KNC 1073

Thermodynamics

Lecture 5 – Thermodynamics Properties of Fluids

Nazeri Abdul Rahman

Dept. of Chemical Engineering and Energy Sustainability
Faculty of Engineering
Universiti Malaysia Sarawak
 Objectives

§ To develop from the first and second laws the fundamental

property relations which underlie the mathematical structure of
thermodynamics.
§ To derive equations which allow calculation of enthalpy and
entropy values from P V T and heat-capacity data.
§ To discuss the diagrams and tables by which property values
§ are presented for convenient use.
§ To develop generalized correlations which provide estimates of
property values in the absence of complete experimental
information.
Property Relations for Homogeneous
Phases
Property Relations for Homogeneous
Phases
Property Relations for Homogeneous
Phases
Property Relations for Homogeneous
Phases
Property Relations for Homogeneous Phases:
Enthalpy and Entropy as Function of T and P
Property Relations for Homogeneous Phases:
Enthalpy and Entropy as Function of T and P
Property Relations for Homogeneous Phases:
Internal Energy as a Function of P and The
Ideal –Gas State
Property Relations for Homogeneous Phases:
Alternative Forms for Liquids
 Property Relations for Homogeneous Phases:
Internal Energy and Entropy as Functions of T
and V
 Property Relations for Homogeneous Phases:
Internal Energy and Entropy as Functions of T
and V
Property Relations for Homogeneous Phases:
The Gibbs Energy as a Generating Function
Property Relations for Homogeneous Phases:
The Gibbs Energy as a Generating Function
Residual Properties
Residual Properties
Residual Properties
Residual Properties
 Residual Properties:
Residual Properties in the Zero-Pressure Limit
 Residual Properties:
Residual Properties in the Zero-Pressure Limit
 Residual Properties:
Residual Properties in the Zero-Pressure Limit
 Residual Properties:
Enthalpy and Entropy from Residual Properties
 Residual Properties:
Enthalpy and Entropy from Residual Properties
 Residual Properties By Equations of State:
Residual properties from the Virial Equations of
State
 Residual Properties By Equations of State:
Residual properties from the Virial Equations of
State
 Residual Properties By Equations of State:
Residual properties from the Virial Equations of
State
 Residual Properties By Equations of State:
Residual properties by Cubic Equations of State
 Residual Properties By Equations of State:
Residual properties by Cubic Equations of State
 Residual Properties By Equations of State:
Residual properties by Cubic Equations of State
Two-Phase Systems
Two-Phase Systems
Two-Phase Systems
Two-Phase Systems: Temperature Dependence
of the Vapor pressure of Liquids
Two-Phase Systems: Corresponding-States
Correlations for Vapor Pressure
 Two-Phase Systems:
Two-Phase Liquid/Vapor Systems
Thermodynamic Diagrams
Thermodynamic Diagrams
Thermodynamic Diagrams
Tables of Thermodynamic Properties
Generalized Property Correlations for Gases
Generalized Property Correlations for Gases
Generalized Property Correlations for Gases
Generalized Property Correlations for Gases
Generalized Property Correlations for Gases
Generalized Property Correlations for Gases
Generalized Property Correlations for Gases
Generalized Property Correlations for Gases
Generalized Property Correlations for Gases:
Extension to Gas Mixture
 Further reading

• Smith. J. M., Van Ness, H. C., and Abbott, M. M., (2005), Chapter 6:
Thermodynamics Properties of Fluids, Introduction to Chemical
Engineering Thermodynamics, 7th Edition, Mc Graw-Hill, New York, USA
• Richard Elliot, J., and Lira, C. T., (1999), Chapter 8: Departure Function,
Introductory Chemical Engineering Thermodynamics, Prentice Hall, Saddle
River, New Jersey, USA