CHEMISTRY 12 – ACID / BASE MIXTURES WORKSHEET

1) What [H3O+] results when 25.0 mL of 1.0 M HCl is mixed with 15.0 mL of 0.30 M KOH?
(3 marks)

[ HCD =

1.0Mx2y5j0ommEn-O.63M0HCtHttClO.b3MO.63MCKOtD-O.30Mxly5jo0nmnf-O.llm0KOHsskttOHO.lMo.lMCHsOtJxs-CH3OD5-COHTsT-O.63-0.l1-0.5eHCD-O.l5oMx60.o0ommEn.O.045oMo@HCtsHttCl2O0O.O45OMO.0450MCeK0tD-O.lO0Mxl40.O

2) Calculate the pH of a solution prepared by adding 60.0 mL of 0.150 M HCl to 140.0 mL of 0.100 M
KOH. (4 marks)

2007
MO
]×s
CHZOTST
0.0700M¥
ml Ktt
KOH OH
.

0.0700 M 0.0700 M

[ OH =
[ OH
-

]st -

= 0.0700 -
0.0450
= 0.0250

Cott ]
'

POH log
-
=

)
=
-

log ( 0.0250
= 1.602 0

PH +
POH = 14.00

+1.602 = 14.00
×

× = 12.40 0
 3) Calculate the [H3O+] in a solution prepared by mixing 25.0 mL of 1.0 M HCl with 50.0 mL of 0.50
M KOH. (3 marks)

[ HCD -

4) Calculate the pH of a solution prepared by mixing 15.0 mL of 0.50 M HCl with 35.0 mL of 1.0 M
l.OMx25.o0ommEnaO.33M0HCtHttCl75O.33M0.33MCeKOtD-O.5OMx50.0ml0.330KOHssKttOHFom.MO.33MO.33MsincetheCH3OD-COHT.theresollingsolu.tonisneutralCpH-3andtheCHsoD-l.Ox1o7mQthisttcanbememorizedorcanbecakulatedusing.CH3oJ.kjPIx.0x1o7mCeHCD-O.5OMxl5.0mL-O.l5M@HCtHttCl5O.0mLO.l5MO.l5MHaOtD-1.OMx35.O

NaOH. (4 marks)

s#L= ml
Natt
NAH
Opom
OH
0.704
.

0.704005 CHEST
]×s=[
]st

MO
[ OH OH
'
-

= 0.70 -

0.55
]
'

0.15=0.55
pOH=
-

logcott

13.740
)
=
-10g (
14.00×+0.26=14.00
0
= 0.26

pH+pOH -

× =
 5) Calculate the pH of a solution prepared by adding 15.0 mL of 0.500 M H2SO4 to 35.0 mL of 0.750
M NaOH. (4 marks)

50.07
[

Natt
ml
NAH OH
.

0.525 M 0.52514

(0-225)
CHEST
]×s=[
0.300=0.225
0.525M¥
]st

MO
[ OH OH
'
-

14.00×+0.648=14.00 = 0.525 -

HaSOBaO.5O0Mxl5.0mL_aO.l5oM@H2SOfs2HttSO425O.OmLO.l5OM0.3O0MHaOtD-O.500Mx35.O

]
'

POH
=
-

logcott
=
-10g
= 0.648 0

pH+pOH=

× = 13.35 0
6) What mass of HNO3 must be added to 250.0 mL of 0.0150 M Al(OH)3 to produce a solution with a
pOH of 2.310, if it is assumed that there is no change in volume when the HNO3 is added?
(4 marks)
basic :[ OH ] in excess
'

:
POH
-
-
2.310 .
.

"

[ OH -]=loP0 AKOHB -
Aptt

30+5=10-2.310
490×103=0.0450
0.0150N

0.045014=4.90×10740
[ OH -]×s= ( OH ]st
'

-
( HNDST
-

X
HNO } H++NO5
X = 0.04am 1

0.04AM 0.040N

0.25002×0.0401 mol 63.0g

GHNO } =

# mol

0.632g
2
=