Yashpatil)1001CJA101021230041)

TG~ @bohring_bot
(1001CJA101021230041) Test Pattern
JEE(Main)
CLASSROOM CONTACT PROGRAMME AIOT
(Academic Session : 2023 - 2024) 14-01-2024
JEE(Main
JEE(Main
+ Advanced)
+ Advanced)
: LEADER
: ENTHUSIAST
TEST SERIES /&JOINT
LEADER
PACKAGE
COURSECOURSE
Time : 3 Hours PAPER (OPTIONAL) Maximum Marks : 300
IMPORTANT NOTE : Students having 8 digits Form No. must fill two zero before their Form No. in OMR. For example,
if your Form No. is 12345678, then you have to fill 0012345678.
egRoiw.kZ funZs 'k % ftu fo|kfFkZ;ksa ds QkWeZ uEcj 8 vadksa ds gSa] mUgs OMR esa QkWeZ uEcj ds igys nks 'kwU; Hkjuk gSA tSls fd] ;fn vkidk QkWeZ uEcj
12345678 gS] rks vkidks 0012345678 Hkjuk gSA
READ THE INSTRUCTIONS CAREFULLY/ Ïi;k bu funsZ'kksa dks /;ku ls i<+sa

ds vuqns'kksa ds fcuk eq gjs a u rksM+s

Important Instructions : egRoiw . kZ funs Z ' k :
1. Immediately fill in the form number on this page of the 1. ijh{kk iqfLrdk ds bl i`"B ij vko';d fooj.k uhys@dkys ckWy ikbaV
Test Booklet with Blue/Black Ball Point Pen. Use of pencil
is strictly prohibited.
isu ls rRdky HkjsaA isfUly dk iz;ksx fcYdqy oftZr gSaA
2. The candidates should not write their Form Number 2. ijh{kkFkhZ viuk QkeZ ua - (fu/kkZ f jr txg ds vfrfjä) ijh{kk
anywhere else (except in the specified space) on the Test iqfLrdk@mÙkj i= ij dgha vkSj u fy[ksaA
Booklet/Answer Sheet.
3. The Test Booklet consists of 90 questions. 3. bl ijh{kk iqfLrdk esa 90 iz'u gaA
S

4. There are three parts in the question paper 1,2,3 4. bl ijh{kk iqfLrdk esa rhu Hkkx 1, 2, 3 gSa] ftlds izR;sd Hkkx esa HkkSfrd
consisting of Physics, Chemistry and Mathematics

DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR/fujh{kd

foKku] jlk;u foKku ,oa xf.kr ds 30 iz'u gSa vkSj izR;sd fo"k;
having 30 questions in each subject and each subject
having Two sections.
esa 2 [k.M gSA
(i) Section-I contains 20 multiple choice questions (i) [k.M-I esa 20 cgqfodYih; iz'u gSA ftuds ds oy ,d fodYi
with only one correct option. lgh gSaA
Marking scheme : +4 for correct answer, 0 if not va d ;ks tuk : +4 lgh mÙkj ds fy,] 0 iz;kl ugha djus ij
attempted and 31 in all other cases. rFkk 31 vU; lHkh voLFkkvksa esaA
(ii) Section-II contains 10 Numerical Value Type (ii) [k.M -II es a 10 la [;kRed eku iz d kj ds iz 'u gSA fdUgh 5
questions. Attempt any 5 questions. First 5 iz'uksa dk mÙkj nhft,A fd;s x;s iz'uksa esa ls dsoy izFke ik¡p
attempted questions will be considered for marking. iz'uksa dks gh vad fn;s tk;saxsA
Marking scheme : +4 for correct answer, 0 if not va d ;ks tuk : +4 lgh mÙkj ds fy,] 0 iz;kl ugha djus ij
attempted and 31 in all other cases. rFkk 31 vU; lHkh voLFkkvksa esaA
5. No candidate is allowed to carry any textual material, 5. ijh{kkFkhZ }kjk ijh{kk d{k @ gkWy esa ifjp; i= ds vykok fdlh Hkh izdkj
printed or written, bits of papers, mobile phone any dh ikB~; lkexzh eqfær ;k gLrfyf[kr dkxt dh ifpZ;ks]a eksckby
electronic device etc, except the Identity Card inside the Qksu ;k fdlh Hkh izdkj ds bysDVªkfud midj.kksa ;k fdlh vU; izdkj
examination hall/room. dh lkexzh dks ys tkus ;k mi;ksx djus dh vuqefr ugha gSaA
6. Rough work is to be done on the space provided for this 6. jQ dk;Z ijh{kk iqfLrdk esa dsoy fu/kkZfjr txg ij gh dhft;sA
purpose in the Test Booklet only.
7. On completion of the test, the candidate must hand over 7. ijh{kk lekIr gksus ij] ijh{kkFkhZ d{k@gkWy NksM+ us ls iwoZ mÙkj i= d{k
the Answer Sheet to the invigilator on duty in the Room/ fujh{kd dks vo'; lkSai nsaA ijh{kkFkhZ vius lkFk bl ijh{kk iq fLrdk
Hall. However, the candidate are allowed to take away
dks ys tk ldrs gSaA
this Test Booklet with them.
8. Do not fold or make any stray marks on the Answer Sheet. 8. mÙkj i= dks u eks M+ s a ,oa u gh ml ij vU; fu'kku yxk,s aA
9. Take g = 10 m/s2 unless otherwise stated. 9. g = 10 m/s2 iz; qDr djsa ] tc rd fd vU; dksb Z eku ugha fn;k x;k gks A
Name of the Candidate (in Capitals)
ijh{kkFkhZ dk uke (cM+s v{kjksa esa) :
Form Number : in figures
QkWeZ uEcj : vadksa esa
: in words
: 'kCnksa esa
Centre of Examination (in Capitals) :
ijh{kk dsUæ (cM+s v{kjksa esa) :
Candidate9s Signature : Invigilator9s Signature :
ijh{kkFkhZ ds gLrk{kj : fujh{kd ds gLrk{kj :
Your Target is to secure Good Rank in JEE(Main) 2024
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 Yashpatil TG~ @bohring_bot PART-1 : PHYSICS
SECTION-I : (Maximum Marks: 80)
This section contains 20 questions. Each question has
4 options for correct answer. Multiple-Choice
Questions (MCQs) Only one option is correct. For
each question, marks will be awarded as follows:
Full Marks : +4 If correct answer is selected.
Zero Marks : 0 If none of the option is selected.
Negative Marks : –1 If wrong option is selected.
1. A one dimensional force is acting on a particle of mass
2 kg. The force is given by F = 4 |x| where x is the
x coordinate of the particle. It starts from x = –4 m
with an initial velocity of 5 m/s and reaches x = + 4 m
with velocity of v m/s. What is v?
(A) 5 m/s
(B) 9.5 m/s approx.
(C) 4.5 m/s approx.
(D) 12.4 m/s approx.
2. Two light strings 1.0 m in length are attached to a
vertical support 1.0 m apart, and a mass of 5.0 kg at the
end of the two strings is whirled about the vertical z-axis
(Fig.). Both strings are taut, so that they and the vertical
support form an equilateral triangle. The tension in the
upper string is measured to be 150 N. What is the
tension in the lower string? Take g = 10 m/s2.
(A) 100 N (B) 50 N
(C) 75 N (D) 125 N
Enthusiast & Leader Course / All India Open Test
Page 2/36 Space for Rough Work / 0फ क?/ के @लए जगह
 ! -I : ( @'$/ : 80)
@ ! / 20 A। 0O / @AA  1 O @ल 4 @= + A।
-A@= +A0 (MCQs) O =ल  @= + @AA AP। 0O
O @ल,  @( (?(@B ?1 @& ?O:
+#C  : +4 0@& @AA  1 (B ? 0? AP।
>C 0  : 0 0@& K .A @= + (A (B ? 0? AP।
#? /  : –1 0@& ल$ @= + (B ? 0? AP।
1. @@A 2 kg 0/?( O # +1 @=@/0 -ल ?01$ AP।
-ल ? /?( F = 4 |x| ?1? @&0? ?$? AP, A? x # ?
x-@(&>? AP। 0A x = – 4 m @O ?1@ . =O 5 m/s @O
?1 . AK$? AP $%? x = + 4 m +1 v m/s =O O @?%
+A$? AP। v ? /?( AP :-
(A) 5 m/s
(B) ल. 9.5 m/s
(C) ल. 4.5 m/s
(D) ल. 12.4 m/s
2. 0O 1.0 m ल -? =?लA &K A  1@ @0 K -&@C 1O
@O 1.0 m &1C @ %$  =?'1 @+K @O K]? 0? AP $%? &K(
1@ @0 O @@1O +1  5.0 kg 0/?( K K]1 @O
 =?'1 z- O @?+O @ ?(@B ?1 /B ?0? ?$? AP। &K(
1@ @0? $(A A AP $?@ 0O $%?  =?'1 @+K  @/-?A
@ .B -(?$O AP। +1A 1 @A / $(?= 150 N /?+? 0? AP।
@(लA 1 @A / $(?= 0? AP ? (g = 10 m/s2 ल)
(A) 100 N (B) 50 N
(C) 75 N (D) 125 N
1001CJA101021230041
E + H / 14012024
 3.
Yashpatil TG~ @bohring_bot
Assertion (A) : A ball is dropped from rest. A second
ball is dropped from rest from the same height as the
first, but 1 s later. The distance between the balls
when both are moving remains constant.
Reason (R) : When both the balls are falling freely,
the acceleration of one ball with respect to another is
zero.
(A) Assertion and Reason are True; Reason is a
correct explanation for Assertion.
(B) Assertion and Reason are True; Reason is
not a correct explanation for Assertion.
(C) Assertion is True, Reason is False.
(D) Assertion is False, Reason is True.
4. A yo-yo has mass M and external radius R. The
central stem has negligible mass and a radius r. The
string is pulled horizontally on the lower side with
a constant force F, while the yo-yo rests on a rough
horizontal surface (Fig.). What is the maximum
value of F for which the yo-yo will roll without
slipping assuming that the coefficient of static
friction between the yo-yo and the surface is µ?
3. %( (A) :  & K @=1?/?= %? @O @1?0? ?$? AP।
1 s -?&  @ $A0 & K .A @=1?/?= %? @O @/?(
? @O @1?0? ?$? AP। &K( & O @$>Aल 1A(O O
&L1?( (O / 0 &C1A @(0$ -(A 1A$A AP।
?1# (R) : - &K( &O /B + @O @1 1AA AP $K 
O @?+O &C@1A & ? =1# >C 0 AP।
(A) A $%? R &K( @ 0 AP, +1 $B R, A ? @AA
+ A1# AP।
(B) A $%? R &K( @ 0 AP, +1 $B R, A ? @AA
+ A1# (AA AP।
(C) A @ 0 AP, +1 $B R @ 0 AP।
(D) A @ 0 AP, +1 $B R @ 0 AP।
4.  yo-yo ? 0/?( M = -? @ 0? R AP। @
O A0 (लA ? ( 0 0/?( = @ 0? r AP। @(लA 1
@O 1 @A K P@$ + @O  @(0$ -ल F ?1?  ? ?$?
AP, -@ yo-yo  1B &1A @$A +1 @=1?/?= %? / AP,
@ &O। F O @@ @'$/ /?( O @ल0O yo-yo @-(?
@,@लO ल^B O ? ? yo-yo = @$A O / 0 %P@$ ?#
#B ? µ AP।

r r
(A) μ mg (A) μ mg
R R
μ mg μ mg
(B) 1− r (B) 1− r
R R
μ mg μ mg
(C) 2r (C) 2r
R
−1 R
−1

