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Case Name: ESTIRENO 1º ENTREGA 28-JUN.HSC

2 LEGENDS
3 Burlington, MA Unit Set: SI
4 USA
Date/Time: Mon Jun 28 11:00:04 2010
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Workbook: Case (Main)
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Material Streams Fluid Pkg: All

11 Name 109 108 106 107 117

12 Vapour Fraction 1.0000 0.0000 1.0000 1.0000 0.0000
13 Temperature (C) 538.3 538.3 324.2 * 1000 * 50.02 *
14 Pressure (kPa) 50.66 * 50.66 85.72 * 300.0 47.40 *
15 Molar Flow (kgmole/h) 1359 0.0000 * 133.1 * 1112 * 1112 *
16 Mass Flow (kg/h) 3.414e+004 0.0000 * 1.411e+004 2.002e+004 2.002e+004
17 Liquid Volume Flow (m3/h) 38.82 0.0000 16.22 20.06 20.06
18 Heat Flow (kJ/h) -2.153e+008 0.0000 1.149e+007 -2.268e+008 -3.160e+008
19 Name 118 111 203 205 201
20 Vapour Fraction 0.0000 1.0000 1.0000 0.0000 0.0000
21 Temperature (C) 50.05 163.9 50.00 50.00 50.00
22 Pressure (kPa) 350.0 * 30.66 147.4 147.4 147.4
23 Molar Flow (kgmole/h) 1112 1659 129.5 129.4 1401
24 Mass Flow (kg/h) 2.002e+004 3.954e+004 939.0 1.337e+004 2.523e+004
25 Liquid Volume Flow (m3/h) 20.06 44.24 4.146 14.81 25.28
26 Heat Flow (kJ/h) -3.160e+008 -3.141e+008 -2.120e+006 1.212e+007 -3.981e+008
27 Name 200 110 115 105 113
28 Vapour Fraction 0.0780 1.0000 0.0000 1.0000 * 0.0000 *
29 Temperature (C) 50.00 * 376.3 20.01 324.2 19.99 *
30 Pressure (kPa) 147.4 30.66 30.66 85.70 101.3 *
31 Molar Flow (kgmole/h) 1659 1359 300.0 133.1 300.0 *
32 Mass Flow (kg/h) 3.954e+004 3.414e+004 5405 1.411e+004 5405
33 Liquid Volume Flow (m3/h) 44.24 38.82 5.415 16.22 5.415
34 Heat Flow (kJ/h) -3.881e+008 -2.281e+008 -8.598e+007 1.149e+007 -8.598e+007
35 Name 112 209 116 212 214
36 Vapour Fraction 1.0000 0.0000 0.0000 0.0000 0.0000
37 Temperature (C) 373.6 50.02 50.02 135.2 55.01
38 Pressure (kPa) 182.4 * 47.40 47.40 80.00 43.00
39 Molar Flow (kgmole/h) 1659 289.0 * 1112 118.6 10.46
40 Mass Flow (kg/h) 3.954e+004 5206 2.002e+004 1.235e+004 1002
41 Liquid Volume Flow (m3/h) 44.24 5.217 20.06 13.66 1.128
42 Heat Flow (kJ/h) -2.972e+008 -8.216e+007 -3.160e+008 1.350e+007 5.943e+005
43 Name 224 220 102 103 213
44 Vapour Fraction 0.0000 0.0000 0.0000 0.0000 1.0000
45 Temperature (C) 101.3 129.5 20.00 * 28.65 55.01
46 Pressure (kPa) 40.00 65.00 100.7 100.7 43.00
47 Molar Flow (kgmole/h) 13.15 105.4 120.0 * 133.1 0.4162
48 Mass Flow (kg/h) 1375 1.098e+004 1.274e+004 1.411e+004 17.57
49 Liquid Volume Flow (m3/h) 1.575 12.08 14.64 16.22 2.333e-002
50 Heat Flow (kJ/h) 1.885e+005 1.309e+007 -1.441e+006 -1.252e+006 -2.080e+004
51 Name 221 100 217 219 218
52 Vapour Fraction 0.0000 0.0000 0.0000 0.0000 0.0000
53 Temperature (C) 20.00 * 19.90 135.3 120.0 120.0 *
54 Pressure (kPa) 14.34 101.3 * 255.0 105.0 205.0 *
55 Molar Flow (kgmole/h) 105.4 120.0 118.6 118.6 118.6
56 Mass Flow (kg/h) 1.098e+004 1.274e+004 1.235e+004 1.235e+004 1.235e+004
57 Liquid Volume Flow (m3/h) 12.08 14.64 13.66 13.66 13.66
58 Heat Flow (kJ/h) 1.095e+007 -1.443e+006 1.350e+007 1.313e+007 1.313e+007
59 Name 222 223 225 101 202
60 Vapour Fraction 0.0000 0.0000 0.0000 0.0000 0.0000
61 Temperature (C) 20.06 20.12 101.4 19.94 50.02
62 Pressure (kPa) 201.3 101.3 200.7 200.7 47.40
63 Molar Flow (kgmole/h) 105.4 105.4 13.15 120.0 1401
64 Mass Flow (kg/h) 1.098e+004 1.098e+004 1375 1.274e+004 2.523e+004
65 Liquid Volume Flow (m3/h) 12.08 12.08 1.575 14.64 25.28
66 Heat Flow (kJ/h) 1.095e+007 1.095e+007 1.889e+005 -1.441e+006 -3.981e+008
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69 Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 1 of 5
Licensed to: LEGENDS * Specified by user.
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Case Name: ESTIRENO 1º ENTREGA 28-JUN.HSC
2 LEGENDS
3 Burlington, MA Unit Set: SI
4 USA
Date/Time: Mon Jun 28 11:00:04 2010
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Workbook: Case (Main) (continued)
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Material Streams (continued) Fluid Pkg: All

