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P07-21

DATE ®
02-01-2022

ADVANCED PATTERN PART TEST-4 (APT-4)


PAPER

2
TARGET : JEE (MAIN + ADVANCED) 2023

COURSE : VIKAAS (JA) | BATCH : 05JA & 06JA

Time : 3 Hours Maximum Marks : 180


CODE

1 Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

INSTRUCTIONS TO CANDIDATES

 Question Paper-2 has three (03) parts: Mathematics, Physics and Chemistry.
 Each part has a total eighteen(18) questions divided into two(02) sections (Section-1 and Section-2).
 Total number of questions in Question Paper-2 are Fifty Four(54) and Maximum Marks are One Hundred Eighty (180).
TYPE OF QUESTIONS AND MARKING SCHEMES
SECTION-1 (Maximum Marks : 36)

 This section contains TWELVE (12) questions. The answer to each question is NUMERICAL VALUE with two digit integer
and decimal upto two digit.
 If the numerical value has more than two decimal places truncate/round-off the value to TWO decimal placed.
 Marking scheme :
 Full Marks : +3 If ONLY the correct numerical value is entered as answer.
 Zero Marks : 0 In all other cases
SECTION-2 : (Maximum Marks : 24)
 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct
 For each question, marks will be awarded in one of the following categories :
 Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
 Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
 Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and both of which are
correct.
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –2 In all other cases
 For example, in a question, if (A),(B) and (D) are the ONLY three options corresponding to correct answers, then :
 Choosing ONLY (A),(B) and (D) will get +4 marks
 Choosing ONLY (A) and (B) will get +2 marks
 Choosing ONLY (A) and (D) will get +2 marks
 Choosing ONLY (B) and (D) will get +2 marks
 Choosing ONLY (A) will get +1 marks
 Choosing ONLY (B) will get +1 marks
 Choosing ONLY (D) will get +1 marks
 Choosing no option (i.e. the question is unanswered) will get 0 marks, and
 Choosing any other combination of options will get –2 mark

NAME OF THE CANDIDATE : ………………………………………………… ROLL NO. :………………..………………………..

I have read all the instructions I have verified the identity, name and roll number
and shall abide by them of the candidate.
------------------------- -------------------------
Signature of the Candidate Signature of the Invigilator

Resonance Eduventures Limited


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INSTRUCTIONS FOR OPTICAL RESPONSE SHEET (ORS)
 Darken the appropriate bubbles on the original by applying sufficient pressure.
 The original is machine-gradable and will be collected by the invigilator at the end of the examination.
 Do not tamper with or mutilate the ORS.
 Write your name, roll number and the name of the examination centre and sign with pen in the space provided for this
purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble under each
digit of your roll number.

DARKENING THE BUBBLES ON THE ORS :


 Use a BLACK BALL POINT to darken the bubbles in the upper sheet.
 Darken the bubble COMPLETELY.
 Darken the bubble ONLY if you are sure of the answer.
 The correct way of darkening a bubble is as shown here :
 There is NO way to erase or "un-darkened bubble.
 The marking scheme given at the beginning of each section gives details of how darkened and not darkened bubbles
are evaluated.
 Zero marks ‘0’ If none of the options is chosen (i.e. the question is unanswered).

FOR INTEGER TYPE QUESTIONS OMR LOOKS LIKE :


 For example, if answer ‘SINGLE DIGIT’ integer type below :
0 1 2 3 4 5 6 7 8 9
 For example, if answer ‘SINGLE DIGIT’ integer with positive / negative type below :
0
– 1
2
3
4
5
6
7
8
9
 For example, if answer ‘DOUBLEDIGIT’ integer type below :
0 0
1 1
2 2
3 3
4 4
5 5
6 6
7 7
8 8
9 9
FOR DECIMAL TYPE QUESTIONS OMR LOOKS LIKE :
COLUMN
1 2 . 3 4
0 0 0 0
1 1 1 1
2 2 2 2
3 3 3 3
4 4 4 4
5 5 5 5
6 6 6 6
7 7 7 7
8 8 8 8
9 9 9 9
 If answer is 3.7, then fill 3 in either 1st or 2nd column and 7 in 3rd or 4th column.
 If answer is 3.07 then fill 3 in 1st or 2nd column ‘0’ in 3rd column and 7 in 4th column.
 If answer is, 23 then fill 2 & 3 in 1st and 2nd column respectively, while you can either leave column 3 & 4 or fill ‘0’ in either
of them.

Resonance Eduventures Limited


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MATHEMATICS
PART : I MATHEMATICS

MATHEMATICS
SECTION – 1 : (Maximum Marks : 36)
 This section contains TWELVE (12) questions. The answer to each question is NUMERICAL VALUE

S
with two digit integer and decimal upto two digit.
 If the numerical value has more than two decimal places truncate/round-off the value to TWO
decimal placed.
 Marking scheme :
 Full Marks : +3 If ONLY the correct numerical value is entered as answer.
 Zero Marks : 0 In all other cases
[kaM 1 ¼vf/kdre vad% 36)
 bl [kaM esa ckjg (12) iz'u gSA izR;sd iz'u dk mÙkj la[;kRed eku (NUMERICAL VALUE) gSa]tks f}&vadh;
iw.kkZad rFkk n'keyo f}&vadu eas gSA
 ;fn la[;kRed eku esa nks ls vf/kd n’'keyo LFkku gS ] rks la[;kRed eku dks n'keyo ds nks LFkkuksa rd
VªadsV@jkmaM vkWQ (truncate/round-off) djsaA
 vadu ;kstuk %&
 iw.kZ vad % +3 ;fn flQZ lgh la[;kRed eku (Numerical value) gh mÙkj Lo:i ntZ fd;k x;k gSA
 'kwU; vad % 0 vU; lHkh ifjfLFkfr;ksa esa

2
12| 4
1. Number of solutions of 2|x  ee|x|log
|x| logee 4
is

2
12| 4
lehdj.k 2|x  ee|x|log
|x| logee 4
ds gyksa dh la[;k gS -

Space for Rough Work (dPps dk;Z ds fy, LFkku)

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MATHEMATICS
2. Let <an> is an infinite geometric sequence with first term 2 cot x and common ratio sin2 x and

MATHEMATICS
<bn> is an infinite geometric sequence with first term sin 2x and common ratio sin2 x . If
 
 
x   0,  , then the minimum value of
 4  ai  b j is

S
i1 j1

ekuk <an> vuUr xq.kksÙkj vuqØe gS ftldk izFke in 2cotx gS rFkk lkoZvuqikr sin2 x rFkk <bn> vuUr

xq.kksÙkj vuqØe gS ftldk izFke in sin 2x gS rFkk lkoZvuqikr sin2 x gSA ;fn x   0,  , rc
 4 
 

a  b
i1
i
j1
j dk U;wure eku gS&

3. If x4 + 3cos(ax2 + bx + c) = 2(x2 – 2) has two solutions with a, b, c  (2, 5), then the maximum value of
ac
b2
ac
;fn x4 + 3cos(ax2 + bx + c) = 2(x2 – 2) ds nks gy gS tgk¡ a, b, c  (2, 5) rc dk vf/kdre eku gS -
b2

