Digital Pace (ADV) DT. 13-11-2022 - Answers & Solution

MUMBAI / DELHI-NCR / PUNE / NASHIK / AKOLA / GOA / JALGOAN / BOKARO / AMRAVATI / DUBAI / DHULE
IIT – JEE: 2024 TW TEST (ADV) DATE: 13/11/22

TOPIC: VECTORS
Answer Key
1. (A)
2. (B)
3. (B)
4. (D)
5. (D)
6. (A)
7. (C)
8. (D)
9. (D)
10. (A)
11. (A)
12. (B)
13. (B)
14. (B)
15. (D)
16. (A)
17. (A)
18. (B)
19. (D)
20. (C)
CENTERS: MUMBAI / DELHI / PUNE / NASHIK / AKOLA / GOA / JALGAON / BOKARO / AMARAVATI / DUBAI / DHULE # 3
TOPIC: MOLE CONCEPT
SOLUTION
21. (B)
3
No. of moles of atom 
1
No. of atoms  3N A
1
No. of deuterium atom   3N A
6001
1
No. of neutron   3  6.02 1023
6001
 3.011020
22. (B)
4.4
No. of moles of C2O42   0.05
88
No. of ions = 0.05 NA
No. of electrons in 1 ion = 12 + 32 + 2 = 46
No. of electrons in 0.05 NA ions = 46  0.05 NA = 2.3 NA
23. (D)
1
No. of moles of O2 in 1 gm dioxygen 
32
1
No. of molecules of O2  NA
32
2N A N A
No. of atoms of O  
32 16
1 gm atomic oxygen
1
 moles of O atoms
16
N
 A atoms of O
16
1 gm of Ozone
1
 moles of O3
48
1
 N A molecules of O3
48
CENTERS : MUMBAI /DELHI /AKOLA /LUCKNOW / NASHIK /PUNE /NAGPUR / BOKARO / DUBAI # 1
3 N
 N A atoms of O = A
48 16
24. (A)
Volume of sea water  1.4 1021 L
 1.4 1024 ml
Wt. of sea water  1.4 1024 gm
 1.4 1021 kg
Wt. of chlorine  19 1.4 1021 gm
19 1.4 1021
No. of moles of chlorine atoms   7.5  1020
35.5
25. (A)
2KClO3  2KCl + 3O2
2 moles 3 moles
C4H8 + 6O2  4CO2 + 4H2O

0.5 moles 3 moles
26. (D)
95
Wt. of pure NaCl  250  gm  237.5 gm
100
237.5
No. of moles of NaCl 
58.5
2NaCl  Na2SO4
237.5 237.5 1
mole  mole
58.5 58.5 2
237.5 1
Wt. of Na2SO4   142 gm  288.24 gm
58.5 2
100
Wt. of impure sample   288.24  320.3 gm
90
27. (A)
CO & CO2
1  a moles a moles
2NaOH + CO2  Na2CO3 + H2O
2a moles a moles
20
2a 
40
1
a  moles
4
1 3
n CO  1   moles
4 4
2CO + O2  CO2
3 3
mole mole
4 4
CO2 + 2NaOH  Na2CO3 + H2O
3 3
mole  2mole
4 4
3
 mole
2
3
  40 gm
2
 60 gm
28. (A)
[Cl ]  0.6 M 
 0.8 V  3   0.2  50  2 
 V  50 
0.6V  30  2.4V  20
1.8V  10
100
V  5.56 ml
18
29. (A)
Wt. of HCl gas = x gm
x
100  40
50  x
100
x gm
3
100 250
Wt. of solution   50  gm
3 3
Volume of solution = 75 ml
250 3
Density   1.11 gm ml
75
30. (C)
Assume 100 gm solution
w
%  20
w
Wt. of glucose = 20 gm
w
%  25
v
20
100  25
v
v  80 ml
100
Density   1.25 gm ml
800
31. (C)
MnO & MnO2
200 100
mole mole
3 3
200 100
No. of moles of Mn    100
3 3
100  55
%Mn  100  72.05
 200   100 
  71    87 
 3   3 
32. (D)
C3H8 + 5O2  3CO2 + 4H2O
0.15 mole
4
n H2O   0.15  0.2 mole
3
No. of molecules of H2O formed  0.2  6 1023
0.2  6 1023
No. of drops of water formed   70
1.7 1021
33. (D)
C H
Mass Ratio 8 : 1
8
Moles ratio : 1
12
2 : 3
EF  C2 H3Ox
16x
10.6  100
24  3  16 x
x  0.2
EF  C2 H3O0.2 or C10 H15O
34. (C)
A + 2B  I
Initial 5 6 0
Final 5–3=2 6–6=0 3
I + C  B + D
3 moles 3 moles 3 moles
Now 3 moles of B again react with unreacted A.
A + 2B  I
Initial 2 3 0
Final 2 – 1.5 = 0.05 3–3=0 1.5
I + C  B + D
1.5 moles 1.5 moles 1.5 moles
Now again B reacts with unreacted A.
A + 2B  I
Initial 0.5 1.5 0
Final 0.5 – 0.5 = 0 1.5 – 1 = 0.5 0.5
I + C  B + D
0.5 moles 0.5 moles 0.5 moles
Total moles of D formed = 3 + 1.5 + 0.5 = 5 moles
35. (B)
98 98
Final volume   V  10V   11V 
100 100
2.2V 220 20
Molarity     0.204
98 11 98 98
11V 
100
36. (D)
No. of moles of glucose = a
Wt. of glucose = 180a gm
Wt. of water = 1000 – 180a gm
a
1 1000
1000  180a
1000
1000  180a  1000a  a 
1180
Final wt. of water = 1000 – 180a + 4000 gm
 1000 
 5000  180   gm
 1100 
 4847 gm
 4.847 kg
1000 1180
Final molality   0.175 m
4.847
37. (B)
Atomic mass of M = a
M + 3F2  MF6
0.250 gm 0.250
mole
0.250 a
 moles
a
0.250
 a  114   0.547
a
0.250a  114  0.250   0.547a
28.5
a  95.96
0.297
38. (B)
total mass
Average molecular mass 
total moles
100
  2.10
90 10

