APT 3 Paper2

DATE ® P09-20
04-10-2020
ADVANCED PATTERN PART TEST-3 (APT-3)

PAPER
TARGET : JEE (MAIN + ADVANCED) 2021
1 COURSE : VIJETA (JP) | BATCH : 01JPA,01JPB,TCHP
Time : 3 Hours Maximum Marks : 204

CODE
1 Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
INSTRUCTIONS TO CANDIDATES
 Question Paper-1 has three (03) parts: Mathematics, Physics and Chemistry.
 Each part has a total eighteen (18) questions divided into two (02) sections (Section-1 and Section-2).
 Total number of questions in Question Paper-1 are Fifty Four(54) and Maximum Marks are Two Hundred Four (204)
Type of Questions and Marking Schemes
SECTION-1 (Maximum Marks : 56)

 This section contains FOURTEEN (14) questions.
 Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is (are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
 Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
 Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
 Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and both of which
are correct.
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –1 In all other cases.
SECTION-2 : (Maximum Marks : 12)
 This section contains TWO (02) paragraphs
 Based on each paragraph, there will be TWO questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct
 Marking scheme :
 Full Marks : +3 If ONLY the correct option is chosen.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered)
 Negative Marks : –1 In all other cases
NAME OF THE CANDIDATE : ………………………………………………… ROLL NO. :………………..………………………..
I have read all the instructions I have verified the identity, name and roll number
and shall abide by them of the candidate.
------------------------- -------------------------
Signature of the Candidate Signature of the Invigilator
Resonance Eduventures Limited

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INSTRUCTIONS FOR OPTICAL RESPONSE SHEET (ORS)
 Darken the appropriate bubbles on the original by applying sufficient pressure.
 The original is machine-gradable and will be collected by the invigilator at the end of the examination.
 Do not tamper with or mutilate the ORS.
 Write your name, roll number and the name of the examination centre and sign with pen in the space provided for this
purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble under each
digit of your roll number.
DARKENING THE BUBBLES ON THE ORS :
 Use a BLACK BALL POINT to darken the bubbles in the upper sheet.
 Darken the bubble COMPLETELY.
 Darken the bubble ONLY if you are sure of the answer.
 The correct way of darkening a bubble is as shown here :
 There is NO way to erase or "un-darkened bubble.
 The marking scheme given at the beginning of each section gives details of how darkened and not darkened bubbles
are evaluated.
 Zero marks ‘0’ If none of the options is chosen (i.e. the question is unanswered).
FOR INTEGER TYPE QUESTIONS OMR LOOKS LIKE :
 For example, if answer ‘SINGLE DIGIT’ integer type below :
0 1 2 3 4 5 6 7 8 9
 For example, if answer ‘SINGLE DIGIT’ integer with positive / negative type below :
0
– 1
2
3
4
5
6
7
8
9
 For example, if answer ‘DOUBLEDIGIT’ integer type below :
0 0
1 1
2 2
3 3
4 4
5 5
6 6
7 7
8 8
9 9
FOR DECIMAL TYPE QUESTIONS OMR LOOKS LIKE :
COLUMN
1 2 . 3 4
0 0 0 0
1 1 1 1
2 2 2 2
3 3 3 3
4 4 4 4
5 5 5 5
6 6 6 6
7 7 7 7
8 8 8 8
9 9 9 9
 If answer is 3.7, then fill 3 in either 1st or 2nd column and 7 in 3rd or 4th column.
 If answer is 3.07 then fill 3 in 1st or 2nd column ‘0’ in 3rd column and 7 in 4th column.
 If answer is, 23 then fill 2 & 3 in 1st and 2nd column respectively, while you can either leave column 3 & 4 or fill ‘0’ in either
of them.

DATE ® P09-20
04-10-2020
ADVANCED PATTERN PART TEST-3 (APT-3)

PAPER
TARGET : JEE (MAIN + ADVANCED) 2021
1 COURSE : VIJETA (JP) | BATCH : 01JPA,01JPB,TCHP
Time (le;) : 3 Hours (?k.Vs) Maximum Marks (vf/kdre vad) : 204

CODE
Ñi;k bu funsZ'kksa dks /;ku ls i<+saA vkidks 5 feuV fo'ks"k :i ls bl dke ds fy, fn;s x;s gSaA
1 vH;fFkZ;ksa ds fy, vuqns'k
 ç'u&i=k 1 eas rhu (03) Hkkx gS % (xf.kr ] HkkSfrdh ,oa jlk;u foKku)
 çR;sd Hkkx esa dqy vBkjg (18) iz'u gS tks nks (02) [kaMks esa foHkkftr gS ¼[kaM 1 vkSj [kaM 2)
 iz'u&i=k 1 esa ç'uksa dh dqy la[;k % pkSou (54) ,oa vf/kdre vad % nks lkS pkj (204) gSaA
ç'uksa ds çdkj vkSj ewY;kadu ;kstuk,¡
[kaM–1 ¼vf/kdre vad : 56½
 bl [kaM esa pkSng (14) iz'u gSA
 izR;sd iz'u ds fy, pkj fodYi fn, x, gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gS¼gSa½A
 izR;sd iz'u ds fy,] fn, gq, fodYiksa esa ls lgh mÙkj ¼mÙkjksa½ ls lacf/kr fodYi ¼fodYiksa½ dks pqfu,A
 izR;sd iz'u ds mÙkj dk ewY;kadu fuEu ;kstuk ds vuqlkj gksxk %
 iw.kZ vad % +4 ;fn dsoy ¼lkjs½ lgh fodYi ¼fodYiksa½ dks pquk x;k gSA
 vkaf'kd vad % +3 ;fn pkjksa fodYi lgh gSa ijUrq dsoy rhu fodYiksa dks pquk x;k gSA
 vkaf'kd vad % +2 ;fn rhu ;k rhu ls vf/kd fodYi lgh gS ijUrq dsoy nks fodYiksa dks pquk x;k gS vkSj nksauks pqus
gq, fodYi lgh fodYi gSaA
 vkaf'kd vad % +1 ;fn nks ;k nks ls vf/kd fodYi lgh gSa ijUrq dsoy ,d fodYi dks pquk x;k gS vkSj pquk gqvk
fodYi lgh fodYi gSA
 'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –1 vU; lHkh ifjfLFkfr;ksa esaA
[kaM–2 ¼vf/kdre vad : 12½
 bl [kaM esa nks (02) vuqPNsn gSaA izR;sd vuqPNsn ij nks iz'u gaSA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls dsoy ,d fodYi lgh gSA
 vadu ;kstuk :
 iw.kZ vad % +3 ;fn flQZ lgh fodYi gh pquk x;k gSA
ijh{kkFkhZ dk uke : ………………………………………………………………jksy uEcj : ………………………..…………………
eSaus lHkh funsZ'kksa dks i<+ fy;k gS vkSj eSa mudk eSusa ijh{kkFkhZ dk ifjp;] uke vkSj jksy uEcj
vo'; ikyu d:¡xk@d:¡xhA dks iwjh rjg tk¡p fy;k gSA
------------------------ ------------------------
ijh{kkFkhZ ds gLrk{kj ijh{kd ds gLrk{kj

vkWfIVdy fjLikal 'khV (ORS) Hkjus ds funs’'Z k
 Åijh ewy i`"B ds vuq:i cqycqyksa (BUBBLES) dks i;kZIr ncko Mkydj dkyk djsaA
 ewy i`"B e'khu&tk¡p gS rFkk ;g ijh{kk ds lekiu ij fujh{kd ds }kjk ,d=k dj fy;k tk;sxkA
 vks-vkj-,l- dks gsj&Qsj@fod`fr u djsaA
 viuk uke] jksy ua- vkSj ijh{kk dsanz dk uke ewy i`"B esa fn, x, [kkuksa esa dye ls Hkjsa vkSj vius gLRkk{kj djsaA buesa ls dksbZ Hkh
tkudkjh dgha vkSj u fy[ksaA jksy uEcj ds gj vad ds uhps vuq:i cqycqys dks dkyk djsaA
ORS ij cqycqyksa dks dkyk djus dh fof/k % :
 Åijh ewy i`"B ds cqycqyksa dks dkys ckWy ikbUV dye ls dkyk djsaA
 cqycqys dks iw.kZ :i ls dkyk djsaA
 cqycqyksa dks rHkh dkyk djsa tc vkidk mÙkj fuf'pr gksA
 cqycqyksa dks dkyk djus dk mi;qDr rjhdk ;gk¡ n'kkZ;k x;k gS %
 dkys fd;s gq;s cqycqys dks feVkus dk dksbZ rjhdk ugha gSA
 gj [k.M ds izkjEHk esa nh x;h vadu ;kstuk esa dkys fd;s x;s rFkk dkys u fd;s x;s cqycqyksa dks ewY;kafdr djus dk rjhdk fn;k x;k gSA.
iw.kkZad@la[;kRed vad ds fy, ORS fuEu çdkj gS :
 mnkgj.k ds fy, , ;fn mÙkj ‘,dy vadh;’ iw.kkZad gS rc :
 0 1 2 3 4 5 6 7 8 9
 mnkgj.k ds fy, , ;fn mÙkj ‘,dy vadh;’ iw.kkZad /kukRed @ _.kkRed gS rc :
0
– 1
2
3
4
5
6
7
8
9
 mnkgj.k ds fy, , ;fn mÙkj ‘f)&vadh;’ iw.kkZad gS rc :
0 0
1 1
2 2
3 3
4 4
5 5
6 6
7 7
8 8
9 9
n'keyo iw.kkZad@la[;kRed vadksa ds fy, ORS fuEu çdkj gS :
COLUMN
1 2 . 3 4
0 0 0 0
1 1 1 1
2 2 2 2
3 3 3 3
4 4 4 4
5 5 5 5
6 6 6 6
7 7 7 7
8 8 8 8
9 9 9 9
 ;fn mÙkj 3.7 gS rc 3 dks 1st ;k 2nd dkWye esa Hkjsa rFkk 7 dks 3rd ;k 4th dkWye esa HkjsaA
 ;fn mÙkj 3.07 gS rks 3 dks 1st dkWye ;k 2nd dkWye esa Hkjsa rFkk ‘0’ dks 3rd dkWye esa rFkk 7 dks 4th dkWye esa HkjsaA
 ;fn mÙkj 23 gS rc 2 dks 1st dkWye esa ] 3 dks 2nd dkWye esa tcfd 3rd vkSj 4th dkWye dks [kkyh NksM+ nsa ;k ‘'kwU; Hkj nsaA

MATHEMATICS
PAPER-1
SECTION – 1 : (Maximum Marks : 56)

 This section contains FOURTEEN (14) questions
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s)
is(are) correct
 For each question, marks will be awarded in one of the following categories :
 Partial Marks : +2 If three or more options are correct but ONLY two options are chosen
and both of which are correct.
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and
it is a correct option.
 For example, in a question, if (A),(B) and (D) are the ONLY three options corresponding to correct answers,
then :
 Choosing ONLY (A),(B) and (D) will get +4 marks
 Choosing ONLY (A) and (B) will get +2 marks
 Choosing ONLY (A) and (D) will get +2 marks
 Choosing ONLY (B) and (D) will get +2 marks
 Choosing ONLY (A) will get +1 marks
 Choosing ONLY (B) will get +1 marks
 Choosing ONLY (D) will get +1 marks
 Choosing no option (i.e. the question is unanswered) will get 0 marks, and
 Choosing any other combination of options will get –1 mark
[kaM 1 : (vf/kdre vad : 56)

 bl [kaM esa pkSng (14) iz'u gSaA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 vkaf'kd vad % +2 ;fn rhu ;k rhu ls vf/kd fodYi lgh gS ijUrq dsoy nks fodYiksa dks pquk x;k gS vkSj
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PAGE-1
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nksauks pqus gq, fodYi lgh fodYi gSaA
 vkaf'kd vad % +1 ;fn nks ;k nks ls vf/kd fodYi lgh gSa ijUrq dsoy ,d fodYi dks pquk x;k gS vkSj
pquk gqvk fodYi lgh fodYi gSA
 mnkgj.k% ;fn fdlh iz'u ds fy, dsoy fodYi (A),(B) vkSj (D) lgh fodYi gS] rc %
 dsoy fodYi (A),(B) vkSj (D) pquus ij +4 vad feysaxs ’
 dsoy fodYi (A) vkSj (B) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (B) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) pquus ij +1 vad feysaxs ’
 dsoy fodYi (B) pquus ij +1 vad feysaxs ’
 dsoy fodYi (D) pquus ij +1 vad feysaxs ’
 dksbZ Hkh fodYi u pquus ij ¼vFkkZr~ iz'u vuqÙkfjr jgus ij½ 0 vad feysaxs vkSj
 vU; fdlh fodYiksa ds la;kstu dks pquus ij –1 vad feysaxs
1

1.

Let n = x n tan–1x dx. If ann+2 + bnn =
0
2
– Cn  n  1 then
(A*) a1, a2, a3, ...... are in A.P. (B*) b1, b2, b3, ...... are in A.P.
  
(C*) c1, c2, c3, ...... are in H.P. (D) – c1, – c2, – c3, ...... are in H.P.
2 2 2
1

ekuk n =  x n tan–1x dx. ;fn ann+2 + bnn = – Cn  n  1 rc
2
0
(A*) a1, a2, a3, ...... lekUrj Js<h esa gSA (B*) b1, b2, b3, ...... lekUrj Js<h esa gSA
  
(C*) c1, c2, c3, ...... gjkRed Js<h esa gSA (D) – c1, – c2, – c3, ...... gjkRed Js<h esa gSA
2 2 2

1
1 1 xn3
 1 x
1
Sol. n+2 = xn+3 tan–1 x – dx
n3 0
n3 2
0
1 n3
 x
 (n + 3)n+2 =
4
–
 1 x
0
2
dx
1
 xn1
IIIry (n + 1)n =
4
–
 1 x
0
2
dx
1
  1
x
n1
 (n + 3)n+2 + (n + 1)n = – dx = –
2 2 n2
0
1
 an = n + 3, bn = n + 1, cn = –
n2
n 1 2
n
k 2  n2 k  n2
2. Let Sn   and Tn   for n = 1,2,3 …….. then
k 1 n3 k 0 n3
n 1
n
k 2  n2 k 2  n2
ekuk Sn   vkSj Tn   , n = 1,2,3 …….. ds fy, rc -
k 1 n3 k 0 n3
4 4 4 4
(A) Sn  (B) Tn  (C*) Sn  (D*) Tn 
3 3 3 3
PAGE-2
1 n  k2 
Sol. We have Sn  
 2  1
n k 1  n 
We have f(x)  x2  1 , which is increasing in [0,1]
1
Clearly, Sn   (x 2  1)dx
0
4
 Sn  ………………(i)
3
4
Similarly, Tn 
3
4
Tn   Sn
3
1 n  k2 
Hindi ;gk¡ Sn    2  1
n k 1  n 
;gk¡ f(x)  x  1 rc [0,1] esa o/kZeku gSA
2
1
Li"Vr;k, Sn  0 (x 2  1)dx
4
 Sn  ………………(i)
3
4
blh izdkj, Tn 
3
4
Tn   Sn
3
3. Which of the following is/are correct?