Let N  3  5  9 where n1, n2, n3  [1, 9]. Then number of ways of selecting the values of n1,
n1 n2 n3
4.
n2, n3
so that N is divisible by 4 is:

ekuk N  3 1  5 2  9 3 tgka n1, n2, n3  [1, 9] rc n1, n2, n3 ds ekuksa dks pquus okys Øep;ksa dh la[;k gksxh
n n n

tcfd N, 4 ls foHkkftr gS&

Space for Rough Work (dPps dk;Z ds fy, LFkku)

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MATHEMATICS
(2009)a
If 2b = |b – 1| + |b + 1| and = (2009) log a2010 a, b  R such that

MATHEMATICS
5.
2010

logba = logbp1 + logbp2 + logbp3 + logbp4,

S
logp b logp b logp b logp b
where p1 < p2 < p3 < p4 are prime numbers, then the value of 4 1
+ 25 3
+ 9 2
+ 67 4
is

(2009)a
;fn 2b = |b – 1| + |b + 1| vkSj = (2009) loga 2010 a, b  R bl izdkj gS fd logba = logbp1 + logbp2 +
2010
logp b logp b logp b logp b
logbp3 + logbp4, tgk¡ p1 < p2 < p3 < p4 vHkkT; la[;k,a gS] rc 4 1
+ 25 3
+ 9 2
+ 67 4
dk
eku gS&

6. Among the 8! permutations of the digits 1, 2, 3, ……, 8; number of arrangements in which product
of any five consecutive digits is divisible by 5 is 2.K! then K + 2 =

vad 1, 2, 3, ……, 8 ds vadksa ls 8! Øep; esa ls foU;klksa dh la[;k 2.K! gS ftlesa fdlh ikap Øekxr vadksa
dk xq.kuQy 5 ls foHkkftr gS] rc K + 2 =

8
1 
7. The term independent of x in the expansion of  x1/ 3  x –1/ 5  is
2 

O;tad  x1/ 3  x –1/ 5  esa x ls Lora=k in gS&


1
2 

Space for Rough Work (dPps dk;Z ds fy, LFkku)

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MATHEMATICS
102013 – 1

MATHEMATICS
8. The digit in unit place of number is
1033 – 1

102013 – 1

S
la[;k ds bdkbZ LFkku dk vad gS&
1033 – 1

9. The coefficient of x5 in (1 – x – x2 + x3)6 is

(1 – x – x2 + x3)6 ds izlkj esa x5 xq.kkad gS -

10. Let q be a positive integer and q  50. If the

sum 98 C30  2.97 C30  3.96 C30  4.95 C30  ...  69 30C30  100 Cq

Find the sum of the digits of q.

ekuk q /kukRed iw.kkZad gS rFkk q  50 ;fn ;ksxQy

C30  2.97 C30  3.96 C30  4.95 C30  ...  69 C30  Cq


30 100
98
rc q ds vadks dk ;ksxQy Kkr dhft,A

Space for Rough Work (dPps dk;Z ds fy, LFkku)

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MATHEMATICS
11. The number of ways of seven digit number with distinct digits of the form a 1 a2 a3 a4 a5 a6 a7,

MATHEMATICS
(ai  0 i  1,2,...,7) be present in decimal system, such that a1  a2  a3  a4  a5  a6  a7 is

S

then value of is
10

n'keyo i)fr esa a1 a2 a3 a4 a5 a6 a7, (ai  0 i  1,2,...,7) :i dh lkr fHkUu-fHkUu vadks dh la[;kvksa dh


la[;k tcfd a1 < a2 < a3 < a4 > a5 > a6 > a7 gks]  gS rc dk eku gS&
10

12. The number of ways of arranging letters of the word 'HAVANA' so that V and N do not appear together

is:

'kCn 'HAVANA' ds v{kjksa dks O;ofLFkr djus ds rjhds gksxsa tcfd V vkSj N ,d lkFk ugha vkrs gks&

Space for Rough Work (dPps dk;Z ds fy, LFkku)

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MATHEMATICS

MATHEMATICS
SECTION – 2 : (Maximum Marks : 24)
 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four

S
option(s) is(are) correct
 For each question, marks will be awarded in one of the following categories :
 Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
 Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
 Partial Marks : +2 If three or more options are correct but ONLY two options are chosen
and both of which are correct.
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and
it is a correct option.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –2 In all other cases.
 For example, in a question, if (A),(B) and (D) are the ONLY three options corresponding to correct
answers, then :
 Choosing ONLY (A),(B) and (D) will get +4 marks
 Choosing ONLY (A) and (B) will get +2 marks
 Choosing ONLY (A) and (D) will get +2 marks
 Choosing ONLY (B) and (D) will get +2 marks
 Choosing ONLY (A) will get +1 marks
 Choosing ONLY (B) will get +1 marks
 Choosing ONLY (D) will get +1 marks
 Choosing no option (i.e. the question is unanswered) will get 0 marks, and
 Choosing any other combination of options will get –2 mark

Space for Rough Work (dPps dk;Z ds fy, LFkku)

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MATHEMATICS
[kaM 2 : (vf/kdre vad : 24)

MATHEMATICS
 bl [kaM esa N% (06) iz'u gSaA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA

S
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad % +4 ;fn dsoy ¼lkjs½ lgh fodYi ¼fodYiksa½ dks pquk x;k gSA
 vkaf'kd vad % +3 ;fn pkjksa fodYi lgh gSa ijUrq dsoy rhu fodYiksa dks pquk x;k gSA
 vkaf'kd vad % +2 ;fn rhu ;k rhu ls vf/kd fodYi lgh gS ijUrq dsoy nks fodYiksa dks pquk x;k gS vkSj
nksauks pqus gq, fodYi lgh fodYi gSaA
 vkaf'kd vad % +1 ;fn nks ;k nks ls vf/kd fodYi lgh gSa ijUrq dsoy ,d fodYi dks pquk
x;k gS vkSj pquk gqvk fodYi lgh fodYi gSA
 'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –2 vU; lHkh ifjfLFkfr;ksa esaA
 mnkgj.k% ;fn fdlh iz'u ds fy, dsoy fodYi (A),(B) vkSj (D) lgh fodYi gS] rc %
 dsoy fodYi (A),(B) vkSj (D) pquus ij +4 vad feysaxs ’
 dsoy fodYi (A) vkSj (B) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (B) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) pquus ij +1 vad feysaxs ’
 dsoy fodYi (B) pquus ij +1 vad feysaxs ’
 dsoy fodYi (D) pquus ij +1 vad feysaxs ’
 dksbZ Hkh fodYi u pquus ij ¼vFkkZr~ iz'u vuqÙkfjr jgus ij½ 0 vad feysaxs vkSj
 vU; fdlh fodYiksa ds la;kstu dks pquus ij –2 vad feysaxs

Space for Rough Work (dPps dk;Z ds fy, LFkku)

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MATHEMATICS

MATHEMATICS
13. If Sr  r  r  r  r  .... , r  0, then which of the following is/are correct.

