Professional Documents
Culture Documents
General Chemistry 2
Quarter 2: Week 6 - Module 6
Reactions in a Cell
STEM – General Chemistry 2
Grade 11/12: Quarter 4: Week 6 - Module 6: Reactions in a Cell
First Edition, 2021
Copyright © 2021
La Union Schools Division
Region I
All rights reserved. No part of this module may be reproduced in any form
without written permission from the copyright owners.
Management Team:
3
Target
In the past lessons you learned how redox reactions takes place in two
reactions, namely reduction and oxidation. You have learned how these two
coupled reactions, causing the lose and gain of electrons. You also have learned
how to balance redox reactions using the change in oxidation number method.
These concepts can help us understand how galvanic cells will functions and will
understand more about redox reactions.
This learning material will provide you with information and activities that
will help you understand the reactions occurring in galvanic cell, and the concepts
regarding reduction potential, oxidation potential and cell potential.
After going through this learning material, you are expected to:
1. Identify the reaction occurring in the different parts of the cell
(STEM_GC11ABIVf-g-172)
2. Define reduction potential, oxidation potential, and cell potential
(STEM_GC11ABIVf-g-176)
4
Galvanic Cell
Jumpstart
5
3. If the electrodes of voltaic cell are connected with wires, what connects the
two electrolytes?
A. Acid bridge B. Base Bridge C. Salt Bridge D. Zinc Bridge
5. Which of the following part of the galvanic cell allows ions to flow back and
forth so that charge does not build up?
A. Electrodes B. Electrolytes C. Salt Bridge D. Voltmeter
9. What do you call the reaction that shows the partial reactions of reduction
and oxidation in a galvanic cell?
A. Electron B. Half reaction C. Oxidation D. Reduction
10. Which of the following properties of galvanic cell measures the tendency of a
chemical species to acquire electrons and thereby be reduced?
A. oxidation B. reduction
C. oxidation potential D. reduction potential
11. In the an electrochemical cell, what is the energy change, measured in volts,
required to add or remove electrons to or from an element or compound?
A. oxidation B. reduction
C. Oxidation potential D. reduction potential
12. What happens to the species’ affinity for electrons if there are more positive
reduction potential?
A. Decrease B. Increase C. Reversed D. The same
13. How are you going to describe reactivity of the salt bridge in a galvanic cell?
A. Fast B. Slow C. Unreactive D. Undefined
14. When performing galvanic cell, what is the standard conditions for the
solutions?
A. 1 M B. 2 M C. 3 M D. 4 M
15. What do chemists used to measure the potentials for oxidations and
reductions of different substances under comparable conditions?
A. Standard oxidation potential B. Standard reduction potential
C. Standard cell potential D. Standard electrode potential
6
Discover
This setup does not generate electric current because the reactants are in
direct contact with each other. To produce electrical energy from this redox
reaction, we need a device to make electrons transfer in an external pathway rather
than directly between reactants. This device is called the galvanic cell, also called
voltaic cell or electrochemical cell.
7
In all electrochemical cells:
1. Oxidation occurs at the anode and anions migrate toward the anode within the
cell. In the figure, SO4-2 ions move from the cathode toward the anode.
2. Reduction occurs at the cathode and cations migrate toward the cathode within
the cell. In the figure, Na+ ions are the cations that move toward the cathode.
3. The flow of electrons in the external circuit is from the anode to the cathode. The
electrons lost during oxidation at the anode leave the system through the metal
electrode, flow through the wire in the external circuit then enter the system at the
cathode where electrons are used (gained) during the reduction reaction.
