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PATTERN CODE P7-19

PAPER-1 : ADVANCED PATTERN CUMULATIVE TEST-4


(ACT-4)
TARGET : JEE (MAIN+ADVANCED) 2021
COURSE NAME : VIKAAS (05JA-06JA)
TEST DATE : 12-12-2021 TARGET DATE : 00-00-21
Test Syllabus: FOM-I, Quadratic Equation, Trigonometry, Sequence and Series,
FOM-II, Binomial Theorem

1. a, b, c, d are distinct integers such that (x –a) (x – b) (x – c) (x – d) = 4 has a root r (Natural number))
then (a + b + c + d) can be equal to
a, b, c, d fHkUu fHkUu iw.kk±d bl izdkj gS fd (x –a) (x – b) (x – c) (x – d) = 4 dk ,d ewy r (izkd`r la[;k) rc
(a + b + c + d) cjkcj gks ldrk gS&
(A*) 4 (B) 6 (C*) 8 (D) 10
Sol. (r –a)(r-b)(r-c)(r-d) = 4 = (2)(-2)(1)(-1)
r-a = 2 r –c =1
r – b = -2 r – d = -1
2r – a- b =0 2r – c –d = 0
a + b = 2r c + d = 2r
a + b + c + d = 4r

2. The expression cos2( +  + ) + cos2( + ) + cos2 – 2cos cos( + ) cos( +  + ) is


(A*) independent of  (B*) independent of 
(C) dependent on    (D) dependent on ,and
O;atd cos2( +  + ) + cos2( + ) + cos2 – 2cos cos( + ) cos( +  + ) dk eku gS&
(A*) ls Lora=k (B*) ls Lora=k
(C) ij fuHkZj    (D) ,vkSj ij fuHkZj
Sol. cos2 + cos2( + ) + cos2( +  + ) – 2cos cos( + ) cos( +  + )
= cos2 + cos2( + ) + cos( +  + ) [cos( +  + ) –2cos cos( + )]
= cos2 + cos2( + ) + cos( +  + ) [cos( +  + ) – cos( +  + ) – cos( + – )]
= cos2 + cos2( + ) – cos( +  + )
cos( +  – )
= cos2 + cos2( + ) – [cos2( + ) – sin2] = 1

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x2  1
3. If the complete solution set of the inequality < 3 is (–, –a) (b, c), then
2x  5
x2  1
vlfedk < 3 dk lEiw.kZ gy leqPp; (–, –a) (b, c) gS] rc
2x  5
(A) abc = 40 (B*)abc = –40
(C) 2a + b + c = – 11 (D*) 2a + b + c = 11
Sol.

x2  1 x 2  1  6x  15 x 2  6x  16
– 3 < 0  0   0  
2x  5 2x  5 2x  5
x 2  8x  2x  16 x(x  8)  2(x  8) (x  8)(x  2)
  0   0   0 
 5 5 5
 x  x  x
 2  2 2
 x  (–, –5/2)  (–2, 8)
5
 a = , b = – 2, c = 8
2

4. If cosx + secx = – 2, then cosnx + secnx is


(A) 2, n  (B) – 2, n  (C*) –2, if n is odd (D*) 2, if n is even
;fn cosx + secx = – 2, rc cosnx + secnx dk eku gS&
(A) 2, n  (B) – 2, n  (C*) –2, ;fn n fo"ke gSA (D*) 2, ;fn n le gSA
Sol. cosx + secx = – 2  cosx = – 1
 cosnx + secnx = – 2 if n is odd
 cosnx + secnx = 2 if n is even
cosx + secx = – 2  cosx = – 1
 cosnx + secnx = – 2 ;fn n fo"ke gSA
 cosnx + secnx = 2 ;fn n le gSA

5. If a, b, c are in H.P., then which of the following is true.

a b c  b b  b
(A*) , , are in H.P. (B) n  a   , n , n  c   are in H.P.
1  2a 1  2b 1  2c  2 2  2

b b b
(C*) c – , ,a– are in G.P. (D*) e1/a, e1/b, e1/c are in G.P.
2 2 2

;fn a, b, c gjkRed Js.kh esa gS rc fuEu esa ls dkSuls lgh gS \

a b c  b b  b
(A*) , , gjkRed Js.kh esa gSA (B) n  a   ,n ,n  c   gjkRed Js.kh esa gSA
1  2a 1  2b 1  2c  2  2  2

b b b
(C*) c – , ,a– xq.kksÙkj Js.kh esa gSA (D*) e1/a, e1/b, e1/c xq.kksÙkj Js.kh esa gSA
2 2 2

a b c
Sol. (A) , , are in H.P.
1  2a 1  2b 1  2c

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1  2a 1  2b 1  2c
 , , are in A.P.
a b c
1 1 1
 , , are in A.P.
a b c
 a, b, c are in H.P.
b b b
(B) a – , , c – are in G.P.   
2 2 2
 b b  b
 n  a   , n , n  c   are in A.P.
 2 2  2
b b b
(C) c – , ,a– are in G.P.
2 2 2
1 1 1
(D) , are in A.P.
a b c
e1/a, e1/b, e1/c are in G.P.

a b c
Hindi (A) , , gjkRed Js.kh esa gSA
1  2a 1  2b 1  2c
1  2a 1  2b 1  2c
 , , lekUrj Js.kh esa gSA
a b c
1 1 1
 , , lekUrj Js.kh esa gSA
a b c
 a, b, c gjkRed Js.kh esa gSA
b b b
(B) a – , , c – xq.kksÙkj Js.kh esa gSA
2 2 2
 b b  b
 n  a   , n , n  c   lekUrj Js.kh esa gSA
 2  2  2
b b b
(C) c – , ,a– xq.kksÙkj Js.kh esa gSA
2 2 2
1 1 1
(D) , lekUrj Js.kh esa gSA
a b c
e1/a, e1/b, e1/c xq.kksÙkj Js.kh esa gSA

6. The value of 2nCn + 2nCn – 1 equals to


2nC
n+
2nC dk eku cjkcj gS &
n–1

1
(A) 2n + 2 Cn + 1 (B) 2n + 2Cn (C*) 2n + 2C
n+1 (D*) 2n + 1Cn
2
2nC
(2n  1)! (2n  2)(2n  1)! 1 (2n  2)!
Sol. n + 2nCn – 1 = 2n + 1Cn = = =
n!(n  1)! 2(n  1) n!(n  1)! 2 (n  1)! (n  1)!
1
= 2n + 2C
n+1
2

Integer (Double) 8

7. Solution of inequality [x]2 – 9[x] – 52 < 0 is [a, b). Find b + 2a (where [.] denotes greatest integer
function)
vlfedk [x]2 – 9[x] – 52 < 0 dk gy [a, b) gS rc b + 2a dk eku Kkr dhft, (tgk¡ [.] egÙke iw.kk±d Qyu gS)
Ans. 07
Sol. [x]2 – 9[x] – 52 < 0

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([x] – 13)([x] + 4) < 0
– 4 < [x] < 13
– 3  [x]  12  x  [–3, 13)

8. When 1127 + 2127 is divided by 16, then find the remainder.


tc 1127 + 2127 dks 16 ls foHkkftr fd;k tkrk gks] rks 'ks"kQy Kkr dhft,A
Ans. 00
Sol. (16 – 5)27 + (16 + 5)27
= 1627 – 27C1 1626 . 5 + 27C2 1625 . 52 +........... + 27C26 . 16 × 526 – 27C27 . 527
+ 1627 + 27C1 1626 . 5 + 27C2 1625 . 52 + ....... + 27C26 16 × 526 + 27C27 527
= 2 [1627 + 27C2 1625 . 52 + ..........+ 27C26 16 . 526 ]
 remainder = 0
Hindi. (16 – 5)27 + (16 + 5)27
= 1627 – 27C1 1626 . 5 + 27C2 1625 . 52 +........... + 27C26 . 16 × 526 – 27C27 . 527
+ 1627 + 27C1 1626 . 5 + 27C2 1625 . 52 + ....... + 27C26 16 × 526 + 27C27 527
= 2 [1627 + 27C2 1625 . 52 + ..........+ 27C26 16 . 526 ]
 'ks"kQy = 0

2 2
9. If 0  x   and 81sin x
 81cos x
 30 , then the smallest value of x is equal to 2 / n , then the value of
n is
2 2
;fn 0  x   rFkk 81sin x  81cos x
 30 , rc x dk U;wure eku 2 / n ds cjkcj gS] rc n dk eku gS&
Ans : 12