(A) S2, S6 , S12, S20 are in A.P. (B) S4 , S9 , S16 are irrational

S
(C) (2S3  1)2,(2S4  1)2,(2S5  1)2 are in A.P. (D) S2, S12, S56 are in G.P.

;fn Sr  r  r  r  r  .... , r  0, rc fuEu esa ls dkSuls lgh gS ?

(A) S2, S6 , S12, S20 lekUrj Js<h esa gSA (B) S4 , S9 , S16 vifjes; gSA
(C) (2S3  1)2,(2S4  1)2,(2S5  1)2 lekUrj Js<h esa gSA (D) S2, S12, S56 xq.kksÙkj Js<h esa gSA

 
2n1
14. If n is positive integer and 3 3  5     where  is an integer and 0    1, then

(A)  is an even integer (B)      is divisible by 22n2


2

 
2n1
(C) The integer just below 3 3  5 divisible by 3 (D)  is divisible by 10

;fn n /kukRed iw.kk±d gS rFkk  3 3  5


2n1
    tgk¡  iw.kk±d gS rFkk 0    1, rc

(A)  (B)      , 22n2 ls


2
le iw.kk±d gSA foHkkftr gSA

3 
2n1
(C) 3 5 ls de iw.kk±d eku] 3 ls foHkkftr gSA (D)  , 10 ls foHkkftr gSA

Space for Rough Work (dPps dk;Z ds fy, LFkku)

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MATHEMATICS
15. If a seven-digit number made up of all distinct digits 8, 7, 6, 4, 2, x, and y is divisible by 3, then

MATHEMATICS
(A) maximum value of x – y is 9 (B) maximum value of x + y is 12

(C) minimum value of xy is 0 (D) minimum value of x + y is 3

S
;fn lHkh fHkUu-fHkUu vad 8, 7, 6, 4, 2, x, vkSj y ls cuh lkr vad dh la[;k, 3 ls foHkkftr gS rc -

(A) x – y dk vf/kdre eku 9 gSA (B) x + y dk vf/kdre eku 12 gSA

(C) xy dk U;wure eku 0 gSA (D) x + y dk U;wure eku 3 gSA

2 5 1
16. Considering the equation + = , where x, y  N. The number of solution of the equation is:
x y 3

(A) 6, if both x and y are even (B) 6, if both x and y are odd

(C) 0, if x is even whereas y is odd (D) 0, if x is odd whereas y is even

2 5 1
ekuk fd lehdj.k + = tgk¡ x, y  N rc lehdj.k ds gyksa dh la[;k gS -
x y 3

(A) 6, ;fn x vkSj y nksuksa le gSA (B) 6, ;fn x vkSj y fo"ke gksA

(C) 0, ;fn x le gS tcfd y fo"ke gSA (D) 0, ;fn x fo"ke gS tcfd y le gS

Space for Rough Work (dPps dk;Z ds fy, LFkku)

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MATHEMATICS
17. The coefficient of x4 in the expansion (1 5x  9x2  13x3  ..........)(1 x 2 )11 is , then sum of digits in

MATHEMATICS
 is S and product of digits in  is P then

(1 5x  9x2  13x3  ..........)(1 x 2 )11 ds izlkj esa x4 dk xq.kkad  gS] rc  esa vadksa dk ;ksxQy S gS rFkk 

S
esa vadksa dk xq.kuQy P gS] rc
(A) S = 9 (B) S = 6 (C) P = 10 (D) P = 7

18. The number of ways in which four different letters can be put in their four addressed envelopes
such that
(A) at least two of them are in the wrong envelopes, are 23
(B) at least two of them are in the wrong envelopes, are 25
(C) exactly two of them are in the correct envelopes, are 6
(D) exactly two of them are in the wrong envelopes, are 7
Øep;ksa dh la[;k gksxh tcfd pkj fHkUu fHkUu v{kjksa dks muds pkj irs fy[ks gq, fyQkQs esa j[kk tkrk gS
tcfd
(A) muesa ls de ls de nks] xyr fyQkQksa esa gS] 23 gSA
(B) muesa ls de ls de nks] xyr fyQkQksa esa gS] 25 gSA
(C) muesa ls Bhd nks] lgh fyQkQs esa gS] 6 gSA
(D) muesa ls Bhd nks] xyr fyQkQs esa gS] 7 gSA

Space for Rough Work (dPps dk;Z ds fy, LFkku)

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PHYSICS
PART : II PHYSICS

PHYSICS
SECTION – 1 : (Maximum Marks : 36)
 This section contains TWELVE (12) questions. The answer to each question is NUMERICAL VALUE
with two digit integer and decimal upto two digit.
 If the numerical value has more than two decimal places truncate/round-off the value to TWO
decimal placed.
 Marking scheme :
 Full Marks : +3 If ONLY the correct numerical value is entered as answer.
 Zero Marks : 0 In all other cases
[kaM 1 ¼vf/kdre vad% 36)
 bl [kaM esa ckjg (12) iz'u gSA izR;sd iz'u dk mÙkj la[;kRed eku (NUMERICAL VALUE) gSa]tks f}&vadh;
iw.kkZad rFkk n'keyo f}&vadu eas gSA
 ;fn la[;kRed eku esa nks ls vf/kd n’'keyo LFkku gS ] rks la[;kRed eku dks n'keyo ds nks LFkkuksa rd
VªadsV@jkmaM vkWQ (truncate/round-off) djsaA
 vadu ;kstuk %&
 iw.kZ vad % +3 ;fn flQZ lgh la[;kRed eku (Numerical value) gh mÙkj Lo:i ntZ fd;k x;k gSA
 'kwU; vad % 0 vU; lHkh ifjfLFkfr;ksa esa

19. Each point mass 2 kg is connected at the end of each uniform rod of length 1 m and mass 1 kg. All
the masses are in XY plane. Find the moment of inertia of system about Z-axis (in kg-m2).
çR;sd 2 kg ds fcUnqor~ nzO;eku 1 m yEckbZ rFkk 1 kg nzO;eku dh le:i NM+ksa ls fp=kkuqlkj tqM+s gq, gSA lHkh
nzO;eku XY ry esa gSA fudk; dk Z-v{k ds ifjr% tM+Ro vk?kw.kZ (kg-m2 esa) Kkr djksA

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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PHYSICS
20. A cubical block of mass 1 Kg is pulled by horizontal force F as shown in figure. The Coefficient of
friction of surface is  = 0.2. The value of force F for which block will topple is xN. Find the value of x.