(A*) If in a triangle ABC, sin3A + sin3B + sin3C = 3 sinA . sinB . sinC, then
a3 + b3 + c3 = 3abc
(B*) If the bisector of angle A of triangle ABC makes an angle  with BC, then
BC
sin  cos
2
sin2 A  sinA  1
(C) In any triangle ABC, minimum value of
A,B,C
sinA is 9
 sin2 A  sinA  1
(D) In any triangle ABC, minimum value of  

A,B,C 
sinA
 is 27


fuEu esa ls dkSulk lgh gS ?
(A*) f=kHkqt ABC esa;fn sin3A + sin3B + sin3C = 3 sinA . sinB . sinC rc a3 + b3 + c3 = 3abc
BC
(B*) ;fn f=kHkqt ABC ds dks.k A dk v)Zd] BC ds lkFk dks.k  cukrk gS rc sin  cos
2
sin2 A  sinA  1
(C) fdlh f=kHkqt ABC esa ;fn 
A,B,C
sinA
dk U;wure eku 9 gS
 sin2 A  sinA  1
(D) fdlh f=kHkqt ABC esa  

A,B,C 
sinA
 dk U;wure eku 27 gSA


Sol.  sin3A + sin3B + sin3C = 3 sin A sin B sin C

 sin A + sin B + sin C = 0 or sin A = sin B = sin C
not possible laHko ugha a=b=c (A)
PAGE-3
A
B   
2
 B C
B   
2
   B  C 
      
 2  2 
BC
sin  cos (B)
2
1 dt   3 t 3 sin2 t 

   x 
dt   2  0 , (0 <  < ) then the value of x
2
4. If x satisfies the equation x
 t 2  2t cos   1  t2  1 
0   3 
can be -
1 dt   3 t 3 sin2 t 
 
2 
;fn x lehdj.k x  x dt   2  0 , (0 <  < ) dsk larq"V djrk gS rc x dk eku gks
 t 2  2t cos   1  t2  1 
0   3 
ldrk gS -
s in sin s in sin
(A*) 2 (B*)  2 (C) 4 (D)  4
   
3 3
t sin2 t
Sol. I1  
3
1  t 2
dt  0 ( it is odd function)( ;g fo"ke Qyu gS)
1 1 1
dt dt 1  1 t  cos  
I2  
0
t  2t cos   1
2
 
0
( t  cos  )  sin 
2 2
 tan 
sin 

 sin  0
1  1 1  cos    cos  
 tan    tan1 
sin   sin    sin 
1  1 1  1  cos      
 cot cot   cot    property  xq. k/kZe 
sin   sin  2  2 
1  1 
 cot cot   cot 1 cot     (0, )
sin  2


2 sin
given equation nh xbZ lehdj.k

. x2  2  0
2 sin
4 sin
x2 

s in
x2 (A), (B)

PAGE-4

5. If area bounded by f(x) = sin(x2) with x axis, from x = 0 to x = is A, then
2

;fn f(x) = sin(x2) }kjk x = 0 ls x = ds e/; x v{k ds lkFk cuk;k x;k {ks=kQy A gS] rks
2
3
2       sin1
(A*) A  (B*) A    1  sin1 (C*) A  
 
 1  sin1
 (D) A 
6 2  2   2  3
/2
Sol. A 
0
sin(x 2 )dx
put x2 = t j[kus ij
2xdx = dt
/2
sin t
A 
0 2 t
dt
 
 sint < t  t   0, 2 
 
/2
t
A  
0
2
dt
3
 2
A
6 2

A  sin1  1
2
  
A  1 sin1
 2 
 
2 2
6. If the area enclosed by the curves max {|x|, |y|}  3 and y  – x + 3 is K, then K is divisible by
3
2 2
;fn oØksa max {|x|, |y|}  3 vkSj y  – x + 3 ls ifjc) {ks=kQy K gS] rc K fdlls foHkkftr gS&
3
(A*) 3 (B*) 6 (C) 8 (D*) 12
Sol. Case-I |x| > |y|
y
y=3
y=x
x=3
x
y=3
y=–3
PAGE-5
Case-II |x| |y|
y
y=3
x=3
x
x=–3
y=–3
union of case (I) and case (II) is a complete square.

y
y=3
x=3
x
1
Area of the shaded region = × Area of the square
3
1
= × 36 = 12
3
Sol. fLFkfr-I |x| > |y|
y
y=3
y=x
x=3
x
y=3
y=–3
fLFkfr-II |x| |y|
PAGE-6
y
y=3
x=3
x
x=–3
y=–3
fLFkfr (I) vkSj (II) dk la?k iw.kZ oxZ gSA

y
y=3
x=3
x
1
Nka;kfdr Hkkx dk {ks=kQy = × oxZ dk {ks=kQy
3
1
= × 36 = 12
3
 2x  8  1
7. If   (x  1)(x  3)(x  5)(x  7)  16  dx    f (x)
where f(x) is of the form of ax2 + bx + c, then -
(A*) f(x) = 0 has complex roots (B*) a + b + c = 4
(C*) f(x) = 0 has irrational roots (D) f(x) = 0 has rational roots
 2x  8  1
;fn    dx   
 ( x  1) ( x  3) ( x  5) ( x  7)  16  f ( x)
tgk¡ f(x) dk :i ax2 + bx + c esa gS rc -
(A*) f(x) = 0 ds lfEeJ ewy gSA (B*) a + b + c = 4

(C*) f(x) = 0 vifjes; ewy gSA (D) f(x) = 0 ds ifjes; ewy gSA
2x  8
Sol. I  (x 2
 8x  7) ( x 2  8x  15)  16
dx
put x2 – 8x = t j[kus ij
dt
I  (t  7) (t  15)  16
dt
  (t  11) 2
1 1
 c  c
t  11 x  8x  11
2
PAGE-7
8. If A and B are two non-singular matrices of order 3 such that – AB is an invertible matrix, then which of
the following statement is/are correct?
(A*) –BA is invertible (B) –BA is not invertible
(C) –BA has its inverse  + A (– BA)–1 B (D*) –BA has its inverse  + B (– AB)–1 A
;fn A vkSj B nks 3 Øe dh nks O;qRØe.kh; vkO;wg bl izdkj gS fd – AB izfrykseh; vkO;wg gS rc fuEu esa ls dkSulk
dFku lgh gS ?
(A*) –BA izfrykseh; gSA (B) –BA izfrykseh; ugh gSA
(C) –BA dk izfrykse  + A (– BA)–1 B gSa (D*) –BA dk izfrykse  + B (– AB)–1 A gSA
Sol. | I  AB |  0
| A 1  B |  0
| A 1A  BA |  0
| I  BA |  0 (A)
Say ekuk (I  AB ) 1 P
I  (I  AB) P
I  P  ABP
 A 1  A 1 P  BP
 I  A 1 PA  BPA
I  BPA  A 1 (I  AB )1 A
 ((I  AB )A )1( A 1 )1
 ( A 1(I  AB )A )1
 ( A 1( A  ABA ))1
 ( I  BA )1
9. In a ABC, A   ,  , B  1, 2 , C  2, 3  and point ‘A’ lies on the line y  2x  3 where ,   integer
and area of the triangle is S such that [S] = 2 where [.] denotes the greatest integer function. Then possible
coordinates of A is/are
,d ABC, A  ,  , B  1, 2 , C   2, 3 rFkk js[kk y  2x  3 ij fcUnq ‘A’ fLFkr gS tgka ,   iw.kkZad rFkk
f=kHkqt dk {ks=kQy S gS rkfd [S] = 2 tgka [.] egÙke iw.kkZad Qyu dks iznf'kZr djrk gSA rks A ds lHkh lEHkkfor funsZ'kkad
gS&
(A*)  7,  11 (B*)  6,  9 (C*) (2, 7) (D*) (3, 9)
Sol : The point A  ,  lies on y  2x  3 . Hence,
fcUnq A ,  js[kk y  2x  3 ij fLFkr gS vr%
  2  3
A   , 2  3
Area of ABC ( ABC dk {ks=kQy)
 2  3 1
1
= 1 2 1
2
2 3 1
1
   2  3    2  3  2  1  1 3  4  
2
1 1
   2  3  1    2  S
2 2
 S  2  2  S  3
PAGE-8
1
 2 2 3
2
4 2 6
  2  6  6    2  6  8    4 (i)
And rFkk   2  4    2  4 or   2  4
   2 or   6 (ii)
From Eqs. (i) and (ii),
lehdj.k (i) rFkk (ii),
8    6 or 2    4
   7,  6, 2, 3
Possible coordinates of A are  7,  11 ,  6,  9 ,  2, 7 , 3, 9 .
A ds lEHkkfor funsZ'kkad  7,  11 ,  6,  9 ,  2, 7 , 3, 9 gSA
10. If a, b, c, d are the roots of the equation x 4  x  1999  0 , then -
abc abd ac d bc d
(A*) equation having roots , , , is x 4 1999  x 3  1  0
d2 c2 b2 a2
is 1999 x  x  1  0
4 3
(B) equation having roots , , ,
d2 c2 b2 a2
(C) equation having roots
1999 (a  b  c ) 1999 (a  b  d) 1999 (a  c  d) 1999 (b  c  d)
, , , is
abc abd acd bcd
x 4  2 1999 x 2  2 x  1999  0
(D*) equation having roots
1999 (a  b  c ) 1999 (a  b  d) 1999 (a  c  d) 1999 (b  c  d)
, , , is
abc abd acd bcd
x 4  2 1999 x 2   2 x  1999  0
;fn a, b, c, d lehdj.k x 4  x  1999  0 ds ewy gS rc -
(A*) ewyksa , , , dh lehdj.k x 4 1999  x 3  1  0 gS
d2 c2 b2 a2
(B) ewyksa , , , dh lehdj.k 1999 x 4  x 3  1  0 gSA
d2 c2 b2 a2
1999 (a  b  c ) 1999 (a  b  d) 1999 (a  c  d) 1999 (b  c  d)
(C) ewyksa , , , dh lehdj.k
abc abd acd bcd
x 4  2 1999 x 2  2 x  1999  0 gSA
1999 (a  b  c ) 1999 (a  b  d) 1999 (a  c  d) 1999 (b  c  d)
(D*) ewyksa , , , dh lehdj.k
abc abd acd bcd
x 4  2 1999 x 2   2 x  1999  0 gSA
Sol. x 4  x  1999  0  a, b, c, d
a + b + c + d = 0, abcd   1999
abc d 1
2
 2 
d d d
1 1 1 1
Equation having roots  ,  ,  , 
a b c d
1 1 1 1
lehdj.k ftlds ewy  ,  ,  ,  gSA
a b c d
PAGE-9
1
X
x
1
put x   in equation
X
1
x dks lehdj.k esa j[kus ij x 4 1999  x 3  1  0
X
1999 (a  b  c ) 1999 ( d)
  d2
abc 1999

d
so equation having roots a2, b2, c2, d2
blfy, lehdj.k esa ewy a2, b2, c2, d2 gSA
can be find by X = x2
X = x2 ls
 x  X in given equation
11. If the (m + 1)th, (n + 1)th and (r + 1)th terms of an A.P. are in G.P. and m, n, r are in H.P., then :
r
(A) common ratio of G.P. so formed is
n
r
(B*) common ratio of G.P. so formed is
m
2
(C*) ratio of the common difference to the first term in the A.P. is –
n
1
(D) ratio of the common difference to the first term in the A.P. is –
2n
;fn lekUrj Js.kh ds in (m + 1)th, (n + 1)th vkSj (r + 1)th xq.kksÙkj Js.kh esa gS rFkk m, n, r gjkRed Js.kh esa gS rc -
r
(A) xq.kksÙkj Js.kh dk lkoZvuqikr gSA
n
r
(B*) xq.kksÙkj Js.kh dk lkoZvuqikr gSA
m
2
(C*) lekUrj Js.kh esa lkoZvUrj vkSj izFke in dk vuqikr – gSA
n
1
(D) lekUrj Js.kh esa lkoZvUrj vkSj izFke in dk vuqikr – gSA
2n
Sol. t m1, t n1, t r 1  G.P.
a  nd a  rd

a  md a  nd
a  nd a  rd a  nd  (a  rd)
  
a  md a  nd a  md  (a  nd)
(n  r )

mn
r
 ( m, n, r  H.P.)
m
a  rd r

a  nd m
a(m  r )  r.d (n  m)
 2mr 
 r.d   m
m  r 
PAGE-10
r.d. m(r  m)
a(m  r ) 
(m  r )
d (m  r ) 2
 
a mr n
sin2 x. sec2 x  2 1  x 2 tan x. sin1 x

12. If  1  x 2 (1  tan2 x)
dx  f (x)  c , where f(0) = 0, then -
(A) f(x) = (sin–1 x) cos2x (B*) f(x) = (sin–1 x) sin2x

       
(C) Range of f(x) is  cos2 1, cos2 1 (D*) Range of f(x) is  sin2 1, sin2 1
 2 2   2 2 
sin2 x. sec2 x  2 1  x 2 tan x. sin1 x
;fn  1  x 2 (1  tan2 x)
dx  f (x)  c tgk¡ f(0) = 0 rc -
(A) f(x) = (sin–1 x) cos2x (B*) f(x) = (sin–1 x) sin2x

       
(C) f(x) dk ifjlj  cos2 1, cos2 1 gSA (D*) f(x) dk ifjlj  sin2 1, sin2 1 gSa
 2 2   2 2 
 sin2 x 2 tan x sin1 x 
Sol. I1  

