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1 2 1 1 2 1
(A) 0 (B) (C) (D) - (A) 0 (B) (C) (D) -
3 3 3 3 3 3
2m F
2m F + –
+ –
q
q
q q
q q
+ – + –
+ – + – 6m F 3m F
6m F 3m F
q q
(A) zero (B) (A) 'kwU; (B)
4 4
2q q
(C) (D) 2q q
3 3 (C) (D)
3 3
22112020 SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg Page 3/39
ALLEN
4. Two small pith balls, each carrying a charge 4. izR;sd q vkos'k fy;s gq, nks y?kq xn~ns kj xsan d yEckbZ dh
q, are attached to the ends of a light rod of
length d, which is suspended from the ceiling
,d gYdh NM+ ds fljksa ls tM q +h gS tks fd fp= esa n'kkZ;s
by a thin torsion-free fiber, as shown in the vuqlkj ejksM+h eqDr irys js'ks ls Nr ls yVdh gAS ;gk¡ ij
figure below. There is a uniform magnetic js'ks ds pkjksa vksj R f=T;k ds csyukdkj izHkkx esa lh/kk
field B, pointing straight down, in the
cylindrical region of radius R around the uhps dh vksj bafxr ,d leku pEq cdh; {ks= B fo|eku
fiber. The system is initially at rest. If the gAS fudk; izkjEHk esa fojkekoLFkk esa gAS ;fn pqEcdh; {ks=
magnetic field is turned off, which of the
gVk fn;k tkrk g]S fuEu esa ls dkuS lk dFku crkrk gS fd
following describes what happens to the
system? fudk; ds lkFk D;k ?kfVr gqvk\
Fiber Fiber
Field Field
Region Region
Rod Rod
q q q q
d d
R R
(
(A) V = 2 - 2 2 Ir ) (
(B) V = 2 + 2 2 Ir ) (
(A) V = 2 - 2 2 Ir ) (
(B) V = 2 + 2 2 Ir )
(C) V = 4.5 Ir (D) V = 3.0 Ir (C) V = 4.5 Ir (D) V = 3.0 Ir
6. Two blocks A and B of masses m and M are 6. nzO;eku m rFkk M ds nks CykWd A rFkk B fp= esa
placed in a platform as shown in the figure. n'kkZ;s vuqlkj ,d IysVQkeZ ij j[ks gSaA iwjh O;oLFkk
The whole arrangement is placed inside an ,d fy¶V esa j[kh gS tks fd uhps dh vksj f (f < g)
elevator which is coming down with an Roj.k ls vk jgh gSA fudk; dh lkE;koLFkk esa fcuk
acceleration f (f < g). What maximum
horizontal force F can be applied to A
ifjorZu A ij vf/kdre fdruk {kSf rt cy F yxk;k
without disturbing the equilibrium of the tk ldrk gS\ (;gk¡ CykWdksa ds chp ?k"kZ.k xq.kkad m
system ? (Here m is coefficient of friction rFkk CykW d B rFkk fy¶V ds Q'kZ ds chp ?k"kZ .k ugha
between blocks & frictionless between block gS A )
B & lift floor)
A
A F
F m
m f
f B M
B M T
T
(A) 2 mmg (B) 2 mm(g – f)
(A) 2 mmg (B) 2 mm(g – f)
(C) 2 mm(g + f) (D) None of these (C) 2 mm(g + f) (D) buesa ls dksbZ ugha
22112020 SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg Page 5/39
ALLEN
7. A bar magnet has a length 8 cm. The 7. ,d NM+ pqEcd dh yEckbZ 8 cm gSA fuj{kh; fLFkfr
magnetic field at a point at a distance 3 cm
ij dsUæ ls 3 cm dh nw jh ij fLFkr fdlh fcUnq ij
from the centre in the broad side-on position
8. For a step-up transformer, the turns 8. fdlh mPpk;h VªkWUlQkWeZj esa ?ksjksa dh la[;k dk vuqikr 3
ratio is 3 and its efficiency is 0.75. The
rFkk bldh n{krk 0.75 gAS izkFkfed dq.Myh eas izokfgr
current flowing in the primary coil is 2A
èkkjk dk eku 2A rFkk bl ij vkjksfir oksYVrk dk eku
and the voltage applied to it is 100 V.