Sol. Let ekuk 81sin


2
x
 y , then rc 81cos
2
x
 81
1sin x
2

81

81
.
sin2 x y
81
2 2 81
Now vc, 81sin x
 81cos x
 30  y   30  y2  30y  81  0  y 2  3y  27y  81  0
y
 y  y  3  27  y  3  0   y  3 y  27  0  y  3 or y  27
2 2 2 2
 81sin x
 3 or 81sin x
 27  34 sin x
 3 or 34 sin x
 33  4 sin2 x  1 or 4 sin2 x  3

1 3 1 3
 sin x  
2
or sin x  
2
 sin x  or sin x 
2 2
 0  x    sin x is  ve

 5  2 
 x or or x  or , clearly, the smallest permissible value of x is .
6 6 3 3 6
 5  2 
 x  or or x  or , Li"Vr;k x dk U;wure laHkkfor eku gSA
6 6 3 3 6

n
 x 2
10. If the 9th term of the expansion    has numerically greatest coefficient, then find the value of
5 5
n – 8.
n
x 2
;fn    ds çlkj esa 9 oka in la[;kRed egÙke xq.kkad j[krk gS] rks n – 8 dk eku Kkr dhft,A
5 5  
Ans. 04
Sol. T10 < T9 > T8
n–9 9 n – 8 8
nC  1 2  1 2
9  5 < nC8   5
5   5  
nC 2  1
9  < nC8  
5 5

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2n! n! 2 1
<   <  n < 12.5
(n – 9)! 9! (n – 8)! 8! 9 n8
n–8 8 n–7 7
nC  1 2  1 2
 5  > C7  5 
n
8  5
5      
nC 2 1 n
8 5 > C7
  5
2 . n! n! 2 1
>  >  n > 11
(n – 8)! 8! (n – 7)! 7! 8 (n – 7)
n = 12

n 1
nr 55
11. If  r  1r  2r  3  3k
r 0
(where n = 10), then 3k is

n 1
nr 55
;fn  r  1r  2r  3  3k
r 0
(tgk¡ n = 10), rc 3k dk eku cjkcj gS&

Ans : 24
n 1
n  1  r  1
Sol. Given sum fn;k x;k ;ksxQy  
r 0
r  1r  2r  3
n 1 n 1
1 1
  n  1 
r 0
 
r  1r  2r  3 r 0 r  2r  3
n  1 n1  1 1  n1  1 1 

2   r 1 r  2
r 0 
  

 r  2 r  3   r 0

   r  2  r  3 

55
 for n = 10 ds fy,  3k  24
24

12. Let f(x) is a polynomial of degree 5 with leading coefficient unity such that f(1) = 5, f(2) = 4, f(3) = 3,
f(4) = 2, f(5) = 1, then sum of roots of f(x) equal to:
ekuk 5 ?kkr dk f(x) ,d cgqin gS ftldk vxzx xq.kkad bdkbZ gS f(1) = 5, f(2) = 4, f(3) = 3, f(4) = 2, f(5) = 1, rc
f(x) ds ewyksa dk ;ksxQy gS -
Ans. 15
Sol. f(x) – (6 – x) = (x – 1) (x – 2) (x – 3) (x – 4) (x – 5)
f(x) = (x – 1) (x – 2) (x – 3) (x – 4) (x – 5) – x + 6
x4 coefficient in f(x) will be
= –(1 + 2 + 3 + 4 + 5) = – 15
So sum of roots 15
Hindi f(x) – (6 – x) = (x – 1) (x – 2) (x – 3) (x – 4) (x – 5)
f(x) = (x – 1) (x – 2) (x – 3) (x – 4) (x – 5) – x + 6
f(x) esa] x4 dk xq.kkad gksxk
= –(1 + 2 + 3 + 4 + 5) = – 15
ewyksa dk ;ksx 15 gSA

13. Find the number of positive integers n such that 105 is a divisor of n 2 + n +1
n ds /kukRed iw.kkZadksa dks Kkr dhft, tcfd 105, n2 + n +1 dk Hkktd gSA
Ans. 00
Sol. The digit in the unit place of n(n + 1) + 1 is 1, 3 or 7.
 5 does not divides n2 + n +1
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 105 is not a divisor of n(n + 1) + 1.
Hindi n(n + 1) + 1 dk bdkbZ LFkku dk vad 1, 3 ;k 7.
 5, n2 + n +1 dks foHkkftr ugh djrk gSA
 105, n(n + 1) + 1 dk Hkktd ugh gSA

14. If numerically greatest co-efficient in expansion of (3x + 4y)16 is the coefficient of TR, find R.
;fn (3x + 4y)16 ds foLrkj esa egÙke la[;kRed xq.kkad] TR dk xq.kkad gS] rks R Kkr dhft,A
Ans. 10
17 17  4
Sol. r r   9ss
3 7
1
4
 R = r + 1 = 9 + 1 = 10

Paragraph for Question Nos. 15 to 16


ç'u 15 ls 16 ds fy, vuqPNsn

Let P(x) be quadratic polynomial with real coefficients such that for all real x the relation
2(1 + p(x)) = P(x – 1) + P(x + 1) holds. If P(0) = 8 and P(2) = 32 then

ekuk fd P(x) f}?kkr cgqin gS ftlds xq.kkad okLrfod gS] lHkh okLrfod x ds fy, lEcU/k
2(1 + p(x)) = P(x – 1) + P(x + 1) larq"V gksrk gSA ;fn P(0) = 8 rFkk P(2) = 32 rc

15. Sum of all coefficients of P(x) is


P(x) ds lHkh xq.kkadksa dk ;ksxQy gS&
(A) 20 (B*) 19 (C) 17 (D) 15
Sol. put x = 1
2[1 + p(1)] = P(0) + p(2)  P(1) = 19
Hindi x=1 j[kus ij
2[1 + p(1)] = P(0) + p(2)  P(1) = 19

16. If the range of p(x) is [m, ) then 'm' is


;fn p(x) ds ifjlj [m, ) gS rc 'm' gS&
(A) –12 (B) –15 (C*) –17 (D) –5
Sol. Let

p(x)  ax 2  bx  c 

p(0)  c  c  8  a 1

p(2)  32  2a  b  12  b  10
p(1)  19  a  b  c  19 

p(x) = x2 + 10x + 8 = (x + 5)2 – 17


minimum = – 17 range [–17, )
Hind ekuk

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p(x)  ax 2  bx  c 

p(0)  c  c  8  a 1

p(2)  32  2a  b  12  b  10
p(1)  19  a  b  c  19 

p(x) = x2 + 10x + 8 = (x + 5)2 – 17


U;wure= – 17 ifjlj [–17, )

Paragraph for Question Nos. 17 to 18


ç'u 17 ls 18 ds fy, vuqPNsn

Consider the multinomial expansion (a + b + c)12, then answer the following questions :

17. Total number of terms in the expansion of (a + b + c)12 are


(A) 65 (B) 66 (C*) 91 (D) 71
Sol. Any term of (a + b + c)12 is ar bs ct where r + s + t = 12
 the number of distinct terms = coefficient of x12 in (1 – x)–3
= 14C12 = 91

18. Coefficient of a10bc in (a + b + c)12 is


(A*) 132 (B) 66 (C) 95 (D) 135
Sol. coefficient of a10 bc = 12C
2 × 2C
1 × 1C
1 = 132

ç'u 17 ls 18 ds fy, vuqPNsn

ekukfd cgqinh; izlkj (a + b + c)12 gS] rks fuEufyf[kr iz'uksa ds mÙkj nhft,A

17. (a + b + c)12 ds izlkj esa inksa dh dqy la[;k gS &


(A) 65 (B) 66 (C*) 91 (D) 71
Sol. (a + b + c)12 dk dksbZ in ar bs ct gS] tgk¡ r + s + t = 12
 fofHkUu inksa dh la[;k = (1 – x)–3 esa x12 dk xq.kkad
= 14C12 = 91

18. (a + b + c)12 esa a10bc dk xq.kkad gS &


(A*) 132 (B) 66 (C) 95 (D) 135
Sol. a10bc dk xq.kkad = 12C
2 × 2C
1 × 1C
1 = 132

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®
PATTERN CODE P10-21

TEST TYPE : ADVANCED PATTERN CUMULATIVE TEST-4 (ACT-4)


TARGET : JEE (MAIN+ADVANCED) 2022
COURSE NAME : VIKAAS (05JA, 06JA)

TEST DATE : 12-12-2021


Test Syllabus : Mathematical tools, Rectilinear Motion,Relative Motion, Newtons Laws
of Motion, Friction, Work Energy and Power, Circular Motion, Centre of Mass,
Rigid Body Dynamics

