 chay mang SSE (laminar flow) MOE, orm 2 orm » 2. Thiét bi phan ting xuc tac tng cé dinn oy, 2. Thiét bi phan ting xuc tac tng cé dinn oy, ‘Thié: bj doan nhigt (adiabatic) Inhgp gu tung ian Tao d6inhigt tang gian Dang da tang 2. Thiét bi phan tng xuc tac tang c6 dinh ‘Thié: bi doan nhiét (adiabatic) i = = es Ga AA Fire 13 Ste showing ow stp ake ts cacy spc te api emg te open vm. “ Figure 194 Optimum two-stage packed bed rectr, ova. 2. Thiét bi phan ting xuc tac tng cé dinn oy, ‘Thié: bi doan nhiét (adiabatic) Thi bf dopn aigt da ting: 4 Trye bp haa aan bp cp hay thost nit tu thi phn tng dé dam bdo cde nhigt 46 i uu trong ving xictéc ¥ Cac kh nongann auge dua vao 0 cae vit gla cac tng mic ta 46 did chinh nhigt 46 ¥ Dong ide endt cing 0 thé due cura cp 6 gira cae {Ung a8 dtu chinh néng a nha det higu sud i da ¥ Db vbi cc phan ing t6a nit, nhit 4 tng am cho 4 chuyénhéa cn bing gidm,nhurg lam cho t6c 5 phan ung ting len, 2. Thiét bi phan tng xuc tac tang c6 dinh ‘Thié: bi doan nhiét (adiabatic) {Gu aide eno} dopn nh aa cdg: Thiét bj dug ‘ach thanh céc bd phén, twuén Igi trong van chuyén va lapdat Xie téc c@c phan 06 yéu cu tai sinhithay thé khac nhau_ C6 thé b6 sung cc tac chat dé day nhanh téc 6 phan ng Cac tng tung gin cb thé tham gia qua inh tach sn pham 8 tang 4 chuyén hoa 7 Néu phan dmg yéu cu nhiét do >300°C, sy lam ngudi trung gian 6 hé thyc hign nho nude sbi, vi thiét bi 1 ting pha dng ede chat lm anh coolen). 2. . Thit bi phan tang xuc tac tang c6 dinh ‘Thié: bi doan nhiét (adiabatic) Ung dung: CCho cc phan ng ob higu dng nhist ahi Cae qué trinh lam sach kni (gas purification): mot ham ltagng nhc kh vi dy NO,) chuyén hea Vi dy: bung 2 Ij NO, trong nha my: 1000 m? xe te trong dng eo xe (1 lit ic tac) Qua trinh mettane héa cée Khi CO, CO, trong téng hop. NH {qua trinn nycrogenation cac phan nyarccacbon knong no ‘rong dong hycrocarbon “Thi bi tong hop NH,, CH.OH 2. Thiét bi phan tng xuc tac tang cé dinh ova. 2. Thiét bi phan tng xuc tac tang cé dinn oy) ym a 2. Thiét bi phan ting xuc tac tng cé dinn oy, Thiét bj phan ing tang ¢é dinh dang chim éng (mutitubutar fixed-bed reactor) ym 2 2. Thiét bi phan ting xuc tac tng cé dinn oy, Thiét bj phan wng tang cé dinh deng chim éng (muttitubular fixed-bed reactor) ‘Muc ninh chinh: cp va tan nhiét cia phan ting cang gan vi tri phan tng cang tot Phan tng toa nhigt: Nhi6t phan tng age iy a bing céc thiétbj trao 46i nhigt Phan tg thu nhiét: Nhiét phan ang duoc cung cp bing cAc thidt bj trao d6i nhiét Con goi la thiét bi "isothermal reactor’ (thiét bi phan Ung dng nhiét) 2. Thiét bi phan ting xuc tac tng cé dinn oy, ‘Thiét bj phan ing tang ¢é dinh deng chim éng (mult-turbular fived-bed reactor) Kich thue céc ng: ID = 20-80 mm ;L=0.5~15m Vo! cae phan tmng t6a nhlgt mann, vi ay: phan