11 Name 210 211 204 215 216

12 Vapour Fraction 0.0000 0.0000 1.0000 0.0000 0.0000
13 Temperature (C) 50.04 50.06 49.93 55.08 55.13
14 Pressure (kPa) 201.3 101.3 97.40 204.3 101.3 *
15 Molar Flow (kgmole/h) 289.0 289.0 129.5 10.46 10.46
16 Mass Flow (kg/h) 5206 5206 939.0 1002 1002
17 Liquid Volume Flow (m3/h) 5.217 5.217 4.146 1.128 1.128
18 Heat Flow (kJ/h) -8.215e+007 -8.215e+007 -2.120e+006 5.946e+005 5.946e+005
19 Name 213B 206 207 208 227
20 Vapour Fraction 1.0000 0.0000 0.0000 0.0000 0.0000
21 Temperature (C) 106.4 50.05 50.10 85.11 * 101.4
22 Pressure (kPa) 101.3 * 282.4 182.4 152.4 100.7
23 Molar Flow (kgmole/h) 0.4162 129.4 129.4 129.4 13.15
24 Mass Flow (kg/h) 17.57 1.337e+004 1.337e+004 1.337e+004 1375
25 Liquid Volume Flow (m3/h) 2.333e-002 14.81 14.81 14.81 1.575
26 Heat Flow (kJ/h) -1.943e+004 1.212e+007 1.212e+007 1.294e+007 1.889e+005
27 Name 114
28 Vapour Fraction 0.0000
29 Temperature (C) 19.99
30 Pressure (kPa) 130.7
31 Molar Flow (kgmole/h) 300.0
32 Mass Flow (kg/h) 5405
33 Liquid Volume Flow (m3/h) 5.415
34 Heat Flow (kJ/h) -8.598e+007
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Compositions Fluid Pkg: All