 1

 x 2

sec 2
x 

dx
 sin2 x 
 

 1 x
2
 sin2x. sin1 x  dx


 (sin2 x) (sin1 x)  c
f ( x)  (sin2 x) (sin1 x)
sin2 x
f ' ( x)   sin2x sin1 x  0  x  [1, 1]
1 x 2
so f(x) is increasing function

blfy, f(x) o/kZeku Qyu gSA
   
Range ifjlj   sin2 1, sin2 1
 2 2 
13. On a circle with centre (2, 1) and radius 3, a variable point ‘A’ is taken, such that perpendiculars from ‘A’ on
a diameter (not containing ‘A’) of circle are divided by a point B in a fixed ratio 1 : 3. Then
(A) locus of point B is a circle with radius 1.
7
(B*) locus of point B is an ellipse concentric with circle with eccentricity .
4
(C) locus of point B is hyperbola with centre as (0, 0) and eccentricity 2 .
(D*) If locus of B is a curves ‘S’ then the locus of perpendicular drawn from foci of S upon any tangent to it,
is the given circle itself
3 bdkbZ f=kT;k ,oa (2, 1) dsUnz okys o`Ùk ij ,d pj fcUnq ‘A’ bl izdkj gS fd ‘A’ ls o`Ùk O;kl ij (tks ‘A’ ls ugh
xqtjrk) Mkys x;s yEc fdlh fcUnq B }kjk ,d fuf'pr vuqikr 1 : 3 esa foHkkftr gksrk gS rc -
(A) fcUnq B dk fcUnqiFk] 1 f=kT;k okyk o`Ùk gksxkA
7
(B*) fcUnq B dk fcUnqiFk] fn;s x;s o`Ùk ds ladsUnzh; ,oa mRdsUnzrk okyk ,d nh?kZo`Ùk gksxkA
4
(C) fcUnq B dk fcUnqiFk ,d vfrijoy; gksxk ftldk dsUnz (0, 0) ,oa mRdsUnzrk 2 gksxhA
(D*) ;fn fcUnq B dk fcUnqiFk ,d oØ ‘S’ gks rks S dh ukfHk ls S dh fdlh Li'kZ js[kk ij Mkys x;s yEcikndk fcUnqiFk
fn;k x;k o`Ùk Loa; gh gksxkA
Sol. ‘B’ lies on ellipse whose length of semi major axis = 3 and length of semi minor axis = 9/4
PAGE-11
‘B’ ,d nh?kZo`Ùk ij fLFkr gksxk ftlds nh?kZ v{k,oa y?kqv{k dh yEckbZ;k¡ Øe'k% = 3 ,oa = 9/4 gksxhA
 AB a  b 
 Ration vuqikr BN  b 
 
B A
(2, 1)

N
14. If , ,  are roots of equation a tan3 + (2a – b) tan + k = 0 given tan + tan = p and tan . tan = q then
;fn , , lehdj.k tan3 + (2a – b) tan + k = 0 ds ewy gS rFkk tan + tan = p vkSj tan . tan = q rc
(A*) ap3 + (2a – b)p = k (B*) k2 + (2a – b)aq2 = a2q3
(C) p = q (D) k3 + (2a – b)a2q2 = a3q3
Sol. We have tan + tan + tan = 0
 tan  = – p
 a(–p)3 + (2a – b)(–p) + k = 0 – option (A)
k
and tan tan tan = –
a
k
tan  = –
aq
3
 k   k 
 a  –  + (2a – b)  –  + k = 0
 aq   aq 
 k2 + (2a – b)aq2 – a2q3 = 0 ........option (B)
gy. ;gka tan + tan + tan = 0

 tan  = – p
 a(–p)3 + (2a – b)(–p) + k = 0 – fodYi (A)
k
rFkk tan tan tan = –
a
k
tan  = –
aq
3
 k   k 
 a  –  + (2a – b)  –  + k = 0
 aq   aq 
 k2 + (2a – b)aq2 – a2q3 = 0 ........ fodYi (B) ls

 This section contains TWO (02) paragraphs.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct 
 Marking scheme :
 Full Marks : +3 If ONLY the correct option is chosen.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –1 In all other cases
 bl [kaM esa nks (02) vuqPNsn gSaA izR;sd vuqPNsn ij nks iz'u gaSA
PAGE-12
 vadu ;kstuk :
 'kwU; vad % 0 ;fn dksbZ Hkh fodYi ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A

Paragraph for Question Nos. 15 to 16
x 2
x2
y = f(x) satisfies the relation

2
f(t)dt 
2 
 t 2 f(t)dt .
x
x 2 2
x
y = f(x) lEcU/k  f(t)dt  
 t 2 f(t)dt dks larq"V djrk gSA
2
2 x
15. Area bounded y = f(x) with x-axis between its points of extrema is
oØ y = f(x) dk blds pje fcUnqvksa ds e/;] x-v{k ls ifjc) {ks=kQy gS&
1 3
(A) n2 (B*) n2 (C) n3 (D) n
2 2
16. If equation f(x) = k has one solution, then the value of k can not be
;fn lehdj.k f(x) = k ,d gy j[krk gS] rc k dk eku cjkcj ugha gks ldrk gS&
1 1
(A) (B*) 1 (C) 0 (D) –
2 2
Sol. Using Leibnitz yscfut ls f(x) – 0 = x + 0 – 1. x2 f(x)
x  1 1
 f(x)   f(x)    , 
1  x2  2 2

iz'u 17 ls 18 ds fy, vuqPNsn
aij  a ji
Let A = [aij]n×n and D(A) = [bij]n×n where bij = ,  i, j
2
aij  a ji
ekuk A = [aij]n×n vkSj D(A) = [bij]n×n tgk¡ bij = ,  i, j
2
17. The number of 3 × 3 matrices A, whose elements are selected from the set {0, 1, 2, 3} such that D(A) = A,
is
3 × 3 Øe ds vkO;wgks A dh la[;k ftuds vo;o leqPp; {0, 1, 2, 3} esa ls bl izdkj pqusa x;s gS fd D(A) = A gS, gksxh
-
(A) 29 (B*) 212 (C) 26 (D) 28
b11 b12 b13   a11 a12 a13 

 b23   a21 a22 a23 
Sol. D(A) = A  b21 b22
b31 b32 b33  a31 a32 a33 
 bij  aij
aij  a ji
  aij ,  i, j
2
 aij  a ji
 A is a symmetric matrix.
A ,d lefer vkO;wg gS
PAGE-13
 4 × 4 × 4 × 4 × 4 × 4 = 212
18. If D(A) and A both matrices are of order 3 × 3 such that D(A) = A, then which of the statements are true?
(i) A is a scalar matrix (ii) A is symmetric matrix
(iii) A may be a unit marix (iv) D(A) = D(AT)
(A) (i), (iii), (iv) (B*) (ii), (iii), (iv) (C) (i), (iv) (D) (i), (ii), (iii), (iv)
;fn 3 × 3 Øe ds vkO;wg A rFkk vkO;wg D bl izdkj gS fd D(A) = A rc fuEufyf[kr esa ls dkSulk dFku lR; gS -
(i) A ,d vfn'k vkO;wg gS (ii) A ,d lefer vkO;wg gS
(iii) A ,d bdkbZ vkO;wg gks ldrk gS (iv) D(A) = D(AT)
(A) (i), (iii), (iv) (B*) (ii), (iii), (iv) (C) (i), (iv) (D) (i), (ii), (iii), (iv)
Sol. D(A) = A  A is a symmetric matrix
D(A) = A  A ,d lefer vkO;wg gS
 A = AT
 D(A) = D(AT)
Also a symmetric matrix A can be a unit matrix.
iqu% lefer vkO;wg A, ,d bdkbZ vkO;wg gks ldrk gS
Hence (ii), (iii) & (iv) are correct.
vr% (ii), (iii) ,oa (iv) lgh gS
D(A) is a scalar matrix
D(A) ,d vfn'k vkO;wg Gs
PAGE-14
PAPER-1


 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s)
is(are) correct
then :

 vU; fdlh fodYiksa ds la;kstu dks pquus ij –1 vad feysaxs
PAGE-15
19. Switch S1 is closed for a long time while S2 remains open. Now at t = 0, S2 is closed while S1 is opened.
The battery is ideal and connecting wires are resistance less. The capacitor 'C' is initially uncharged then
select correct statement(s)
fLop S1 yEcs le; ls cUn (closed) gS tcfd S2 [kqyk (open) jgrk gSA vc t = 0 ij S2 cUn gS tcfd S1 [kqyk gSA
cSVjh vkn'kZ gS rFkk la;ksftr rkj çfrjks/kghu gSA la/kkfj=k 'C' çkjEHk esa vukosf'kr gSA lgh fodYi pqfu;sasA

(A*) At time t = 0, reading of ammeter is .
5R
(B) At time t = 0, reading of ammeter is zero
9
(C*) Heat developed till time t = 5RC n2 in resistance 3R is C2
40
t

(D*) After time t > 0 charge on the capacitor follows the equation Cεe 5RC

(A*) t = 0, le; ij vehVj dk ikB;kad gSA
5R
(B) t = 0 le; ij] vehVj dk ikB;kad 'kwU; gSA
9
(C*) t = 5RC n2 rd çfrjks/k 3R esa mRiUu Å"ek C2 gSA
40
t

(D*) t > 0 le; i'pkr~ la/kkfj=k ij vkos'k lehdj.k Ce 5RC
dk vuqlj.k djrk gSA
Sol. At t = 0– ij At t = 0 ij

i=
5R
Equation of charge of capacitor la/kkfj=k ds vkos'k dh lehdj.k
q = ce–t/
q = ce–t/5RC
at t = 5 RC n 2 ij
c
q=
2
1 2 1 2 3 2
Change in energy of capacitor la/kkfj=k dh ÅtkZ esa ifjorZu = c – c = c
2 8 8
3 2 3 9
Heat in 3R (3R esa Å"ek) = c × = c2
8 5 40
20. The conductor AB of mass 1kg is sliding over two parallel conducting rails separated by a distance of 1m
 
and is in a region of inward uniform magnetic field B  0.1 kˆ . At time t = 0, AB is projected towards right
with speed v0 .
PAGE-16
1kg nzO;eku dk pkyd AB, 1m dh nwjh ij fLFkr nks lekUrj pkyd iVfj;ks ij fQly jgk gS rFkk vUnj dh vksj ,d
leku pq- {kS=k B  0.1 kˆ  ds {ks=k esa gSA t = 0 le; ij AB, v0 pky ls nkW;h vksj iz{ksfir fd;k tkrk gSA
t

600
(A*) the velocity of AB as a function of time is given as v = v 0 e
t

AB dk osx le; ds Qyu ds :i eas v = v 0 e 600
}kjk fn;k tkrk gSA
v0
(B*) the velocity of rod becomes at t = 600 n(2)
2
v0
t = 600 n(2) ij NM dk osx gks tk;sxkA
2
v
(C*) the induced current is 0 A at t = 600 n(2)
120
v0
t = 600 n(2) ij izsfjr /kkjk A gSA
120
v  
t
(D*) the induced emf as a function of time is given as  0  e 600

 10 
v 
t

izsfjr fo|qr okgd cy le; ds Qyu ds :i esa  0  e 600
}kjk fn;k tkrk gSA
 10 
Sol. Retarding force eanu cy F = B0 
B v 
2
B .v.
= B0  0   = 0
 R  6
2
B0 v
retardation = (at any instant of time)
6 1
2
B0 v
eanu = (fdlh Hkh le; ij)
6 1
2
B0 v dv –dv B 2  v  t
=–  =  0  dt n  0  
6 dt v  6   
v 600
 
t

v  v0e 600
v0
At t = 600 n (2)  v=
2
v0
t = 600 n (2) ij  v=
2
t
B0 v Bv Bv v v 0  600
i=  0  0 0  0 [ R = 6 , |B0| = 0.1 T] E = B0 v = e
R R 12 120 10
21. A capacitor of capacitance C and an ideal inductor of inductance L are connected in series with an ideal
battery of emf E. The resistance of circuit is negligible. If initially capacitor is uncharged and key is closed
at t = 0 then select the correct statement(s) :
PAGE-17
C /kkfjrk dk ,d la/kkfj=k rFkk L izsjdRo dh ,d vkn'kZ izsjd dq.Myh Js.khØe esa E fo|qr okgd cy dh vkn'kZ cSVjh
ls tqM+s gq, gSA ifjiFk dk izfrjks/k ux.; gSA ;fn izkjEHk esa la/kkfj=k vukosf'kr gS ,oa t = 0 ij dqath can dh tkrh gS rc
lgh dFku@dFkuksa dk p;u fdft,A
(A) Maximum charge on capacitor is CE