tng oxy hhéa-> qua trinh sé chi 66 thé xay ra tong thiét bi xtc tac tdng 6 inh néu nhigt d6 06 thé cuge Khéng ché trong mét khoang hep. ym a 2. Thiét bi phan ting xuc tac tng cé dinn oy, ‘Thiét bj phan ing tang ¢é dinh deng chim éng (mult-turbular fived-bed reactor) cae yéu od Dien tichbé mat ruyén nhgt loth tic cht ni ae (6ng nhé > hat xe tac nho > t6n tht ép subt én) Nita cia i cht uy mht pha gn nhigt yu cu ebiachdt wie tac Tbe 40 dong tc chat thug pha ton a8 dm bdo qua Win trayén nh ben tong dng xe te. ym a 2. Thiét bi phan ting xuc tac tng cé dinn oy, Thiét bj phan wng tang cé dinh deng chim éng (muititubular fixed-bed reactor) Bidu kién ly tréng: “wall-coated” catalytic reactor xc téc duge quet len bé mat trong oila cac éng. no khan khi ap dung: ky thuat phui bé mat + viée thay thé xic tac trong quy m6 lon. ym a 2. Thiét bi phan ting xuc tac tng cé dinn oy, Thiét bj phan dng tang cé dinh deng chim éng (multi-turbular fixed-bed reactor) Moi chat truyén nhigt (Heat transfer media) Moi chét ruyén ntigt dang bc hot: Vaporizng heat transfer media > trong céc phn (ng tba nhit anh ‘Su dung nude s6ica0 ap (pressurized boilng water): Nuée kndng chay, c6 nbigt héa hoi cao, hoi nudecb thé duge dang trong cc quy trinh kha. Tay thude vao ap sudt hoi bao héa, nhiet 49 trong khoang 100 (atm) -310° (100bar) ym a 2. Thiét bi phan ting xuc tac tng cé dinn oy, ‘Thiét bj phan ing tang ¢é dinh deng chim éng (mulicturbular fived-bed reactor) ym ES 2. Thiét bi phan ting xuc tac tng cé dinn oy, Thiét bj phan dng tang cé dinh deng chim éng (multi-turbular fixed-bed reactor) Moi chat truyén nhigt (Heat transfer media) ‘D6 trénh hién twong cavitation (xém thye): ¥ HO sir dung dén 220°C; ¥ 3 3000! chu > 300°C: »8n gp mud néng chay 1 cas mugs nate (200-500°C) 16 mu carbonat(400-000°C) Vin a8: corrosion 2. Thiét bi phan ting xuc tac tng cé dinn oy, ‘Thiét bj phan ieng tang ¢é dinh deng chim éng (muli-turbular fived-bed reactor) M@i chat truyén nhigt (Heat transfer media) Khuyét diém cua truyén nhiét bang khi: + Khéi lvgng riéng thap + D6 dan nhiét thap: 2. Thiét bi phan ting xuc tac tng cé dinn oy, ‘Thiét bj phan ing nghich dong (Revorse-flow reacton 2. Thiét bi phan ting xuc tac tng cé dinn oy, ‘Thiét bj phan ing nghich dong (Revorse-flow reacton ¥ Diém thuan trao déi nhiét V kong cain cp nhiét (autothormal) abu thiét ké thiét bi phan ing phi hop. ¥ Ung dung dug trong phan tng oxy héa, chay. (Chi cdn chénh lech nhigt 46 doan ahigt Knoang 10K [a c0 thé ap dung cho cae quaitrinn phan ung téa nhiét & dibu kién 500°C) don gin nhung higu qua trong 2. Thiét bi phan tng xuc tac tang c6 dinh ‘Thiét bj phan ing nghich dong (Revorse-flow reacton ova. 2 2. Thiét bi phan tng xuc tac tang c6 dinh ‘Thiét bj phan ing nghich dong (Revorse-flow reacton ova. x 