PAPER-1
SECTION – 1 : (Maximum Marks : 24)
 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is(are) correct
 For each question, marks will be awarded in one of the following categories :
 Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
 Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
 Partial Marks : +2 If three or more options are correct but ONLY two options are chosen
and both of which are correct.
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and
it is a correct option.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –2 In all other cases.
 For example, in a question, if (A),(B) and (D) are the ONLY three options corresponding to correct
answers, then :
 Choosing ONLY (A),(B) and (D) will get +4 marks
 Choosing ONLY (A) and (B) will get +2 marks
 Choosing ONLY (A) and (D) will get +2 marks
 Choosing ONLY (B) and (D) will get +2 marks
 Choosing ONLY (A) will get +1 marks
 Choosing ONLY (B) will get +1 marks
 Choosing ONLY (D) will get +1 marks
 Choosing no option (i.e. the question is unanswered) will get 0 marks, and
 Choosing any other combination of options will get –2 mark

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[kaM 1 : (vf/kdre vad : 24)
 bl [kaM esa N% (06) iz'u gSaA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad % +4 ;fn dsoy ¼lkjs½ lgh fodYi ¼fodYiksa½ dks pquk x;k gSA
 vkaf'kd vad % +3 ;fn pkjksa fodYi lgh gSa ijUrq dsoy rhu fodYiksa dks pquk x;k gSA
 vkaf'kd vad % +2 ;fn rhu ;k rhu ls vf/kd fodYi lgh gS ijUrq dsoy nks fodYiksa dks pquk x;k gS vkSj
nksauks pqus gq, fodYi lgh fodYi gSaA
 vkaf'kd vad % +1 ;fn nks ;k nks ls vf/kd fodYi lgh gSa ijUrq dsoy ,d fodYi dks pquk x;k gS vkSj
pquk gqvk fodYi lgh fodYi gSA
 'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –2 vU; lHkh ifjfLFkfr;ksa esaA
 mnkgj.k% ;fn fdlh iz'u ds fy, dsoy fodYi (A),(B) vkSj (D) lgh fodYi gS] rc %
 dsoy fodYi (A),(B) vkSj (D) pquus ij +4 vad feysaxs ’
 dsoy fodYi (A) vkSj (B) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (B) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) pquus ij +1 vad feysaxs ’
 dsoy fodYi (B) pquus ij +1 vad feysaxs ’
 dsoy fodYi (D) pquus ij +1 vad feysaxs ’
 dksbZ Hkh fodYi u pquus ij ¼vFkkZr~ iz'u vuqÙkfjr jgus ij½ 0 vad feysaxs vkSj
 vU; fdlh fodYiksa ds la;kstu dks pquus ij –2 vad feysaxs


19. The potential energy ‘U’ for a force field F is such that
U = – kxy
Where ‘k’ is a contant

,d cy F ds fy, fLFkfrt ÅtkZ
U = – kxy
tgkWa ‘k’ ,d fu;rkad gS

  
 
  

(A*) F  ky i x j (B) F  kx i y j
   
 
(C*) F is conservative force (D) F is non-conservative force
 
F ,d laj{kh cy gS F ,d vlaj{kh cy gS
v
Sol. Fx = –  ky
x
v
Fy    kx
y
 
Also dk;Z W.D. 
 F .ds

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  
   

 k
  y i  x j . dx i  dy j 
   

 k
 d  xy 
= kxy (independent of path iFk ls Loar=k gS)

So, F is conservative force

bl izdkj cy F laj{kh gSA

20. When a cylinder is spinned and placed somewhere on surface of a rough inclined plane as shown then
after release.
fp=kkuqlkj pØ.k djrs gq, csyu dks urry dh [kqjnqjh ur lrg ij fdlh LFkku ij j[kk tkrk gS rc bls eqDr
djus ds ckn

(A*) The cylinder may continue to accelerate down and never be in pure rolling.
(B*) The cylinder may accelerate up for some time then retard and come down in pure rolling.
(C*) The cylinder may accelerate down continuously and pure rolling will start after some time.
(D) Friction will act on cylinder in upward direction initially and later it will be downward direction.
(A*) csyu yxkrkj uhps dh vksj Rofjr gks ldrk gS vkSj dHkh Hkh 'kq) yksVuh xfr ugha djsxkA
(B*) csyu Åij dh vksj dqN le; ds fy, Rofjr gks ldrk gS rc efUnr gksxk vkSj uhps vkrs gq, 'kq) yksVuh xfr
djsxkA
(C*) csyu yxkrkj uhps dh vksj Rofjr xfr dj ldrk gS rFkk dqN le; ckn 'kq) yksVuh xfr izkjEHk djsxkA
(D) csyu ij ?k"kZ.k izkjEHk esa Åij dh vksj dk;Zjr gS rFkk ckn esa uhps dh vksj dk;Zjr gks tk;sxkA
tan 
Sol. (A) if  < , it will not be in pure rolling.
3
(B) If mg cos  > mg sin  , cylinder will accelerate up initially for some time.
(C) If mg sin  > mg cos , cylinder will accelerate down continuously.
(D) Friction will always act in upward direction.
tan 
Sol. (A) ;fn  < , ;g 'kq) yksVuh xfr ugha djsxkA
3
(B) ;fn mg cos  > mg sin  , csyu izkjEHk esa dqN le; ds fy, Åij dh vksj Rofjr gks tk;sxkA
(C) ;fn mg sin  > mg cos , csyu yxkrkj uhps dh vksj Rofjr gks tk;sxkA
(D) ?k"kZ.k ges'kk Åij dh vksj gh yxsxkA

21. The x–t graph of a particle moving along a straight line is shown in fig.
ljy js[kk esa xfreku d.k ds fy, x–t xzkQ n'kkZ;k x;k gSA
x

Parabola
ijoy;

Time(t)
T 2T le;
Choose correct representation(s) of motion in following graphs:
rks xfr dks iznf'kZr djus okys lgh xzkQ dk p;u djks

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Speed
pky
(A*)

Time(t)
T 2T le;
Distance
nwjh
(B*)

Time(t)
T 2T le;

Distance
nwjh
(C)

Time(t)
T 2T le;
a
(Acceleration)
(D*) Roj.k
(t)

Sol. As x-t graph is parabolic acceleration (a) is constant. At t = 0 velocity is positive, become zero at
t = T and further decreases. Hence a is –ve.
x-t xzkQ ,d ijoy; gS rFkk Roj.k fu;r gSA t = 0 ij osx /kukRed gS rFkk ?kVdj t = T ij 'kwU; tkrk gSA blds
i'pkr vksj ?kVrk gS vr% Roj.k _.kkRed gSA
22. The end B of the rod AB which makes an angle ‘  ’ with the floor is being pulled with a constant velocity
V0 as shown. The length of the rod is L. At the instant when  = 37º ?
,d NM+ AB tks fp=kkuqlkj lrg ls ‘  ’ dks.k ij fLFkr gS] dk fljk B fu;r pky V0 ls fp=kkuqlkj [khapk tkrk gSA
NM+ dh yEckbZ L gSA rks tc  = 37º gS ml {k.k ?
y

 v0
O B x

4 V0 5 V0
(A*) Velocity of end A is downwards (B*) Angular velocity of rod is
3 3L

5 V0
(C*) Speed of COM of the rod is (D) none of these
6
4 V0 5 V0
(A*) fljs A dk osx uhps dh vksj (B*) NM+ dks dks.kh; osx
3 3L

5 V0
(C*) NM+ ds nzO;eku dsUnz dh pky gS (D) buesa ls dksbZ ugh
6

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Sol.
4l
5 Instantaneous
A axis of rotation
rkR{kf.kd ?kw.kZu
3l
v{k
VA 5

 = 370 v0
V0 x

V 0 .5 V A .5
  
3L 4L
4 V0
VA 
3
l 5 V0
(V)  .
 com = 
2 6
23. A heavy homogeneous cylinder has a mass m and radius R. It is accelerated by a horizontal force F,
which is applied through a rope wound around a light drum of radius r attached to the cylinder. The
coefficient of static friction is sufficient for the cylinder to roll without slipping :
,d Hkkjh le:i csyu ftldk nzO;eku m rFkk f=kT;k R gSA bldks {kSfrt cy F vkjksfir djds Rofjr fd;k tkrk
gSA bl cy dks csyu ds dsUnz ls r f=kT;k ds gYds Mªe ij fyiVh gqbZ jLlh ij vkjksfir fd;k tkrk gSA LFkSfrd
?k"kZ.k xq.kkad csyu dks fcuk fQlys yq<dkus ds fy, i;kZIr gSA lgh dFku NkVksa

Choose the correct options :


dkSuls dFku lR; gSa %
2F
(A*) acceleration of centre of cylinder is a = (R + r)
3 mR
2F
csyu ds dsUnz dk Roj.k a = (R + r)
3 mR

2  1 r 
(B*) friction assumed to be in the opposite direction of F is f =   F
3 2 R 

2  1 r 
?k"kZ.k cy F ds foijhr fn'kk esa f =   F ds cjkcj gSA
3 2 R 

 r  1 F
(C) If    a will be greater than
R  2 m

 r  1 F
;fn    gks rks a dk eku ls T;knk gksxk
R  2 m

2  1 r 
(D) Friction assumed to be in the direction of F is f =   F
3 2 R 

2  1 r 
?k"kZ.k cy F dh fn'kk esa f =   F ds cjkcj gSA
3 2 R 

Sol.

