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e = oom 10.10 LO16-14"BASAL SAND” Oct-96 Fluo AALye Loertos CENTRAL FILE ClOscisss = - SOSCIENCES Resenor Fut Suey Wife * for . PETRO-TECH PERUANA S.A. Lo16-14 Lobitos Talara-Offshore CENTRAL FILE GEOSCIENCES RFL 96190 21-0c-96 A product of Core Laboratories Venezuela, S.A. ‘The snales, opisions or interroations conan in this report are based upon obeerations and material supplied by the chin! for whose crclusve and confderial use this repo has been race. The interpretations o oinons expressed represent the bet judgement of Core Laboratories. Core Laboratories assumes no responsibly and makes no varranty of representations, express of implied, a3 10 the Productivity, proper operations or proftabieness, however, of any ol gas, coal oF cher mineral, propery, wel or sand in eemnecion with "wich sch report is used or relied upon for any reason whatever e e ((RRe48 CORE LABORATORIES | VENEZUELA, S.A. RFLC9610.010 October 21, 1996 PETRO-TECH PERUANA, S.A. Av, Los Incas 460. Lima 27-Peri Attention: Mr. John W. Mayers Production Manager Subject: Reservoir Fluid Study Well: LOI6-14 Field: LOBITOS File: REL 96190 Gentlemen: Separator gas and liquid samples from the subject welll were collected by representatives of Core Laboratories Venezuela, S.A. on July 24, 196. The samples were delivered to our fluids laboratory in Maracaibo for use in the performance of a reservoir fluid study. The final report of this study ‘may be found on the following pages It has been a pleasure 10 perform this reservoir fluid study for PETRO-TECH PERUANA, S.A. Should any questions arise or if we may be of further service in any way, please do not hesitate 10 contact us. Sincerely, CORE LABORATORIES VENEZUELA, S.A. CENTRAL FILE briny A per GEOSCIERICES ‘James Fortner (/ Manager Reservoir Fluids Lab JFisr. Callo 25 (via a EI Mojén) Km 3, al lado de la Pepsi-Cola, Apartado 116, Maracaibo, Edo, Zulia Telfs.: (061) 575484 - 572922 - 579423 - 579849 - 578715 - 578225, Fax: (061) 578684 - 910987 TABLE OF CONTENTS Laboratory Procedures. Summary of PVT Data. General Well Information. Quality Control of the Samples... Separator Gas Composition. Separator Liquid Composition. Recombination Data. Welistream Composition... Pressure Volume Relations. Differential Vaporization. Viscosity of Reservoir Fluid Separator Tests. Composition of Separator Test Gases... Differential Vaporization Data Adjusted to Surface Conditions. Nomenclature and Equations... RFL 96100 Page 22 23-25 26 - 30 Appendix CENTRAL FILE GEOSCIERICES CORE LABORATORIES. Relative Volume ¥-Function Relative Oil Volume Solution Gas/0it Ratio Oi Density {Incremental Gas Gravity Deviation Factor, Z Reservoir Fluid Viscosity ‘Single-Phase Oil Viscosity ‘Solution Gas / Oil Relation ‘Single-Phase Oil Viscosity RFL 96190 LIST OF FIGURES Pressure-Volume Relations Differential Vaporization Viscosity Analysis Differential Veporization Data Adjusted to Surface Conditions fg Al A2 Bl B2 B3 BS cr Dl D2 CENTRAL FILE GEOSCIENCES CORE LABORATORIES. ORATORY PROCEDURES PETRO-TECH PERUANA, S.A. Reservoir Fluid Study LOI6-14 Well Lobitos Field RFL 96190 On July 24 of 1996, separator gas and separator liquid samples were collected by Core Laboratories representatives and delivered to our Maracaibo laboratory. The quality checks were performed at laboratory temperature, measuring the bubble point pressure of the separator liquid samples, opening pressures and air content for the separator gases. A summary of the samples received may be found on page four (4) The composition of the separator gas was measured through Cy. by routine, and temperature programmed chromatography. The composition of the separator liquid was measured through Czo. using the spikeflash/chromatography technique. The results of these analyses are presented on pages five (5) and six (6), respectively After correcting the separator gas and stock tank liquid production rates for the factors shown on page seven (7), the producing gas-liquid ratio was calculated to be 683 cubic feet of separator gas at 14.7 psia and 60 °F per barrel of separator liquid at 40 psig and 62 °F, This gas/liquid ratio was used in conjunction with the measured hydrocarbon compositions of the separator products to calculate the reservoir fluid composition. This composition is presented on page eight (8). The gas and liquid samples were then physically recombined at their producing gas/liquid ratio, and the resulting fluid was used for the remainder of the study. A portion of the recombined reservoir fluid was charged to a high pressure, windowed cell and then heated to the reported original reservoir temperature of 129 °F. During the constant composition expansion at this temperature, a bubble point was observed at 3580 psig. The results of the pressure-volume relations are presented on pages nine (9) through twelve (12). During the differential vaporization at the reservoir temperature, the fluid evolved a total of 731 cubic feet of gas at 14.7 psia and 60 °F per barrel of residual oil at 60 °F. The resulting relative oil volume factor was 1.350 barrels of saturated fuid per barrel of residual oil at 60 °F. The oil density and the properties of the evolved gases were measured at each point during the differential pressure depletion. The data are included in the summary of the differential vaporization analysis on pages thirteen (13) through eighteen (18). CENTRAL FILE GEOSCIENCES PETRO-TECH PERUANA, S.A. LO16-14 WELL File: RFL 96190 The viscosity of the reservoir fluid was measured over a wide range of pressures at reservoir temperature in a rolling-ball viscosimeter. The viscosity of the fluid was found to vary from a minimum of 0.92 centipoises at the saturation pressure to a maximum of 3.72 centipoises at atmospheric pressure. The results of the viscosity measurements are presented on pages nineteen (19) through twenty-one (21). Small portions of the reservoir fluid were subjected to three separator tests to determine the effects of separator pressure on gas/oil ratio, stock tank oil gravity and formation volume factor. These data can be found on page twenty-two (22). The separator gases from the separator tests were collected and chromatographically analyzed in the laboratory. The results of the separator gas compositions are presented on pages twenty three (23) through twenty-five (25). The separator test data were then used to adjust the differential vaporization results. The adjusted differential vaporization data are presented on pages twenty-six (26) through thirty (30), The report includes graphical representations with analytical expressions which model the data sets as a function of pressure at the reported reservoir temperature. An appendix is also provided which defines the nomenclature and extends the analytical relationships CENTRAL FILE, GEOSCIBNCES PETRO-TECH PERUANA S.A. Lo16-14 RFL 96190 SUMMARY OF PVT DATA Reported Reservoir Conditions Average Reservoir Pressure 4216 sig Average Reservoir Temperature . 129 * Pressure-Volume Relations Saturation Pressure 7 3580 psig ‘Avg Single-Phase Compressibilty 8.85 6 whips ( 5000 to 9580 psig ) ‘Thermal Exp @ 5000 psig 1.03834 Vat 129°F /Vat6orF Differential Vaporization Data ( at 3580 psig and 129°F ) Solution Gas/Oil Ratio 731 ‘cf bbl of residual ol at 60°F Relative Oil Volume 1,360 BbI/ bof resiaual ol at 60°F Density of Reservoir Fluid 0.7263 gee Reservoir Fluid Viscosity 0.820 ep at 2580 psig and 129 °F Separator Test Results Separator Conditions Formation | Total Sotution | Tank oil Gravity Volume Factor | Gas/OilRetio | (API at60°F) psig *F a © 135 70 1317 681 338 80 70 1.319 685 337 40 70 1.328 702 338 (A) Barrels of saturated ol per bare of stock tank ol at 60°F, (@) Tota! standard cubic oot af gas per barrel of stock tank ol at 60 °F Page t CENTRAL FILE GEOSCIENCES: CORE LABORATORIES General Well Information PETRO-TECH PERUANA S.A. Lo16-14 RFL 96190 Company. PETRO-TECH PERUANA S.A, Well Name. Lot6-14 ‘API Well Number. . File Number... RFL 96190 Date Sample Collected. 