8
Anode (Oxidation): Zn(s) Zn+2 (aq) + 2 e-
Cathode (Reduction): Cu+2(aq) + 2e- Cu(s)
Overall cell reaction: Zn(s) + Cu+2(aq) Zn+2 (aq) + Cu(s)
To simplify cell descriptions, a shorthand electrochemical notation or cell diagram
is often used. The cell in Figure is abbreviated as:
Zn| Zn+2 (aq)|| Cu+2(aq)|Cu
Sample problem:
Give the electronically balanced half-reactions for the ionic reaction,
Ag+(aq) + Mg(s) Ag(s) + Mg2+(aq)
Solution:
The half-reactions are:
Electrochemical notation:
Mg|Mg2+(aq)||2 Ag+(aq)|2 Ag
Reduction Potential, Oxidation Potential, and Cell Potential
9
Reduction Half-Reaction Standard Reduction Potential (V)
F2(g)+2e- → 2F-(aq) +2.87
S2O82-(aq)+2e- → 2SO42-(aq) +2.01
O2(g)+4H+(aq)+4e- → 2H2O(l) +1.23
Br2(l)+2e- → 2Br-(aq) +1.09
Ag+(aq)+e- → Ag(s) +0.80
Fe3+(aq)+e- → Fe2+(aq) +0.77
I2(l)+2e- → 2I+(aq) +0.54
Cu2+(aq)+2e- → Cu(s) +0.34
Sn4+(aq)+2e- → Sn2+(aq) +0.15
S(s)+2H+(aq)+2e- → H2S(g) +0.14
2H+(aq)+2e- → H2(g) 0.00
Sn2+(aq)+2e- → Sn(g) -0.14
V3+(aq)+e- → V2+(aq) -0.26
Fe2+(aq)+2e- → Fe(s) -0.44
Cr3+(aq)+3e- → Cr(s) -0.74
Zn2+(aq)+2e- → Zn(s) -0.76
Mn2+(aq)+2e- → Mn(s) -1.18
Na+(aq)+e- → Na(s) -2.71
Li+(aq)+e- → Li(s) -3.04
Reduction potential chart. Credits from: https://chem.libretexts.org/
Oxidation potential (electrode potential, reduction potential; E θ) The energy
change, measured in volts, required to add or remove electrons to or from an
element or compound. The reference reaction is the removal of electrons from
hydrogen in a standard hydrogen half-cell (i.e. H2(gas) at 1 atm pressure delivered
to a 1.0 M solution of H+ ions at 25°C, into which a platinum electrode has been
inserted): H2 → 2H+ + 2e−, This energy change is given the value of zero. The
oxidation potential of other species are determined relatively by measuring the
potential difference between a half-cell containing an aqueous solution of the
oxidized and reduced forms of the test substance, and the standard hydrogen half-
cell. For example, for Fe2+ → Fe3+ + e−, Eθ = 0.77, for Mn2+ → Mn3+ + e−, Eθ = 1.51.
With decreasing values of oxidation potential, the reduced form of a couple (e.g.
Fe2+) will itself reduce the oxidized form of a couple with a higher oxidation
potential (e.g. Mn3+). The oxidation potentials obtained under these controlled
conditions are called standard electrode potentials, or sometimes standard
reduction potentials.
In a galvanic cell, current is produced when electrons flow externally
through the circuit from the anode to the cathode because of a difference in
potential energy between the two electrodes in the electrochemical cell. In the
Zn/Cu system, the valence electrons in zinc have a substantially higher potential
energy than the valence electrons in copper because of shielding of the s electrons
of zinc by the electrons in filled d orbitals. Hence electrons flow spontaneously from
zinc to copper(II) ions, forming zinc(II) ions and metallic copper. Just like water
flowing spontaneously downhill, which can be made to do work by forcing a
waterwheel, the flow of electrons from a higher potential energy to a lower one can
also be harnessed to perform work.
10
The measured potential of a cell also depends strongly on the concentrations
of the reacting species and the temperature of the system. To develop a scale of
relative potentials that will allow us to predict the direction of an electrochemical
reaction and the magnitude of the driving force for the reaction, the potentials for
oxidations and reductions of different substances must be measured under
comparable conditions. To do this, chemists use the standard cell potential (E°cell),
defined as the potential of a cell measured under standard conditions—that is, with
all species in their standard states (1 M for solutions, concentrated solutions of
salts (about 1 M) generally do not exhibit ideal behavior, and the actual standard
state corresponds to an activity of 1 rather than a concentration of 1 M. Corrections
for non ideal behavior are important for precise quantitative work but not for the
more qualitative approach that we are taking here. 1 atm for gases, pure solids or
pure liquids for other substances) and at a fixed temperature, usually 25°C.
The potential of the cell under standard conditions (1 M for solutions, 1 atm for
gases, pure solids or liquids for other substances) and at a fixed temperature (25°C)
is called the standard cell potential (E°cell). Only the difference between the
potentials of two electrodes can be measured.
Explore
2. KI + Cl2 KCl + I2
8. CO + I2O5 CO2 + I2
10. Chlorine gas oxidises Fe2+ ions to Fe3+ ions. In the process, chlorine is
reduced to chloride ions.
11
Enrichment Activity 2. Define me.
Direction: Using the standard reduction potential concept, explain the following
situations.
Deepen
The scoring rubric below will be used in assessing your output. Use a
separate sheet to write your answer.
Scoring Rubric
12
Gauge
Direction: Choose the best answer. Use a separate sheet for your answers.
1. The redox reaction happening in a galvanic cell permits the flow of what kind
of particle shown in a voltmeter?
A. Electrolyte B. Electrons C. Neutrons D. Protons
3. What porous material allows ions to flow back and forth so that charge does
not build up?