Then the voltage and the current flowing 100 V gAS f}rh;d dq.Myh esa oksYVrk rFkk izokfgr èkkjk
V V
(A) (A)
x x
V V
(B) (B)
x x
V V
(C) (C)
x x
V V
(D) (D)
x x
22112020 SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg Page 7/39
ALLEN
10. A block of mass 1 kg is kept over another 10. 1 kg nzO;eku dk ,d CykWd 2 kg nz O;eku ds nwljs
block of mass 2 kg and the whole system is
CykWd ds Åij j[kk tkrk gS rFkk lEiw.kZ fudk; ,d fpdus
kept on a smooth X-Z plane. Block of mass
1kg is being moved continuously with X-Z ry ij j[kk tkrk gAS 1 kg æO;eku ds CykWd dks
velocity 1 m/s towards positive X-axis and yxkrkj 1 m/s ds osx ls /kukRed X-v{k dh vksj xfr
lower block is moved continuously with djk;h tkrh gS rFkk uhps okys CykWd dks yxkrkj èkukRed
velocity 1m/s towards positive Z-axis as
Z-v{k ds vuqfn'k 1 m/s ds osx ls fp=kuqlkj xfr
shown in figure. If coefficient of friction
between two blocks is 0.1, the rate at which djk;h tkrh gAS ;fn nksuksa CykWdksa ds chp ?k"kZ.k xq.kkad
heat is generated will be 0.1 gS rks og nj ftlls Å"ek mRiék gksxh] g%S &
Y Y
(vertical) (vertical)
g=10m/s2 g=10m/s2
1m/s 1m/s
X X
(horizontal) (horizontal)
Z Z
1m/s 1m/s
1 1
(D) J/sec (D) J/sec
2 2
l
l
r0
r0 w
w
22112020 SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg Page 9/39
ALLEN
12. Currents I 1 and I 2 flow in the wires shown 12. /kkjk I1 rFkk I2 fp= esa n'kkZ;s vuqlkj rkjksa esa izokfgr gksrh
in figure. The magnetic field is zero on
x-axis at distance x to the right of O. gAS x v{k ij O ds nkb± vksj x nwjh ij pEq cdh; {ks=
Then, 'kwU; gS rks&
I1 I1
I1 O (a,0) I2 I1 I2
O (a,0)
(–a,0) (–a,0)
I2 I2
æ I1 ö æ I1 ö
(A) x = ç ÷a (A) x = ç
è I2 ø ÷a
è I2 ø
2æI ö æI ö
(B) x = ç I ÷ a 2
(B) x = ç I ÷ a
è 1 ø è 1 ø
1æI -I ö
2 æI -I ö
(C) x = ç I + I ÷ a 1 2
(C) x = ç I + I ÷ a
è 1 2ø è 1 2ø
1æI +I ö
2 æI +I ö
(D) x = ç I - I ÷ a 1 2
(D) x = ç I - I ÷ a
è 1 2ø è 1 2ø
O
O
mg æ 103 ö mg æ 103 ö
+ 3÷ (A) ç + 3÷
(A) ç 2 è 3 ø
2 è 3 ø
mg æ 103 ö mg æ 103 ö
- 3÷ (B) ç - 3÷
(B) ç 2 è 3 ø
2 è 3 ø
mg æ 3ö mg æ 3ö
(C) ç 103 - ÷ (C) ç 103 - ÷
2 è 3 ø 2 è 3 ø
mg æ 3ö mg æ 3ö
(D) ç 103 + ÷ (D) ç 103 + ÷
2 è 3 ø 2 è 3 ø
22112020 SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg Page 11/39
ALLEN
14. A circular loop of radius 2 m is kept in a 14. 2 m f=T;k dk ,d o` rh; yw i 2T lkeF;Z ds ,d
magnetic field of strength 2T (plane of loop
pqEcdh; {ks= esa j[kk tkrk gS (ywi dk ry pqEcdh; {ks=
is perpendicular to the direction of magnetic
2
2 dh fn'kk ds yEcor~ g)S ywi dh rkj dk izfrjks/k Wm -1
Wm -1 .
field). Resistance of the loop wire is p
p
A conductor of length 4m is sliding with a gS = esa n'kkZ;s vuqlkj 4m yEckbZ dk ,d pkyd
speed 2 ms–1 as shown in the figure. Find 2ms dh pky ls fQly jgk g SA NM+ ij dk;Z jr
–1
the instantaneous force acting on the rod : rkR{kf.kd cy Kkr djksA ;g ekurs gaS fd NM+ dk ux.;
(Assuming the rod to have a negligible
resistance)
izf rjks/k gSA
Ä Ä Ä Ä Ä Ä Ä Ä Ä Ä Ä Ä
Ä Ä Ä Ä Ä Ä Ä Ä Ä Ä Ä Ä
Ä Ä Ä Ä Ä Ä Ä Ä Ä Ä –1
Ä Ä
2ms
–1 2ms
Ä Ä Ä Ä Ä Ä Ä Ä Ä Ä Ä Ä
Ä Ä Ä Ä Ä Ä Ä Ä Ä Ä Ä Ä
a ac a
ac
a ac a
ac
at at
at at (C) (D)
(C) (D)
t t
t t
22112020 SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg Page 13/39
ALLEN
18. A short bar magnet of magnetic moment 18. pEq cdh; vk?kw.kZ 0.4 J T–1 dh ,d y?kq NM + pEq cd
0.4 J T–1 is placed in a uniform magnetic field
0.16 T ds ,d ,dleku pqEcdh; {ks= esa j[kh tkrh gA S
of 0.16 T. The magnet is in stable equilibrium
when the potential energy is pqEcd LFkkbZ lkE;koLFkk esa gS tc fLFkfrt ÅtkZ g&S
(A) 0.64 J (B) zero (A) 0.64 J (B) 'kwU;
(C) –0.082 J (D) –0.064 J (C) –0.082 J (D) –0.064 J
19. Two identical balls are set into motion 19. nks ,d leku xsansa ,d lkFk leku Å¡pkbZ h ls xfr djkbZ
simultaneously form equal heights h. While tkrh gAS xsan A {kfS rtor~ v osx ls Qsadh tkrh gS tcfd
the ball A is thrown horizontally with velocity v,
xsan B Lo;a uhps fxjus ds fy, eqDr dh tkrh gAS og
the ball B is just released to fall by itself.
Choose the alternative that best represents fodYi pqfu;s tks A rFkk B dh xfr dks fp= esa n'kkZ;s
the motion of A and B with respect to an vuqlkj /kjkry ds lkis{k v/2 osx ds lkFk xfr djrs
observer who moves with velocity v/2 with izs{kd ds lkis{k lgh ls n'kkZrk g&S
respect to the ground as shown in the figure.