37 Name 109 108 106 107 117

38 Comp Mole Frac (E-Benzene) 0.0096 0.0096 0.9823 * 0.0000 * 0.0000 *
39 Comp Mole Frac (Styrene) 0.0830 0.0830 0.0075 * 0.0000 * 0.0000 *
40 Comp Mole Frac (Toluene) 0.0032 0.0032 0.0102 * 0.0000 * 0.0000 *
41 Comp Mole Frac (Benzene) 0.0022 0.0022 0.0000 * 0.0000 * 0.0000 *
42 Comp Mole Frac (Ethylene) 0.0022 0.0022 0.0000 * 0.0000 * 0.0000 *
43 Comp Mole Frac (Hydrogen) 0.0801 0.0801 0.0000 * 0.0000 * 0.0000 *
44 Comp Mole Frac (H2O) 0.8176 0.8176 0.0000 * 1.0000 * 1.0000 *
45 Comp Mole Frac (Methane) 0.0022 0.0022 0.0000 * 0.0000 * 0.0000 *
46 Comp Mole Frac (EGly-DiAceta) *** *** *** *** ***
47 Name 118 111 203 205 201
48 Comp Mole Frac (E-Benzene) 0.0000 0.0079 0.0034 0.0977 0.0000
49 Comp Mole Frac (Styrene) 0.0000 0.0680 0.0201 0.8515 0.0000
50 Comp Mole Frac (Toluene) 0.0000 0.0026 0.0027 0.0306 0.0000
51 Comp Mole Frac (Benzene) 0.0000 0.0018 0.0046 0.0181 0.0000
52 Comp Mole Frac (Ethylene) 0.0000 0.0018 0.0224 0.0004 0.0000
53 Comp Mole Frac (Hydrogen) 0.0000 0.0656 0.8405 0.0005 0.0000
54 Comp Mole Frac (H2O) 1.0000 0.8506 0.0837 0.0012 1.0000
55 Comp Mole Frac (Methane) 0.0000 0.0018 0.0227 0.0001 0.0000
56 Comp Mole Frac (EGly-DiAceta) *** *** *** *** ***
57 Name 200 110 115 105 113
58 Comp Mole Frac (E-Benzene) 0.0079 0.0096 0.0000 0.9823 0.0000 *
59 Comp Mole Frac (Styrene) 0.0680 0.0830 0.0000 0.0075 0.0000 *
60 Comp Mole Frac (Toluene) 0.0026 0.0032 0.0000 0.0102 0.0000 *
61 Comp Mole Frac (Benzene) 0.0018 0.0022 0.0000 0.0000 0.0000 *
62 Comp Mole Frac (Ethylene) 0.0018 0.0022 0.0000 0.0000 0.0000 *
63 Comp Mole Frac (Hydrogen) 0.0656 0.0801 0.0000 0.0000 0.0000 *
64 Comp Mole Frac (H2O) 0.8506 0.8176 1.0000 0.0000 1.0000 *
65 Comp Mole Frac (Methane) 0.0018 0.0022 0.0000 0.0000 0.0000 *
66 Comp Mole Frac (EGly-DiAceta) *** *** *** *** ***
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69 Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 2 of 5
Licensed to: LEGENDS * Specified by user.
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Case Name: ESTIRENO 1º ENTREGA 28-JUN.HSC
2 LEGENDS
3 Burlington, MA Unit Set: SI
4 USA
Date/Time: Mon Jun 28 11:00:04 2010
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Workbook: Case (Main) (continued)
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Compositions (continued) Fluid Pkg: All