24-Jul-86 ‘Sample Type. Separator Geographical Location, Talara-Offshore Field Lobitos Well Description Formation, Basal Salina Poo! (or Zont Lobitos Offoshore Date Completed... Elevation, ft Producing Interval 9464-9460MD. ft Total Depth 5 ft Tubing Size, 0 in Tubing Depth. o ft Casing Size 51/2" in Casing Depth. Plug at 9750MD tt Pressure Survey Data Data from Original Discovery Well Date 12-Dec-95 Reservoir Pressure 4216 psig Data at Sample Collection Date. 24-Jul-96 Reservoir Pressure. . Reservoir Temperature, 4129 Pressure Tool . ig Flowing Bottorn-Hole Pressure, 1360 psig Flowing Tubing Pressure, 135 psig * Data not forvarded io Gore Laboratories CENTRAL FILE GEOSCIENCES Page2 CORE LABORATORIES PETRO-TECH PERUANA S.A. Lo16-14 RFL 96190 Production Data Data from Original discovery Well Location Lobitos Offshore Date. : 13-Apr-96 Oil Gravity @ STP. . u “APL Separator Pressure . psig Separator Temperature. . °F Production Rates Gas, . 177 Msct/O Liquid, : 1120 STbbuD GassLiquid Ratio... . 694 seffobl Separator Conditions Primary Separator Pressure. 40 psig Primary Separator Temperature. 62 F Secondary Separator Pressure. C psig Secondary Separator Temperature. cl °F Primary Separator Gas Production Rate. 7 Msc Gas Factors - Field Values: Pressure Base, 147 sia Temperature Base 60 °F Compressibilty Factor (Fpv) 1.0029 Gas Gravity Factor (Fg)... 1.2082 Laboratory Vaiues: Pressure BASE... nonin 147 psie Temperature Base... snnscnnnnn 60 F Compressibity Factor (Fv), 4.0047 Gas Gravity Factor (Fg) 1.1964 ‘Adjusted Primary Separator Gas Prod Rate. 770 Msc Primary Separator Liquid Rate 1128 boVD at 62°F Stock Tank Liquid Rate. 1120 bolD at 60 °F Separator Gas / Separator Liquid Ratio. seffobl Separator Gas / Stock Tank Liquid Ratio. seffobl Stock Tank Liquid / Separator Gas Ratio. boIMscf ‘Separator Liquid / Stock Tank Liquid Ratio. 1.007 bolbbl at 60 °F "Data nat forwarded to Core Laboratories, CENTRAL FILE Pages GEOSCIENCES core \asoratories PETRO-TECH PERUANA S.A. Lo16-14 RFL 96190 PRELIMINARY CHECKS OF SAMPLE QUALITY AND SUMMARY OF SAMPLES RECEIVED Separator Gas ‘Sampling Conditions: Laboratory Opening Conditions Cylinder Number Air psig - psig - Content (mot %) 49233 40 2 38 70 0.33 A-togea* 40 62 38 70 ost ‘Separator Liquid ‘Sampling Conditions | Laboratory Bubblepomnt cylinder Number Water psig - psig - Recovered (ce) cv-03-0003 40 62 40 70 0 4642130" 40 62 40 2 ° * These samples selected for recombination and further analysis. CENTRAL FILE . GEOSCIENCES age 4 CORE LABORATORIES PETRO-TECH PERUANA S.A. Lot6-14 RFL 96190 COMPOSITION OF PRIMARY STAGE SEPARATOR GAS (by Programmed-Ternperature, Capilary Chromatography) rant] Liquid Component Mol% | Products| Densay | Mw «cpm | (gies) Hydrogen Sulfide 0.00 Carton Dioxide on 8172 44010 Nitrogen 0.25 0.808 28013 Methane e472 02007 16.043 Ethane 669 © 1.784 03862 30070 Propane 4161143 05070 44097 |so-Butane 108 0348 05629 58123 Butane 162 0509 0580 58123 iso-Pentane ost 0188 06264 72.150 -Pertane 034 0123 Ogst1 72.150 Hexanes, 024 0093 0.6850 840 Heptanes 018 0078 0720 980 Octanes 010 0045 07450 107 Nonanes 002 0010 07640 121, Tous. TOOT ABS] Properties of Plus Fractions Lugua | Ucuia CCompenent Moi | Density | api | mw (amvice) | Gravity Heptanes plus 030 o7ss2 613 1013 Note: Component properties assigned rom iterature, “ref: Gas Producers & Suppliers Association (GPSA) Engineering Data Book Pages ‘SAMPLING CONDITIONS 40 psig 62°F Gas Cyinder ‘10969 ‘Average Sample Properties Ctical Pressure, psia 6809 Critical Temperature, 3083 ‘Average Molecular Weight 2023 Caleulated Gas Gravity (ar = 1.000 ) 0.699 at 147 psia and 60°F Heating Value, Btulsc ery cast G1088 ses 1228 CENTRAL FILE GEOSCIENCES CORE LABORATORIES. PETRO-TECH PERUANA S.A. Lot6-14 RFL96190 COMPOSITION OF PRIMARY STAGE SEPARATOR LIQUID (by FlastvExtended Chromatography) guid ‘Component Moi | wea | Density | Mw (emvee) Hysrogen Sutide 000 0.00 SAMPLING CONDITIONS Carbon Dioxide 000 0.00 Nitrogen 001 0.00 asoes 28.013 40 psig Methane 087 007 029607 16.043, 62°F Ethane 058 008 03562 30.070 Propane 184 033 05070 44097 Iso-Butane 261 073 0se29 58.123 Butane 328 091 058d 58.123, iso-Pentane 247 085 06248 72.150 Liguid Cynder r-Pentane 181 063 oss1t 72180 4642130 Hexanes 408 163 06850 840 Heptanes 832 383 07220 960 Octanes 1224 © 627 07450 107 ‘Average Sample Properties Nonanes ast 493 07640 121, Decanes 651 418 0780 134 ‘Average Molecuar Weight. 