All India Open Test-1 (Aiot-1) : Time: 3 Hours Maximum Marks: 300

® P1A-19
DATE
29-12-2019
ALL INDIA OPEN TEST-1 (AIOT-1)
(JEE MAIN PATTERN)
CODE TARGET : JEE (MAIN + ADVANCED) 2020
1 COURSE : ALL INDIA TEST SERIES (VIKALP) | CLASS : XII/XIII
Time : 3 Hours Maximum Marks : 300
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
INSTRUCTIONS TO CANDIDATES
 Question paper has three (03) parts: Physics, Chemistry and Mathematics.
 Each part has a total twenty five (25) questions divided into two (02) sections (Section-1 and Section-2).
 Total number of questions in Question paper are Seventy Five (75) and Maximum Marks are Three Hundred only (300).
Type of Questions and Marking Schemes
SECTION-1 (Maximum Marks : 80)

 This section contains TWENTY (20) questions
 Each question has FOUR options (A), (B), (C) and (D) ONLY ONE of these four option is correct
 Marking scheme :
 Full Marks : +4 If the corresponding to the answer is darkened
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –1 In all other cases.
SECTION – 2 : (Maximum Marks : 20)
 This section contains FIVE (05) questions. The answer to each question is NUMERICAL VALUE with two digit integer
and decimal upto one digit.
 If the numerical value has more than two decimal places truncate/round-off the value to ONE decimal placed.
 Full Marks : +4 If the corresponding to the answer is darkened
 Zero Marks : 0 In all other cases.
NAME OF THE CANDIDATE : ………………………………………………… ROLL NO. :………………..………………………..
I have read all the instructions I have verified the identity, name and roll number
and shall abide by them of the candidate.
------------------------- -------------------------
Signature of the Candidate Signature of the Invigilator
Resonance Eduventures Limited

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INSTRUCTIONS FOR OPTICAL RESPONSE SHEET (ORS)
 Darken the appropriate bubbles on the original by applying sufficient pressure.

 The original is machine-gradable and will be collected by the invigilator at the end of the examination.
 Do not tamper with or mutilate the ORS.
 Write your name, roll number and the name of the examination centre and sign with pen in the space provided for this
purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble under each
digit of your roll number.
DARKENING THE BUBBLES ON THE ORS :

 Use a BLACK BALL POINT to darken the bubbles in the upper sheet.
 Darken the bubble COMPLETELY.
 Darken the bubble ONLY if you are sure of the answer.
 The correct way of darkening a bubble is as shown here :
 There is NO way to erase or "un-darkened bubble.
 The marking scheme given at the beginning of each section gives details of how darkened and not darkened bubbles
are evaluated.
 Zero marks ‘0’ If none of the options is chosen (i.e. the question is unanswered).
FOR INTEGER TYPE QUESTIONS OMR LOOKS LIKE :

 For example, if answer ‘SINGLE DIGIT’ integer type below :
0 1 2 3 4 5 6 7 8 9
 For example, if answer ‘DOUBLEDIGIT’ integer type below :

0 0
1 1
2 2
3 3
4 4
5 5
6 6
7 7
8 8
9 9
FOR DECIMAL TYPE QUESTIONS OMR LOOKS LIKE :
COLUMN
1 2 . 3 4
0 0 0 0
1 1 1 1
2 2 2 2
3 3 3 3
4 4 4 4
5 5 5 5
6 6 6 6
7 7 7 7
8 8 8 8
9 9 9 9
 If answer is 3.7, then fill 3 in either 1st or 2nd column and 7 in 3rd or 4th column.
 If answer is 3.07 then fill 3 in 1st or 2nd column ‘0’ in 3rd column and 7 in 4th column.
 If answer is, 23 then fill 2 & 3 in 1st and 2nd column respectively, while you can either leave column 3 & 4 or fill ‘0’ in either
of them.

PART-A 3. In the given figure the fixed pulley is smooth
and light where as movable pulley is rough
SECTION – 1 : (Maximum Marks : 80) and has some mass. There is no slipping
 This section contains TWENTY (20) questions. between the pulley and the string. Then
 Each question has FOUR options (1), (2), (3) magnitude of acceleration of the point P on the
and (4) ONLY ONE of these four option is movable pulley is. (If block is moving with an
acceleration a)
correct
 Full Marks : +4 If ONLY the correct option is a
chosen.
 Zero Marks : 0 If none of the options is
chosen (i.e. the question is unanswered).
 Negative Marks : –1 In all other cases
P
1. An isosceles triangle is to be cut from one a
(1) a (2)
edge of a square lamina of uniform mass 2
density such that the remaining portion when a
suspended from apex P of the cut will remain (3) 2a (4)
2
in equilibrium in any position. The value of h is.

4. A capillary tube with very thin walls is held
vertical and is attached to an end of a light
horiozontal rod which is pivoted at its midpoint.
A mass is suspended through the other end to
 P keep the rod in horizontal position. Now the
lower end of the capillary tube is just brought in
h contact with the surface of water. An additional
mass 0.157 g is attached to the other end to
keep the rod in horizontal position. What is the
 2  2  3  2 
(1)    (2)    radius of the capillary tube ? Surface tension of
 2   2  the water is 0.075 N/m. Contact angle between
   
tube and water is 0º.
3  3   2  2  (1) 3.3 mm (2) 6.6 mm
(3)     (4)   
 2   2  (3) 9.9 mm (4) 1.1 mm
   
5. Light rays from a very distant source travels
2. Moment of inertia of a uniform solid cone along +x direction and fall on two identical thin
about an axis passing through its centre of lenses with focal length F>0 and their optical
gravity and parallel to its base is (m is mass of axes along x-axis. One at x = 0 and the other
cone, its height is h and its radius R = h) at x = d (< F). The rays will focus at x =
F (F  d )
10 (1) d
(1) MR2 2F  d
3
F (F  d )
3 (2) d
(2) MR2 d
5
F (F  d )
3 (3) d 
(3) MR2 2 (F  d )
10
2
3 F
(4) MR 2 (4) d 
16 2 (F  d )
Space for Rough Work
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6. A horizontal tube, open at both ends contains 9. The frequency of sonometer wire is f, but when the
a column of liquid. The length of this liquid weight producing the tension is completely immersed
column does not change with temperature. If f
 = co-efficient of volume expansion of liquid in water the frequency becomes and on
2
and  = coefficient of linear expansion of the immersing the weight in a certain liquid the frequency
material of the tube. Then f
(1)  =  becomes . The specific gravity of liquid is.
3
(2)  = 2
4 10
(3)  = 3 (1) (2)
(4)  = 0 3 9
15 32
(3) (4)
7. A coal based thermal power plant producing 12 27
electricity operates between the temperatures
27ºC and 227ºC. The plant works at 80% of its 10. A slightly tapering wire of length  and end radii 'a'
maximum theoretical efficiency. Complete and 'b' is subjected to tension F. Y is the Young's
burring of 1 kg of coal yields 3600 KJ of heat. Modulus. The extension produced in the wire is.
A house needs 10 units of electricity each day. F F ab
(1) (2)
Coal used for supplying the amount of energy  Yab 2 2
Y a  b
for the house in one year is
(1) 1141 kg F ab F a  b
(3) (4)
(2) 580 kg Y a  b Y a
2
 b
2
(3) 605 kg
(4) 765 kg 11. A non conducting ring of radius 4 cm has
varying linear charge density which is given by
8. Initially spring is compressed by distance x0  = 3cos c/m. The net electric dipole moment
from equilibrium position. At this compression of the ring is given by
3K
block is given velocity v = x0. So that the
m 
compression in the spring increases and block
start SHM (Spring constant K). Equation of
motion of block is.
(1) 48 Cm (2) 12 × 10–4 Cm
v (3) 12 Cm (4) 48 × 10–4 Cm
K 12. A parallel beam of light of wavelength 5000 Å is
incident on slit S. Another two slit S1 and S2 are
illuminated at distance 2m as shown in the
x0 figure. The minimum distance between S1 and
 K   S2 such that maximum intensity will occur at O is.
(1) y = y  3 x 0 sin  t  
 m 3 
 
S1
 K  
(2) y  2x0 sin  t   O
 m 6  S S2
 
 K  
(3) y  3 x 0 sin  t   2m 2m
 m 6  Screen
 
(1) 10 mm (2) 1 mm
 K  
(4) y  2 x 0 sin  t   1
 m 3  (3) mm (4) 5 mm
  2
®
13. From ideal instruments current measured is 17. The first diffraction minima due to a single slit
I = 10.0 A, potential difference measured is diffraction is at  = 30º for a light of wavelength
V = 100.0 volt, length of wire is 31.4 cm and 5000 Å. The width of the slit is
diameter of wire is 2.00 mm. The resistivity of (1) 5 × 10–4 cm (2) 1.0 × 10–4 cm
wire will be (in correct significant figures) –4
(3) 2.5 × 10 cm (4) 1.25 × 10–4 cm
( = 3.14)
(1) 1.00 × 10–4  m
18. During the propagation of electromagnetic
(2) 1.0 × 10–4  m
waves in a medium:
(3) 1 × 10–4  m
(1) Electric energy density is double of the
(4) 1.000 × 10–4  m
magnetic energy density.
14. When the light of wavelength 400 nm is incident (2) Electric energy density is half of the
on a metal surface of work function 2.3 eV magnetic energy density.
photoelectrons are emitted. A fastest (3) Electric energy density is equal to the
photoelectron combines with a He2+ ion to form magnetic energy density.
He+ ion in its 3rd excited state and a photon is (4) Both electric and magnetic energy
emitted in this process. Then the energy of the densities are zero.
photon emitted during combination is. (Assume
energy of He2+ to be zero)
19. A particle moves along x-axis in positive
(1) 4.2 eV
direction. Its acceleration 'a' is given as
(2) 5.7 eV
(3) 6.5 eV a = cx + d, where x denotes the x-coordinate
(4) 6.8 eV of particle, c and d are positive constants. For
velocity-position graph of particle to be of type
15. The combination of the gates in figure as shown in figure, the value of speed of
produces particle at x = 0 should be.
A
(1) AND gate (2) XOR gate

(3) NOR gate (4) NAND gate
16. A parent radioactive nucleus A (decay 4d
2
d
2
constant A) converts into a radioactive (1) (2)

c c
nucleus B of decay constant B. Initially
number of nuclei of B is zero. At any time NA 2d
2
8d
2
and NB are number of atoms of nuclide A and (3) (4)

c c
B respectively then maximum value of NB is.
 AN A 20. In a large building, there are 15 bulbs of 40W,
(1)
B 5 bulbs of 100 W, 5 fans of 80 W and 1 heater
 BN A of 1 kW. The voltage of the electric mains is
(2) 220 V. The minimum capacity of the main fuse
A
of the building will be:
 A   B N B
(3) (1) 8 A
B
(2) 10 A
B (3) 12 A
(4) NA
 A  B (4) 14 A
®
23. A source of sound is moving along a circular
SECTION – 2 : (Maximum Marks : 20) orbit of radius 3 m with angular velocity of
 This section contains FIVE (05) questions. The 10 rad/s. A sound detector located far away
answer to each question is NUMERICAL from the source is executing SHM along the
VALUE with two digit integer and decimal upto line BD with amplitude BC = CD = 6 m. The
one digit. 5
 If the numerical value has more than two frequency of oscillation of the detector is

decimal places truncate/round-off the value
per second. The source is at the point A when
to ONE decimal placed.
detector is at the point B. If the source emits a
 Full Marks : +4 If ONLY the correct option is
sound of frequency 340 Hz. If the minimum
chosen.
frequency recorded by the detector (velocity of
 Zero Marks : 0 In all other cases
sound = 330 m/s) is 10 x (in Hz) then value of
x is :
21. A uniform rod of length L and mass M is
placed on a smooth horizontal surface. The
rod is hinged at the end A and is free to rotate
A
in horizontal plane about a vertical axis B C D
passing through A. As shown in figure there is
L
a nail N at a perpendicular distance from
4
24. Inside a uniformly charged infinitely long cylinder
end A of rod. At t = 0 and impulse P0 is applied
of radius R and volume charge density . There
3L
at a distance from end A. The impulse is is a spherical cavity of radius
R
. A point P is
4
2
in the horizontal plane and is perpendicular to located at a distance 2R from the axis of the
8  ML cylinder as shown. The electric field strength at
the rod. At t  , the rod returns to its
27 P 0 xR
the point P is , where value of x is :
initial position. If the impulse of the force 54  0
390 P 0
exerted by the nail on the rod is , then R
x
value of x is
N R/2 R
P
O
L/4
25. In the circuit shown, the switch 'S' is closed at

A 3L/4 P0 t = 0, then current through the battery after
126
steady state is reached is Ampere,
22. An open rectangular tank of height 3m and x
length and width respectively 5m and 3m where value of x is :

1F
contains water upto height 2m. It is 4 2
accelerated horizontaly along the longer side.
The acceleration that tank can be given so that 2F 4 5mH
108
10% of water spills out is (in m/s2), then 6 3
N
the value of N is : (g = 10 m/s2)
24V
®
PART – B 27. Ratio of Tb / Kb for 6% (W/V) AB2 is 1 mol/kg
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, and also for 9% (W/V) A2B it is 1 mol/kg
N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, (AB2 and A2B both are non-electrolytes).
Si = 28, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr Hence, atomic masses of A and B are
= 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65,
respectively : (assume molality = molarity)
As = 75, Br = 80, Ag = 108, I = 127, Ba = 137,
(1) 60, 90
Hg = 200, Pb = 207]
(2) 40, 40
SECTION – 1 : (Maximum Marks : 80) (3) 40, 10
 This section contains TWENTY (20) questions. (4) 10, 40
 Each question has FOUR options (1), (2), (3) and
(4) ONLY ONE of these four option is correct 28. A hydrogen electrode is immersed in a solution
 Marking scheme : with pH = 0 (HCl). By how much will the
 Full Marks : +4 If ONLY the correct option potential (reduction) change if an equivalent
is chosen.
amount of NaOH is added to the solution. (Take
pH
2
= 1 atm & T = 298 K).
chosen (i.e. the question is
unanswered). (1) increase by 0.41 V
 Negative Marks : –1 In all other cases (2) increase by 59 mV
(3) decrease by 0.41 V

26. Which of the following statements is correct for (4) decrease by 59 mV
gas A having molar mass 16 g and density
0.75 g/L at 2 atm pressure and 27°C

A B Zn C
29. ZnCO3   ZnO    
temperature. ( impure )
(1) Force of attraction are dominating than Zn

correct coding of A, B & C is
( pure )
force of replusion among the gas
(A) (B) (C)
molecules. (1) Calcination Coke Fractional
(2) Force of repulsion are dominating than distillation
force of attraction among the gas (2) Calcination Carbon Fractional
molecules. monoxide distillation

(3) Calcination Electrolysis Liquation
(3) Gas molecules are behaving ideally
(4) Roasting Coke Poling
(4) Nothing can be said with certainity
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30. Two mole of an ideal gas is expanded 34. A radioactive isotope zXA is converted into
irreversibly and isothermally at 37ºC until its Z - 8Y

A – 16 by -decay. If 1 gram-atom zXA,
volume is doubled and 3.41 kJ heat is 4
produced 3 mol 2He in 34.65 hour then
absorbed from surrounding. Stotal (system +
disintegration constant of zXA is (in hr-1) is :
surrounding) is :
(1) 8 × 10-2 (2) 4 × 10-2
(1) –0.52 J/K (2) 0.52 J/K
(3) 2 × 10-2 (4) 3.6 × 10-3
(3) 22.52 J/K (4) 0
35. Which of the following is incorrect match ?
31. Bromine water reacts with SO2 to form : (1) Z = 48, group No. = 12, period No. = 5
(1) H2O and HBr (2) HBr and S (2) [Xe]4f7 5d1 6s2, group No. = 3, period
(3) H2SO4 and HBr (4) S and H2O No. = 6
(3) [Rn] 6d2 7s2, group No. = 4, period
32. A reaction at 300 K with G° = – 1743 J /mol No. = 7

consists of 3 mole of A(g), 6 mole of B(g) and (4) Z = 56, group No. = 2, period No. = 6
3 mole of C(g). If A, B and C are in equilbrium
in 1 litre container then the reaction may be 36. S1 : On adding acid to aqueous solution of
[Given : 2 = e0.7, R = 8.3 J/K - mol] K2CrO4, its colour changes from yellow to
(1) A + B C (2) A B + 2C orange.

2 2
(3) 2A B+C (4) A + B 2C S2 : CrO 4 and Cr 2 O 7 exist in equilibrium
over wide range of pH from 2 to 6.
33. Which of the following hydrolysis reaction is (1) Statement-1 is correct statement-2 is not a
incorrect at moderate temperature? correct explanation of statement-1

(2) Statement-1 is correct statement-2 is also
(1) 4BF3 + 3H2O  H3BO3 + 3HBF4
a correct explanation of statement-1
(2) 2NF3 + 3H2O  N2O3 + 6HF
(3) Statement-1 is correct statement-2 is not
(3) NCl3 + 3H2O  NH3 + HOCl
correct.
(4) BiCl3 + H2O  BiOCl  + 2HCl
(4) Statement-1 is not correct and statement-2
is correct.
37. Which of the following statements regarding 40. 0.2% solution of phenol acts as __________ &
silicones is not correct. ? 1% solution of phenol acts as _________
(1) Silicones have good thermal stability.
(1) antiseptic, disinfectant
(2) Liquid silicones are lubricants.
(2) disinfectant, antiseptic
(3) Silicones are chemically inert substances.
(3) analgesic, disinfectant
(4) Silicones are hydrophilic in nature.
(4) antipyretic, antiseptic
38. Identify the correct order in which bond order

is increasing in the following. 41. The labels of two bottles containing
(1) NO < O

< C
2
< He
 compounds I and II were lost. The names of
2 2 2
 2  these compounds were available in a register.

