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PART I

SAFETY DATA SHEET


This form has been prepared in accordance with the Regulation on Safety Data Sheets Regarding Harmful
Substances and Mixtures published in the Official Gazette dated 13.12.2014 and numbered 29204.

Substance/Mixture Name: UPHOLSTERY ADHESIVE


Preparation Date: 10.04.2019
New Edit Date: 10.04.2019
Number of Regulations: 01
Form No: A-S-00200
Sayfa 1 / 8

PART II
1) IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/ DISTRIBUTOR
1.1. Substance/Identity of the mixture:
Name of the product UPHOLSTERY ADHESIVE
CAS No *
EICS No *
1.2 Relevant identified uses of the substance or mixture and uses advised against:
1.2.1 Related uses Adhesive
1.2.2. Not recommended uses Information not available.
1.3. Information of the supplier of the safety data sheet
Manufacturer
ADALAR KİMYA SAN. TİC. AŞ.
Dilovası Organize Sanayi Bölgesi 4. Kısım Ceyhan Cad. No:8 Gebze / KOCAELİ
Tel: (262) 724 89 07-08-09
Fax: (262) 724 89 05
E-mail: info@adalarkimya.com
1.4. Emergency phone number
ADALAR KİMYA SAN. TİC. AŞ
Dilovası Organize Sanayi Bölgesi 4. Kısım Ceyhan Cad. No:8 Gebze / KOCAELİ
Tel: (262) 724 89 07-08-09
Fax: (262) 724 89 05
E-mail: info@adalarkimya.com
national Poisen Cent (UZEM) 114
Emergency Call 112
2) HAZARDS IDENTIFICATION
2.1. Classification of substance and mixture
2.1.1. Classification according to Regulation (EC) No 1272/2008 [CLP]/GHS
Skin Corrosion/Irritation, Hazard Category 2, H315
Serious Eye Damage/Eye Irritation, Category 2, H319 Carcinogen, Category 2, H351
Specific Target Organ Toxicity, Single exposure, Hazard Category 3, Anesthesia H336

2.2. Label elements


Danger Signal

Warning Phrase Attention


Hazard statement H315 - Causes skin irritation
H319 - Causes serious eye
irritation
H336 - May cause drowsiness or
Decisive Components for Labeling Contains dichloromethane.
Precautionary Statements
(1) Prevention P201 Read special instructions before use.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
PART I
SAFETY DATA SHEET
This form has been prepared in accordance with the Regulation on Safety Data Sheets Regarding Harmful
Substances and Mixtures published in the Official Gazette dated 13.12.2014 and numbered 29204.

Substance/Mixture Name: UPHOLSTERY ADHESIVE


Preparation Date: 10.04.2019
New Edit Date: 10.04.2019
Number of Regulations: 01
Form No: A-S-00200
Sayfa 2 / 8

P280 Wear protective gloves/protective clothing/eye protection/face protection.


(2) Intervention P304 + P340+ P312 IF INHALED: Move victim to fresh air and breathe easily.
Hold it in a comfortable position. If you feel unwell, call the NATIONAL POISON ADVICE CENTER PHONE 114 or
your doctor/physician.
P308 + P313 IF exposed or concerned: Get medical advice/attention. P337 +
P313 If eye irritation persists: Get medical advice/attention
(3) Storage
(4) Disposal
2.3 Other damages
In case of fire, toxic fumes may be released.
3) COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Items
The substance is mixed.
3.2. Mixtures

Concentration
Substance name EINECS CAS No 67/548 EEC Classification
(%)
Resin 232-479-9 Not classified %35-40
Styrene Isoprene Rubber (SIS) 8050-26-8 Not Classified %33
Eye Irritation 2, H319
Dichloromethane 200-838-9 75-09-2 Skin Irritation 2, H315 %30-35
Carcinogenicity 2,