A B
A B
h h
h v/2
v/2 h
ground
ground
A B A B
A B A B
(A) (B)
(A) (B)
A B A
A B B
A B
(C) (D)
(C) (D)
A
A
B
B
C
C
S
S
(A) t ® ¥
(A) t ® ¥
(B) t = RC
(B) t = RC
(C) t = RCloge(2)
(C) t = RCloge(2)
(D) all the t values (D) t ds lHkh ekuksa ds fy;s
22112020 SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg Page 15/39
ALLEN
SECTION-II : (Maximum Marks: 20) [kaM -II : (vf/kdre vad : 20)
This section contains FIVE questions. bl [kaM esa ik¡ p iz'u gSaA
The answer to each question is a iz R ;s d iz ' u dk mÙkj ,d la[;kRed eku
NUMERICAL VALUE. (NUMERICAL VALUE) gSA
For each question, enter the correct iz R ;s d iz ' u ds mÙkj ds lgh la [ ;kRed eku
numerical value (If the numerical value has (;fn la[;kRed eku esa nks ls vf/kd n'keyo LFkku
more than two decimal places, truncate/ g]S rks la[;kRed eku dks n'keyo ds nks LFkkuksa rd
round-off the value to TWO decimal places; VªadsV@jkmaM vkWQ (truncate/round-off) djs_a mnkgj.k
e.g. 6.25, 7.00, –0.33, –.30, 30.27, –127.30, if 6.25, 7.00, –0.33, –.30, 30.27, –127.30, ;fn mÙkj
answer is 11.36777..... then both 11.36 and
11.36777..... g]S rks 11.36 vkjS 11.37 nksuksa lgh gksxsa)
11.37 will be correct) by darken the
dks izfo"B djus ds fy, vks-vkj-,l- esa vuq:i cqycqys
corresponding bubbles in the ORS.
dks dkyk djsaA
For Example : If answer is –77.25, 5.2 then
mnkgj.k ds fy, : ;fn mÙkj –77.25, 5.2 g]S rks cqycqyksa
fill the bubbles as follows.
dks fuEu izdkj ls dkyk djsaA
+ – + – + – + –
0 0 0 0 • 0 0 0 0 0 0 • 0 0 0 0 0 0 • 0 0 0 0 0 0 • 0 0
1 1 1 1 • 1 1 1 1 1 1 • 1 1 1 1 1 1 • 1 1 1 1 1 1 • 1 1
2 2 2 2 • 2 2 2 2 2 2 • 2 2 2 2 2 2 • 2 2 2 2 2 2 • 2 2
3 3 3 3 • 3 3 3 3 3 3 • 3 3 3 3 3 3 • 3 3 3 3 3 3 • 3 3
4 4 4 4 • 4 4 4 4 4 4 • 4 4 4 4 4 4 • 4 4 4 4 4 4 • 4 4
5 5 5 5 • 5 5 5 5 5 5 • 5 5 5 5 5 5 • 5 5 5 5 5 5 • 5 5
6 6 6 6 • 6 6 6 6 6 6 • 6 6 6 6 6 6 • 6 6 6 6 6 6 • 6 6
7 7 7 7 • 7 7 7 7 7 7 • 7 7 7 7 7 7 • 7 7 7 7 7 7 • 7 7
8 8 8 8 • 8 8 8 8 8 8 • 8 8 8 8 8 8 • 8 8 8 8 8 8 • 8 8
9 9 9 9 • 9 9 9 9 9 9 • 9 9 9 9 9 9 • 9 9 9 9 9 9 • 9 9
22112020 SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg Page 17/39
ALLEN
4. A disc of mass M and radius R is placed on a 4. M nzO;eku rFkk R f=T;k dh ,d pdrh ,d [kqjnjh
rough horizontal surface. A light rod of
{kfS rt lrg ij j[kh tkrh gAS fp= esa n'kkZ;s vuqlkj ,d
length 2R is fixed to the disc at point A as
2R yEckbZ dh gYdh NM+ pdrh ls fcUnq A ij fLFkj dh
3
shown in the figure and force Mg is 3
2 tkrh gS rFkk nwljs fljs ij cy Mg vkjksfir fd;k
applied at the other end. The minimum 2
value of coefficient of friction between disc tkrk gAS pdrh rFkk {kSfrt lrg ds chp U;wure ?k"kZ.k
and horizontal surface so that disc starts to xq.kkad dk eku rkfd pdrh fcuk fQlys yq <+duk çkjEHk
roll without slipping is given by m, then find
the value of 10m.
dj ns] m }kjk fn;k tkrk gS rks 10m dk eku Kkr djksA
A 2R 3/2Mg
A 2R 3/2Mg
R/2
R/2
O
O
R
R
5. Four very long, current carrying wires 1, 2, 5. pkj cgqr yEcs /kkjkokgh rkj 1, 2, 3 rFkk 4 fp= esa n'kkZ;s
3 and 4 in the same plane intersect to form a vuqlkj izR;sd Hkqtk ij 40 cm oxZ cukus ds fy, ,d gh
square 40 cm on each side, as shown in
figure. Find the magnitude of the current I ry esa çfrPNsn djrs gAS rkj 2 esa /kkjk I dk ifjek.k Kkr
in wire 2, so that the magnetic field at the djks rkfd oxZ ds dsUnz ij pEq cdh; {ks= 'kwU; gksA ;g
centre of the square is zero. Assume that ekurs gaS fd fdlh Hkh rkj ds ;qXe ds chp fr;Zd lEidZ
there are no cross-contacts between any pair
of wires. Give your answer in ampere. ugha gAS vkidk mÙkj ,fEi;j esa nhft;sA
10A 10A
I 8A I 8A
WIRE 4 WIRE 4
20A 20A
WIRE 3 WIRE 3
(A) Ph—NH—Ph < Ph—NH2 < (A) Ph—NH—Ph < Ph—NH2 <
H H
N N