PHYSICS
1 Kg nzO;eku ds ?kukdkj CykWd dks {kSfrt cy F }kjk fp=kkuqlkj [khapk tkrk gSA lrg ds fy, ?k"kZ.k xq.kkad
 = 0.2 gSA CykWd ds iyVus ds fy, cy F dk eku xN gks rks] x dk eku Kkr djksA
F

21. Two blocks of masses 6kg and 3kg are attached to the two ends of a massless spring of spring
constant 22 N/m. If spring is compressed and released on a smooth horizontal surface then find
the time period (in seconds) of each block.
6kg rFkk 3kg nzO;eku ds nks CykWd 22 N/m fLizax fu;rkad dh nzO;ekughu fLizax ds nksuksa fljks ls tqM+s gq, gSaA
;fn fLizax laihMhr dh tkrh gS rFkk ?k"kZ.kjfgr {kSfrt lrg ij NksM+h tkrh gS rks izR;sd CykWd dk vkorZ dky
¼lSd.M esa½ Kkr djksA

22. Find the amplitude (in cm) of a particle due to superposition of two SHM along the same line.
x1 = 5 sin (t – 37º) ; x2 = 6 cos t. (x1 and x2 are in cm and t in second)
,d dh ljy js[kk ds vuqfn'k ,d d.k ij nks ljy vkorZ xfr ds v/;kjksi.k ls çkIr vk;ke (cm esa) dk eku
D;k gksxk
x1 = 5 sin (t – 37º) ; x2 = 6 cos t. (x1 rFkk x2 lseh0 esa ,oa t lSd.M esa gS)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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23. A uniform thin, rod AB of length L and mass m is undergoing fixed axis rotation about end A, such
that end A remains stationary as shown. The kinetic energy of section AP of rod is equal to kinetic

PHYSICS
AP
energy of section BP of rod at an instant. Then the ratio of length AP and length AB, that is, is
AB
1
equal to 1/ 3
, then value of 5Y will be :
Y
m nzO;eku rFkk L yEckbZ dh ,d le:i iryh NM+ AB, vfUre fcUnq A ls xqtjus okyh fLFkj v{k ds ifjr%
bl izdkj ?kw.kZu dj jgh gS fd vfUre fljk A fp=kkuqlkj fLFkj jgrk gSA ml {k.k NM+ ds Hkkx AP dh xfrt
AP 1
ÅtkZ NM+ ds Hkkx BP dh xfrt ÅtkZ ds cjkcj gSA rc yEckbZ AP rFkk AB dk vuqikr vFkkZr~ , 1/ 3
ds
AB Y
cjkcj gS] rc 5Y dk eku gksxk &
m ,L

A P B

24. One end of a spring is fixed to the ceiling and other end is attached to a block. The block is
released when spring is relaxed. The product of time period and amplitude is 8 S.I. units. If spring
is cut in two equal parts and the two springs are attached to the block as shown in figure. The
block is released when both springs are relaxed. If the product of time period and amplitude in S.I.
units is x, then find the value of 14x.
fdlh fLizax dk ,d fljk Nr ls rFkk nwljk fljk CykWd ls tqM+k gqvk gS tc fLizax izkd`frd yEckbZ ij gS rc
CykWd dks NksM+k tkrk gSA vkorZdky vkSj vk;ke dk xq.kuQy 8 (S.I. bdkbZ ek=kd esa½ gSA vc fLizax dks nks
leku Hkkxksa esa dkV fn;k tk;s rFkk fp=kkuqlkj CykWd ls nks fLizax tksM+ nh tkrh gSA tc nksuksa fLizax viuh
izkd`frd yEckbZ esa gS rc CykWd dks NksM+k tkrk gSA ;fn vkorZdky vkSj vk;ke dk xq.kuQy ¼ S.I. bdkbZ ek=kd
esa½ x gS rks 14x dk eku Kkr djksA

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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PHYSICS
25. A body is executing SHM under the action of force whose maximum magnitude is 5 0 2 N. The

PHYSICS
magnitude of force acting on the particle at the instant when its kinetic energy and potential are
equal is. (Assume potential energy to be zero at mean position)
,d oLrq ,d cy ds v/khu ljy vko`fr xfr djrh gSA ftldk vf/kdre ifjek.k 5 0 2 N gSA ml {k.k ij
tc d.k dh xfrt ÅtkZ fLFkfrt ÅtkZ ds cjkcj gS] d.k ij dk;Zjr cy dk ifjek.k fdruk gSA (ekfu, fd
ek/; fLFkfr ij fLFkfrt ÅtkZ 'kwU; gSA)

26. A solid cylinder of radius 2m is kept on an inclined plane on its base and it does not slide. The
angle of incline plane is 53° with horizontal and it is fixed. If maximum height (in metre) of the
cylinder for it not to topple is x, then find value of 4x.
2m f=kT;k dk ,d Bksl csyu ,d ur ry ij blds vk/kkj ij j[kk gS ,oa ;g fQlyrk ugha gSA {kSfrt ls ur
ry dk dks.k 53° gS ,oa ;g fLFkj gSA ;fn csyu ds ugha iyVus ds fy, bldh vf/kdre Å¡pkbZ ¼ehVj esa½ x gS
rks 4x dk eku Kkr djksA

27. A uniform rod AB of length 4m and mass 12 kg is thrown such that just after the projection the
centre of mass of the rod moves vertically upwards with a velocity 10 m/s and at the same time it is

rotating with an angular velocity rad/sec about a horizontal axis passing through its mid point.
2
Just after the rod is thrown it is horizontal and is as shown in the figure. If the acceleration
(in m/sec2) of the point A in m/s2 when the centre of mass is at the highest point is x, then find the
value of 5x. (Take g = 10m/s2 and 2 = 10)
,d le:i NM+ AB ftldh yEckbZ 4m rFkk nzO;eku 12 kg gS dks bl izdkj Qsadk tkrk gS fd Qsadus ds rqjUr
i'pkr~ NM+ dk nzO;eku dsUnz Å/okZ/kj Åij dh vksj 10 m/s osx ls rFkk blh le; e/; fcUnq ls ikfjr {kSfrt

v{k ds lkis{k jsfM;u/lsd.M dks.kh; osx ls ?kw.kZu xfr djrh gSA NM+ dks Qsadus ds rqjUr i'pkr~ ;g {kSfrt
2
voLFkk esa gS rFkk fp=k esa iznf'kZr gSA ;fn tc nzO;eku dsUnz mPpre fcUnq ij gks rc fcUnq A dk Roj.k
(m/sec2 esa) x gS rks 5x dk eku Kkr djksA (g = 10m/s2 rFkk 2 = 10)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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PHYSICS
28. A uniform solid hemisphere of mass m and radius R is attached to the roof with a chord of torsional