11 Name 112 209 116 212 214

12 Comp Mole Frac (E-Benzene) 0.0079 0.0000 0.0000 0.0928 0.1555
13 Comp Mole Frac (Styrene) 0.0680 0.0000 0.0000 0.8958 0.3823
14 Comp Mole Frac (Toluene) 0.0026 0.0000 0.0000 0.0114 0.2453
15 Comp Mole Frac (Benzene) 0.0018 0.0000 0.0000 0.0000 0.2150
16 Comp Mole Frac (Ethylene) 0.0018 0.0000 0.0000 0.0000 0.0004
17 Comp Mole Frac (Hydrogen) 0.0656 0.0000 0.0000 0.0000 0.0000
18 Comp Mole Frac (H2O) 0.8506 1.0000 1.0000 0.0000 0.0014
19 Comp Mole Frac (Methane) 0.0018 0.0000 0.0000 0.0000 0.0000
20 Comp Mole Frac (EGly-DiAceta) *** *** *** *** ***
21 Name 224 220 102 103 213
22 Comp Mole Frac (E-Benzene) 0.8210 0.0020 1.0000 * 0.9823 0.0232
23 Comp Mole Frac (Styrene) 0.0761 0.9980 0.0000 * 0.0075 0.0392
24 Comp Mole Frac (Toluene) 0.1029 0.0000 0.0000 * 0.0102 0.0905
25 Comp Mole Frac (Benzene) 0.0000 0.0000 0.0000 * 0.0000 0.2243
26 Comp Mole Frac (Ethylene) 0.0000 0.0000 0.0000 * 0.0000 0.0990
27 Comp Mole Frac (Hydrogen) 0.0000 0.0000 0.0000 * 0.0000 0.1465
28 Comp Mole Frac (H2O) 0.0000 0.0000 0.0000 * 0.0000 0.3488
29 Comp Mole Frac (Methane) 0.0000 0.0000 0.0000 * 0.0000 0.0286
30 Comp Mole Frac (EGly-DiAceta) *** *** *** *** ***
31 Name 221 100 217 219 218
32 Comp Mole Frac (E-Benzene) 0.0020 1.0000 0.0928 0.0928 0.0928
33 Comp Mole Frac (Styrene) 0.9980 0.0000 0.8958 0.8958 0.8958
34 Comp Mole Frac (Toluene) 0.0000 0.0000 0.0114 0.0114 0.0114
35 Comp Mole Frac (Benzene) 0.0000 0.0000 0.0000 0.0000 0.0000
36 Comp Mole Frac (Ethylene) 0.0000 0.0000 0.0000 0.0000 0.0000
37 Comp Mole Frac (Hydrogen) 0.0000 0.0000 0.0000 0.0000 0.0000
38 Comp Mole Frac (H2O) 0.0000 0.0000 0.0000 0.0000 0.0000
39 Comp Mole Frac (Methane) 0.0000 0.0000 0.0000 0.0000 0.0000
40 Comp Mole Frac (EGly-DiAceta) *** *** *** *** ***
41 Name 222 223 225 101 202
42 Comp Mole Frac (E-Benzene) 0.0020 0.0020 0.8210 1.0000 0.0000
43 Comp Mole Frac (Styrene) 0.9980 0.9980 0.0761 0.0000 0.0000
44 Comp Mole Frac (Toluene) 0.0000 0.0000 0.1029 0.0000 0.0000
45 Comp Mole Frac (Benzene) 0.0000 0.0000 0.0000 0.0000 0.0000
46 Comp Mole Frac (Ethylene) 0.0000 0.0000 0.0000 0.0000 0.0000
47 Comp Mole Frac (Hydrogen) 0.0000 0.0000 0.0000 0.0000 0.0000
48 Comp Mole Frac (H2O) 0.0000 0.0000 0.0000 0.0000 1.0000
49 Comp Mole Frac (Methane) 0.0000 0.0000 0.0000 0.0000 0.0000
50 Comp Mole Frac (EGly-DiAceta) *** *** *** *** ***
51 Name 210 211 204 215 216
52 Comp Mole Frac (E-Benzene) 0.0000 0.0000 0.0034 0.1555 0.1555
53 Comp Mole Frac (Styrene) 0.0000 0.0000 0.0201 0.3823 0.3823
54 Comp Mole Frac (Toluene) 0.0000 0.0000 0.0027 0.2453 0.2453
55 Comp Mole Frac (Benzene) 0.0000 0.0000 0.0046 0.2150 0.2150
56 Comp Mole Frac (Ethylene) 0.0000 0.0000 0.0224 0.0004 0.0004
57 Comp Mole Frac (Hydrogen) 0.0000 0.0000 0.8405 0.0000 0.0000
58 Comp Mole Frac (H2O) 1.0000 1.0000 0.0837 0.0014 0.0014
59 Comp Mole Frac (Methane) 0.0000 0.0000 0.0227 0.0000 0.0000
60 Comp Mole Frac (EGly-DiAceta) *** *** *** *** ***
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Licensed to: LEGENDS * Specified by user.
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Case Name: ESTIRENO 1º ENTREGA 28-JUN.HSC
2 LEGENDS
3 Burlington, MA Unit Set: SI
4 USA
Date/Time: Mon Jun 28 11:00:04 2010
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Workbook: Case (Main) (continued)
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Compositions (continued) Fluid Pkg: All

11 Name 213B 206 207 208 227

12 Comp Mole Frac (E-Benzene) 0.0232 0.0977 0.0977 0.0977 0.8210
13 Comp Mole Frac (Styrene) 0.0392 0.8515 0.8515 0.8515 0.0761
14 Comp Mole Frac (Toluene) 0.0905 0.0306 0.0306 0.0306 0.1029
15 Comp Mole Frac (Benzene) 0.2243 0.0181 0.0181 0.0181 0.0000
16 Comp Mole Frac (Ethylene) 0.0990 0.0004 0.0004 0.0004 0.0000
17 Comp Mole Frac (Hydrogen) 0.1465 0.0005 0.0005 0.0005 0.0000
18 Comp Mole Frac (H2O) 0.3488 0.0012 0.0012 0.0012 0.0000
19 Comp Mole Frac (Methane) 0.0286 0.0001 0.0001 0.0001 0.0000
20 Comp Mole Frac (EGly-DiAceta) *** *** *** *** ***
21 Name 114
22 Comp Mole Frac (E-Benzene) 0.0000
23 Comp Mole Frac (Styrene) 0.0000
24 Comp Mole Frac (Toluene) 0.0000
25 Comp Mole Frac (Benzene) 0.0000
26 Comp Mole Frac (Ethylene) 0.0000
27 Comp Mole Frac (Hydrogen) 0.0000
28 Comp Mole Frac (H2O) 1.0000
29 Comp Mole Frac (Methane) 0.0000
30 Comp Mole Frac (EGly-DiAceta) ***
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Energy Streams Fluid Pkg: All