4) FIRST AID MEASURES


4.1. Description of first aid measures
General information First aid responders should take care of their own protection and use the recommended protective
clothing (chemical resistant gloves, splash protection). If there is potential for exposure, see Section 8
for concrete personal protective equipment.
If inhaled Remove person to fresh air. If not breathing, provide artificial respiration. If breathing is difficult, oxygen
should be given by qualified personnel. Call a doctor or transfer to a medical facility.
In contact with skin Wash with plenty of water.
In contact with eyes Rinse immediately with running water continuously for 15 minutes. Consult medical
personnel. Appropriate emergency eyewash fountain should be located nearby.
If swallowed Do not vomit. Immediately call a doctor and/or transport the patient to an
emergency facility.
4.2 Most important symptoms and effects, both acute and delayed
Apart from the information in the First Aid Measures (above), signs of emergency medical attention and special treatment needed
(below), other important symptoms and effects are described in Chapter 11.
4.3 Indication of any immediate medical attention and special treatment needed
Adequate ventilation and oxygenation of the patient should be ensured. Administer 100% oxygen therapy. Exposure may increase
"myocardial irritability". Do not use drugs that support the sympathetic system unless absolutely necessary. A physician should decide
whether to induce vomiting, as if inhaled it can be rapidly absorbed through the lungs and affect the whole body. If lavage is
performed, respiratory and/or esophageal control is recommended. When it comes to emptying the stomach, the risk of poisoning and
the danger of lung aspiration must be compared. If the burn has occurred, treat it as any thermal burn after cleaning the burned area.
There is no specific antidote. Supportive care. Treatment depends on the physician's judgment in response to the patient's reactions
PART I
SAFETY DATA SHEET
This form has been prepared in accordance with the Regulation on Safety Data Sheets Regarding Harmful
Substances and Mixtures published in the Official Gazette dated 13.12.2014 and numbered 29204.

Substance/Mixture Name: UPHOLSTERY ADHESIVE


Preparation Date: 10.04.2019
New Edit Date: 10.04.2019
Number of Regulations: 01
Form No: A-S-00200
Sayfa 3 / 8

Carboxyl hemoglobin can exacerbate pre-existing conditions that are susceptible to reduced oxygen uptake, such as chronic lung
disease, coronary artery disease or anemia. Skin contact may aggravate pre-existing dermatitis.

5) FIRE FIGHTING MEASURES


5.1. Fire extinguishers
Suitable fire extinguishers Water mist or fine spray. Dry extinguishing agent. Carbon dioxide fire extinguishers.
Foam. A carefully applied water mist can be used as a blanket for fire suppression.

Unsuitable fire extinguishers No data available


5.2. Special hazards arising from the substance or mixture
Hazardous combustion products: During fire, smoke may contain the original substance as well as unspecified toxic and/or irritating
compounds. Hazardous fire by-products can be the following and other products: Hydrogen chloride. Carbon monoxide. carbon
dioxide. Materials formed during combustion may contain traces of the following substances: Phosgene. Chlorine.
The container may leak gas or rupture due to fire. Although this material does not have a flash point, it can burn at room temperature.
Because vapors are heavier than air, they can travel long distances and accumulate in low-level areas.
5.3.Yangın söndürme ekipleri için tavsiyeler
Keep unnecessary people away; isolate the hazardous area and prevent unnecessary entry into the area. Stand against the wind. Stay
away from low areas where gases (fumes) can accumulate. Use water spray to cool fire-exposed containers and fire-affected areas
until the fire is out and the danger of re-ignition has passed. Immediately withdraw all personnel from the area if the noise from the
ventilation safety device increases or the container becomes discolored. Move container out of fire area if this can be done safely.
Burning liquids can be moved by spraying water to protect personnel and minimize property damage. A carefully applied water mist
can be used as a blanket for fire suppression.
Use an ambient-free high-pressure breathing apparatus and wear protective fire clothing (including fire helmet, coat, trousers, boots,
and neoprene fire gloves). If protective materials are not available or unavailable, fight the fire from a protected location or from a
safe distance.
6) ACCIDENTAL RELEASE MEASURES
6.1.Personal precautions, protective equipment and emergency procedures
Isolate the area. For further preventive measures, see Chapter 7, Usage. Unnecessary and unprotected personnel
prevent it from entering the area. Keep personnel away from low level areas. Keep personnel away from confined or poorly ventilated
areas. Take the wind behind your back where the material spills. Ventilate the area. Only trained and suitably maintained personnel
should perform cleaning operations. Before entering the area, the procedures for entering indoor areas must be fulfilled. Use
appropriate safety device. See Section 8, Exposure Control/Personal Protection for more information.
6.2. Environmental precautions
The material sinks in water. Do not allow to enter soil, ditches, sewers, drains, waterways and/or groundwater.
6.3. Methods and materials for containment and cleaning up
If possible, the spread of spilled material should be limited. Small spills: Collect in appropriately labeled, suitable containers. Large spills:
In case of overflow, ditch the area to prevent spread. Pump into appropriately labeled, suitable containers. See Chapter 13, Disposal
considerations for more information.
7) HANDLING AND STORAGE
7.1. Precautions for safe use
Do not swallow. Avoid contact with eyes and skin. Avoid breathing the vapour. Wash thoroughly after handling. Keep the container
closed. Use with proper ventilation. Containers, even emptied, may contain steam. Do not drill, grind, weld or similarly work on or near
empty containers. Do not enter confined spaces unless there is proper ventilation. To avoid uncontrolled emissions, transfer the steam
from the container to the storage tank. Since the vapors of this product are heavier than air,
PART I
SAFETY DATA SHEET
This form has been prepared in accordance with the Regulation on Safety Data Sheets Regarding Harmful
Substances and Mixtures published in the Official Gazette dated 13.12.2014 and numbered 29204.

