Analytical Chem CC - quanti

Stoichiometry

1. If a penny has a molar mass of 2.51 g/mole, what is the mass of 1.00 millimole of pennies?
(1 millimole = 1 × 10−3 mole)
A. 1.51 × 1021 g B. 2.51 × 103 g C. 6.02 × 1020 g D. 2.51 × 10−3 g E. 2.38 × 1022 g

2. The molar mass of boron is 10.81 g/mole. What is the mass of a single boron atom?
A. 1.661 × 10−24 g B. 1.795 × 10−23 g C. 6.510 × 1024 g D. 1.536 × 10−25 g E. 1.081 × 101 g

3. The molar mass of nitrogen (N2) is 28.0 g/mole. What is the mass of a single nitrogen atom?
A. 2.32 × 10−23 g B. 4.65 × 10−23 g C. 9.30 × 10−23 g D. 4.30 × 10−22 g E. 8.43 × 10−22 g

4. What mass of chlorine is present in 5.00 grams of carbon tetrachloride (CCl 4)?
A. 0.130 g B. 1.15 g C. 0.564 g D. 4.61 g E. 0.922 g

5. How many atoms are present in 5.00 grams of iron?

A. 8.95 × 10−2 atoms B. 3.36 × 1018 atoms C. 1.88 × 1021 atoms D. 5.39 × 1022
atoms E. 3.36 × 1026 atoms

6. . How many hydrogen atoms are present in 1.0 g of NH3?

A. 0.059 atoms B. 0.18 atoms C. 3.5 × 1022 atoms D. 1.1 × 1023 atoms E. 1.2 × 1022 atoms

Empirical and Molecular Formula

7. Isopentyl acetate, a molecule composed of C, H, and O, smells like bananas. Combustion

analysis of 1.750 grams of this molecule yields 1.695 g H2O and 4.142 g CO2. What is the
simplest formula for isopentyl acetate?
a. C7H14O2 b. C7H7O4 c. C8H10O3 d. C8H16O e. C9H6O

8. Combustion analysis of 0.800 grams of an unknown hydrocarbon yields 2.613 g CO 2 and

0.778 g H2O. What is the percent composition of the hydrocarbon?
a. 66.6% C; 33.4% H b. 82.3% C; 17.7% H c. 89.1% C; 10.9% H
d. 92.4% C; 7.60% H e. not enough information given to solve the problem
9. Soft drink bottles are made of polyethylene terephthalate (PET), a polymer composed of
carbon, hydrogen, and oxygen. If 2.8880 g PET is burned in oxygen it produces 1.0000 g
H2O and 6.1058 g CO2. What is the empirical formula of PET?
a. CHO b. CH7O5 c. C5H7O d. C8H10O e. C10H8O5

10. Nitrogen and oxygen form an extensive series of oxides with the general formula NxOy.
What is the empirical formula for an oxide that contains 30.44% by mass nitrogen?

a. N2O b. NO c. NO2 d. N2O3 e. N2O5

11. Find the mass of water of crystallization in 6.0 g hydrated copper(II) sulphate,
CuSO4 • 5H2O.
A. 0.36 g B. 0.43 g C. 0.61 g D. 2.17 g

12. A compound contains 42.9% C, 2.4 % H, 16.6 % N an 38.1 % O. The addition of 3.16 g
of this compound to 75.0 ml of cyclohexane (d= 0.779 g/cm3) gives a solution with a
freezing point at 0.0oC. What is the molecular formula of the compound. ( Freezing point
of cyclohexane is 6.50oC and Kf = 20.2oC/m.
A. C2H3NO B. C3H2NO2 C. C4H6N2O2 D. C6H4N2O4

13. A 40.0 ml sample of 0.25 M KOH is added to 60.0 ml of 0.15 M Ba(OH) 2. What is the
molar concentration of OH –(aq) in the resulting solution.(Assume that the volumes are
additive)
A. 0.10 B. 0.19 C. 0.28 D. 0.40

14. A solution containing 2.95 g solute of in 100 g cyclohexane had a freezing point
of 4.18°C, pure cyclohexane has a fpt of 6.50°C. The molal freezing point constant of
cyclohexane is 20.2°C /molal. 
a. What is the molecular mass of the solute?
A. 128 B. 160 C. 192 D. 256
b. . if the solute is sulfur , what it is molecular formula
A. S8 B. S6 C. S5 D. S4