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F – f = ma
2
mR
Fr + fR = 
2
a = R
2F
Solving gy djus ij a = (R + r)
3 mR

2  1 r 
f=   F
3 2 R 

 r  1
If   
R  2

f will be forward
f vkxs rjQ gksxk
F
 F + f = ma  a> .
m

24. A particle falls through a vertical height ‘h’ and makes perfectly elastic impact with a smooth inclined
plane of inclination ‘  ’ with horizontal. The time interval between its first and second impact on the
incline
{kSfrt ls dks.k ij >qds gq, ,d fpdus urry dh lrg ls ‘h’ ÅpkbZ ls fxjk;k x;k ,d d.k urry ls iw.kZr;k
izR;kLFk VDdj djrk gSA rks urry ij izFke VDdj rFkk f}rh; VDdj ds e/; le;kUrjky gSA
1 1

(A) is proportional to h 2
ds lekuqikrh (B*) is proportional to h2 ds lekuqikrh
1
(C) is proportional to ds lekuqikrh (D*) independent of ‘  ’ ls Lora=k
cos 
Sol.
V sin  V cos 

V


V cos 

V sin 


After collision, VDdj ds ckn
2v cos  2v 2
t    2gh
g cos  g g

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SECTION – 2 : (Maximum Marks : 24)
 This section contains EIGHT (08) questions
 The answer to each question is a DOUBLE DIGIT INTEGER ranging from 00 to 99, both inclusive
 Marking scheme :
 Full Marks : +3 If ONLY the correct option is chosen.
 Zero Marks : 0 In all other cases

[kaM 2 : (vf/kdre vad : 24)


 bl [kaM esa vkB (08) iz'u gSaA
 izR;sd iz'u dk mÙkj 00 ls 99 rd, nksuksa 'kkfey] ds chp dk ,d f} vadh; iw.kk±d gSA
 vadu ;kstuk :
 iw.kZ vad % +3 ;fn flQZ lgh fodYi gh pquk x;k gSA
 'kwU; vad % 0 vU; lHkh ifjfLFkfr;ksa esaA

25. In the figure shown a lift goes downwards with a constant retardation. An observer in the lift observers a
conical pendulum in the lift, revolving in a horizontal circle with time period 2 seconds. The distance
between the centre of the circle and the point of suspension is 2.0 m. Find the retardation of the lift
in m/s2. Use 2 = 10 and g = 10 m/s2
fn, x, fp=k esa fy¶V fu;r eanu ls uhps dh vkSj xfr dj jgh gSA ,d izs{kd tks fy¶V ds vUnj gS] 2 lSd.M ds
vkorZ&dky okys {kSfrt o`Ùk esa pDdj dkV jgs dksfudy isa.Mwye ¼'kaDokdkj yksyd½ dks ns[krk gSA o`r ds dsUnz ,oe~
yVdu fcUnq ds chp nwjh 2.0 m gSA fy¶V dk eanu Kkr dhft,A mi;ksx esa ysa 2 = 10 vkSj g = 10 m/s2

Ans. 10
cos  h
Sol. T = 2 = 2
g e ff . g e ff .

geff. = g + a ; put T = 2  a = 10 m/s2.


Ans. Retardation = 10 m/s2

26. A uniform solid disc of mass 1 kg and radius 1m is kept on a rough horizontal surface. Two forces of
magnitude 2N and 4N have been applied on the disc as shown in the figure. Linear acceleration of the
centre of mass of the disc is if there is no slipping.
,d 1 kg nzO;eku rFkk 1m f=kT;k dh le:i Bksl pdrh ,d [kqjnjh {kSfrt lrg ij j[kh gqbZ gSA bl pdrh ij
2N rFkk 4N ifjek.k ds nks cy fp=kkuqlkj yxk;s tkrs gSA bl pdrh ds nzO;eku dsUnz dk jsf[kd Roj.k gS (;fn dksbZ
fQlyu ugh gks rks)
2N

4N

Ans. 00
Sol. Taking torque about contact point,  = 4 × R – 2× 2R = 0, Fnet = 0
laidZ fcUnq ds lkis{k cyk?kw.kZ,  = 4 × R – 2× 2R = 0, Fnet = 0

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27. A ball of mass M strikes another ball of mass m at rest. If they separate in mutually perpendicular
2M
directions. Then coefficient of impact e = . Calculate 2.
25 m
M nzO;eku dh ,d xsan fojkekoLFk esa fLFkr m nzO;keu dh xsan ls Vdjkrh gSA ;fn VDdj ds i'pkr nksuksa ,d nwljs
2M
ds yEcor~ fn'kk esa xfr djrh gS rks izR;koLFkku xq.kkad e = gS 2dk eku Kkr djksA
25 m
Ans. 25
Sol.
v1 u cos
m
u 
u
M 90–
M
v2 u sin
Mu cos = m. v1
v1 M
e= =
u cos  m

28. Find the twice of ratio of maximum to minimum moment of inertia of a uniform solid sphere. Axis to be
considered through the material of sphere.
,d leku Bksl xksys ds vf/kdre rFkk U;wure tMRo vk?kw.kksZ ds vuqikr dk nqxquk Kkr djksA v{k xksys ds inkFkZ ls
xqtjrh gqbZ ekusA
Ans. 07
7 2
mR
5 7
Sol. =
2 2 2
mR
5

29. A solid cylinder of radius 2m is kept on an inclined plane on its base and it does not slide. The angle of
incline plane is 53° with horizontal and it is fixed. If maximum height (in metre) of the cylinder for it not
to topple is x, then find value of 4x.
2m f=kT;k dk ,d Bksl csyu ,d ur ry ij blds vk/kkj ij j[kk gS ,oa ;g fQlyrk ugha gSA {kSfrt ls ur ry
dk dks.k 53° gS ,oa ;g fLFkj gSA ;fn csyu ds ugha iyVus ds fy, bldh vf/kdre Å¡pkbZ ¼ehVj esa½ x gS rks 4x dk
eku Kkr djksA
Ans. 12
Sol. Since it does not topple, for limiting condition. N should pass through A. The torque about A must be
zero.
pqafd ;g iyVrk ugha gS] lhekUr fLFkfr ds fy, N, A ls xqtjsxkA A ifjr% cyk?kw.kZ 'kwU; gksxkA
R 2R 2  2
 tan  =  h= = m
h/2 ta n  4 /3

30. A uniform rod AB of length 4m and mass 12 kg is thrown such that just after the projection the centre of
mass of the rod moves vertically upwards with a velocity 10 m/s and at the same time it is rotating with an

angular velocity rad/sec about a horizontal axis passing through its mid point. Just after the rod is thrown
2
it is horizontal and is as shown in the figure. If the acceleration (in m/sec2) of the point A in m/s2 when the
centre of mass is at the highest point is x, then find the value of 5x. (Take g = 10m/s2 and 2 = 10)
,d le:i NM+ AB ftldh yEckbZ 4m rFkk nzO;eku 12 kg gS dks bl izdkj Qsadk tkrk gS fd Qsadus ds rqjUr
i'pkr~ NM+ dk nzO;eku dsUnz Å/okZ/kj Åij dh vksj 10 m/s osx ls rFkk blh le; e/; fcUnq ls ikfjr {kSfrt v{k

ds lkis{k jsfM;u/lsd.M dks.kh; osx ls ?kw.kZu xfr djrh gSA NM+ dks Qsadus ds rqjUr i'pkr~ ;g {kSfrt voLFkk esa
2

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gS rFkk fp=k esa iznf'kZr gSA ;fn tc nzO;eku dsUnz mPpre fcUnq ij gks rc fcUnq A dk Roj.k (m/sec2 esa) x gS rks 5x
dk eku Kkr djksA (g = 10m/s2 rFkk 2 = 10)

Ans. 25
Sol. Time in which C.M. reaches its highest point = 1 sec. (from v = u + at, putting v = 0, u = +10, a = 10
m/sec2) after projection angular velocity will not change as the torque of external forces is zero.