(2) O 2 < NO < C 2 < He 2
2  
Following are structures of I and II. Which
(3) C 2 < He 2 < O 2 < NO
combination of reagents can help in
  2
(4) He 2 < O 2 < NO < C 2
distinguishing these compounds?
39. The reactants X & Y of the following reaction

are
HO O
–
OH
X+Y   
H2O
(1) + CH3CHO (I) NaHCO3
(II) NaNO2 / HCl followed by -Naphthol in

(2)
aq.NaOH
(III) CHCl3 + NaOH
(3)
(IV) Neutral FeCl3
(1) I and II (2) III and IV
(4) (3) II and III (4) I and IV
42. The compounds 'X' and 'Y' formed in the 44. Identify the Y and Z in the following reaction.
following reaction are NH2
O NaNO , HCl  CHCl

   2   X   Y 
3
 Z
H+ H 2 O , 5º C H 2O NaOH
H
X+Y
OH OH OH
CHO
(1) hemiacetals with identical physical and
(1) Y = Z=
chemical properties.
CHO
(2) acetals with identical physical and chemical
(2) Y = Z=
properties.
(3) hemiacetals with different physical and + –

N2Cl CHCl2
(3) Y = Z=
(4) acetals with different physical and chemical
properties. OH O–CHO
(4) Y = Z=
43. The major product of the following reaction
sequence is
45. Consider the following reactions
Ph
(i) B2H6 NaBH4
(ii) H2O2/NaOH (I) D-Glucose     X
(iii) conc. H2SO4,  NaBH4

Me (II) D-Mannose     Y
Ph Ph NaBH4
(III) D-Fructose     Products
(1) (2)
The product/s in reaction (III) is / are
Me (1) X only
Ph Ph (2) Y only
(3) (4) (3) Neither X nor Y
Me (4) Both X and Y

OH
SECTION – 2 : (Maximum Marks : 20) 48. In FCC structure the total number of voids in
 This section contains FIVE (05) questions. The 0.6 mol of compound is x(1023). What is the
answer to each question is NUMERICAL VALUE value of 'x' ? {NA = 6×1023/mol}

with two digit integer and decimal upto one digit.
 If the numerical value has more than two decimal
places truncate/round-off the value to ONE 49. Reaction of phenol with NaOH followed by
decimal placed. heating with CO2 under high pressure, and

 Full Marks : +4 If ONLY the correct option
subsequent acidification gives compounds X
is chosen.
as the major product, which can be purified by
steam distillation. When reacted with acetic
46. The given reaction is an important step in anhydride in the presence of a trace amount of
Ostwald’s method for manufacturing of HNO3. conc. H2SO4 compound X produces Y as the
If we start with 6.8 g of NH3 and 40 g of O2, major product. If molecular mass of the final
then what mass % of excess reagent will be product (Y) is M then report your answer as
left behind ? M/10.
NH3 + O2   NO + H2O
50. How many Natural Occurring Essential -
47. 2665 mg of an octahedral complex amino acids has aromatic ring in side chain?
CrCl3.6H2O needs 3.4 g of AgNO3 for
complete precipitation of its all the free
chloride ions. If the given complex is subjected
to dehydration then the weight
(in g) of anhydrous complex obtained will be?
Report your answer by rounding off upto one
decimal place.
53. If x = 5 and y = –2 then x – 2y = 9. The
PART – C
contrapositive of this statement is
SECTION – 1 : (Maximum Marks : 80)
(1) If x – 2y = 9 then x = 5 and y = –2
 This section contains TWENTY (20) questions.
(2) If x – 2y  9 then x  5 and y  –2
 Each question has FOUR options (1), (2), (3) and
(4) ONLY ONE of these four option is correct (3) If x – 2y  9 then x  5 or y  –2
(4) If x – 2y  9 then either x  5 or y = –2
is chosen.
 Zero Marks : 0 If none of the options is 54. If the roots of the equation x2 –2ax + a2 + a – 3 = 0
chosen (i.e. the question is are real and less than 3 then
unanswered).
(1) a < 2
 Negative Marks : –1 In all other cases
(2) 2  a  3
51. The area bounded by the curves y = 6x – x2
(3) 3 < a  4
and y = x2 – 2x is
(4) a > 4
64
(1)
6
55. If log2(a + b) + log2(c + d)  4 then minimum
64
(2) value of a + b + c + d is
3
(1) 2
(3) 22
(2) 4
(4) 21
(3) 6
(4) 8
52. The complex number z = x + iy which satisfy
z – 5i
the equation = 1 lies on 56. How many five letter words are to be formed
z  5i
out of the letters of the word INFINITESIMAL
(1) the real axis
(1) 22640
(2) the straight line y = 5
(2) 22650
(3) a circle passing through origin
(3) 22660
(4) the imaginary axis (4) 22670
Reg./ Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
MJD/JRAIOT1291219C1-10
57. The system of equations 60. The line passing through the extremity A of
the major axis and extremity "B" of the minor
x + y + z =  – 1
axis of the ellipse x2 + 9y2 = 9 meets its
x + y + z =  – 1
auxiliary circle at the point M. Then the area
x + y + z =  – 1 of the triangle with vertices at A, M and the
has no solution if  is equal to origin.

31
(1) 2 (1)
10
(2) 1 29
(2)
(3) – 2 10
21
(4) 1, –2 (3)
10
27
(4)
58. In a ABC, angles A,B,C are in 2 : 3 : 4 10
respectively then the cosA is equal to

61. The sum of the squares of deviations for 10
b
(1) observations taken from their mean 50 is 250.
2a
The coefficient of variation is
c (1) 10%
(2)
2a
(2) 40%
3a (3) 50%
(3)
2b (4) 0.1%
3b
(4) 62. The sides of a triangle are
2c
2 2 2 2 2 2
(b  c ), (c  a ), (a  b ), where a, b,
59. The number of points at which the function c > 0. The area of triangle is given by
1
f(x) = (x – |x|)2(1– x + |x|)2 is not differentiable (1) b c
2 2
2
in the interval (–3, 4) is
1 4
(2) a
(1) Zero 2
(2) One 3 2 2
(3) b c
2
(3) Two
3
(4) Three (4)  bc 
2
63. A point equidistant from the lines 4x + 3y + 10 = 0, 66. Minimum distance between the curves
5x – 12y + 26 = 0 and 7x + 24y – 50 = 0 is y = x2 + x + 1 and x = y 2 + y + 1 is
(1) (1, –1) (1) 2
(2) (1, 1)
(2) 2 2
(3) (0, 0)
1
(4) (0, 1) (3)
2
(4) 2
64. Tangents are drawn from the point (a, a) to
the circle x2 + y2 – 2x – 2y – 6 = 0. If the 
67. Unit vector c is inclined at an angle  to unit
angle between the tangents lie in the range
 
   vectors a and b which are perpendicular to

 ,  , then the exhaustive range of values
3      
each other. If c = ( a + b ) + µ( a × b )
of a is -
where µ,  are real then  belongs to -
(1) (1, )
 
(2) (–5, –3)  (3, 5) (1) 0, 
 2
(3) (–2 2 , –1)  (3, )  

(2)  ,
(4) (–3, –1)  (3, 5) 2 
  3 
(3)  , 
65. A tangent and a normal are drawn at the 4 4 
point P(16, 16) of the parabola y2 = 16x which  

(4)  , 
cut the axis of the parabola at the point A and 4 2
B respectively. If the center of the circle

through P, A and B is C, then acute angle 68. Two lines whose equation are
x  3 y  2 z 1 x  2 y  3 z  2
between PC and axis of x is   and  
2 3  3 2 3
1 1
(1) tan lie in the same plane then the value of sin–1sin
2
is equal to
(2) tan–1 2
(1) 3
1 3
(3) tan (2)   3
4
(3) 4
1 4
(4) tan
3 (4)  – 4
x SECTION – 2 : (Maximum Marks : 20)
69. Let f(x)   
 { 1  | 1  t |} dt , x  2
 This section contains FIVE (05) questions. The
0
 5 x  7, x  2 answer to each question is NUMERICAL VALUE
Then f(2) is -  If the numerical value has more than two decimal
places truncate/round-off the value to ONE
(1) continuous but not differentiable decimal placed.
(2) continuous and differentiable is chosen.
(3) non continuous and non differentiable x 1

71. If the range of the function y = on the
x 1
(4) Differentiable but not continuous interval 0  x  4 be [a, b], then the value of
5b  2a 
72. For any integer n, the integral

70. The sum of the coefficients of x and x 2 in the 
2
e
sin x 3
cos ( 2 n  1) x dx has the value
9
0
3  3 1 
expansion of 2
(1 + x + 2 x )  x  
is
 2 3 x 
73. The equation |x + 2| – |x + 1| + |x – 1| = k,
7 x  R, k  N. Number of values of k for which
(1)
18 the equation has four solutions is "n" then
10 + n is equal to
7
(2) 
18 74. Solution of differential equation
dy 2x
 2 y
is x2e–y = ky2 + c then k is
dx x  2 ye
7
(3) equal to
24
75. A pair of dice is thrown, if 5 appears on at
(4) 
7 least one of the dice, then the probability that
24
a
the sum is 10 or greater is . Where a and b
b
are co prime. Then value of (a + b) is ?
® P1A-19
DATE
29-12-2019
(JEE MAIN PATTERN)
CODE TARGET : JEE (MAIN + ADVANCED) 2020
1 COURSE : ALL INDIA TEST SERIES (VIKALP) | CLASS : XII/XIII

Time (le;) : 3 Hours (?k.Vs) Maximum Marks (vf/kdre vad) : 300
Ñi;k bu funsZ'kksa dks /;ku ls i<+saA vkidks 5 feuV fo'ks"k :i ls bl dke ds fy, fn;s x;s gSaA
(Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose).
INSTRUCTIONS TO CANDIDATES
Question paper has three (03) parts: Physics, Chemistry ç'u&i=k eas rhu (03) Hkkx gS % (HkkSfrdh ] jlk;u foKku ,oa
and Mathematics.
xf.kr)
Each part has a total twenty five (25) questions divided into çR;sd Hkkx esa dqy iPphl (25) iz'u gS tks nks (02) [kaMks esa
two (02) sections (Section-1 and Section-2). foHkkftr gS ¼[kaM 1 vkSj [kaM 2)
Total number of questions in Question paper are Seventy Five iz'u&i=k esa ç'uksa dh dqy la[;k % fipgÙkj (75) ,oa vf/kdre
(75) and Maximum Marks are Three Hundred only (300). vad % rhu lkS (300) gSaA
ç'uksa ds çdkj vkSj ewY;kadu ;kstuk,¡ (Type of Questions and Marking Schemes)
[kaM–1 ¼vf/kdre vad : 80½ | SECTION-1 (Maximum Marks : 80)
This section contains TWENTY (20) questions bl [kaM esa chl (20) iz'u gSaA
Each question has FOUR options (1), (2), (3) and (4) izR;sd iz'u esa pkj fodYi (1), (2), (3) rFkk (4) gSaA bu pkj fodYiksa
ONLY ONE of these four option is correct) esa ls dsoy ,d fodYi lgh gSaA
 Marking scheme:  vadu ;kstuk
 Full Marks : +4 If the corresponding to the
 iw.kZ vad % +4 ;fn flQZ lgh fodYi gh pquk x;k gSA
answer is darkened
 Zero Marks : 0 If none of the options is chosen  'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS
(i.e. the question is unanswered). ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 Negative Marks : –1 In all other cases.  _.k vad % –1 vU; lHkh ifjfLFkfr;ksa esaA
[kaM–2 ¼vf/kdre vad : 20½ | SECTION – 2 : (Maximum Marks : 20)

This section contains FIVE (05) questions. The answer to bl [kaM esa ik¡p (05) iz'u gSA izR;sd iz'u dk mÙkj la[;kRed
each question is NUMERICAL VALUE with two digit integer eku (NUMERICAL VALUE) gSa]tks f}&vadh; iw.kkZad rFkk
and decimal upto one digit.
n'keyo ,dy vadu eas gSA
If the numerical value has more than two decimal places ;fn laa[;kRed eku esa nks ls vf/kd n’'keyo LFkku gS] rks la[;kRed eku dks
truncate/round-off the value to ONE decimal placed. n'keyo ds ,d LFkku rd VªadsV@jkmaM vkWQ (truncate/round-off) djsaA
 Marking scheme  vadu ;kstuk
 Full Marks : +4 If the corresponding to the
 iw.kZ vad % +4 ;fn flQZ lgh fodYi gh pquk x;k gSA
answer is darkened
 Zero Marks : 0 In all other cases  'kwU; vad % 0 vU; lHkh ifjfLFkfr;ksa esaA
ijh{kkFkhZ dk uke : ………………………………………………………………jksy uEcj : ………………………..…………………

eSaus lHkh funsZ'kksa dks i<+ fy;k gS vkSj eSa mudk eSusa ijh{kkFkhZ dk ifjp;] uke vkSj jksy uEcj
vo'; ikyu d:¡xk@d:¡xhA dks iwjh rjg tk¡p fy;k gSA
------------------------ ------------------------
ijh{kkFkhZ ds gLrk{kj ijh{kd ds gLrk{kj

vkWfIVdy fjLikal 'khV (ORS) Hkjus ds funsZ’'k (INSTRUCTIONS FOR OPTICAL RESPONSE SHEET (ORS)
Darken the appropriate bubbles on the original by applying Åijh ewy i`"B ds vuq:i cqycqyksa (BUBBLES) dks i;kZIr ncko
sufficient pressure. Mkydj dkyk djsaA
The original is machine-gradable and will be collected by the ewy i`"B e'khu&tk¡p gS rFkk ;g ijh{kk ds lekiu ij fujh{kd ds
invigilator at the end of the examination. }kjk ,d=k dj fy;k tk;sxkA
Do not tamper with or mutilate the ORS. vks-vkj-,l- dks gsj&Qsj@fod`fr u djsaA
Write your name, roll number and the name of  the viuk uke] jksy ua- vkSj ijh{kk dsanz dk uke ewy i`"B esa fn, x,
examination centre and sign with pen in the space provided [kkuksa esa dye ls Hkjsa vkSj vius gLRkk{kj djsaA buesa ls dksbZ Hkh
for this purpose on the original. Do not write any of these
details anywhere else. Darken the appropriate bubble under tkudkjh dgha vkSj u fy[ksaA jksy uEcj ds gj vad ds uhps vuq:i
each digit of your roll number. cqycqys dks dkyk djsaA
ORS ij cqycqyksa dks dkyk djus dh fof/k % (DARKENING THE BUBBLES ON THE ORS) :
Use a BLACK BALL POINT to darken the bubbles in the
Åijh ewy i`"B ds cqycqyksa dks dkys ckWy ikbUV dye ls dkyk djsaA
upper sheet.
Darken the bubble COMPLETELY. cqycqys dks iw.kZ :i ls dkyk djsaA
Darken the bubble ONLY if you are sure of the answer. cqycqyksa dks rHkh dkyk djsa tc vkidk mÙkj fuf'pr gksA
cqycqyksa dks dkyk djus dk mi;qDr rjhdk ;gk¡ n'kkZ;k x;k gS %
The correct way of darkening a bubble is as shown here :
There is NO way to erase or "un-darkened bubble. dkys fd;s gq;s cqycqys dks feVkus dk dksbZ rjhdk ugha gSA
The marking scheme given at the beginning of each section
 gj [k.M ds izkjEHk esa nh x;h vadu ;kstuk esa dkys fd;s x;s rFkk dkys
gives details of how darkened and not darkened bubbles are
evaluated.
u fd;s x;s cqycqyksa dks ewY;kafdr djus dk rjhdk fn;k x;k gSA.
For example, if answer ‘SINGLE DIGIT’ integer type below : mnkgj.k ds fy, , ;fn mÙkj ‘,dy vadh;’ iw.kkZad gS rc :
0 1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9
For example, if answer ‘DOUBLEDIGIT’ integer type below : mnkgj.k ds fy, , ;fn mÙkj ‘f)&vadh;’ iw.kkZad gS rc :
0 0 0 0
1 1 1 1
2 2 2 2
3 3 3 3
4 4 4 4
5 5 5 5
6 6 6 6
7 7 7 7
8 8 8 8
9 9 9 9
FOR DECIMAL TYPE QUESTIONS OMR LOOKS LIKE : n'keyo iw.kkZad@la[;kRed vadksa ds fy, ORS fuEu çdkj gS :
COLUMN COLUMN
1 2 . 3 4 1 2 . 3 4
0 0 0 0 0 0 0 0
1 1 1 1 1 1 1 1
2 2 2 2 2 2 2 2
3 3 3 3 3 3 3 3
4 4 4 4 4 4 4 4
5 5 5 5 5 5 5 5
6 6 6 6 6 6 6 6
7 7 7 7 7 7 7 7
8 8 8 8 8 8 8 8
9 9 9 9 9 9 9 9
If answer is 3.7, then fill 3 in either 1 st or 2nd column and 7 in ;fn mÙkj 3.7 gS rc 3 dks 1 ;k 2nd dkWye esa Hkjsa rFkk 7 dks 3rd ;k
st
rd th
3 or 4 column. 4th dkWye esa HkjsaA
If answer is 3.07 then fill 3 in 1st or 2nd column ‘0’ in 3rd column ;fn mÙkj 3.07 gS rks 3 dks 1st dkWye ;k 2nd dkWye esa Hkjsa rFkk ‘0’
and 7 in 4th column. dks 3rd dkWye esa rFkk 7 dks 4th dkWye esa HkjsaA
If answer is, 23 then fill 2 & 3 in 1 st and 2nd column ;fn mÙkj 23 gS rc 2 dks 1st dkWye esa ] 3 dks 2nd dkWye esa tcfd
respectively, while you can either leave column 3 & 4 or fill rd
3 vkSj 4th dkWye dks [kkyh NksM+ nsa ;k ‘'kwU; Hkj nsaA
‘0’ in either of them.