Titration
15.Which of the following statements concerning the apparatus routinely used for titration
is INCORRECT?
A. Pipette is used to transfer a fixed amount of a solution accurately.
B. Measuring cylinder is used to deliver variable volumes of a solution accurately.
C. Electronic balance is used for fast and accurate weighing.
D. Volumetric flask is used to make up a certain solution to a specific volume accurately.
16. A solution containing 25.3 ml of 0.1065 N HCl is added to one containing 92.2 ml of 0.2715
M H2SO4 and 50.0 ml of 1.00 N KOH are added. The final solution is ______.
A. is alkaline B. acid C. neutral D. cannot be determined

17. How many ml of 6.0 M H2SO4 would be required to neutralize 100 ml of 3 M NaOH
solution?
A. 25 ml B. 40 ml C. 50 ml D. 75 ml

18. How many drops of 0.1 M HNO3 solution are required to neutralize 15 drops of 0.2 M
Ba(OH)2 solution?
A. 40 B. 50 C. 60 D. 70

19 . A 0.5000g sample of pure CaCO3 is dissolved in water to which 50.00 ml of HCl solution
have been added. The solution then requires 6.20 ml of NaOH solution of which 1.000ml =
1.110 ml of HCl. What is the normality of the HCl solution?
A. 0.2307 B. 0.2284 C. 0.3125 D. 0.3540

20. what is the percentage of total acid expressed as acetic acid in a sample of vinegar if 3.000
g of the vinegar require 20.50 ml of 0.1150 N KOH solution for an end point with
phenolphthalein indicator?
A. 3.21% B. 4.33 % C. 4.72 % D. 5.21 %

21. In the analysis of a 2.00 g sample of lime by titration with H2SO4 ,

A. 0.15 N B. 0.20 N C. 0.25 N D. 0.30 N

22. A mixture of Na2CO3 and BaCO3 weighing 0.2000 g requires 30.00 ml of 0.1000 N acid for
complete neutralization. What is the percentage Na 2CO3 in the sample?
A. 55.7 % B. 44.3 % C. 50.5 % D. 49.5 %

23. What wt of BaCO3 should be added to 1.000 g Li2CO3 so that the mixture will require the
same volume of the standard acid for neutralization as would the same weight of CaCO 3?
A. 0.719 g B. 0.450 g C. 1.005 g D. 0.985 g

24. A sample consisting of Na2CO3, NaOH and inert matter weighs 1.179 grams. It is titrated
with 0.3000 N HCl with phenolthalein as the indicator, and the solution became colorless after
the addition of 48.16 ml. Methyl orange is then added and 24.08 ml more of the acid are
needed for the color change. What is the percentage of Na 2CO3 in the sample?
A. 24.51% B. 64.95% C. 4.06% D. 76.15%

25. What is the normality of a solution of KOH if 45.18 ml are required to neutralize 0.300 g of
pure oxalic acid(H2C2O4.2H2O)?
A. 0.1053 B. 0.1153 C. 0.2135 D. 0.3125

26. Calculate the alkaline strength of pearl ash ( impure potassium carbonate) in terms of
percent K2O from the following data: Sample = 0.3500 g; HCl used = 48.03 ml; NaOH used
for back titration = 2.02 ml; 1.000 ml HCl= 0.005300 g Na 2CO3 ; 1.000 ml NaOH = 0.02192 g
KHC2O4.H2O
A. 45.2 % B. 54.0% C. 60.5 % D. 65.8 %
27. What weight of sample of impure oxalic acid should be taken for titration by 0.5000 N
NaOH so that the percentage of H2C2O4.2H2O will be twice the buret reading?
A. 0.0315 g B. 0.063 g C. 1.89 g D. 2.280 g

28. What volume of a 1 M solution of hydrochloric acid is required to neutralize 80 ml of a

0.50 M NaOH solution?
A. 320 ml B. 160 ml C. 80 ml D. 40 ml

29. How many ml of 0.200 M NaOH will completely neutralize 100 ml of 0.250 M H 2SO4?
A. 125 B. 175 C. 225 D. 250
Ans. D

30. When 50 ml of nitric acid solution was titrated with 0.334 M NaOH, it required 42.80 ml of
the base to achieve the equivalence point. What is the molarity of the nitric acid solution?
A. 0.286 b. 0.826 C. 0.682 D. 0.628