In 1 sec., the rod will rotate by an angle = t = × 1 rad.
2
The rod will be vertical with point A at the lowest point.
2
 4
 aA = g – 2L/2 = 10 – = 5 m/sec2 .
42
gy og le; tc nzO;eku dsUnz mPpre fcUnq ij gS = 1 sec. (v = u + at ls v = 0, u = +10, a = 10 m/sec2 j[kus ij)
Qsadus ds i'pkr~ dks.kh; osx ugha cnyrk gS] D;ksafd cká cyksa dk cyk?kw.kZ 'kwU; gSA

1 lsd.M esa NM+ }kjk ?kqek x;k dks.k = t = × 1 rad.
2
NM+ Å/okZ/kj gksxh rFkk fcUnq A fuEure fLFkfr esa gksxkA
2
 4
 aA = g – 2L/2 = 10 – = 5 m/sec2 .
42

31. In the figure shown a thin light inextensible string is wrapped around a uniform disc. One end of the
string is fixed to the ceiling of the lift and the other end is fixed to the circumference of the disc.
Acceleration ‘a’ of the lift in such that the centre of disc does not move with respect to ground. Find the
a
value of . String does not slip on pulley.
g

iznf'kZr fp=k esa ,d iryh gYdh vforkU; Mksjh ,d leku pdrh ds pkjksa vksj fyiVh gqbZ gSA Mksjh dk ,d fljk
fy¶V dh Nr ls tqM+k gqvk gS rFkk nqljk fljk pdrh dh ifj/kh ij fLFkj gSA fy¶V dk Roj.k ‘a’ bl izdkj gS fd
a
pdrh dk dsUnz /kjkry ds lkis{k xfr ugha djrk gSA dk eku Kkr djksA Mksjh f?kjuh ij fQlyrh ugh gSA
g
a

Ans. 02
T

A
Sol. mg

acm = 0
aA = a =  . R ...(i)
T – mg = 0 ...(ii)
2
mR
T.R = . ....(iii)
2
a
 g= Ans. 2
2

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32. A constant force F is acting on the block of mass m = 2 kg which is moving vertically upward under
gravity. At time t = 0 upward velocity is 3 m/sec and at time t = 3 sec upward velocity becomes 6 m/sec.
Acceleration due to gravity is g = 10 m/sec2. Find the impulse provided by force F to block for time
interval of 3 seconds.
xq:Ro ds vf/kd Åij xfr'khy m = 2 kg nzO;eku ds CykWd ij fu;r cy F dk;Zjr gSA t = 0 ij Åij dh rjQ osx
3 m/sec rFkk t = 3 sec Åij dh rjQ osx 6 m/sec. gks tkrk gSA xq:Roh; Roj.k g = 10 m/sec2 gSA 3 sec. ds
vUrjky es CykWd dks cy F }kjk fn;k x;k vkosx Kkr djks &

Ans. 66 Ns
Sol. All impulse lHkh vkosx = mv2 – mv1
Ft – mgt = mv2 - mv1
Ft = mgt + mv2 – mv1
= (2) (10) (3) + (2) (6) – (2) (3)
= 60 + 6
Ft = 66 Newton second
= impulse by F }kjk vkosx
SECTION – 3 : (Maximum Marks : 12)
 This section contains TWO (02) paragraphs.
 Based on each paragraph, there will be TWO questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct 
 Marking scheme :
 Full Marks : +3 If ONLY the correct option is chosen.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –1 In all other cases
[kaM 3 : (vf/kdre vad : 12)
 bl [kaM esa nks (02) vuqPNsn gSaA izR;sd vuqPNsn ij nks iz'u gaSA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls dsoy ,d fodYi lgh gSA
 vadu ;kstuk :
 iw.kZ vad % +3 ;fn flQZ lgh fodYi gh pquk x;k gSA
 'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –1 vU; lHkh ifjfLFkfr;ksa esaA

Paragraph for Question Nos. 33 to 34


ç'u 33 ls 34 ds fy, vuqPNsn
Two blocks A and B of masses m and 2m respectively are placed on smooth horizontal floor. They are
connected by a spring. A third block C of mass m moves with velocity v 0 along the line joining A and B
and collide elastically with A, as shown in figure. At a certain instant of time t0 after collision, it is found
that the instantaneous velocities of A and B are the same. Further at this instant the compression of
spring is found to be x0. Then :
nks CykWd A rFkk B ftuds nzO;eku Øe'k% m rFkk 2m gS mudks ,d fpdus {kSfrt rFkk fLFkj Q'kZ ij j[kk tkrk gS
mudks fLizax ls tksM+k tkrk gS rhljk CykWd C tks fd nzO;eku m dk gS mldks v0 osx ls A rFkk B dks tksM+us okyh
js[kk ds vuqfn'k pyk;k tkrk gS rFkk ;g CykWd A ls fp=kkuqlkj izR;kLFk VDdj djrk gSA VDdj ds ckn fdlh le;
t0 ij ;g ik;k tkrk gS fd A o B ds rkR{kf.kd osx leku gS rFkk bl {k.k ij fLizax esa laihMu x0 gSA rc

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33. The common velocity of A and B at time t0 is :
A rFkk B dk le; t0 ij mHk;fu"B osx gS &
(A) v0 (B) v0/2 (C) 3v0/4 (D*) v0/3

34. Maximum compression of the spring is proportional to :


fLizax esa egRre laihMu lekuqikrh gS &
(A*) v0 (B) v02 (C) v03 (D) v0

Sol. Velocity of A just after collision = V0 and velocity of C just after collision = 0
K.E. of system A, B and spring just after collision
VDdj ds Bhd ckn A dk osx = V0 rFkk VDdj ds Bhd ckn C dk osx = 0
VDdj ds Bhd ckn fudk; (A, B o fLizax) dh xfrt Å+tkZ
1
= mv02 + 0 + 0
2
K.E. of system at time t0 (t0 le; ij fudk; dh KE)
C A B
m v0 m 2m

1 1 1
= mv2 + (2m) v2 + kx02
2 2 2
where V is common velocity at time t0
By cons. of energy
le; t0 ij mHk;fu"B osx v gSA ÅtkZ laj{k.k ls
1 1 1
mv02 = mv2 + mv2 + kx02 ............. (1)
2 2 2
By conservation of linear momentum
js[kh; laosx laj{k.k ls
mv0 = mv + 2mv  v = v0/3 ............. (2)
From (1) & (2)
2
1 3m v0 1
mv02 – = kx02
2 2 9 2

1  1 1
mv02 1   = kx02
2  3  2

2 2
2m v 0 2m v 0
= x02 Hence k = 2
3k 3x0

Compression in spring is maximum when both have same velocity


tc fLizax esa laihMu vf/kdre gksxk rc muds osx leku gksaxsA

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Paragraph for Question Nos. 35 to 36
ç'u 35 ls 36 ds fy, vuqPNsn
One end of massless inextensible string of length  is fixed and other end is tied to a small ball of mass
m. The ball is performing a circular motion in vertical plane. At the lowest position, speed of ball is
20 g . Neglect any other forces on the ball except tension and gravitational force. Acceleration due to
gravity is g.
,d Hkkjghu vfoLrj.kh; jLlh ftldh yEckbZ  gS bldk ,d fljk fLFkj tM+or~ gS rFkk nwljs fljs ls ,d NksVh xsan
ftldk nzO;eku m gS dks cka/kk tkrk gSA xsan m/okZ/kj ry esa o`Ùkh; xfr dj jgh gSA lcls fuEure fLFkfr ij xsan dh
pky 2 0 g gSA xsan ij dsoy ruko cy o xq:Rokd"kZ.k cy dks gh fyft;s rFkk nwljs cyksa dk ux.; ekusaA
xq:Rokd"kZ.k ds dkj.k Roj.k g gSA

35. Motion of ball is in nature of


(A) circular motion with constant speed
(B*) circular motion with variable speed
(C) circular motion with constant angular acceleration about centre of the circle.
(D) none of these
xsan dh xfr dh izÑfr gS
(A) fu;r pky ds lkFk o`Ùkh; xfr
(B*) ifjorhZ pky ds lkFk o`Ùkh; xfr
(C) o`Ùk esa dsUnz ds lkis{k fu;r dks.kh; Roj.k ds lkFk o`Ùkh; xfr
(D) buesa ls dksbZ ugha
Sol. As speed of ball is variable, so motion is non uniform circular motion.
pwafd xsan dh pky ifjorhZ gS vr% vleku o`Ùkh; xfr gSA
36. At the highest position of ball, tangential acceleration of ball is -
lcls mPpre fLFkfr ij xsan dk Li'kZ js[kh; Roj.k gksxk -
(A*) 0 (B) g (C) 5 g (D) 16 g
Sol. At the highest position of ball, net tangential force is zero, hence tangential acceleration of ball is zero,
lcls mPpre fLFkfr ij xsan dk Li'kZ js[kh; Roj.k 'kwU; gksxk]

