65. An average cup (250 mL) of coffee contains 125 mg of caffeine C8H10N4O2.

What is the molarity of caffeine in the coffee?

A. 0.0026 M C. 0.0078 M
B. 0.0033 M D. 0.0054 M

67. What is the volume of a 0.5 M KCl solution containing 25 g of KCL? Atomic
mass: K = 39.10; Cl = 34.45
A. 700 mL C. 745 mL
B. 680 mL D. 690 mL

69. How much water must be added to 100 mL of a 0.75 M solution of KCl to make
a 0.04 M solution?
A. 0.188 L C. 1.833 L
B. 1.775 L D. 1.918 L

71. To what volume must 10 mL of 10 M HNO3 solution must be diluted to produce

a 0.1 M solution?
A. 1000 mL C. 500 mL
B. 2000 mL D. 1500 mL

73. Commercial nitric acid is approximately 15.4 M. What volume of commercial

nitric acid must be used to prepare 5 liters of 6 M nitric acid?
A. 1.28 L C. 1.95 L
B. 1.83 L D. 1.42 L

75. How many mL of water must be added to 50 mL of 10 M HNO3 to prepare 4 M

HNO3?
A. 50 mL C. 125 mL
B. 250 mL D. 75 mL

77. How much 5% w/v NaCl solution can be prepared from 3 g of NaCl?
A. 60 mL C. 15 mL
B. 16.67 mL D. 167 mL

79. What is the molality of a solution which contains 20 g of cane sugar C 12H22O11
dissolved in 125 g of water?
A. 0.468 m C. 0.495 m
B. 0.424 m D. 0.477 m

81. A solution was 2.4 m and contained 245 g of solvent. Calculate the molality of
the solution after dilution with 125 g more of solvent.
A. 5.88 m C. 3.38 m
B. 2.29 m D. 1.59 m
83. Calculate the molality of an aqueous solution 2.24 m in sucrose, C 12H22O11.
Assume that the density of the solution is 2.05 g/mL
A. 1.65 m C. 1.55 m
B. 1.45 m D. 1.75 m

85. How many grams of 5% w/w NaCl solution are necessary to yield 3.2 g of NaCl?
A. 16 g C. 40 g
B. 10 g D. 64 g

87. Calculate the mole fraction of ammonia in a 2 m solution of NH3 in water.

A. 0.0347 C. 0.0235
B. 0.0419 D. 0.0512

89. Calculate the molality of an alcohol in aqueous solution if the mole fraction of
the alcohol is 0.15.
A. 9.8 m C. 6.9 m
B. 5.3 m D. 1.9 m

91. An aqueous solution of glucose, C2H12O6 has a mole fraction of 0.4 for glucose.
What is the molality of this solution?
A. 31 m C. 37 m
B. 46 m D. 54 m

93. The pH of a 0.001M HCl solution is ____.

A. 1 C. 5
B. 7 D. 3

95. Two hundred milliliters of 0.5 M HCl is diluted to 5 liters with water. What will
be its pH?
A. 1.4 C. 1.6
B. 1.5 D. 1.7

97. A gas has a density of 2 moles per liter at 0°C. Under what pressure is the gas?
A. 44.8 atm C. 58.2 atm
B. 50.2 atm D. 49.5 atm

99. An air compressor used for spraying paint has a tank capacity of 0.4 m 3 that
contains air at 27°C and 6 atm. How many moles of air does the tank hold?
A. 90 moles C. 106 moles
B. 116 moles D. 98 moles
101. Calculate the pressure of 0.444 mol of gas in a sample occupying 666 mL at
-8°C.
A. 1580 kPa C. 1420 kPa
B. 1640 kPa D. 1470 kPa

103. How many moles of Helium are needed to fill a balloon that has a volume of
6.45 L and a pressure of 800 mm Hg at a room temperature of 24°C? Assume ideal
gas behavior.
A. 0.265 C. 0.278
B. 0.255 D. 0.223

105. Calculate the density of carbon dioxide at 0.99 atm and 55°C.
A. 1.62 g/L C. 1.19 g/L
B. 1.32 g/L D. 1.94 g/L

107. A weight of 15 g of NO gas in a 2.24-liter container at a temperature of 273°C

will be under what pressure?
A. 10 atm C. 7 atm
B. 8 atm D. 9 atm

109. The density of nitrogen is 1.25 kg/m3 at STP. Determine the density of nitrogen
at 42°C and 730 mm mercury.
A. 1.40 kg/m3 C. 1.90 kg/m3
3
B. 1.09 kg/m D. 1.04 kg/m3

111. A 500 mL sample of gas in a cylinder with a movable piston at is heated at STP
constant pressure to 41°C. What is the final volume?
A. 157,000 mL C. 575 mL
B. 435 mL D. 150 mL

113. Given a 500 mL sample of H2 at 2 atm pressure. What will be the volume when
the pressure is changed to 720 torr?
A. 237 mL C. 474 mL
B. 528 mL D. 1060 mL

115. A 100 ft3 volume of nitrogen at 27°C and 15 psia is compressed to fill a tank
that is initially empty and has a volume of 5 ft 3. If the final temperature of the
nitrogen is 17°C, what is the absolute pressure in the tank?
A. 290 psia C. 330 psia
B. 180 psia D. 240 psia

117. The volume of one mole of gaseous water at 100°C and 1 atmosphere pressure
is ____.
A. 18.8 L C. 22.2 L
B. 40.2 L D. 30.6 L
119. Mercury is a gas at 500°C. What is the average energy of mercury atoms at this
temperature?
A. 1.2 × 10-20 J C. 1.4 × 10-20 J
B. 1.6 × 10-20 J D. 1.8 × 10-20 J

121. The average kinetic energy of nitrogen molecules changes by what factor when
the temperature is increased from 30°C to 60°C.
A. 30 C. 2
B. ½ D. 28

123. Compute the rms speed of O2 molecules at STP.

A. 461 m/s C. 489 m/s
B. 428 m/s D. 456 m/s

125. At what temperature will the molecules of an ideal gas have twice the rms
speed they have at 20°C?
A. 900°C C. 960°C
B. 940°C D. 920°C

127. An object must have a speed of at least 11.2 km/s to escape from Earth’s
gravitational field. At what temperature will the rms speed for H 2 molecules equal
to the escape speed?
A. 1.0 × 104 K C. 1.5 × 104 K
B. 1.2 × 104 K D. 1.8 × 104 K