la/kkfj=k ij vf/kdre~ vkos'k CE gksxkA
(B*) Maximum charge on capacitor is 2CE
la/kkfj=k ij vf/kdre~ vkos'k 2CE gksxkA
(C*) Maximum potential difference across inductor is E
izsjd dq.Myh ds fljks ij vf/kdre~ foHkokUrj E gksxkA
(D) Maximum potential difference across inductor is 2E
izsjd dq.Myh ds fljks ij vf/kdre~ foHkokUrj 2E gksxkA
Sol. W B = UC + UL
when q is maximum i = 0  UL = 0
tc q vf/kdre~ gS i = 0  UL = 0
q2
qE =  qmax = 2CE
2C
Charge on the capacitor will oscillates between 0 & 2CE
la/kkfj=k ij vkos'k 0 o 2CE ds e/; nksyu djsxkA
By KVL ls
q
E= + VL
C
Minimum value of q is zero so maximum value of VL = E
q dk U;wure~ eku 'kwU; gS vr% VL dk vf/kdre~ eku = E gksxkA
22. An ideal inductor, (having initial current zero) a resistor and an ideal battery are connected in series at time
t = 0. At any time t, the battery supplies energy at the rate PB, the resistor dissipates energy at the rate PR
and the inductor stores energy at the rate PL.
,d vkn'kZ izsjdRo ('kwU; izkjfEHkd /kkjk), ,d izfrjks/k rFkk ,d vkn'kZ cSVjh dks t = 0 ij Js.khØe esa tksM+rs gSaA fdlh
le; t ij] cSVjh PB nj ls ÅtkZ iznku djrh gS] izfrjks/k PR nj ls ÅtkZ àkl djrk gS rFkk izsjdRo PL nj ls ÅtkZ
lafpr djrk gS &
(A*) PB = PR + PL for all times t. (B) PR < PL for all times t.
(C*) PR < PL only near the starting of the circuit. (D) PR > PL only near the starting of the circuit.
(A*) lHkh le; t ij PB = PR + PL (B) lHkh le; t ij PR < PL
(C*) ifjiFk ds 'kq: gksus ds rqjUr ckn PR < PL (D) ifjiFk ds 'kq: gksus ds rqjUr ckn PR > PL
Sol. By principal of energy conservation. PB = PR + PL
di
Near the starting of the circuit PR = i2 R and PL = L i .
dt
di
As has greater value at the starting of the circuit, PL > PR
dt
gy% ÅtkZ laj{k.k ds fl)kUr ls & PB = PR + PL
di
ifjiFk 'kq: gksus ds utnhd & PR = i2 R rFkk PL = L i .
dt
di
ifjiFk 'kq: gksus ds le; dk eku T;knk gksxk & PL > PR
dt
PAGE-18
23. Two spherical soap bubbles in vaccum are connected through a narrow tube. Radius of left bubble is R
and that of other is slightly smaller than R. Air flows from right to left very slowly. At any instant r 1, A1, V1, n1
are radius, surface area, volume and number of moles of gas in the left bubble and r 2, A2, V2, n2 are same
for right bubble. Assume that temperature remains constant :
fuokZr esa nks xksyh; lkcqu ds cqycqysa ,d iryh ufydk }kjk tqM+s gq, gSA ck;sa cqycqys dh f=kT;k R gS ,oa vU; dh
f=kT;k R ls gYdh lh de gSA fdlh {k.k ij ck;sa cqycqys dh f=kT;k] i`"Bh; {ks=kQy] vk;ru ,oa xSl ds v.kqvksa dh
la[;k Øe'k% r1, A1, V1, n1 gS rFkk nka;s cqycqys ds fy, blhizdkj r2, A2, V2, n2 gSA ekfu,sa fd rkieku fu;r jgrk gS :
Suppose at any instant number of moles in left bubble is 4 times of number of moles in right bubble then
select correct statement(s) :
ekfu,sa fd fdlh {k.k ij cka;s cqycqys esa eksyksa dh la[;k nka;s cqycqys esa eksyksa dh la[;k dk 4 xquk gS] rc :
2 8
(A*) r2 = R (B*) r1 = R
5 5
(C*) A1 + A2 = constant (D) V1 + V2 = constant
4s
Sol. Pressure in left bubble cka;s cqycqys esa nkc =
r1
4 3
Volume of left bubble cka;s cqycqys dk vk;ru = r1
3
4s 4
Pressure in right bubble nka;s cqycqys esa nkc = = r23
r 3
n1 + n2 = 2n
r12 + r22 = 2R2
A1 + A2 and rFkk n1 + n2 are constant fu;r gS
n1 r12 4 2R 2
 2   r22 
n2 r2 1 5
2
r2  R
5
8
r1  R
5
24. A proton is fired from origin with velocity v  v 0 ˆj  v 0kˆ in a uniform magnetic field B  B0 ˆj
In the subsequent motion of the proton
(A) its z-coordinate can never be negative
(B*) its x-coordinate can never be positive
(C) its x-and z-coordinates cannot be zero at the same time
(D*) its y-coordinate will be proportional to its time of flight
,d izksVkWu dks ewy fcUnq ls osx v  v 0 ˆj  v 0kˆ ls ,d leku pqEcdh; {ks=k B  B0 ˆj esa nkxk tkrk gSA
izksVkWu dh v/kksfyf[kr xfr esa
(A) bldk z-funsZ'kkad dHkh&Hkh _.kkRed ugha gks ldrk gSA
(B*) bldk x-funsZ'kkad dHkh&Hkh /kukRed ugha gks ldrk gSA
(C) bldk x-rFkk z-funsZ'kkad leku le; ij 'kwU; ugha gks ldrk gSA
(D*) bldk y- funsZ'kkad blds mM~M;u dky ds lekuqikrh gksxkA
Sol. The path of the particle will be helix as shown in figure. Clearly x-coordinate is always negative. z-
coordinate can be negative and positive both. x and z coordinate will be zero at the same time at points A,
C etc.
PAGE-19
y = v0t  y  t
fp=k esa n'kkZ;s vuqlkj d.k dk iFk gsyhDl gksxkA Li"Vr% x-funsZ'kkad ges'kk _.kkREkd gksxkA z- funsZ'kkad _.kkRed o
/kukRed gks ldrk gSA x rFkk z funsZ'kkad leku le; ij fcUnq A, C bR;kfn;ksa ij 'kwU; gksxk
y = v0t  y  t
25. Two capacitor of 2 F and 3 F are charged to 150 volt and 120 volt respectively. The plates of a
capacitors are connected as shown in the figure. A discharged capacitor of capacity 1.5 F falls to the free
ends of the wire. Then after the system comes in steady state :
2F o 3F ds nks la/kkfj=kksa dks Øe'k% 150 oksYV o 120 oksYV rd vkosf'kr fd;k tkrk gSA la/kkfj=kksa dh IysVksa dks
fp=kkuqlkj tksM+k tkrk gSA 1.5 F /kkfjrk ds ,d fujkosf'kr la/kkfj=k dks la;kstu rkj ds eqä fljksa ij fxjk;k tkrk gSA
rc fudk; ds LFkk;h voLFkk esa vkus ds ckn &
(A*) Charge on the 1.5 F capacitor will become 180 C.

(B*) Charge on the 2 F capacitor will become 120 C.
(C*) +ve charge flows through A from left to right.
(D) +ve charge flows through A from right to left.
(A*) 1.5 F la/kkfj=k ij vkos'k 180 C gks tkrk gSA (B*) 2 F la/kkfj=k ij vkos'k 120 C gks tkrk gSA
(C*) A ij /kukRed vkos'k ck;ha ls nk;ha vksj cgrk gSA (D) A ij /kukRed vkos'k nka;h ls ck;ha vksj cgrk gSA
Sol. In the initial state, charge on each capacitor is shown in figure-1.
izkjfEHkd voLFkk esa] izR;sd la/kkfj=k ij vkos'k fp=k-1 ds vuqlkj gSA
Let charge q flow anticlockwise in the circuit before it achieves steady state as shown in figure-2.
Applying KVL to figure 2.
ifjiFk esa vkos'k q fp=kkuqlkj okekorZ fn'kk esa cgrk gSA rks fp=k-2 ds vuqlkj ;g LFkk;h voLFkk izkIr djrk gSA
fp=k-2 esa KVL yxkus ij
360  q q 300  q
   q = 180 C
3 1.5 2
 Final charge on 1.5 F capacitor is q = 180 C and final charge on 2 F capacitor is
300 – q = 120 C.
la/kkfj=k 1.5 F ij vfUre vkos'k q = 180 C gS rFkk 2 F la/kkfj=k ij vfUre vkos'k 300 – q = 120 C.
26. Three blocks each of equal mass m are connected with wires W 1 and W 2 of equal cross-sectional area a
and Young's modulus Y. Neglect the friction.
PAGE-20
W1
m
W2
m
2mg mg
(A*) strain in wire W 1 is (B) strain in wire W 1 is
3aY 3aY
mg 2mg
(C*) strain in wire W 2 is (D) strain in wire W 2 is
3aY 3aY
leku nzO;eku m ds rhu xqVds rkj W 1 ,oa W 2 ds lkFk tqM+s gq, gS ftudh leku vuqizLFk dkV {ks=kQy a ,oa ;ax
xq.kkad Y gSaA ?k"kZ.k ux.; gS
W1
m
W2
m
2mg mg
(A*) W 1 rkj esa foÑfr gSA (B) W 1 rkj esa foÑfr
gSaA
3aY 3aY
mg 2mg
(C*) W 2 rkj esa foÑfr gSA (D) W 2 rkj esa foÑfr gSA
3aY 3aY
2mg 2g
Sol. Acceleration of blocks xqVds dk Roj.k = =
3m 3
2mg
Tension in wire W 1 is T1 = ma =
3
2mg
W 1 rkj esa ruko T1 = ma = gS
3
2g
Tension in wire W 2 is T2 then T2 + mg – T1 = m ×
3
2g
W 2 rkj esa ruko T2 gS] rc T2 + mg – T1 = m ×
3
2mg 2mg mg
 T2 + mg – = T2 =
3 3 3
T1 2mg
Strain in wire W 1 is = =
aY 3aY
T1 2mg
W 1 rkj esa foÑfr = =
aY 3aY
T2 mg
Strain in wire W 2 is = =
aY 3aY
T2 mg
W 2 rkj esa foÑfr = =
aY 3aY
27. A bullet of mass m = 1kg strikes a block of mass M =2kg connected to a light spring of stiffness
k =3N/m with a speed V0 = 3m/s. If the bullet gets embedded in the block then. [Moderate]
PAGE-21
,d m = 1kg nzO;eku dh xksyh ,d M = 2kg nzO;eku ds CykWd ls (tks fd fLizax fu;rkad k =3N/m okyh fLizax ls tqM+k
gSA) osx V0 = 3m/s. ls Vdjkrh gSA ;fn xksyh xqVds ds vUnj /kal tkrh gS rks
(A) linear momentum of bullet and block system is not conserve during impact because spring force is
impulsive.
(B*) linear momentum of bullet and block system is conserve during impact because spring force is
nonimpulsive.
(C) Maximum compression in the spring is 2m.
(D*) The maximum compression in the spring is 1m.
(A) VDdj ds nkSjku CykWd o xksyh fudk; dk js[kh; laosx lajf{kr ugha gS D;ksfd fLizaxcy vkosxh gSA
(B*) VDdj ds nkSjku CykWd o xksyh fudk; dk js[kh; laosx lajf{kr gS D;ksfd fLizaxcy vukosxh gSA
(C) fLizax esa vf/kdre lEihM+u 2m gSA
(D*) fLizax esa vf/kdre lEihM+u 1m gSA
Sol. Velocity of the system just after the collision VDdj ds Bhd ckn fudk; dk osx
mv 0
mvo = (m + M) V  V=
(m  M)
Using work energy theorem. dk;Z ÅtkZ izes; ls
K = W AII = W g + W N + W S (Assume friction force is absent) ¼ekfu;s fd ?k"kZ.k cy vuqifLFkr gS½ ......(i)
1 1
0– (m + M) V2 = 0 + 0 – K X2max
2 2
m2 v o2 mv 0 m2 v 02
= K X2max  Xmax = =
(m  M) K(M  m) K(M  m)
28. A rectangular bar is uniformly loaded axially with force per unit area  as shown. Shown is a section AA in
the bar.


A

(A) Normal stress for the section is  (independent of )

(B*) Shear stress for the section is maximum for  = 45° and is equal to
2
(C*) Normal stress for the section is  sin2
(D*) Shear stress for the section is minimum for  = 90° and is equal to zero
,d vk;rkdkj NM+ v{kh; :Ik esa ,d leku Hkkj ls izfr ,dkad {ks=kQy ds cy  ls fp=kkuqlkj Hkkjhr gSA n'kkZ;s x;s
NM+ ds vuqizLFk Hkkx AA' esa
PAGE-22


A

(A) vuqizLFk Hkkx esa vfHkyEc izfrcy  gS (ls Lora=k gS)

(B*) vuqizLFk Hkkx esa Li'kZ js[kh; izfrcy  = 45° ds fy, vf/kdre gS rFkk ds cjkcj gSA
2
(C*) vuqizLFk Hkkx esa vfHkyEc izfrcy  sin2 gS
(D*) vuqizLFk Hkkx esa Li'kZ js[kh; izfrcy  = 90° ds fy, U;wure gS rFkk 'kwU; ds cjkcj gSA
F sinθ
Sol.  = =  sin2
S cosecθ
F s inθ
= =  sin  cos 
S s ecθ
 sin2
=
2
F
S = Area ({kS=kQy)
A
F cos 
S
  Area ({kS=kQy)

sin
F sin 
F
29. The capacitance of a parallel plate capacitor is C0 when the plates has air between them. This region is
now filled with a dielectric slab of dielectric constant K. The capacitor is connected to a cell of emf E and
the slab is taken out :
(A*) charge EC0(K – 1) flows through the cell
(B*) energy E2C0(K – 1) is absorbed by the cell
(C) the energy stored in the capacitor is reduced by E2C0(K – 1)
1 2
(D*) the external agent has to do E C0(K – 1) amount of work to take out the slab
2
,d lekUrj iV~V la/kkfj=k dh /kkfjrk C0 gS] tc IysVks ds e/; gok gSA bl {ks=k dks vc k ijkoS|qrkad dh ijkoS|qr
ifV~Vdk ls Hkjk tkrk gSA la/kkfj=k E fo-ok- cy ds lsy ls tqMk gS rFkk ifêdk dks ckgj yk;k tkrk gSA
(A*) lsy ls izokfgr vkos'k EC0(K – 1) gSA
(B*) lsy }kjk vo'kksf"kr ÅtkZ E2C0(K – 1) gSA
(C) la/kkfj=k esa laxzfgr ÅtkZ E2C0(K – 1) }kjk ?kVrh gSA
1 2
(D*) ckg; dkjd }kjk ifêdk dks ckgj fudkyus esa fd;k x;k dk;Z E C0(K – 1) gSA
2
Sol. Initial charge on capacitor = KC0E
PAGE-23
Charge after removing slab = C0E
Amount of charge flows through the cell = KC0E – C0E = C0E (K – 1)
Energy absorbed by cell = C0E (K – 1). E0 = C0E2 (K – 1)
Initial energy stored in capacitor = 1/2 kC0 E2
Final energy stored in capacitor = 1/2 C0 E2
Energy reduces in capacitor by = 1/2 C0 E2 (k – 1)
1
Work done by external agent E2C0 (K  1)
2
la/kkfj=k ij izkjfEHkd vkos'k = KC0E
ifV~Vdk dks gVkus ds i'pkr~ vkos'k = C0E
cSVjh ls izokfgr vkos'k dh ek=kk = KC0E – C0E = C0E (K – 1)
cSVjh }kjk vo'kksf"kr ÅtkZ = C0E (K – 1). E0 = C0E2 (K – 1)
la/kkfj=k esa laxzfgr izkjfEHkd ÅtkZ = 1/2 kC0 E2
la/kkfj=k esa laxzfgr vfUre ÅtkZ = 1/2 C0 E2
la/kkfj=k esa ÅtkZ esa deh = 1/2 C0 E2 (k – 1)
1
cká dkjd }kjk fd;k x;k dk;Z E2C0 (K  1)
2
30. A circular disc of radius R rolls without slipping on a rough horizontal surface. At the instant shown its
linear velocity is V, linear acceleration a, angular velocity  and angular acceleration . Four points A, B, C
and D lie on its circumference such that the diameter AC is vertical & BD horizontal then choose the
correct options.
R f=kT;k dh ,d o`Ùkkdj pdrh [kqjnjh lrg ij fcuk fQlys yksVuh xfr djrh gSA fp=k esa iznf'kZr {k.k ij bldk
js[kh; osx v, js[kh; Roj.k a, dks.kh; osx rFkk dks.kh; Roj.k gSA pkj fcUnq A, B, C rFkk D bldh ifjf/k ij bl
izdkj fLFkr gS fd O;kl AC Å/okZ/kj gS] rFkk O;kl BD {ksfrt gS rc lgh fodYiksa dk p;u dhft,A
C
a
D v B
(A*) VB = V 2  (R)2 (B*) VC = V + R