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®

Course : 05JA (ACT-4) Test Date : 12-12-2021


Test Type : (JEE ADVANCED PATTERN) Target Date : 00.00.2021
Paper 1 Time Duration :
Paper 2 Time Duration :
Common with (05JA & 06JA)
SYLLABUS :
Introduction to Chemistry, Atomic Structure, Mole Concept, Gaseous State-1,2 ,
Chemical Equilibrium, Thermodynamics and Thermochemistry(upto reversibleand
irreversiblepricess)
SYLLABUS :
Periodic Table, BIN, Chemical Bonding-1, 2,3 (Upto Back bonding)
ACT-1, ACT-4 | PAPER-1 | PATTERN NO. 10-21
S.No. Subject Nature of Questions No. of Questions Marks Partial Marks Negative Total
1 to 06 MCQ (Partial Marking) 6 4 +1 –2 24
07 to 14 Maths Integer (Double digit) 8 3 - 0 24
15 to 18 Comprehension SCQ (2 Com. × 2 Q.) 4 3 - –1 12
19 to 24 MCQ (Partial Marking) 6 4 +1 –2 24
25 to 32 Physics Integer (Double digit) 8 3 - 0 24
33 to 36 Comprehension SCQ (2 Com. × 2 Q.) 4 3 - –1 12
37 to 42 MCQ (Partial Marking) 6 4 +1 –2 24
43 to 50 Chemistry Integer (Double digit) 8 3 - 0 24
51 to 54 Comprehension SCQ (2 Com. × 2 Q.) 4 3 - –1 12
Total 54 Total 180
ACT-1, ACT-4 | PAPER-2 | PATTERN NO. 10-21
S.No. Subject Nature of Questions No. of Questions Marks Partial Marks Negative Total
1 to 02 Match listing 2 4 - –1 8
03 to 06 Maths MCQ (Partial Marking) 4 4 +1 –1 16
07 to 18 Single digit integer with positive/negati 12 3 - –1 36
19 to 20 Match listing 2 4 - –1 8
21 to 24 Physics MCQ (Partial Marking) 4 4 +1 –1 16
25 to 36 Single digit integer with positive/negati 12 3 - –1 36
37 to 38 Match listing 2 4 - –1 8
39 to 42 Chemistry MCQ (Partial Marking) 4 4 +1 –1 16
43 to 54 Single digit integer with positive/negati 12 3 - –1 36
Total 54 Total 180

PAPER-1
SECTION – 1 : (Maximum Marks : 24)

 This section contains SIX (06) questions.


 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is(are) correct
 For each question, marks will be awarded in one of the following categories :
 Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
 Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
 Partial Marks : +2 If three or more options are correct but ONLY two options are chosen
and both of which are correct.
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and
it is a correct option.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –2 In all other cases.
 For example, in a question, if (A),(B) and (D) are the ONLY three options corresponding to correct
answers, then :
 Choosing ONLY (A),(B) and (D) will get +4 marks
 Choosing ONLY (A) and (B) will get +2 marks
 Choosing ONLY (A) and (D) will get +2 marks
 Choosing ONLY (B) and (D) will get +2 marks
 Choosing ONLY (A) will get +1 marks
 Choosing ONLY (B) will get +1 marks
1
 Choosing ONLY (D) will get +1 marks
 Choosing no option (i.e. the question is unanswered) will get 0 marks, and
 Choosing any other combination of options will get –2 mark

[kaM 1 : (vf/kdre vad : 24)


 bl [kaM esa N% (06) iz'u gSaA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad % +4 ;fn dsoy ¼lkjs½ lgh fodYi ¼fodYiksa½ dks pquk x;k gSA
 vkaf'kd vad % +3 ;fn pkjksa fodYi lgh gSa ijUrq dsoy rhu fodYiksa dks pquk x;k gSA
 vkaf'kd vad % +2 ;fn rhu ;k rhu ls vf/kd fodYi lgh gS ijUrq dsoy nks fodYiksa dks pquk x;k gS vkSj
nksauks pqus gq, fodYi lgh fodYi gSaA
 vkaf'kd vad % +1 ;fn nks ;k nks ls vf/kd fodYi lgh gSa ijUrq dsoy ,d fodYi dks pquk x;k gS vkSj
pquk gqvk fodYi lgh fodYi gSA
 'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –2 vU; lHkh ifjfLFkfr;ksa esaA
 mnkgj.k% ;fn fdlh iz'u ds fy, dsoy fodYi (A),(B) vkSj (D) lgh fodYi gS] rc %
 dsoy fodYi (A),(B) vkSj (D) pquus ij +4 vad feysaxs ’
 dsoy fodYi (A) vkSj (B) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (B) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) pquus ij +1 vad feysaxs ’
 dsoy fodYi (B) pquus ij +1 vad feysaxs ’
 dsoy fodYi (D) pquus ij +1 vad feysaxs ’
 dksbZ Hkh fodYi u pquus ij ¼vFkkZr~ iz'u vuqÙkfjr jgus ij½ 0 vad feysaxs vkSj
 vU; fdlh fodYiksa ds la;kstu dks pquus ij –2 vad feysaxs

37. For the reaction A(g) + B(g) 3C(g), at 25ºC, a 5L rigid vessel contains 4, 2 and 1mol of A, B and
C respectively. The direction of reaction is :
25ºC ij vfHkfØ;k A(g) + B(g) 3C(g), ds fy, 5L ds n`<+ ik=k esa A,B o C ds Øe'k% 4, 2 o 1 eksy gSA
vfHkfØ;k dh fn'kk gksxh&
(A) Forward if KC for the reaction is 10–3 mol lit–1
(B*) Backward if KC for the reaction is 5 × 10–3 mol lit–1
(C) Forward if KC for the reaction is 5 × 10–3 mol lit–1
(D*) Forward if KC for the reaction is 3 × 10–2 mol lit–1
(A) vxzfn'kk ;fn vfHkfØ;k ds fy, KC =10–3 mol lit–1 gSA
(B*) i'pfn'kk ;fn vfHkfØ;k ds fy, KC = 5 × 10–3 mol lit–1 gSA
(C) vxzfn'kk ;fn vfHkfØ;k ds fy, KC = 5 × 10–3 mol lit–1 gSA
(D*) vxzfn'kk ;fn vfHkfØ;k ds fy, KC =3 × 10–2 mol lit–1 gSA
(1/ 5)3 1
Sol. QC =  = 0.025
(4 / 5)(2 / 5) 40

38. The photons corresponding to first line of Balmer series of He + ion are incident on Platinum metal which
has work-function of 6.55 eV. Then, which of the following is/are correct?
(A) Platinum does not emit photoelectrons.
(B*) Photoelectric effect is observed.
(C*) The KE of fastest moving photoelectrons is about 1 eV.
(D*) The minimum de-Broglie wavelength of emitted photoelectrons is about 12.3 Å

2
He+ vk;u dh ckej Js.kh dh izFke js[kk ls lEcfU/kr QksVkWu IysfVue /kkrq] tks 6.55 eV dk;Z Qyu j[krh gS] ij
vkifrr gksrs gS] rc fuEu esa ls dkSulk@dkSuls lgh gS@gSa \
(A) IysfVue izdk'k bysDVªkWu mRlftZr ugha djrk gSA
(B*) izdk'k bysfDVªd izHkko izsf{kr gksrk gSA
(C*) rhoz xfr'khy izdk'k bysDVªkWuksa dh KE yxHkx 1 eV gSA
(D*) mRlftZr izdk'k bysDVªkWuksa dh U;wure Mh&czksXyh rjaxnS/;Z 12.3 Å gSA
Sol. Energy of photons = 13.6 eV × 4 × {1/4 – 1/9} = 7.55 eV, which is greater than work function of
Platinum. Thus, photoelectrons are emitted with KEmax = 7.55 – 6.55 = 1 eV.
12.3
The MINIMUM de-Broglie wavelength of such electrons is Å =
V
QksVkWuksa dh ÅtkZ = 13.6 eV × 4 × {1/4 – 1/9} = 7.55 eV, tks IysfVue ds dk;ZQyu ls vf/kd gksrh gSA bl izdkj
KEmax = 7.55 – 6.55 = 1 eV ds lkFk izdk'k bysDVªkWu mRlftZr gksrs gSaA
12.3
bl izdkj ds bysDVªkWuks dh U;wure Mh&czksXyh rjaxnS/;Z Å = gSA
V