Substance/Mixture Name: UPHOLSTERY ADHESIVE


Preparation Date: 10.04.2019
New Edit Date: 10.04.2019
Number of Regulations: 01
Form No: A-S-00200
Sayfa 4 / 8

It can build up in tanks, pits, small rooms, and even equipment used for degreasing metal parts (degreaser). vapors of this product.
Do not enter pits, closed and unventilated areas suspected of being present without using special breathing apparatus and a person
who can provide assistance if necessary. on CONTACT CONTROLS AND PERSONAL PROTECTION8. See section.

7.2. Conditions for safe storage, including any incompatibilities


Electric castings. Do not use or store near open flames, heat or sources of ignition. Keep the container tightly closed when not in use. Do
not store in the following places: Zinc. Aluminum. Aluminum alloys Plastic
7.3. Specific uses
See Section 1.2 for relevant identified uses.
Dichloromethane ACGIH TWA 50 ppm ACGIH TWA BEI TR OEL TWA (8 Hours) 1 740 mg/m3 500 ppm
8) EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1.Control parameters
Chemical Name Limits
Diklorometan ACGIH TWA 50 ppm
3
TR OEL TWA (8 Saat) 1 740 mg/m 500 ppm
8.2. Exposure controls
Appropriate engineering controls
Use engineering control methods to keep the concentration in air below the limiting conditions. Use only in enclosed systems or with
local exhaust ventilation unless applicable exposure limit requirements or guidelines are available. Exhaust systems should be designed
to remove air from the steam/aerosol generating source and from people working there. Lethal concentrations can be found in poorly
ventilated areas.
Personel protective measures

Hand protection Use gloves with chemical resistance classified under EN374. Protective gloves against chemicals and
microorganisms. Preferred impermeable materials for gloves include: viton, polyvinyl alcohol, Ethyl vinyl
alcohol laminate ("EVAL"). Acceptable glove sealing materials include: butyl rubber, In case of prolonged
and frequently repeated contact, it is recommended to use a glove of protection class 5 or higher
(penetration time greater than 240 minutes according to EN 374). If only brief contact is expected, it is
recommended to use gloves of protection class 3 or higher (penetration time greater than 60 minutes
according to EN 374). CAUTION: While choosing a glove for a specific application and usage period in the
workplace, the following should be considered, but not limited to: Other chemicals that may be handled,
physical requirements (cut/puncture protection, dexterity, heat protection), body reactions to the glove
material together with the glove supplier's recommended instruction/specification.

Eye Protection Use chemical goggles. Chemical protection glasses must comply with EN 166 or equivalent standards. If
exposure to vapor causes eye discomfort, use a full-face respirator

Breath Protection Concentrations in air should always be kept below the exposure limit. When respiratory protection is
required for some procedures, use an approved over-compressed air respirator. For emergency action
where the atmospheric level is unknown, use an approved self-contained, positive-pressure breathing
apparatus or positive-pressure, self-contained air line.
PART I
SAFETY DATA SHEET
This form has been prepared in accordance with the Regulation on Safety Data Sheets Regarding Harmful
Substances and Mixtures published in the Official Gazette dated 13.12.2014 and numbered 29204.

Substance/Mixture Name: UPHOLSTERY ADHESIVE


Preparation Date: 10.04.2019
New Edit Date: 10.04.2019
Number of Regulations: 01
Form No: A-S-00200
Sayfa 5 / 8

Use an approved over-compressed air respirator in confined or poorly ventilated areas.


