bo Practice Test - Chapter 9 Name__F°*) _ Molecular Geometry and Bonding Theories Date Periad L_MULTIPLE CHOICE: Cirele the ltr that best completes eachstatement below. No ‘alculators are allowed onthis Practice Test! “Target I can determine the Bond angle, geometric shape aod the elecvon domain shape of ‘molecule or ton based upon the VSEP.R. Theory. 1M oft flovgtanaenig pf decrnen ti mt Cee, ‘ 7 a ae owe ose Gab) 8 ~ 2 i Xn 3. Which one ofthe following may we draw both polar and nonpolar Lewis structures? eas NES ae A fla es Se ie 2 @ Seng Prax prise = = oe « @Eel s vs structure ofthe eyaide ion most closely resembles which ofthe following?” >) = NIN b> 6 CO NO, Cot CEN - ° e:e0 ys) ohn eins in any molecule? wee 09.s° 4 10 ©. Allof these are reasonable angle. "Target! can eaplan why sonboadingeletvon domains laa paler puleive Inefaction other domains tan do bonding electron domains. 7. Which molecule below would have the greatest repulsion of elestons resulting inthe smallest bond angle S aN 22 0Tee Tia pT on ep os me Wt plop ates C8 Which ofthe bonds below isthe most polar? (Review from Chapter 8) [Bement oe [S| SE Pome clecronepativiy [I$ [2.1 [28 [28 [30 [33 pe Meee ytabisoke be wt aa Geral py a CEES RS CED ce E10. Which one molecule below will have a zero dipole moment? LONE BNO HON a SOp ee ASTON GOMT RT ae “Target 5:1 can precio yp of hy BAA OPOIGL ot an Gen wROTSCTET © 11. The SFY ion has a square pyramid structure, The hybridization ofthe orbitals in sulfur is 4 a dep 8 aap ar apt © 12, ln wishot te oloving ss ae the two tems NOT propery hte? ‘sp? and 109.5 Toa par and 20 @ cca nd p> repent ‘e. spare planar and dsp? Ay 13. Sulfur forms the following compounds: $02, $Fs, SC, SCl. Which form of hybridization is NOT represented by these molecules? bg esd dsp? oe, dap}“Target 6 ca explain the diference betveen Sigma bond and wp bond cam also detenmine the Pia aes eles ea 14, Fort a-f, identify which statements below i characteristic ofa pi (p) ora sigma (6) bond Sa. Formed by the head-to-head bond between atoms 2b. Formed above and below the bond axis, Pc. A tie bond would contin wo ofthese. Pd. This bonding occurs from te sideways overlap ofan electron inp orbitals 2 ©. A triple bond would contain to ofthese. © Wikhote toring fev tote seme ech 3 oon co; @ Se © So. A. 16. Wich one ofthe flowing iste when he C= Cand CC bonds are compared? “he tiple onde shorerthan the double bond. ‘The dole bod onan more pi bonds The doube-ond ener is ihe thn the tipl-bnd energy 4 The double bond contin ess sigma bonds Tafel 7 can oxpan what eeclne eceon nd ie sigiicanee OTe AIC Dn delocalized lens mean. GD inte vin stnes eo tt eo an ton K gn ir when sts have esonane ofa dbl ond Eke psd wh ein en eee oligo ‘They “stabilize” the roel. Tey ar aera wih toning © Tear mnealand wt sigue SigFREE RESPONSE: Complete cach ofthe following fee response guesioins kn the spaces provided, 1, Ansmer the following questions about Xe and XeFy. ‘Xen was ect wilh ony gen aid yore o form compounds such as XeO, and XeT. Draw ach ofthe molecules represented below. b. On the bass ofthe Lewis eletron-dt diagrams you drew for part (a), predict the following: 0) Thegomeriehage ofthe XeOs ole Tergensl gy ce midel (Teint vac eas Fenn EF sped ‘c. Predict whether the XeO3 molecule is polar or nonpolar. Justify your prediction. polar since lone pair of electrons on central 4. Explain why the CHF molecule is polr, where the CF4 molecule isnot Obe wn. é a Le, This 18 nen eeler F-C-F ' eee Vecavse We poll om ‘Fe FH cowbell abem 7S This 15) golar equal From each Since Hand F Lleerine obemn Vase di Flere elechre nega}uc HS ond He elechrons are not shared equally2. Daw the Levis dot structure for a nonpolar molecule that has a moleculer formula of ShHtzBre a ca Sizd 4 Glvans) 1 Thereare_ST__ sigma onds and___' _piton nhs moteuie? »b, The hybridization around each carbon is__SP* _, and the bond angles (20° This molecule is nonpolar because itis Symndricand thas Caucetled dipoles, «Draw he tw pr rer thi compo an ine whe dpe tet, on i dh + {saKS Pate “ @. Be & TR ey 13) 3. List all possible molectlar geometries which have sp” hybridized orbitals. tevehecbel ; risinad Qyranidel ¥ bod 4. dente mea stg tae ava pr soe BoukGser) | Bact Gp?) | Ste-saus, T-Phpel— { spon orranll Sox Nis, spd P 5. Rligenon “Saba sige Sue 335K GEN \Withthe information above suggest a reason why CHyCN has a higher boiling pint han C3Hy (Ch pile f © angle 6 Draw the structure for acetic acid (HsC-COOH) below. Then answer the folowing two ‘questions, NOTE: The sezond carbon is double bonded to the Fist oxygen anc single-bonded to the second O. The His attached wo the second oxygen ° f he ¢ 4. What ft moc ge resent oi > ktahekesT> usm plerare owe potter9. The following chart reinforces the valence bond theory. ‘Molecule orfon_ | Overlap of ovals Forning te sigma ‘bond between the cental atom andthe bonded atoms around i PAs ean P bated wan Sorbihd entt = se ©9) on Yee S barctel e/a p abt on O ial ep G2) om Ha C with ar sorbihl exthe . ont ap abht a dh 0 es pk om He Pash ste p arb cntte F se 5934) an HhS wit a porbrteh om te OL XeFCly spade om Wa Ke ¥/ ae ode om Gt, EXO7, Name a compound with both ionic and covalent bonds, 8, Name three elements which 8) cannot have expanded octets when it is the central atom in a molecule. No Wo. donot ned oes ie Dat compsends,°7 #, Be, B TSR] Se] = ——] Rca Boied Foro] Hyon Bad ve Soman pomeny | Romevde | Ronse ase imary | Sata’ | sein a F np jee 9 1 3/, | pe | 56? | 107 f ee 4 or ie ver 8 fe | se fiz p} Wee? | eran! | 27 i o |? oid 190 7 i ; 2 Io | we gd |%, oa i aot? a, |? foe! | aah i ‘ u uy - o - PL P 3 pa % 8. Identify any molecules above that has pi bonding? $2, , HCN10. Following is a integrative problem using the mole concept and Chapters 8 and 9. A compound consists of 61.70 %C1 10.40 "LC and 27.80 %S by mass. Knowing ‘this determine the following ', What Is the empirical formula(which is also the molecular formula) of this compound? f G oh {utet = (AZ, = a poe Qo ‘ i Ef wt LP, = | S drhogS a 4 C8, fae yas Psy a é b. Draw the Lewis dot structure. (Note: Carbon Is the central atom!) Whe- Yres ies 24 te 7 ee | \ & ct €. This moleculehas 3 _ sigma and Li sonds. 2 4d. What is the hybridization around the :arbon? SO