(D) μ mgR (D) μ mgR

2 2

R 2 − r2 R 2 − r2
Enthusiast & Leader Course / All India Open Test 1001CJA101021230041

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 5.
Yashpatil TG~ @bohring_bot
Jupiter's moon "lo" has a radius of one third of the
earth and mass 5 ×10 –5 that of Jupiter and an
orbital radius about Jupiter that is 6 times Jupiter's
own radius (Fig. ). Given that Jupiter's mass is 300
times that of Earth and that its radius is 30 times
larger than Earth's, calculate the acceleration due
to gravity on "lo" at the point A nearest Jupiter.
5. ज@C पट1 O च /? "lo"  @ 0? पD =A 9O ए @,:? ,-?
0/?0, ज@C पट1 ? 5 ×10 –5 0B ? :P ,-? 9 ज@C पट1 O
9?पO  A0 @ 0? ज@C पट1  =0ं  @ 0?  6 0B A
:P, @च .OO। ज@C पट1 ? 0/?0, पD =A 9O 300 0B ? =
@ 0? 30 0B ? @/ :ो ,ो "lo" प1 ज@C पट1 O 9-9O
0ज.A @ -, @- .B A प1 B =A0 =1+ :ो? :-

(A) 0.02 m/s2 approx (A) ल. 0.02 m/s2

(B) 0.05 m/s2 approx (B) ल. 0.05 m/s2
(C) 0.1 m/s2 approx (C) ल. 0.1 m/s2
(D) 0.25 m/s2 approx (D) ल. 0.25 m/s2
6. A uniform wedge whose cross section is that of 6. ए 9/ प =Oज, @ज9? 0B - ?ट ए 9/-?: @ .जB
an equilateral triangle and weight 30 N is floating O 9/?0 ,-? .?1 30 N :P ,-? 0: जल / @ं > प 9O
in water in a partially submerged position. The
डC-A : @ -@, / ,P1 1:? :P। जल ? 0 = 1000 kg/m3 :P।
density of water is 1000 kg/m3. What is the depth
to which the wedge is submerged in water if the 0@. =Oज  ल -? 1m :ो ,ो जल / =Oज  @,0A :1?
length of wedge is 1m? (approx) (ल.) डC-A : :P ?

(A) 5 cm (B) 7 cm (A) 5 cm (B) 7 cm

(C) 24 cm (D) 2 cm (C) 24 cm (D) 2 cm
Enthusiast & Leader Course / All India Open Test 1001CJA101021230041

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 7.
Yashpatil TG~ @bohring_bot
A piece of tungsten of mass 50 g is placed over a 7. 0/?( 50 g O  ( O  B]O K  +1  ल -O
flame for long time. The metal is then quickly
@/0 $ 1? 0? AP। @ '?$B K - >A $? @O 22°C +1
transferred to a well-insulated aluminum
300 g ल @O .1O  120 g 0/?( O  B?ल
calorimeter of mass 120 g containing 300 g of
water at 22 °C. After some time the temperature  0@B /@(0/ P लK1A/?+A / %?(? $ 1$ @0? ?$? AP। B

of the water reaches a maximum value of 31 °C.
You may use these values of specific heat
capacity : water 4.2 × 103 J kg−1 K−1;
tungsten 1.05 × 102 J kg−1 K−1;
aluminium 9.45 × 102 J kg−1 K−1.
temperature of the flame? (Approx)
@/0 -?& ल ? $?+/?( 31 °C @'$/ /?( $ +A
?$? A। ल  @=@>  /?'? 1$? 4.2 × 103 J kg−1 K−1;
 ( O @ल0O 1.05 × 102 J kg−1 K−1; $%?  0@B /@(0/ O
@ल0O 9.45 × 102 J kg−1 K−1 ल।   लL ?
What is the
$?+/?( (ल.) 0? AK? ?

(A) 2000° C (A) 2000° C

(B) 1700° C (B) 1700° C
(C) 2400° C (C) 2400° C
(D) 900° C (D) 900° C
8. You are trying to construct a compound 8. + ,K@ &C1A 1.0 cm = 4.0 cm =?लO &K ल@ 
microscope given two lenses with focal length
@A?0$? @O  @0B @C /&> -(?(? ?A$O AP। ल@ K
1.0 cm and 4.0 cm. How far apart should you
@$(A &C1A +1 1? ?(? ?@A0O $?@ K#A0
place the lenses in order to obtain an angular
magnification of 60? ='( 60 ? AK ?

(A) 9.6 cm (A) 9.6 cm

(B) 14.6 cm (B) 14.6 cm
(C) 12.3 cm (C) 12.3 cm
(D) 18.2 cm (D) 18.2 cm

Enthusiast & Leader Course / All India Open Test 1001CJA101021230041

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 9.
Yashpatil TG~ @bohring_bot
Match the list-I with lis-II. 9. @C A-I = @C A-II ? @/ल?(  @0O।
List-I List-II @C A-I @C A-II

(P)
Numerical value of maximum power
(in watt) delivered to Rext is
(1) 1 1
(P) (1)
2 2
Rext K &A 0A @'$/ >@ ?
@ 0? / /?( (=?ॅ /) AP।

3 (Q) (2) 3
(Q) (2) 2
Numerical value of potential 2 @- &B A = B O / 0 @=.=? $1 ?
defference (in volt) between point A & @ 0? / /?( (=K  /) AP
B is

(R) (3) 6
(R) (3) 6 $?1 AB ( 0 @$1K' =?ल? AP। AB @O
Wire AB has negligible resistance.
Numerical value of current (in ampere) @($ '?1? (@ +01 /) ? @ 0? /
through AB is /?( AP

(S) (4) 4 (S) (4) 4

  P@O @$1K' K 
Six resistances are arranged in
tetrahedron (shown in solid lines) $B ,ल 0 @= 0?@ (@$$M 1O ? ?1?
configuration. All resistance are equal. &@>$) / 0=@ %$ @0? 0? AP। A =
Numerical value of equivalent B O / 0 $B 0 @$1K' ( Ω /) ?
resistance (in Ω) between A & B is @ 0? / /?( AP।
(A) P → 4; Q → 3; R → 2; S → 1 (A) P → 4; Q → 3; R → 2; S → 1
(B) P → 3; Q → 2; R → 4; S → 1 (B) P → 3; Q → 2; R → 4; S → 1
(C) P → 1; Q → 2; R → 3; S → 4 (C) P → 1; Q → 2; R → 3; S → 4
(D) P → 2; Q → 3; R → 1; S → 4 (D) P → 2; Q → 3; R → 1; S → 4
Enthusiast & Leader Course / All India Open Test 1001CJA101021230041

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 Yashpatil TG~ @bohring_bot
10. An open organ pipe of length 94 cm and radius 5 cm
resonates with a tuning fork of frequency 160 Hz and
320 Hz. If these correspond to fundamental mode
and first overtone respectively, what is the speed of
sound (in m/s)?
(A) 320 (B) 310.4 (C) 300.8 (D) 339.2
11. Charge is distributed throughout a sphere with
the charge density given by ρ = ρ 0 for r < a,
ρ = ρ 0 (r – R)/(a – R) for a < r < R, and ρ = 0
for R < r. Choose the correct graph for the
electric field as a function of r. Use R = 3a.
10. ल -? 94 cm $%? @ 0? 5 cm =?ल?  ल
B ? (
+?+ =D@ 160 Hz $%? 320 Hz =?लO = 1 @O
((B ?@&$ AK$? AP। 0@& 0A /> /ल
C .$C @='? $%? %/
@' =1 O @$ A $K =@(  ?ल (m/s /) AP :-
(A) 320 (B) 310.4 (C) 300.8 (D) 339.2
11. @@A KलO +1 =O> K @= @ ?1 @=$1A$ @0? 0?
AP @ r < a O @ल0O =O> ( = ρ = ρ 0 = a < r < R O
@ल0O ρ = ρ 0 (r – R)/(a – R) = R < r O @ल0O ρ = 0
AP। r O ,ल( O + / @= $B O ? @AA 1O  @B (0O।
R = 3a ल।

(A) (B) (A) (B)

(C) (D) (C) (D)

12. Four charges +Q, – Q, +Q and – Q are placed at a
corners of a square of diagonal length 2L in the same
order. What is the electric potential at a point P which
lies on one of the diagonals of the square at a distance
R from the centre of the square, with R >> L ?
12. @=# ल -? 2L =?लO = O K( +1 ?1 =O> +Q,
– Q, +Q = – Q @/?( / / 1O 0O AP। = O O @O R
&1C A +1 = O @@A  @=# +1 @ %$ @- &B P +1 @= $B
@=.= 0? AK? -@ R >> L AP ?

kQ kQL2 3kQL2 3kQL2 kQ kQL2 3kQL2 3kQL2

(A) (B) (C) (D) (A) (B) (C) (D)
R R3 2R3 R3 R R3 2R3 R3
Enthusiast & Leader Course / All India Open Test 1001CJA101021230041

