Chemistry

w
Questions & Solutions

PAPER - 2
Date & Day: 28th August 2022, SUNDAY
Duration & Time: 3 Hrs. | 14:30 - 17:30 IST
Total Marks: 180
SUBJECT : CHEMISTRY
Resonance Eduventures Limited

REGISTERED & CORPORATE OFFICE : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : 0744-2777777, 0744-2777700 | FAX No. : +91-022-39167222 | To Know more : sms RESO at 56677
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN : U80302RJ2007PLC024029
This solution was download from Resonance JEE (ADVANCED) 2022 Solution portal
PAPER-2 : INSTRUCTIONS TO CANDIDATES
 Question Paper-1 has three (03) parts: Physics, Chemistry and Mathematics.
 Each part has a total Eighteen (18) questions divided into three (03) sections (Section-1, Section-2, Section-3)
 Total number of questions in Question Paper-2 are 54 and Maximum Marks are One Hundred and Eighty (180).
Type of Questions and Marking Schemes
SECTION-1 (Maximum marks: 24)

• This section contains EIGHT (08) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on
screen virtual numeric keypad in the place designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct integer is entered;
Zero Marks : 0 If the question is unanswered;
Negative Marks : –1 In all other cases.
SECTION 2
This section contains SIX (06) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is (are) correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of
which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option;
Zero Marks : 0 If unanswered;
Negative Marks : −2 In all other cases.
• For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct
answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;
choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
choosing any other option(s) will get −2 marks.
SECTION 3
• This section contains FOUR (04) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
• For each question, choose the option corresponding to the correct answer.
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
JEE (ADVANCED) 2022 | DATE : 28-08-2022 | PAPER – 2 | CHEMISTRY
PART - III : CHEMISTRY

SECTION-1 (Maximum marks: 24)
• This section contains EIGHT (08) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on
screen virtual numeric keypad in the place designated to enter the answer.
Full Marks : +3 If ONLY the correct integer is entered;
Zero Marks : 0 If the question is unanswered;
Negative Marks : –1 In all other cases.
Q.1 Concentration of H2SO4 and Na2SO4 in a solution is 1 M and 1.8 × 10–2 M, respectively. Molar solubility
of PbSO4 in the same solution is X × 10–Y M (expressed in scientific notation). The value of Y is ________.
[Given: Solubility product of PbSO4 (Ksp) = 1.6 × 10–8. For H2SO4, 𝐾𝑎1 is very large and 𝐾𝑎2 = 1.2 × 10–2]
Ans. (6)
Sol. [H2SO4] = 1M & [Na2SO4] = 1.8x10-2 M
H2SO4  H+ + HSO41-
1M 1M 1M
1 102
H+ + SO42-  HSO41- K= 
K a2 1.2
1M 1.8 x 10-2 1M
(1-x) (1.8x10-2-x) (1+x)
(1  x ) 100
K= =
(1  x )(1.8 x102  x ) 1 .2
 1.2 + 1.2 x = (100-100x) (1.8x10-2-x)
1.2 + 1.2 x = 1.8 – 1.8 x – 100 x + 100 x2
100 x2 – 100.6 x + 0.6 = 0
100.6  (100.6)2  4x100x0.6
x =
2x100
100.6  10120.36  240 100.6  99.4
= 
200 200
x = 0.006 = 0.6 × 10-2
[SO4-2] = (1.08 × 10-2 – 0.6 × 10-2) = 1.2 × 10-2
K sp (PbSO4) = [Pb2+] [SO42-] = 1.6 × 10-8
= [Pb2+] × 1.2 x 10-2 = 1.6 × 10-8
1.6 4
[Pb2+] = x 10-6 = × 10-6
1.2 3
Y=6
Ans. =6
Q.2 An aqueous solution is prepared by dissolving 0.1 mol of an ionic salt in 1.8 kg of water at 35ºC. The salt
remains 90% dissociated in the solution. The vapour pressure of the solution is 59.724 mm of Hg. Vapor
pressure of water at 35ºC is 60.000 mm of Hg. The number of ions present per formula unit of the ionic
salt is _______.
Ans. (5)
Resonance Eduventures Ltd.

