Fiitjee: All India Test Series

FIITJEE
ALL INDIA TEST SERIES

JEE (Advanced)-2022
CONCEPT RECAPITULATION TEST – III
PAPER –1
TEST DATE: 31-07-2022
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
Section – A
1. B
Sol. So as to obtain path difference between the signal from A1 and A2 at P, the path length A1P and
A2P need to be determined.
A1 N
200 m 800 m
M
200 m
A2 L
600 m
P(Person)
2 2 2
In A 2LP,  A 2P   PL    A 2L 
2 2 2
  A 2P    600  200    800 
2 2
  400    800 
 A 2P  894.43m
2 2 2
In A1NP,  A 1P   PN   A1N
2 2
  600  200    800 
 A1P  1131.37m
Path difference   A1P  A 2P  236.94m
Since the person is at the position of third order maximum,
   3    n 
or 3  236.94m
   79m
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-CRT-III (Paper-1)-PCM(Sol.)-JEE(Advanced)/22 2
2. A
Sol. If at a distance r from the centre of the earth the body has velocity v, by conservation of
mechanical energy,
1  GMm  1  GMm 
mv 2    2
  mv e    
2  r  2  R 
2GM  R 
or v 2  v 2e   1
R  r 
But as v e  2gR and 
g  GM / R2 
2
v  2gR  2gR R / r   1
2gR2 dr 2g
or v , i.e, R
r dt r
t 1 R h
1/2
i.e, 0 dt  R 2g R r dr
2 1  3 /2
i.e, t R  h   R3 /2 
3 R 2g 
3/ 2
1 2R  h 
i.e, t  1    1
3 g  R  
3. D
Sol. Initial activity if nuclei A 0  N0
Activity if nuclei at time t, A   N
 N0 et
A  A 0 e t ....(i)
55
Since activity decreases at 4.0% per hour, so activity of Co radio nuclide at t  1hr,
A  A 0  A 0  A 0 1   , where   0.04 ...(ii)
Taking log of Eq. (i), we get
A
log   t ...(iii)
A0
A 0 1  
or log  t
A0
1
or    ln 1   
t
On substituting values, we get
  1.1 105 s 1
4. A
Sol. Amplitude of oscillation of block initially
2mg
A
k
Velocity when it strikes upper block
2 2
k  2mg   mg   k  mg 
      3  
m  k   k   m k 
mg
New equilibrium is at x  from relaxed state of upper spring.
2k
3 AITS-CRT-III (Paper-1)-PCM(Sol.)-JEE(Advanced)/22
If A’ is new amplitude then

2
2k  mg  k  mg 
 A '2    3  
m  2k  m k 
7 mg
A'   5 cm
2 k
5. BC
Sol. The diagram shows the path of a ray AB incident at B on the sphere at angle i. The path ABCD
shows the refracted ray BC, inside the sphere with angle r of refraction and the emergent ray CD
with angle of emergence i.
N
B
A i r C M
r i
D
Obviously OBC  OCB  r .

Hence ABN  DCM  i for all values of i.
Also, if ABN  90, grazing incident at B, then
DCM  90, grazing emergence at C.
But AB and CD will not be parallel.
6. ACD
Sol. AT 50 Hz,
I1 = I2
XL = XC
V2
Z R   50
P
100 / 2
I1  I2   2A
50
Inet  I1  I2  2 2 A
LCR branch behaves as a pure resistive branch
7. AB
di
Sol. Bvl  L
dt
Bl
  vdt  di
L
x i
Bl
  dx   di
L 0 0
Blx
 i ….(i)
L
Now F  ma  mg  Bil ….(ii)
From eqns. (i) and (ii)
d2 x B l2
2
 g x
dt mL
B2l2 mL
 2   1 and amplitude A  g  2 2
mL Bl
8. ACD
1
Sol. U  0E2  volume
2
2
1  Q0 
 0      x  d
2   2 0 
1 Q20
   xd
2 3 0
dU  1 Q2  Q2 d
   3 0  1 d   30
F
dx  2  0  2 0
2
F F Q0
Hence  
A d 2 4 0
1 1 Q02 Q02
Energy density   0 E2   0 
2 2 
2 0 
2
2 4 0
9. BCD
 x 
Sol. y  4 sin   cos  96t  ....(i)
 15 
But y  2a sin kx cos t
  