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 Yashpatil TG~ @bohring_bot
13. For each electromagnet at the left of the drawing, 13.
find whether it will be attracted to or repelled
from the permanent magnet at the right.
(A) The electromagnet in figure (a) will be
attracted to the magnet but the electromagnet
in figure (b) will be repelled by the magnet.
(B) The electromagnet in figure (b) will be
attracted to the magnet but the electromagnet
in figure (a) will be repelled by the magnet.
(C) The electromagnet in figure (a) as well as
(b) will be attracted to the magnet.
(D) The electromagnet in figure (a) as well as
(b) will be repelled by the magnet.
14. The armature of an electric drill motor has a 14.
resistance of 15 Ω . When connected to a 120.0 V
outlet, the motor rotates at its normal speed and
develops a back emf of 108 V. What is the
current when the motor runs at only half speed?
(A) 0.3 A
(B) 4.4 A
(C) 1.2 A
(D) 2.0 A
Enthusiast & Leader Course / All India Open Test
Page 8/36 Space for Rough Work / 0फ क?/ के @लए जगह
@ / -?0A 1 &@>$ 0O @= $B B - O @ल0O ?$
 @0O @ 0A &?0A 1 &@>$ %?0A B - O @ल0O
@?$ AKA 0? @$@?$।
(A) @ (a) / @= $B B -, B -  1 @?$
AKA $%? @ (b) / @= $B B -, B - @O
@$@?$ AKA।
(B) @ (b) / @= $B B -, B -  1 @?$
AKA $%? @ (a) / @= $B B -, B - @O
@$@?$ AKA।
(C) @ (a) $%? (b) / @= $B B -, B -  1
@?$ AKA।
(D) @ (a) $%? (b) / @= $B B -, B - @O
@$@?$ AKA।
@@A @= $B @ ल /K1 O /1 ? @$1K' 15 Ω AP। @O
120.0 V @($ O @?% K](O +1 /K1 +(A @?/? 0 ?ल
+1 #C ( 1$A AP $%? 108 V ? @=1K'A @= $B =?A -ल
 + ( 1$A AP। '?1? ? /?( 0? AK? - /K1 O =ल
'A ?ल @O ल$A AP?
(A) 0.3 A
(B) 4.4 A
(C) 1.2 A
(D) 2.0 A
1001CJA101021230041
E + H / 14012024
 Yashpatil TG~ @bohring_bot
15. A parallel plate capacitor is filled with a dielectric
whose dimensions are the same as that of the
capacitor. The capacitor is connected to a battery.
Statement 1: If the dielectric is pulled out, the
electric field inside the capacitor increases.
Statement 2: The electric field inside the dielectric
is lesser than the electric field in the region
outside the dielectric.
(A) Statement – 1 and Statement – 2 both are True.
(B) Statement – 1 and Statement – 2 both are false.
(C) Statement – 1 is True, Statement – 2 is False.
(D) Statement – 1 is False, Statement – 2 is True.
16. Light is incident on the surface of metallic sodium,
whose work function is 2.3 eV. The maximum
speed of the photoelectrons emitted by the surface is
1.2 × 106 m/s. What is the wavelength of the light?
(A) 570 nm (B) 710 nm
(C) 320 nm (D) 194 nm
17. The thermometers show two readings of the
temperature of a liquid using a Celsius
thermometer. Which of the following is the best
estimate of the change in temperature of the liquid?
15.  @/? $1 + @'? 1 K @O +1?=P $B @O .1? 0? AP
@@? ?1 @'? 1 O @/?( AP। @'? 1 K  -P1A
@O K]? ?$? AP।
%( – 1: 0@& +1?=P $B K -?A1  ? ?0O $K @'? 1 O
&1 @= $B O -^$? AP।
%( – 2: +1?=P $B O &1 @= $B O , +1?=P $B O -?A1
.? / @= /?( @= $B O @O / AP।
(A) %( – 1 $%? %( – 2 &K( @ 0 AP।
(B) %( – 1 $%? %( – 2 &K( @ 0 AP।
(C) %( – 1 @ 0 AP, %( – 2 &K @ 0 AP।
(D) %( – 1 @ 0 AP, %( – 2 &K @ 0 AP।
16. ?0,ल( 2.3 eV =?लO '?@ = @K@!0/  @$A +1
?> +@$$ @0? ?$? AP। @$A ?1?  @@$M ?>
लO ?ॅ(  @'$/ ?ल 1.2 × 106 m/s AP। ?>
 $1&P 0 0? AP ?
(A) 570 nm (B) 710 nm
(C) 320 nm (D) 194 nm
17. @O@ @0@ $?+/?+A O +0K @O  = O $?+/?( O &K
+? M 0? K @ / &>?0? 0? AP। @( ( / @O = O
$?+/?( / + 1=$( ? @=?@' @AA ल( AP :-

(A) 32.0 ± 1°C (A) 32.0 ± 1°C

(B) 32 ± 1°C (B) 32 ± 1°C
(C) 32.0 ± 0.5°C (C) 32.0 ± 0.5°C
(D) 32 ± 0.5°C (D) 32 ± 0.5°C
Enthusiast & Leader Course / All India Open Test 1001CJA101021230041

E + H / 14012024 Space for Rough Work / 0फ क?/ के @लए जगह Page 9/36
 Yashpatil TG~ @bohring_bot
18. The ratio rX
of the radius of an unknown 18. ए ?, 0?@. AX
Z ,-? ए AटA0/ 0?@. 31 T 
rT rX
nucleus AZ X to a tritium nucleus 31 T is rX = 1.10. @ 0? ? 0पB ?,
rT
= 1.10 :P। .ो0 0?@. / 0C ?ॅ0
rT
Both nuclei contain the same number of neutrons.  9/?0 9ं 0? @= /?0 :P। AZ X O प / ?, 0?@.
Identify the unknown nucleus in the form AZ X. ो प:च?@00O।
(A) 42 He (B) 32 He (C) 21 H (D) 53 Li (A) 42 He (B) 32 He (C) 21 H (D) 53 Li
19. Two polarisers whose transmission axes are 19. .ो =B  @0 9ंच1+ ए-.9C 1O O ल -=,् :P, ो
perpendicular to each other are placed so that 9 ?1 1? 0? :P @ 0O प9 / @, 0?@प, :ो,O :P।
they partially overlap. The polarisers in this 9 0= -? / =B  ? उप0ो ए Aल  >?ं, 9,:
arrangement are used to view the calm surface of ो .O0O O @ल0O @0? ?,? :P। @0 0 1O  / ?>
a lake. To explain the light pattern in the diagram @, प ो 9/0O O @ल0O = 0,? :ोA :-
shown below, we need.

(A) Both Brewster’s law and Malu’s law.
(B) Neither Brewster’s law or Malu’s law.
(C) Brewster’s law but not Malu’s law.
(D) Malu’s law but not Brewster’s law.
20. A p-n junction diode operates in first and third
quadrant as shown by dot in the graph below. The
diode can be:
(A) O=O ट1 @00/ = /Oल9 @00/  ।
(B) 0? ,ो O=O ट1 @00/ 0? :A /Oल9 @00/  ।
(C) O=O ट1 @00/  प1 ,B /Oल9 @00/  0: ।
(D) /Oल9 @00/  प1 ,B O=O ट1 @00/  0: ।
20. ए p-n 9ं@/ ड?0ोड .@>, 1O  / @- .B ?1? .@>,
-/ = ,D,A0 च,-B ?> / च?@ल, :ो,? :P। 0: ड?0ोड :ो
9,? :P :-

(A) Photo diode (B) Light emitting diode (A) ?> ड?0ोड (B) ?> उ 9 ड?0ोड
(C) Rectifier (D) Solar cell (C) =/ (D) 9ोल1 9Oल
Enthusiast & Leader Course / All India Open Test 1001CJA101021230041