A. Acid bridge B. Copper bridge C. Salt bridge D. Zinc bridge
5. To maintain electrical neutrality, where does the anions SO 4-2 from the salt
bridge move into?
A. Anode B. Cathode C. Electrodes D. Wires
6. What do you call the diagram or reaction that shows only the oxidation or
reduction reaction?
A. Full-reaction B. Half-reaction C. Galvanic D. Electrolytic
10. Electrons flow spontaneously from zinc to copper(II) ions, forming zinc(II)
ions and metallic copper, this is because zinc has higher ____.
A. Potential Energy B. Kinetic energy C. Electrons D. Electrodes
13
12. In determining the standard cell potential, what is measured between the
potentials of the two electrodes?
A. Difference B. Quotient C. Product D. Sum
13. How many electrons does Au lost? Au+(aq) + Ca(s) Au(s) + Ca2+(aq)
A. 1 B. 2 C. 3 D. 4
14. What is the reaction does Ca undergo? Au+(aq) + Ca(s) Au(s) + Ca2+(aq)
A. anode B. cathode C. oxidation D. reduction
15. Which of the following shows a correct reduction reaction of the redox
reaction, Au+(aq) + Ca(s) Au(s) + Ca2+(aq).
A. Au+(aq) Au(s) B. Au (aq) Au+(s) C. Ca(s) Ca2+(aq) D. Ca2+(aq)Ca(aq)
14
Answer Key
Jumpstart
1. B 6. C 11. C
2. B 7. A 12. B
3. C 8. B 13. C
4. B 9. B 14. A
5. C 10. D 15. C
EXPLORE ENRICHMENT ACTIVITY 1
1. Oxidation half-reaction: Mg(s) Mg2+(aq) + 2e-
Reduction half-reaction: 2 H+ + 2 e- H2
Electrochemical notation: Mg|Mg2+(aq)||2 H+(aq)|H2
2. Oxidation half-reaction: Cl2 Cl- + e-
Reduction half-reaction: I- + e- I2
Electrochemical notation: Cl2|KCl||KI|I2
3. Oxidation half-reaction: Cr+ Cr3+ + 2e-
Reduction half-reaction: Sn4+ + 2e- Sn2+
Electrochemical notation: Cr+| Cr3+||Sn4+|Sn2+
4. Oxidation half-reaction: 2 Fe (s) 2 Fe 3+ + 6e-
Reduction half-reaction: 3Hg 2+ + 6e- 3 Hg2
Electrochemical notation: 2 Fe (s) | 2 Fe 3+||3Hg 2+|3 Hg2
5. Oxidation half-reaction: 2 As (s) 2 As+3 + 6e-
Reduction half-reaction: 3 Cl2 + 6e- 2 Cl-
Electrochemical notation: 2 As (s) | 2 As+3 ||3 Cl2 |2 Cl-
6. Oxidation half-reaction: Br- Br2 + 2e-
Reduction half-reaction: Cl2 + 2e- Cl-
Electrochemical notation: Br- | Br2|| Cl2| Cl-
7. Oxidation half-reaction: O O-2 + 2e-
Reduction half-reaction: Fe+3 + 3e- Fe
Electrochemical notation: CO| CO2|| Fe2O3| Fe
8. Oxidation half-reaction: O O-2 + 2e-
Reduction half-reaction: I-5 + 5e- I2
Electrochemical notation: CO| CO2|| I2O5| I2
9. Oxidation half-reaction: Sn2+ Sn4+ + 2e-
Reduction half-reaction: 2 Fe3+ + 2e- 2 Fe 2+
Electrochemical notation: Sn2+| Sn4+||2 Fe3+ | 2 Fe 2+
10. Oxidation half-reaction: Fe2+ Fe3+ + e-
Reduction half-reaction: Cl2 + e- Cl-
Electrochemical notation: Fe2+ | Fe3+ || Cl2| Cl-
Gauge
1. B 5. A 9. B 13. A
2. A 6. B 10. A 14. C
3. C 7. B 11. A 15. A
4. C 8. C 12. A
15
References:
Books:
Ilao, Luciana V., Betty M. Lontoc, Edwehna Elinore S. Paderna-Gayon. General
Chemistry 2: Galvanic Cells. 1st ed. Manila. Rex Book Store, Inc. 2016.
Website:
16
chem.libretexts.org. “Cell Potential Under Standard Conditions.” Accessed March 1,
2021.https://chem.libretexts.org/Bookshelves/General_Chemistry/Map%3
A_Chemistry_-
_The_Central_Science_(Brown_et_al.)/20%3A_Electrochemistry/20.4%3A_C
ell_Potential_Under_Standard_Conditions#:~:text=The%20potential%20of%2
0the%20cell,two%20electrodes%20can%20be%20measured.
17