208.73 Undecanes. S19 368 07800 147 Calculated Density at 0 psig and 60°F... 0.8541 Dodecanes. 418 322 08000 161 Tridecanes 472 395 08110 175 Tetredecanes 401 365 08220 190 Pertadecanes 374 369 08320 208 Headecanes 259 © 275 08360 222 Heptadecanes 252 © 288 08470 237 Properties of Plus Fractions Octadecanes 260 313 08520 251 Nonadecanes 187 198 0.8570 263 Tad) Lead Elcosanes plus 1612 4668 09764 604 || Pius Fraction Moi | was | Density | APL | mw (arriee) | Gravty Hepianes plus e282 9477 08783 © 302230 Undecanes ps 47.24 7558 09120735334 Peniacecanes pus 23.14 61.07 0946 185438 Eicosanes plus «16.12 «4868 «0.9764 «133604 Torus CT CENTRAL FILE GEOSCIENCES core iasoraTories PETRO-TECH PERUANA S.A. Lo16-14 RFL 96190 WELLSTREAM RECOMBINATION CALCULATION (based on field production data) Conditions for Recombination Calculations Primary Stage at 40 psig and 62 °F ‘Sock Tank a 0 psig and 60 °F Field Gas Rate Correction Factors ei tatios « Gas Gravy (air=1.000) 0.684 Primary Stage Gas Flow Rate, MscfiD soon T7790 Gas Gravity Factor, 41,2082 ‘Stock Tank Liquid Flow Rate, BOVD .. 1120 Field Gas / Oi Ratio, sc/STBD! 693.75 Gas Deviation Factor, Z 0.994 Super Compressibilty Factor, Fpv 1.0028 Pressure Base, psia 147 1d Ratios « Primary Stage Gas Flow Rate, Msct/D 77020 Rate Correction Factors - PPrmary Stage Liquid Flow Rate, DOU 1128 Prmary Stage Gas / il Ratio, sc/S"bb1 682.90 Gas Gravity (airt.000) 0.690 Gas Gravy Factor, Fg 1.1964 Stock Tank Ligue Flow Rate, BUD senses 1120 Corrected Gas / Oi Rai, sclSTEbI 687.68 Gas Deviation Factor, 2 oat ‘Supercompressibity Factor, Fv... 1.0047 Pressure Base, psia 147 Laboratory L quid Rate Correction Factors Lguid Volume Factor, S'BOUSTHbI @ 60°F 1.0070 BBkumen, Sediment & Water (BS&W) Factor 11.000 Wellstream Recombination Ratio motel. 1.2860 * From: Standing, MB., "Volumetric and Phase Sahar of Oi Fed yrocerbon Sytem" SPE (Dalla)1977, 8h Econ, Aspendi ~ Data not supplied to Core Laboratories CENTRAL FILE GEOSCIBRICES Poge7 ‘CORE LABORATORIES Lote-14 RFL 96190 PETRO-TECH PERUANA S.A. COMPOSITION OF RECOMBINED WELLSTREAM (trom calculated recombination of separator products) guia Component Mot% | wie | Densty | Mw fomiee) Hydrogen Sulfide 000 000 RECOMBINATION CONDITIONS Carbon Dioxide 008 003 8172 44010 hitrogen 014 0.04 0.8086 28.013, 40 psig Methane 4754735 0.2007 16043 62°F Ethane 397 148 03862 30.070 Propane 300 1.27 05070 44097 ‘so-Butane 175 098 05829 58.123 Butane 235 132 058d $8123, Recombination Parameters |so-Pertane 433 096 06244 72.150 nPentane 099 069 06311 72150 Primary Stage Gas / Ol Rat, scfiS"Bb| Heranes 193 156 0.8880 840 at recombination conditions 682.90 Heptanes 379 350 07220 960 Wellstream Recombination Ratio ctanes 548 565 07450 107 ‘moles gas / mole liquid. 1.2560 Noranes 378 44107640 121, Decanes 289 © 373 07780 134 LUndecanes, 230 © 328 07800 147 ‘Average Wellstream Properties Dodecanes. 185 287 0.8000 161 Tridecanes 209° © 352 OBt10 175 ‘Average Molecular Weight seven 1088 ‘Tetradecanes 478 326 08220 190 CCateuated Densty at 0 pelg and 60°F... 0.7348 Pentadecanes 188 329 08320 208 Hexadecanes 145 248 08360 222 Heptadecanes 442-286 08470 237 Properties of Plus Fractions Octadecanes 145-278 0.9520 251 Nonadecanes 070 1.77 08570 263, Tad] gad Eicosanes plus 745 4159 09764 604 || Plus Fraction mois | wre | Densty | apt | mw (orice) | Gravity Heptanes plus 3689 8405 087 © 30228 Undecanes pus «20856736 «0910023534 Pentadecanes plus 1293 $445 09418 «186438 Elcosanes plus 745 4159 09764 133604 Totals. Lie00 105007 CENTRAL FILE GEOSCIENCES Page 8 CORE LABORATORIES PETRO-TECH PERUANA S.A. Lo16-14 RFL 96190 VOLUMETRIC DATA (at 129°) Saturation Pressure (Psat) 3580 psig Density at Psat 0.7263 gmice Thermal Exp @ 5000 psig 1.09834 V at 129 °F /V at 60°F AVERAGE SINGLE-PHASE COMPRESSIBILITIES Single-Phase Pressure Range Compressibility sig { west 5000 to ‘4800 8.46 E-6 4500 to 4216 268E6 4216 to ‘4000 8.00 -6 4000 to 3900 9266-6 3900 to 3800 9448-6 3800 to 3700 965E-6 3700 to 3600 SB7E-6 3600 to 3580 10.01E-6 CENTRAL FILE ao GEOSCIEBCES cone AsoRATORIES PETRO-TECH PERUANA S.A. Lo16-14 RFL 96190 PRESSURE-VOLUME RELATIONS (at 