Page 10/36 Space for Rough Work / 0फ क?/ के @लए जगह E + H / 14012024
 Yashpatil TG~ @bohring_bot
SECTION-II : (Maximum Marks: 20)
This section contains 10 questions Candidates have to
attempt any 5 questions out of 10. If more than 5
questions are attempted, then only first 5 attempted
questions will be evaluated.
The answer to each question is a Numerical Value.
For each question, enter the correct integer value (In
case of non-integer value, the answer should be
rounded off to the nearest Integer).
Answer to each question will be evaluated according to
the following marking scheme:
Full Marks : +4 If correct answer is entered.
Zero Marks : 0 If the question is unanswered.
Negative Marks : –1 If wrong answer is entered.
1. A 30 kg block is resting on a flat horizontal table.
On top of this block is resting a 15 kg block, to
which a horizontal spring is attached, as the
drawing illustrates. The spring constant of the
spring is 325 N/m. The coefficient of kinetic
friction between the lower block and the table is
0.600, and the coefficient of static friction
between the two blocks is 0.900. A horizontal
→
force F is applied to the lower block as shown.
This force is increasing in such a way as to keep
the blocks moving at a constant speed. At the
point where the upper block begins to slip on the
lower block, determine the magnitude of the
force in N. Take g = 10 m/s2.
Enthusiast & Leader Course / All India Open Test
E + H / 14012024 Space for Rough Work / 0फ क?/ के @लए जगह
 !-II : ( @'$/ : 20)
@ ! / 10 A।  /A&=?1 K 10 / @O @@A .A 5 ?
0?@ 1(? AP। 0@& 5 @O @' ? 0?@ @0? ?$? AP, $K
O =ल +AलO 5 ? /C 0?( @0? ??।
0O ?  1 @ 0? / /?( (Numerical Value) AP।
0O O @ल, @AA +#C ? /?( & 1 (&>/ल= @O $( /,
 1 K @($/ +#C ? / @ल? ?(? ?@A। )
0O O  1 ? /C 0?( @( (@ल@$ ( 0K(? O
(@B ?1 @0? ??:
+#C  : +4 0@& @AA  1 & @0? 0? AP।
>C 0  : 0 0@& K .A  1 & (A @0? 0? AP।
#? /  : –1 0@& ल$  1 & @0? 0? AP।
1.  30 kg ल?ॅ K  @/$ल @P $ O-ल +1
@=1?/?= %? / 1? 0? AP। @ ल?ॅ O >A? +1  15 kg
ल?ॅ 1? AP @@@O  @P $ @  @ ?(@B ?1 ]B A A AP।
@  ? @  @(0$? 325 N/m AP। @(लO ल?ॅ = O-ल
O / 0 @$ ?# #B ? 0.600 AP $%? &K( ल?ॅ O
/ 0 %P@$ ?# #B ? ? /?( 0.900 AP। @(लO ल?ॅ
→
+1  @P $ -ल F @ ?(@B ?1 ल?0? ?$? AP। @ -ल K
@ ?1 -^?0? ?$? AP @ ल?ॅ  @(0$ ?ल @O
@$>Aल 1AO। @@ @- &B +1 +1A ल?ॅ, @(लO ल?ॅ +1
@,@ल(? ?1 . 1$? AP, =A? -ल ? + 1/?# (N /) ?$
 @0O। (g = 10 m/s2 ल।)
1001CJA101021230041
Page 11/36
 2.
Yashpatil TG~ @bohring_bot
A small 0.500-kg object moves on a frictionless
horizontal table in a circular path of radius 1.00 m.
The angular speed is 6.28 rad/s. The object is
attached to a string of negligible mass that passes
through a small hole in the table at the center of
the circle. Someone under the table begins to pull
the string downward to make the circle smaller. If
the string will tolerate a tension of no more than
1280 N, what is the radius of the smallest possible
circle (in cm) on which the object can move?
3. A 0.30-m-thick sheet of ice covers a lake. The air
temperature at the ice surface is −15°C. In five
minutes, the ice thickens by a small amount. Assume
that no heat flows from the ground below into the
water and that the added ice is very thin compared to
0.30 m. Find the number of micrometers by which
the ice thickens. Take thermal conductivity of ice as
0.2 W/mK, density of water = 1 gm/cc, density of ice
is 0.9 gm/cc, Latent heat of fusion = 333.33 kJ/kg.
4. Two strings have different lengths and linear
densities, as the drawing shows. They are joined
together and stretched so that the tension in each
string is 216.0 N. The free ends of the joined string
are fixed in place. Find the lowest frequency (in Hz)
that permits standing waves in both strings with a
node at the junction. The standing wave pattern in
each string may have a different number of loops.
Enthusiast & Leader Course / All India Open Test
Page 12/36 Space for Rough Work / 0फ क?/ के @लए जगह
2.  K? 0.500-kg ? @+ ! @@A ?#1@A$ P@$
P -ल +1 1.00 m @ 0? O =D ??1 +% / @$ 1$? AP।
K#A0 ?ल 6.28 rad/s AP। @+ ! K ( 0 0/?(
=?लA  1 @A @O K]? ?$? AP, K =D O O +1 O -ल
/ -(O  KO @ @O AK1 B1$A AP। O -ल O (AO
@ %$ K 0@ =D K K? -(?(O O @ल0O @ 1 @A K
(AO  1  $? AP। 0@& 0A 1 @A 1280 N @O
@' ? $(?= (A =A( 1 @$A AP $K @+ ! @@
0C($/ @.?@=$ @ 0? (cm /) O =D +1 @$ 1
@$? AP ?
3.  0.30-m /KA -,  >A @@A Aल K "$A AP।
-,  @$A +1 =?0B $?+/?( −15°C AP। +? @/( /
-,  + /? ? / /K? -^$A AP। /?(? '1?$ल @O
ल O &1  /?  K /? ? =?@A$ (A AK$A AP
$%? B](O =?लA -, 0.30 m  $Bल(? / 0 $
+$लA AP। -,  /K? / =D@ /? K/A1 / ?$
 @0O। -,   /A0 ?ल$?. 0.2 W/mK, ल ?
( = = 1 gm/cc, -, ? ( = 0.9 gm/cc =
@ल(  B  /? = 333.33 kJ/kg ल।
4. @ / ल- ल ल -? = 1P @ ( =  &K 1@ @0?
&>?0A 0A AP।  A @?% K]1 @ ?1 $@($ @0?
?$? AP @ 0O 1 @A / $(?= ? /?( 216.0 N AP। ]B A
A 1 @A O /B @@1 K @@A %?( +1 @ %1 1 @&0? 0?
AP। =A 0(C $/ =D@ (Hz /) ?$  @0O @@O ?1#
&K( 1@ @0 / ?/A $1 -(O $%?  @( + & @@' +1
A । 0O 1 @A / ?/A $1 @$ + / ल+C  @=@. (
@ 0? AK @$A AP।
1001CJA101021230041
E + H / 14012024
 5.
Yashpatil TG~ @bohring_bot
A particle of mass m = 2 kg is moving at 5 m/s
in a given direction and is struck by an impulsive
force F that deflects its direction of motion
through 60 ◦ and doubles the magnitude of its
velocity. The same impulsive force F is applied
to a mass of 5m at rest. What is the resulting
kinetic energy of mass 5m (in J)?
6. For the circuit shown in the drawing, find the
current 'I' (in A) through the 2.00 Ω resistor.
7. In a circuit consisting of a battery and a
resistor R = 20 ohms, we connect a voltmeter
first in series, then in parallel with the resistor.
The reading of the voltmeter is the same in
both the cases. The resistance of the voltmeter
is RV = 500 ohms. Determine the internal
resistance r of the battery. Write 10r (in ohms).
8. A concave mirror produces magnified and inverted
image of size 4 times the object. Find the modulus of
the focal length of the mirror (in cm) if the distance
between object and its image is equal to 90 cm.
Enthusiast & Leader Course / All India Open Test
E + H / 14012024 Space for Rough Work / 0फ क?/ के @लए जगह
5. 0/?( m = 2 kg ?  # &A 0A @&>? / 5m/s @O
@$>Aल AP $%? @O =OA0 -ल F @&0? ?$? AP K @$
 @&>? K 60◦ @O @=@ल$ 1 &O$? AP $%? @O =O ?
+ 1/?# &B (B ? 1 &O$? AP। =AA =OA0 -ल F @=1?/ /
@ %$  5m 0/?( +1 ल?0? ?$? AP। 0/?(
5m  + 1#?/A @$ ? (J /) ?$  @0O।
6. &@>$M + 1+% O @ल0O 2.00 Ω @$1K' @O =?@A$
'?1? 'I' (A /) ?$  @0O।
7.  -P1A $%? @$1K' R = 20 ohms @O -(O  + 1+%
/  =K /A1 K +AलO @$1K' O O#A / / $%?
@,1 @/? $1 / / K]? ?$? AP। =K /A1 ?
+? M 0? &K( @ %@$0 / @/?( AP। =K /A1 ?
@$1K' RV = 500 / AP। -P1A ? $ 1 @$1K' r
?$  @0O। 10r ? /?( (ohms /) AK?।
8.  =$ल &+# @- - O ?1 ? 4 (B ? =@'$ =
 ? @$@- - -(?$? AP। 0@& @- - = @O @$@- - O
/ 0 &1C A 90 cm AK $K &+#  ,K@ &1C A ? + 1/?#
(cm /) ?$  @0O।
1001CJA101021230041
Page 13/36
 9.
Yashpatil TG~ @bohring_bot
In an electric circuit in series with a source of 9.  @= B$ + 1+% / @= B$ =?A -ल ɛ0 O ?O$ O
emf ɛ0 , resistor R0 and inductor L = 1 H (Fig), if O#A / /  @$1K' R0 = O1 B !लA L = 1 H
resistance R0 = 1.0 Ohm the current in the circuit B]O A AP, P@? @ @ / &>?0? 0? AP। 0@&
would I0 = 1 A. From a certain moment the @$1K' R0 = 1.0 Ohm AK $K + 1+% / '?1? I0 = 1A
resistance of the rheostat was changed so that the AKA।  @(@ $ # +1 @O '?1? @(0$? ? @$1K' @
current decreases with time according to the law ?1 + 1=@$$ @0? ?$? AP @ '?1? @/0 O @?%
t t
I = I0 ( 1 − ), where τ = 0.5 sec. Determine I = I0 ( 1 − ) O (B@?1 + 1=@$$M AK$A AP, A?
τ τ
τ
the resistance (in ohm) of the circuit after time τ = 0.5 sec AP। '?1? + 1=$( O ?1 . AK(O O t=
2
τ
t= after the beginning of the current change. @/0 +'pk$ + 1+% ? @$1K' (/ /) ?$  @0O।
2

10. The minimum energy of an electron necessary for
ionization of atom of hydrogen, is equal to W0.
Suppose that a hydrogen atom and helium atom
both in ground state collide inelastically so that
hydrogen atom is ionized. If the hydrogen was at
rest and helium was moving with at least energy
of xW0, find the value of x.
10. A? K( +1/?#B O 0(( O @ल0O @@A लO ?ॅ( 
= 0 0(C $/ ? W0 AP। /?( /ल
C = %? / @ %$
 A? K( +1/?#B = AA@ल0/ +1/?#B &K( 0? %
+ @O 1?$O A $?@ A? K( +1/?#B 0@($ AK ?0O।
0@& A? K( @=1?/ / %? $%? AA@ल0/ xW0  0(C $/
? O @?% @$>Aल %? $K x ? /?( ?$  @0O।

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Page 14/36 Space for Rough Work / 0फ क?/ के @लए जगह E + H / 14012024
 Yashpatil TG~ @bohring_bot PART-2 : CHEMISTRY

SECTION-I : (Maximum Marks: 80)  !-I : ( @'$/ : 80)

This section contains 20 questions. Each question has @ ! / 20 A। 0O / @AA  1 O @ल 4 @= + A।
4 options for correct answer. Multiple-Choice -A@= +A0 (MCQs) O =ल  @= + @AA AP। 0O
Questions (MCQs) Only one option is correct. For O @ल,  @( (?(@B ?1 @& ?O:
each question, marks will be awarded as follows: +#C  : +4 0@& @AA  1 (B ? 0? AP।
Full Marks : +4 If correct answer is selected. >C 0  : 0 0@& K .A @= + (A (B ? 0? AP।
Zero Marks : 0 If none of the option is selected. #? /  : –1 0@& ल$ @= + (B ? 0? AP।
Negative Marks : –1 If wrong option is selected.
1. What will be the pH of 1% (w/w) aqueous 1. ल=# NaA O 1% (w/w) @ल0 @=ल0(  pH 0? AKA?
solution of salt NaA ? [Given: Ka(HA) = 10 –6 , @&0? AP : Ka(HA) = 10 –6 ,
density of solution = 1.2 gm/ml, @=ल0( ? ( = = 1.2 gm/ml
Molecular mass of HA = 98, HA ? @ = 0/?( = 98,
Atomic mass of Na = 23]. Na ? +1/?@ =0 0/?( = 23.
(A) 4.5 (B) 9 (A) 4.5 (B) 9
(C) 10.5 (D) 9.5 (C) 10.5 (D) 9.5
2. Consider following solutions in given solvents : 2. @&0O 0O @=ल?0K /O @( ( @=ल0(K +1 @=?1  @0O :
I : 0.3 M aqueous glucose solution I : 0.3 M लA0 ल C K@ @=ल0(
II : 0.2 M aqueous sodium chloride solution
II : 0.2 M लA0 @K@!0/ लK1?! @=ल0(
III : 0.3 M aqueous ammonium phosphate solution
IV : 0.4 M benzoic acid in benzene (dimerises III : 0.3 M लA0 /K@(0/ ,?ॅ ,O  @=ल0(
upto 50%) IV : -A( /O 0.4 M -K ल (50% $ @ ल D $
Select incorrect statement from given options for AK ?$? AP)
the above given solutions : +1K @&0O 0O @=ल0(K O @ल0O ल$ %( @B (0O :
(A) I and IV are isotonic solutions. (A) I $%? IV @/+1?@1A @=ल0( AP।
(B) III is hypertonic as compared with each of I, (B) I, II $%? IV  $ल
B (? /O III @$+1?@1A AP।
II and IV.
(C) IV is hypotonic as compared with each of I, (C) I, II, III  $ल
B (? /O IV ++1?@1A AP।
II and III.
(D) II is hypotonic as compared with III but (D) III  $ल B (? /O II +1?@1A AP लO@( I, IV 
hypertonic as compared with I and IV. $लB (? /O @$+1?@1A AP।

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E + H / 14012024 Space for Rough Work / 0फ क?/ के @लए जगह Page 15/36
 3.
Yashpatil TG~ @bohring_bot
Assertion : Although the shapes of 2s and 2p 3.
orbitals are different, an electron has the same
energy when it is in the 2s orbital as when it is
present in 2p orbital for all single electron species.
Reason : The energy of an electron in a hydrogen
atom is determined solely by the principal
quantum number.
(A) Assertion is false but Reason is true.
(B) Assertion is true but Reason is false.
(C) Both Assertion and Reason are true and
Reason is the correct explanation of Assertion.
(D) Both Assertion and Reason are true and Reason
is NOT the correct explanation of Assertion.
4. Which of the following set of elements have most 4.
negative electron gain enthalpy in their respective
groups.
(A) (S , Na , F)
(B) (S , Cl , Ne)
(C) (S , Sb , Cl)
(D) (F , P , Se)
5. E° (SRP) of different half cells are given 5.
2+ /Cu = 0.34 volt ; EZn2+ /Zn = – 0.76 volt
o
ECu o o
%( : @.A ल लO ?ॅ ( +A>A O @ल0O A?ल? @
2s $%? 2p    D @$0? @. ( – @. ( AK$A AP
@,1 .A ( &K(   2s $%? 2p / +@ %$
लO ?ॅ (  ? @/?( AK$A AP
?1# : A? K( +1/?#B /  लO ?ॅ (  ?
K O =ल /B 0 =? / @ 0? ?1? @('? 1$ @0?
?$? AP
(A) %( ल$ AP लO@( ?1# @AA AP
(B) %( @AA AP लO@( ?1# ल$ AP
(C) %( $%? ?1# &K( @AA AP $%? ?1#, %( ?
@AA + A1# AP
(D) %( $%? ?1# &K( @AA AP $%? ?1#, %( ?
@AA + A1# (A AP
@( ( / @O L( @O @/B 0 O $ =  लO ?ॅ( A#
 %P +A (O @ -@'$ =? / @=?@' #? / AK$A
AP
(A) (S , Na , F)
(B) (S , Cl , Ne)
(C) (S , Sb , Cl)
(D) (F , P , Se)
@=@. ( @OलK  E° (SRP) @&0O 0O AP
2+ /Cu = 0.34 volt ; EZn2+ /Zn = – 0.76 volt
ECu o