(C*) aA = (a – R) 2  ( 2R) 2 (D*) aD = (a  2R)2  (R) 2
Sol. (A, B, C, D)
a, v
a, v
31. In series LCR circuit voltage drop across resistance is 8 V and voltage across inductor to is 6 V across
capacitor is 12 volt. Then select incorrect alternative/s :
Js.kh LCR ifjiFk esa izfrjks/k ds fljksa ij foHko iru 8 V gS rFkk izsjd dq.Myh ds fljks ij oksYVst 6 V gS rFkk la/kkfj=k
ds fljks ij 12 V gSA rc vlR; fodYiksa dk p;u fdft,A
(A*) Voltage of the source will be leading current in the circuit
ifjiFk esa L=kksr oksYVst /kkjk ls vkxs ¼leading½ gksxkA
(B*) Voltage drop across each element will be less than the applied voltage
izR;sd vo;o ds fljks ij foHko iru vkjksfir oksYVst ls de gksxkA
(C*) Power factor of circuit will be 4/3
ifjiFk dk 'kfDr xq.kkad 4/3 gksxkA
(D*) Source voltage is 26 volt
L=kksr oksYVst 26 oksYV gSA
R IR 8 4
Sol. Since, cos = = = =
Z IZ 10 5
PAGE-24
R IR 8 4
pwafd, cos = = = =
Z IZ 10 5
(cos dHkh Hkh ,d ls vf/kd ugha gks ldrk gSA)
Also ¼rFkk½, IxC > IxL  XC > XL
Current will be leading (/kkjk vkxs gksxh)
In a LCR circuit (,d LCR ifjiFk esa)
V  (VL – VC )2  VR2  (6 – 12)2  82  10
V = 10 ; which is less than voltage drop across capacitor.
V = 10 ; tks la/kkfj=k ds fljksa ij foHko iru ls de gSA
32. In the given AC circuit current and potential difference across the resistance inductor and capacitor are
shown in figure. Then which of the following options is/are correct :
R = 5 VL =20 Volt VC=30 Volt
1A
~
(A*) current leads the voltage in phase (B) voltage leads the current in phase.
1
(C*) power factor of the circuit is (D) Applied voltage is 15 V.
5
fn;s x;s izR;korhZ /kkjk ifjiFk esa izfrjks/k] izsjdRo ,oa la/kkfj=k ij /kkjk o foHkokUrj fp=k esa n'kkZ;s x;s gSA rc fuEu es a
ls dkSUklk@dkSUkls dFku lR; gSa %
R = 5 VL =20 Volt VC=30 Volt
1A
~
(A*) /kkjk dyk esa foHko ls vkxs gksrh gSA (B) foHko dyk esa /kkjk ls vkxs gksrk gSA
1
(C*) ifjiFk dk 'kfDr xq.kkad gksrk gSA (D) vkjksfir foHko 15 V gSA
5
Sol. Current leads the voltage (/kkjk dyk esa foHko ls vkxs gSA) i VR
V0 = (VL  VC )2  VR2 V0
= 100  25 = 5 5 V
VC – VL
V 5 1
P.F. = R = =
V0 5 5 5

PAGE-25
 vadu ;kstuk :


ç'u 33 ls 34 ds fy, vuqPNsn
A large tank of cross-section area A contains liquid of density . A cylinder of density / 4 and length ,
and cross-section area a (a <<A) is kept in equilibrium by applying an external vertically downward force as
shown. The cylinder is just submerged in liquid. At t = 0 the external force is removed instantaneously.
Assume that water level in the tank remains constant.
,d cM+k VSad gS ftldk dkV{ks=k A gS rFkk mlesa Hkjs nzo dk ?kuRo gSA ,d / 4 ?kuRo dk csyu o yEckbZ  rFkk
dkV{ks=k a (a << A) ds csyu dks ,d ckº; Å/okZ/kj uhps cy yxkdj lkE;oLFkk esa j[kk tkrk gSA csyu] nzo esa Bhd
Mwck gSA le; t = 0 ij ckº; cy dks gVk fn;k tkrk gSA ;g ekfu, fd Vsad esa ikuh dk Lrj ogh fu;r cuk jgrk gSA
33. The acceleration of cylinder immediately after the external force is removed is
ckº; cy gVkus ds rqjUr ckn csyu dk Roj.k &
(A) g (B) 2g (C*) 3g (D) zero 'kwU;
Sol.
34. The speed of the cylinder when it reaches its equlibrium position is
tc ;g lkE;oLFkk ij igq¡p tkrk gSA rks ml le; csyu dh pky
1 3
(A) g (B*) g (C) 2g (D) 2 g
2 2
Sol. The density of liquid is four times that of cylinder, hence in equlibrium postion one fourth of the cylinder is
submerged.
3
So as the cylinder is released from initial postion, it moves by to reach its equlibrium position. The
4
4g 3
upward motion in this time is SHM. Therefore required velocity is vmax = A.  = and A = .
4
3
Therefore vmax = g
2
nzo dk ?kuRo csyu ds ?kuRo dk pkj xquk gSA vr% lkE;oLFkk esa csyu dk ,d pkSFkkbZ Mqck jgsxkA vr% csyu dks
3
vkjfEHkd fLFkfr ls NksM+us ij ;g nwjh lkE;oLFkk ls igq¡psxkA Åij dh rjQ xfr SHM gS vr% vko';d osx vmax =
4
4g 3 3
A.  = rFkk A = vr% vf/kdre osx vmax = g
4 2
PAGE-26
ç'u 35 ls 36 ds fy, vuqPNsn
A uniform disc of mass 'm' and radius 'R' is free to rotate in horizontal plane about a vertical smooth fixed
axis passing through its centre. There is a smooth groove of small width along the radius of the disc and
one small ball of same mass is attached to a spring as shown in figure. Initially spring is in its natural
2
R m0
length of . The disc is given initial angular velocity 0 and released (spring constant k = )
2 2
'm' nzO;eku rFkk 'R' f=kT;k dh ,dleku pdrh blds dsUnz ls xqtjus okyh Å/okZ/kj fpduh fLFkj v{k ds lkis{k {kSfrt
ry esa ?kw.kZu djus ds fy, LorU=k gSA pdrh dh f=kT;k ds vuqfn'k vYi pkSM+kbZ dk fpduk [kk¡pk (groove) gS rFkk
R
leku nzO;eku dh ,d NksVh xsan fp=kkuqlkj fLçax ls tqM+h gSA çkjEHk esa fLçax dh viuh LokHkkfod yEckbZ esa gSA
2
2
m0
pdrh dks çkjEHk esa 0 dks.kh; osx fn;k tkrk gS rFkk fQj NksM+k tkrk gS (fLçax fu;rkad k = )
2
R
35. Angular velocity of disc when elongation in spring becomes will be :
2
R
pdrh dk dks.kh; osx tc fLçax esa foLrkj gks tkrk gS :
2
0 0 30
(A) (B*) 0 (C) (D)
2 4 4
Sol. By angular momentum conservation dks.kh; laosx laj{k.k ls
2 2
mR R R mR
0 + m0 × =  + mR × R
2 2 2 2
0  3 
+ 0 = = 0
2 4 2 2
R
36. Radial velocity of ball when elongation in spring becomes will be :
2
R
xsan dk f=kT;h; osx tc fLçax esa foLrkj gks tkrk gS :
2
0R 0R 30R
(A) 0R (B*) (C) (D)
2 4 4
Sol. By energy conservation ÅtkZ laj{k.k ls
1  R2 
2 2
1 mR 2
1  R 1 mR 2 02 1  R
. .02 + m.  0  = . . + . m  0  + mVr2 + k  
2 2 2  2 2 2 4 2  2  2  4 
1 3 1  R2 
mVr2 = m02R2 – k  
2 16 2  4 
1  1
mvr2 = m02R2  
2 8
02R 2 R
Vr2 =  Vr = 0
4 2
PAGE-27
PAGE-28
PAPER-1


 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is(are) correct
then :
 vU; fdlh fodYiksa ds la;kstu dks pquus ij –1 vad feysaxs ’
37. Which of the following produce(s) N2 gas?

fuEu esa ls dkSulk@dkSuls N2 xSl mRikfnr djrs gS@gSa \
 
(A*) (NH4 )2 Cr2O7   (B*) NH4NO2  
® Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
JPA_P1-29
Toll Free : 1800 200 2244 | 1800 258 5555 | CIN: U80302RJ2007PLC024029
HNO2 HNO2
(C*) H2NCSNH2   (D*) H2NCONH2  

Sol. NH4NO2  N2  H2O
H2NCONH2 
HNO2
N2  CO2  H2O
38. Select the correct statement(s) :

(A) Amongst ammonium molybdate test for phosphate ion and chromyl chloride test for chloride ion,
at least one test involves a redox reaction.
(B*) SO32– decolourises KMnO4 in acidic medium and produces no gas.
(C) AgNO3 gives yellow colored precipitates with Na3PO4 as well as Na3AsO4.
(D*) Sulphides of Group 12 of Modern periodic table are all different coloured precipitates.
lgh dFku@dFkuksa dk p;u dhft;s &
(A) QkWLQsV vk;u ds fy, veksfu;e eksfyCMsV ijh{k.k rFkk DyksjkbM vk;u ds fy, Øksfey DyksjkbM ijh{k.k esa de
ls de ,d ijh{k.k esa jsMkWDl vfHkfØ;k lfEefyr gksrh gSA
(B*) SO32– vEyh; ek/;e esa KMnO4 dks jaxghu djrk gS rFkk dksbZ Hkh xSl mRikfnr ugha djrk gSA
(C) AgNO3, Na3PO4 lkFk gh Na3AsO4 ds lkFk ihys jax dk vo{ksi nsrk gSA
(D*) vk/kqfud vkorZ lkj.kh ds oxZ 12 ds lYQkbM lHkh fHkUu jax vo{ksi gksrs gSA
Sol. (A) Na2 HPO4 (aq) + 12(NH4)2MoO4 + 23HNO3  (NH4)3PMo12O40  (canary yellow) + 2NaNO3 +
21NH4NO3 + 12H2O (not a redox reaction).
4Cl–(s) + Cr2O72–(s) + 6H+ (conc.)  2CrO2Cl2 (deep red vapours) + 3H2O (not a redox reaction).
(B) (A) SO32 contain S in +4 & hence it gets oxidized to +6 as SO24 .
(C) Ag3PO4 : Yellow ; Ag3AsO4 : Red.
(D) Sulphides of Group 12 of Modern periodic table are all different coloured precipitates (ZnS - white,
CdS - yellow, HgS - black).
Sol. (A) Na2 HPO4 (aq) + 12(NH4)2MoO4 + 23HNO3  (NH4)3PMo12O40  (dsusjh ihyk) + 2NaNO3 + 21NH4NO3
+ 12H2O (jsMkWDl vfHkfØ;k ugha).
4Cl–(s) + Cr2O72–(s) + 6H+ (conc.)  2CrO2Cl2 (xgjh yky ok"i) + 3H2O (jsMkWDl vfHkfØ;k ugha).
(B) (A)SO32 esa S +4 vkWDlhdj.k voLFkk j[krk gS rFkk blfy, ;g SO24 ds :i esa +6 esa vkWDlhÑr gksrk gSA
(C) Ag3PO4 : ihyk ; Ag3AsO4 : yky
(D) vk/kqfud vkorZ lkj.kh ds oxZ 12 ds lYQkbM lHkh fHkUu jaxhu vo{ksi gksrs gSA (ZnS - lQsn, CdS - ihyk, HgS
- dkyk).
39. NO2   Gas Z

Dil HCl
Gas Z   Gas P

NaOH / Zn
Select correct statement(s) :

(A*) Gas P turns red litmus blue
(B*) When Mohr's salt is treated with NaOH, gas P is one of the product
(C) Gas P is neutral oxide of nitrogen which gives brown ring test
(D*) Gas P is water soluble gas
ruq HCl
NO2   xSl Z
NaOH / Zn
xSl Z   xSl P
lgh dFku@dFkuksa dks igpkfu,&
(A*) xSl P yky fyVel dks uhyk djrh gSA
(B*) tc eksgj yo.k dks NaOH ds lkFk mipkfjr fd;k tkrk gS] rks xSl P ,d mRikn gksrk gSA
(C) xSl P ukbVªkstu dk mnklhu vkWDlkbM gS tks Hkwjk oy; ijh{k.k nsrk gSA
(D*) xSl P ty foy; xSl gSA
JPA_P1-30
Sol. gas Z = NO2 gas P = NH3 (water soluble and basic in nature)
Ammonia is obtained by reaction of NaOH with Mohr's salt
xSl Z = NO2 xSl P = NH3 (ty foy; rFkk {kkjh; izÑfr)
veksfu;k eksgj yo.k ds lkFk NaOH dh vfHkfØ;k }kjk izkIr gksrh gSA
40. Salt AB undergoes anionic hydrolysis and its 0.1 M solution has pOH as 5 then select correct
statement(s):
(A*) Kh is equal to Kb of B– (B*) pKa of HB is 5
(C*) h is 0.01% (D*) pH of 0.1 M HB is 3
yo.k AB _.kk;fud ty vi?kVu nsrk gS rFkk bldk 0.1 M foy;u 5 pOH j[krk gS] rc lgh dFku@dFkuksa dk
p;u dhft,&
(A*) Kh , B– ds Kb ds cjkcj gksrk gSA (B*) HB dk pKa 5 gSA
(C*) h 0.01% gSA (D*) 0.1 M HB dh pH 3 gSA
Sol. B– + H2O  HB + OH–
c(1–h) ch ch
c = 0.1 M
ch = 10–5
h = 10–4
Kh = ch2 = 10–9
Ka(HB) = 10–5
Kb of B– = 10–9
1
pH = (5 – (–1)) = 3
2
+
[Ag ]
41.
–
[Br ]
In which case above graph can not be obtained ?
(A*) NH3 is added in saturated solution of AgBr.
(B*) AgNO3(s) is added in saturated solution of AgBr.
(C*) AgNO3(s) is added in unsaturated solution of AgBr.
(D) NaBr(s) is added in unsaturated solution of AgBr.
dkSulh fLFkfr esa mijksDr xzkQ izkIr gks ugha ldrk gS] tc &
(A*) AgBr ds larÌr foy;u esa NH3 feykrs gSA
(B*) AgBr ds larÌr foy;u esa AgNO3(s) feykrs gSA
(C*) AgBr ds vlarÌr foy;u esa AgNO3(s) feykrs gSA
(D) AgBr ds vlarÌr foy;u esa NaBr(s) feykrs gSA
42. When SO3 is taken in 10 L vessel and equilibrium is established between SO 3, SO2 and O2 :
1
SO2 (g)  O2 (g)
2
equilibrium mixture is found to be 1.6 g/L at equilibrium temperature 300 K. Which of the following
conclusion(s) can be made using the datas given?
(A*) Number of moles of SO3 initially is 0.2 mol
(B) Total number of moles is 0.5 mol at equilibrium
(C*) Number of moles of SO3 at equilibrium can't be calculated as additional data(s) is/are required
(D) Partial pressure SO3 is 0.492 atm at equilibrium
tc SO3 dks 10 L ik=k esa fy;k tkrk gS rks lkE; SO3, SO2 rFkk O2 ds e/; LFkkfir gksrk gS
1
SO2 (g)  O2 (g)
2
JPA_P1-31
lkE; feJ.k lkE; rki 300 K ij 1.6 g/L ik;k tkrk gSA fuEu esa ls dkSulk@dkSuls fu"d"kZ mijksDr vkWdM+ksa ds
iz;ksx ls fn;s tk ldrs gSa \
(A*) izkjEHk esa SO3 ds eksyksa dh la[;k 0.2 eksy gSA