Skin Protection Wear protective clothing that is impermeable to this material. The choice of protective materials such as
face shields, gloves, boots, aprons or full body suits depends on the process.
Other *
Environmental Exposure Controls Keep away from ditches, surface and ground water.
9) INFORMATION ON PHYSICAL AND CHEMICAL PROPERTIES
9.1.Basic physical and chemical properties
Appearance Liquid
Appearance Light cream, Red
Odor idiosyncratic
Density 1,10 - 1,17 g/cm3 at 19 - 21 °C
pH No data
Erime noktası / Donma noktası No data
Boiling point 80 °C at 1.013 hPa
Flash Point No data
Fluidity 70 -120 s at 19 - 21 °C
Flammability (Solid, gas) No data
Lower and upper flammability or Explosion No data
vapor pressure No data
vapor density No data
Relative density No data
Resolution No data
Partition coefficient (n-octanol/water) No data
auto ignition temperature No data
decomposition temperature No data
Viscosity No data
explosive properties No data
Oxidizing properties No data
9.2.Other Informations
No data
10) STABILITY AND REACTIVITY
10.1. Reaction
It is stable under normal conditions. It has no known reaction.
10.2.Chemical stability
No decomposition when used properly.
10.3. Possibility of hazardous reactions
Exposure to high temperatures may cause the product to decompose. Avoid open flames, welding sparks and other high temperature
sources that can provoke thermal decomposition. Protect from direct sunlight or sources of ultraviolet rays
10.4. Conditions to avoid
Exposure to high temperatures may cause the product to decompose. Avoid open flames, welding sparks and other high
temperature sources that can provoke thermal decomposition. Protect from direct sunlight or ultraviolet light sources.
10.5. Substances to be avoided
Avoid contact with materials that cause oxidation. Avoid contact with: Strong bases. Water contamination can cause corrosion as a
PART I
SAFETY DATA SHEET
This form has been prepared in accordance with the Regulation on Safety Data Sheets Regarding Harmful
Substances and Mixtures published in the Official Gazette dated 13.12.2014 and numbered 29204.

Substance/Mixture Name: UPHOLSTERY ADHESIVE


Preparation Date: 10.04.2019
New Edit Date: 10.04.2019
Number of Regulations: 01
Form No: A-S-00200
Sayfa 6 / 8

result of the formation of hydrochloric acid. Avoid contact with the following types of metals: Zinc dusts. Aluminum powders.
Magnesium powders. Potassium. Sodium. Avoid unconscious contact with: Amines
10.6. Hazardous decomposition products
The formation of hazardous decomposition products is dependent on temperature, air supply and the presence of other substances.
Decomposed products include, but are not limited to: Hydrogen chloride.
Material that may contain traces of decomposition products: Chlorine. phosgene
11) TOXICOLOGICAL INFORMATION
11.1. Information on toxic effects
Toxic effects It has been observed that methylene chloride increases the incidence of malignant tumors in mice and
benign tumors in rats. Animal studies for methylene chloride alone, as well as epidemiological studies in
humans, have shown no tumorigenic response. When used as recommended, methylene chloride is not
considered to have measurable carcinogenic effects in humans. Studies have shown that tumors seen in
mice are species specific. Studies in workers with concomitant exposure to methylene chloride and 1,2-
dichloropropane have reported increased incidences of cholangiocarcinoma.
Oral LD50>2000 mg/kg (rat)
Dermal LD50>2000 mg/kg (rat)
Respiratory In closed or poorly ventilated areas, vapors can accumulate easily and cause unconsciousness and death.
Vapors may cause irritation of the upper respiratory tract (nose and throat). Overexposure can impair the
blood's ability to transport oxygen, causing carboxyhemoglobinemia. Very little anesthetic or narcotic
effects may be seen at methylene chloride concentrations of 500-1000 ppm. Levels higher than 1000 ppm
can cause dizziness and intoxication, respectively, and concentrations of 10 000 ppm can cause
unconsciousness and death. In addition, these high levels can also cause irregular heartbeats. In addition,
these high levels can also cause irregular heartbeats.
LC50, mouse, 4 Hours, steam, 86 mg/l
Other Inhalation into the lungs during ingestion or vomiting may result in rapid absorption and damage by other
body systems.
12) ECOLOGICAL INFORMATION
12.1.Toxicity
Fish The substance is not harmful to aquatic organisms (LC50/EC50/IC50 greater than 100 mg/L).
LC50, Pimephales promelas (Carp calf), flow-through test, 96 Hours, 193 mg/l
NOEC, Pimephales promelas (Carp calf), flow-through test, 28 d, growth, 83 mg/l
Spineless LC50, Daphnia magna (Water flea), static test, 27 mg/l, OECD Test Guideline 202 or Equivalent
Alga EbC50, Pseudokirchneriella subcapitata (green algae), 96 Hours, Biomass, > 662 mg/l, OECD Test Guideline 201 or
Equivalent
12.2. Persistence and degradability
Permanence Biodegradation: Biodegradation may occur under aerobic conditions (if oxygen is present).
The rate of biodegradation may increase as the soil and/or water acclimate.
10-Day Window: Not applicable.
Biodegradation: 66 % Exposure
time: 50 Hours Method:
Simulation study
12.3. Bioaccumulation potential
Bioaccumulation Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition
coefficient ( n-octanol/water)(log POW): 1.25 at 20 °C Measured
PART I
SAFETY DATA SHEET
This form has been prepared in accordance with the Regulation on Safety Data Sheets Regarding Harmful
Substances and Mixtures published in the Official Gazette dated 13.12.2014 and numbered 29204.