33 Name E-CVR-101 Q-E102 Q-P101 Q-E103 Q-E104

34 Heat Flow (kJ/h) 0.0000 * 8.913e+007 8242 9.090e+007 8.233e+005
35 Name Q-K101 QR-T101 QC-T101 QR-T102 QC-T102
36 Heat Flow (kJ/h) 1.684e+007 2.756e+006 1.627e+006 5.737e+007 5.724e+007
37 Name E-P107 Q-E105 Q-P100 Q-P104 E-P105
38 Heat Flow (kJ/h) 369.7 2.141e+006 1945 2755 3624
39 Name e Q-E106 Q-P108 Q-P103 Q-P106
40 Heat Flow (kJ/h) czxcxz 3.724e+005 3025 1090 252.0
41 Name Q-K102 Q-P102
42 Heat Flow (kJ/h) 1365 209.3
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Unit Ops
45 Operation Name Operation Type Feeds Products Ignored Calc Level
46 107 108
47 CVR-101 Conversion Reactor 106 109 No 500.0 *
48 E-CVR-101 E-CVR-101
49 118 107
E-102 Heater No 500.0 *
50 Q-E102
51 207 208
E-104 Heater No 500.0 *
52 Q-E104
53 117 118
P-101 Pump No 500.0 *
54 Q-P101
55 224 225
P-107 Pump No 500.0 *
56 E-P107
57 100 101
P-100 Pump No 500.0 *
58 Q-P100
59 205 206
P-104 Pump No 500.0 *
60 Q-P104
61 212 217
P-105 Pump No 500.0 *
62 E-P105
63 221 222
P-108 Pump No 500.0 *
64 Q-P108
65 209 210
Q-P103 Pump No 500.0 *
66 Q-P103
67 214 215
P-106 Pump No 500.0 *
68 Q-P106
69 Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 4 of 5
Licensed to: LEGENDS * Specified by user.
1
Case Name: ESTIRENO 1º ENTREGA 28-JUN.HSC
2 LEGENDS
3 Burlington, MA Unit Set: SI
4 USA
Date/Time: Mon Jun 28 11:00:04 2010
5
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Workbook: Case (Main) (continued)
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Unit Ops (continued)
11 Operation Name Operation Type Feeds Products Ignored Calc Level
12 113 114
P-102 Pump No 500.0 *
13 Q-P102
14 109 110
E-101 Heat Exchanger No 500.0 *
15 103 105
16 115 111
MX-102 Mixer No 500.0 *
17 110
18 102 103
MIX-101 Mixer No 500.0 *
19 227
20 200 205
21 TFS-101 3 Phase Separator 203 No 500.0 *
22 201
23 112 200
E-103 Cooler No 500.0 *
24 Q-E103
25 220 221
E-105 Cooler No 500.0 *
26 Q-E105
27 217 218
E-106 Cooler No 500.0 *
28 Q-E106
29 111 112
K-101 Compressor No 500.0 *
30 Q-K101
31 213 213B
K-102 Compressor No 500.0 *
32 Q-K102
33 VLV-104 Valve 206 207 No 500.0 *
34 VLV-107 Valve 218 219 No 500.0 *
35 VLV-108 Valve 222 223 No 500.0 *
36 VLV-100 Valve 101 102 No 500.0 *
37 VLV-103 Valve 201 202 No 500.0 *
38 VLV-105 Valve 210 211 No 500.0 *
39 VLV-109 Valve 203 204 No 500.0 *
40 VLV-106 Valve 215 216 No 500.0 *
41 VLV-110 Valve 225 227 No 500.0 *
42 VLV-101 Valve 114 115 No 500.0 *
43 RCY-1 Recycle 105 106 No 3500 *
44 RCY-2 Recycle 116 117 No 3500 *
45 202 209
TEE-101 Tee No 500.0 *
46 116
47 208 212
48 QR-T101 213
T-101 Distillation No 2500 *
49 214
50 QC-T101
51 219 224
52 T-102 Distillation QR-T102 220 No 2500 *
53 QC-T102
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69 Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 5 of 5
Licensed to: LEGENDS * Specified by user.