129°F) Pressure Relative Y-Funetion Density psig Volume (A) (8) mice 5000 0.9874 0.7386 4800 0.9816 0.7325 194216 0.9941 0.7307 4000 0.9960 0.7283 3900 0.9969 0.7286 3800 0.9979 0.7279 3700 0.9988 07272 +3600 0.9998 0.7265 b»3580 1.0000 0.7263 3535 1.0022 3610 1.0035 3490 1.0046 3480 1.0051 3420 1.0084 3075 1.0320 5.107 2640 1.0769 4.603 2215 1.1479 4.139 1860, 1.2431 3775 1580 1.3580 3.504 1945 1.4999 3.208 1160 1.6589 3.126 1000 1.8495 2.993 940 1.9391 2.044 720 2.4031 2.774 610 2.7647 2.694 530 3.1207 2.638 370 4.2966 2.531 (A) Relative Volume: ViVsat or volume at indicated pressure per volume at saturation pressure (8) Where: Y-Funetion = (Pabe)* (Wivsat (Psat-P) 7 Page 10 CENTRAL FILE GEOSCIENCES CORE LABORATORIES Relative Volume PETRO-TECH PERUANA S.A. LO16-14 FL 96190 RELATIVE VOLUME (at 129 °F) 1.0000 9960 9980 3040 3500 Pressure, psig uve Vou Expresso: LEGEND Ys a+b KOI" +6 OKC)" wee: a= 23720004 00 0015 © Laboratory Osta be -2.371960+ 00 jp 8584 Condence Links ——— Antica Expression ‘Saturation Pressure: 3580 pig Current Reservoir Pressure: 4216 psig c= 3.914430. 05, Note: XG (iensiontoes °C) = Py Pat Confidence level: 90% Confidence interval: 000008) Pressure-Volume Relations "r squared’ 900008 Figure A-t Page 11 ‘CORE LABORATORIES CENTRAL FILE GEOSCIENCES Y-Functon PETRO-TECH PERUANA S.A. Lo1e-14 RRL 96190 Y-FUNCTION (at 129 °F) 00 en a ee ee Pres, 29 Function Expression: — Ye a4 D (6146 0) where: ° abor = 2.295850+ 00 oss ay zascabe: 0 f Confidence Limits 5408. ip 1431 ontidene cm 2.942000" 00 eae Note: Xe (dimorsionless %) = Pi/ Psat, ‘Saturation Pressure: 3580 psig (Current Resarvor Prossure: 4216 peig conte wx reer. Voune etton oxen s-0otos Presse seme aioe ‘r squared’: 999498 . Poa cone LAsoRAToRES CENTRAL FILE GEOSCIENCES PETRO-TECH PERUANA S.A. Lo16-14 RFL 96190 DIFFERENTIAL VAPORIZATION (at 129 °F) Gas Solution | Relative | Relative ol Deviation | Formation | incremental Pressure | Gas/Oil oll Total Density | Factor | Volume Gas psie Ratio | Volume | Volume amec z Factor | Gravity rsa) | Boas) | eric) o (ai=t.c00)_| b»3580 731 1.350 1.350 0.7263 3200 657 1.319 1.377 0.7345 0.841 0.00436 0.689 2800 580 1.288 1.424 0.7431 0.843 0.00502 0.676 2400 504 1.259 1.498 0.7518 0.853 0.00582 0.685 2000 430 1.230 1816 0.7608 ges = 0.00718 0.655 1600 356 4.202 1.809 0.7697 0.881 0.00908 0.649 4200 283 1.175 2.185 0.7780 0.895 © 0.01227 0.650 800 207 4.147 2.888 0.7888 0913 0.01866 0.662 400 126 1.116 5.184 0.7997 0.939 © 0.03771 0.706 150 62 1.089 12,754 0.8087 see 0.09783 0.798 0 0 1.033 0.8298 1.728 @80°F =1.000 Gravity of Residual Oil Density of Residual Oil 33.4°API at 60°F 0.8573 gmlec at 60 °F (A) Cubic Feet of gas a 14.7 psia and 60 °F per Bart! of relcual ol at 6 °F (8) Baral of oi at indicated pressure and temperature per Barrel of residual lat 60 °F. (©) Barrels of ol pus berated gas at indicated pressure and temperature per Barrel of residual ol at 60 °F. (©) Cubic Feet of gas at incicated pressure and temperature per Cubic Feat at 14,7 psia and 60 °F Page 13, CORE LABORATORIES. a g PETRO-TECH PERUANA S.A. Lote-14 FL 96190 RELATIVE OIL VOLUME (at 129 °F) 1.350 1.300 1280 1200 1.150 1.100 1.080 1.000 ° 500 ee a ee | Pressure, psig ‘elatve Cl Volume Express. _ LEGEND Ye a+bOD+6 O01 were a= 1,099120+00 le 0371 co Laboratory Data bs 8511026. 03, js 1.630 Confidence Limits = 2245390-07 _— ‘Analytical Expression Note: Xi fneremental %) = pressure, psig ‘Saturation Pressure: 9580 psig Confidence lovel: 20% Confidence interval: sf-0.00089 Differential Vaporization "r squared’ ‘999962 Figure Bet Page 14 CORE LABORATORIES CENTRAL FILE GEOSCIENCES Solution Gas/Oil Ratio PETRO-TECH PERUANA S.A. Lote-14 RL 96190 SOLUTION GAS/OIL RATIO (sctfobl at 129 °F ) 2500 3000 3500 4000 ° 500 1000 +1500 Pressure, pig ‘Solution Gas/O1 Ratio lon: Express oy Ys a+b (+6 OM'I+d OO" whore: a= 7.624916. 04 le 0.492 2 peepee b= 7.49502e+ 00 j= 1.452 orien ae c= 2.40293e- 03 ee 0.061 eae d= -2.194700+ 01 Note: X (incremental %) = pressure, pg ‘Saturation Pressure: 9580 psig —— a eee ees Dror! Vepertaion “r squared’: 999917 Figure CENTRAL FILE GEOSCIENCES il Density PETRO-TECH PERUANA S.A. Lote-14 RFL96190 OIL DENSITY (gmicc at 129 °F) 8200 8000 7400 d= 8.657176. 