PHYSICS
constant C and performing torsional SHM. If time period (in seconds) of SHM is x, then find the

2
value of 5x. (Take m = 15 kg, R = m, C = 6 Nm/rad.)

m nzO;eku rFkk R f=kT;k dk le:i Bksl v)Z xksyk ejksM+h fu;rkad C dh jLlh dh lgk;rk ls Nr ls

fp=kkuqlkj yVdk gqvk gS rFkk ejksM+h yksyd ds :i esa ljy vkorZ xfr djrk gSA ;fn bldh ljy vkorZ xfr

2
dk vkorZ dky x gS rks 5x dk eku Kkr djksA (m = 15 kg, R = m, C = 6 Nm/rad. ysasA)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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PHYSICS
29. A non–viscous ideal fluid is flowing vertically downwards in a pipe. The area of cross-section at

PHYSICS
section 'A' is double that at section 'B'. Vertical distance between section A and section B is h and
h
the height of water column in tube (2) is more than that in tube (1) by distance. If the
2

velocity(m/s) of the fluid at section A is x, then find the value of 6x. (if h = 2.7 m)
,d v';ku vkn'kZ nzo uyh esa Å/okZ/kj uhps dh rjQ çokfgr gSA Hkkx A ij vuqçLFk dkV {ks=kQy Hkkx B dh
rqyuk esa nqxquk gSA Hkkx A rFkk B ds chp Å/okZ/kj nwjh h gS rFkk uyh (2) esa ty LrEHk dh Å¡pkbZ uyh (1) ls
h
T;knk gSA ;fn Hkkx A ij nzo çokg osx (m/s esa) x gS rks 6x dk eku Kkr djksA (;fn h = 2.7 m)
2

uyh(1)

uyh(2)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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PHYSICS
30. Two immiscible liquids are poured in a U–tube having densities 1 = 1.0 × 103 kg/m3 and

PHYSICS
h1
2 = 3.0 × 103 kg/m3. If the ratio of heights (of the liquids above their interface) is x, then find the
h2

value of 7x.

U–ufydk esa nks vfeJ.kh; nzo ftuds ?kuRo 1 = 1.0 × 103 kg/m3 rFkk 2 = 3.0 × 103 kg/m3 gSA ;fn (nksuks

h1
nzoks ds vUr% i`"B ls) nzoksa dh Å¡pkbZ;ksa dk vuqikr dk eku x gS rks 7x dk eku Kkr djksA
h2

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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PHYSICS

SECTION – 2 : (Maximum Marks : 24)

PHYSICS
 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is(are) correct
 For each question, marks will be awarded in one of the following categories :
 Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
 Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
 Partial Marks : +2 If three or more options are correct but ONLY two options are chosen
and both of which are correct.
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and
it is a correct option.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –2 In all other cases.
 For example, in a question, if (A),(B) and (D) are the ONLY three options corresponding to correct
answers, then :
 Choosing ONLY (A),(B) and (D) will get +4 marks
 Choosing ONLY (A) and (B) will get +2 marks
 Choosing ONLY (A) and (D) will get +2 marks
 Choosing ONLY (B) and (D) will get +2 marks
 Choosing ONLY (A) will get +1 marks
 Choosing ONLY (B) will get +1 marks
 Choosing ONLY (D) will get +1 marks
 Choosing no option (i.e. the question is unanswered) will get 0 marks, and
 Choosing any other combination of options will get –2 mark
[kaM 2 : (vf/kdre vad : 24)
 bl [kaM esa N% (06) iz'u gSaA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad % +4 ;fn dsoy ¼lkjs½ lgh fodYi ¼fodYiksa½ dks pquk x;k gSA
 vkaf'kd vad % +3 ;fn pkjksa fodYi lgh gSa ijUrq dsoy rhu fodYiksa dks pquk x;k gSA
 vkaf'kd vad % +2 ;fn rhu ;k rhu ls vf/kd fodYi lgh gS ijUrq dsoy nks fodYiksa dks pquk x;k gS vkSj
Space
nksauks pqfor
us gq,Rough
fodYi Work / (dPpsgSaAdk;Z ds fy, LFkku)
lgh fodYi
 vkaf'kd vad % +1 ;fn nks ;k nks ls vf/kd fodYi lgh gSa ijUrq dsoy ,d fodYi dks pquk
x;k gS vkSj pquk gqvk fodYi lgh fodYi gSA
 'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –2 vU; lHkh ifjfLFkfr;ksa esaA
 mnkgj.k% ;fn fdlh iz'u ds fy, dsoy fodYi (A),(B) vkSj (D) lgh fodYi gS] rc %
 dsoy fodYi (A),(B) vkSj (D) pquus ij +4 vad feysaxs ’
 dsoy fodYi (A) vkSj (B) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (B) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) pquus ij +1 vad feysaxs ’
 dsoy fodYi (B) pquus ij +1 vad feysaxs ’
 dsoy fodYi (D) pquus ij +1 vad feysaxs ’
 dksbZ Hkh fodYi u pquus ij ¼vFkkZr~ iz'u vuqÙkfjr jgus ij½ 0 vad feysaxs vkSj
 vU; fdlh fodYiksa ds la;kstu dks pquus ij –2 vad feysaxs

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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31. A body is floating in a beaker containing water. The beaker is dropped. The upthrust on the body
due to water is

PHYSICS
(A) Zero
(B) equal to the weight of the body in air with respect to ground.
(C) equal to the apparent weight of the water displaced with respect to ground.
(D) equal to the apparent weight of the immersed portion of the body with respect to beaker.
,d oLrq ik=k esa Hkjs ikuh esa rSj jgh gSA ik=k dks fxjk;k tkrk gSA ikuh ds dkj.k oLrq ij yxus okyk iz.kksn
(upthrust) cy D;k gksxk &
(A) 'kwU;
(B) gok esa /kjkry ds lkis{k oLrq ds Hkkj ds cjkcj
(C) /kjkry ds lkis{k foLFkkfir ikuh ds vkHkklh Hkkj ds cjkcj
(D) ik=k esa lkis{k oLrq ds Mwcs gq, Hkkx ds vkHkklh Hkkj ds cjkcj

32. A simple pendulum is kept suspended vertically in a stationary bus. The bus starts moving with an
acceleration a towards left. As observed inside the bus: (Neglect frictional forces on pendulum and
assume size of the ball to be very small.)