PART-A Hkkx– A
SECTION – 1 : (Maximum Marks : 80) [kaM 1 : (vf/kdre vad : 80)
 This section contains TWENTY (20) questions.  bl [kaM esa chl (20) iz'u gSaA
 Each question has FOUR options (1), (2), (3) and  izR;sd iz'u esa pkj fodYi (1), (2), (3) rFkk (4) gSaA bu
(4) ONLY ONE of these four option is correct pkjksa fodYiksa esa ls dsoy ,d fodYi lgh gSaA
 Marking scheme :  vadu ;kstuk :
 Full Marks : +4 If ONLY the correct option  iw.kZ vad % +4 ;fn flQZ lgh fodYi gh pquk x;k
is chosen. gSA
 Zero Marks : 0 If none of the options is  'kwU; vad % 0 ;fn dksbZ Hkh fodYi ugha pquk x;k
chosen (i.e. the question is unanswered). gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 Negative Marks : –1 In all other cases  _.k vad % –1 vU; lHkh ifjfLFkfr;ksa esaA
1. An isosceles triangle is to be cut from one 1. ,d leku nzO;eku ?kuRo okys oxZ ls lef}ckgq
edge of a square lamina of uniform mass f=kHkqtkdkj vkd`fr fp=kkuqlkj bl izdkj dkVh
density such that the remaining portion when
tkrh gS fd tc bls 'kh"kZ P ls yVdk;k tkrk gS
suspended from apex P of the cut will remain
in equilibrium in any position. The value of h rks ;g ges'kk lkE;koLFkk esa jgrk gS rks h dk eku
is. gS
 
 P P

h h
 2  2   2  2 
(1)     
  (1) 

2
  2 
 
3  2  3  2 
(2)     
  (2) 

2
  2 
 
3  3  3  3 
(3)       
  (3)  

2
  2 
 
 2  2   2  2 
(4)     
  (4) 

2
  2 
 
Space for Rough Work / (dPps dk;Z ds fy, LFkku)
®
2. Moment of inertia of a uniform solid cone 2. ,dleku Bksl 'kadq dk blds nzO;eku dsUnz ls
about an axis passing through its centre of xqtjus okyh rFkk blds vk/kkj ds lekUrj] v{k ds
gravity and parallel to its base is(m is mass of lkis{k tM+Ro vk?kw.kZ ('kadq dk nzO;eku m gS rFkk
cone, its height is h and its radius R = h)
bldh Å¡pkbZ h rFkk f=kT;k R = h gS) Kkr djks&
10
(1) MR2 10
3 (1) MR2
3
3
(2) MR2 3
5 (2) MR2
5
3
(3) MR2 3
10 (3) MR2
10
3 3
(4) MR2 (4) MR2
16 16
3. In the given figure the fixed pulley is smooth 3. fp=kkuqlkj fLFkj f?kjuh gYdh rFkk fpduh gS rFkk
and light where as movable pulley is rough
xfreku f?kjuh [kqjnjh gS rFkk dqN nzO;eku gSA
and has some mass. There is no slipping
f?kjuh rFkk jLlh esa dksbZ fQlyu ugh gS rks P
between the pulley and the string. Then
magnitude of acceleration of the point P on fcUnq ds Roj.k dk ifjek.k gS % (;fn CykWd a Roj.k
the movable pulley is. (If block is moving with
ls xfr djrk gS)
an acceleration a)
a
a
P
P
(1) a
(1) a
a
a (2)
(2) 2
2
(3) 2a (3) 2a
a a
(4) (4)
2 2
®
4. A capillary tube with very thin walls is held 4. ,d iryh nhokjks okyh ds'k ufydk e/; fcUnq ij
vertical and is attached to an end of a light fdyfdr gYdh NM+ ds ,d fljs ij Å/okZ/kj :Ik
horiozontal rod which is pivoted at its
midpoint. A mass is suspended through the
ls tqM+h gqbZ gSA NM+ ds nqljs fljs ij ,d nzO;eku
other end to keep the rod in horizontal bl izdkj j[kk tkrk gS] fd NM+ {kSfrt voLFkk esa
position. Now the lower end of the capillary jgsA vc ds'kuyh dk uhpyk fljk ty dh lrg ds
tube is just brought in contact with the
lEidZ esa yk;k tkrk gS rFkk ,d vfrfjDr nzO;eku
surface of water. An additional mass 0.157 g
is attached to the other end to keep the rod in 0.157 g dks nwljs fljs ij tksM+k tkrk gS rkfd NM+
horizontal position. What is the radius of the {kSfrt voLFkk esa jgsA ds'kufydk dh f=kT;k fdruh
capillary tube ? Surface tension of the water gSA ty dk i`"B ruko 0.075 N/m gS rFkk ty o
is 0.075 N/m. Contact angle between tube
and water is 0º. ufydk ds e/; lEidZ dks.k 0º gSA
(1) 3.3 mm (1) 3.3 mm
(2) 6.6 mm (2) 6.6 mm
(3) 9.9 mm (3) 9.9 mm
(4) 1.1 mm (4) 1.1 mm
5. Light rays from a very distant source travels 5. vuUr nwjh ij j[ks izdk'k L=kksr ls fdj.ks x-fn'kk essa
along +x direction and fall on two identical xfr djrs gq, nks irys ySlksa ftudh Qksdl nwjh
thin lenses with focal length F>0 and their
F > 0 gS] rFkk izdkf'k; v{k x-ds vuqfn'k gS] ij
optical axes along x-axis. One at x = 0 and
the other at x = d (< F). The rays will focus at vkifrr gksrh gSA ,d x = 0 rFkk nwljk x = d (< F) ij
x= j[kk gS rks fdj.ks fuEu eku ij Qksdl gksrh gS x =
F (F  d ) F (F  d )
(1) d (1) d
2F  d 2F  d
F (F  d ) F (F  d )
(2) d (2) d
d d
F (F  d ) F (F  d )
(3) d  (3) d 
2 (F  d ) 2 (F  d )
2 2
F F
(4) d  (4) d 
2 (F  d ) 2 (F  d )
6. A horizontal tube, open at both ends contains 6. nksuks fljks ij [kqyh {kSfrt ufydk fdlh nzo dk
a column of liquid. The length of this liquid
LrEHk j[krh gSA bl LrEHk dh yEckbZ rkieku ds
column does not change with temperature. If
 = co-efficient of volume expansion of liquid lkFk ifjofrZr ugh gksrh gSA ;fn vk;ru izlkj
and  = coefficient of linear expansion of the xq.kkad o js[kh; izlkj xq.kkad gS rks
material of the tube. Then
(1)  = 
(1)  = 
(2)  = 2 (2)  = 2
(3)  = 3 (3)  = 3
(4)  = 0 (4)  = 0
®
7. A coal based thermal power plant producing 7. ,d dkW;ys ij vk/kkfjr rkih; 'kfDr IykaV rkieku
electricity operates between the temperatures 27ºC rFkk 227ºC ds e/; /kkjk mRiUu djrk gSA
27ºC and 227ºC. The plant works at 80% of
Iykad viuh vf/kdre lS)kfUrd {kerk dk 80% dk;Z
its maximum theoretical efficiency. Complete
djrk gSA ;gk¡ 1 kg dks;ys ds iw.kZ tyus ij 3600
burring of 1 kg of coal yields 3600 KJ of heat.
A house needs 10 units of electricity each KJ Å"ek mRiUu gksrh gSA ;fn ,d ?kj dks 10 bdkbZ
day. Coal used for supplying the amount of /kkjk dh izfrfnu vko';drk gSA rc ?kj dks ,d o"kZ
energy for the house in one year is rd ÅtkZ nsus esa fdrus dks;ys dh vko';drk gksxh
(1) 1141 kg
(1) 1141 kg
(2) 580 kg (2) 580 kg
(3) 605 kg (3) 605 kg
(4) 765 kg (4) 765 kg
8. Initially spring is compressed by distance x0 8. izkjEHk esa fLizax ewy yEckbZ ls x0 lihfM+r gSA bl
from equilibrium position. At this compression
3K
3K
laihMu ij CykWd dks v = x0 osx fn;k tkrk
m
block is given velocity v = x0. So that
m
gS rkfd Lizhax es laihMu c<s rFkk CykWd ljy
the compression in the spring increases and
vkoZr xfr djsa (fLizax fu;rkad K) CykWd dh xfr
block start SHM (Spring constant K).
Equation of motion of block is. dh lehdj.k gSA
v v
K K
x0 x0
 K    K  
(1) y = y  3 x 0 sin  t   (1) y = y  3 x 0 sin  t  
 m 3   m 3 
   
 K    K  
(2) y  2 x 0 sin  t   (2) y  2 x 0 sin  t  
 m 6   m 6 
   
 K    K  
(3) y  3 x 0 sin  t   (3) y  3 x 0 sin  t  
 m 6   m 6 
   
 K    K  
(4) y  2 x 0 sin  t   (4) y  2 x 0 sin  t  
 m 3   m 3 
   
®
9. The frequency of sonometer wire is f, but 9. lksuksehVj rkj dh vko`fr f gS ijUrq ruko mRiUu
when the weight producing the tension is
djus okys Hkkj dks iw.kZ:Ik ls ty esa Mqcksus ij
completely immersed in water the frequency
f
f
vko`fr gks tkrh gS] fdlh vksj nzo esa Hkkj dks
2
becomes and on immersing the weight in
2
f
f Mqcksus ij vko`fr gks tkrh gS rks bl nzo dk
a certain liquid the frequency becomes . 3
3
The specific gravity of liquid is.

fof'k"V xq:Ro gS
4 4
(1) (1)
3 3
10 10
(2) (2)
9 9
15 15
(3) (3)
12 12
32 32
(4) (4)
27 27
10. A slightly tapering wire of length  and end 10. ,d FkksM+s Vsifjx rkj ftldh yEckbZ rFkk fljks
radii 'a' and 'b' is subjected to tension F. Y is dh f=kT;k;s 'a' rFkk 'b' gS] ij F ruko yxk;k tkrk
the Young's Modulus. The extension
gSA Y ;ax xq.kkad gSA rkj esa mRiUu izlkj gksxkA
produced in the wire is.
F
F (1)
(1)  Yab
 Yab
F ab
F ab (2)
(2) Y a
2
 b
2
2 2
Y a  b
F ab
F ab (3)
(3) Y a  b
Y a  b
F a  b
F a  b (4)
(4) 2 2
2 2 Y a  b
Y a  b
®
11. A non conducting ring of radius 4 cm has 11. 4 cm f=kT;k dh vpkyd oy; ij ifjofrZ js[kh;
varying linear charge density which is given vkos'k ?kuRo  = 3cos c/m gS rks oy; dk dqy
by  = 3cos c/m. The net electric dipole
f}/kqzo vk?kw.kZ gksxkA
moment of the ring is given by
 
(1) 48 Cm (1) 48 Cm

(2) 12 × 10–4 Cm (2) 12 × 10–4 Cm
(3) 12 Cm (3) 12 Cm
(4) 48 × 10–4 Cm (4) 48 × 10–4 Cm
12. A parallel beam of light of wavelength 5000 Å 12. 5000 Å rjaxnS/;Z dh lekUrj izdk'k fdj.ks fNnz S
is incident on slit S. Another two slit S1 and S2 ij vifrr gksrh gSA 2m nwjh ij fp=kkuqlkj j[kh nks
are illuminated at distance 2m as shown in
fNnz S1 rFkk S2 izdkf'kr gksrh gS rks S1 rFkk S2 ds
the figure. The minimum distance between S1
and S2 such that maximum intensity will occur
e/; U;qure nwjh D;k gksxh rkfd O ij vf/kdre
at O is. rhozrk izkIr gks
S1 S1
O O
S S2 S S2
2m 2m 2m 2m
Screen Screen
(1) 10 mm (1) 10 mm
(2) 1 mm (2) 1 mm
1 1
(3) mm (3) mm
2 2
(4) 5 mm (4) 5 mm
®
13. From ideal instruments current measured is 13. fdlh vknZ'k midj.kks ls ekih xbZ /kkjk I = 10.0
I = 10.0 A, potential difference measured is
A, foHkokUrj V = 100.0 oksYV, rkj dh yEckbZ 31.4
V = 100.0 volt, length of wire is 31.4 cm and
diameter of wire is 2.00 mm. The resistivity of cm rFkk rkj dk O;kl 2.00 mm. gS rks rkj dh
wire will be (in correct significant figures) izfrjks/kdrk gksxh (lgh lkFkZd vadks esas) ( = 3.14)
( = 3.14)
(1) 1.00 × 10–4  m
(1) 1.00 × 10–4  m
(2) 1.0 × 10–4  m
(2) 1.0 × 10–4  m
(3) 1 × 10–4  m (3) 1 × 10–4  m
(4) 1.000 × 10–4  m (4) 1.000 × 10–4  m
14. When the light of wavelength 400 nm is 14. tc 400 nm rjax nS/;Z dk izdk'k 2.3 eV
incident on a metal surface of work function dk;ZQyu okys /kkrq lrg ij vkifrr gksrk gS rks
2.3 eV photoelectrons are emitted. A fastest
izdk'k bysDVªkWu ckgj fudyrs gSA ,d lcls rst
photoelectron combines with a He2+ ion to
izdk'k bysDVªkWu He2+ vk;u ls tqM dj He+ vk;u
form He+ ion in its 3rd excited state and a
photon is emitted in this process. Then the cukrk gS tks rhljh mrsftr voLFkk es gksrk gS rFkk
energy of the photon emitted during ,d QksVksu bl izfØ;k es fudyrk gS] rks QksVksu
combination is. (Assume energy of He2+ to be dh ÅtkZ tks feyus ds nkSjku fudyrk gS] gksxh
zero) (He2+ dh ÅtkZ 'kqU; ekus)
(1) 4.2 eV
(1) 4.2 eV
(2) 5.7 eV (2) 5.7 eV
(3) 6.5 eV (3) 6.5 eV
(4) 6.8 eV (4) 6.8 eV
15. The combination of the gates in figure 15. fp=k es iznf'kZr }kjks dk la;kstu mRiUu djsxk %
produces
A
A
B
B
(1) AND }kj

(1) AND gate
(2) XOR gate (2) XOR }kj
(3) NOR gate (3) NOR }kj

(4) NAND gate (4) NAND }kj
®
16. A parent radioactive nucleus A (decay 16. ,d jsfM;ks lfØ; ukfHkd A ({k; fu;rkad A),
constant A) converts into a radioactive
jsfM;kslfØ; ukfHkd B ({k; fu;rkad B) es {kf;r
nucleus B of decay constant B. Initially
gksrk gSA B ds izkjfEHkd ukfHkdks dh la[;k 'kwU; gSA
number of nuclei of B is zero. At any time N A
and NB are number of atoms of nuclide A and
;fn NA o NB, A rFkk B ds ukfHkdks dh fdlh le;
B respectively then maximum value of NB is. la[;k gS rks NB dk vf/kdre eku gS %
 AN A  AN A
(1) (1)
B B
 BN A  BN A
(2) (2)
A A
 A   B N B  A   B N B
(3) (3)
B B
B B
(4) NA (4) NA
 A  B  A  B
17. The first diffraction minima due to a single slit 17. ,d fNnz foorZu ds fy, izFke fufEu"B  = 30º ij]
diffraction is at  = 30º for a light of 5000 Å rjax nS/;Z okys izdk'k ds fy, curk gS rks
wavelength 5000 Å. The width of the slit is
fNnz dh pkSM+kbZ gSA
(1) 5 × 10–4 cm
(1) 5 × 10–4 cm
(2) 1.0 × 10–4 cm
(2) 1.0 × 10–4 cm
(3) 2.5 × 10–4 cm (3) 2.5 × 10–4 cm
(4) 1.25 × 10–4 cm (4) 1.25 × 10–4 cm
18. During the propagation of electromagnetic 18. ,d ek/;e esa fo|qr pqEcdh; rjaxksa ds lapj.k ds
waves in a medium: nkSjku %
(1) Electric energy density is double of the
(1) fo|qrh; ÅtkZ ?kuRo pqEcdh; ÅtkZ ?kuRo dk
nqxquk gSA
(2) Electric energy density is half of the
(2) fo|qrh; ÅtkZ ?kuRo pqEcdh; ÅtkZ ?kuRo dk
vk/kk gSA
(3) Electric energy density is equal to the
(3) fo|qrh; ÅtkZ ?kuRo pqEcdh; ÅtkZ ?kuRo ds
(4) Both electric and magnetic energy
cjkcj gSA
densities are zero. (4) nksuksa fo|qrh; ,oa pqEcdh; ÅtkZ /kuRo 'kwU; gSA
®
19. A particle moves along x-axis in positive 19. x-v{k ds vuqfn'k /kukRed fn'kk esa xfr djrs gq;s
direction. Its acceleration 'a' is given as ,d d.k ds fy, Roj.k 'a' fn;k tkrk gS a = cx + d
a = cx + d, where x denotes the x-coordinate
tgk¡ x d.k dk x-funsZ'kkad iznf'kZr djrk gS] c rFkk
of particle, c and d are positive constants. For
d /kukRed fu;rkad gSA osx&foLFkkiu xzkQ fn[kk;s
velocity-position graph of particle to be of
type as shown in figure, the value of speed of x;s fp=kkuqlkj gksus ds fy, x = 0 ij d.k dh pky
particle at x = 0 should be. dk eku gksuk pkfg, &
2 2
4d 4d
(1) (1)
c c
2 2
d d
(2) (2)
c c
2 2
2d 2d
(3) (3)
c c
2 2
8d 8d
(4) (4)
c c
20. In a large building, there are 15 bulbs of 40W, 20. ,d o`gr Hkou esa, 40W ds 15 cYc, 100 W ds 5
5 bulbs of 100 W, 5 fans of 80 W and 1 cYc, 80 W ds 5 ia[ks ,oa 1 kW dk 1 ghVj gSA
heater of 1 kW. The voltage of the electric
fctyh ds esUl dh oksYVrk 220 V gSA Hkou ds
mains is 220 V. The minimum capacity of the
main fuse of the building will be:
eq[; ¶;qt dh U;wure {kerk gksxh%
(1) 8 A (1) 8 A
(2) 10 A (2) 10 A
(3) 12 A (3) 12 A
(4) 14 A (4) 14 A
®
SECTION – 2 : (Maximum Marks : 20) [kaM 2 ¼vf/kdre vad% 20)
 This section contains FIVE (05) questions. The  bl [kaM esa ik¡p (05) iz'u gSA izR;sd iz'u dk mÙkj
answer to each question is NUMERICAL VALUE