02 ‘Note: Xa (dimensionless ) = Pi/ Peat 7200 ° a a ee a a Pressure, psig ‘ll Denaty Expression below bubblepoln): Broresion Oss oe LEGEND Y= a+b (Xd)*i + 6 (Xa)*] +d (Xd)*k ware 8.295616 01 i= 0.551 ° Laboratory Data, be 5:185140- 02 }e 0307 Confidence Lins c= -6.850900- 02 ke 0.969 Analytical Expression ‘Saturation Pressure: 9580 psig ‘Confidence level: 909% Confidence iterval: +f: 0.00005 ges Differential Vaporization ‘r squared’: 998934 Figure B-3 Page 16 CORE LABORATORIES CENTRAL FILE GEOSCIENCES Incremental Gas Gravity PETRO-TECH PERUANA S.A. Lo1e-14 FL 96190 GAS GRAVITY (at 129 °F) 500 ‘00 1500 2000 200 2000 2500 Pressure, psig (Gas Gravity Expression: LEGEND ye a+b KA)" +6 (XA)"] were s Laboratory Data a= 1.727890 00 te gare Peon * Analytical Expression Saturation Pressure: 2580 pig Note: Xd (nansinlgs 6) P/ Pas, Confidence level: 99% Confidence interval: +{- 0.0055 a saat Vapor ‘rsquared’ soera2 Figure B-# Poge 17 CORE LABORATORIES CENTRAL FILE GEOSCIENCES Deviation Factor, Z PETRO-TECH PERUANA S.A. Lote-14 FL 96190 DEVIATION FACTOR, Z (at 129 °F) Deveton Factor Expreasion: LEGEND Ye a4 DOG" + 0 06") wher: 9.98885e- 01 Im 0.300 © coma in be -2292776- 01 F 0018 = 5.695626. Analytical Expression ‘Saturation Pressure: 3560 91g Note: Xa (dimensionless %) = PI/ Peat, CContigense level: 00% pay wo. Ditlorential Vaporzation ‘requared': 990977 J Page 18 CORE LABORATORIES CENTRAL FILE GEOSCIENCES PETRO-TECH PERUANA S.A. Lo16-14 RFL 98190, RESERVOIR FLUID VISCOSITY (at 129 °F) Olt Gas OW/Gas Pressure Viscosity Viscosity Viscosity Pe °p o ratio '5000 4.06 4500 1.01 4000 0.962 3800 0.942 3580 0.920 3200 0.989 0.0228 449 2800 1.01 0.0203 43.9 2400 1.09 0.0182 59.5 2000 1.18 0.0168 713 1600 131 0.0152 26.0 1200 1.48, 0.0141 105 800 173 0.0131 132 400 213 0.0122 175 150 281 0.0114 228 0 372 * Gas Viecosy data Viecosiy of Natural Gases” oumal ef Petroleum Technology, Auguat, 1966, pp. 97-1000. Page 19 ee GEOSCIEN STASL FILE culate om corelaion of Lee AL, Gonzalez MH, and Eakin 8.E. “Tho CORE LABORATORIES 8 Viecoaly PETRO-TECH PERUANA S.A. Lo1e-14 FL 96190 RESERVOIR FLUID VISCOSITY (op at 129 °F) Proesu, rai (lt Viecosty Expreeton: “ o LEGEND ya a+b KG)l+ 0 K+ d KOE whore: as 2.723180+ 00 i 0550 e Laboratory Data be 1.36t0¢e+ 01 i 0.500 Confidence Limits = -1.72721e+ 01 k= 1.000 Analytical Expression Ca ‘Saturation Pressure: 3580 psig Noe: (emensinlese%) = Pi Pat, Confidence lev: 0% 1 Confidence interval +41:0.0259 ep Rolling-Ball Viscosity ‘r squared’ 980186 Figure G-1 Page 20 ‘CORE LABORATORIES CENTRAL FILE GEOSCIENCES Single Phase Viscosty PETRO-TECH PERUANA S.A. Lo1e-14 RAL 96190 SINGLE-PHASE FLUID VISCOSITY (op at129°F) 1.100 1.060 1.020 3500 S750 4000 4250 4500 4780 5000 Pressure, psig ‘Single-Phate Viscostty Expression: LEGEND ye a+d (O01 whee: ° Laboratory Data a= 9.200820- 01 fe 1.015 b= 9.079430- 05 Confidence Limits Analytical Expression ‘Saturation Pressure: 2580 psig ‘Note: &X (cotta) « | Psat -Pi psig Confidence level: 90% Rolling-Ball Viscos! Confidence interval: +1- 0.0028 op meres nl "rsquared’ 399764 Page 21 CORE LABORATORIES. CENTRAL FILE GEOSCIENCES PETRO-TECH PERUANA S.A. Lo16-14 RFL 96190 SEPARATOR FLASH ANALYSIS Flash Gas/Oil GasiOil__] Stock Tank] Formation] Separator] Specific | Oil Phase Conditions Ratio Ratio | OllGravity| Volume | Volume | Gravity of | Density (sett) (seustobl) | ateorr | Factor | Factor | Flashed Gas| (gmec) peo | iO @ (arty | Bot) | 0) | (Alret.000) 3580 129 0.7265 13570 612 630 1.029 0.650" 0.8435 0 70 5 51 338 1317 1.005 1.109 0.9612 Rsfo= 681 3580 129, 0.7268 90 70 638 650 1019 0.687" 0.8475 0 70 35 350387 1319 1.005 1.093 0.8514 Rstb= 685 3680 129, 0.7268 40 70 682 690 1012 0710" 0.8489 0 70 2 12 336 4.928 1.005 1.010 0.8522 Rsfo= 702 * Collected and analyzed in the laboratory by gas chromatogra. (8) Cubie Feet of gas at 14.7 psia and 60°F per Bare of ol at incicated pressure anc temperature (@) Cube Feet of gas at 14.7 psia and 60 °F per Bare of Stock Tank Ci at 60 °F. (C) Barrels of saturate oat 3580 psig and 129 °F per Barel of Stock Tank Oi at 60°F. (0) Barrels of cl at incicated pressure