+ /Ag = 0.8 volt ; EMg 2+ /Mg = – 2.37 volt + /Ag = 0.8 volt ; EMg 2+ /Mg = – 2.37 volt
o
EAg o o
EAg o

In which cell among the following Δ G° per mole
of electron is most negative : -
(A) Zn (s) | Zn2+ (1 M) || Mg2+ (1 M) | Mg (s)
(B) Zn (s) | Zn2+ (1 M) || Ag+ (1 M) | Ag (s)
(C) Cu (s) | Cu2+ (1 M) || Ag+ (1 M) | Ag (s)
(D) Ag (s) | Ag+ (1 M) || Mg2+ (1 M) | Mg (s)
L(@O @Pल /O  /Kल लO ?ॅ( O @ल0O Δ G° ? /?(
@=?@' #? / AP : -
(A) Zn (s) | Zn2+ (1 M) || Mg2+ (1 M) | Mg (s)
(B) Zn (s) | Zn2+ (1 M) || Ag+ (1 M) | Ag (s)
(C) Cu (s) | Cu2+ (1 M) || Ag+ (1 M) | Ag (s)
(D) Ag (s) | Ag+ (1 M) || Mg2+ (1 M) | Mg (s)

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 6.
Yashpatil TG~ @bohring_bot
The conductivity of saturated solution of 6. Ba3(PO4)2 O @$D @=ल0(  ?ल$?
Ba3(PO4)2 is 1.2 × 10 –5 Ω –1 cm –1. The limiting 1.2 × 10 –5 Ω –1 cm –1 AP। BaCl2, K3PO4 $%? KCl
equivalent conductivities of BaCl2, K3PO4 and KCl  @A/?$ $B 0? ?ल$? /> 160, 140 $%?
are 160, 140 and 100 Ω –1 cm2 eq –1, respectively. 100 Ω –1 cm2 eq –1 AP $K Ba3(PO4)2 ? @=लO0$?
The solubility product of Ba3(PO4)2 is : #B (,ल AP :
(A) 1 × 10 –5 (A) 1 × 10 –5
(B) 1.08 × 10 –23 (B) 1.08 × 10 –23
(C) 1.08 × 10 –25 (C) 1.08 × 10 –25
(D) 1.08 × 10 –27 (D) 1.08 × 10 –27
7. In a nitration experiment, 10.0g of benzene gave 7. (? A1# 0K / 10.0g -A(, 13.2 g
13.2 g of nitrobenzene. The percentage yield for (? K-A( &O$A AP $K -A( O (? A1# O @ल0O @$>$
nitration of benzene is : ल@ ' AP :
(A) 83.7% (A) 83.7%
(B) 62.5% (B) 62.5%
(C) 98.2% (C) 98.2%
(D) 26.6% (D) 26.6%
8. For the following spontaneous process 8. 1 atm $%? 268 K +1 @( ( =$ /
H2O( ℓ ) → H2O(s) at 1 atm and 268 K, which of
H2O( ℓ ) → H2O(s) O @ल0O L(@O @= + @AA AP?
the following option is true ?
[Given : Δ Ssys = Entropy change of system and [@&0? AP : Δ Ssys = $   K+A + 1=$( $%?
Δ Ssurr = Entropy change of surrounding during the
Δ Ssurr = / O &L1?( + 1=O>   K+A + 1=$(]
process]
(A) Δ Ssurr > 0 (A) Δ Ssurr > 0
(B) Δ Ssys > 0 (B) Δ Ssys > 0
(C) Δ Ssurr < 0 (C) Δ Ssurr < 0
(D) Δ Ssys = – Δ Ssurr (D) Δ Ssys = – Δ Ssurr
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 9.
Yashpatil TG~ @bohring_bot
For the hypothetical reaction involving three ideal 9. ? +@( @.@ 0? @@/ $A( &> P@ @@ /@ल$ A
gases as given below : A2(g) + B2(g) ⇌ 2AB(g) O @ल0O
A2(g) + B2(g) ⇌ 2AB(g)
&A  @.@ 0? O @ल0O 200 K +1 Δ rG° $%? Δ rS°
Δ rG° and Δ rS° are 20 kJ/mol and – 20 JK –1 mol –1
/> 20 kJ/mol $%? – 20 JK –1 mol –1 AP।
respectively at 200 K. For the given reaction
Δ r CP is 20 JK –1 mol –1 then calculate Δ rH° for Δ r CP , 20 JK –1 mol –1 AP $K &A  @.@ 0? O @ल0O
the given reaction at 400 K : 400 K +1 Δ rH° AP :
(A) 20 kJ/mol (A) 20 kJ/mol
(B) 7.98 kJ/mol (B) 7.98 kJ/mol
(C) 28 kJ/mol (C) 28 kJ/mol
(D) 18 kJ/mol (D) 18 kJ/mol
10. Which of the following statement is incorrect? 10. @( ( / @O L(@? %( ल$ AP?
(A) Only oxidizing acids (nitric and hot (A) O =ल  @A?1 ल ((?@  $%? / @?@ $
concentrated sulphuric) react with Cu @ 0B 1) Cu O @?% @ 0? 1$O A।
(B) The high energy to transform Cu(s) to (B) Cu(s) O Cu2+(g) / +?$ 1$ 1(O / @ल0O  
Cu2+(g) is balanced by its hydration enthalpy ? @ ल0K(  %P +A ?1? @$@B ल$ AK$A AP
(C) Both, the observed as well as calculated (C) 0 3d- O#A O $ =  $ल
B (?  $ल
B (? / Cu O
2+ /M values for Cu are highest as compared
EMo
@ल0O O@ $ O @?% – @?% + 1@ल$ EMo 2+/M &K(
to other 3d-series elements. /?( @'$/ AK$O A
(D) Among all 3d series elements, only Zn has (D) @ +#C 3d O#A O $ =? / O =ल Zn  3rd IE ?
more 3rd IE value than 3rd IE of Cu /?(, Cu  3rd IE  $लB (? / @' AP
11. Which of the following actinoid elements 11. @( ( / @O L(@O @ (K! $ = O "6d" +O ?> / K
contains no electron in "6d" subshell. लO ?ॅ( +@ %$ (A AP
(A) Americium (Am = 95) (A) /O 1@@0/ (Am = 95)
(B) Curium (Cm = 96) (B) 0C 10/ (Cm = 96)
(C) Lawrencium (Lr = 103) (C) ल?1O (@A0/ (Lr = 103)
(D) Protactinium (Pa = 91) (D) KO A@(0/ (Pa = 91)

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 Yashpatil TG~ @bohring_bot
12. Treatment of D-glucose with aqueous NaOH 12. D- लB K@ K लA0 NaOH O @?% +? 1$ 1(O O
results in a mixture of monosaccharides, which are + 1#?/ = + /K(K@OO1?! ? @/ # ? AK$? AP, K AP

(A) , and (A) , $%?

(B) , and (B) , $%?

(C) , and (C) , $%?

(D) , $%?
(D) , and

13. 13.

X, Y and Z will be :
X, Y $%? Z /> A O :
(A) CH2 = CH2 , CH3 – CH3, CH3CH2 – I (A) CH2 = CH2 , CH3 – CH3, CH3CH2 – I
(B) CH3 – CH2 – I, CH3 – CH3 , CH2 = CH2 (B) CH3 – CH2 – I, CH3 – CH3 , CH2 = CH2
(C) CH3 – CH2 – I, , CH2 = CH2 (C) CH3 – CH2 – I, , CH2 = CH2

(D) CH3 – CH2 – I, CH2 = CH2, (D) CH3 – CH2 – I, CH2 = CH2,

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 Yashpatil TG~ @bohring_bot
14. Which of the following complex show stereo 14. @( ( / @O L(@? @Bल, @ @=/ @/?=0=$? &@>$ 1$?
isomerism. AP
(I) [Ni(en)3]Cl2 (I) [Ni(en)3]Cl2
(II) [CoCl2(en)2]Cl (II) [CoCl2(en)2]Cl
(III) [NiCl2(Ph3P)2] (III) [NiCl2(Ph3P)2]
(IV) [Co(H2O)3F3] (IV) [Co(H2O)3F3]
(A) II & IV only (B) I, II, III, & IV (A) O =ल II $%? IV (B) I, II, III, $%? IV
(C) I, II & III only (D) I, II & IV only (C) O =ल I, II $%? III (D) O =ल I, II $%? IV
15. Considering 2s-2p mixing to be non-operative, which 15. /?( @ 2s-2p @/ल?( (?ॅ( +1O @= AP $K @( ( / @O
of the following specie(s) can undergo a transition L(@A +A>A ? HOMO (@1O !) @O LUMO
from HOMO (gerade) to LUMO (ungerade). ( (@1O !) / @ /# (transition) AK @$? AP
(A) N2 (B) C2 (A) N2 (B) C2
(C) Li2Θ (D) B2 (C) Li2Θ (D) B2
16. The compound A in the following reaction is : 16. @( ( @.@ 0? / 0L@ A AP :
A −−−−−−−−−−−−−
i CH MgBr H O
() 3

(ii) Conc. H SO / Δ
→ B −−−−−−−−→ C + D
/ 2 ( i) O 3

(ii) Zn/H2 O
A −−−−−−−−−−−−−
i CH MgBr H O
() 3

(ii) Conc. H SO / Δ
→ B −−−−−−−−→ C + D
/ 2 ( i) O 3

(ii) Zn/H2 O
2 4 2 4

Ba(OH ) Ba(OH )
D −−−−−−2→ D −−−−−−2→

(A) (A)

(B) (B)

(C) (C)

(D) (D)
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 Yashpatil TG~ @bohring_bot
17. Which set of reagent (in the correct order) would 17. @./ ? L(@? @/B 0 (@AA / /) @( ( + 1=$(
accomplish the following transformation ? K +1C ? 1O ??

−−→
I
−−II→ −−→
I
−−II→

(A) BH3 – THF; H2O2/NaOH H2SO4 (A) BH3 – THF; H2O2/NaOH H2SO4

(B) KOH/THF; CH3I H2/Pd/C (B) KOH/THF; CH3I H2/Pd/C

(C) H2/Lindlar catalyst NaNH2/THF; CH3I (C) H2/Lindlar catalyst NaNH2/THF; CH3I
(D) NaNH2/NH3( ℓ ); CH3I H2/Lindlar catalyst (D) NaNH2/NH3( ℓ ); CH3I H2/Lindlar catalyst

H O Δ H O Δ
18. −− −−−→ (P) −−−−−−−−
Sn HCl
/ NaNO HCl
→ (Q) −−−−−→ (R)
o
2/ 2 /
18. −− −−−→ (P) −−−−−−−−
Sn HCl
/ NaNO HCl

0 Co
→ (Q) −−−−−→ (R)
2/ 2 /

0 C

−−−−−−−−−−−
1 CHCl KOH
( ) 3/
→ (S) −−−−−−−−−−−
1 CHCl KOH
( ) 3/

(2) HCl (dil.)