39. Which of the following statement(s) is/are correct for real gas ?
fuEu es ls dkSulk@dkSuls dFku okLrfod xSl ds fy, lgh gS@gSa\
(A*) lim(PVm ) = constant, at constant high temperature
p0

(B*) In general low pressure region attractive forces are dominating


(C*) Real gas shows maximum deviation at high pressure and low temperature
(D*) In general for hydrogen gas 'b' dominates over 'a'
(A*) lim(PVm ) = fu;r] mPp fu;r rki ij
p0

(B*) lkekU; :i es] U;wu nkc {kS=k es vkd"kZ.k cy izHkkoh gksrs gSA
(C*) okLrfod xSl mPp nkc rFkk U;wu rki ij vf/kdre fopyu n'kkZrh gSA
(D*) lkekU; :i es gkbMªkstu xSl ds fy, 'b', 'a' ij izHkkoh gksrk gSA
Sol. Theory based

40. The element(s) which can shows both positive & negative oxidation state is -
fuEu esa ls dkSulk@dkSuls rRo /kukRed vkSj _.kkRed nksuksa vkWDlhdj.k voLFkk n'kkZrk gS@gSa \
(A*) I (B) Mg (C) He (D*) H
Sol. Refer notes.
uksV~l ns[ksaA

41. Which of the following is/are correct for the formation of  bond ?
(A*) overlapping of px-px (Z internuclear axis)
(B*) overlapping of py-py orbitals (Z internuclear axis)
(C) overlapping of dyz-dyz orbitals (X internuclear axis)
(D*) overlapping of dxy-dxy orbitals (X internuclear axis)
fuEu esa ls dkSulk@dkSuls  ca/k ds fuekZ.k ds fy, lgh gS@gSa \
(A*) px-px dk vfrO;kiu (Z vUrjukfHkdh; v{k)
(B*) py-py d{kdks dk vfrO;kiu (Z vUrjukfHkdh; v{k)
(C) dyz-dyz d{kdks dk vfrO;kiu (X vUrjukfHkdh; v{k)
(D*) dxy-dxy d{kdks dk vfrO;kiu (X vUrjukfHkdh; v{k)
Sol. (D) overlapping of dyz-dyz orbitals (X internuclear axis) gives bond.
dyz-dyz d{kdks dk vfrO;kiu (X vUrjukfHkdh; v{k) ca/k nsrk gSA

42. Which of the following statements is/are correct ?


(A*) Chlorine atom has highest Heg –ve value in periodic table.
(B) Chlorine atom is highest electronegative atom in periodic table.
(C*) Electron gain enthalpy of A+ ion is equal to IE1 of A atom (with opposite sign)
(D) IE1 of Zn is less then Cu.

3
fuEu esa ls dkSuls@dkSulk dFku lgh gS@gSa \
(A*) vkorZ lkj.kh esa Dyksjhu ijek.kq dh mPpre Heg –ve bysDVªkWu xzg.k djus dh m"ek gSA
(B) vkorZ lkj.kh esa Dyksjhu ijek.kq dh mPpre fo|qr_.krk gSA
(C*) A+ /kuk;u dh bysDVªkWu xzg.k djus dh m"ek A ijek.kq ds IE1 ds cjkcj gksrh gS ¼–ve½A
(D) Zn dk IE1 Cu ls de gSA
Sol. It is fact.

SECTION – 2 : (Maximum Marks : 24)


 This section contains EIGHT (08) questions
 The answer to each question is a DOUBLE DIGIT INTEGER ranging from 00 to 99, both inclusive
 Marking scheme :
 Full Marks : +3 If ONLY the correct option is chosen.
 Zero Marks : 0 In all other cases
[kaM 2 : (vf/kdre vad : 24)
 bl [kaM esa vkB (08) iz'u gSaA
 izR;sd iz'u dk mÙkj 00 ls 99 rd, nksuksa 'kkfey] ds chp dk ,d f} vadh; iw.kk±d gSA
 vadu ;kstuk :
 iw.kZ vad % +3 ;fn flQZ lgh fodYi gh pquk x;k gSA
 'kwU; vad % 0 vU; lHkh ifjfLFkfr;ksa esaA

43. In n2 n1 transition in Li+2 will have the same wavelength as that of n = 4 to n = 2 transition in
Hydrogen. Determine value of (n2 + n1).
Li+2 esa n2 n1 laØe.k] gkbMªkstu esa n = 4 ls n = 2 rd laØe.k ds leku rjax)S/;Z j[krk gSA (n2 + n1) dk eku
Kkr djksA
Ans. 18
Sol. In Li+2 n = 12 to n = 6 will have the same wavelength as that of n = 4 to n = 2 in hydrogen.
Li+2 esa n = 12 ls n = 6 dh rjax}S/;Z gkbMªkstu esa n = 4 ls n = 2 ds leku gksxhA

44. Mr. Santa has to decode a number "ABCDEF" where each alphabet is represented by a single digit.
Suppose an orbital whose radial wave function is represented as
(r)  k1.er / k2 (r 2  5k 3r  6k 32 )
From the following information given about each alphabet then write down the value of
{(A × D) + (B + C + E + F)} where each alphabet corresponds to a value.
Info A = Value of n where "n" is principal quantum number
Info B = No. of angular nodes
Info C = Azimuthal quantum number of subshell to which orbital belongs
Info D = No. of subshells having energy between (n + 5)s to (n + 5)p where n is principal quantum
number
Info E = Orbital angular momentum of given orbital.
Info F = Radial distance of the spherical node which is farthest from the nucleus
(Assuming: k3 = 1)
Jheku lUrk dks la[;k "ABCDEF" ds dwV [kksyus gS (to decode) tgk¡ izR;sd v{kj dks ,dy la[;k ds }kjk
iznf'kZr fd;k tkrk gSA ekuk ,d d{kd gS ftldk f=kT;h; rjax Qyu fuEu izdkj iznf'kZr gS&
(r)  k1.er / k2 (r 2  5k 3r  6k 32 )
izR;sd v{kj ds ckjs esa fuEu lwpuk nh x;h gS rc {(A × D) + (B + C + E + F)} dk eku fyf[k;sA tgk¡ izR;sd v{kj
,d eku ls lEcfU/kr gSA
lwpuk A = "n" dk eku tgk¡ "n" eq[; dok.Ve la[;k gSA
lwpuk B = dks.kh; uksM+ksa dh la[;k
lwpuk C = lEcfU/kr d{kd ds midks'k dh f}xa'kh Dok.Ve la[;k
lwpuk D = (n + 5)s o (n + 5)p ds e/; ÅtkZ j[kus okys midks'kksa dh la[;k tgk¡ n eq[; Dok.Ve la[;k gSA
lwpuk E = fn;s x;s d{kd dk d{kd dks.kh; laosx
lwpuk F = xksyh; uksM+ tks ukfHkd ls lcls nwj gS] dh f=kT;h; nwjh ( k3 = 1 ekurs gq,)
Ans. 12.00
4
Sol. Orbital is 3s because no rterm   = 0 & polynomial is of order 2  n –  – 1 = 2 or n = 3
(A = 3, B = 0, C = 0, D = 3, E = 0, F = 3)
Sol. d{kd 3s ls gS D;ksafd dksbZ rin ugha gS   = 0 o cgqin 2 dksfV dk gS  n –  – 1 = 2 or n = 3
(A = 3, B = 0, C = 0, D = 3, E = 0, F = 3)

45. Human lungs can absorb 9 gm O2 per hour. If all oxygen atoms are converted to carbohydrates
(C6H12O6), How long (in hour) will it take to produce 540g C6H12O6 ?
ekuo QsQMs 9 xzke O2 izfr ?kaVs vo'kksf"kr dj ldrs gSaA ;fn lHkh vkWDlhtu ijek.kqvks a dks dkcksZgkbMªsV (C6H12O6)
esa ifjofrZr fd;k tkrk gS] rks 540 g C6H12O6 cukus ds fy, fdruk le; ¼?k.Vs esa½ yxsxk \
Ans. 32
Sol.
O2  C6H12O6
Applying POAC for oxygen
vkWDlhtu ds fy, POAC iz;qDr djus ij]
540
2  nO2 = 6 
180
nO2 = 9 mole
9  32
time taken = = 32 hour
9
9  32
iz;qDr le; = = 32 hour
9