and temperature per Barel of Stock Tank Oil at 60 *F. CENTASL FILE Page 22 GEOSCIENCES (CORE LABORATORIES e e PETROTECH PERUNA, S.A. Lot6-14 FL 96190 Composition of Separator Test Gas (From Chromatographic Technique ) ta Component oie | cpu | Mw | dens (gree) ‘Sampling Conditions Hydrogen Sulfide 000 Carbon Dioxide 0.10 44010 8172 135 psig Nirogen 034 28013 2068 70°F Methane 8857 36043 2597 Ethane 598 1.595 30070 3558 Propane 289 «785 aes? 506s iso-Butane 061 199 58.123 5623, Butane oes 284 $8,123 S834 ‘Sample Characteristics Iso-Pentane 073 08472180 6241 ‘-Pentane 015 054 72150 6305, Hexanes 013.043 84.000 6850 Ccrical Pressure (psa) esas Heptanes 008 034 96.000 7220 Crtical Temperature *R) 3744 Octanes 008 027 107.00 7450 Nonanes 002 ‘010 121.00 7640 Average Molecular Weight 18.82 Decanes Oct 005 13400 7780 Undecares 001 ‘006 147.00 7890 Calculated Gas Gravity (air = 1.000) 0850 Dodecanes plus Trace Gas Gravity Factor, FQ nee 1.2406 ‘Super Compressiity Factor, Fpv ‘al sampling Condtions 10117 Totals Loos] ae Z-Factor ‘at sampling contons * some OSTT Properties of Plus Fractions at 1427 psia and 60°F Gross Heating Valve re (BTUisct dry gas) 1181 Component Mai% | mw | dens | art igrvee) | Geawty Test Conditions Heptanes plus. 018 1074 0743 588 Decanes plus 002 1405 0786 483 135 Psig oPsig Undecanes plus oo 1470 0704 485 10°F 70°F * From: Standing, M.B., "Volumetric and Phase Behavior of Oi Field Hydrocarbon Systems", SPE (Dallas), 977, 8th Econ, Append I. CENTRAL FILE Page 23 GEOSCIENCES CORE LABORATORIES PETROTECH PERUANA, S.A. Lo16-14 FL 96190 Composition of Separator Test Gas (From Chromatographic Technique ) Te Component Moi% | Gem | mw | Dens rier) ‘Sampling Conditions Hydrogen Sulfide 0.00 Carbon Dioxide on 4010 8172 Nitrogen oat 28013 8086 Methane 67.19 16083 2907 thane 628 1678 30.070 3558 Propane 337 S77 44057 5065 Iso-Butane 076 248 $8,123 5623 Butane 109 343 58.173 S834 ‘Sample Characteristics Iso-Pentane O31 4113, 72.150 zat nPentane 020 97272150 6305 Hevanes 014 054 84.000 6850 Cctieal Pressure (psa) e629 Heptanes 011 048 96.000 7220 Creal Temperature *R) . 3705 Octanes 007 032 10700 7480 Nonanes 003 015 121.00 7640 Average Molecular Weight 19.32 Decanes 002.011 13800 780 Undecanes. 0.01 ‘005 14700 7800 Calouated Gas Gray (alr = 1.000) oss? Dodecanes plus Trace Ges Gravity Factor, FO 12248, ‘Super Compreesibity Factor, Fpv at sampling CondtONS on 1.0083 Totals [isa0e [353] I Gas Z-Facter ‘at sampling condtions * oes at 147 psa and 60 °F Properties of Plus Fractions Gross Heating Valve ta (@TUsst ary gas) 4178 Component Mois | mw | Dens | art (gree) | Gravy | Test Conditions Heptanes pus 024 1078 072 $90 Decanes plus 003 1383 o7ee 48.8 90Psig oPsig Undecanes plus oor 1470 0783488 10°F 10 * From: Standing, M. Hydrocarbor B., "Volumetric and Phase Behavier of Oi Field n Systems", SPE (Dalis),1877, th Eton, Append I CENTRAL FILE rage2t GEOSCIENCES CORE LABORATORIES PETROTECH PERUANA, S.A. Lo16-14 RFL 96190 Composition of Separator Test Gas (From Chromatographic Technique ) Ta Component mois | sem | mw | Dene (amce) ‘Sampling Conditions Hycrogen Sulfide 0.00 Carbon Dioxide on 44010 8172 40 psi NNirogen 034 20013 8088 70°F Methane 8394 16.063 2067 Ethane 685 1.828 30070 3588 Propane 432° 1.188 44087 ‘5065, iso-Butane 110 359 88.123 5623 Butane 470 535 $8,123 5834 Sample Characteristics iso-Pentane 056 197 72180 6241 r-Pentane 037 13472180 e205, Hexanes 023 108 86000 6850, Cte Pressure psa) 6508 Heptanes 023 057 96000 7220 Crtical Temperature *R) 3017 Octanes 015 068 107.00 7450 Nonanes 003 ots 121.00 76a Average Molecular Wg ss 2057 Decanes 002 011 13400 7780 Undecanes oot 008 147.00 7890 Calculated Gas Gravity (r= 1.000) onto Dodecanes plus 001 007 168.00 8060, Gas Gravity ee 1.1868 ‘Super Compressibity Factor, Fv at eampling conditions| 1.0006 [ieee | Aas T Ges Z-Factor at sampling conditions * oat at 147 ps Properties of Plus Fractions Gross Heating Value (BTUs dry $88) on 1245 Component Mot | mw AP Test Conditions Heptanes plus 04s 1058 0739 588 Decanes pus 00s 1458 0787 484 40 sig oPsig Undecanes pus 002 1575 0797 459 70°F 10°F * From: Standing, M.., “Volumetric and Phase