la[;kRed eku (NUMERICAL VALUE) gSa] tks
f}&vadh; iw.kkZad rFkk n'keyo ,dy&vadu eas gSA
 ;fn la[;kRed eku esa nks ls vf/kd n’'keyo LFkku gS ]
rks la[;kRed eku dks n'keyo ds nks LFkkuksa rd
VªadsV@jkmaM vkWQ (truncate/round-off) djsaA
decimal placed.
 vadu ;kstuk :
 Full Marks : +4 If ONLY the correct option is
 iw.kZ vad % +4 ;fn flQZ lgh fodYi gh pquk x;k
chosen. gSA
21. A uniform rod of length L and mass M is 21. ,d L yEckbZ o M nzO;eku dh le:Ik NM+ {kSfrt
placed on a smooth horizontal surface. The
rod is hinged at the end A and is free to
fpduh lrg ij j[kh gSA NM+ ,d fljs ij A fcUnq
rotate in horizontal plane about a vertical axis ij fdyfdr gS rFkk A ls xqtjus okyh Å/okZ/kj v{k
passing through A. As shown in figure there
L ds lkis{k ?kweus ds fy, LorU=k gSA fp=kkuqlkj A
is a nail N at a perpendicular distance
4
3L
from end A of rod. At t = 0 and impulse P0 is fljs ls yEcor~ nwjh ij ,d vkosx P0 yxk;k
4
3L
applied at a distance from end A. The
4 tkrk gSA vkosx {kSfrt o NM+ ds yEcor~ gSA
impulse is in the horizontal plane and is
8  ML
8  ML t  ij NM+ iqu% izkjfEHkd fLFkfr ij vk
perpendicular to the rod. At t  , the 27 P 0
27 P 0
rod returns to its initial position. If the impulse tkrh gSA ;fn fdy }kjk NM+ ij yxk;s x, cy dk
of the force exerted by the nail on the rod is
390 P 0
390 P 0 vkosx gS rks x dk eku gSS
, then value of x is x
x
N N
L/4 L/4
A 3L/4 P0 A 3L/4 P0
®
22. An open rectangular tank of height 3m and 22. ,d [kqys vk;rkdkj VSad es ftldh ÅpkbZ 3m o
length and width respectively 5m and 3m
5m gS] 2m dh ÅpkbZ rd ty Hkjk gSA ;fn ;g
contains water upto height 2m. It is
accelerated horizontaly along the longer side. yEch Hkqtk ds vuqfn'k Rofjr gksrk gSA Roj.k dk eku
The acceleration that tank can be given so
108
(m/s2 esa) gS] ftlds fy, 10% ty ckgj vk
108 N
that 10% of water spills out is (in m/s2),
N
then the value of N is : (g = 10 m/s2) tkrk gS] rks N dk eku gS : (g = 10 m/s2)
23. A source of sound is moving along a circular 23. ,d /ofu L=kksr 3 m dh f=kT;k ds o`r ij 10 rad/s
orbit of radius 3 m with angular velocity of 10
ds dks.kh; osx ls ?kwe jgk gSA ,d /ofu lalqpd tks
rad/s. A sound detector located far away from
BD js[kk ds vuqfn'k ljy vkoZrxfr dj jgk gS]
the source is executing SHM along the line
BD with amplitude BC = CD = 6 m. The ftlds fy, BC = CD = 6 m vk;ke gS] cgqr nwj
5
frequency of oscillation of the detector is 5
 j[kk gqvk gSA lalqpd dh vko`fr izfr lsd.M gSA

per second. The source is at the point A

L=kksr A fcUnq ij gS tc lalqpd B ij gSA ;fn
when detector is at the point B. If the source
emits a sound of frequency 340 Hz. If the L=kksr dh vko`fr 340 Hz gS rks lalqpd }kjk izsf{kr
minimum frequency recorded by the detector dh xbZ U;qure vko`fr 10 x (Hz esa) gS rks x dk eku
(velocity of sound = 330 m/s) is 10 x (in Hz)
gS % (/ofu dk osx = 330 m/s)
then value of x is :
A A
B C D B C D
®
24. Inside a uniformly charged infinitely long 24. R f=kT;k ds le:Ik vkosf'kr vkos'k ?kuRo okys
cylinder of radius R and volume charge
R
density . There is a spherical cavity of radius
vuUr csyu ds vUnj f=kT;k dh xksykdkj
2
R
2
. A point P is located at a distance 2R from xqfgdk gSA fp=kkuqlkj ,d fcUnq P csyu dh v{k ls
the axis of the cylinder as shown. The electric xR

2R nwjh ij gSA P fcUnq ij fo|qr {kS=k gS rks
54  0
xR
field strength at the point P is , where
54  0
x dk eku gSA
value of x is :
R
R
R/2 R
R/2 R P
P O
O
25. In the circuit shown, the switch 'S' is closed at 25. fn[kk;s x, fp=k esa t = 0 ij dqWth S dks pkyq dj
t = 0, then current through the battery after

fn;k tkrk gS rks LFkkbZ voLFkk ds Ik'pkr~ cSVjh ls
126
steady state is reached is Ampere,
x 126
izokfgr /kkjk ,Eih;j gS] tgkW x dk eku gS :
x
where value of x is :
4 2 1F 1F

4 2
2F 4 5mH 2F 4 5mH
6 3 6 3
24V 24V
®
PART – B PART – B
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, Atomic masses : [H = 1, D = 2, Li = 7, C = 12,
N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27,
Si = 28, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Si = 28, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40,
Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65,
As = 75, Br = 80, Ag = 108, I = 127, Ba = 137, As = 75, Br = 80, Ag = 108, I = 127, Ba = 137,
Hg = 200, Pb = 207] Hg = 200, Pb = 207]

 vadu ;kstuk :
is chosen.
gSA
chosen (i.e. the question is  'kwU; vad % 0 ;fn dksbZ Hkh fodYi ugha pquk x;k
unanswered). gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
26. Which of the following statements is correct 26. 2 ok;qe.Myh; nkc rFkk 27° C rki ij xSl A ds
for gas A having molar mass 16 g and fy,] ftldk eksyj nzO;eku 16 g rFkk ?kuRo
density 0.75 g/L at 2 atm pressure and 27°C 0.75 g/L gS] fuEu esa ls dkSulk dFku lR; gS\
temperature. (1) xSl ds v.kqvksa ds e/; izfrd"kZ.k cy dh rqyuk
(1) Force of attraction are dominating than esa vkd"kZ.k cy iz/kku@vf/kd izHkkoh
force of replusion among the gas
(dominating) gSA
molecules.
(2) xSl ds v.kqvksa ds e/; vkd"kZ.k cy dh rqyuk
(2) Force of repulsion are dominating than
esa izfrd"kZ.k cy iz/kku@vf/kd izHkkoh
force of attraction among the gas
(dominating) gSA
molecules.
(3) xSl ds v.kq vkn'kZ O;ogkj dj jgs gSA
(3) Gas molecules are behaving ideally
(4) fuf'prrk ls dqN dgk ugha tk ldrkA
(4) Nothing can be said with certainity
Space for Rough Work / (dPps dk;Z ds fy, LFkku )
27. Ratio of Tb / Kb for 6% (W/V) AB2 is 1 mol/kg 27. Tb / Kb dk vuqikr] 6% (W/V) AB2 ds fy,
and also for 9% (W/V) A2B it is 1 mol/kg 1 eksy@kg gS rFkk 9% (W/V) A2B ds fy, Hkh
(AB2 and A2B both are non-electrolytes). 1 eksy@kg gS ¼AB2 rFkk A2B nksuksa oS|qr
Hence, atomic masses of A and B are vu&vi?kV~; gSa½A bl izdkj A rFkk B ds ijek.kq
respectively : (assume molality = molarity)
nzO;eku Øe'k% gSa % ¼ekuk eksyyrk = eksyjrk½
(1) 60, 90
(1) 60, 90
(2) 40, 40 (2) 40, 40
(3) 40, 10 (3) 40, 10
(4) 10, 40 (4) 10, 40

28. A hydrogen electrode is immersed in a 28. ,d gkbMªkstu bysDVªkWM dks pH = 0 (HCl) okys
solution with pH = 0 (HCl). By how much will foy;u esas Mwcks;k tkrk gS] rks foHko (vip;u)
the potential (reduction) change if an ifjorZu fdruk gksxk] ;fn foy;u esa NaOH dh
equivalent amount of NaOH is added to the
rqY;kad ek=kk feyk;h tkrh gS\ (yhft, pH
2
= 1
solution. (Take pH = 1 atm & T = 298 K).
2
atm rFkk T = 298 K).
(1) increase by 0.41 V
(1) 0.41 V c<+sxk
(2) increase by 59 mV (2) 59 mV c<+sxk
(3) decrease by 0.41 V (3) 0.41 V ?kVsxk
(4) decrease by 59 mV (4) 59 mV ?kVsxk
v ' kq) ' kq)

A B Zn C A B C
29. ZnCO3   ZnO     29. ZnCO3   ZnO   Z n   Z n A,
( impure )
Zn B rFkk C dk lgh feyku gS&

correct coding of A, B & C is
( pure )
(A) (B) (C) (A) (B) (C)

(1) fuLrkiu dksd izHkkth vklou
(1) Calcination Coke Fractional
distillation (2) fuLrkiu dkcZu izHkkth vklou
(2) Calcination Carbon Fractional eksuksvkWDlkbM
monoxide distillation
(3) fuLrkiu oS|qrvi?kVu nzohdj.k
(3) Calcination Electrolysis Liquation
(4) Roasting Coke Poling (4) HktZu dksd n.M foyksMu
30. Two mole of an ideal gas is expanded 30. ,d vkn'kZ xSl ds nks eksy 37ºC ij] vuqRØe.kh; o
irreversibly and isothermally at 37ºC until its
lerkih; :i ls nqxus vk;ru rd izlkfjr gksrs gS
volume is doubled and 3.41 kJ heat is
o ifjos'k ls 3.41 kJ Å"ek dk vo'kks"k.k gksrk gSA
absorbed from surrounding. Stotal (system +
Sdqy ¼fudk; $ ifjos'k½ gSa %
surrounding) is :
(1) –0.52 J/K (2) 0.52 J/K (1) –0.52 J/K (2) 0.52 J/K
(3) 22.52 J/K (4) 0 (3) 22.52 J/K (4) 0
31. Bromine water reacts with SO2 to form : 31. czksehu ty] SO2 ds lkFk fØ;k dj cukrk gS &
(1) H2O and HBr (2) HBr and S (1) H2O o HBr (2) HBr o S
(3) H2SO4 and HBr (4) S and H2O

(3) H2SO4 o HBr (4) S o H2O
32. A reaction at 300 K with G° = – 1743 J /mol 32. 300 K rki ij ,d vfHkfØ;k ftlesa A(g) ds 3eksy]
consists of 3 mole of A(g), 6 mole of B(g) and B(g)ds 6 eksy rFkk C(g) ds 3 eksy lfEefyr gS]
3 mole of C(g). If A, B and C are in equilbrium ds fy,G° dk eku – 1743 J /mol gSA ;fn A, B
in 1 litre container then the reaction may be rFkk C ,d yhVj ds ik=k esa lkE; ij gS] rks laHkkfor
[Given : 2 = e0.7, R = 8.3 J/K - mol] vfHkfØ;k gS&
(1) A + B C [fn;k gS : 2 = e0.7, R = 8.3 J/K - mol]
(2) A B + 2C (1) A + B C
(2) A B + 2C
(3) 2A B+C
(3) 2A B+C
(4) A + B 2C
(4) A + B 2C
33. Which of the following hydrolysis reaction is 33. fuEu es ls dkSulh tyvi?kVu vfHkfØ;k e/;e rki
incorrect at moderate temperature? ij xyr gS \
(1) 4BF3 + 3H2O  H3BO3 + 3HBF4 (1) 4BF3 + 3H2O  H3BO3 + 3HBF4
(2) 2NF3 + 3H2O  N2O3 + 6HF (2) 2NF3 + 3H2O  N2O3 + 6HF
(3) NCl3 + 3H2O  NH3 + HOCl (3) NCl3 + 3H2O  NH3 + HOCl
(4) BiCl3 + H2O  BiOCl  + 2HCl (4) BiCl3 + H2O  BiOCl  + 2HCl
34. A radioactive isotope zXA is converted into 34. ,d jsfM;kslfØ; leLFkkfud zXA] -{k; ds }kjk
Z - 8Y
A – 16 by -decay. If 1 gram-atom zXA,
Z - 8Y
A – 16 es ifjofrZr gksrk gSA ;fn 1 xzke ijek.kq
produced 3 mol 2He4 in 34.65 hour then
zX
A, 34.65 ?k.Vs esa 3 eksy 2He4 mRikfnr djrk gS]
disintegration constant of zXA is (in hr-1) is :
(1) 8 × 10-2
rks zXA dk fo?kVu fu;rkad ¼hr-1 esa ½ gS &
(2) 4 × 10-2 (1) 8 × 10-2
(2) 4 × 10-2
(3) 2 × 10-2
(3) 2 × 10-2
(4) 3.6 × 10-3
(4) 3.6 × 10-3

35. Which of the following is incorrect match ? 35. fuEu esa ls dkSulk xyr lqesfyr gS \
(1) Z = 48, group No. = 12, period No. = 5
(1) Z = 48, oxZ la[;k = 12, vkorZ la[;k = 5
(2) [Xe]4f7 5d1 6s2, group No. = 3, period
No. = 6 (2) [Xe]4f7 5d1 6s2, oxZ la[;k = 3, vkorZ la[;k = 6
(3) [Rn] 6d2 7s2, group No. = 4, period

(3) [Rn] 6d2 7s2 , oxZ la[;k = 4 , vkorZ la[;k = 7
No. = 7
(4) Z = 56, oxZ la[;k = 2, vkorZ la[;k = 6
(4) Z = 56, group No. = 2, period No. = 6
36. S1 : On adding acid to aqueous solution of 36. S1 : K2CrO4 ds tyh; foy;u esa vEy feykus ij]
K2CrO4, its colour changes from yellow to
bldk jax ihys ls ukjaxh jax esa ifjofrZr gksrk gSA
orange.
2 2
2 2
S2 : CrO 4 rFkk Cr 2 O 7 pH 2 ls 6 rd dh
S2 : CrO 4 and Cr 2 O 7 exist in equilibrium
over wide range of pH from 2 to 6. foLr`r ijkl ij lkE; esa fo|eku gksrs gSA
(1) Statement-1 is correct statement-2 is not (1) dFku-1 lgh gS rFkk dFku-2, dFku-1 dk lgh
Li"Vhdj.k ugha gSA
(2) Statement-1 is correct statement-2 is also
(2) dFku-1 lgh gS rFkk dFku-2, dFku-1 dk lgh
(3) Statement-1 is correct statement-2 is not Li"Vhdj.k Hkh gSA

correct.
(3) dFku-1 lgh gS rFkk dFku-2 lgh ugha gSA
(4) Statement-1 is not correct and statement-
(4) dFku-1 lgh ugha gS rFkk dFku-2 lgh gSA
2 is correct.
37. Which of the following statements regarding 37. fuEu esa ls dkSulk dFku flfydkWu ds lanHkZ esa lgh
silicones is not correct. ? ugha gS\
(1) Silicones have good thermal stability.
(1) flfydkWu vPNk rkih; LFkkf;Ro j[krs gSaA
(2) Liquid silicones are lubricants.
(2) nzo flfydkWu Lusgd (lubricants) gksrs gSaA
(3) Silicones are chemically inert substances.
(3) flfydkWu jklk;fud :i ls vfØ; inkFkZ gSA
(4) Silicones are hydrophilic in nature.
(4) flfydkWu tyLusgh izÑfr ds gksrs gSA
38. Identify the correct order in which bond order 38. lgh Øe igpkfu,] ftlesa ca/k Øe c<+rk gS&
is increasing in the following.
 2 
(1) NO < O 2 < C 2 < He 2
 2 
(1) NO < O 2 < C 2 < He 2
 2 
 2  (2) O 2 < NO < C 2 < He 2
(2) O 2 < NO < C 2 < He 2
2  
(3) C
2
< He

< O

< NO (3) C 2 < He 2 < O 2 < NO
2 2 2
  2   2
(4) He 2 < O 2 < NO < C 2 (4) He 2 < O 2 < NO < C 2
39. The reactants X & Y of the following reaction 39. fuEu vfHkfØ;k ds fØ;kdkjd X rFkk Y gSa %
are HO O
HO O –
OH
X+Y   
H2O
–
OH
X+Y   
H2O
(1) + CH3CHO
(1) + CH3CHO
(2)
(2)
(3)
(3)
(4)
(4)
40. 0.2% solution of phenol acts as __________ 40. fQuksy dk 0.2% foy;u _______ ds leku rFkk
& 1% solution of phenol acts as _________ fQuksy dk 1% foy;u _______ ds leku dk;Z
(1) antiseptic, disinfectant djrk gSA
(2) disinfectant, antiseptic (1) iwfrjks/kh] dhVk.kquk'kd
(3) analgesic, disinfectant (2) dhVk.kquk'kd] iwfrjks/kh
(4) antipyretic, antiseptic (3) nnZuk'kd] dhVk.kquk'kd
(4) Tojuk'kh] iwfrjks/kh
41. The labels of two bottles containing 41. ;kSfxd I rFkk II ;qDr nks cksryksa dk ukekadu fdlh
compounds I and II were lost. The names of dkj.ko'k [kks tkrk gS ysfdu bu ;kSfxdksa ds uke
these compounds were available in a ,d jftLVj esa ntZ gSA ;kSfxd I rFkk II dh lajpuk
register. Following are structures of I and II.
uhps nh xbZ gSA bu ;kSfxdksa ds e/; foHksn djus ds
Which combination of reagents can help in
fy, fuEu esa ls dkSuls vfHkdeZd ;qXe dk mi;ksx
distinguishing these compounds?
fd;k tk ldrk gS \
(I) NaHCO3
(I) NaHCO3
(II) NaNO2 / HCl followed by -Naphthol in