(B) lkE; ij eksyksa dh dqy la[;k 0.5 eksy gSA
(C*) lkE; ij SO3 ds eksyksa dh la[;k dh x.kuk ugha dj ldrs D;ksafd vfrfjDr vk¡dM+@
s vk¡dM+ks dh vko';drk
gksrh gS@gaSA
(D) lkE; ij SO3 dk vkaf'kd nkc 0.492 atm gSA
Sol. Equilibrium mass = 16 g = Initial mass (mass conservation)
16
Initial moles of SO2 =  0.2 mol
80
All other conclusions require additional datas i.e. equilibrium constant, degree of dissociation,
equilibrium pressure.
Sol. lkE; nzO;eku = 16 g = izkjfEHkd nzO;eku (nzO;eku laj{k.k)
16
SO2 ds izkjfEHkd eksy =  0.2 eksy
80
vU; lHkh fu"d"kksZ dks vfrfjDr vk¡dM+ksa vFkkZr~ lkE; fu;rkad] fo;kstu dh ek=kk] lkE; nkc dh vko';drk gksrh gSA
43. A gaseous substance AB2(g) converts to AB(g) in presence of solid A(s) as

AB2(g) + A(s) 2 AB(g)
The initial pressure and equilibrium pressure are 0.7 bar and 0.95 bar. Now the equilibrium mixutre is
expanded reversibly and isothermally till the total gas pressure falls to 0.4 bar. Then select correct
option(s) ?
(A) Mole percent of AB(g) at final equilibrium is nearly 27%
(B*) Mole percent of AB2(g) at final equilibrium is nearly 32.5%
5
(C*) Kp for the equilibrium is
9
(D) Ratio of equilibrium pressure of AB2(g) at initial and final equilibrium is more than 2 but less than 3
Bksl A(s) dh mifLFkfr esa ,d xSlh; inkFkZ AB2(g), AB(g) esa fuEu izdkj ifjofrZr gksrk gSA
AB2(g) + A(s) 2 AB(g)
izkjfEHkd nkc rFkk lkE; nkc 0.7 ckj rFkk 0.95 ckj gSA vc lkE; feJ.k dks dqy xSl nkc 0.4 ckj de gksus rd
mRØe.kh; :i ls rFkk lerkih; :i ls izlkfjr djrs gS] rc lgh fodYi@fodYiksa dk p;u dhft;s \
(A) vfUre lkE; ij AB(g) dk eksy izfr'kr yxHkx 27% gSA
(B*) vfUre lkE; ij AB2(g) dk eksy izfr'kr yxHkx 32.5% gSA
5
(C*) lkE; ds fy, Kp gSA
9
(D) izkjfEHkd rFkk vfUre lkE; ij AB2(g) ds lkE; nkc dk vuqikr 2 ls vf/kd ysfdu 3 ls de gksrk gSA
Ans. (B) and rFkk (C)
Sol. AB2(g) + A(s) 2AB(g)
0.7 – x 2x
Total pressure (dqy nkc) = 0.7 – x + 2x = 0.95
x = 0.25
(0.5)2 0.25 5
Kp =  
(0.45) 0.45 9
Let at new equilibrium (ekuk u;s lkE; ij)
AB2(g) + A(s) 2AB
x y
then rc x + y = 0.4
y2 5
Kp = 
x 9
y2 5

0.4  y 9
JPA_P1-32
y = 0.27
0.27
AB =  100 = 67.5%
0.4
% AB2 = 32.5%
44. Balance the following chemical reaction with simplest integer coefficients: a, b, c, d and e and then
choose the correct option(s);
ljyre iw.kZ xq.kkad % a, b, c, d rFkk e ;qDr fuEu jklk;fud vfHkfØ;k dks lUrqfyr dhft, rFkk lgh
fodYi@fodYiksa dks pqfu,&
a Cr2O72– + b H2O2 + c H+  d CrO(O2)2 + e H2O
(A*) a is 1 (B) b is 6 (C*) d is 2 (D*) e is 5
(A*) a, 1 gSA (B) b, 6 gSA (C*) d, 2 gSA (D*) e, 5 gSA
Sol. 1 Cr2O7 + 4 H2O2 + 2 H  2 CrO(O2)2 + 5 H2O
2– +
45. Which of the following is/are correct about the reaction FeS2 + O2  Fe2O3 + SO2
M M
(A*) Equivalent weight of FeS2 is (B*) Equivalent weight of SO2 is
11 5
(C) S has –2 oxidation state in FeS2 (D) 1 mol of FeS2 requires 7/4 mol of O2
fuEu esa ls dkSulk@dkSuls vfHkfØ;k FeS2 + O2  Fe2O3 + SO2 ds ckjs esa lgh gS@gSa \
M M
(A*) FeS2 dk rqY;kadh Hkkj gSA (B*) SO2 dk rqY;kadh Hkkj
gSA
11 5
(C) FeS2 esa S , –2 vkWDlhdj.k voLFkk j[krk gSA (D) 1 eksy FeS2 dks 7/4 eksy O2 dh vko';drk gksrh gSA
Sol. 2Fe+2  (Fe+3)2 + 2e
M
Eq. wt. of FeS2 =
11
2(S–)2  4(S+4) + 20 e
M
Eq. wt. of SO2 =
5
4FeS2 + 11O2  2Fe2O3 + 8SO2
S have –1 state
Sol. 2Fe+2  (Fe+3)2 + 2e

M
FeS2 dk rqY;kadh Hkkj =
11
2(S–)2  4(S+4) + 20 e
M
SO2 dk rqY;kadh Hkkj =
5
4FeS2 + 11O2  2Fe2O3 + 8SO2
S, –1 vkWDlhdj.k voLFkk j[krk gSA
46. Wolf Kishner reduction can be used for converting

(A*) Benzophenone to Diphenyl methane (B) Benzaldehyde to Benzyl alcohol
(C*) Benzaldehyde to Toluene (D) Acetophenone to propane
fuEu esa ls fdlds :ikUrj.k ds fy, oqYQ fd'uj vip;u iz;qDr fd;k tk ldrk gS&
(A*) csUtksfQukWu dks MkbZQsfuy esFksu
esa (B) csUtsfYMgkbM dks csfUty ,YdksgkWy esa
(C*) csUtsfYMgkbM dks VkWywbZu esa (D) ,lhVksfQukWu dks izksisu esa
Wolf CH2
C=O
Sol. Kishner
oqYQ
C=O CH2
fd'uj
47. Benzyl chloride can be prepared from toluene by chlorination with
JPA_P1-33
csfUty DyksjkbM dks fuEu esa ls fdlds lkFk Dyksjhuhdj.k }kjk VkWywbZu ls cuk;k tk ldrk gS &
(A*) SO2Cl2 (B) SOCl2 (C) PCl5 (D*) Cl2/
JPA_P1-34
48. Which of the following combination of reactants can be used to prepare the following given compound?
fuEufyf[kr fn;k x;k mRikn cukus ds fy, fØ;kdkjdksa dk dkSulk@dkSuls la;kstu iz;qDr fd;k tk ldrk gS@gSa \
OH
CH3 CH3
Ph
(1)CH3 –MgBr  excess  (1)CH3 –MgBr  vkf/kD; 
 (A*) Ph–C–O–CH3    
(2)H O,H 2

(2)H2O,H
O
(1)Ph–MgBr  excess  (1)Ph–MgBr  vkf/kD; 
(B) Ph–C–CH3    
(2)H O,H 2

(2)H2O,H
O

(1)Ph–MgBr  excess 
(C) CH3–C–Cl  
(1)Ph–MgBr

 vkf/kD;
(2)H O,H 2

(2)H2O,H
O
Ph
(1)CH3 –MgBr  excess  (1)CH3 –MgBr  vkf/kD; 
(D*) CH3–C–O    
(2)H O,H 2

(2)H2O,H
O
OH
Sol. (A) CH3MgBr (excessvkf/kD;) + Ph–C–O–CH3 
CH3 CH3
O Ph
OH
(B) PhMgBr (excess vkf/kD;) + Ph–C–CH3  CH3 Ph

Ph
O
Ph OH
(D) CH3–C–O
(1)CH3 –MgBr  excess 
 
 vkf/kD;  
(1)CH3 –MgBr

(2)H2O (2)H2O,H CH3 CH3
O Ph
49. Which of the following are correctly matched with major product :
OH NH2
Br /H O
(A) 
2 2
 (B)
(1) NaNO /HCl(0ºC )

2

(2) CuBr/HBr
Br
Br OH
OH
(1) CCl /OH
COOH (1) Br / Fe
(C*) 
4

 (D*) 
2

(2) H2O/ H (2) Mg/Ether
(3) O2
(4) H2O
OH
fuEu esa ls dkSulh vfHkfØ;k@vfHkfØ;kvksa esa eq[; mRikn lgh :i lqesfyr gS@gSa&
OH NH2
Br /H O
(A) 
2 2
 (B)
(1) NaNO /HCl(0ºC )

2

(2) CuBr/HBr
Br
Br OH
OH
(1) CCl /OH
COOH (1) Br /Fe
(C*) 
4

 (D*) 
2

(2) H2O/ H (2) Mg/bZFkj
(3) O2
(4) H2O
OH
JPA_P1-35
50. The correct order of nucleophilicity for following species is/are :
fuEu iztkfr;ksa esa ls ukfHkdLusfgrk dk lgh Øe gS@gSa&
 
(A*) NH2  NH3  Ph – NH2 (B*) Me  O  Me2CH  O  Me3C  O
(C) F  Cl  Br     (in DMSO) (D*) > N(C2H5)3
Sol. (B) Me3C–O– is stranger base but weaker nucleophile due to presence of steric hindrance
(C) Nucleophilicity of halides in water = F  Cl  Br    
Nucleophilicity of halides in DMSO = F  Cl  Br    
(D) No flipping and lesser steric hindrance so is stronger nucleophile
Sol. (B) Me3C–O– izcyre {kkj gS ysfdu f=kfoe ck/kk dh mifLFkfr ds dkj.k nqcZy ukfHkdLusgh gSA
(C) ty esa gsykbMksa dh ukfHkdLusfgrk = F  Cl  Br    
DMSO esa gsykbMksa dh ukfHkdLusfgrk = F  Cl  Br    
(D) iyVu (flipping) vuqifLFkr rFkk U;wu f=kfoe ck/kk vr% izcyre ukfHkdLusgh gSA

 vadu ;kstuk :
 _.k vad % –1 vU; lHkh ifjfLFkfr;ksa esaA a

5.6 g iron is treated with hot concentrated H2SO4 to form a solution of Fe2+ and Fe3+ ions. After the
release of SO2 gas volume of solution 'S' is made upto 100 ml with water.
vk;ju ds 5.6 g dks xeZ lkanz H2SO4 ds lkFk mipkfjr djds Fe2+ rFkk Fe3+ dk ,d foy;u cuk;k tkrk gSA
SO2 xSl ds fu"dklu ds i'pkr~ feJ.k esa ty feykdj 100 ml vk;ru dk foy;u 'S' cuk;k tkrk gSA
51. If the above solution 'S' is titrated with 0.1 M KMnO 4 in neutral condition, volume of KMnO4 used is 100
ml. Moles of Fe2+ in the solution 'S' is :
;fn mDr foy;u 'S' dks mnklhu ifjfLFkfr esa 0.1 M KMnO4 ds lkFk vuqekfir djrs gSa] rks KMnO4 dk iz;qDr
vk;ru 100 ml gSA rc foy;u 'S' esa Fe2+ ds eksy gSa %
(A) 0.01 (B) 0.06 (C) 0.07 (D*) 0.03
Sol. m eq. of Fe2+ = m eq. of KMnO4 = 0.1 × 3 × 100 = 30
JPA_P1-36
moles of Fe2+ in solution 'S' = 0.03
Fe2+ ds feyh rqY;kad = KMnO4 ds feyh rqY;kad = 0.1 × 3 × 100 = 30
foy;u 'S' esa Fe2+ ds eksy = 0.03
52. If the solution 'S' is titrated with KI iodometrically, volume of 1.4M Na2S2O3 solution used is :
;fn foy;u 'S' dks vk;ksMksferh; :i ls KI ds lkFk vuqekfir fd;k tkrk gS] rc 1.4M Na2S2O3 foy;u dk
iz;qDr vk;ru gS %
(A) 30 ml (B*) 50 ml (C) 40 ml (D) 100 ml
Sol. Fe3+ + KI  I2 + Fe2+
I2 + Hypo  2I– + S4O62–
m eq. of Fe3+ = m eq. of I2
 0.07 × 1000 = m eq. of S2O32–
70
 volume of N2S2O3 used = = 50 ml
1.4
gy Fe3+ + KI  I2 + Fe2+
I2 + gkbiks  2I– + S4O62–
Fe3+ ds feyh rqY;kad = I2 ds feyh rqY;kad
 0.07 × 1000 = S2O32– ds feyh rqY;kad
70
 iz;qDr N2S2O3 dk vk;ru = = 50 ml
1.4

H
+ EtOH
Ot
53. The electrophile in first step is
izFke in esa bysDVªkWuLusgh gS &
  
(A) CH3 CH2 (B*) H  (C) CH3  CH2  CH– CH3 (D) CH3CH2CH2 CH2
54. The electrophile in second step is

f}rh; in esa bysDVªkWuLusgh gS &
  
(A) CH3 CH2 (B) H (C*) CH3 CHCH2CH 3 (D) CH3CH2CH2 CH2
+ H
Sol. I. 
+ EtOH
II. 
 O
Ex H

-H
OEt
PAPER-2


 This section contains TEN (10) questions.