2 4
39. (A)
CH4 & C2 H 6
a mole a mole
total no, of moles = 2a
total volume   22.4  2a 
total wt.  16  a    30  a  46a
46a
density   1.03 gm
 22.4 2a 
40. (C)
2 103
Initial no. of moles of Ca atoms 
40
1.2 1019
Moles of Ca atoms removed 
6 1023
No. of moles of Ca atom left
2 103 1.2 1019
 
40 6 1023
 0.5 104  0.2 104  3105
TOPIC: QUADRATIC EQUATION
Solution
41. (C)
In order that the quadratic equation may have two roots with opposite signs, it must have real roots
with their product negative, i.e. if the discriminant,
4(a2  1)2  12(a2  3a  2)  0
1 2
and (a  3a  2)  0
3
Both of these conditions get satisfied if a2  3a  2  0
i.e., if (a 1)(a  2)  0 or if 1  a  2 .
42. (C)
If D is the discriminant of the equation x 2  4qx  2q 2  r  0 , then
D  16q 2  4(2q 2  r )  8q 2  4r
 822  4(4  4 )  4(2  2 )2  0
Hence the equation x 2  4qx  2q 2  r  0 has always two real roots i.e. both real roots.
43. (C)
We know that ax2  bx  c  0 if a  0 and b2  4ac  0 .
1 mx 2  x  1
 mx  1   0  0
x x
 mx2  x 1  0 and x  0
Now mx2  x 1  0 if m  0 and 1  4m  0
1
or if m  0 and m 
4
1
Thus the minimum value of m is .
4
44. (A)
 p  p
Let roots of lx2  nx  n  0 are  and  , given that       .....(i)
 q q
n n
   and  
l l
 p q n  
Now         
q  p l  
(  )  (  )
 0.