(A) time period of oscillation of the pendulum will be 2 for any value of a.
2 2
a  g

(B) time period of oscillation of the pendulum will be 2 only when a < < g.
2 2
a  g

 a 
(C) angular amplitude of oscillation will be tan–1   for any value of a < g.
 g 

 a 
(D) angular amplitude of oscillation will be tan–1   only when a < < g.
 g 

Space for Rough Work / (dPps dk;Z ds fy, LFkku)


fLFkj cl esa ljy yksyd fp=kkuqlkj m/okZ/kj yVdk gqvk gSA cl ck;sa rjQ a Roj.k ls xfr djuk izkjEHk djrh
gSA cl ds vUnj ls izsf{kr djus ij (yksyd ij izfrjks/kh cy ux.; gS rFkk xksyd dk vkdkj vYi ekusaA)
(A) yksyd ds nksyuksa dks vkorZdky a ds fdlh eku ds fy, 2  gksxkA
2 2
a  g

(B) yksyd ds nksyuksa dks vkorZdky dsoy a < < g ds fy, 2  gksxkA
2 2
a  g

 a 
(C) a < g ds fy, nksyuksa dk dks.kh; vk;ke tan–1   gksxkA
 g 

 a 
(D) dsoy a < < g ds fy, nksyuksa dk dks.kh; vk;ke tan–1   gksxkA
 g 

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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PHYSICS
33. A uniform disc of mass m and radius R rotates about a fixed vertical axis passing through its

PHYSICS
centre with angular velocity  A particle of same mass m and having velocity 2 R towards
centre of the disc collides with the disc moving horizontally and sticks to its rim.

(A) The angular velocity of the disc will become /3.

(B) The angular velocity of the disc will become 5 /3.

37
(C) The impulse on the particle due to disc is m R
3

37
(D) The impulse on the disc due to hinge is m R
3

,d le:i pdrh ftldk æO;eku m o f=kT;k R ,d fLFkj Å/okZ/kj v{k tks mlds dsUæ ls xqtj jgh gks ds

lkis{k ?kwe jgh gSA ,d d.k ftldk æO;eku m rFkk osx 2 R gSA pdrh ds dsUæ dh vksj {kSfrt xfreku gS
rFkk blls VDdj ds i'pkr~ ifjf/k ij fpid tkrh gS

(A) pdrh dk dks.kh; osx /3 gksxkA

(B) pdrh dk dks.kh; osx 5/3 gksxkA

37
(C) pdrh ds dkj.k d.k ij m R vkosx gksxkA
3

37
(D) dhy ds dkj.k pdrh ij m R vkosx gksxkA
3

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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PHYSICS
34. A simple pendulum A and a homogeneous rod B hinged at its end are released from horizontal

PHYSICS
position as shown in figure.

(A) The times period of swing of simple pendulum is greater than that of rod if L = 

(B) The time period of swing of simple pendulm is equal to that of rod if L = 

2
(C) The time period of swing of simple pendulum is greater than that of rod if L =
3

2
(D) The time period of swing of simple pendulum is equal to that of rod if L = .
3

(A) (B)
L

,d ljy yksyd A rFkk ,d le:i NM+ B dks blds ,d fljs ls dhydhr fd;k x;k gS rFkk bUgsa {kSfrt

fLFkfr ls NksMk tkrk gSA

(A) ljy yksyd dk vkorZdky NM+ ds vkorZdky ls vf/kd gksxk ;fn L = rks

(B) ljy yksyd dk vkorZdky NM+ ds vkorZdky ls cjkcj gksxk ;fn L = rks

2
(C) ljy yksyd dk vkorZdky NM+ ds vkorZdky ls vf/kd gksxk ;fn L =
3

2
(D) ljy yksyd dk vkorZdky NM+ ds vkorZdky ls cjkcj gksxk ;fn L =
3

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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PHYSICS
35. A spring block system is put into SHM in two experiments. In the first, the block is pulled from the
equilibrium position through a displacement d1 and then released. In the second, it is pulled from

PHYSICS
the equilibrium position through a greater distance d2 and then released. In both the experiments,
(A) period of the motions are same.
(B) frequency of the motions are same.
(C) maximum kinetic energy of the motion are same.
(D) angular frequency of the motions are same
,d fLiazx xqVds dh fudk; dks nks iz;ksxksa esa ljy vkorZ xfr ds fy, iz;qDr fd;k tkrk gSA igys iz;ksx esa
xqVds dks lkE;koLFkk ls d1 nwjh rd foLFkkfir djds NksM+k tkrk gSA nwljs iz;ksx esa vf/kd d2 nwjh rd
foLFkkfir djds NksM+k tkrk gSA nksuksa iz;ksxksa esa

(A) nksuksa xfr;ksa dk vkorZdky leku gSA


(B) nksuksa xfr;ksa dh vko`fÙk leku gSA
(C) nksuksa xfr;ksa dh vf/kdre xfrt ÅtkZ leku gSA
(D) nksuksa xfr;ksa dh dks.kh; vko`fÙk leku gSaA

36. A small ball of mass m is released from rest from a height h above the liquid surface. The density

of ball is : (assume no splash)
3
(A) If h  H, then the ball will be able to enter the liquid of higher density
7H
(B) If h  , then the ball will be able to strike the bottom of the vessel
2
(C) If h = 2H, then the ball will cross the interface of two liquids with kinetic energy = mgH
(D) If h = 0 then ball will float on the surface

Space for Rough Work / (dPps dk;Z ds fy, LFkku)


m nzO;eku dh xsan dks fLFkjkoLFkk ls nzo lrg ls h Å¡pkbZ ls NksMk tkrk gSA xsan dk ?kuRo gSA (ekuk ikuh
3
mNyrk ugh gS)
(A) ;fn h  H, gks rks xsan vf/kd ?kuRo ds nzo eas izos'k djsxhA
7H
(B) ;fn h  , gks rks xsan ik=k ds ry ij Vdjkus ;ksX; gSA
2
(C) ;fn h = 2H, gks rks xsan nksuks nzoks dh l;qDr lrg ij xfrt ÅtkZ = mgH ls xqtjrh gSA
(D) ;fn h = 0 gks rks xasn lrg ij rSjxhA

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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CHEMISTRY

PART : III CHEMISTRY


Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,

CHEMISTRY
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

SECTION – 1 : (Maximum Marks : 36)


 This section contains TWELVE (12) questions. The answer to each question is NUMERICAL VALUE
with two digit integer and decimal upto two digit.
 If the numerical value has more than two decimal places truncate/round-off the value to TWO
decimal placed.
 Marking scheme :
 Full Marks : +3 If ONLY the correct numerical value is entered as answer.
 Zero Marks : 0 In all other cases

[kaM 1 ¼vf/kdre vad% 36)


 bl [kaM esa ckjg (12) iz'u gSA izR;sd iz'u dk mÙkj la[;kRed eku (NUMERICAL VALUE) gSa]tks f}&vadh;
iw.kkZad rFkk n'keyo f}&vadu eas gSA
 ;fn la[;kRed eku esa nks ls vf/kd n’'keyo LFkku gS ] rks la[;kRed eku dks n'keyo ds nks LFkkuksa rd
VªadsV@jkmaM vkWQ (truncate/round-off) djsaA
 vadu ;kstuk %&
 iw.kZ vad % +3 ;fn flQZ lgh la[;kRed eku (Numerical value) gh mÙkj Lo:i ntZ fd;k x;k gSA
 'kwU; vad % 0 vU; lHkh ifjfLFkfr;ksa esa

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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CHEMISTRY
37. Calculate the work done (in atm L) for the following process of an ideal gas (assume n 2 = 0.7).
,d vkn'kZ xSl ds fuEu izØe ds fy, fd;k x;k dk;Z (atm L esa) ifjdfyr dhft, (ekuk n 2 = 0.7) –

CHEMISTRY
2 atm

P

1 atm

1 1
22.4 11.2
1 1
(L )
V

2
3.0

P
(atm) 1
1.0 3
38.