Reg. Office & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph. No.: +91-744-2777777, 2777700 | FAX No. : +91-022-39167222
To Know more : sms RESO at 56677 | Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN : U80302RJ2007PLC024029
7340010333
This solution was download from Resonance JEE (ADVANCED) 2022 Solution portal PAGE # 1
Sol. Mole of salt = 0.1 mole

1.8×103
Mole of solvent (H2O) = = 100
18
𝑝º–𝑝𝑠 𝑖𝑛𝑠𝑜𝑙𝑢𝑡𝑒
RLVP  = =
𝑝º 𝑖𝑛𝑠𝑜𝑙𝑢𝑡𝑒 +𝑛𝑠𝑜𝑙𝑣𝑒𝑛𝑡
60–59.724 𝑖×0.1
 =
60 100
 600 – 597.24 = 0.6i
 0.6i = 2.76
 i = 4.6
i = 1 + (n – 1) = 4.6
(n – 1)0.9 = 3.6
n=5
Number of ions present per formula unit of ion is = 5.
Q.3 Consider the strong electrolytes ZmXn, UmYp and VmXn. Limiting molar conductivity (º) of UmYp and VmXn
are 250 and 440 S cm 2 mol-1, respectively. The value of (m + n + p) is _______.
Given:
Ion Zn+ Up+ Vn+ Xm– Ym–
º (S cm2 mol–1) 50.0 25.0 100.0 80.0 100.0
º is the limiting molar conductivity of ions
The plot of molar conductivity () of ZmXn vs c1/2 is given below.
Ans. (7)
Sol. ZmXn, UmYp, VmXn
M =? 250 440 S cm2 mol–1
M (UmYp) = m × 25 + p(100) = 250
25 m + 100p = 250 ….(i)
M (VmXn) = m × 100 + n × 80 = 440 …(ii)
For ZmXn  cM = M – b c
 cn = 340 (From graph)
M (ZmXn) = m × 50 + n × 80 = 340 …(iii)
From equation (ii) & (iii) m = 2 & p = 2; n = 3
(m + n + p) = 7 Ans. 7

Ph. No.: +91-744-2777777, 2777700 | FAX No. : +91-022-39167222
7340010333
Q.4 The reaction of Xe and O2F2 gives a Xe compound P. The number of moles of HF produced by the
complete hydrolysis of 1 mol of P is _______.
Ans. (2)
Xe + O2F2 XeF2 + O2(g)

Sol. (P)
H2O
Xe + 2HF + ½O2
Q.5 Thermal decomposition of AgNO3 produces two paramagnetic gases. The total number of electrons
present in the antibonding molecular orbitals of the gas that has the higher number of unpaired electrons
is _______.
Ans. (6)

Sol. 2AgNO Ag
3 O(s) + 2NO (g)
2 2

2Ag (s) + ½O2(g)

Both NO2 and O2 are paramagnetic as NO2 has only unpaired electron while O 2 has two unpaired
electrons. Electronic configuration of O2 (16) is
(1s)2 (*1s)2 (2s)2 (*2s)2 (2pz)2 (2p2x = 2p2y) (*2px1 = *2p1y)
Total number of electrons in antibonding orbitals is = 6
Q.6 The number of isomeric tetraenes (NOT containing sp-hybridized carbon atoms) that can be formed from
the following reaction sequence is ________.
Ans. (2)
Br
Sol. Na, liq NH3 Br2 (excess)
Birch Br
Reduction Br
Br
Bromination
Br
alc. KOH
&
Br
Br
Br E and Z
Q.7 The number of -CH2- (methylene) groups in the product formed from the following reaction sequence is
________.
Ans. (0)

Ph. No.: +91-744-2777777, 2777700 | FAX No. : +91-022-39167222
7340010333
O O
O3 , Zn / H2O KMnO 4
Sol. 
 
H OH
O
NaOH, electrolys is Cr2 O 3
OH  
770 K, 20 atm
No. of methylene group formed in the product = 0.
Q.8 The total number of chiral molecules formed from one molecule of P on complete ozonolysis (O3, Zn/H2O)
is ________.
Ans. (2)
Sol.
(C) (E)
OH OH
(A) (G)
O O O O
CH3–C–H CH3–C–H
O (B) Chiral H O
Achiral Chiral Achiral
al (D)
O O (F)
HO O O
O O
Achiral
HO
Achiral HO
Achiral
SECTION 2
This section contains SIX (06) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is (are) correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of
which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option;
Zero Marks : 0 If unanswered;
• For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct
answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2marks;