(II) NaNO2 / HCl rRi'pkr~ tyh; NaOH es 
aq.NaOH
us¶FkkWy
(III) CHCl3 + NaOH
(III) CHCl3 + NaOH
(IV) Neutral FeCl3 (IV) mnklhu FeCl3
(1) I and II (1) I rFkk II
(2) III and IV

(2) III rFkk IV
(3) II and III

(3) II rFkk III
(4) I and IV
(4) I rFkk IV
42. The compounds 'X' and 'Y' formed in the 42. fuEu vfHkfØ;k es fufeZr ;kSfxd 'X' rFkk 'Y' gS&
following reaction are O
H+
O H
X+Y
H+
H
X+Y OH
OH
(1) leku HkkSfrd rFkk jklk;fud xq.kksa ;qDr
(1) hemiacetals with identical physical and
gseh,lhVsy
(2) leku HkkSfrd rFkk jklk;fud xq.kksa ;qDr

(2) acetals with identical physical and
,lhVsy
(3) fHkUu HkkSfrd rFkk jklk;fud xq.kksa ;qDr
(3) hemiacetals with different physical and
chemical properties. gseh,lhVsy

(4) acetals with different physical and
(4) fHkUu HkkSfrd rFkk jklk;fud xq.kksa ;qDr ,lhVsy
43. The major product of the following reaction 43. fuEu vfHkfØ;k vuqØe dk ize[q k mRikn gksxkA
sequence is Ph
(i) B2H6
Ph (ii) H2O2/NaOH
(i) B2H6
(ii) H2O2/NaOH (iii) conc. H2SO4, 
Me
(iii) conc. H2SO4, 
Me
Ph Ph
Ph Ph
(1) (2)
(1) (2)
Me
Me
Ph Ph
Ph Ph
(3) (4)
(3) (4)
Me OH
Me OH
44. Identify the Y and Z in the following reaction. 44. fuEu vfHkfØ;k esa Y ,oa Z dks igpkfu;s&
NH2 NH2
NaNO , HCl  CHCl
   2   X   Y 
3
 Z NaNO , HCl  CHCl
H 2 O , 5º C H 2O NaOH
   2   X   Y 
3
 Z
H 2 O , 5º C H 2O NaOH
OH OH OH OH
CHO CHO
(1) Y = Z= (1) Y = Z=
CHO CHO
(2) Y = Z= (2) Y = Z=
+ –
N2Cl CHCl2 + –
N2Cl CHCl2
(3) Y = Z= (3) Y = Z=
OH O–CHO OH O–CHO
(4) Y = Z= (4) Y = Z=
45. Consider the following reactions 45. fuEufyf[kr vfHkfØ;kvksa dk izs{k.k dhft;sA
NaBH4
(I) D-Glucose     X NaBH4
(I) D-Xywdkst     X
NaBH4
(II) D-Mannose     Y NaBH4
(II) D-esuksl     Y
NaBH4
(III) D-Fructose     Products NaBH4
(III) D-ÝqDVksl     mRikn
The product/s in reaction (III) is / are vfHkfØ;k (III) esa mRikn gS+/ gSa &
(1) X only
(1) dsoy X
(2) Y only
(2) dsoy Y
(3) Neither X nor Y
(3) u rks X vkSj ugha Y
(4) Both X and Y
(4) X vkSj Y nksuksa
 bl [kaM esa ik¡p (05) iz'u gSA izR;sd iz'u dk mÙkj
 ;fn la[;kRed eku esa nks ls vf/kd n’'keyo LFkku gS ]
rks la[;kRed eku dks n'keyo ds nks LFkkuksa rd
VªadsV@jkmaM vkWQ (truncate/round-off) djsaA
decimal placed.
 vadu ;kstuk :
is chosen. gSA
46. The given reaction is an important step in 46. HNO3 ds fuekZ.k ds fy, vksLVokWYM fof/k esa uhps
Ostwald’s method for manufacturing of HNO3. nh xbZ vfHkfØ;k ,d egRoiw.kZ in gSA ;fn ge
If we start with 6.8 g of NH3 and 40 g of O2, vfHkfØ;k] 6.8 g NH3 o 40 g O2 ls izkjEHk djrs
then what mass % of excess reagent will be gksa] rks vkf/kD; esa fy;s x;s vfHkdeZd dk fdruk
left behind ? % 'ks"k jg tk;sxk \
NH3 + O2   NO + H2O
NH3 + O2   NO + H2O
47. 2665 mg of an octahedral complex 47. ,d v"VQydh; ladqy CrCl3.6H2O ds

CrCl3.6H2O needs 3.4 g of AgNO3 for 2665 ehyh xzke esa blds lHkh eqDr DyksjkbM
complete precipitation of its all the free vk;uksa ds iw.kZ vo{ksi.k ds fy, AgNO3 ds 3.4g
chloride ions. If the given complex is vko';d gksrs gSaA ;fn fn;s x;s ladqy dk
subjected to dehydration then the weight
futZyhdj.k djk;k tk,] rc izkIr vuknZz ladqy dk
(in g) of anhydrous complex obtained will be?
Hkkj ¼xzke esa½ D;k gksxk \
Report your answer by rounding off upto one
decimal place.
48. In FCC structure the total number of voids in 48. FCC lajpuk esa 0.6 eksy ;kSfxd esa fjfDrdkvksa dh
0.6 mol of compound is x(1023). What is the dqy la[;k x(1023) gSA 'x' dk eku D;k gS?
value of 'x' ? {NA = 6×1023/mol} {NA = 6×1023/mol}
49. Reaction of phenol with NaOH followed by 49. fQukWy dh NaOH ds lkFk vfHkfØ;k djkus ds
heating with CO2 under high pressure, and i'pkr~ CO2 ds lkFk mPp nkc ij xeZ fd;k tkrk
subsequent acidification gives compounds X gS rRi'pkr~ vEyhdj.k djus ij ,d eq[; ;kSfxd
as the major product, which can be purified
X curk gS tks fd Hkki vklou }kjk 'kksf/kr fd;k
by steam distillation. When reacted with
tk ldrk gSA ;kSfxd X dks lkanz H2SO4 dh lw{e
acetic anhydride in the presence of a trace
ek=kk es ,lhfVd ,ugkbMªkbM ds lkFk fØ;k djkus
amount of conc. H2SO4 compound X
ij ,d eq[; ;kSfxd Y mRikfnr gksrk gSA
produces Y as the major product. If
;fn vfUre mRikn (Y) dk v.kqHkkj M gks] rks viuk
molecular mass of the final product (Y) is M
mÙkj M/10 ds :i es fyf[k,A
then report your answer as M/10.
50. How many Natural Occurring Essential - 50. izkÑfrd :i ls ik;s tkus okys vko';d -,ehukas
amino acids has aromatic ring in side chain? vEy fdrus gksxsa] ftudh ik'oZ J`a[kyk es ,sjksesfVd
oy; mifLFkr gks\
PART – C Hkkx – C
 Marking scheme :  vadu ;kstuk :
 Full Marks : +4 If ONLY the correct option  iw.kZ vad % +4 ;fn flQZ lgh fodYi gh pquk x;k
is chosen.
gSA
 'kwU; vad % 0 ;fn dksbZ Hkh fodYi ugha pquk x;k
chosen (i.e. the question is
gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
unanswered).
51. The area bounded by the curves y = 6x – x2 51. oØksa y = 6x – x2 vkSj y = x2 – 2x ls ifjc)
and y = x2 – 2x is {ks=kQy gS -
64
(1) 64
6 (1)
6
64
(2) 64
3 (2)
3
(3) 22 (3) 22
(4) 21 (4) 21
z – 5i
52. The complex number z = x + iy which satisfy 52. lfEeJ la[;k z = x + iy tks lehdj.k =1
z  5i
z – 5i
the equation = 1 lies on dks larq"B djrs gS] fLFkr gS -
z  5i
(1) okLrfod v{k ij

(1) the real axis
(2) the straight line y = 5 (2) ljy js[kk y = 5 ij
(3) a circle passing through origin (3) (0, 0) ls xqtjus okys o`Ùk ij
(4) the imaginary axis (4) dkYifud v{k ij
MJRAIOT1291219C1-24
53. If x = 5 and y = –2 then x – 2y = 9. The 53. ;fn x = 5 rFkk y = –2 gS] rks x – 2y = 9 bl dFku
contrapositive of this statement is dk çfrifjofrZr gS&
(1) If x – 2y = 9 then x = 5 and y = –2 (1) ;fn x – 2y = 9 rc x = 5 rFkk y = –2
(2) If x – 2y  9 then x  5 and y  –2 (2) ;fn x – 2y  9 rc x  5 rFkk y  –2
(3) If x – 2y  9 then x  5 or y  –2 (3) ;fn x – 2y  9 rc x  5 ;k y  –2
(4) If x – 2y  9 then either x  5 or y = –2 (4) ;fn x – 2y  9 rc ;k rks x  5 ;k y = –2
54. If the roots of the equation x2 –2ax + a2 + a – 3 = 0 54. ;fn lehdj.k x2 – 2ax + a2 + a – 3 = 0 ds ewy
are real and less than 3 then okLrfod gS rFkk 3 ls de gS rc -
(1) a < 2 (1) a < 2
(2) 2  a  3 (2) 2  a  3
(3) 3 < a  4 (3) 3 < a  4
(4) a > 4 (4) a > 4
55. If log2(a + b) + log2(c + d)  4 then minimum 55. ;fn log2(a + b) + log2(c + d)  4 rc a + b + c + d

value of a + b + c + d is dk U;wure eku gS -
(1) 2
(1) 2
(2) 4 (2) 4
(3) 6 (3) 6
(4) 8 (4) 8
56. How many five letter words are to be formed 56. 'kCn INFINITESIMAL ds v{kjksa ls ik¡p v{kjks ds
out of the letters of the word INFINITESIMAL fdrus 'kCn cuk, tk ldrs gS -
(1) 22640 (1) 22640
(2) 22650 (2) 22650
(3) 22660 (3) 22660

(4) 22670
(4) 22670
MJRAIOT1291219C1-25
57. The system of equations 57. lehdj.kksa
x + y + z =  – 1 x + y + z =  – 1
x + y + z =  – 1 x + y + z =  – 1
x + y + z =  – 1 x + y + z =  – 1
has no solution if  is equal to ds fudk; dk dksbZ gy ugh gS ;fn  =

(1) 2 (1) 2
(2) 1 (2) 1
(3) – 2 (3) – 2
(4) 1, –2 (4) 1, –2
58. In a ABC, angles A,B,C are in 2 : 3 : 4 58. ABC esa, dks.k A,B,C Øe'k% 2 : 3 : 4 esa gS] rc
respectively then the cosA is equal to cosA dk eku cjkcj gS&
b
(1) b
2a (1)
2a
c
(2) (2)
c
2a
2a
3a
(3) 3a
2b
(3)
2b
3b 3b
(4) (4)
2c 2c
59. The number of points at which the function 59. fcUnqvksa dh la[;k gksxh tcfd Qyu
f(x) = (x – |x|)2(1– x + |x|)2 is not differentiable f(x) = (x – |x|)2(1– x + |x|)2 vUrjky (–3, 4) esa
in the interval (–3, 4) is vodyuh; ugh gS -
(1) Zero (1) 'kwU;
(2) One (2) ,d
(3) Two (3) nks
(4) Three (4) rhu
MJRAIOT1291219C1-26
60. The line passing through the extremity A of 60. nh?kZo`Ùk x2 + 9y2 = 9 ds nh?kZv{k ds fljs A rFkk
the major axis and extremity "B" of the minor
y?kqv{k ds fljs B ls xqtjus okyh js[kk lgk;d o`Ùk
axis of the ellipse x2 + 9y2 = 9 meets its
auxiliary circle at the point M. Then the area dks fcUnq M ij feyrk gS rc f=kHkqt ftlds 'kh"kZ A,
of the triangle with vertices at A, M and the M vkSj ewyfcUnq gS dk {ks=kQy gS -
origin.
31
31 (1)
(1) 10
10
29
29 (2)
(2) 10
10
21
21 (3)
(3) 10
10
27
27 (4)
(4) 10
10
61. The sum of the squares of deviations for 10 61. 10 izs{k.kksa ds fy, muds ek/; 50 ls fy;k x;k
observations taken from their mean 50 is 250. fopyuksa ds oxksZ dk ;ksxQy 250 gS rc pfjrk
The coefficient of variation is xq.kkad gS -
(1) 10% (1) 10%
(2) 40% (2) 40%
(3) 50% (3) 50%
(4) 0.1% (4) 0.1%
62. The sides of a triangle are 62. f=kHkqt dh Hkqtk,a
(b
2 2
 c ), (c
2 2
 a ), (a
2 2
 b ), where a, b, (b
2 2
 c ), (c
2 2
 a ), (a
2 2
 b ), gS
c > 0. The area of triangle is given by tgk¡ a, b, c > 0 rc f=kHkqt dk {ks=kQy gS -
1 2 2 1 2 2
(1) b c (1) b c
2 2
1 4 1 4
(2) a (2) a
2 2
3 3 2 2
(3) b c
2 2
(3) b c
2 2
3
(4)
3
 bc  (4)  bc 
2 2
MJRAIOT1291219C1-27
63. A point equidistant from the lines 4x + 3y + 10 = 0, 63. js[kkvksa 4x + 3y + 10 = 0, 5x – 12y + 26 = 0 vkSj
5x – 12y + 26 = 0 and 7x + 24y – 50 = 0 is 7x + 24y – 50 = 0 ls cjkcj nqjh ij fLFkr fcUnq gS -
(1) (1, –1)
(1) (1, –1)
(2) (1, 1)
(2) (1, 1)
(3) (0, 0) (3) (0, 0)
(4) (0, 1) (4) (0, 1)
64. Tangents are drawn from the point (a, a) to 64. fcUnq (a, a) ls o`Ùk x2 + y2 – 2x – 2y – 6 = 0 ij
the circle x2 + y2 – 2x – 2y – 6 = 0. If the Li'kZ js[kk,a [khph tkrh gS ;fn Li'kZ js[kkvksa ds e/;
angle between the tangents lie in the range
  
  
dk dks.k]  ,  esa gS rc a dk ekuksa dk fu''ks"kh
 ,  , then the exhaustive range of values 3 
3 
(lEiw.kZ) ifjlj gS -
of a is -
(1) (1, ) (1) (1, )
(2) (–5, –3)  (3, 5) (2) (–5, –3)  (3, 5)
(3) (–2 2 , –1)  (3, ) (3) (–2 2 , –1)  (3, )
(4) (–3, –1)  (3, 5) (4) (–3, –1)  (3, 5)
65. A tangent and a normal are drawn at the 65. ijoy; y2 = 16x ds fcUnq P(16, 16) ij Li'kZ js[kk
point P(16, 16) of the parabola y2 = 16x which o vfHkyEc js[kk tks ijoy; dh v{k dks Øe'k A
cut the axis of the parabola at the point A and
rFkk B ij dkVrh gS ;fn P, A vkSj B ls xqtjus
B respectively. If the center of the circle
okyk o`Ùk C gS rc PC vkSj x-v{k ds e/; U;wu
through P, A and B is C, then acute angle
dks.k gS -
between PC and axis of x is
1 1
1 1 (1) tan
(1) tan 2
2
(2) tan–1 2
(2) tan–1 2
1 3
1 3 (3) tan
(3) tan 4
4
1 4
1 4 (4) tan
(4) tan 3
3
MJRAIOT1291219C1-28
66. Minimum distance between the curves 66. oØksa y = x2 + x + 1 rFkk x = y 2 + y + 1 ds e/;
y = x2 + x + 1 and x = y 2 + y + 1 is U;wure nwjh gS &
(1) 2
(1) 2
(2) 2 2
(2) 2 2
1 1
(3) (3)
2 2
(4) 2 (4) 2
   
67. Unit vector c is inclined at an angle  to unit 67. bdkbZ lfn'k c bdkbZ lfn'k a vkSj b tks ,d
 
nqljs ls yEcor~ gS ds lkFk dks.k ij >qds gq, gS
vectors a and b which are perpendicular to
    
    
;fn c = ( a + b ) + µ( a × b ) tgk¡ µ, 
each other. If c = ( a + b ) + µ( a × b )
where µ,  are real then  belongs to - okLrfod gS rc  fLFkr gS -
   
(1) (1) 0, 
0,   2
 2
   
(2)  ,
(2)  ,
 2   2 
  3 
  3  (3)
(3)  , 
 ,  4 4 
4 4 
 
  (4)  , 
(4)  ,  4 2
4 2
x  3 y  2 z 1
68. Two lines whose equation are 68. nks js[kk,a ftuds lehdj.k  
2 3 
x  3 y  2 z 1
 
 x  2 y  3 z  2
2 3
vkSj   ,d gh lery ij gS]
3 2 3
x  2 y  3 z  2
and   lie in the same
3 2 3 rc sin–1sin dk eku cjkcj gS&
plane then the value of sin–1sin is equal to
(1) 3
(1) 3
(2)   3
(2)   3
(3) 4 (3) 4
(4)  – 4 (4)  – 4
MJRAIOT1291219C1-29
x x
69. Let f(x)   

 { 1  | 1  t |} dt , x  2
69. ekuk f(x)   
 { 1  | 1  t |} dt , x  2
0 0
 5 x  7, x  2  5 x  7, x  2
Then f(2) is - rc f, x = 2 ij gS -
(1) continuous but not differentiable