10 20
Volume (L)

Calculate the magnitude of work involved (in atm L) during the given process for an ideal gas.
vkn'kZ xSl ds fy;s fn;s x;s izØe esa lfEefyr ¼ involved ½ dk;Z ds ifjek.k dh (atm L esa) dh x.kuk djsaA
39. When a monoatomic ideal gas undergoes an adiabatic reversible process, its temperature and
volume are related by equation TVn = constant. Find the value of n.
tc ,dy ijek.oh; vkn'kZ xSl :)ks"eh; mRØe.kh; izØe ls xqtjrh gS] rks bldk rki rFkk vk;ru lehdj.k
TVn = fu;r }kjk lEcfU/kr gksrk gSA n dk eku Kkr dhft,A

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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CHEMISTRY
40. 1 mol of a real gas obeys P(Vm – b) = RT; where 'b' and 'R' are constants. If the compressibility
factor of gas is 1.11 and occupied volume of the gas is Xb then determine value of X.

CHEMISTRY
1 eksy okLrfod xSl P(Vm – b) = RT dh ikyuk djrh gS; tgk¡ 'b' vkSj 'R' fLFkjkad gSA ;fn xSl dk lEihM~;rk
xq.kkad 1.11 gS vkSj xSl }kjk xzg.k fd;k x;k vk;ru Xb gS rks X dk eku Kkr dhft,A

41. A sample of HI(g) is placed in flask at a pressure of 0.2 atm. At equilibrium the partial pressure of
HI(g) is 0.04 atm. What is Kp for the given equilibrium ?
2HI (g) H2 (g) + 2 (g)
HI(g) dk ,d izkn'kZ 0.2 atm nkc ij ,d ¶ykLd esa fy;k x;k gSA lkE; ij] HI(g) dk vkaf'kd nkc 0.04 atm
gSA fn;s x;s lkE; ds fy, Kp D;k gS\
2HI (g) H2 (g) + 2 (g)

42. Four moles of an ideal diatomic gas ( = 1.4) at 300 K and 12 atm expanded irreversibly &
adiabatically to a final pressure of 2.4 atm against a constant pressure of 2 atm. Calculate W & H
|XY|
(magnitude only). Report your answer as , where W = X × 100R , H = Y × 10R and R is
10
gas constant.

300 K rFkk 12 atm


ij ,d vkn'kZ f}ijek.oh; xSl ( = 1.4) ds pkj eksy dks vuqRØe.kh; o :)ks"eh; :i ls
2 atm fu;r nkc ds fo:) izlkfjr dj vfUre nkc 2.4 atm rd ys tk;k tkrk gSA W o H dh x.kuk
|XY|
¼dsoy ifjek.k½ dhft,A viuk mÙkj ds :i esa nhft,] tgk¡ W = X × 100R, H = Y × 10R rFkk
10
R xSl fu;rkad gSA

43. How many lone pairs are present in TeCl4 ?


TeCl4 esa fdrus ,dkdh ;qXe mifLFkr gS \

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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CHEMISTRY
44. How many of the following orbital overlappings is not possible in bond formation according to
VBT.

CHEMISTRY
VBT ds vk/kkj ij fuEu es ls fdrus ijek.oh; d{kdksa dk vfrO;kiu laHko ugh gS \

(a) (b)

s-orbital p-orbital

(c) + (d)

(c) (d)

p-orbital p-orbital
– +
(e) (f)
+ –

(e) (f)

45. How many total number of unshared electrons pairs are present in a Lewis dot structure of
perxenate ion (XeO64–) :
ijftusV vk;u (XeO64–) dh yqbZl fcUnq lajpuk esa vlk¡f>r bysDVªkWu ;qXeksa dh dqy fdruh la[;k mifLFkr
gS\

46. How many of the following molecules do not follow octet rule?
fuEu esa ls fdrus v.kq v"Vd fu;e dk vuqlj.k ugha djrs gSa \
PCl5, BF3, NO2, NO, SF4, CO, ClO2, O3 , SF6 , BCl3

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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CHEMISTRY
47. In the correct Lewis dot structure of CO2, the total number of lone pairs are :
CO2 dh lgh yqbZl fcUnq lajpuk esa] ,dkdh ;qXeksa dh dqy la[;k gS&

CHEMISTRY
48. In the given structure of diazomethane CH2N2 :
H
C=N=N
H
What is the formal charge on central N-atom ?
MkbZ,tksesFksu] CH2N2 dh nh x;h lajpuk esa
H
C=N=N
H
dsfUnz; N-ijek.kq ij vkSipkfjd vkos'k D;k gS \

SECTION – 2 : (Maximum Marks : 24)


 This section contains SIX (06) questions.


 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is(are) correct
 For each question, marks will be awarded in one of the following categories :
 Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
 Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
 Partial Marks : +2 If three or more options are correct but ONLY two options are chosen
and both of which are correct.
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and
it is a correct option.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –2 In all other cases.
 For example, in a question, if (A),(B) and (D) are the ONLY three options corresponding to correct
answers, then :
 Choosing ONLY (A),(B) and (D) will get +4 marks
 Choosing ONLY (A) and (B) will get +2 marks
 Choosing ONLY (A) and (D) will get +2 marks
 Choosing ONLY (B) and (D) will get +2 marks
 Choosing ONLY (A) will get +1 marks
 Choosing ONLY (B) Space will get for marks Work / (dPps dk;Z ds fy, LFkku)
+1 Rough
 Choosing ONLY (D) will get +1 marks
 Choosing no option (i.e. the question is unanswered) will get 0 marks, and
 Choosing any other combination of options will get –2 mark

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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CHEMISTRY