 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is(are) correct.
JPA_P1-37
then :
 bl [kaM esa nl (10) iz'u gSaA
 dsoy fodYi (A),(B) vkSj (D) pquus ij +4 vad feysaxs
 dsoy fodYi (A) vkSj (B) pquus ij +2 vad feysaxs
 dsoy fodYi (A) vkSj (D) pquus ij +2 vad feysaxs
 dsoy fodYi (B) vkSj (D) pquus ij +2 vad feysaxs
 dsoy fodYi (A) pquus ij +1 vad feysaxs
 dsoy fodYi (B) pquus ij +1 vad feysaxs
 dsoy fodYi (D) pquus ij +1 vad feysaxs
 vU; fdlh fodYiksa ds la;kstu dks pquus ij –2 vad feysaxs ’
37. An amount of 0.2 mol of each A2(g) and B2(g) is introduced in a sealed flask and heated to 2000 K then
following equilibrium is established : A2(g) + B2(g) 2AB(g)
At equilibrium moles of AB is 0.3 mol At this stage 0.1 mol of C2(g) is added and a new equilibrium is
also established as : A2(g) + C2(g) 2AC(g)
At the new equilibrium the moles of AB(g) becomes 0.24 mol.
(A*) Equilibrium constant for first reaction is 36
(B) Equilibrium constant for first reaction is 32
(C) Equilibrium constant for second reaction is 16
(D*) Equilibrium constant for second reaction is 18
JPA_P1-38
A2(g) rFkk B2(g) izR;sddh 0.2 eksy ek=kk dks ,d lhyc) ¶ykLd es fy;k tkrk gS rFkk 2000 K rd xeZ fd;k
tkrk gS rks fuEu lkE; LFkkfir gksrk gS& A2(g) + B2(g) 2AB(g)
lkE; ij AB ds eksy 0.3 eksy gSA bl voLFkk ij 0.1 eksy C2(g) feyk;k tkrk gS rFkk u;k lkE; Hkh LFkkfir gksrk
gS& A2(g) + C2(g) 2AC(g)
u;s lkE; ij AB(g) ds eksy 0.24 eksy gks tkrs gSA
(A*) izFke vfHkfØ;k ds fy, lkE; fu;rkad 36 gSA
(B) izFke vfHkfØ;k ds fy, lkE; fu;rkad 32 gSA
(C) f}rh; vfHkfØ;k ds fy, lkE; fu;rkad 16 gSA
(D*) f}rh; vfHkfØ;k ds fy, lkE; fu;rkad 18 gSA
Sol. Initially izkjEHk esa
A2 + B2 2AB
0.2–x 0.2–x 2x = 0.3
x = 0.15
 0 .3   0 .3 
  
KC =  v  v 

900
 0 . 05  0 . 05  25
  
 v  v 
When 0.1 mole C2 added
tc 0.1 eksy C2 feyk;k tkrk gS
A2 + B2 2AB
0.2–x1–y 0.2–x1 2x1 = 0.24
x1 = 0.12
A2 + C2 2AC
0.2–x1–y 0.1–y 2y
KC for  eqm
 eqm ds fy, KC
 0.24   0.24 
  
900
  v  v 
25  0.2  0.12  y   0.08 
  
 v  v 
y = 0.06
KC for  eqm
 eqm ds fy, KC
KC 
0.12 0.12  18
0.02 0.04
38. x g of H2O2 require 100 mL of M/5 KMnO4 in a titration in a solution having pOH = 1.0
which of following is/are correct ?
(A) The value of x is 1.7 g (B*) The value of x is 0.34 g
(C*) MnO4 changes to MnO42 (D*) H2O2 change to O2
pOH = 1.0 j[kus okys ,d foy;u esa] ,d vuqekiu esas x g H2O2 ds fy, M/5 KMnO4 ds 100 mL vko';d gS&
fuEu esa ls dkSulk lgh gS@gSa\
(A) x dk eku 1.7 g gSA (B*) x dk eku 0.34 g gSA
 2
(C*) MnO4 , MnO4 esa ifjofrZr gksrk gSA (D*) H2O2, O2 esa ifjofrZr gksrk gSA
Sol. pOH = 1 strong basic medium
 MnO4–  MnO4–2 (n = 1)
2OH¯ + H2O2  O2 + 2H2O + 2e–
meq. of H2O2 = meq of MnO4–
JPA_P1-39
x 1
34 × 1000 = 100 × 5 × 1
2
x = 0.34 g
Sol. pOH = 1 izcy {kkjh; ek/;e
 MnO4–  MnO4–2 (n = 1)
2OH¯ + H2O2  O2 + 2H2O + 2e–
H2O2 dk feyh rqY;kad = MnO4– dk feyh rqY;kad
x 1
34 × 1000 = 100 × 5 × 1
2
x = 0.34 g
39. Which combination gives SO2 ?

dkSulk la;kstu SO2 nsrk gS \
(A*) P4 + SOCl2 (B) H2SO4 + NH3 (C*) P4 + SO2Cl2 (D*) P4 + conc. H2SO4
Sol. (A) P4 + SOCl2  PCl3 + SO2 + S2Cl2
(B) H2SO4 + NH3(NH4)2SO4
(C) P4 + SO2Cl2  PCl5 + SO2
(D) P4 + conc. H2SO4  H3PO4 + SO2+ H2O
40. Consider the following reaction sequence :

A (aq) + NaOH (aq)  B (g) + NaCl (aq)

A (aq) + C (aq)  D (g) + NaCl (aq) + H2O
FeSO4 (aq) + CH3COOH (aq) + C (aq)  [Fe(H2O)5(NO)]SO4
If gas B turns moist red litmus paper blue, then which of the following is/are correct?
(A*) C may be NaNO2. (B) C may be NaNO3.
(C*) Gas D may be N2. (D) Gas D may be N2O.
fuEu vfHkfØ;k vuqØe dk voyksdu dhft,&
A (aq) + NaOH (aq)  B (g) + NaCl (aq)

A (aq) + C (aq)  D (g) + NaCl (aq) + H2O
FeSO4 (aq) + CH3COOH (aq) + C (aq)  [Fe(H2O)5(NO)]SO4
;fn xSl B ue yky fyVel i=k dks uhyk djrh gS] rks fuEu esa ls dkSulk@dkSuls lgh gS@gSa \
(A*) C, NaNO2 gks ldrk gSA (B) C, NaNO3 gks ldrk gSA
(C*) xSl D, N2 gks ldrh gSA (D) xSl D , N2O gks ldrh gSA
Sol. B is ammonia. Hence, A must contain ammonium ions. A is NH4Cl. Brown ring test is given by
both nitrite and nitrate, but for nitrate concentrated sulphuric acid must be employed. Thus, C
can be NaNO2 but not NaNO3.
B veksfu;k gS] blfy, A esa veksfu;e vk;u gksus pkfg,A A, NH4Cl gSA Hkwjk oy; ijh{k.k ukbVªkbV rFkk ukbVªsV
nksuksa ds }kjk fn;k tkrk gS] ysfdu ukbVªsV ds fy, lkfUnzr lY¶;wfjd vEy iz;qDr gksuk pkfg,A vr% C, NaNO2 gks
ldrk gS ysfdu NaNO3 ugha A

NH4Cl + NaNO2  N2 + NaCl + H2O.
41. Which of the following compound(s) have two  bond in it’s structure ?
fuEu esa ls dkSulk@dkSuls ;kSfxd bldh lajpuk esa nks  ca/k j[krs gS@gSas\
JPA_P1-40
X + Y + Z
H2O
P W
+ ;wfj;k X + Y + Z
¼mnklhu vkWDlkbM+½
pwusa dk ikuh
Hkwjk vo{ksi H2O nwf/k;k foy;u

P W
X
(A*) X (B*) Y (C) W (D) P
Sol. HNO2 + NH2 – C – NH2  N2  CO2  H2O
|| (x) (y) (z)
O
HO
Mg  N2  Mg3N2 
2
NH3 
CuO
N2
(x) (w) (p) (x)
Ca(OH)2  CO2  CaCO3

Milky solution
NH3  K 2 [HgI4 ] / OH  HgO.HgNH2

(p) Brownppt. I
Sol. HNO2 + NH2 – C – NH2  N2  CO2  H2O

|| (x) (y) (z)
O
HO
Mg  N2  Mg3N2 
2
NH3 
CuO
N2
(x) (w) (p) (x)
Ca(OH)2  CO2  CaCO3

nwf/k;k foy;u
NH3  K 2 [HgI4 ] / OH  HgO.Hg NH2
(p) Hkwjk vo{ski. I
42. A sample of hard water has Ca2+ ion concentration of 80 ppm if all the Ca2+ ion are replaced by H+ ion,
keeping the electroneutrality of solution then select the correct statement(s) ;
[Kw of water at 62ºC = 10–13, log 2 = 0.3]
(A*) pH of resulting solution at 62ºC is 2.4
(B*) pOH of resulting solution at 62ºC is 10.6
(C) pOH of resulting solution at 62ºC is 10.3
(D) None of these
dBksj ty dk ,d izkn'kZ Ca2+ vk;u dh 80 ppm lkUnzrk j[krk gS] ;fn foy;u dh oS|qrmnklhurk dks cuk, j[krs
gq, leLr Ca2+ vk;uksa dks H+ vk;uksa }kjk izfrLFkkfir djrs gSa ; rks lgh dFku@dFkuksa dk p;u dhft, &
[62°C ij ty dk Kw = 10–13, log 2 = 0.3]
(A*) 62ºC ij ifj.kkeh foy;u dh pH 2.4 gSA
(B*) 62ºC ij ifj.kkeh foy;u dh pOH 10.6 gSA
JPA_P1-41
(C) 62ºC ij ifj.kkeh foy;u dh pOH 10.3 gSA
(D) buesa ls dksbZ ugha
Sol. 80g Ca+2 present in 106 g of water or 103 L of water
n 2
[Ca+2] = Ca = 2×10–3 M
VL
1 mol of Ca+2 ion is replaced by 2 mols of H+
SO, [H+] = 4×10–3
pH = 2.4
pOH = 13 – 2.4 = 10.6
JPA_P1-42
gy- 106 g ty ;k 103 L ty esa mifLFkr 80g Ca+2
n 2
[Ca+2] = Ca = 2×10–3 M
VL
1 eksy Ca+2 vk;u 2 eksy H+ }kjk izfrLFkkfir gksrs gSaA
vr%, [H+] = 4×10–3
pH = 2.4
pOH = 13 – 2.4 = 10.6
43. Which of the following reaction/s give same product ?

fuEu esa ls dkSulh vfHkfØ;k@vfHkfØ;k,¡ leku mRikn nsrh gSSa \
CH = CH2 CH3
Cl
H
(A*) +  (B*) + + AlCl3
CH3
|
CH3
OH
CHOH
H
(C*) +  (D*) + H

CH3
CH = CH2
+ +
H H3C
Sol. (A)
CH3 CH3
Cl
+
AlCl3 H3C
(B)
CH3 CH3
OH + +
H H3C
(C)
CH3
|
CHOH CH3
+
H +
H3C
(D)
OH
Dil. HNO3
44.    M + N
(Major) (Minor)
36% 25%
Observe the following reaction & choose the correct options:
(A) Product M is more acidic than product N
(B*) Product M has lower boiling point than product N
JPA_P1-43
(C*) Both M & N can be separated by steam distillation
OH
NO2
(D*) Product M is
OH
ruq HNO

3
 M + N
(eq[;) (U;wu)
36% 25%
mijksDr vfHkfØ;k dk voyksdu dj lgh fodYi@ fodYiksa dk p;u dhft,&
(A) mRikn M, mRikn N dh rqyuk esa vf/kd vEyh; gSA
(B*) mRikn M dk DoFkukad fcUnq mRikn N dh rqyuk esa de gksrk gSA
(C*) mRikn M o N nksuksa dks Hkki vklou }kjk i`Fkd fd;k tk ldrk gSA
OH
NO2
(D*) mRikn M gSA
OH OH
NO2
Sol. M is & N is
NO2
OH OH
NO2
M gS o N gSA
NO2
45. Consider following two amides one acyclic (A) and other a bridgehead amide (B) as shown:
n'kkZ;s x;s fuEu nks ,ekbMks] ,d vpØh; ¼A½ rFkk vU; lsrq'kh"kZ ,ekbM (B) dk voyksdu dhft,A
O
x N and
N
y
(A) O
(B)
Identify the correct the statement/s :
lgh dFku@dFkuksa dks igpkfu;s&
(A*) Nitrogen of B is more Basic than A
(B*) C-N bond y in B is longer than C-N bond x in A
(C*) Rate of hydrolysis of B in acidic medium is greater than that of A
(D*) nitrogen of B is more nucleophillic than A
(A*) B A ls vf/kd {kkjh; gSA

(B*) B esa C-N ca/k x, A esa C-N ca/k y ls cM+k gSA
(C*) vEyh; ek/;e esa B ds tyvi?kVu dh nj] A dh vis{kk vf/kd gksrh gsA
(D*) B dk ukbVªkstu A dh vis{kk vf/kd ukfHkdLusgh gSA
JPA_P1-44
Bridgehead amide
Sol. Amide
O O
N N
N N
O O
significant resonance insignificant resonance
form form (poor overlap)
Consequence the C-N bond has considerable Bridgehead amides are considerable easier
double bond character (which makes amides to cleave
quite resistant to cleavage)
There is considerable double-bond character between C and N in A, because of delocalisation of lone
pair of N in A. Thus, it is less basic and less nucleophillic.
Needless to say the overlap between the lone pair on N and the carbonyl nitrogen is now extremely
poor in B. This results in a considerably weaker C-N bond, one that is very easily cleaved.
Sol. lsrq'kh"kZ ,ekbM+
,ekbM+
O O
N N
N N
O O
lkFkZd vuqukn :i vlkFkZd vuqukn :i ¼nqcZy
vfrO;kiu½
ifj.kkeLo:i C-N ca/k i;kZIr f)ca/k xq.k (tks VwVus ds fy, blls ges Kkr gksrk gS fd lsrq'kh"kZ ,ekbM vklkuh ls VwV
izfrjks/kh ,ekbM cukrk gSa½ j[krk gSA tkrs gSaA
;gk¡ A esa C rFkk N ds e/; i;kZIr f}ca/k xq.k gS] D;ksafd A esa N ds ,dkdh ;qXe dk foLFkkuhdj.k gksrk gSA
blfy,
;g U;wu {kkjh; rFkk U;wu ukfHkdLusgh gksrk gSA
;g dguk vko';d ugha gS fd N ij ,dkdh ;qXe ds e/; vfrO;kiu gksrk gS rFkk dkckZfs uy ukbVªkstu vc B esa
nqcZy gksrk gSA blds ifj.kkeLo:i i;kZIr nqcZy C-N ca/k curk gS] vFkkZr~ ;g vf/kd vklkuh ls VwV tkrk gSA
46. Which of the following option/s contain more acidic hydrogen (attached with oxygen) than hydrogen
(attached with oxygen) of given compound:
fuEu esa ls dkSulk@dkSuls fodYi esa fn;s x;s ;kSfxd ds gkbMªkstu ¼vkWDlhtu ls tqM+k½ dh vis{kk vf/kd vEyh;
gkbMªkstu ¼vkWDlhtu ls tqM+k½ mifLFkr gS@gSa \
HO
O O
HO
OH HO
(A*) (B) (C) (D*)
HO O
O O O O O

Sol. lp of O anion take part in conjugation A.S.  (stability of conjugate).
..