→ (S)
(2) HCl (dil.)

Compound (S) is : 0L@ (S) AP :

(A) (B) (A) (B)

(C) (D) (C) (D)

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 Yashpatil TG~ @bohring_bot
19. List-I (Compound) List-II (Test) 19. @C A-I (0L@) @C A-II (+1A #)
(1) +ve 0K!K,?/
(P) (1) +ve Iodoform test (P)
+1A #

(2) +ve 0@K@?0(?!

(Q) (2) +ve Isocynide test (Q)
+1A #

(3) +ve Liebermann (3) +ve @ल-1/?(

(R) (R)
nitroso test (? K@K +1A #

(S) (4) +ve ?ॅलO @

(4) +ve Tollen's test (S)
+1A #

(A) P→1, Q→3, R→2, S→4

(A) P→1, Q→3, R→2, S→4 (B) P→4, Q→2, R→3, S→1
(B) P→4, Q→2, R→3, S→1 (C) P→1, Q→2, R→3, S→4
(C) P→1, Q→2, R→3, S→4 (D) P→4, Q→3, R→2, S→1
(D) P→4, Q→3, R→2, S→1
20. Which of the following reaction yields a coloured 20. @( ( / @O L(@A @.@ 0? 1A( P@ &O$A AP
gas.
1500o C 1500o C
(A) C + P 2 O5
(coke)
−−−−→ (A) C + P 2 O5
(coke)
−−−−→
(B) 4HCl + O2 −− −−→
CuCl

723 K
2
(B) 4HCl + O2 −− −−→
CuCl 2

723 K

(C) (C)
(D) H2O + HCN → (D) H2O + HCN →

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 Yashpatil TG~ @bohring_bot
SECTION-II : (Maximum Marks: 20)  !-II : ( @'$/ : 20)
This section contains 10 questions Candidates have to @ ! / 10 A।  /A&=?1 K 10 / @O @@A .A 5 ?
attempt any 5 questions out of 10. If more than 5 0?@ 1(? AP। 0@& 5 @O @' ? 0?@ @0? ?$? AP, $K
questions are attempted, then only first 5 attempted O =ल +AलO 5 ? /C 0?( @0? ??।
questions will be evaluated. 0O ?  1 @ 0? / /?( (Numerical Value) AP।
The answer to each question is a Numerical Value. 0O O @ल, @AA +#C ? /?( & 1 (&>/ल= @O $( /,
For each question, enter the correct integer value (In  1 K @($/ +#C ? / @ल? ?(? ?@A। )
case of non-integer value, the answer should be 0O O  1 ? /C 0?( @( (@ल@$ ( 0K(? O
rounded off to the nearest Integer). (@B ?1 @0? ??:
Answer to each question will be evaluated according to +#C  : +4 0@& @AA  1 & @0? 0? AP।
the following marking scheme: >C 0  : 0 0@& K .A  1 & (A @0? 0? AP।
Full Marks : +4 If correct answer is entered. #? /  : –1 0@& ल$  1 & @0? 0? AP।
Zero Marks : 0 If the question is unanswered.
Negative Marks : –1 If wrong answer is entered.
1. Consider the reaction given below which is use 1. (AO &A 0A @.@ 0? +1 @=?1  @0O K @ #B ? /
for the detection of phosphates in inorganic salt @='ys?# / ,? ,O  0(  +A?( O @ल +0K 
by using a Molybdenum compound "A". ?$A AP $%? @/ /?ॅलA !O(/ ?  ल=# A +0K
@0? ?$? AP
Na2HPO4 + "A" + HNO3 → B +
(Canary yellow ppt.) Na2HPO4 + "A" + HNO3 → B +
(Canary yellow ppt.)
"C" + "D" + "E"
"C" + "D" + "E"
Find the number of oxygen atoms in (B) Canary O (O1A +Aल? = O+ (B) /  @A( +1/?#
B  Bल
yellow ppt. @ 0? -$?0O
2. B2 H6(g) + 6Cl2(g) → 2BCl3 + 6HCl(g) ; 2. B2 H6(g) + 6Cl2(g) → 2BCl3 + 6HCl(g) ;
Δ r H = −1326kJ ...(i) Δ r H = −1326kJ ...(i)
BCl3(g) + 3H2 O( ℓ ) → H3 BO3(g) + 3HCl(g) ; BCl3(g) + 3H2 O( ℓ ) → H3 BO3(g) + 3HCl(g) ;
Δ r H = −112.5 kJ ...(ii) Δ r H = −112.5 kJ ...(ii)
B2 H6(g) + 6H2 O(l) → 2H3 BO3(s) + 6H2(g) ; B2 H6(g) + 6H2 O(l) → 2H3 BO3(s) + 6H2(g) ;
Δ H = −493.4 kj ...(iii) Δ H = −493.4 kj ...(iii)
1 1 1 1
H2(g) + Cl2(g) → HCl(g) ; Δ H = −92.3 kJ ...(iv) H2(g) + Cl2(g) → HCl(g) ; Δ H = −92.3 kJ
...(iv)
2 2 2 2
Using the above given thermochemical data at 300 K +1 +1K @&0O 0O  /?1?@?0@( ] ?
300 K, calculate molar enthalpy of sublimation of 0K 1$O A0O 300 K +1 H3BO3 O  =+?$(  /Kल1
H3BO3 at 300 K (in kJ/mole).  %P +A (kJ/mole /)  #(?  @0O
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 3.
Yashpatil TG~ @bohring_bot
When the following skeleton equation is 3. - @( ( @/A1# K @@ /@ल$ +A>A O 0(C $/
balanced with smallest whole number
1@@/A1#@/@$ #B ? ?1? @$@B ल$ @0? ?$? AP $K
stoichiometric co-efficients of species involved,
A? K @?! 0(K $%? 0K!?! 0(K O
what is the sum of stoichiometric co-efficients of
1@@/A1#@/$A0 #B ?K ? 0K 0? AP?
hydroxide ions and iodide ions,
basic
basic
I − (aq) + MnO−4 (aq) −−−−−→ IO− (aq) + MnO2 (s) I − (aq) + MnO−4 (aq) −−−−−→ IO− (aq) + MnO2 (s)
medium medium

4. Wavelength of electron waves in two Bohr orbits is 4. &K -KA1  ? / ( लO ?ॅ( $1  $1 &P 0 3 : 5
in ratio 3 : 5. The ratio of kinetic energy of electron O (+B ?$ / AP $K @/?(  ? / लO ?ॅ(  @$

in these same orbits is 25 : x, hence x is ......... . ? ? (+B ?$ 25 : x AP $K x AP ......... .

5. Number of dibasic oxo-acids that contain bond 5. @( ( / @O @O @ ?1A0  @K ल  @ 0? -$?0O

between two identical atoms ("X"-"X") @(/ &K @/?( +1/?#
B O / 0 -'( +@ %$ AK ("X-X")
H2S2O8 , H4P2O5 , H5P3O10 , H2S4O6 , H4P2O8 , H2S2O8 , H4P2O5 , H5P3O10 , H2S4O6 , H4P2O8 ,
H2N2O2 H2N2O2

6. In the hofmann bromoamide degradation & 6. A?ॅ,/?( K/K/?! @( (A1# $%? K/K,?/ @.@ 0?

bromoform reaction, the minimum number of moles /  +?@&$ @$ /Kल /A( $%? @$/Kल K/K,?/ O @ल0O

of Br2 & NaOH required for per mole of amine & = 0 Br2 $%? NaOH O /Kल  0(C $/ @ 0?

per mole of bromoform produced is (P, Q) & (P', Q') /> (P, Q) $%? (P', Q') AP $K ? /?(

respectively. Then the value of is : AP :

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 7.
Yashpatil TG~ @bohring_bot
How many reaction correctly matched with their 7. @$(A @.@ 0? (O /B 0  +?& O @?% @AA + @O

major product : @/B O@ल$ AP :

Θ
Θ OH
→
OH
→ (i) −−

(i) −−

(ii)
(ii)

(iii)
(iii)

(iv) CH3 – CHO CH3 – CH=CH – CHO

(iv) CH3 – CHO CH3 – CH=CH – CHO

(v)
(v)

(vi)
(vi)

(vii)
(vii)

(viii) Cl3C – CHO Cl3C – CH2OH +

(viii) Cl3C – CHO Cl3C – CH2OH +
Cl3C – COONa
Cl3C – COONa
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 Yashpatil TG~ @bohring_bot
8. 8.

Mono - brominated product(s) /K(K- K/A(AD $  +?&

Find number of fraction obtained after fractional /K(K K/A(AD $  +?& O .?=A @=( O +'pk$ ?
distillation of mono-brominated products .?  @ 0? -?$0O
9. Identify total number of compounds which are 9. @( ( / @O @O 0L@  @ 0? -$?0O K लA0 NaOH
soluble in aq-NaOH and aq-NaHCO3 both : $%? aq-NaHCO3 &K( / @=लO0>Aल AP :

, , , ,

, , , ,

, HCl, , , HCl, ,

, ,

10. Number of 'd'-block halides that do not exist or 10. @( ( / @O @O 'd'- ल?ॅ AOल?!  @ 0? -$?0O K
are highly unstable @ $ = (A 1$O A 0? 0@' %?0A AP
FeI3 , MnCl3 , TiF2 , VI4 , NiCl2 , CrBr3 , MnI4 FeI3 , MnCl3 , TiF2 , VI4 , NiCl2 , CrBr3 , MnI4

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 Yashpatil TG~ @bohring_bot PART-3 : MATHEMATICS

SECTION-I : (Maximum Marks: 80)  ड-I : (अ@/,/ अं: 80)