Behavior of Ol Field Hycrocarbon Systems", SPE (Dallas), 1977, 8th Eston, Append CENTRAL FILE ge 25 Groscimnces Coe MBORATORES PETRO-TECH PERUANA S.A. Lo16-14 RFL 96190 DIFFERENTIAL VAPORIZATION ADJUSTED TO SEPARATOR CONDITIONS* Gas Solution | Formation | Formation | Oil owas Pressure | Gas/oi | Volume | Volume | Density | Viscosity sig Ratio Factor | Factor grvee Ratio Rs (A) Bo(8) ©, 5000) 681 4,300 0.7356 4500, 681 1.308 0.7325 4216 681 1,309 0.7307 4000 681 4.312 0.7293 3900 681 1313 0.7288 3800 681 1.914 0.7278 3700 681 1.31 07272 3600 681 1.317 0.7265 b» 3580 681 1317 0.7263 3200 608 1.287 0.00438 (0.7345; 422 2800 533 1.287 0.00502 0.7431 42.9 2400 459 1.228 0.00582 (0.7518 593 2000 387 1.200 0.00718 0.7606. 709 1600 315 4173 0.00808 0.7687 857 1200 243, 1.146 0.01227 0.780 105 800 170 4.119 oorsss = 0.7888 132 400 90 1.089 0.03771 0.7997 176 150 28 1.062 0.09783 0,887 229 o 1.008 0.8296 “Separator Conditions First Stage 135 psig at 70°F Stock Tank Opsig at 70°F (A) Cubic Feet of gas at 14.7 psia and 60°F per Barrel of Stock Tank Oi at 60°F. (@) Bare of oi at indicated pressure and temperature per Bare of Stock Tank Oi at 60°F. (©) Cube Feet of gas at indicated pressure ad temperature per Cubic Feet at 14.7 psia and 60“. Page 25 CORE LABORATORIES PETRO-TECH PERUANA S.A. Lot6-14 RFL 96190 DIFFERENTIAL VAPORIZATION ADJUSTED TO SEPARATOR CONDITIONS* Gas Solution | Formation | Formation | Oil Olas Pressure | Gas/oil_ | Volume | Volume | Density | Viscosity 9 Ratio Factor | Factor | gmc Ratio Rs) 8018) © 5000 685 7.302 0.7356 4500 685 41.308 0.7325 426 685 1.311 0.7307 4000685 1.313 0.7283 3900685 1.318 0.7286 3800685. 1.316 0.7278 3700685, 4.317 0.7272 3600685. 1.318 0.7265 by 9580685 1.319 0.7263 3200612 1.289 0.00436 0.7345 41.9 2800 837 1.259 0.00502. 0.7431 498 2400 463 1.230 0.00582 0.7518 59.5 2000 390 1.202 0.00718 0.7608 m3 1600 318 1.174 0.00908 0.7697 86.0 1200 247 1148 0.01227 0.7790 105 800 173 4121 ores 0.7888 192 400 93 1.090 0.03771 0.7997 178 150 3 1.064 0.08763 (0.8087 229 ° 1.009 0.8298 “Separator Conditions First Stage 90 psig at 70°F Stock Tank 0 psig at 70°F (A) Cubie Feet of gas at 147 psia and 60 °F per Barel of Stock Tank Oi at 60 °F. (8) Barrel of lat incicated pressure and temperature per Baral of Stock Tank Ol at 60 °F. (©) Cubic Feet of gas at indicated pressure and temperature per Cubic Feet at 14.7 psa and 60 °F. Pege2? CENTRAL FILE CORE LABORATORIES GEOSCIENCES PETRO-TECH PERUANA S.A. Lo16-14 RFL 96190 DIFFERENTIAL VAPORIZATION ADJUSTED TO SEPARATOR CONDITIONS* Gas Solution | Formation | Formation | oi | oGes Pressure | Gasioi | volume | Volume | Density | Viscosity #0 Ratio | Factor | Factor | gmee | Ratio recy _| bo) © 5000 702 1.312 0.7356 45007021388 0.7325 46 7021.92 0.7307 40007022 1.324 0.7298 3900 702, 1:325 0.7286 3800702, 1.328 07279 3700 021.827 07272 3600 702 1.329 0.7265 bs 3580-702, 1.328 0.7263 3200 629 1.208 «0.00886 0.7345 1.9 2800 «553. 1.268 «0.00502 7ast «49.8 2400 «479,=1.238«=«0.00582 «O71 898 2000 «4051.21 .00718 © 07606713 1600 333.84 00000807697 88.0 1200 26148700127 07790 108 aoo 871.128 .0t86s «7888182 400 108-=«= 1.098» 0.0977 07987175 150043 4072 0.09783 «0.8087 228 ° 1017 0.8208 *Separator Conditions First Stage 40 psig at 70°F Stock Tank O psig at 70°F (A) Cubic Feet of gas at 14.7 psia and 60°F per Bare of Stock Tank Oil at 60°F. (6) Barrel of of at incicated pressure and temperature per Bare! of Stock Tank Oi at 60°F. (C) Cubic Feet of gas at indicated pressure and temperature per Cubic Feet at 14.7 psia and 60 °F, Pee28 CENTRAL FILE CORE LABORATORIES GEOSCIENCES Ce ee ee a ee ee ee ‘Solution Gas / 08 Ratio PETRO-TECH PERUANA S.A. Lo16-14 FL 96190, SOLUTION GAS/OIL RATIO (scfiSTobl ) 800 700 F 800 500 400 300 200 100 ° 500 1000 —«1500«=« 20002500 300035004000 Pressu. pig LEGEND — _Diterenat Veperzaion DV Adjusted to Separator 135 psig at 70°F SM sees as Figure D-1 40g at 70°F > Pepe 2 CORE LABORATORIES CENTRAL FILE GEOSCIENCES CORE LABORATORIES g a as eae g BB aa gi zg 2 aa 5 3 ro eg 3 ° ES ga. 8 , 68 z uz z % Be, 35/1 a 2) Gee 52 a28 9 8 i Zoe Sa & a: zy 2 BD 3 18 @ §

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