45. (D)
Let the correct equation be x2  px  q  0 .....(i)
Roots found by the first student are 6 and 2.
Their sum  6  2  8   p
and the product  6  2  12  q
So, (i) reduces to x2  8x  12  0 .....(ii)
But he has committed mistake only in the coefficient of x i.e. in p. So q remains equal to 12 while p
in the actual equation has been taken wrongly by the first student.
Now roots found by the second student are 2 and –9.
Their sum  9  2  7   p and the product
= – 9×2 = –18 =q i.e., p =7 and q  18 in (i)
But he has committed mistake only in the constant term i.e. in q. So p remains equal to 7.
Hence correct equation from (i) is x2  7 x 12  0
 ( x  4)( x  3)  0  x  4, 3 .
46. (A)
   p,   q
If the given roots be A and B, then
A  ( )2 (  )(2  2  )
 ( p 2  4q) p( p 2  q)  p[ p 4  5 p 2q  4q 2 ]
B  22 (  )  q2 p
 S  A  B  p[ p4  5 p2q  5q 2 ]
P  p 2 q 2 ( p 4  5 p 2 q  4q 2 )
The required equation is x2  Sx  P  0 .
Trick : Check by putting p  3, q  2 so that   2,   1.
Now roots of required equation will be 21,12 .
Therefore S  33 and P  252 which is given by the option (A).
47. (D)
Let the correct equation be ax2  bx  c  0 and the correct roots  and  .
Taking c wrong, the roots are 3 and 2.
    3  2  5 .....(i)
Also a  1 and c  6
   c / a  6 .....(ii)
Solving (i) and (ii), the correct roots are 6 and – 1.
48. (A)
Let the roots are  and 
so, 3  3  (  )3  3(  )
 (a  2)3  3(a  3)(a  2)
 a3  9a2  27a  26  (a  3)3  1
It assumes the least value, if (a  3)3  0 .
 a 3.
49. (A)
As the coefficients are real and one root is 2  i, therefore, another root is 2  i (conjugate of 2  i ).
Let the third root be  then sum of the roots  2  i  2  i  
 (5)  4      1
So, the other two roots are 2  i and 1.
50. (C)
We have x2  px  (1  p)  0 …..(i)
(1  p)2  p(1  p)  (1  p)  0
(1  p)[1  p  p 1]  0 ; p 1
Put p 1 in equation (i),
x2  x  0  x( x  1)  0 i.e., x  0  1 .
51. (A)
( x  1)( x  3)
y
( x  2)
Here x cannot be 2.
 Either both N r and D r are positive
x  1, x  3 and x  2  x  3 .....(i)
Or N r is negative and D r is negative
x  1 and x  2  1  x  2 …..(ii)
From (i) and (ii), 1  x  2 or x  3 .
52. (D)
Domain of definition of the function y  x( x  3) is x( x  3)  0 i.e. x  0 or x  3 .....(i)
Given equation can be re-written as
9 | x |2 19 | x | 2  0
 (9 | x | 1)(| x | 2)  0
 | x | 2 or | x | 1/ 9
 Solution of the given equation are  2, 1/ 9
In the domain (i), the required solutions are 2, 1/ 9 .
53. (C)
Given that x2  2ax  a2 is a factor of
x3  3 px  2q  0
Let x3  3 px  2q  ( x2  2ax  a 2 )( x  ) ,
where  is a constant.
Then equating the coefficients of like powers of x on both sides,
x3  3 px  2q  x3  (2a  ) x 2  (a 2  2a) x  a 2
 2a    0    2a ….. (i)
and 3 p  a 2  2a …..(ii)
and 2q  a2 …..(iii)
Put the value of  in (iii),
 2q  2a3  q  a3 ..…(iv)
Put the value of  in (ii),
 3 p  a 2  2a(2a)  a 2  4a 2  3a 2
 3 p  3a2  p  a2  p  (q)2/3  p3  q2 .
54. (A)
Roots ,  lie in the interval (0,1)(  ) , so
(i)   0, (ii) f (0)  0, f (1)  0 , (iii) 0     2
 Here    3  2 1 for every k
Hence no such k exist.
55. (A)
56. (A)
x2  x  1
From k  2
x  x 1
We have x2 (k  1)  x(k  1)  k  1  0
As given, x is real  (k  1)2  4(k  1)2  0
 3k 2 10k  3  0
Which is possible only when the value of k lies between the roots of the equation 3k 2 10k  3  0
1 1
That is, when  k  3 {Since roots are and 3}
3 3
57. (A)
x  1  1  1  ..... to 
We have x  1  x
 x2  1  x  x2  x  1  0
1 1 4 1 5
 x 
2 2
1 5
As x  0 , we get x 
2
58. (C)
Given equations are 2x2  3x  5  0 and x2  2x  3  0 have a common root if
x2 x 1
   x 2  , x   or   1, 0 .
  1
59. (A)
b c
As given, sin   cos    , sin  cos  
a a
To eliminate  , we have
1  sin 2   cos2   (sin   cos )2  2sin  cos 
b 2 2c
   a 2  b 2  2ac  0
a2 a
60. (C)
Let   1 and the other root is  , then product of roots 1.
c ( a  b) c ( a  b)
 
a(b  c) a (b  c)

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MUMBAI / DELHI-NCR / PUNE / NASHIK / AKOLA / GOA / JALGOAN / BOKARO / AMRAVATI / DUBAI / DHULE

IIT – JEE: 2024 TW TEST (ADV) DATE: 13/11/22

C4H8 + 6O2  4CO2 + 4H2O

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