This section contains 20 questions. Each question has 9 ंड / 20 :। 0O / 9:A  1 O @लए 4 @= + :।
4 options for correct answer. Multiple-Choice -:@= +A0 (MCQs) O =ल ए @= + 9:A :P। 0O
Questions (MCQs) Only one option is correct. For O @लए, अं @0 0?09B ?1 @.ए ज?एंO:
each question, marks will be awarded as follows: ++C अं : +4 0@. 9:A  1 च0B ? 0? :P।
Full Marks : +4 If correct answer is selected. > C 0 अ ं : 0 0@. ो .A @= + 0: च0B ? 0? :P।
Zero Marks : 0 If none of the option is selected. ऋ+? / अं : –1 0@. ल, @= + च0B ? 0? :P।
Negative Marks : –1 If wrong option is selected.
1. Suppose ABC is a triangle such that ∠ BAC is a 1. /?0? @ .जB ABC 9 ?1 :P @ ∠ BAC 9/ो+ :P।
right angle. A point H is located at BC such that
ए @- .B H, BC +1 9 ?1 :P @ AH, BC O ल -=,्
AH is perpendicular to BC. If ∠ ABC = θ , AB = a,
AC + AH
AC + AH :P। 0@. ∠ ABC = θ , AB = a ,-? Lim
and the value of Lim = 10, then the θ →0 θ
θ →0 θ
value of a is equal to ? /?0 10 :P, ,ो a ? /?0 :P
(A) 1 (A) 1
(B) 2 (B) 2
(C) 5 (C) 5
(D) 10 (D) 10
2. Let g be a differentiable function satisfying 2. /?0? g ए अ=ल0A0 ,ल0 :P जो
x x
4 2
∫ (x − t + 1) g(t) dt = x + x for all x > 0. The ∫ (x − t + 1) g(t) dt = x4 + x2 , ∀ x > 0 ो 9ं,B
0 0

value of is equal to 1,? :P, ,ो ? /?0 :P

(A) π (A) π
6 6
π π
(B) (B)
3 3
(C) π (C) π
4 4
π π
(D) (D)
2 2

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 3.
Yashpatil TG~ @bohring_bot
Assertion A : P(A ∩ B ∩ C) = P ( AB ) . P ( B ) . P (C) 3. %( A : P(A ∩ B ∩ C) = P ( A ) . P ( B ) . P (C) AP।
C B C
Reason R : P ( A ) is probability of event A when ?1# R : P ( A ), (? A  ?@0$? AP - (? B
B B
event B has already happened. @$ AK 
B AP।
(A) Both A and R are correct and R is the (A) A $%? R &K( @AA AP $%? R, A ? @AA + A1#
correct explanation of A AP।
(B) Both A and R are correct and R is not the (B) A $%? R &K( @AA AP $%? R, A ? @AA + A1#
correct explanation of A (A AP।
(C) A is correct but R is not correct (C) A @AA AP +1 $B R @AA (A AP।
(D) A is not correct but R is correct (D) A @AA (A AP +1 $B R @AA AP।
π
12
π
12
2
tan x − 3 tan2 x − 3
4. The value of definite integral ∫ dx 4. @(@ $ @/?ल( ∫ dx ? /?( AP
3tan2 x − 1 3tan2 x − 1
0 0
is equal to

(A) π 1
ℓn (
3−1
) (A) π 1
ℓn (
3−1
)
√ √

+ +
12 2− 3 12 3 2 − √3
√ 3 √ √

(B) π 1
ℓn (
3−1
) (B) π 1
ℓn (
3−1
)
√
+
√
+
8 2 − √3 8 3 2 − √3
√ 3 √

(C) π 1 3−1
(C) π 1
ℓn (
3−1
) ℓn ( )
√
−
√
−
12 12 3 2 − √3
√ 3 2− 3 √ √

(D) π 1
ℓn (
3−1
) (D) π 1
ℓn (
3−1
)
√ √

− −
8 2 − √3 8 3 2 − √3
√ 3 √

5. Let S be the set of 8-digit numbers 5. /?(?  -   @ 0? k1k2k3k4k5k6k7k8

k1k2k3k4k5k6k7k8 (all digits distinct) where (@.A  @. (-@. () ? @/B 0 S AP
k1> k2 > k3 > k4 < k5 < k6 < k7 < k8. Then n(S) is A? k1> k2 > k3 > k4 < k5 < k6 < k7 < k8 AP।
equal to $- n(S) AP
(A) 90 (A) 90
(B) 3150 (B) 3150
(C) 1575 (C) 1575
(D) 180 (D) 180
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 6.
Yashpatil TG~ @bohring_bot 6.
Volume of parallelopiped whose coinitial @/? $1 ?M,ल ? 0$(, @@ @/@?/A .B ?0

edges are given by vector →α , →³ and →´ , where →α , →³ @@&> →α , →³ $%? →´ ?1? &A ?$A AP A? →α , →³ $%? →´

and →´ are unit vectors which are bisecting the ? @@&> A K $A( ल -=$M @@&> O -A O K# K

angle between three orthonormal vectors, is @/@ .?@$ 1 1AO A, AP

1 1
(A) (A)
2 √2 2 √2
(B) √ 2 (B) √ 2

(C) 2 √2 (C) 2 √2
1 1
(D) (D)
√ 2 √ 2
7. If the normal at the end points of a variable chord 7. 0@& +1=ल0 y2 – 4y – 2x = 0 1 A=? PQ O @$/
PQ of parabola y2 – 4y – 2x = 0 are perpendicular, @@1 +1  O 0O @.ल - ल -=$M AP, $K P $%? Q +1
then the tangent at P & Q will intersect at  A  +> 1O ? @@ +1 @$ O & 1O A
(A) x + y = 3 (A) x + y = 3
(B) 3x – 7 = 0 (B) 3x – 7 = 0
(C) y + 3 = 0 (C) y + 3 = 0
(D) 2x + 5 = 0 (D) 2x + 5 = 0
8. Let x1y1z1, x2y2z2 and x3y3z3 be three 3-digit 8. /?(? x1y1z1, x2y2z2 $%? x3y3z3 $A(   @/
∣ x1 y1 z1 ∣ ∣ x1 y1 z1 ∣
∣ ∣ ∣ ∣

even numbers and Δ = ∣ x2

∣
y2 z2 ∣∣. Then Δ is @ 0?0 A $%? Δ = ∣
∣
x2 y2 z2 ∣∣ AP। $- Δ AP
∣ ∣ ∣ ∣
∣ x3 y3 z3 ∣ ∣ x3 y3 z3 ∣
(A) divisible by 2 but not necessarily by 4. (A) 2 @O @=.?0 +1 $B = 0 (A 4 @O @=.? 0 AK
(B) divisible by 4 but not necessarily by 8. (B) 4 @O @=.? 0 +1 $B = 0 (A 8 @O @=.? 0 AK
(C) divisible by 8 (C) 8 @O @=.? 0
(D) None of these (D) (/ @O K (A

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 9.
Yashpatil TG~ @bohring_bot 9.
List-I List-II @C A-I @C A-II
g (x ) g (x )
dt dt
If f(x) = ∫ where 0@& f(x) = ∫ AP
0
√ 1+ t3 √ 1 + t3
0
cos x cos x
(A) (I) 3 (A) (I) 3
g(x) = ∫ (1 + sin t2 ) dt then A? g(x) = ∫ (1 + sin t2 ) dt
0 0

the value of f ′ ( π ) AK, $K f ′ ( π ) ? /?( AP

2 2
If f(x) is differentiable 0@& f(x) =ल(A0 ,ल( AP
function which is not K @.A x * R O @ल >C 0

(B) identically zero ∀ x * R and (II) 2 (B) (A AP $%? @.A x O @ल (II) 2
x x
2
satisfy ∫ f(t) dt = (f (x)) for ∫ f(t) dt = (f (x))2 K @ $B
0 0
all x then 2 + f(2) equals 1$? AP , $K 2 + f(2) -1?-1 AP
b
b
If ∫ (2 + x − x2 ) dx is 0@& ∫ (2 + x − x2 ) dx
a
(C) (III) 1 (C)
a
(III) 1
maximum then (a + b) has the @'$/ AK, $K (a + b) ?
value equal to (where b > a) /?( AP (A? b > a)
sin 2x b
If lim ( +a+ )=0 0@&
x→0 x3 x2
(D) then (3a + b) has the value (IV) – 1 sin 2x b
(D) lim ( +a+ )=0 (IV) – 1
x→0 x 3 x2
equal to
AK, $K (3a + b) ? /?( AP
(A) A → IV; B → I; C → II; D → III
(A) A → IV; B → I; C → II; D → III
(B) A → III; B → IV; C → I; D → II
(B) A → III; B → IV; C → I; D → II
(C) A → IV; B → I; C → III; D → II
(C) A → IV; B → I; C → III; D → II
(D) A → II; B → I; C → IV; D → III
(D) A → II; B → I; C → IV; D → III

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 Yashpatil TG~ @bohring_bot 3n1
4
3n1
4
−1 + i√3 −1 + i√3
10. If α + i ³ = ( ) (1 − i)
−2n2
, 10. 0@& α + i ³ = ( ) (1 − i)
−2n2
,
2 2
(where n1 and n2 are positive integer) then which (A? n1 $%? n2 '(? / +#C ? AP) AK, $K @( ( / @O
L(@? @ 0 AP
of the following is FALSE (Given i = √ −1)
(@&0? 0? AP @ i = −1)
√

(A) α = 0 if only one of n1 and n2 is odd (A) α = 0 0@& n1 $%? n2 / @O O =ल  @=?/ AP।
(B) ³ = 0 if both n1 and n2 are odd (B) ³ = 0 0@& &K( n1 $%? n2 @=?/ AP।
(C) α = 0 if both n1 and n2 are even (C) α = 0 0@& &K( n1 $%? n2 @/ AP।
(D) ³ = 0 if both n1 and n2 are even (D) ³ = 0 0@& &K( n1 $%? n2 @/ AP।
11. The area bounded by the curve x = logey, 11. = x = logey, x = ey – 2, x = e – ey, x = – 1 ?1?
x = ey – 2, x = e – ey, x = – 1 is A + B ℓ n(1 + e ),
2 + 1- O ,ल A + B ℓ n(1 + e ) AK, $K |A + B| AP
then |A + B| is 2
1 1 1 1
(A) 2 + (B) 2 + e – (A) 2 + (B) 2 + e –
e e e e
(C) 2 (D) 1 (C) 2 (D) 1
e e
12. If the planes x – y – z = 0, x – y + sin α ⋅ z = 0 and 12. 0@& @/$ल x – y – z = 0, x – y + sin α ⋅ z = 0
x + sin α ⋅ y – z = 0 pass through a straight line, $%? x + sin α ⋅ y – z = 0  @1ल 1O ? @O B1$O AP,
then number of values of α in [0, 2021 π ] is/are $K [0, 2021 π ] / α O /?(  @ 0? AP
(A) 1010 (A) 1010
(B) 1011 (B) 1011
(C) 2020 (C) 2020
(D) 2021 (D) 2021
13. The mean and standard deviation of the marks of 20 13. 20 ? ? O  ? /? 0 $%? /?( @=ल( />
students were found to be 40 and 15 respectively. 40 $%? 15 +?0? 0? AP। -?& /, 0A +$? ल? @ 60 ?
Later, it was discovered that a score of 60 was K1 ल$A @O 40 O + / +^? 0? 0?, $K @AA @1#
wrongly read as 40, then the correct variance will be AK?
(A) 232 (B) 236 (A) 232 (B) 236
(C) 240 (D) 244 (C) 240 (D) 244