(A) ymax  4 sin   5   2 3cm
 15 
2 
(B) k      30cm
 15
30 cm
 
2 2
Thus, third node is formed at 30 cm from one end of the string.
(C) Differentiating eqn. (i) w.r.t. time:
 x 
v  4(96)sin   sin  96 t 
 15 
At x  7.5 and t  0.25,
 
v  4  96   sin  sin  24   0
 2
(D) y  y1  y 2
 x   x 
y  2 sin   96t   2sin   96t 
 15   15 
x
y  4 sin cos 96t
15
Hence, options (B), (C) and (D) are correct.
10. AB
Sol. (i) Using the law of conservation of momentum along horizontal direction.
m m
3u u
60 60
mu sin60 3mu sin60
60 60
mu mu
mu cos60
3 mu sin 60  mu sin 60  10m  2m  V

2 mu sin60  12mV
 3
2 mu   12mV
 2 
 
u 3
V
12
(ii) Impulse in the string = change in momentum in vertical direction
 mu cos 60  3mu cos60  2mu
1 1 2
mu2  m  3u   5mu2
(iii) Initial K.E. 
2 2
1 mu2
K.E. gained by the system  12m  V 2 
2 8
2
mu 39
 Loss in energy  5mu2   mu2
8 8
Section – B
11. 3
1240
Sol.  th   620
2
620
eAk  d
dN eA 100
i e dt 
dt hc  hc

eAk 2 620


1 1 620  4002  k
2

2c 400
1240  2
220  1020 0.031
   2.8A  3A
1240  2 100
12. 7
Sol. 2 2
P0A P0A PA P0A
Final condition Final condition

P0 P
Volume of the cylinder remains constant 
T0 2T0
 P  2P0
Now, PA  P0 A  f
  P  P0  A  f
dN dN
  2P0  P0  A   
dl     2r
dl dl
dN P0  r 2 P r 105  5  102
   0 
dl   2  r 2 2  0.2
 125  102 N / m
13. 2
Sol. t C  lC 
B
b–x x
C G O
A
mg  b  x  g
 
IC 2b
Using parallel axis theorem
IC  m2b  b  x 
Section – C
14. 00008.66
Sol. u m
P
 /6 Q
M
/3
2 / 3
O
T
t PQ   1sec
2
 2usin  
tPQ 
g
 1
2u  
 2 1
10
U = 10 m/s
At highest point velocity of ball = ucos   5 3 m / s
15. 00017.32
Sol. Since POQ is equilateral triangle
 u2 sin2
 Range of ball = PQ=
2 g
3
 10  5 3
2
 L  10 3 m
16. 00000.50
mv
Sol. R  10m 
qB
90o
0.1 50
B  0.5T
1 10
17. 00003.00
1
Sol. 1.8  gt 2
2
t = 0.6 sec
qB 1
  t  t  0.5  0.6  3 rad
m 0.1
18. 00001.76
Sol. h0  h1h2  1.6  0.9  1.2mm  2a
1.2  2aA    1
   1.76
19. 00000.70
Sol. d  1.2 mm; D  140 cm
D
   0.7 mm
d
Chemistry PART – II
Section – A
20. B
Sol. O O O
CH3O  
NH2 NH Br Br N Br
OH
CH3O
C
H3 CO N O
CH3OH O
C
N
N Br
O
H3 CO NH
21. C
Sol.
OH OH
NaNO 2+HCl
Ph C CH CH3 Ph C CH CH3
Ph NH 2 Ph
OH O CH3
CH3
H
Ph C CH Ph C CH
Ph Ph
22. C
1
Sol. A : Cl  Cl2  e 
2
P1
1/ 2
1 P 
C : Cl2  e   Cl  Q  1
2  P2 
P2
0.059
E cell  0  logQ
1
For E cell  0; P1  P2
23. B
Sol. For system consisting of two immiscible liquids.
PSolution  PH02 O  Pn0butylchloride  1 atm  760 mm
Pn0butyl chloride  760  570  190mm of Hg
Also in vapour state

nH2 O  PH0 O 570
 0 2 
nn butyl chloride  Pn butyl chloride 190
H2 O / 18
3
nbutyl chloride / 92.5
H2 O 3  18 0.58
 
nbutyl chloride 92.5 1
24. C
Sol. Option ABC are optically active because of chirality in molecule
Option D having two similar gp. so achiral molecule.
25. BCD
Sol. Based on nomenclature system of geometrical isomers.
26. ABD
Sol. By application of Jahn Teller distortion effect. In d1, d2, d4, d5 low spin d6 high spin J. Teller effect
observed.
27. AD
Sol. Red bauxite  Al2 O3   KOH  KAlO2  H2 O
Residue contain Fe 2O3 as impurity
28. AB
Sol. Hall – Heroult’s process
Aluminum is liberated at the cathode and gets located at the bottom of tank
Oxygen liberated at anode combines with the carbon of the anode to produce carbon monoxide.
29. AB
Sol.  H2 O( )
H  OH 
(aq) (aq)
H0  13.7  4.18 kJ / mole

