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Electrochemistry
(전기화학)
Mon: 12 pm – 2:45 am
※ Presentation 40 %
※ Final exam 45 %
※ attendance 10 %
※ attitude 5%
40 % 45 % 5% 10 % 100 %
Expected Schedules
1주차 General electrochemistry 9주차 Presentation
2주차 Electrochemical cells
3주차 Electrochemical cells 10주차 Electrochemical methods
11주차 Electrochemical Applications
4주차 Presentation 12주차 Electrochemical Applications
13주차 Presentation
5주차 Presentation
4
Textbook
• Electrochemical Methods, Fundamentals and Applications,
2nd edition, by A. J. Bard and L. R. Faulkner (main)
6
Properties of electrolytes
κ : conductivity [S/cm]
G: conductance [S]
l : distance of separating charged plates [cm]
A : cross-sectional area [cm2]
Kinetics of electrochemistry
Current-overpotential
relation
8
Mass transfer
Nernst-Plank
equation
Diffusion Migration
Convection
9
Li-ion Batteries (LIBs)
Discharge
Charge
Electrode
Dielectri
c
• 𝐶 ∶ Capacitance
ε𝑟ε0𝐴 • E : Specific energy density
𝐶 = E = 1/2𝐶𝑉2 • ε𝑟 : dielectric constant of materials
𝑑 • ε0 : Permittivity of vacuum
• d : effective thickness of double layer
• A : effective surface area of electrode