(B) < < (B) < <
N N N N
H H
NH2 NH2
22112020 SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg Page 19/39
ALLEN
2. Among the given reactions, which is the best 2. fuEu esa ls dkuS lh vfHkfØ;k] SN2 vfHkfØ;k dk loZJ"s B
example of SN2 reaction ? mnkgj.k g&S
CH3 CH3
CH3 CH3 CH3OH
CH3OH (A) ¾¾¾¾
®
(A) ¾¾¾¾ ®
Cl OCH3
Cl OCH3
CH3 CH3
CH3 CH3
(B) H3C C H2 O
Br ¾¾¾ ® H3C C OH
(B) H3C C H2 O
Br ¾¾¾ ® H3C C OH
CH3 CH3
CH3 CH3
s
s (C) Ph-CH2–Cl ¾¾¾¾
CH3O
® Ph–CH2–OCH3
(C) Ph-CH2–Cl ¾¾¾¾® Ph–CH2–OCH3
CH3O
DMSO
DMSO
CH3
CH3
AgNO3
AgNO3 (D) H3C C CH2 Cl ¾¾¾¾ ®
(D) H3C C CH2 Cl ¾¾¾¾
H2 O
® H2 O
CH3
CH3
OH OH
H3C C CH2 CH3 H3C C CH2 CH3
CH3 CH3
3. Which of the following reaction will give 3. fuEu esa ls dkuS lh vfHkfØ;k ls eq[; mRikn ds :i esa
different alcohol as major product ? vyx ,sYdksgkWy izkIr gksxk\
(A) ¾¾¾¾
2 H+ / H O
® (B) H+ / H O
¾¾¾¾
2
® (A) ¾¾¾¾
2
®
H+ / H O (B) ¾¾¾¾
2 H+ / H O
®
(C) ¾¾¾¾
2 H+ / H O
® (D) ¾¾¾¾
2 H+ / H O
® (C) ¾¾¾¾
2
®
H+ / H O (D) ¾¾¾¾
2
®
H+ / H O
(B) Ph — O — Me ¾¾
HI
®
(B) Ph — O — Me ¾¾
HI
®
(C) Ph — O — Ph ¾¾¾¾
H /H O + (C) Ph — O — Ph ¾¾¾¾
H /H O
®
+
2
® 2
O O
Cl Mg (D) MeO Cl Mg
(D) MeO ¾¾¾ ® ¾¾ ¾®
5. Which of the following reaction cannot 5. fuEu esa ls fdl vfHkfØ;k esa vafre mRikn ds :i esa
produce amine as final product. ,ehu ugha cu ldrk g\ S
O O
N H
N H
(A) CH3—C—OH ¾¾¾¾¾ ® 3 (A) CH —C—OH ¾¾¾¾¾
Conc. H SO
® 3
2 4
Conc. H SO 2 4
3
O O (i) N 3 H Conc. H 2 SO 4
(B)
(i) N 3 H Conc. H 2 SO 4
¾¾¾¾¾¾¾ (ii) LiAlH 4
® (B) ¾¾¾¾¾¾¾ (ii) LiAlH 4
®
O O (i) NH 2 OH
(C)
(i) NH 2 OH
¾¾¾¾
(ii) H+ / D
® (C) ¾¾¾¾
(ii) H+ / D
®
O O
(i) NH 3 / D
(D) (i) NH 3 / D
¾¾¾¾¾
(ii) NaOH, Br2
® (D) ¾¾¾¾¾
(ii) NaOH, Br2
®
OH OH
6. By which of the following reaction sequence 6. fuEu esa ls fdl vfHkfØ;k Øe ls Nylon–5 cuk ldrs g\
aS
can Nylon–5 be prepared.
Å
( i)NH2 - OH,(ii )H + H2O
( i)NH2 - OH,(ii )HÅ + H2O (A) O ¾¾¾¾¾¾¾¾
(iii) D + H3 OÅ
® Nylon–5
(A) O ¾¾¾¾¾¾¾¾
(iii) D + H3 OÅ
® Nylon–5
( i )N 3 H,H2SO4
(B)
( i )N 3 H,H2SO4
O ¾¾¾¾¾¾ ® Nylon–5 (B) O ¾¾¾¾¾¾
(ii ) D + H3 OÅ
® Nylon–5
(ii ) D + H3 OÅ
O O
O—Et O—Et
Å
( i )Na - O - Et, ( ii ) H3O + D
(C)
( i )Na - O - Et, (ii )H3 OÅ + D
¾¾¾¾¾¾¾¾¾
® Nylon–5 (C) ¾¾¾¾¾¾¾¾
(iii )NH - OH, HÅ , H OÅ
¾® Nylon–5
O—Et (iii )NH2 - OH, HÅ , H3OÅ O—Et (iv) D / H3OÅ
2 3
(iv ) D / H OÅ
O
3
O
(D) All of these (D) mijksDr lHkh
Enthusiast Course 0000CJA102120023
22112020 SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg Page 21/39
ALLEN
7. Which of the following statement is 7. fuEu esa ls dkuS lk dFku xyr g\
S
incorrect?
(A) As2S3 ,d ½.kkosf'kr lkWy gAS
(A) As2S3 is a negatively charged sol.
(B) dksykbMksa ds }kjk czkmfu;u xfr o fV.My izHkko
(B) Brownian movement and Tyndall effect
iznf'kZr fd;s tkrs gaSA
are shown by colloids
(C) tc ,d nzo] nwljs nzo esa ifj{ksfir gksrk gS rks bls
(C) When liquid is dispersed in liquid, it is
called gel. ty
S dgrs gSaA
(D) Gold number is a measure of protective (D) Lo.kZ la[;k] nzo Lusgh dksykbM dh laj{k.k {kerk dk
power of lyophilic colloid.
eki gksrh gSA
8. The distance of spherical nodes from nucleus 8. fn;s x;s d{kd ds fy,] ukfHkd vkjS xksykdj uksM ds
for the given orbital are
e/; dh nwjh&
3/2 3/2
1 æ Zö 1 æ Zö
y radial = [( s2 - 4s + 3)] exp( -s / 2) y radial = [( s2 - 4s + 3)] exp( -s / 2)
9 2 çè a 0 ÷ø 9 2 çè a 0 ÷ø
2Zr 2Zr
where a0 & Z are the constants and s = tgka a0 rFkk Z fu;rkad gaS rFkk s=
a0 a0
3 a0 1 a0 3 a0 1 a0
(C) , (C) ,
2 Z 2 Z 2 Z 2 Z
a 0 3 a0 a 0 3 a0
(D) , (D) ,
Z 2 Z Z 2 Z
Cl
(D) dh rqyuk esa H2O ds
Cl
for reaction with H2O
Cl
lkFk vfHkfØ;k ds fy, vf/kd fØ;k'khy gS
10. Which of the following is correct on the basis 10. MOT ds vk/kkj ij dkuS lk dFku lR; g\
S
of MOT ?