Mv
 mole
1000
200  0.862
Moles of HCl  mole
1000
= 0.1724 mole of H+
200  0.431
Moles of Ba  OH2  mole
1000
=0.0862 mole Ba (OH)2
= 0.1724 mole of OH–
Thus, H   OH  , hence no reactant is left unreacted.
r H0 for 0.1724 mol H or OH ion
 0.1724  57.2  9.86 kJ
Thus, (A) is correct.
Hcalorimeter  Cp T  435 JK 1 T K
 435TJ  0.435T kJ
Hsolution  m.s T  400  4.184 TJ
 1673.6 T J  1.6736 T kJ
HTotal   0.435 T  1.6736T  kJ
 9.86   0.435  1.6736 T
T  4.6760
 T2  T1   4.6760
 T2  T1  4.676  20.48  4.676
 25.16 o C
Thus, (B) is correct.
Section – B
30. 7
Sol. 2Cu2  4I 
 I2
2I  H2 SO4  2H  I2  SO2  2H2 O
Conc.
 MnO4 /H
2I  I2
2 
Cr2 O7 /H
2I  I2
2I  Cl2  2Cl  I2
2I  CaOCl2  2H  CaCl2  H2 O  I2
2I  4H  2NO 2  I2  2NO  2H2O
( I converts into I2 when it reacts with oxidizing agents)
31. 3
Sol. O.N. of Cr in X(FeO.Cr2O3) = + 3
O.N. of Cr in Z  Na2 Cr2O7   6
32. 6
Sol. Isoelectric pH is the pH at which there is no migration of Zwitter ion on passing electric current.
pH(with NaOH)  pH  with HCl 
pH 
2
9.714  2.286
 6
6
Section – C
33. 00019.20
Sol. 

H2 O     
 H  OH

K eq  K w  H  OH   1 10 14 at 298 K

 G0  2.303 RT log K w
  2.303  0.002  298log1 1014
 19.2 kcal mol1
34. 00018.46
Sol. 

H  OH 
 H2 O
G0  19.2 kcal mol1
H0  13.7kcal mol1(s tan dard value)
 G0  H0  TS 0
H0  G0
 S 0 
T
13.7  19.2
 
298
 0.01846 kcal mol1K 1
35. 00004.06_00004.07
Sol. Mole fraction of CH3OH = 0.1
Mole fraction of CH2OH = 0.3
Mole fraction of H2O = 0.6
Sum of mole fraction = 1.0
Thus, moles of CH3 OH  1  32g
Moles of CH3 CH2OH  3   138 g
Moles of H2 O  6   108 g
Molality of CH3OH
Moles of CH3 OH

kg of solvent H2 O  CH3 CH2 OH 
1
  4.065 molal
246 / 1000
36. 00049.64
Sol. Mass percentage of CH3CH2OH
138
  100  49.64%
278
37. 00303.00
90
Sol. Cu in 15 g brass  15   13.5 g
100
13.5
 mol  0.2126mol
63.5
HNO3 required = 4 times of Cu taken
 0.2126  4 mol  0.8504 mol
1.5
Zn in 15 g brass  1.5 g  mol
65.0
HNO3 required = 2.5 times of Zn taken
1.5
  2.5  0.0577 mol
65.0
Total HNO3 = 0.9081mol
volume(mL)  molarity
Sinc,  mol
1000
0.9081 1000
 V  mL    303mL
3.0
38. 00009.52
Sol. NO2 is due to Cu only.
Thus, NO2 formed = 2 times of Cu taken
= 2 × 0.2126 mol
 Volume at STP 2  0.2126  22.4L  9.52L
Mathematics PART – III
Section – A
39. D
  
1   1 1 
Sol. S1  S 2     
2 k  1   6k  12  6k  12  
  
1 1 1 1
 2  S1  S 2   1  2
 2  2  2  ........ --------------- (1)
1 5 7 11
2
 1 1 1
Let    2  2  2  ....... ----------------- (2)
6 1 2 3
 1 1
2
 2  2  ....... ------------------ (3)
2 2 4
 1 1
   ....... ------------------ (4)
32 32 6 2
 1
2
 2  ....... ------------------ (5)
6 6
Now, (2) – { (4) – (5) + (3)} gives
2 1  2  2 1
 2  S1  S 2   1  S1  S2    1  
3 2 3  18 2
40. D
Sol. A/2 A
E D
Q P
I
B/2 C/2
B C
2 
 B   C  ,  A 
3 3
B AP BI AB
sin  and 
2 AB sin  A / 2  cos  C / 2 
AP sin B / 2  cos  C / 2 
 