Ph. No.: +91-744-2777777, 2777700 | FAX No. : +91-022-39167222
7340010333
choosing ONLY (B) and (D) will get +2 marks;

choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;
choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
choosing any other option(s) will get −2 marks.
Q.9 To check the principle if multiple proportion, a series of pure binary compounds (P mQn) were analyzed
and their compositions is tabulated below. The correct option(s) is (are)
Compound Weight % of P Weight % of Q
1 50 50
2 44.4 55.6
3 40 60
(A) If empirical formula of compound 3 is P3Q4, then the empirical formula of compound 2 is P3Q5.
(B) If empirical formula of compound 3 is P3Q2, and atomic weight of element P is 20, then the atomic
weight of Q is 45.
(C) If empirical formula of compound 2 is PQ, then the empirical formula of compound 1 is P5Q4.
(D) If atomic weight of P and Q are 70 and 35, respectively, the the empirical formula of compound 1 is P2Q.
Ans. (BC)
3P 40 2
Sol. (A) Compound 3 # if compound is P3O4   
4Q 60 3
P 8

Q 9
3P 44.8
compound 2 # P3Q5  
5Q 55.6
P 5
 0.8
Q 3
4 8

3 6
Option 'A' is wrong
(B) compound 3
40
P =2 1.5 3
20
formula = P3Q2
60 4
Q  1 2
45 3
P 44.4
(C) compound 2   = 0.8
Q 55.6
5P 5 P
compound 1    1
4Q 4 Q
(D) compound 1 #
50
P 1
70
formula = PQ2
50
Q 2
35
Ans. B, C

Ph. No.: +91-744-2777777, 2777700 | FAX No. : +91-022-39167222
7340010333
Q.10 The correct option(s) about entropy (S) is(are)

[R = gas constant, F = Faraday constant, T = Temperature]
𝑑𝐸 𝑅
(A) For the reaction, M(s) + 2H+(aq)  H2(g) + M2+(aq), if 𝑐𝑒𝑙𝑙 = , then the entropy change of the reaction
𝑑𝑇 𝐹
is R (assume that entropy and internal energy changes are temperature independent).
(B) The cell reaction, Pt(s) | H2(g, 1bar) | H+(aq, 0.01M) || H+(aq, 0.1M) | H2(g, 1bar) | Pt(s), is an entropy
driven process.
(C) For racemization of an optically active compound, S > 0.
(D) S > 0, for [Ni(H2O)6]2+ + 3 en  [Ni(en)3]2+ + 6H2O (where en = ethylenediamine).
Ans. (BCD)
n2
Sol. (B) Cell reaction  H2(g)A + 2H+(aq)C  H2(g)C + 2H+(aq)A
0.059 [H ]2
Ecell = log  2A
2 [H ]C
2
0.059  102 
= log  1 
2  10 
 
Ecell = 0.059 V so G = –ve
G = H – TS
As G is negative so reaction is entropy driven.
n2
(A) M(s) + 2H+(aq)   H2(g) + M2+(aq)
 d E cell 
S = nF  
 dT 
R 
S = nF   = 2R
F 
(C) For racemization of an optical active compound S > 0
(D) [Ni(H2O)6]2+ + 3en  [Ni(en)3]3+ + 6H2O
as number of species increase so S > 0 Ans. = (BCD)
Q.11 The compound(s) which react(s) with NH3 to give boron nitride (BN) is(are)
(A) B (B) B2H6 (C) B2O3 (D) HBF4
Ans. (ABC or BC)
HighTemperatur e
Sol. (i) B2H6 + NH3  (BN)x
excess T  200 C
o
Boron nitride slippery solid has same structure as graphite. (Inorganic graphite)
900º𝐶
(ii) B2O3 + 2NH3 → 2(BN) + 3H2O
Q.12 The correct option(s) related to the extraction of iron from its ore in the blast furnace operating in the
temperature range 900 – 1500 K is(are)
(A) Limestone is used to remove silicate impurity.
(B) Pig iron obtained from blast furnace contains about 4% carbon.
(C) Coke (C) converts CO2 to CO.
(D) Exhaust gases consist of NO2 and CO.
Ans. (ABC)
Sol. At 900 – 1500 K (higher temperature range in the blast furnace):
C + CO2  2 CO ; FeO + CO  Fe + CO2
Limestone is also decomposed tom CaO which removes silicate impurity of the ore as slag. The slag is
in molten state and separates out from iron.
CaCO3  CaO + CO2 ; CaO + SiO2  CaSiO3

Ph. No.: +91-744-2777777, 2777700 | FAX No. : +91-022-39167222
7340010333
Q.13 Considering the following reaction sequence, the correct statement(s) is(are)
(A) Compounds P and Q are carboxylic acids.