(A) ca/k lkeF;Z % CO > CO+
(A) Bond strength of CO > CO+ (B) ca/k yEckbZ dk Øe : O2 > O2+ > O2–
(B) Bond length order : O2 > O2+ > O2–
(C) v;q f Xer bys D Vª k W u ks a dh la [ ;k dk Øe :
(C) Number of unpaired electrons order : O2 > NO > CO
O2 > NO > CO
(D) ABMO bys D Vª k W u ks a dh la [ ;k dk Øe :
(D) Number of ABMO electrons order :
Be2 < O2 < N2–
Be2 < O2 < N2–
22112020 SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg Page 23/39
ALLEN
11. Ag |Ag+|| Cl– |AgCl| Ag 11. Ag |Ag+|| Cl– |AgCl| Ag
If above cell contain same [Ag +] in both
cathodic and anodic half cell then select
;fn mijksDr lsy esa] dFS kksfM; vkjS ,uksfM; nksuksa v¼Z
correct option : lsykas esa [Ag+] leku gS rc lgh fodYi gksxk\
(A) E Cell = 0 (B) E oCell = 0 (A) E Cell = 0 (B) E oCell = 0
(C) E Cell > 0 (D) E Cell < 0 (C) E Cell > 0 (D) E Cell < 0
H+ / H O H+ / H O
12. ¾¾¾¾
2
® P (major product) 12. ¾¾¾¾
2
® P (eq[; mRikn)
Which of the following reaction will give fuEu esa ls dkuS lh vfHkfØ;k ls mijksDr vfHkfØ;k ds
same alcohol (P) leku ,Ydksgy (P) fufeZr gksxk\
NH2 NH2
(A) HONO
¾¾¾® (A) HONO
¾¾¾®
NH2 NH2
(C) HONO
¾¾¾® (C) HONO
¾¾¾®
4
14. One mole homo triatomic gas effuses 14. leku ifjfLFkfr;ksa esa ,d eksy le f=ijekf.o; xSl]
3
Cl Cl Me
Me
CH3 CH3
CH3 CH3 Me H
Me H H Cl H Cl H Cl H Cl
H Cl H Cl
15. Cl H Cl H Cl Et 15. Cl H Cl H Cl Et
H Cl H Cl
C2H5 C2H5
C2H5 C2H5
Et H Et
(III) (III) H
(I) (II) (IV) (I) (II) (IV)
Which of the following statement is false mijksDr leko;fo;ksa ds lUnHkZ esa] fuEu esa ls dkSulk
about these isomers ? dFku xyr gS\
(A) I and II are a pair of enantiomer
(A) I rFkk II izfrfcEc :i leko;fo;ksa dk ;qXe
(B) III and IV are a pair of enantiomer (B) III rFkk IV izfrfcEc :i leko;fo;ksa dk ;qXe
(C) I and II are a pair of diastereomers (C) I rFkk II foofje leko;fo;ksa dk ;qXe
(D) I and IV are a pair of diastereomers (D) I rFkk IV foofje leko;fo;ksa dk ;qXe
22112020 SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg Page 25/39
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16. Which of the following ester on heating will 16. fuEu esa ls dkSulk ,LVj xeZ fd, tkus ij ,slh eq[;
produce major alkene with 5a hydrogen and ,sYdhu mRikfnr djsxk ftlesa 5a gkbMªkt
s u mifLFkr gksa
not showing Geometrical isomerism.
rFkk T;kfefr; leko;ork iznf'kZr ugha djrh gks\
(A) (B)
O—C—CH3 O—C—CH3
(A) O—C—CH3 (B) O—C—CH3
O O
O O
Ph
Ph
(C) (D)
O—C—CH3 O—C—CH3
(C) O—C—CH3 (D) O—C—CH3
O O
O O
R R OH R R OH
+
O H + /H 2 O
18. O
H /H 2 O
18.
R
R R OH R OH
Which of the following will produce fuEu esa ls fdlds }kjk gkbMªVs dh lokZf/kd ek=k mRikfnr
maximum amount of hydrate ? gksxh\
O O
O O
(A) (B) (A) (B)
H Ph H
H Ph H
O O
O O
(C) (D) (C) (D)
H H Ph
H H Ph
O
O
(B)
CH 3 H (B)
CH 3 H
O
O
(C)
(C) H 3C Cl
H 3C Cl
O O
(D) H 3C OH
(D)
H 3C OH
22112020 SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg Page 27/39
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SECTION-II : (Maximum Marks: 20) [kaM -II : (vf/kdre vad : 20)
This section contains FIVE questions. bl [kaM esa ik¡ p iz'u gSaA
The answer to each question is a
iz R ;s d iz ' u dk mÙkj ,d la[;kRed eku
NUMERICAL VALUE. (NUMERICAL VALUE) gSA
– – + – + –
+ +
0 0 0 0 • 0 0 0 0 0 0 • 0 0 0 0 0 0 • 0 0 0 0 0 0 • 0 0
1 1 1 1 • 1 1 1 1 1 1 • 1 1 1 1 1 1 • 1 1 1 1 1 1 • 1 1
2 2 2 2 • 2 2 2 2 2 2 • 2 2 2 2 2 2 • 2 2 2 2 2 2 • 2 2
3 3 3 3 • 3 3 3 3 3 3 • 3 3 3 3 3 3 • 3 3 3 3 3 3 • 3 3
• • 4 4 4 4 • 4 4 4 4 4 4 • 4 4
4 4 4 4 4 4 4 4 4 4 4 4
5 5 5 5 • 5 5 5 5 5 5 • 5 5 5 5 5 5 • 5 5 5 5 5 5 • 5 5
6 6 6 6 • 6 6 6 6 6 6 • 6 6 6 6 6 6 • 6 6 6 6 6 6 • 6 6
7 7 7 7 • 7 7 7 7 7 7 • 7 7 7 7 7 7 • 7 7 7 7 7 7 • 7 7
8 8 8 8 • 8 8 8 8 8 8 • 8 8 8 8 8 8 • 8 8 8 8 8 8 • 8 8
• • 9 9 9 9 • 9 9 9 9 9 9 • 9 9
9 9 9 9 9 9 9 9 9 9 9 9
22112020 SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg Page 29/39
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4. How many moles of Grignard reagent will 4. fuEu vfHkfØ;k esa fn;s x;s ;kfS xd ds ,d eksy ds fy,
be consumed per mole of given compound
xzhU;kj vfHkdeZd ds fdrus eksy mi;ksx esa fy, tk;sxas\
during the following reaction ?