46. Equal volumes of two gases, which do not react together, are enclosed in separate vessels. Their
pressures are 100 mm of Hg and 40 mm of Hg respectively. If the two vessels are joined together, then
what will be the pressure of the resulting mixture (in mm of Hg) (temperature remaining constant) :
nks xSlsa] tks fd i`Fkd ik=k esa gSa rFkk os ,d lkFk vfHkfØ;k ugha djrh] mudk leku vk;ru] Øe'k% 100 mm of Hg
rFkk 40 mm of Hg dk nkc j[krk gSA ;fn nksuksa ik=kksa dks ,d lkFk tksM+ fn;k tk,] rc ifj.kkeh feJ.k dk nkc
D;k gksxk % (mm of Hg esa) ¼rki dks fu;r ekuas½
Ans. 70
Sol. Let, vol of containers be V & temp be T
ekuk fd ik=k dk vk;ru V gS rFkk rkieku T gS
P1 = 100 mm P2 = 400mm
P1V P2 V
n1 = & n2 =
RT RT
(P  P2 )  V
n1 + n2 = 1
RT
After joining two containers final vol = (V+V) = 2V(for gases)
ik=kksa dks tksMus ds i'pkr~ vfUre vk;ru = (V+V) = 2V(xSlksa ds fy,)
n1  n2  RT (P1  P2 )  V RT P1  P2  (100  40) mm
Pfinal = = × = = = 70 mm
Vfinal RT 2V 2 2

47. How many total number of unshared electrons pairs are present in a Lewis dot structure of perxenate
ion (XeO64–) :
ijftusV vk;u (XeO64–) dh yqbZl fcUnq lajpuk esa vlk¡f>r bysDVªkWu ;qXeksa dh dqy fdruh la[;k mifLFkr gS \
Ans. 16
Sol. 16 lone pairs, hence 32 unshared electrons.
16 ,dkdh ;qXe, blfy, 32 vlk¡f>r bysDVªkWu

5
48. The total number of orbitals involved in the overlapping in XeO 2F4?
XeO2F4 esa vfrO;kiu esa Hkkx ysus okys d{kdks dh dqy la[;k gS \
Ans. 16
Sol. Total no. of  bonds = 6
Total no. of  bonds = 2
total no. of bonds= 6+2 = 8
No. of orbitals involved= 2*8=16
Sol. dqy  ca/k = 6
dqy  ca/k = 2
dqy ca/kks dh la[;k = 6+2 = 8
fufgr d{kdksa dh la[;k = 2*8=16

49. In which of the following all bond length are not equal ?
(a) PCl5 (b) SF4 (c) ClF3 (d) XeF2
(e) [SF5]+ (f) [ClF4]+ (g) [XeF3]+ (h) O3
(i) P4 (white)
fuEu esa ls fdu Lih'kht esa lHkh ca/k yEckbZ;k¡ cjkcj ugha gS \
(a) PCl5 (b) SF4 (c) ClF3 (d) XeF2
(e) [SF5]+ (f) [ClF4]+ (g) [XeF3]+ (h) O3
(i) ('osr)
Ans. 06 (a, b, c, e, f, g)
Sol. PCl5, SF4, ClF3, [SF5]+, [ClF4]+, [XeF3]+.
PCl5  sp3d
SF4 
ClF3 sp3d   [XeF2 sp3d 
 [SF5] sp d 
+ 3

 [ClF4]+  sp3d
[XeF3]+ sp3d

50. The number of S–S bonds in sulphur trioxide trimer (S3O9) is :


lYQj Vªkb vkWDlkbM f=kyd (S3O9) esa S–S ca/k dh la[;k gS %
Ans. 00

Sol.

SECTION – 3 : (Maximum Marks : 12)


 This section contains TWO (02) paragraphs.
 Based on each paragraph, there will be TWO questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct 
 Marking scheme :
 Full Marks : +3 If ONLY the correct option is chosen.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –1 In all other cases

[kaM 3 : (vf/kdre vad : 12)


 bl [kaM esa nks (02) vuqPNsn gSaA izR;sd vuqPNsn ij nks iz'u gaSA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls dsoy ,d fodYi lgh gSA
 vadu ;kstuk :
 iw.kZ vad % +3 ;fn flQZ lgh fodYi gh pquk x;k gSA
 'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –1 vU; lHkh ifjfLFkfr;ksa esaA

6
Paragraph for Question Nos. 51 to 52
iz'u 51 ls 52 ds fy, vuqPNsn
SO3 gas is taken in a container of constant volume. It dissociates to give SO 2 and O2. The observed
molar mass of the mixture is 64 g/mol. On this basis, answer the following questions
[(2SO3(g) 2SO2(g) + O2(g)].
,d fu;r vk;ru ds ,d ik=k esa SO3 xSl dks fy;k tkrk gSA ;g fo;ksftr gksdj SO2 o O2 nsrh gSA feJ.k dk
izsf{kr eksyj nzO;eku 64 g/mol gSA bl vk/kkj ij fuEu iz'uksa ds mÙkj nhft, [(2SO3(g) 2SO2(g) +
O2(g)]A

51. The degree of dissociation of SO3 is :


SO3 ds fy, fo;kstu dh ek=kk fuEu gS &
1 1 1 1
(A) (B*) (C) (D)
4 2 8 5

52. Select the correct option(s) :


lgh fodYi@fodYiksa dk p;u dhft;s&
 1
(A*) Mole fraction of SO2 in the mixture is (B) Mole fraction of SO3 in the mixture is
5 5
1 4
(C) Mole fraction of SO2 in the mixture is (D) Mole fraction of SO3 in the mixture is
5 5

lgh fodYi@fodYiksa dk p;u dhft;s&


 1
(A*) feJ.k esa SO2 dk eksy&fHkUu gSA (B*) feJ.k esa SO3 dk eksy&fHkUu gSA
5 5
1 4
(C) feJ.k esa SO2 dk eksy&fHkUu gSA (D) feJ.k esa SO3 dk eksy&fHkUu gSA
5 5
Sol. 2SO3 2SO2 + O2
M M
= 1 + (n – 1)
MObs. Mizsf{kr
80 3 
 = 1 +   1 
64 2 
5 
 =1+
4 2
If initially a moles of SO3 are taken
;fn izkjEHk esa a eksy SO3 fy;k tkrk gSA
1
nSO3 = a(1 – ) = a ×
2
 3    1 5a
nT = a  1    1   = a  1   =
 2    4 4
1
nSO2 = a = a ×
2
2 2 1
 XSO3 = , XSO2 = , XO2 =
5 5 5

7
Paragraph for Question Nos. 53 to 54
iz'u 53 ls 54 ds fy, vuqPNsn
Answer 53 and 54 by appropriately matching the information given in the three columns of the
following table.
Observe the three columns in which column-1:compound, column-2 : shape while in column-3 :
Hybridisation are given.
Column-1 (Compound) Column-2 (Shape) Column-3 (Hybridisation)
(I) XeF4 (i) Tetrahedral (P) sp3
(II) ClF3 (ii) Square planar (Q) sp2
(III) SiF4 (iii) Bent (R) sp3d
(IV) CH3OCH3 (iv) T-shape (S) sp3d2
fuEu lkj.kh ds rhu dkWye es nh xbZ lwpuk ds mfpr lqesy }kjk 53, vkSj 54 ds mÙkj nhft,A
rhu dkWyeksa dk voyksdu dhft;s ftlesa dkWye-1 : ;kSfxd] dkWye-2 : vkÑfr tcfd dkWye-3 : ladj.k fn;s x;s gSaA
dkWye-1 (;kSfxd) dkWye-2 (vkÑfr) dkWye-3 (ladj.k)
(I) XeF4 (i) prq"Qydh; (P) sp3
(II) ClF3 (ii) oxZ leryh; (Q) sp2
(III) SiF4 (iii) cs U V ¼eq M + h gq b Z ½ (R) sp3d
(IV) CH3OCH3 (iv) T-vkÑfr (S) sp3d2

53. Which of the following combination is true for compound which have 2 lone pair of electrons on central
atom?
;kSfxd tks fd dsUnzh; ijek.kq ij 2 ,dkdh bysDVªkWu ;qXe j[krk gS ds fy, fuEu esa ls dkSulk la;kstu lR; gS \
(A*) (I), (ii), (S) (B) (I), (ii), (R) (C) (I), (i), (P) (D) (II), (iv), (Q)

Sol. XeF4 2 lone pair on central atom square planar sp3d2


dsUnzh; ijek.kq ij 2 ,dkdh ;qXe oxZ leryh; sp3d2

54. Which combination is correct for the compound having bond angle > 109º28' ?
;kSfxd ftlesa ca/k dks.k > 109º28' ds fy, lgh la;kstu gS ?
(A) (III), (i), (P) (B*) (IV), (iii), (P) (C) (IV), (ii), (P) (D) (I), (ii), (S)

Sol. CH3–O–CH3 O 2 lone pair on central atom bent sp3


H3C CH3
dsUnzh; ijek.kq ij 2 ,dkdh ;qXe csUV ¼eqM+h gqbZ½ sp3

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