Substance/Mixture Name: UPHOLSTERY ADHESIVE


Preparation Date: 10.04.2019
New Edit Date: 10.04.2019
Number of Regulations: 01
Form No: A-S-00200
Sayfa 7 / 8

Bioconcentration factor (BCF): 2 - 40 Fish. measured


12.4. Mobility in soil
Mobility potential in soil is very high (Poc between 0 and 50). Partition coefficient(Koc): 46.8 Estimated.
12.5. Results of PBT and vPvB assessment
This substance is not considered to be persistent, bioaccumulative and toxic (PBT). This substance is not considered to be very
persistent and very bioaccumulative (vPvB).
12.6. Other adverse effects
This substance is not among the ozone depleting substances listed in Annex I to Regulation (EC) No 1005/2009 (REACH).
13) DISPOSAL INFORMATION
13.1. Waste treatment methods
Disposal methods: This product, when disposed of unused and uncontaminated, must be considered hazardous waste under European
Community Directive 2008/98/EC. All disposal practices must comply with all national and regional laws and municipal or local
regulations governing hazardous waste. Additional assessments may be required for used, contaminated and residual materials. Do
not discharge into sewers, above ground or into any water. Uncleaned package: Containers, even emptied, may contain steam. Do not
drill, grind, weld or similarly work on or near empty containers.

14) TRANSPORT INFORMATION


14.1.UN Number
Not applicable
14.2. UN proper shipping name
Not applicable
14.3. Transport hazard class(es)
Not applicable
14.4.Packing group
Not applicable
14.5.Environmental damages
Not applicable
14.6. Special precautions for the user
Not applicable
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code
Not applicable
15) REGULATORY INFORMATION
15.1. Health, safety and environmental legislation specific for the substance or mixture
ADR - European Agreement on the International Carriage of Dangerous Goods by Road
IMDG Code - International Code on Dangerous Goods Transported by Sea
Recycling of Some Non-Hazardous Wastes (17.06.2011 /R.G. 27967) Waste Management
Regulation - (02.04.2015 / R.G. 29314)
Regulation on Health and Safety Measures in Working with Chemical Substances - (12.08
2013/ R.G.28733) Regulation on Use of Personal Protective Equipment in Workplaces -
(2.07. 2013 / R.G.28695)
Regulation on Safety Data Sheets Regarding Harmful Substances and Mixtures
15.2. Chemical safety assessment
No chemical safety assessment has been carried out.
PART I
SAFETY DATA SHEET
This form has been prepared in accordance with the Regulation on Safety Data Sheets Regarding Harmful
Substances and Mixtures published in the Official Gazette dated 13.12.2014 and numbered 29204.

Substance/Mixture Name: UPHOLSTERY ADHESIVE


Preparation Date: 10.04.2019
New Edit Date: 10.04.2019
Number of Regulations: 01
Form No: A-S-00200
Sayfa 8 / 8

16) OTHER INFORMATION


This SDS has been prepared within the information received from the raw material owner company.
Issuer Certificate
No: TSE/GBF-A- 2353

This safety information file applies to all products below.

UNIVEX 682, 683, 684 , 684-Y, 686, 686-Y, 688, 689

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