OH OH
MeHN MeHN
(1) CH - MgBr (excess)
(1) CH3 - MgBr (excess)
¾¾¾¾¾¾¾¾¾
® ¾¾¾¾¾¾¾¾¾
3
®
O Å O Å
(2) H3 O
(2) H3 O
H H
CH 2OH CH 2OH O
O
5. Identify correct number of statements 5. lgh dFkuksa dh la[;k crkb;sA
(i) Chloral hydrate shows intramolecular (i) Dyksjy gkbMªV
s esa vUr%vkf.od H–ca/k mifLFkr gksrs
H–bond. gSaA
(ii) Mono anion of caro’s acid shows
intramolecular H–bond
(ii) dSj ks vEy ds ,dy ½.kk;u es a vUr%vkf.od
H–ca/k mifLFkr gksrs gSaA
(iii) Order of bond angle : Cl2O > F2O
(iv) Order of bond angle : F2O < H2O
(iii) ca/k dks.k dk Øe % Cl2O > F2O
(v) Order of bond angle : AsI3 > AsBr3 > AsCl3 (iv) ca/k dks.k dk Øe % F2O < H2O
(vi) BF3, CH4, PCl5, SF6, IF7, XeF4 all are (v) ca/k dks.k dk Øe % AsI3 > AsBr3 > AsCl3
Non–polar
(vi) BF 3 , CH 4, PCl 5, SF 6 , IF 7 , XeF 4 lHkh
(vii) p-nitrophenol has less boiling point as v/kqzoh; gaSA
compared to o–nitrophenol
(vii) o–ukbVªk fs QukWy dh rqyuk esa p-ukbVª kfs QukWy dk
(viii) In trisilyl amine (SiH3)3 N, the Si—N
bond length is lesser than expected DoFkukad de gksrk gS
value (viii) Vªkbflfyu ,ehu (SiH3)3 N esa Si—N ca/k yEckbZ]
(ix) The Be atom in BeCl 2 (s) is sp 3 visf{kr ls de gksrh gAS
hybridised.
(ix) BeCl2(s) esa Be ijek.kq sp3 ladfjr gksrk gAS
22112020 SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg Page 31/39
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p/ 2 p/ 2 1
x
1
tan -1 x x tan -1 x
3. Given I = ò sin x
dx , J = ò
x
dx . Then 3. fn;k x;k gS I= ò0
sin x
dx , J = ò
0
x
dx
0 0
I I
value of is : rc dk eku gS
J J
4. ƒ(x) is a polynomial of degree 6 which 4. ;fn ƒ(x) ,d 6 dh ?kkr dk cgqin gS tks vUrjky (0,¥)
decreases in the interval (0,¥) and increases esa ?kVrk g S rFkk vUrjky (– ¥,0) es a c<+r k gSA ;fn
in the interval (–¥,0). If ƒ'(2) = 0, ƒ'(0) = 0,
ƒ'(2) = 0, ƒ'(0) = 0, ƒ"(0) = 0, ƒ(0) = 1 rFkk
8
ƒ"(0) = 0, ƒ(0) = 1 and ƒ(1) – ƒ(–1) = , then 8
5 ƒ(1) – ƒ(–1) = ] rc ƒ(1) + ƒ(–1) dk eku g&S
5
ƒ(1) + ƒ(–1) equals-
8 1
8 1 (A) (B) -
(A) (B) - 5 3
5 3
(C) 2 (D) 1
(C) 2 (D) 1
5. If a1, a2 ...... an are the integers in the range 5. ;fn f ( x ) = 9 - x -1 - 2 x - 4 - x - 2 ds ifjlj
of f ( x ) = 9 - x - 1 - 2 x - 4 - x - 2 , then esa iw.kk±d a1, a2 ...... an ga]S rc
n n
6. The area of the region bounded by the 6. lehdj.k |x + 2y| + |2x – y| = 10 }kjk ifjc¼
equation, |x + 2y| + |2x – y| = 10 is {ks= ds {ks=Qy dk eku g&S
(A) 40 (B) 80
(A) 40 (B) 80
(C) 200 (D) 100 (C) 200 (D) 100
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7. If a1x1 + a2x2 + a3x3 + a4x4 = 1432 7. ;fn a1x1 + a2x2 + a3x3 + a4x4 = 1432
a7x1 + a6x2 + a5x3 + a8x4 = 2341 a7x1 + a6x2 + a5x3 + a8x4 = 2341
a11x1 + a12x2 + a13x3 + a10x4 = 3412 a11x1 + a12x2 + a13x3 + a10x4 = 3412
a17x1 + a16x2 + a15x3 + a14x4 = 4321 a17x1 + a16x2 + a15x3 + a14x4 = 4321
where a1, a2, a3 ......... a17 are in A.P. with tgka a1, a2, a3 ......... a17 lekUrj Js.kh esa gSa rFkk
a1 + a2 + a3 .......... a17 = 4369. a1 + a2 + a3 .......... a17 = 4369.