2. Thiét bi phan ting xuc tac tng cé dinn oy, ‘Thiét bj phan ing nghich dong (Revorse-flow reacton 2. Thiét bi phan ting xuc tac tng cé dinn oy, ‘Thiét bj phan ing nghich dong (Revorse-flow reacton Bat Igi: van hanh © ché d6 khéng én dinh, va cn phai van chinh cdc dong khi lon theo chu ky. ova. a 3. Thiét bi phan Ung xtc tac tang soi & 3. Thiét bi phan Ung xic tac ting soi a7 Sh o o o FigA. Indutia gas distributors (a) Perforated plate; moze plate: bubblecsp plate & 3. Thiét bi phan Ung xic tac ting soi Cracking xic tac (ECC) > 88 gay cdc hytocabon mach 2 Pn ung th oi 2 'Sytgotnann coke im cho chat xe te bi mdt host to it han > uc tac dupe tl sh dng ech dt coke Dang hrbng KN wang mot nt ting 6 > aga cone ye dong a ew oe og 2 Nn 0 tgs tie i sit 850-7500 5 Nnta6 db phan ung chin = 480-540°C 2 Theos dong 01 ~ 076 mls 3. Thiét bi phan Ung xtc tac tang soi Cracking xic tac 3. Thiét bi phan Ung xtc tac tang soi ‘Téng hgp acrylonitrile Thufin loi: 3. Thiét bi phan Ung xtc tac tang soi > Chuyén ven d8 dang vi cac hat suc tac 6 trang thai t8ng si thé hign gidng nh la chat long » Phan bé rhigt déng nhdt > Dign tich t6p xiic Khi-Rén lon do cdc hat xtc tac trong TB tng s6i thuéng c6 kich thuéc nhs > Qua trinh ruyén nhigt hig qua Bat ot: 4 3. Thiét bi phan Ung xtc tac tang soi > Tham chi phi tach phan rn ra hhdi 98m phim kn » Thdi gian lu cita cdc tac chat thong dbng éu do sy tao thanh cdc bong bing > Sy mai mén bé mat trong cia thiét bj do chat ran chuyén déng voi téc d6 cao. 2» C6 kha nang bi mat trang thal ting ‘s6i(defiuidized) khi cac hat xéc tic két lai tao thanh het bn » Kho khain trong vige chuyén quimd (scale-up) 3. Thiét bi phan Ung xtc tac tang soi 3. Thiét bi phan Ung xac tac ting soi gf (Ghractace ice bedvencior [Pd bed vncor [Spa eng onan tivo - cote ang oT ETT tarts | Finale venta Pion nd amcor ‘pimang ce |e te mang tah |r noat in nae ee cenit nen teem apace eraser (lerhestee0 Bane [rae SET, ao | Tao HATA Se ws hotineng nang akg vn ann nn yen mth ks ‘Ceding kl nage bite ar ah |- dong chy c@ Kh (Plug | (backmixing) co thé din ee Fwy simone obec nn no TRE RSCFat a a RTS In) db abu rt og (002-6 mm) od ‘Sy phan BO nhiét [Sy tao tanh cae dm — |= NRBt a6 phan bd tong nee = Ierscwtre my [eran era tr [oergconatms [eer ménorgion |hém trong phan Ging téa_ |6i, ob thé c6 cic thiét bi dd te rao 8h nt ben ong ving soi rma. s rma. o Tinh toan khdi lveng xuc tac y Bai toan “Thi bi phn ig nic tc ting edn (fined reactor cho phn tig pha ki ti nh (2 bar, 300°C), nhip iu A 100%, vi ming suit 10 tn sn phimvngiy, xem ei ki li kh 1 twémg ton 9 xe tie 6 hog inh nur nha Vinh Khong tay A oP M8 80 (pinot Pr vie io, (hom i'kg"') E20 kmot bor Ke lotr! Keaober! Kapa Pe Xtc dinh lung chét xic tic thu

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