BI sin  A / 2 
AQ sin  C / 2  cos B / 2 
similarly 
CI sin  A / 2 
AP AQ A 
   cot  cot  3 .
BI CI 2 6
41. B
Sol. Since, x, y, z are not all zero, therefore given system of equation has non-trivial solution
1 a 3 a 2
 a3 1 a1  0
a2 a1 1
 a12  a 22  a 32  2a1a 2a 3  1 ...(1)
Since, a1  m  m  and m is not an integer.
 0  a1  1  0  1  a12  1 ...(2)
From eq.(1),
1  a 22  a 23  a12  2a1a 2 a 3  1  a22 1  a32   a1  a2a3 2 ...(3)
Similarly,
2
1  a 1  a    a  a a 
1
2
3
2
2 1 3 ...(4)
2
1  a 1  a    a  a a 
2
1 2
2
3 1 2 ...(5)
From Eq. (5),
2
1  a2 2  a  a1a2 
 3 0
1  a12
From Eq. (4),
 
1  a 32  0  3  a12  a2 2  a3 2  0  a12  a 22  a 3 2  3  1  2a1a2a3  3 [FromEq. (1]
 a1a2 a3  1
42. B
Sol. Let  be the common root, then
 2  a  m  1  0 ...(i)
  b   m  4   0
2
...(ii)
  c  m  15   0
2
...(iii)
adding Equations (i) and (ii) and subtracting Equation (iii)
 2  m  10  0 ...(iv)
1 2n r x 2
but m  lim
n n

r 1 n2  r 2
= 
0
2
1 x2
dx  1  x 2
0
 
 5  1 , Now, m   5  1  1
Now, from equation (iv),  2  1  10  0    3 ...(v)

Now, number of determinants of order 2 having 0, 1, 2, 3 = 4! = 24.
a a2
Let 1  1 be one such determinant and there exists another determinant.
a3 a 4
a3 a4
2  (obtained on interchanging R1 and R2) such that 1   2  0
a1 a2
P = sum of all the 24 determinants = 0
Since,   p    0 , From equation (v),   3
43. A
Sol. Let A = B, then 2A + C = 180 and 2 tan A + tan C = 100
Now, 2 A + C = 180  tan 2A = –tan C ...(i)
Also, 2 tan A + tan C = 100 ...(ii)
 2 tan A – 100 = – tan C
From Equations (i) and (ii), we have

2 tan A
2 tan A – 100 =
1  tan2 A
2x
Let tan A = x, then  2x  100
1 x2
 x 3  50x 2  50  0
Let f  x   x 3  50x 2  50  0
Then, f '  x   3x 2  100x
100
Then, f '  x   0 has roots 0,
3
 100 
Also, f 0  f  0
 3 
Thus, f(x) = 0 has exactly three distinct real root. Therefore, tan A and hence A has three distinct
values. Thus, there exist exactly three non-similar isosceles triangles
44. AC
Sol. (ay – bx)2 + 4xy = 0
 a2y2 + b2x2 + (4 – 2ab)xy = 0
a2 y b2 x
    2ab  a   0
x y
y
Put t
x
 a t – (2ab – 4)t + b2 = 0
2 2
D = (2ab – 4)2 – 4a2b2

= 4(4 – 4ab) = 16(1 – ab) must be a perfect square.
45. AB
Sol. From the figure it is clear that C1AC2 = 90
Similarly C1BC2 = C1CC2 = C1DC2 = 90
Thus ABCD is a cyclic quadrilateral with C1C2
as diameter ABCD is clearly not a square.
C2
C1
/2
/2–/2
A
46. ABCD
2
a2 b2  a  b 
Sol. (A)  
1 1 2
2 2
a b ab
 
ab 2
a2  b2
  ab abc = 8
1 1 1 1 1 1
(C) as 2  2  2   
a b c ab bc ca
a2b2 + b2c2 + c2a2  abc(a + b + c)
 a2b2  b2 c 2  c 2a2  8abc

(D) a2 + b2 + c2  ab + bc + ca
3(a2 + b2 + c2)  (a + b + c)2
= 64
64
 a2  b2  c 2 
3
2 2 2
 a  b  c  18
47. AC
Sol. sin + sin+ sin = 1 – sin
cos2 + 1 – 2 sin2 + 1 – 2sin2 + 1 – 2sin2  10 /3
1
 cos2  + 2  sin2   sin2   sin2  
3
2 2
1  sin   sin   sin   1  2 1  sin  
 1 – 2sin2  +2 =
3 3 3
2 2
 3 – 6sin   2 sin  – 4sin + 3.
 