Then the value of [x1 + x2 + x3 + x4] is rc [x1 + x2 + x3 + x4] dk eku g&S (tgka [.] egÙke
(where [.] denotes G.I.F.) iw.kk±d Qyu dks O;Dr djrk g)S
(A) 11 (B) 10 (C) 13 (D) 9 (A) 11 (B) 10 (C) 13 (D) 9
d2y d2y
8.
p q
If x y = (x + y)
p+q
then the value of is 8. ;fn xpyq = (x + y)p + q rc dx 2 dk eku gS
dx 2
(where p, q Î N) : (tgka p, q Î N)
(A) 0 (B) –1 (A) 0 (B) –1
(C) 1 (D) None of these (C) 1 (D) buesa
ls dksbZ ugha
2
9. If a and b are the roots of the equation 9. ;fn a rFkk b lehdj.k x + 10x – 7 = 0 ds ewy gSa
2
x + 10x – 7 = 0 then the value of
(
a12 + b12 - 7 a10 + b10 )
12
a +b -7 a +b 12
( 10 10
) rc
(
2 a +b11 11
) dk eku g&S
(
2 a +b 11 11
) is
(A) 5 (B) –5 (C) 10 (D) –10 (A) 5 (B) –5 (C) 10 (D) –10
dy dy
10. If = sin(x + y) then which of the following 10. ;fn = sin(x + y) rc fuEUkfyf[kr esa ls lR; dFku
dx dx
is correct
g&S
(A) sec (x + y) – tan (x + y) = x + c
(A) sec (x + y) – tan (x + y) = x + c
(B) sec (x + y) + tan (x + y) = x + c (B) sec (x + y) + tan (x + y) = x + c
(C) tan (x + y) – sec (x + y) = x + c (C) tan (x + y) – sec (x + y) = x + c
(D) None of these (D) bueas ls dksbZ ugha
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22112020 SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg Page 33/39
ALLEN
æp ö æp ö æp ö æp ö
11. If tan ç + q ÷ + tan ç - q ÷ = l sec 2q , then l 11. ;fn tan ç + q ÷ + tan ç - q ÷ = l sec 2q gks] rks l
è4 ø è4 ø è4 ø è4 ø
12. Suppose A and B are two non-singular 12. ekuk A rFkk B, n dksfV ds nks O;wRØe.kh; vkO;wg bl
2
matrices of order 'n' such that AB = BA and izdkj gaS fd AB = BA2 rFkk B5 = I, rc fuEUkfyf[kr esa
5
B = I, then which of the following is correct
ls lR; dFku g&S
31 31
(A) A =I (B) A =I (A) A
31
=I (B) A
31
=I
30 50 30 50
(C) A =I (D) A =I (C) A =I (D) A =I
where I is an identity matrix of order n tgka I, n dksfV dk bdkbZ vkO;wg gS
r r r
13. If position vectors of the points A, B & C are 13. ;fn fcUnqvksa A, B rFkk C ds fLFkfr lfn'k Øe'k% a, b, c
r r r
a, b, c respectively and the points D & E gaS rFkk fcUnqvksa D ,oa E js[kk[k.M AC rFkk AB dks
divides line segments AC and AB in the ratio Øe'k% 2 : 1 rFkk 1 : 3 ds vuqikr esa ckaVrk g]S rc BD
2 : 1 & 1 : 3 respectively. Then point of
dk EC dk izfrPNsn fcUnq EC dks fdl vuqikr esa
intersection of BD & EC divides EC in the
ratio ckaVsxk&
(A) 2 : 1 (B) 1 : 3 (A) 2 : 1 (B) 1 : 3
14. In an equilateral triangle, if inradius is a 14. ,d leckgq f=Hkqt esa ;fn vUr%f=T;k ,d ifjes; la[;k
rational number, then which of the following g]S rc fuEUkfyf[kr esa ls vlR; dFku gS&
are incorrect-
(A) ifjf/k lnoS ifjes; gS
(A) perimeter is always rational
(B) {ks=Qy lnoS vifjes; gS
(B) area is always irrational
(C) ifjo`Ùk f=T;k lnSo ifjes; gS
(C) circumradius is always rational
(D) exradii are always rational (D) ckg~; f=T;k lnoS ifjes; gS
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ALLEN
15. If a and b are are the real roots of the 15. ;fn a rFkk b lehdj.k x3 – px – 4 = 0, p Î R ds
3
equation x – px – 4 = 0, p Î R such that okLrfod ewy bl izdkj gaS fd 2a + b = 0 rc (2a3 + b3)
3 3
2a + b = 0 then the value of (2a + b ) equals dk eku gS
(A) 6 (B) 9 (C) 12 (D) 48 (A) 6 (B) 9 (C) 12 (D) 48
x x –1 x x –1
16. Consider the function f(x) = xe + (xe ) , 16. ekuk Qyu f(x) = xe + (xe ) g]S
where x Î R - { 0} , then which of the tgka x Î R - { 0} , rc fuEUkfyf[kr esa ls lR; dFku g&S
following statement(s) is CORRECT? (A) f(x) dk LFkkuh; mfPPk"B x = x0 ij izkIr gksrk g]S tgka
(A) f(x) attains its local maxima at x = x0,
x 0 Î( 0,1)
where x 0 Î( 0,1)