31. A 0.250 g sample of the solid acid was dissolved in water and exactly neutralized by 40.0
ml of 0.125 N base. What is the equivalent weight of the acid?
A. 40 B. 44 C. 48 D. 50

32. A 48.4 ml sample of HCl solution requires 1.24 g of pure CaCO 3 for complete
neutralization . Calculate the normality of the acid.
A. 0.512 B. 0.476 C. 0.412 D. 0.386

33. A 25 ml sample of 0.024 M HBr is mixed with 25.0 ml of 0.023 M KOH . What is the pH of
the resulting mixture?
A. 1.90 B. 3.30 C. 7.00 D. 11.7

34. A student is titrating 50 ml of 0.20 N HCl solution with a solution of 0.2 N KOH. He
accidentally adds one ml too much titrant. What is the pH of the resulting solution?
A. 10.3 B. 11.3 C. 2.7 D. 7.3

35. A sample of impure sulphide ore contains 42.43% Zn. Find the percentage of pure ZnS in
the sample.
A. 67.10 % B. 63.10 % C. 56.05 % D. 52.15 %

36. A sample of impure cuprite Cu2O contains 66.6% copper. What is the percentage of pure
Cu2O in the sample?
A. 45 % B. 55% C. 65 % D. 75 %

37. A 1.2048 g of impure Na2CO3 is dissolved and allowed to react with a solution of CaCl 2. The
resulting CaCO3 after precipitation, filtration, and drying was found to weigh 1.0362 g.
Assuming that the impurities do not contribute to the weight of the precipitate, Calculate the
percent purity of Na2CO3.
A. 86.2% B. 88.9 % C. 91.1 % D. 93.2 %
38. Hydrogen peroxide maybe oxidized to O2 or it may be reduced to H2O. Which represents
the milliequivalent weight of H2O2 as an oxidizing agent and as a reducing agent?
A. 0.03402 B. 0.01134 C. 0.00851 D. 0.01701

39. Calculate the normality of NaOH if 10 ml of NaOH reacts with 20 ml of 0.4 M sulphuric acid.
A. 1.6 N B. 0.8 N C. 2.6 N D. 3.2 N

40. What volume of of 0.224 N adipic acid solution would be used in the titration of
1.022cm3 0.0317 N Ba(OH)2
A. 1.20 ml B. 1.45 ml` C. 2.05 ml D. 3.60 ml

41 . What is the equivalent weight of an acid 1.243 g of which required 31.72 cm 3 of 0.1923 N
standard base for neutralization?
A. 180 B. 194 C. 204 D. 210

42 . What volume of 0.115 M HClO4 solution is required to neutralize 50.00 ml of 0.0875 M

NaOH?
A. 0.115ml B. 38.0 L C. 38.0 ml D. 50.0 ml

43. What volume of 0.128 M HCl is required to neutralize 2.87 g of Mg(OH)?

A. 0.0126 L B. 0.385 L C. 0.769 L d. 22.4 L

44. Tartaric acid H2C4H4O8 has two acidic hydrogens. The acid is often present in wines and
precipitates from solution as the wine ages. A solution containing an unknown concentration
of the acid is titrated with NaOH. It requires 22.62 ml of 2.000 M NaOH solution to titrate
both acidic protons in 40.00 ml of tartaric acid solution. Calculate the molarity of the tartaric
acid.
A. 0.02262 M B. 0.04524 M C. 0. 5655 M D. 1.131 M

45. A 15.10 g sample of an unstable hydrated salt , Na2SO4 .xH 2O was found to contain 7.05 g
of water. Determine the empirical formula of the salt.
A. Na2SO4.3H2O B. Na2SO4.4H2O C. Na2SO4.6H2O D. Na2SO4. 7H2O

46. A 3.592 g sample of hydrated magnesium bromide, MgBr2⋅xH2O, is dried in an oven. When
the anhydrous salt is removed from the oven, its mass is 2.263 g. What is the value of x?
A. 1 B. 3 C. 6 D. 8 E. 12