Sol. O _.kk;u
..
dk lp la;qXeu esa Hkkx ysrk gS A.S.  (la;qXeh dk LFkkf;Ro)

 This section contains EIGHT (08) questions. The answer to each question is NUMERICAL VALUE with two
digit integer and decimal upto two digit.
 If the numerical value has more than two decimal places truncate/round-off the value to TWO decimal
placed.
JPA_P1-45
 Marking scheme :
 Full Marks : +3 If ONLY the correct numerical value is entered as answer.
 Zero Marks : 0 In all other cases
[kaM 2 ¼vf/kdre vad% 24)
 bl [kaM esa vkB (08) iz'u gSA izR;sd iz'u dk mÙkj la[;kRed eku (NUMERICAL VALUE) gSa]tks f}&vadh; iw.kkZad
rFkk n'keyo f}&vadu eas gSA
 ;fn la[;kRed eku esa nks ls vf/kd n’'keyo LFkku gS ] rks la[;kRed eku dks n'keyo ds nks LFkkuksa rd VªadsV@jkmaM
vkWQ (truncate/round-off) djsaA
 vadu ;kstuk %&
 iw.kZ vad % +3 ;fn flQZ lgh la[;kRed eku (Numerical value) gh mÙkj Lo:i ntZ fd;k x;k gSA
 'kwU; vad % 0 vU; lHkh ifjfLFkfr;ksa esa
47. Calculate pH of 1 M (CH3COO)(CN)Ca salt solution at 25ºC.

25ºC ij 1 M (CH3COO)(CN)Ca yo.k foy;u dh pH ifjdfyr dhft,A
[Ka (CH3COOH) = 10–5, Ka(HCN) = 10–10]
Ans. 12.00
  Kw
Sol. CNaq .  H2O HCNaq.  OHaq . ; Kh1   104
KaHCN
  Kw
CH3COOaq .  H2O CH3COOHaq.  OHaq .; Kh2   109
K aCH COOH
OH  
3

CKh1  CKh2
= 1 10 4  1 10 9 = 10–2
48. Density of an equilibrium mixture (obtained by taking PCl 5 only initially) involving PCl5, Cl2 & PCl3 at 1
atm & 27° C is 6.25 gm/litre. Calculate % dissociation of PCl5 at the same temperature.
PCl5(g) PCl3(g) + Cl2(g)
lkE; feJ.k (tks fd izkjEHk esa dsoy PCl5 ysdj izkIr fd;k tkrk gS) tksfd PCl5, Cl2 o PCl3 ;qDr gS dk 1 atm nkc
o 27° C rki ij ?kuRo 6.25 gm/litre gSA rks leku rki ij PCl5 dk izfr'kr fo?kVu Kkr dhft,&
Ans. 39.00
Sol. PM = dRT
6.25  0.08  300
M= = 150
1
1 –      
W 208.5
Mavg = T =
nT 1 
208.5
1 + =
150
= 0.39
% = 39
49. 1 g sample containing KO2 and some inert impurity is dissolved in excess of aqueous HI solution and
finally diluted to 100 ml. The solution is filtered off and 20 ml of filtrate required 15 ml, 0.4 M Na 2S2O3
solution to reduce the liberated iodine. If mass% of KO 2 in original sample is y % then find y/35.5 value?
KO2 rFkk dqN vfØ; v'kqf) ;qDr 1 g izkn'kZ dks tyh; HI foy;u ds vkf/kD; esa ?kksyk tkrk gS rFkk vUr esa
100ml rd ruq fd;k tkrk gSA foy;u dks Nkuk tkrk gS rFkk 20 ml Nfu=k dks fu"dkflr vk;ksMhu dks vipf;r
djus ds fy, 15 ml 0.4 M Na2S2O3 dh vko';drk gksrh gSA ;fn okLrfod izkn'kZ esa KO2 dk nzO;eku izfr'kr y%
gS rks y/35.5 eku Kkr dhft,A
Ans. 02.00
Sol. The balanced redox reaction is
JPA_P1-46
2KO2 + 6H  2KOH + 2H2O + 32
meq. of hypo = 15×0.4 = 6 = meq of I2
Total I2 liberated = 15 m mol
m mol of KO2 in original sample = 10
mass % = 10×10–3 × 71 × 100 = 71% = y
Sol. larqfyr jsMkWDl vfHkfØ;k gSA
2KO2 + 6HI  2KOH + 2H2O + 3I2
gkbiks dk feyh rqY;kad = 15×0.4 = 6 = I2 ds feyh rqY;kad
fu"dkflr dqy I2 = 15 m mol.
okLrfod izkn'kZ esa KO2 ds feyheksy = 10
nzO;eku % = 10×10–3 ×71×100 = 71% = y
conc.
50. S8 HNO (B)
3
Brown gas
Boiling
(C)
with Na2SO3
clear solution
+ HCl
(D) + (E)
colourless gas white
turbidity
How many of the following statement(s) about the given reaction flow diagram are correct ?
(I) Hybridisation of gas (D) is sp2
(II) Gas (D) cannot act as oxidizing agent
(III) Gas (D) gives starch-iodate test
(IV) Gas (D) can decolourises acidified KMnO4
(V) Gas (B) is paramagnetic.
(VI) White turbidity is of SO 2Cl2
(VII) Sulphur has only two allotropes.
(VIII) In the given process compound (C) disproportionates into (D) and (E).
(IX) Hybridization of gas (B) is sp3
(X) (C) reacts with AgNO3 to form soluble complex
S8 lkanz (B)
HNO3
Hkwjh xSl
Na2SO3 ds lkFk
(C)
mckyus ij
Li"V foy;u + HCl
(D) + (E)
jaxghu xSl lQsn xanykiu
(white turbidity)
fn;s x;s vfHkfØ;k izokg fp=k (reaction flow diagram) ds ckjs esa fdrus dFku lgh gS@gSa \
(I) xSl (D) dk ladj.k sp2 gSA
(II) xSl (D) vkWDlhdkjd dk dk;Z ugha djrh gSA
(III) xSl (D) LVkWpZ vk;ksMsV ijh{k.k nsrh gSA
(IV) xSl (D) vEyhÑr KMnO4 dks fojathÑr dj ldrh gSA
(V) xSl (B) vuqpqEcdh; gSA
(VI) lQsn xanykiu SO2Cl2 dk gSA
(VII) lYQj ds dsoy nks vij:i gksrs gaSA
(VIII) fn;s x;s izØe esa ;kSfxd (C) dk (D) o (E) esa fo"kekuqikrhdj.k gksrk gSA
JPA_P1-47
(IX) xSl (B) dk ladj.k sp3 gSA
(X) (C), AgNO3 ds lkFk fØ;k djds foys;'khy tfVy cukrk gSA
Ans. 05.00
Sol. (I), (III), (IV), (V), (VIII), (X)
S  6HNO3   6NO2  H2SO4  2H2O
(A) (B)
S  Na2SO3  Na2S 2O3
(A) (C)
Na2S2O3  2HCl  SO2  S  2NaCl  H2O
(D) (E)
Excess of (C) reacts with AgNO3 to form soluble complex
(C) dk vkf/kD; AgNO3 ds lkFk fØ;k djds foys;'khy tfVy cukrk gSA
51. How many of the following give colourless gas/gases with conc. H 2SO4 :
fuEu esa ls dqy fdrus lkUnz H2SO4 ds lkFk jaxghu xSl@xSls nsaxs&
H2C2O4, NaCl, K,
HCOOH, KClO3, Na2CO3
KBr, Na3PO4, K4[Fe(CN)6]
Ans. 05.00
52. In the following chlorination reaction, the number of possible achiral products is/are :
fuEufyf[kr Dyksjhuhdj.k vfHkfØ;k esa fufeZr lEHko vfdjSy mRiknksa dh l[;k gS@gSa &
Cl2 / h
   Monochloro product eksuksDyksjks mRikn
Ans. 04.00
CH3 CH3
Cl
Cl
Sol.
Cl Cl
Cis Trans
53. How many alkene/s react faster than propene with dil.H2SO4?
fuEu esa ls fdruh ,Ydhu] izksihu dh rqyuk esa ruq H2SO4 ds lkFk rhozrk ls fØ;k djrh gSaA
Ph
Ph CH3O
(a) (b) (c) (d)
Ph
O
H2 N
(e) (f) (g) (h) Cl
Ans. 06.00
Sol. (a, b , c ,d , e , g)
rate of addition of E  stability of cation
E ds ;ksx dh nj  èkuk;u dk LFkkf;Ro
54. Consider the given sequence of reaction
fuEu vfHkfØ;k vuqØe ij fopkj dhft, &
O O
H3C C HO C
O 
1.Li AlH4 (excess)
2.H2 0

H3C
The total number of possible organic products will be _____.

lEHko dkcZfud mRiknksa dh dqy la[;k gksxh&
Ans. 03.00
JPA_P1-48
O O
HO CH2OH
H3C C HO C
O

1.LiAlH4
2.H2 0
H C
Sol. 3 + + CH3CH 2OH
H3C
OH
Total 3 products are possible.

dqy rhu mRikn lEHko gSaA
JPA_P1-49

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DATE ® P09-20

ADVANCED PATTERN PART TEST-3 (APT-3)

Time : 3 Hours Maximum Marks : 204

SECTION-1 (Maximum Marks : 56)

NAME OF THE CANDIDATE : ………………………………………………… ROLL NO. :………………..………………………..

Resonance Eduventures Limited

Resonance Eduventures Limited

ADVANCED PATTERN PART TEST-3 (APT-3)

Time (le;) : 3 Hours (?k.Vs) Maximum Marks (vf/kdre vad) : 204

Resonance Eduventures Limited

Resonance Eduventures Limited

 This section contains FOURTEEN (14) questions

 Full Marks : +4 If only (all) the correct option(s) is (are) chosen.

and both of which are correct.

 Negative Marks : –1 In all other cases.

 Choosing ONLY (A),(B) and (D) will get +4 marks

 Choosing ONLY (A) and (B) will get +2 marks

 Choosing ONLY (A) and (D) will get +2 marks

 Choosing ONLY (B) and (D) will get +2 marks

 Choosing ONLY (A) will get +1 marks

 Choosing ONLY (B) will get +1 marks

 Choosing ONLY (D) will get +1 marks

 Choosing any other combination of options will get –1 mark

[kaM 1 : (vf/kdre vad : 56)

3. Which of the following is/are correct?

Sol.  sin3A + sin3B + sin3C = 3 sin A sin B sin C

union of case (I) and case (II) is a complete square.

fLFkfr-II |x| |y|

fLFkfr (I) vkSj (II) dk la?k iw.kZ oxZ gSA

(A*) f(x) = 0 ds lfEeJ ewy gSA (B*) a + b + c = 4

sin2 x. sec2 x  2 1  x 2 tan x. sin1 x

(A) f(x) = (sin–1 x) cos2x (B*) f(x) = (sin–1 x) sin2x

(A) f(x) = (sin–1 x) cos2x (B*) f(x) = (sin–1 x) sin2x

so f(x) is increasing function

gy. ;gka tan + tan + tan = 0

SECTION – 2 : (Maximum Marks : 12)

Paragraph for Question Nos. 15 to 16

Paragraph for Question Nos. 17 to 18

b11 b12 b13   a11 a12 a13 

 This section contains FOURTEEN (14) questions

[kaM 1 : (vf/kdre vad : 56)

(D*) the induced emf as a function of time is given as  0  e 600

(A) Maximum charge on capacitor is CE

(A*) Charge on the 1.5 F capacitor will become 180 C.

(A*) VB = V 2  (R)2 (B*) VC = V + R

SECTION – 2 : (Maximum Marks : 12)

Paragraph for Question Nos. 33 to 34

 This section contains FOURTEEN (14) questions

37. Which of the following produce(s) N2 gas?

38. Select the correct statement(s) :

39. NO2   Gas Z

Gas Z   Gas P

Select correct statement(s) :

(A*) izkjEHk esa SO3 ds eksyksa dh la[;k 0.2 eksy gSA

43. A gaseous substance AB2(g) converts to AB(g) in presence of solid A(s) as

Sol. 2Fe+2  (Fe+3)2 + 2e

46. Wolf Kishner reduction can be used for converting

47. Benzyl chloride can be prepared from toluene by chlorination with

(B) PhMgBr (excess vkf/kD;) + Ph–C–CH3  CH3 Ph

(C) F  Cl  Br     (in DMSO) (D*) > N(C2H5)3

(D) No flipping and lesser steric hindrance so is stronger nucleophile

SECTION – 2 : (Maximum Marks : 12)

Paragraph for Question Nos. 51 to 52

Paragraph for Question Nos. 53 to 54

(A) f(x) = 0 ds lfEeJ ewy gSA (B) a + b + c = 4

(A) VB = V 2  (R)2 (B) VC = V + R