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 Yashpatil TG~ @bohring_bot
14. Let the tangent drawn at any point P(t) on the
curve y2 = 4ax ; a > 0 having focus at S intersects
the axis at point T. If the locus of the orthocentre
of Δ PST intersects y2 = 4ax at points A and
B other than origin, then (AB)2 is
(A) 3a2 (B) 12a2
(C) 36a2 (D) 48a2
15. STATEMENT 1 : Diagonals of any parallelogram
inscribed in an ellipse always intersect at the
centre of the ellipse.
STATEMENT 2 : Centre of the ellipse is the only
point at which two chords can bisect each other
and every chord passing through the centre of the
ellipse gets bisected at the centre
(A) Both the statement 1 and Statement 2 are true
(B) Both the Statement 1 and Statement 2 are false
(C) Statement 1 is true but Statement 2 is false
(D) Statement 1 is false but Statement 2 is true
16. The vector →a = i^ + 2j^ + k^ lying in the plane of the
vectors →b = i^ + j^ and →a bisects the angle between
→b and →c . If |→c | = √2, then →c ⋅ →a is
14. /?न? = y2 = 4ax ; a > 0 +1 @9A @- .B P(t) +1 +>
1O ?  चA ई :P, =  न?@. S +1 :P जो अ ो T +1
?ट,A :P। 0@. Δ PST O ल -O ? @- .+B -, y2 = 4ax
ो /ल C @- .B O अल?=? @- .B A ,-? B +1 ?ट,? :P, ,ो
(AB)2 -1?-1 :P
(A) 3a2 (B) 12a2
(C) 36a2 (D) 48a2
15. -न 1 : .A =D O अ ,, @9A 9/? ,1 च,.B जB O
@=+ 9.P= .A =D O O +1 ?ट,O :P।
-न 2 : .A =D ? O :A ए/? @- .B :P @ज9 +1 .ो
जA=?एं ए .9B 1O ो 9/@ .?@ज, 1 9,A :P ,-? .A =D
O O 9O जB 1नO =?लA 0O जA=? O +1 9/@ .?@ज,
:ो ज?,A :P।
(A) -न 1 ,-? -न 2 .ोन 9 0 :P।
(B) -न 1 ,-? -न 2 .ोन अ9 0 :P।
(C) -न 1 9 0 +1 ,B -न 2 अ9 0 :P।
(D) -न 1 अ9 0 +1 ,B -न 2 9 0 :P।
16. 9@.> →a = i^ + 2j^ + k^ , 9@.> →b = i^ + j^ ,-? →c O 9/,ल
/ @ -, :P ,-? →b ए=ं →c O / 0 ो+ ो 9@.> →a
9/@ .?@ज, 1,? :P। 0@. |→c | = √2 :ो, ,ो →c ⋅ →a :P

(A) 1 (B) 2 (C) 3 (D) √3 (A) 1 (B) 2 (C) 3 (D) √3

2 2

−11 −11
17. If ; (x ≠ ) and 17. 0@. ; (x ≠ ) ,-?
3 3

det(adj(adjA)) = (14)4. Then the sum of possible det(adj(adjA)) = (14)4 :P। x O 9.A 9ं.= /?न ?
value(s) of x is 0ो,ल :P
(A) 2 (B) – 2 (A) 2 (B) – 2
22 (C) 0 22
(C) 0 (D) − (D) −
3 3
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 Yashpatil TG~ @bohring_bot
18. If the variable line y = kx + 2h is tangent to an 18. 0@& 1 1O ? y = kx + 2h, &A =D 2x2 + 3y2 = 6 
ellipse 2x2 + 3y2 = 6, then locus of P(h, k) is a +> 1O ? AP, $K P(h, k) ? @- &+B % >?= C AP @@
conic C whose eccentricity equals to :-  O $? AP :-
(A) √ 5 (A) √5
2 2

(B) √ 7 (B) √7
3 3

(C) √ 7 (C) √7
2 2
(D) √ 7 (D) √ 7
3 3
19. The polynomial P(x) is the remainder upon dividing 19. x K x2 – 5x + 6 @O @=.?@$ 1(O +1 -A+& P(x)
2007

x2007 by x2 – 5x + 6. If P(0) can be expressed as >O?,ल AP। 0@& P(0) K mn(mr – nr) O + / 0
mn(mr –nr) where m & n are co-prime (m < n) & r * N @0? ? @$? AP A? m $%? n @A- .? 0 AP (m < n)
(m + n)r (m + n)r
then value of is $%? r * N AK, $K ? /?( AP
2006 2006
(A) 2 (A) 2
(B) 5 (B) 5
(C) 6 (C) 6
(D) 10 (D) 10
20. Let R1 and R2 be two relations defined as follows : 20. &K @ - ' R1 $%? R2 (AO @&0O 0O A :
R1 = {(a,b) * R2 : a2 + b2 * Q } and R1 = {(a,b) * R2 : a2 + b2 * Q } $%?
R2 = {(a,b) * R2 : a2 + b2 + Q}, R2 = {(a,b) * R2 : a2 + b2 + Q},
where Q is the set of all rational numbers. Then : A? Q @.A + 1/O0 @ 0? ? @/B 0 AP, $K :
(A) R2 is transitive but R1 is not transitive (A) R2 @ ?/ AP +1 $B R1 @ ?/ (A AP।
(B) R1 is transitive but R2 is not transitive (B) R1 @ ?/ AP +1 $B R2 @ ?/ (A AP।
(C) R1 and R2 are both transitive (C) R1 1 R2 &K( @ ?/ AP।
(D) Neither R1 nor R2 is transitive (D) (? $K R1 (? AA R2 @ ?/ AP।

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 Yashpatil TG~ @bohring_bot
SECTION-II : (Maximum Marks: 20)  !-II : ( @'$/ : 20)
This section contains 10 questions Candidates have to @ ! / 10 A।  /A&=?1 K 10 / @O @@A .A 5 ?
attempt any 5 questions out of 10. If more than 5 0?@ 1(? AP। 0@& 5 @O @' ? 0?@ @0? ?$? AP, $K
questions are attempted, then only first 5 attempted O =ल +AलO 5 ? /C 0?( @0? ??।
questions will be evaluated. 0O ?  1 @ 0? / /?( (Numerical Value) AP।
The answer to each question is a Numerical Value. 0O O @ल, @AA +#C ? /?( & 1 (&>/ल= @O $( /,
For each question, enter the correct integer value (In  1 K @($/ +#C ? / @ल? ?(? ?@A। )
case of non-integer value, the answer should be 0O O  1 ? /C 0?( @( (@ल@$ ( 0K(? O
rounded off to the nearest Integer). (@B ?1 @0? ??:
Answer to each question will be evaluated according to +#C  : +4 0@& @AA  1 & @0? 0? AP।
the following marking scheme: >C 0  : 0 0@& K .A  1 & (A @0? 0? AP।
Full Marks : +4 If correct answer is entered. #? /  : –1 0@& ल$  1 & @0? 0? AP।
Zero Marks : 0 If the question is unanswered.
Negative Marks : –1 If wrong answer is entered.
1. Let f and g be two real valued differentiable 1. /?(? f $%? g, R +1 &K =? $@= /?( =ल(A0 ,ल(
f ′ (x) g 2 (x) f ′ (x) g 2 (x)
functions on R such that = ∀ x * R. @ ?1 AP @ = ∀ x * R AP।
g ′ (x) f 2 (x) g ′ (x) f 2 (x)
If f(10) = 5, g(10) = 2 and g(2) = 1, then the value of 0@& f(10) = 5, g(10) = 2 $%? g(2) = 1 AK,
(f (2))3 is $K (f (2))3 ? /?( AP
© max. (1 + x, 1 − x) ; for x < 0 © max. (1 + x, 1 − x) ; for x < 0
2. Let f(x) = ª
« . 2. /?(? f(x) = ª
«
min. (1 + x, 1 + x2 ) ; for x ⩾ 0 min. (1 + x, 1 + x2 ) ; for x ⩾ 0
If N and M are respectively the number of points AP।
of discontinuity and the number of points of 0@& ,ल( f(x) O /> @$$ $%? (- =ल(A0
non-differentiability of the function f(x), then @- &B  @ 0? N $%? M AP, $K (N + M) ? /?( ?$
find (N + M).  @
π
2
π
2
9
2
3. If In = ∫ sin(2nx). cot x dx, then find the value of 3. 0@& In = ∫ sin(2nx). cot x dx AP, $K ∑ In ?
π n=1
0 0
9
2 /?( ?$  @
∑ In .
π n=1

4. Let zi, i = 1,2,3,4,5,6 be the roots of equation 4. /?(? @/A1# z6 + z4 = 2 O /ल

C zi, i = 1,2,3,4,5,6 AP,
6 6
z6 + z4 = 2, then ∑ |zi |4 is equal to $K ∑ |zi |4 ? /?( -1?-1 AP
i=1 i=1

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 5.
Yashpatil TG~ @bohring_bot
Let f(x) be a differentiable function such that 5. /?(? f(x) =ल(A0 ,ल( @ ?1 AP @
2f(x + y) + f(x – y) = 3f(x) + 3f(y) ∀ x, y * R 2f(x + y) + f(x – y) = 3f(x) + 3f(y) ∀ x, y * R $%?
and f ′ (0) = 0, then the value of f(5) + f ′ (5) is f ′ (0) = 0 AP, $K f(5) + f ′ (5) ? /?( AP
6. The minimum value of (tanP – cosQ)2 + 6. (tanP – cosQ)2 + (cotP – sinQ)2 ? 0(C $/ /?(,
(cotP – sinQ)2, (where P & Q are independent (A? P $%? Q =$ 1 AP) α − √ ³ O + / A? α ,
variables) is of form α − √ ³ whered α , ³ are
³ ?D $ @ 0?0 AP, $K | ³ – α | ? /?( AP
natural numbers then value of | ³ – α | is
7. The number of solution(s) of the equation 7. $1?ल [0, 2022 π ] / @/A1#
sin (3x − π ) + 2cos2 (x + 5 π ) + 1 = 0 in sin (3x − π ) + 2cos2 (x + 5 π ) + 1 = 0 O Aल
6 18 6 18
[0, 2022 π ], is  @ 0? AP
8. There are 5000 identical passes for an event 8.  @/?1KA O @ल0O 5000 @/?( +?@ AP @ AO 100
which is to be distributed among 100 persons 0@ 0 P1, P2, P3 .... P100 O / 0 @ ?1 @=$1A$
P1, P2, P3 .... P100 such that Pi gets at least (i – 1) @0? ?$? AP @ Pi K / @O / (i – 1) +?@ ? AK$O AP।
passes. The number of ways of distributing the +?@ K @=$1A$ 1(O O $1A @ 0? mCn AP,$K (m – n)
passes is mCn then the greatest value of (m – n) is ? @'$/ /?( AP
^ → ^ ^ ^ → ^ ^
9. Let →a = ^i + j^ + k, b and →c = j − k be three vectors 9. /?(? →a = ^i + j^ + k, b $%? →c = j − k $A( @@&> @
such that →a × →b = →c and →a ⋅ →b = 1. If the length of ?1 AP @ →a × →b = →c $%? →a ⋅ →b = 1 AP। 0@& @@&>
projection vector of the vector →b on the vector →a × →c +1 @@&> →b O O+ @@&>  ल -? ℓ AP, $K
→a × →c is ℓ , then the value of 6 ℓ 2 is equal to 2
6 ℓ ? /?( -1?-1 AP
10
10. If the sum of the coefficients of all the positive
10. 0@& (2x + 3 )
3
O @ +& @?1 / x O @.A '(? /
even powers of x in the binomial expansion of x
10 @/ ?$ O #B ? ? 0K,ल 510 – ³ .39 AP, $K ³
(2x + 3 )
3
is 510 – ³ .39, then ³ is equal to -1?-1 AP
x

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