 8 sin2 – 4sin  0     0, 
 6
 A, C.
48. ABCD
Sol. Let f(x) = x
1
g(x) =
x
f(x) g(x) = 1
periodic
(B) f(x) = x
g(x) = – x
f(x) + g(x) = 0
periodic
(C) f(x) = x
g(x) = x
f(x) – g(x) = 0
periodic
(D) f(x) = sinx
g(x) = x2
f(g(x)) = sinx
Periodic.
Section – B
49. 5
Sol.
(z3) R Q (z2)

O 
P (z1)
z 2 OQ i z2
 e  ei 
z1 OP z1 cos 
z 3 OR i2 z3
 e  ei2 
z1 OP z1 cos 2
z3 cos2  2  3
z 22  z12 cos2    
z1 cos 2 cos 2 2 3
2 3
 cos2 =
4
2 o
 2 cos  = 1 + cos 30   = 15
50. 8
2 2 2 2
Sol. x + 81y = 81 ……. (1) and x + y = 9
2 2
 81x + 81y = 9  81 ……. (2)
Solving, (1) and (2), by subtracting
80x2 = 81  8
81 9
 x2 = , similarly, y 2  .
10 10
Above gives the point of intersection say (x 1, y1).
Tangent at (x1, y1) to the circle x2 + y2 = 9 is
x
xx1 + yy1 = 9, m1 =  1   9  3 .
y1
Slope of tangent to ellipse is
3
x1 1 9 1 3 
3 m1  m2 81
     m2  m2 =   tan  = 
y1 81 1 81 81 1  m1m2 9
1
81
( 3  80)  81 8
 tan  =  tan  =    3 tan  = 8.
81 90 3
51. 2
Sol. E = event of any one cutting a spade in one cut
n(E) = 13C1
n(S) = 52C1
P(E) = 1/4 = p, P E = q 
Probability of a winning = p + qqqqp + qqqqqqqqp+ ……
p 64
= 4
 
1 q 175
64  350 
 350 = 350  = 128    = 2.
175  64 
Section – C
52. 00001.00
Sol.
y = (x-1)2
1
y=x
0 1 2
2
0   a  1  1
 a  [0, 2)  a  0, 1
53. 00001.17
Sol. Area will be bounded when (a –1)2 = 0
1
A    x 2  x1  dy
0
and 1
7
A  
0
 
y  1  y dy 
6
 1.17
54. 00000.52
2
Sol. Curve C is  x  1  y 2  1
and x2 – 3y2 – 2x + 1 = 0 represents
lines x  3 y  1  0 and x  3 y  1  0
passing through centre of circle (1, 0)
1 1  
Hence area of smaller region r 2     
2 23 6
55. 00003.24
Sol.
Q C
A B
(1, 0) (2, 0)
P
(0, -2)
Maximum distance is along the line through P passing from centre 'A' and is equal to
5  1.
56. 00001.00
Sol. We have  t 2  t 3  t 2  t1   4;  t 4  t 3  t 4  t1   4
Hence t 2  t  t1  t 3   t1t 3  4  0 is satisfied by t2 & t4
So, t 2  t 4  1 t1  t 3  & t 2 t 4  t1t 3  4
t2  t4
 1
t1  t 3
57. 00004.00
Sol. We have  t 2  t 3  t 2  t1   4;  t 4  t 3  t 4  t1   4
Hence t 2  t  t1  t 3   t1t 3  4  0 is satisfied by t2 & t4
So, t 2  t 4  1 t1  t 3  & t 2 t 4  t1t 3  4
2 2 2
 t1  t3    t1  t3   4t1t3   t 2  t 4   4t 2 t 4  16
2
  t 2  t 4   16  16
 t1  t 3 min
4

Fiitjee: All India Test Series

Uploaded by

Document Information

Original Description:

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Fiitjee: All India Test Series

Uploaded by

Copyright:

Available Formats

FIITJEE

ALL INDIA TEST SERIES

ANSWERS, HINTS & SOLUTIONS

If A’ is new amplitude then

Obviously OBC  OCB  r .

mu sin60 3mu sin60

3 mu sin 60  mu sin 60  10m  2m  V

P0A P0A PA P0A

Final condition Final condition

Also in vapour state

H0  13.7  4.18 kJ / mole

K eq  K w  H  OH   1 10 14 at 298 K

Mathematics PART – III

Now, from equation (iv),  2  1  10  0    3 ...(v)

From Equations (i) and (ii), we have

D = (2ab – 4)2 – 4a2b2

 a2b2  b2 c 2  c 2a2  8abc

You might also like