(B) Compound S decolorizes bromine water.
(C) Compounds P and S react with hydroxylamine to give the corresponding oximes.
(D) Compound R reacts with dialkylcadmium to give the corresponding tertiary alcohol.
Ans. (AC)
O O O O
Zn/Hg,HCl SOCl2
Sol. AlCl3
HO HO Cl
o o o
P Q R
AlCl3 Zn/Hg,HCl
Cl
o o a hydrocarbon
R S
Option (A) – Correct, as both P and Q are carboxylic acid.
Option (B) – Incorrect, “S” – deactivated benzene ring does not decoloriz.
Option (C) – Correct, both P and S have carbonyl group and form oxime.
Option (D) – Incorrect, acid chloride with dialkyl cadmium gives ketone not the tertiary alcohol.
Q.14 Among the following, the correct statement(s) about polymers is(are)
(A) The polymerization of chloroprene gives natural rubber.
(B) Teflon is prepared from tetrafluoroethene by heating it with persulphate catalyst at high pressures.
(C) PVC are thermoplastic polymers.
(D) Ethene at 350-570 K temperature and 1000-2000 atm. pressure in the presence of a peroxide initiator
yields high density polythene.
Ans. (BC)
Sol. Option (A) – incorrect Polymerization of isoprene gives natural rubber.
Option (D) – incorrect. High density polythene is manufactured at low temperature and pressure using
Ziegler-Natta catalyst.
SECTION 3
• This section contains FOUR (04) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
• For each question, choose the option corresponding to the correct answer.
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);

Ph. No.: +91-744-2777777, 2777700 | FAX No. : +91-022-39167222
7340010333
Q.15 Atom X occupies the fcc lattice sites as well as alternate tetrahedral voids of the same lattice. The packing
efficiency (in %) of the resultant solid is closest to
(A) 25 (B) 35 (C) 55 (D) 75
Ans. (B)
Sol. No. of atoms per unit cell (Z)
1 1
Z = 8 [corner] + 6[Face] + 4 [Alternate TV]
8 2
Z=1+3+4
Z=8
It is diamond like structure in which
√3𝑎
2r =
4
8
 a=( 𝑟)
√3
4
8× 𝜋𝑟 3
PF = 3
8 3
× 100 = 35%
[ 𝑟]
√3
Q.16 The reaction of HClO3 with HCl gives a paramagnetic gas, which upon reaction with O 3 produces
(A) Cl2O (B) ClO2 (C) Cl2O6 (D) Cl2O7
Ans. (C)
Sol. HClO3 + HCl ClO2 + H2O
(X)
O3
Cl2O6 ClO3
(Y)
Q.17 The reaction of Pb(NO3)2 and NaCl in water produces a precipitate that dissolves upon the addition
of HCl of appropriate concentration. The dissolution of the precipitate is due to the formation of
(A) PbCl2 (B) PbCl4 (C) [PbCl4]2– (D) [PbCl6]2–
Ans. (C)
Pb2+ + dil. HCl  PbCl2 
 [PbCl4]2– excess
Sol.
HCl
Q.18 Treatment of D-glucose with aqueous NaOH results in a mixture of monosaccharides, which are
(A) , and
(B) , and

Ph. No.: +91-744-2777777, 2777700 | FAX No. : +91-022-39167222
7340010333
(C) , and
(D) , and
Ans. (C)
Sol. D-glucose with aq. NaOH results in a mixture of mannose, glucose and fructose in equilibrium via enediol
intermediate (Tautomerization).
CH2–OH
O
H O Fructos
– H
C OH e
OH
H OH OH
H O
C
HO H
D-Glucose Enediol
Mannose
END OF THE QUESTION PAPER

Ph. No.: +91-744-2777777, 2777700 | FAX No. : +91-022-39167222
7340010333

Chemistry

Uploaded by

Document Information

Original Description:

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Chemistry

Uploaded by

Copyright:

Available Formats

w

Questions & Solutions

Duration & Time: 3 Hrs. | 14:30 - 17:30 IST

Total Marks: 180

Resonance Eduventures Limited

SECTION-1 (Maximum marks: 24)

PART - III : CHEMISTRY

Resonance Eduventures Ltd.

Sol. Mole of salt = 0.1 mole

Resonance Eduventures Ltd.

Xe + O2F2 XeF2 + O2(g)

2Ag (s) + ½O2(g)

Resonance Eduventures Ltd.

Resonance Eduventures Ltd.

choosing ONLY (B) and (D) will get +2 marks;

Resonance Eduventures Ltd.

Q.10 The correct option(s) about entropy (S) is(are)

Resonance Eduventures Ltd.

(A) Compounds P and Q are carboxylic acids.

Resonance Eduventures Ltd.

Resonance Eduventures Ltd.

END OF THE QUESTION PAPER

Resonance Eduventures Ltd.

You might also like