(1) lrr ijUrq vodyuh; ugh
(2) continuous and differentiable (2) lrr~ vkSj vodyuh;
(3) non continuous and non differentiable (3) vlrr~ rFkk vodyuh; ugh
(4) Differentiable but not continuous (4) vodyuh; ijUrq lrr~ ugh
9
3  3 1 
70. The sum of the coefficients of x and x2 in the 70. 2
(1 + x + 2 x )  x  
ds foLrkj esa x vkSj x2 ds
2 3x 
9
3  3 1 
expansion of 2
(1 + x + 2 x )  x  
is
2 3x  xq.kkadksa dk ;ksxQy gS&
7
(1) 7
18 (1)
18
7 7
(2)  (2) 
18 18
7 7
(3) (3)
24 24
7 7
 (4) 
(4) 24
24
MJRAIOT1291219C1-30
 bl [kaM esa ik¡p (05) iz'u gSA izR;sd iz'u dk mÙkj
 If the numerical value has more than two decimal  ;fn la[;kRed eku esa nks ls vf/kd n’'keyo LFkku gS ]
places truncate/round-off the value to ONE rks la[;kRed eku dks n'keyo ds nks LFkkuksa rd
decimal placed. VªadsV@jkmaM vkWQ (truncate/round-off) djsaA
 Full Marks : +4 If ONLY the correct option  vadu ;kstuk :
is chosen.  iw.kZ vad % +4 ;fn flQZ lgh fodYi gh pquk x;k gSA
x 1 x 1
71. If the range of the function y = on the 71. ;fn Qyu y = dk ifjlj vUrjky 0  x  4
x 1 x 1
interval 0  x  4 be [a, b], then the value of esa [a, b] gS rc 5b  2a dk eku cjkcj gS&
5b  2a 
72. For any integer n, the integral 72. fdlh iw.kkZd n ds fy, lekdy
 
2 2
  dk eku gS -
sin x 3 sin x 3
e cos ( 2 n  1) x dx has the value e cos ( 2 n  1) x dx
0 0
73. The equation |x + 2| – |x + 1| + |x – 1| = k, 73. lehdj.k |x + 2| – |x + 1| + |x – 1| = k, x  R,

x  R, k  N. Number of values of k for which k  N. k ds ekuksa dh la[;k "n" gksxh tcfd
the equation has four solutions is "n" then lehdj.k ds pkj gS rc 10 + n dk eku gS -
10 + n is equal to
dy 2x
74. Solution of differential equation 74. vody lehdj.k  2 y
dk gy
dx x  2 ye
dy 2x
 2 y
is x2e–y = ky2 + c then k is
dx x  2 ye
x2e–y = ky2 + c gS] rks k dk eku gS&
equal to
75. A pair of dice is thrown, if 5 appears on at 75. iklksa ds ,d ;qXe dks QSdk tkrk gSA ;fn de ls
least one of the dice, then the probability that de ,d ikls ij 5 vkrk gS rks mu ij vkus okyh
a la[;kvksa dk ;ksx 10 ;k mlls vf/kd gksus dh
the sum is 10 or greater is . Where a and b
a
b izkf;drk gSA tgk¡ a vkSj b lg vHkkT; la[;k,¡
b
are co prime. Then value of (a + b) is ?
gSA rks (a + b) dk eku Kkr dhft,A
MJRAIOT1291219C1-31
(JEE MAIN PATTERN)
TARGET : JEE (MAIN + ADVANCED) 2020
DATE : 29-12-2019 COURSE : ALL INDIA TEST SERIES (VIKALP) | CLASS : XII/XIII
HINTS & SOLUTIONS

PART-A : PHYSICS 5. Light rays from ………………….
1. An isosceles …………………. Sol. For second lens
h u=F–d
Sol. COM of triangular portion is at from base f=F
3
F (F  d )
 v=
COM of square portion is at from base 2F  d
2
   h  6. A horizontal tube ………………….
M   m  Sol. V = A × 
3  3 
2  3 
ycm =  h h=   AT = AT
M  m  2   =  = 2
 
7. A coal based ………………….
2. Moment of inertia ………………….
A  T 
2
Sol. Maximum efficiency of engine =  1    1 0 0 = 40%
 T 
 1 
Sol.   overall efficiency = 0.4 x 0.8 = 0.32
Requirement of house in one year
= 10 × 365 units = 3650 kwh = 3650 × 3600 kJ
B
R
M  x2  3650  3600
 in p u t 

2 2
AB = .  x .d x   x  kJ
1 0 .3 2
0
2
 R .R  4 
In p u t
3  c o a l re q u ire d   1141 kg
R 36000
3M x 4
 3M R 5
R
5
 3
MR2
 
4
=  x  dx =    =
3  3  20 5  4 8. Initially spring is ………………….
R 4  R  
0
Applying parallel axis theorem, Sol. v =  A 2
 x
2

2  Amplitude A = 2x0
 3R  3
 AB = cm +   = MR2
 4  4 9. The frequency of ………………….
3M R
2 Sol. f  T
cm = Ans.
16 4
0  w
3
3. In the given figure ………………….
Sol. 32
L  w
27
10. A slightly tapering ………………….

a b
F dr F
Sol. e =
  KY r
2
=
 Yab
a
P a/2 b  a
K=

a/2
a
a/2 11. A non conducting ………………….
2
=
a Sol. P =
 3 R cos  d    2 R cos  
–4
2R = 48 × 10 cm
4. A capillary tube …………………. 12. A parallel beam ………………….

2
2 2 d
Sol. T.2r cos = mg Sol. x = 2 D  d  2D 
D
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
SOLJRAIOT1291219C1-1
d
2 8  ML
 n t2   t1
D 27 P 0
d= D  , when n = 1 
=
13. From ideal instruments …………………. 2t2
2 3 2
D V ( 3 . 14 ) ( 2 . 00  10 ) 100 . 0 L M
2
Sol.  = =  P =  0  
4 Li 4  ( 0 . 314 ) 10 . 0 4 3
–4
= 1.00 × 10
P = 12P0
14. When the light ………………….
Sol. E = 3.1 eV
22. An open rectangular ………………….
K.E.max = 0.8 eV
Sol.
E
He
 = – 3.4 eV
E = K.E.max – E4
= 4.2 eV y

15. The combination …………………. 5
3–y
Sol. Y  AB (NAND gate)
5
16. A parent radioactive ………………….
Sol. For maximum 1 90
× 5 × y × 3 + (3 – y) × 5 × 3 = 5 × 2 × 3 ×
BNB = ANA 2 100
17. The first diffraction …………………. 12

Sol. dsin =  y=
5
18. During the propagation ………………….
y a
Sol. Both the energy densities are equal. tan = =
5 g
19. A particle moves ………………….
dv 24
Sol. (Moderate) a = v = cx + d a =
dx 5
Let at x = 0 v=u
v x
23. A source of sound ………………….

 v dv 
 (c x  d ) d x
Sol. Min frequency is recorded when source is at N and detector is at
u 0
C
or v2 = cx2 + 2dx + u2
V  V0  330  ( A  ) det ector 
v shall be linear function of x if cx2 + 2dx + u2 is perfect Fmin = F =   × 340
V  Vs  330  ( R  ) 
square  source 
20. In a large building ………………….

Sol. Total power (P) = (15 × 40) + (5 × 100) + (5 × 80) + (1 × 24. Inside a uniformly ………………….
1000) = 2500W
P = VI R R
Sol. E = 
2500 125 40 54  0
I = A= = 11.3 A
220 11
Minimum capacity should be 12 A
25. In the circuit shown ………………….
21. A uniform rod …………………. Sol. In steady state
Sol. 4

P
L/4 6 3

0
24 V
3L/4 P0 63
Req = 4 + =6
3L M
2 6  3
P0  0
4 3 
I=  4A
 R eq
t1 =
2 0
PART-B : CHEMISTRY Element having electronic configuration [Xe]4f7 5d1 6s2 is a
lanthanoid. All lanthanoids belong to group 3 and period 6.
26. Which of the following ............. Element having electronic configuration [Rn] 6d2 7s2 is an
Sol. PM = dRT actinoid. All actinoids belong to group 3 and period 7.
Element, having Z = 56, is Ba. It is member of group 2 and
PM 2  16
period 6.
0 .0 8 2 1  3 0 0
d= RT = = 1.3 36. S1 : On adding acid to .............
density is gas lower than ideal gas. 2  2
Volume will be greater and repulsive forces are dominating Sol. 2 CrO 4  2 H Cr 2 O 7  H 2 O
 Yellow   Orange 
27. Ratio of Tb / Kb for .............
37. Which of the following .............
1000 K b w 1
Sol.  Tb = Sol. Silicon rubber is chemically inert straight-chain polymer. Methyl
m 1w 2
silicones can be used as light duty lubricating oil. Silicones are
hydrophobic in nature.
 Tb 1000  6
(AB2) = =1
K m1  100
38. Identify the correct order .............
b
Sol.
 m1 (AB2) = 60 = A + 2B Diatomic species Bond order
 Tb 1000  9  0.5
(A2B) = =1 He 2
K b
m1  100 2 3.0
C
 m1 (A2B) = 90 = 2A + B 2
on solving A + 2B = 60  1.5
O 2
2A + B = 90
we get A = 40; B = 10 NO 2.5
28. A hydrogen electrode ............. BO for the speices haing (1 to 2) electrons = n/2
Sol. pH changes from 0 to 7. | 4  n |
BO for the speices haing (3 to 6) electrons =
 [H+] changes from 1 to 10–7 M. 2
Accordingly Ered. decreases by 0.059 log 10–7 |8  n |
i.e. 0.059 × (–7) = – 0.41 volt. BO for the speices haing (7 to 14) electrons =
2
BO for the speices haing (15 to 20) electrons = | 20  n |
30. Two mole of an ideal .............
2
V2
Sol. Ssystem = nR In = 2 × R × In 2 = 11.52 J/K
V1 39. The reactants X & Y .............
3 .4 1  1 0 0 0
Ssurrounding = – = – 11 J/K Sol. It is aldol formation reaction between and
310
Stotal = + 11.52 – 11 = + 0.52 J/K

.
40. 0.2% solution of .............
31. Bromine water reacts .............
Sol. Small concentration of phenol (0.2%) acts as antiseptic while 1%
Sol. SO2 + Br2 + 2H2O 2HBr + H2SO4 solution of phenol acts as disinfectant.
32. A reaction at 300 K ............. 41. The labels of two bottles .............
Sol. G° = – RT ln Keq Sol. Neutral FeCl3 gives positive test with I and II so I and II cannot
or, – 1743 = – 8.3 × 300 × ln keq distinguish with FeCl3 solution.
CHCl3 + NaOH react with both compounds so it cannot use to
33. Which of the following............. distinguish.
Sol. (2) Absence of vacant orbitals/ vacant d-orbitals.
42. The compounds 'X' and .............
34. A radioactive isotope.............
A   A – 16 CH3 O
Sol. zX Z - 8Y + 4 2He4
1 mol 0 0 H+
Sol. H x+y
1–0.75 0.75 3 mol
t75% = 2× t50% H
OH
or 34.65 = 2× t50%

34 . 65 CH3 OH
 t50% =
2
H
0 .6 9 3 0 . 693  2
K= = = 4 ×10–2 H
t50% 34 . 65 OH
H3C OH H3C H
35. Which of the following .............
Sol. Element , having Z = 48, is Cd
It is member of group 12 and period 6. H O H H O OH
(x) (y)
x and y are hemiacetal and are diastereisomers of each when subjected to dehydration it will lose 0.01 mole H2O i.e.
other, so they will have different physical and chemical 0.18 gm = 180 mg
properties.  remaining wt. = 2665 – 180 = 2485 mg = 2.485 g  2.5 g
43. The major product of ............. 48. In FCC structure the total .............
Ph Ph Ph
Sol. In FCC structure, APh
to m : T V : O V
B2H6 Conc. 1 : 2 : 1
Sol. HTotal
2SO4 number of voids = 0. 6 × 2 × NA + 0.6 × NA
OH = 10.8 ×1023
Me Me H B Me H
3 Me H
49. Reaction of phenol with .............
OH OH O O O
Ph Ph Ph
Conc. C CH3–C–O–C–CH3
H2SO4 Sol. 1. CO2,NaOH
OH Conc. H2SO4
OH 2. H3O+
e H B Me H
3 Me H O
C—CH3
44. Identify the Y and Z............. O
OH + OH O O O O
–
NH2 N2Cl
C CH3–C–O–C–CH3 C
1. CO2,NaOH OH
NaNO , HCl OH Conc. H2SO4
Sol.    2   2. H3O+
H 2 O , 5º C
Molecular formula of Y = C9H8O4
(X) Molecular mass of (Y) = 108 + 9 + 64 = 180
OH OH 50. How many Natural Occurring .............

Sol. 1. Phenyl alanine - –CH2–C6H5
CHO
 CHCl
  
3
 2. Tryptophan -
H 2O NaOH
(Y) (Z)
45. Consider the following .............

3. Histidine -
Sol. (4) D-Fructose gives two products on reduction as a new
chiral atom is formed at C–2 carbon.
46. The given reaction is ............. PART-C : MATHEMATICS

Sol. 4NH3 + 5O2   4NO + 6H2O
51. The area bounded................
6 .8 40
Mole 4
17 32
A   (6 x  x )  (x  2 x ) d x
2 2
= 0.4 = 1.25 Sol.
m o le 0 .4 1 .2 5 0
s t. c o e ff . 4 5 4
 (8 x
= 0.1 = 0.25 A   2 x )d x
2
0 .4  5 0
(LR) Moles reacted = = 0.5
4 4
 2 3 128 64
A  4x  x  64  
2
So, Moles left = 0.75 sq. units
 
( m O ) le f t  3 0 3 3
 % of excess reagent left =
2
× 100
( m O ) in it ia l 52. The complex number................
2
Sol. |z – 5i| = |z + 5i|
0 .7 5  3 2
= × 100 = 60 [|z – z1| = |z – z2|] Represent perpendicular bisector of z1 and z2
40
(0,5)
47. 2665 mg of an octahedral .............
Sol. CrCl3 .6H2O mol. wt. = 266.5
2.665 (0,–5)
moles given = = 0.01
266.5
3.4 53. If x = 5 and y = –2................
moles of AgNO3 consumed = = 0.02 Sol. Let p, q, r be the three statements such that
170 p : x = 5, q : y = –2 and r : x – 2y = 9
(molecular mass of AgNO3 = 108 + 14 + 48 = 170) Here given statement is (p  q)  r and its contrapositive is ~r
 ~(p  q)
 Cl– (free) = 0.02 mole i.e. ~r  (~p  ~q)
 complex is [CrCl(H2O)5] Cl2.H2O i.e. if x – 2y  9 then x  5 or y  –2
54. If the roots of the................ 2 2
x y
Sol. D > 0  a < 3 Ellipse is + =1
f(x) = (x – )(x – ) where both are less than 3 9 1
f(3) = (+)(+)  a2 – 5a + 6 > 0 2 2
x y
(a – 2)(a – 3) > 0 a < 2 or a > 3 Auxiliary circle is + =1
but a < 3 9 9
 a < 2 is the required
1
Area of OAM = OA. OM sin( – 2)
55. If log2(a + b) + log2(c + d) ................ 2
Sol. (a + b)(c + d)  24
1
(a  b )  (c  d) = .3.3 sin2
Now  [(a + b)(c + d)]1/2 2
2
1
  161/2 tan  = from AOD
 4 3
a+b+c+d8 1
2
3 3
56. How many five letter................ sin 2 = =
Sol. 13 letters (4, 2N, 7 diff) 9 type 1 5
All different 9C55! = 15120 1
9
5!
2 alike 3 different 2 8
C1. C3 = 6720 9 3 27
2! area = . =
2 5 10
5!
3 alike 2 alike 1 different 2C2. 7C1 = 210 61. The sum of the squares................
2!2!
16
5!
 (x
2
1 8 Sol. – 50 ) = 250
3 alike 2 different C1. C2 = 560 i
3! i1
10
5! 1 250
2 =  (x
2
3 alike 2 alike 1C1.1C1 = 10 i
– 50 ) = = 25
3 !2! 10 i1 10
5! =5
4 alike 1 different 1C1.8C1 = 40 5
4! coefficient of variation × 100 = 10%
total = 22660 50
57. The system of................ 62. The sides of a triangle................

Sol.  = 0 ( + 2)( – 1) = 0
1
 = – 2 or 1 Sol.  = b'c' sin A'
2
58. In a ABC, angles................ 2 2 2
b' c' a'
Sol. 2x + 3x + 4x = 9x = 180º cos A' =
x = 20º 2b ' c '
A = 40º 2 2 2 2 2 2
(c  a )  (a  b )  (b  c )
B = 60º or cos A' =
C = 80º 2 2 2 2
2 {( c  a )( a  b )}
a b c
  2a
2
s in 4 0 º s in 6 0 º s in 8 0 º =
2 2 2 2
c 2 {( c  a )( a  b )}
=
2 s in 4 0 º c o s 4 0 º  sin A' = 1 – cos A'
2 2
4 2 2
a  (b c )
59. The number of points................ =1– 2 2 2 2 2 2 4

2 2
…(1)
c b  c a  a b  a b' c'
Sol. for x > 0 f(x) = 0
x=0 f(x) = 0 1 1 2 2
 Area = b'c' sin A' = b c by (1)
x<0 f(x) = 4x2(1– 2x)2 2 2
clearly f(x) is cont as well as derivable for x  R 
63. A point equidistant................
60. The line passing through................ Sol. 42 + 32 = 52, 52 + 122 = 132, 72 + 242 = 252
Hence, the distance of (0, 0) from the three sides are
M 10 26 50
, , i.e. each 2
Sol. B 5 13 25
1 
0 3 A 64. Tangents are drawn................
Sol. The point (a, a) lies outside the circle (1, 1), 2 2
 s' > 0
or 2a2 – 4a – 6 = 0
or a2 – 2a – 3 > 0
(a + 1) (a – 3) > 0 dy
 a < –1 or a > 3 …(1) = 2x + 1
If  be the angle between the tangents then from the figure dx
 r 2 2 1
tan   (g) ….(2)  – =–1
2 s' 2a
2
 4a  6 2 x1  1
     x1 = 0, y = 1
Since        required point (x1,y1)  (0, 1)
3 6 2 2 minimum distance between two curve = 2x length of r from (0,
   1) on the y = x
tan  tan  tan
6 2 2 –1
= 2x = 2 .
  1  2
 tan lies in  , 

2  3 

2 2 1 67. Unit vector c is................

  by (2) Sol. Given a.b = 0 c.a = c b = 1.1 cos 
2
2a  4a  6 3 c.a = (a.a + a.b) + a.(a × b)
or a2 – 2a – 15 < 0 1.1 cos  = (1 +0) + .0
or (a + 3) (a – 5) < 0  = cos 
 –3 < a < 5 …(3)  c.c = 2 (a + b) + 2 (1.1 sin 90ºn) 2 + 2µ ((a + b) . (a × b)]
Hence from (1) and (3), we get 1 = 2(1 + 1 + 2.0) + µ2.1 + 2µ.0
a (–3, –1) (3, 5) 1 = 2 cos2 + 2
2 = 1 – 2 cos2   0
65. A tangent and a normal................
1
Sol. cos2  
(16,16)P 2
  3 
90º   ,  
4 4 
 68. Two lines whose................