[kaM 2 : (vf/kdre vad : 24)


bl [kaM esa N% (06) iz'u gSaA

CHEMISTRY

 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad % +4 ;fn dsoy ¼lkjs½ lgh fodYi ¼fodYiksa½ dks pquk x;k gSA
 vkaf'kd vad % +3 ;fn pkjksa fodYi lgh gSa ijUrq dsoy rhu fodYiksa dks pquk x;k gSA
 vkaf'kd vad % +2 ;fn rhu ;k rhu ls vf/kd fodYi lgh gS ijUrq dsoy nks fodYiksa dks pquk x;k gS vkSj
nksauks pqus gq, fodYi lgh fodYi gSaA
 vkaf'kd vad % +1 ;fn nks ;k nks ls vf/kd fodYi lgh gSa ijUrq dsoy ,d fodYi dks pquk
x;k gS vkSj pquk gqvk fodYi lgh fodYi gSA
 'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –2 vU; lHkh ifjfLFkfr;ksa esaA
 mnkgj.k% ;fn fdlh iz'u ds fy, dsoy fodYi (A),(B) vkSj (D) lgh fodYi gS] rc %
 dsoy fodYi (A),(B) vkSj (D) pquus ij +4 vad feysaxs ’
 dsoy fodYi (A) vkSj (B) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (B) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) pquus ij +1 vad feysaxs ’
 dsoy fodYi (B) pquus ij +1 vad feysaxs ’
 dsoy fodYi (D) pquus ij +1 vad feysaxs ’
 dksbZ Hkh fodYi u pquus ij ¼vFkkZr~ iz'u vuqÙkfjr jgus ij½ 0 vad feysaxs vkSj
 vU; fdlh fodYiksa ds la;kstu dks pquus ij –2 vad feysaxs

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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CHEMISTRY
49. A gas shows following graph at 25ºC.

CHEMISTRY
Which is/are correct for the gas ?
(A) Gas shows only negative deviation throughout the graph
(B) Boyle temperature of gas must be more than 25ºC.
(C) Molar volume of gas is less than that of ideal molar volume at 25ºC in low pressure region.
(D) In the high pressure region, the gas is less compressible than ideal gas at 25ºC.

25ºC ij ,d xSl fuEu vkjs[k n'kkZrh gSA

vkn'kZ xSl
okLrfod xSl (A)
?kuRo

nkc
xSl ds fy, dkSulk@dkSuls fodYi lgh gS@gSa \
(A) lEiw.kZ vkjs[k esa xSl dsoy _.kkRed fopyu n'kkZrh gSA
(B) xSl dk ckW;y rkieku 25ºC ls vf/kd gksuk pkfg,A
(C) xSl dk eksyj vk;ru fuEu nkc {ks=k esa 25ºC ij vkn'kZ eksyj vk;ru ls de gksrk gSA
(D) mPp nkc {ks=k esa 25ºC ij vkn'kZ xSl dh rqyuk esa xSl de laihfM+r gksrh gSA

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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CHEMISTRY
50. Consider the reaction :
12
KC=10

CHEMISTRY
P(g) + 2Q(g) R(g) + S(g)
Initial conc. 2M 4M 0 0
then select correct statement(s)
(A) At equilibrium [R(g)] = [S(g)]  2M
~
 10–4M
(B) At equilibrium [P(g)] = [Q(g)] ~

(C) At equilibrium [P(g)]  10–4M


~
 2  10–4M
(D) At equilibrium [Q(g)] ~

vfHkfØ;k dk voyksdu dhft, &


12
KC=10
P(g) + 2Q(g) R(g) + S(g)
izkjfEHkd lkUnzrk 2M 4M 0 0
rks lgh dFku@dFkuksa dk p;u dhft,&
 2M
(A) lkE; ij [R(g)] = [S(g)] ~

(B) lkE; ij [P(g)] = [Q(g)] 


~ 10–4M

(C) lkE;  10–4M


~
ij [P(g)]

 2  10–4M
(D) lkE; ij [Q(g)] ~

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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CHEMISTRY
51. At 57°C, gaseous dinitrogen tetraoxide is 50% dissociated at 1 atm. [N2O4(g) 2NO2(g)].
Select the correct option(s) :

CHEMISTRY
R = 8.3 JK–1 mol–1 , In 10 = 2.3 , log 2 = 0.3 , log 3 = 0.48
57°C o 1 atm ij, xSlh; MkbZukbVªkstu VsVªkvkWDlkbM 50% fo;ksftr gksrk gSA [N2O4(g) 2NO2(g)]

lgh fodYi@fodYiksa dk p;u dhft,&


R = 8.3 JK–1 mol–1 , In 10 = 2.3 , log 2 = 0.3 , log 3 = 0.48
(A) G° = – 755.96 J mol–1 (B) G° = – 856.48 J mol–1
4 3
(C) KP = atm (D) KP = atm
3 4

52. Which of the following statement is/are correct ?


(A) dz 2 orbital used in sp3d hybridization

(B) sp3d3 hybridization involving pentagonal bipyramidal geometry


(C) sp3d2 hybridization involved dx2 – y2 and dyz atomic orbitals

(D) pz orbital used by C atom for pi-bonding in CO32– (ion in x-y plane)

fuEu esa ls dkSulk@dkSuls dFku lgh gS@gSa \


(A) dz 2 d{kd fufgr sp3d ladj.k esa iz;qDr gksrk gSA

(B) sp3d3 ladj.k esa iapdks.kh; f}fijkfeMh; T;kfefr mifLFkr gSA


(C) sp3d2 ladj.k esa dx2 – y2 rFkk dyz ijek.oh; d{kd mifLFkr gksrs gSA
(D) pz d{kd CO32– vk;u (x-y ry esa) esa ikbZ-ca/ku ds fy;s C ijek.kq }kjk iz;qDr gksrk gSA

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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CHEMISTRY
53. Which of the following statesments are correct for B2H6
(A) Each boron is sp3 hybridised

CHEMISTRY
(B) four terminal 'H' & two 'B' atom are in same plane but two bridge hydrogen in different plane.
(C) It has 4  bond & 2 bridge bond
(D) 8  bonds are present in it
buesa ls dkSulk dFku lgh gS B2H6 ds fy,&
(A) izR;sd cksjksu sp3 ladfjr gksrk gSA
(B) pkj Nksj okys (terminal) 'H' ijek.kq o nks 'B' ijek.kq leku ry esa gksrs gSa ysfdu nks lsrq gkbMªkstu ijek.kq
fHkUu ry esa gksrs gSaA
(C) blesa 4  rFkk 2 lsrq ca/k gksrs gSaA
(D) blesa 8  ca/k mifLFkr gksrs gSaA

54. Which of the following is/are correct for the formation of  bond ?
(A) overlapping of px-px (Z internuclear axis)
(B) overlapping of py-py orbitals (Z internuclear axis)
(C) overlapping of dyz-dyz orbitals (X internuclear axis)
(D) overlapping of dxy-dxy orbitals (X internuclear axis)
fuEu esa ls dkSulk@dkSuls  ca/k ds fuekZ.k ds fy, lgh gS@gSa \
(A) px-px dk vfrO;kiu (Z vUrjukfHkdh; v{k)
(B) py-py d{kdks dk vfrO;kiu (Z vUrjukfHkdh; v{k)
(C) dyz-dyz d{kdks dk vfrO;kiu (X vUrjukfHkdh; v{k)
(D) dxy-dxy d{kdks dk vfrO;kiu (X vUrjukfHkdh; v{k)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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