(B) f(x) dk LFkkuh; fuEUkf"B x = –1 ij izkIr gksrk gS
(B) f(x) attains its local minima at x = –1
(C) f(x) dk LFkkuh; fuEUkf"B x = x0 ij izkIr gksrk g]S tgka
(C) f(x) attains its local minima at x = x0,
x 0 Î (1, ¥)
where x 0 Î (1, ¥)
(D) f(x) attains its local minima at x = x0, (D) f(x) dk LFkkuh; fuEUkf"B x = x0 ij izkIr gksrk g]S tgka
17. The number of different AP's whose first 17. fHkUUk lekUrj Jsf.k;ksa dh la[;k ftlds izFke rhu in
cos 2q cos 2q
three terms are cos q, ,cos3q is/are cos q, ,cos3q g]S gksxh&
2 2
(A) 0 (B) 1 (C) 2 (D) 3 (A) 0 (B) 1 (C) 2 (D) 3
18. Let OABC be a parallelogram with 18. ekuk OABC ,d lekUrj prq H kq Z t g S ftles a
uuur uuur uuur uuur
OA = 2iˆ + ˆj - 2kˆ and OC = 4iˆ - 2jˆ - 6kˆ . If P is OA = 2iˆ + ˆj - 2kˆ rFkk OC = 4iˆ - 2jˆ - 6kˆ gSA ;fn
the center of the parallelogram and Q is such P lekUrj prqHkqZt dk dsUnz gS rFkk Q bl izdkj gS fd
uuur uuur uuur uuur uuur
uuur uuur uuur
( )
that PQ ´ OA ´ OC = 0 and PQ = 3 5 then (
PQ ´ OA ´ OC = 0 ) rFkk PQ = 3 5 rc
volume of tetrahedron ABCQ is (cubic units) prq"Qyd ABCQ dk vk;ru gksxk&(?kuh; bdkbZ)
(A) 15 (B) 15 5 (A) 15 (B) 15 5
22112020 SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg Page 35/39
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19. Suppose ' f ' is a real valued function defined 19. ekuk 'f ' ,d okLrfod ekuks okyk Qyu vUrjky [1, ¥)
on [1, ¥) with f(1) = 1 such that ' f ' satisfies ij bl iz d kj ifjHkkf"kr g S fd f(1) = 1 ,oa
1 1
f ¢ ( x) = , then which of the f ¢ ( x) = dks larq"V djrk g]S rc fuEUkfyf[kr
(
x2 + f ( x ) )
2
(
x2 + f ( x ) )
2
p
p (B) f ( x ) < 1 + " x³ 1
(B) f ( x ) < 1 + " x³ 1 4
4
p
p (C) f ( x ) > 1 + "x³1
(C) f ( x ) > 1 + "x³1 4
4
1 + 2b + ab
(B) 1 + 2b + ab
b + ab (B)
b + ab
1+b+a
(C) 1+ b+a
a+b (C)
a+b
1 + b + ab
(D) 1 + b + ab
a + ab (D)
a + ab
+ – + –
+ – + –
0 0 0 0 • 0 0 0 0 0 0 • 0 0
0 0 0 0 • 0 0 0 0 0 0 • 0 0
1 1 1 1 • 1 1 1 1 1 1 • 1 1
1 1 1 1 • 1 1 1 1 1 1 • 1 1
2 2 2 2 • 2 2 2 2 2 2 • 2 2
2 2 2 2 • 2 2 2 2 2 2 • 2 2
3 3 3 3 • 3 3 3 3 3 3 • 3 3
3 3 3 3 • 3 3 3 3 3 3 • 3 3
4 4 4 4 • 4 4 4 4 4 4 • 4 4
4 4 4 4 • 4 4 4 4 4 4 • 4 4
5 5 5 5 • 5 5 5 5 5 5 • 5 5
5 5 5 5 • 5 5 5 5 5 5 • 5 5
6 6 6 6 • 6 6 6 6 6 6 • 6 6
6 6 6 6 • 6 6 6 6 6 6 • 6 6
7 7 7 7 • 7 7 7 7 7 7 • 7 7
7 7 7 7 • 7 7 7 7 7 7 • 7 7
8 8 8 8 • 8 8 8 8 8 8 • 8 8
8 8 8 8 • 8 8 8 8 8 8 • 8 8
9 9 9 9 • 9 9 9 9 9 9 • 9 9
9 9 9 9 • 9 9 9 9 9 9 • 9 9
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1. Let ' f ' be a function from the set of all 1. ekuk fd 'f ' lHkh v½.kkRed iw.kk±dksa ds leqqPPk; ls Lo;a
non-negative integers into itself such that esa ifjHkkf"kr ,d Qyu bl izdkj gS fd
2 2 2 2
(f(2n + 1)) – (f(2n)) = 6f(n) + 1 and f(2n) ³ f(n), (f(2n + 1)) – (f(2n)) = 6f(n) + 1 rFkk f(2n) ³ f(n),
then the value of f(4) – f(3) rc f(4) – f(3) dk eku g&S
2. If Sn =
(
n 2n 2 + 9n + 13 ) (Sn = sum of first n 2. ;fn Sn =
(
n 2n 2 + 9n + 13 ) ( Sn = ,d vuqØe ds
6 6
terms of the sequence) then the value of ¥
1
izFke n inksa dk ;ksxQy g)S ] rc å dk
¥ r =1 r Sr - Sr -1
1
år Sr - Sr -1
r= 1 eku g&S
x 5 - 2x x 5 - 2x
3. ò dx = +c, 3. ò dx = +c]
(5 - 4x - x ) 2 3/2
a 5 - bx - x 2 (5 - 4x - x ) 2 3/2
a 5 - bx - x 2
é1 0 2ù é1 0 2ù
4. Let A = êê 2 0 1 úú , then det((A – I) – 4A) is
3 4. ekuk A = êê 2 0 1 úú , rc det((A – I)3 – 4A) g&S
êë1 1 2úû êë1 1 2úû
5. If m and M respectively denotes the 5. ;fn |2z + 1|, (tgk¡ |z – 2i| £ 1) dk U;wure rFkk
minimum and maximum value of |2z + 1|
vf/kdre ekuk Øe'k% m rFkk M gks] rks (M – m) dk
where |z – 2i| £ 1 then (M – m) equals
eku gksxk