A
Sol. for both lines to be coplanar
(–16,0) C (4,0) B(24,0)
2 3 
3 2 3  0    4
1 1 1
a = 4, the point (16, 16) corresponds to (at2, 2at) sin–1sin4 =  – 4

for t = 2
ty = x + at2 x
is tangent and y = –tx + 2at + at3 is normal
Putting y = 0, we get A(–at2, 0) = (–16, 0) 69. Let f ( x )   
 { 1  | 1  t |} dt , x  2
................
B(2a, at2, 0) = (24, 0) 0
The circle through A, B, P will be on AB as diameter as  5 x  7, x  2
APB = 90º. Hence center C is mid-point of AB is (4, 0)
x
16  0 16 4
 Slope of PC =
16  4

12

3
= tan
Sol. f(x)   
 { 1  | 1  t |} dt , x  2
,
0
 4   5 x  7, x  2
  = tan–1 =   
 3  1 x
66. Minimum distance................

f(x) 
 1  (1  t )  dt 
 1  (1  t )  dt
0 1
Sol. Since both curves y = x2 + x + 1 & x = y2 + y + 1 are images
1 x
of each other in y = x  t   t2 
2
minimum distance between two curves lies along their  2 t     
common normal  2   2  1
So, common normal r to y = x 0
let (x1, y1) be the common normal point on y = x2 + x + 1  1  x

2
1
 2      
 2 
 2   2
2
x
 f(x) = 1 +
2
5 x  7 x  2
 2
f(x)   x
1 x  2

 2
L = R = V = 2 at x = 2  continuous 74. Solution of differential................
f (2  h)  f (2 )
2 y
Sol. x d y  2 ye d y  2 xd x
L '  lim
h 0  h y 2 y
2 xe dx  x e d y  2 yd y
5(2  h)  7  3 y
 lim  5 d( x e
2
)  2 yd y
h 0  h
2 y 2
f(2  h )  f(2 ) x e  y  c
R' = ht  2
h 0 h
75. A pair of dice is thrown................
L' ± R' so not differentiable at x = 2
Sol. Let A = event of appearance of 5 on at least one of the dice and
 B = event of sum of numbers on the two dice being 10 or greater
70. The sum of the................ Then, A = { (5, 1), (5, 2), (5, 3), (5, 4), (5, 5), (5, 6), (1, 5), (2, 5),
9
(3, 5), (4, 5), (6, 5)}
Sol. (1 + x + 2x3)  x 2 
3 1 
 B ={(4, 6), (5, 5), (6, 4), (5, 6), (6, 5), (6, 6)} A  B = {(5, 5), (5,
2 3x  6), (6, 5)}
Required probability,

 3 
9
3 
8
1 P(A  B) 3 / 36 3
= (1  x  2 x 3 )   x 2   9 C 1  x 2    P(B/A) = = =
  2 
 2 3x P ( A) 11 / 36 11
7 2
3   1 
C2  x 2   
9

2   3x 
6 3 5 4
3   1  3 2  1 
 C3  x 2 
9
  
9
C4 x   
2   3x  2   3x 
4 5
3   1 
 C5  x 2  
9

2   3x 
3 6
3 2  1 

9
C6 x    
2   3x 
3 2  1 
2 7

C7  x  
9
  ..... 
2   3x  
3
3 1 7
Hence coefficient of x = 9C6    6 =
2 3 18
coefficient of x2 = 0
71. If the range of the................

dy 2
Sol. = 2
 0
dx ( x  1)
That means is entirely increasing in [0, 4].
Hence the function is minimum at x = 0, with y = -1 and is
maximum at x = 4 with y = 3/5.
72. For any integer n................

2
sin x
Sol.  f(x) = e cos3(2n + 1)x
2
sin x
f( – x) = – e cos3(2n + 1)x = – f(x)
2a
use property
 f ( x ) dx = 0 (where f(2a – x) = – f(x))
0
73. The equation |x + 2|................
y=3
Sol.
y=2
y=1
(JEE MAIN PATTERN)
ANSWER KEY
CODE-1
PART-A (PHYSICS)
1. (3) 2. (4) 3. (4) 4. (1) 5. (1) 6. (2) 7. (1)
8. (2) 9. (4) 10. (1) 11. (4) 12. (2) 13. (1) 14. (1)
15. (4) 16. (1) 17. (2) 18. (3) 19. (2) 20. (3) 21. (32.5)
22. (22.5) 23. (25.5) 24. (12.5) 25. (31.5)
PART-B (CHEMISTRY)
26. (2) 27. (3) 28. (3) 29. (1) 30. (2) 31. (3) 32. (3)
33. (2) 34. (2) 35. (3) 36. (2) 37. (4) 38. (4) 39. (2)
40. (1) 41. (1) 42. (3) 43. (3) 44. (1) 45. (4) 46. (60.0)
47. (02.5) 48. (10.8) 49. (18.0) 50. (03.0)
PART-C (MATHEMATICS)
51. (2) 52. (1) 53. (3) 54. (1) 55. (4) 56. (3) 57. (3)
58. (2) 59. (1) 60. (4) 61. (1) 62. (1) 63. (3) 64. (4)
65. (4) 66. (1) 67. (3) 68. (4) 69. (1) 70. (1) 71. (05.0)
72. (00.0) 73. (10.0) 74. (01.0) 75. (14.0)
(JEE MAIN PATTERN)
la d s r ,oa gy
PART-A : PHYSICS 5. vuUr nwjh ij j[ks ………………….
1. ,d leku nzO;eku …………………. Sol. f}rh; ySal ds fy,
h u=F–d
Sol. f=kHkqtkdkj vkd`fr dk nzOe;ku dsUnz ij vk/kkj ls gksxk f=F
3
F (F  d )
 v=
oxZ dk nzOe;ku dsUnz vk/kkj ls ij gksxk 2F  d
2
   h  6. nksuks fljks ij ………………….
M   m 
3  3  Sol. V = A × 
2  3 
ycm =  h h=  
AT = AT
M  m  2 
   =  = 2
2. ,dleku Bksl 'kadq …………………. 7. ,d dkW;ys ij ………………….

A
 T 
2
Sol. batu dh vf/kdre n{krk =  1    1 0 0 = 40%
 T 
Sol.  1 
  dqy n{krk = 0.4 x 0.8 = 0.32
,d lky esa ?kj dh vko';drk
B = 10 × 365 units = 3650 kwh = 3650 × 3600 kJ
R
M  x2  3650  3600

2 2
AB = .  x .d x   x  infuos
p u'tk  kJ
1 2  4  0 .3 2
0  R .R
3 In p u t
R  vko';d
c o a l re qdks
u; ykd 
ire  1141 kg
3M x 4
 3M R 5
R
5
 3 36000
MR2

4
=   x  dx =    =
3  4  R
3  20 5  4
R    
0 8. izkjEHk esa fLizax ewy ………………….
lekUrj v{k çes; ls
2
Sol. v =  A 2
 x
2

 3R  3
 AB = cm +   = MR2  vk;ke A = 2x0
 4  4
2 9. lksuksehVj rkj dh ………………….
3M R
cm = Ans.
16 Sol. f  T
4
3. fp=kkuqlkj fLFkj …………………. 0  w
3
Sol.
32
L  w
27
a
10. ,d FkksM+s Vsifjx ………………….
b
F dr F
P
Sol. e =
  KY r
2
=
 Yab
a/2 a
b  a
a/2 K=
a 
a/2
2
11. 4 cm f=kT;k dh ………………….
a
=
2R Sol. P =
 3 R cos  d    2 R cos  
–4
4. ,d iryh nhokjks …………………. = 48 × 10 cm
Sol. T.2r cos = mg
12. 5000 Å rjaxnS/;Z …………………. 2
3L M
2 P0  0
2 2 d 4 3
Sol. x = 2 D  d  2D 
D 
2 t1 =
d 2 0
 n ; d= D  , when n = 1
D 8  ML
t2   t1
13. fdlh vknZ'k midj.kks …………………. 27 P 0
D V
2
( 3 . 14 ) ( 2 . 00  10
3
)
2
100 . 0 
Sol.  = =  =
4 Li 4  ( 0 . 314 ) 10 . 0 2t2
= 1.00 × 10–4 L M
2
P =  0  
14. tc 400 nm rjax …………………. 4 3
Sol. E = 3.1 eV P = 12P0
K.E.max = 0.8 eV
E  = – 3.4 eV 22. ,d [kqys vk;rkdkj ………………….
He
Sol.
E = K.E.max – E4
= 4.2 eV
y

15. fp=k es iznf'kZr …………………. 5
3–y
Sol. Y  AB (NAND }kj)
5
16. ,d jsfM;ks lfØ; ………………….
1 90
Sol. vf/kdre ds fy, × 5 × y × 3 + (3 – y) × 5 × 3 = 5 × 2 × 3 ×
2 100
BNB = ANA
12
17. ,d fNnz foorZu …………………. y=
5
Sol. dsin = 
y a
tan = =
18. ,d ek/;e esa …………………. 5 g
Sol. nksuksa ÅtkZ ?kuRo leku gSaA
24
a =
19. x-v{k ds vuqfn'k …………………. 5
dv
Sol. (Moderate) a = v = cx + d 23. ,d /ofu L=kksr ………………….
dx Sol. tc L=kksr N ij o lalqpd C ij gS rks U;qure vko`fr izkIr gksrh gS
ekuk x = 0 ij v = u V  V0  330  ( A  ) det ector 
v x Fmin = F =   × 340
V  Vs  330  ( R  ) 
 
 
source
 v dv  (c x  d ) d x
24. R f=kT;k ds le:Ik ………………….
u 0
R R
;k v2 = cx2 + 2dx + u2 Sol. E = 
40 54  0
v, ;gk¡ x dk jsf[kd Qyu gksxkA ;fn cx2 + 2dx + u2 ,d iw.kZ oxZ
gksA
25. fn[kk;s x, fp=k esa ………………….
20. ,d o`gr Hkou esa ………………….
Sol. dqy 'kfDr (P) = (15 × 40) + (5 × 100) + (5 × 80) + (1 × 1000) Sol. LFkkbZ voLFkk esa
= 2500W
P = VI 4
2500 125
I = A= = 11.3 A
220 11
U;wure /kkjk 12 A gksuh pkfg,A 6 3
21. ,d L yEckbZ o …………………. 24 V
Sol.
 63
Req = 4 + =6
P
6  3
L/4

0 I=  4A
R eq
3L/4 P0
PART-B : CHEMISTRY 35. fuEu esa ls dkSulk xyr .............
Sol. Z = 48 j[kus okyk rRo Cd gSA
26. 2 ok;qe.Myh; nkc rFkk 27° C ............. ;g oxZ 12 rFkk vkorZ 6 dk lnL; gSA
Sol. PM = dRT bysDVªkWfud foU;kl [Xe]4f7 5d1 6s2 j[kus okyk rRo ySUFksukWbM gSA
2  16 lHkh ySUFksukWbM oxZ 3 rFkk vkorZ 6 ls lEcfU/kr gSA
PM
bysDVªkWfud foU;kl [Rn] 6d2 7s2 j[kus okyk rRo ,fDVukWbM gSA
0 .0 8 2 1  3 0 0
d= RT = = 1.3 lHkh ,fDVukWbM oxZ 3 rFkk vkorZ 7 ls lEcfU/kr gSA
xSl dk ?kuRo vkn'kZ xSl ls de gSA Z = 56 j[kus okyk rRo Ba gSA ;g oxZ 2 rFkk vkorZ 6 dk lnL; gSA
vk;ru vf/kd gksxk rFkk izfrd"kZ.k cy izHkkoh gksxkA
36. S1 : K2CrO4 ds tyh; .............
27. Tb / Kb dk vuqikr............. 2  2
Sol. 2 CrO 4  2H Cr 2 O 7  H 2 O
1000 K b w 1    
Sol.  Tb =  ihyk   ukjaxh 
   
m 1w 2
 Tb 1000  6 37. fuEu esa ls dkSulk dFku .............

(AB2) = =1
K b
m1  100 Sol. flfydkWu jcj jklk;fud :i ls vfØ; ljy J`¡[kyk cgqyd gSA
 m1 (AB2) = 60 = A + 2B esfFky flfydkWu gYds Lusgd rsy ds :i esa iz;qDr gks ldrs gSA
 Tb 1000  9 flfydkWu tyfojks/kh izÑfr ds gksrs gSA
(A2B) = =1
K m1  100
b 38. lgh Øe igpkfu, .............
 m1 (A2B) = 90 = 2A + B Sol.
gy djus ij A + 2B = 60 f}ijek.oh; Lih'kht ca/k Øe
2A + B = 90  0.5
gesa izkIr gksrk gS A = 40; B = 10 He 2
2 3.0
C 2
28. ,d gkbMªkstu bysDVªkWM dks .............
 1.5
Sol. pH 0 ls 7 rd ifjofrZr gksrh gSA O 2
 [H+] 1 ls 10–7 M rd ifjofrZr gksrh gSA NO 2.5
blds vuqlkj Evip;u 0.059 log 10–7 ?kVrk gS
vFkkZr~ 0.059 × (–7) = – 0.41 volt. (1 ls 2) bysDVªkWu j[kus okyh Lih'kht ds fy, BO = n/2
| 4  n |
(3 ls 6) bysDVªkWu j[kus okyh Lih'kht ds fy, BO =
30. ,d vkn'kZ xSl ds nks eksy ............. 2
|8  n |
V2 (7 ls 14) bysDVªkWu j[kus okyh Lih'kht ds fy, BO =
Sol. Sfudk; = nR In = 2 × R × In 2 = 11.52 J/K 2
V1
| 20  n |
(15 ls 20) bysDVªkWu j[kus okyh Lih'kht ds fy, BO =
3 .4 1  1 0 0 0 2
Sifjos'k = – = – 11 J/K
310
Stotal = + 11.52 – 11 = + 0.52 J/K
39. fuEu vfHkfØ;k ds .............
31. czksehu ty] SO2 ds lkFk............. Sol. ;g rFkk ds e/; ,sYMkWy fuekZ.k
Sol. SO2 + Br2 + 2H2O 2HBr + H2SO4
vfHkfØ;k gSA
32. 300 K rki ij ,d .............
Sol. G° = – RT ln Keq 40. fQuksy dk 0.2% foy;u.............
or, – 1743 = – 8.3 × 300 × ln keq
Sol. fQukWy dh lw{e lkUnzrk (0.2%) iwfrjks/kh dh rjg dk;Z djrk gSA
33. fuEu es ls dkSulh ............. tcfd fQukWy dk 1% foy;u dhVk.kquk'kd dh rjg dk;Z djrk gSA
Sol. (2) fjDr d{kdks @ fjDr d-d{kdksa dh vuqifLFkfr
34. ,d jsfM;kslfØ; ............. 41. ;kSfxd I rFkk II ;qDr nks .............

A   A – 16
Sol. zX Z - 8Y + 4 2He4 Sol. mnklhu FeCl3 ;kSfxd I rFkk II ds lkFk /kukRed ijh{k.k nsrk gS
1 mol 0 0
1–0.75 0.75 3 mol blfy, FeCl3 foy;u dk mi;ksx ;kSfxd I rFkk II ds e/; foHksnu
t75% = 2× t50%
or ;k 34.65 = 2× t50% djus ds fy, ugha fd;k tk ldrk gSA
34 . 65
 t50% = CHCl3 + NaOH nksuksa ;kSfxdkssa ds lkFk vfHkfØ;k djrk gSA blfy,
2
0 .6 9 3 0 . 693  2 bldk Hkh mi;ksx bu nksuksa ;kSfxdksa ds foHksnu ds fy, ugha fd;k tk
K= = = 4 ×10–2
t50% 34 . 65 ldrk gSA
42. fuEu vfHkfØ;k es ............. e ksy 0 .4 1 .2 5
j l l e hd j . kfe r h 4 5
CH3 O x q. kkad
H+ = 0.1 = 0.25
Sol. H x+y
0 .4  5
H (LR) vfHkd`r eksy = = 0.5
OH 4
 blfy,] 'ks"k cps eksy = 0.75
CH3 OH
 vkf/kD; esa cps vfHkdeZd dk %
H m O  ' ks" k
2 0 .7 5  3 2
= × 100 = × 100 = 60
H
OH m O izkjEHk
2
40
H3C OH
47. ,d v"VQydh; .............
O Sol. CrCl3 .6H2O dk v.kq Hkkj = 266.5
H H
(x) 2.665
H3C H fn;s x;s eksy = = 0.01
266.5
H O OH 3.4
(y) AgNO3 ds iz;qDr ¼[kpZ gq,½ eksy = = 0.02
xrFkk y gseh,lhVsy gSa rFkk izR;sd ,d nwljs ds foofje 170
leko;oh gSa] vr% ;s fHkUu HkkSfrd rFkk jklk;fud xq.k j[ksxsaA (AgNO3 dk vkf.od nzO;eku = 108 + 14 + 48 = 170)
 Cl– (eqDr) = 0.02 eksy
43. fuEu vfHkfØ;k vuqØe ............. 
vr% ladqy [CrCl(H2O)5] Cl2.H2O gSA
Ph Ph Ph
tc futZyhdj.k fd;kPh tkrk gS] rc ;g H2O ds 0.01 eksy R;kxrk gS
B2H6 Conc.
vFkkZ
H2SO4 r ~ 0.18 gm = 180 mg
Sol.
OH  'ks"k Hkkj = 2665 – 180 = 2485 mg = 2.485 g  2.5 g
Me Me H B Me H
3 Me H
48. FCC lajpuk esa 0.6 eksy .............
Ph Ph Ph Sol. FCC lajpuk esa,
Conc. ij e k. kq : p r q" Q y d h; fj fD r d k : v "V Q y d h; fj fD r d k
H2SO4 1
:
2
: 1
OH fjfDrdkvksa dh dqy la[;k = 0. 6 × 2 × NA + 0.6 × NA

e H B Me H = 10.8 ×1023
3 Me H
49. fQukWy dh NaOH ds lkFk .............
44. uEu vfHkfØ;k esa Y.............
+ – OH OH O O O
NH2 N2Cl
C CH3–C–O–C–CH3
Sol. 1. CO2,NaOH
NaNO 2, HCl OH Conc. H2SO4
Sol.     2. H3O+
H 2 O , 5º C
O
(X)
C—CH3
OH OH O
OH OH O O O O
CHO
 CHCl
  
3
 C CH3–C–O–C–CH3 C
H 2O NaOH 1. CO2,NaOH OH
OH Conc. H2SO4
2.(Z)H3O+
(Y)
Y dk v.kqlw=k = C9H8O4
45. fuEufyf[kr vfHkfØ;kvksa ............. (Y) dk v.kqHkkj = 108 + 9 + 64 = 180
Sol. (4) D-ÝqDVkst vip;u ds i'pkr~ C–2 dkcZu ij ,d u;k fdjSy
ijek.kq cukrk gSA 50. izkÑfrd :i ls ik;s tkus .............
Sol. 1. Qsfuy,ykfuu - –CH2–C6H5
46. HNO3 ds fuekZ.k ds fy, .............
2. fVªIVksQsu -
Sol. 4NH3 + 5O2   4NO + 6H2O
6 .8 40
eksy 17 32
= 0.4 = 1.25
3 . fgLVhMhu -
PART-C : MATHEMATICS 5!
4 ,d leku] 1 fHkUu 1C1.8C1 = 40
4!
51. oØksa y = 6x – x vkSj................
2
dqy = 22660
4
A   (6 x  x )  (x  2 x ) d x
2 2
Sol. 57. lehdj.kksa x + y + z =  – 1................
0
Sol.  = 0 ( + 2)( – 1) = 0
4
 = – 2 or 1
A   (8 x  2 x )d x
2
0 58. ABC esa, dks.k A,B,C................

4 Sol. 2x + 3x + 4x = 9x = 180º
 2 3 128 64 x = 20º
A  4x  x  64  
2
 
oxZ bdkbZ A = 40º
 3 0 3 3
B = 60º
C = 80º
52. lfEeJ la[;k z = x + iy................
a b c
Sol. |z – 5i| = |z + 5i|  
[|z – z1| = |z – z2|], z1 o z2 ds yEc v)Zd dks O;Dr djrk gSA s in 4 0 º s in 6 0 º s in 8 0 º
c
(0,5) =
2 s in 4 0 º c o s 4 0 º
59. fcUnqvksa dh la[;k gksxh................

(0,–5) Sol. x > 0 f(x) = 0
x=0 f(x) = 0
x<0 f(x) = 4x2(1– 2x)2
53. ;fn x = 5 rFkk y = –2................ Li"Vr;k f(x), x  R ds fy, lrr vkSj vodyuh; gSA
Sol. ekuk p, q, r rhu dFku bl çdkj gS fd
p : x = 5, q : y = –2 and r : x – 2y = 9
60. nh?kZo`Ùk x2 + 9y2 = 9 ds................
;gk¡ fn;k x;k dFku (p  q)  r gS vkSj bldk çfrifjofrZr ~r
 ~(p  q)gS M
vFkkZr~ ~r  (~p  ~q) Sol. B
vFkkZr~ ;fn x – 2y  9 rc x  5 ;k y  –2 1 
0 3 A
54. ;fn lehdj.k x2 – 2ax +................
Sol. D > 0  a < 3
f(x) = (x – )(x – ) tgk¡ nksuksa 3 ls de gS
f(3) = (+)(+)  a2 – 5a + 6 > 0
(a – 2)(a – 3) > 0 a < 2 or a > 3 2 2
ijUrq a < 3 x y
nh?kZo`Ùk + =1
 a < 2 vHkh"V gSA 9 1
2 2
x y
55. ;fn log2(a + b) + log2(c + d) ................ lgk;d o`Ùk + =1 gSA
Sol. (a + b)(c + d)  24 9 9
(a  b )  (c  d) 1
vc  [(a + b)(c + d)]1/2 {ks=kQy OAM = OA. OM sin( – 2)
2 2
  161/2 1
 4 = .3.3 sin2
2
a+b+c+d8
1
tan  = from AOD
56. 'kCn INFINITESIMAL ds................ 3
Sol. 13 v{kj (4, 2N, 7 fHkUu) 9 type 1
lHkh fHkUu 9C55! = 15120 2
3 3
sin 2 = =
5! 1 5
2 ,d leku] 3 fHkUu 2C1.8C3 = 6720 1
2! 9
5! 9 3 27
3 ,d leku] 2 ,d leku 1 fHkUu 2C2. 7C1 = 210 {ks=kQy = . =
2!2! 2 5 10
5!
3 ,d leku] 2 fHkUu 1C1.8C2 = 560 61. 10 izs{k.kksa ds fy, muds................
3!
16
 (x
2
5! Sol. – 50 ) = 250
3 ,d leku] 2 ,d leku 1C1.1C1 = 10 i
3 !2! i1
1
10
250 65. ijoy; y2 = 16x ds................
 =  (x
2
2
i
– 50 ) = = 25 Sol.
10 i1 10
(16,16)P
=5
90º
5
pfjrk dk xq.kkd × 100 = 10%
50
A 
62. f=kHkqt dh Hkqtk,a ................
(–16,0) C (4,0) B(24,0)
1
Sol.  = b'c' sin A'
2
2 2 2
b' c' a'
cos A' =
2b ' c '
a = 4 fcUnq (16, 16) ds laxr fcUnq (at2, 2at) t = 2 ds fy,
2 2 2 2 2 2
(c  a )  (a  b )  (b  c ) ty = x + at2
or ;k cos A' =
2 2 2 2 Li'kZ js[kk gS rFkk y = –tx + 2at + at3 vfHkyEc js[kk gSA
2 {( c  a )( a  b )}
y = 0 j[kus ij A(–at2, 0) = (–16, 0)
2a
2 B(2a, at2, 0) = (24, 0)
= A, B, P ls tkus okyk o`Ùk AB dks O;kl ekudj [khpk x;k gS APB
2 2 2 2
2 {( c  a )( a  b )} = 90º vr% AB dk e/; fcUnq C(4, 0) gSA
 sin2A' = 1 – cos2A' 16  0 16 4
a
4
 (b c )
2 2  PC dh izo.krk =   = tan
=1–  …(1) 16  4 12 3
2 2 2 2 2 2 4 2 2
c b  c a  a b  a b' c'
 4 
1 1 2 2
  = tan–1 =    (4)
 {ks=kQy = b'c' sin A' = b c by (1)  3 
2 2

66. oØksa y = x2 + x + 1................
63. js[kkvksa 4x + 3y + 10 = 0................
Sol. 42 + 32 = 52, 52 + 122 = 132, 72 + 242 = 252 Sol. pwfd nksuksa oØ y = x2 + x + 1 vkSj x = y2 + y + 1, y = x esa ,d nqljs
10 26 50
ds izfrfcEc gSA nks oØksad ds e/; U;wure nwjh muds mHk;fu"B
vr% (0, 0) dh rhuksa Hkqtk,a dh nwjh , , gS vFkkZr~ vfHkyEc ds vuqfn'k gksrh gSA
5 13 25
blfy, mHk;fu"B vfHkyEc y = x ds yEcor~ gSA
izR;sd 2 gSA
ekuk (x1, y1), oØ y = x2 + x + 1 ij mHk;fu"B vfHkyEc dk fcUnq gSA
64. fcUnq (a, a) ls o`Ùk................
Sol. fcUnq (a, a) o`Ùk ds ckgj gS (1, 1), 2 2
 s' > 0
;k 2a2 – 4a – 6 = 0
;k a2 – 2a – 3 > 0
(a + 1) (a – 3) > 0
 a < –1 ;k a > 3 …(1)
;fn  fn, x, fp=k ls Li'kZ js[kkvksa ds e/; dks.k gS dy
= 2x + 1
 r 2 2
tan   (g)….(2) dx
2 s' 2
 4a  6
2a 1
 – =–1
    2 x1  1
pwfd       
3 6 2 2  x1 = 0, y = 1
   vHkh"V fcUnq (x1,y1)  (0, 1)
tan  tan  tan nks oØksa ds e/; U;wure nwjh = 2x (0, 1) ls y = x ij yEc dh yEckbZ
6 2 2
–1
  1  = 2x = 2 .
 tan lies in  , 
2   2
 3 
2 2 1 
  by (2) 67. bdkbZ lfn'k c bdkbZ................
2
2a  4a  6 3
Sol. fn;k x;k gS a.b = 0 c.a = c b = 1.1 cos 
;k a2 – 2a – 15 < 0 c.a = (a.a + a.b) + a.(a × b)
;k (a + 3) (a – 5) < 0 1.1 cos  = (1 +0) + .0
 –3 < a < 5 …(3)  = cos 
vr% (1) vkSj (3) ls  c.c = 2 (a + b) + 2 (1.1 sin 90ºn) 2 + 2µ ((a + b) . (a × b)]
a (–3, –1) (3, 5) 1 = 2(1 + 1 + 2.0) + µ2.1 + 2µ.0
 1 = 2 cos2 + 2
2 = 1 – 2 cos2   0
1 6 3 5 4
cos2   3   1  3 2  1 
2  C3  x 2   
9
 
9
C4 x   
2   3x  2   3x 
  3 
  ,   4 5
4 4  3   1 
 C5  x 2  
9

2   3x 
68. nks js[kk,a ftuds lehdj.k................
Sol. nksuksa js[kkvksa ds leryh; gksus ds fy, 3 2  1 
3 6
3   1 
2 7



9
C6 x     9C7  x 2     ..... 
2 3 
2   3x  2   3x  

3 2 3  0    4
3
1 1 1 3 1 7
vr% x dk xq.kkad = C6    9
=
sin sin4 =  – 4
–1 6
2 3 18
x2 dk xq.kkad = 0
x
69. ekuk f(x)   

 { 1  | 1  t |} dt , x  2
................ 71. ;fn Qyu y =
x 1
dk................
0 x 1
 5 x  7, x  2
dy 2
Sol. =  0
 x
dx ( x  1)
2
Sol. f(x)   
 { 1  | 1  t |} dt , x  2
, bldk vFkZ gS fd [0, 4] esa o/kZeku gSA
0 vr% f(x)] x = 0, y = –1 ij U;wure gS rFkk x = 4, y = 3/5 ij
 5 x  7, x  2
vf/kdre gSA
1 x
f(x) 
 1  (1  t )  dt 
 1  (1  t )  dt 72. fdlh iw.kkZd n ds................
2
0 1 sin x
Sol.  f(x) = e cos3(2n + 1)x
1 x
 t  t  1  x 1
2 2 2 2
 f( – x) = – e
sin x
cos3(2n + 1)x = – f(x)
 2 t       2      
 2 
 2   2  1  2   2 2a
0
x
2
xq.k/keZ  f ( x ) dx = 0 ls (tgk¡ f(2a – x) = – f(x))
 f(x) = 1 + 0
2
5 x  7 x  2 73. lehdj.k |x + 2| – |x + 1|................
 2
f(x)   x
1 x  2 Sol.

 2
y=3
y=2
L = R = V = 2 at x = 2  continuous
y=1
f (2  h)  f (2 )
L '  lim
h 0  h
5(2  h)  7  3
 lim  5
h 0  h dy 2x
74. vody lehdj.k  ................
f(2  h )  f(2 )
2 y
dx x  2 ye
R' = ht  2
h 0 h 2 y
Sol. x d y  2 ye d y  2 xd x
L' ± R' so not differentiable at x = 2
y y

2
2 xe dx  x e d y  2 yd y
9
y
3  3 1  2
2
ds................ d( x e )  2 yd y
70. (1 + x + 2 x )  x  
2 3x 
x e
2 y
 y
2
 c
9
3 1 
Sol. (1 + x + 2x3)  x 2   75. iklksa ds ,d ;qXe dks QSdk................
2 3x 
Sol. ekuk A = de ls de ,d ikls ij 5 vkus dh ?kVuk rFkk B = nksuksa iklks
  3 
9
3 
8
1 ij izkIr la[;kvksa dk ;ksx 10 ;k mlls vf/kd gksus dh ?kVuk gSA
= (1  x  2 x 3 )   x 2   9 C 1  x 2    Then, A = { (5, 1), (5, 2), (5, 3), (5, 4), (5, 5), (5, 6), (1, 5), (2, 5),
  2   2  3 x
(3, 5), (4, 5), (6, 5)}
7 2 B ={(4, 6), (5, 5), (6, 4), (5, 6), (6, 5), (6, 6)} A  B = {(5, 5), (5,
3   1  6), (6, 5)}
C2  x 2   
9

2   3x 
vHkh"B izkf;drk
P(A  B) 3 / 36 3
P(B/A) = = =
P ( A) 11 / 36 11
(JEE MAIN PATTERN)
ANSWER KEY
CODE-1
PART-A (PHYSICS)
1. (3) 2. (4) 3. (4) 4. (1) 5. (1) 6. (2) 7. (1)
8. (2) 9. (4) 10. (1) 11. (4) 12. (2) 13. (1) 14. (1)
15. (4) 16. (1) 17. (2) 18. (3) 19. (2) 20. (3) 21. (32.5)
22. (22.5) 23. (25.5) 24. (12.5) 25. (31.5)
PART-B (CHEMISTRY)
26. (2) 27. (3) 28. (3) 29. (1) 30. (2) 31. (3) 32. (3)
33. (2) 34. (2) 35. (3) 36. (2) 37. (4) 38. (4) 39. (2)
40. (1) 41. (1) 42. (3) 43. (3) 44. (1) 45. (4) 46. (60.0)
47. (02.5) 48. (10.8) 49. (18.0) 50. (03.0)
PART-C (MATHEMATICS)
51. (2) 52. (1) 53. (3) 54. (1) 55. (4) 56. (3) 57. (3)
58. (2) 59. (1) 60. (4) 61. (1) 62. (1) 63. (3) 64. (4)
65. (4) 66. (1) 67. (3) 68. (4) 69. (1) 70. (1) 71. (05.0)
72. (00.0) 73. (10.0) 74. (01.0) 75. (14.0)

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® P1A-19

1 COURSE : ALL INDIA TEST SERIES (VIKALP) | CLASS : XII/XIII

Time : 3 Hours Maximum Marks : 300

Type of Questions and Marking Schemes

SECTION-1 (Maximum Marks : 80)

 Full Marks : +4 If the corresponding to the answer is darkened

 Negative Marks : –1 In all other cases.

SECTION – 2 : (Maximum Marks : 20)

and decimal upto one digit.

 Full Marks : +4 If the corresponding to the answer is darkened

 Zero Marks : 0 In all other cases.

NAME OF THE CANDIDATE : ………………………………………………… ROLL NO. :………………..………………………..

Resonance Eduventures Limited

 Darken the appropriate bubbles on the original by applying sufficient pressure.

DARKENING THE BUBBLES ON THE ORS :

FOR INTEGER TYPE QUESTIONS OMR LOOKS LIKE :

 For example, if answer ‘DOUBLEDIGIT’ integer type below :

Resonance Eduventures Limited

Space for Rough Work

Space for Rough Work

(1) AND gate (2) XOR gate

constant A) converts into a radioactive (1) (2)

and NB are number of atoms of nuclide A and (3) (4)

Space for Rough Work

25. In the circuit shown, the switch 'S' is closed at

length and width respectively 5m and 3m where value of x is :

Space for Rough Work

(3) decrease by 0.41 V

0.75 g/L at 2 atm pressure and 27°C

(1) Force of attraction are dominating than Zn

molecules. monoxide distillation

Space for Rough Work

irreversibly and isothermally at 37ºC until its Z - 8Y

(3) H2SO4 and HBr (4) S and H2O No. = 6

(3) [Rn] 6d2 7s2, group No. = 4, period

32. A reaction at 300 K with G° = – 1743 J /mol No. = 7

(1) A + B C (2) A B + 2C orange.

over wide range of pH from 2 to 6.

incorrect at moderate temperature? correct explanation of statement-1

Space for Rough Work

38. Identify the correct order in which bond order

 2  these compounds were available in a register.

distinguishing these compounds?

39. The reactants X & Y of the following reaction

(1) + CH3CHO (I) NaHCO3

(II) NaNO2 / HCl followed by -Naphthol in

(III) CHCl3 + NaOH

(1) I and II (2) III and IV

(4) (3) II and III (4) I and IV

Space for Rough Work

following reaction are NH2

O NaNO , HCl  CHCl

(3) hemiacetals with different physical and + –

(iii) conc. H2SO4,  NaBH4

(3) (4) (3) Neither X nor Y

Me (4) Both X and Y

Space for Rough Work

answer to each question is NUMERICAL VALUE value of 'x' ? {NA = 6×1023/mol}

decimal placed. heating with CO2 under high pressure, and

left behind ? M/10.

CrCl3.6H2O needs 3.4 g of AgNO3 for

complete precipitation of its all the free

chloride ions. If the given complex is subjected