{tem 1 refers to the following reaction, y, LC No, HES, NO, o 0+ HN — NH —@)~ No, —> c= N — NB —G)— NO, + 1,0 HC He? The reaction above between propanone and 2, 4 dinitrophenythydrazine is (A) addition (B) hydrolysis (©) __ substitution (@)P condensation Which pair of compounds can be used to. 4. «=A compound which displays optical make propyl methanoate? isomerism must have cHOH OH (A) double bonds ED Cita (B) — aplane of symmetry (B) _ C,H,OH and CH,COOH at least one asymmetric carbon (©) CH,OH and CH,COOH atom (D) mirror images that are super- ©) H and C,H,COOH npossble Item 3 refers to the three amines, X, Y and . Pe tae fllbeniig forlan tem 5 refers to the following structure. —NH, X: CH,CICHCINH, aa Y: CH, CH, NH, cu, Z: C,H,CH, N Which of the following sets of pH values J. Based on the TUPAC rules, the name of the is LIKELY to be for the amines, X. Y and compound abave'is Z respectively? (A) t-phenylbutan-1-amine x * transitions which occur by absorption of energy in the visible region of the spectrum (C) Electrons absorb energy, become excited and move to higher energy levels. ‘The molecule absorbs energy in the red/blue region of the spectrum not the yellow/orange section of the spectrum. ©) ‘A compound absorbs light of frequency 940 MHz. The wavelength, in em, of the light absorbed is (¢ = 3.0 x 10* ms") 3191 (B) 31.91 107 (C) 3191x107 (D) 31.91 x 10° 29. 30. Which of the following may Pe eliminated i 2 by calibrating a measuring instrument? (A) Lack of precision (B) Random errors only Systematic errors only, (D) _ Random and systematic errors Which ofthe following bonds would show the STRONGEST absorption in [R spec” troscopic analysis? (A) Sulfur-hydrogen (B) Carbon-hydrogen GQ) Onygen-hydrogen (D) _Nitrogen-hydrogen Which of the following statements about partition coefficient may be true? 1. The partition coefficient does not vary with temperature. 11. The two solutions have to be concentrated for the partition coefficient to be a constant. IIL. The solute has to be in the same molecular state in both solvents for the partition coefficient to be a constant. (A) Lonly (B) Monly Il only (D) Land If only AO AN TA THE NEYT PAGESh. 32. 33. -9- In one of the steps involved in the manufacture of sulfuric acid, sulfur dioxide andoxygenaremixed to form sulfur trioxide according to the following equation: 2S0,(g) + O,(g) — 2S0,(g) Which of the following options describes the effect of adding the catalyst VO, to the mixture? Yield Reaction Rate (A)_| Increases Tnereases ‘No change Increases (©) [Nochange | No change (D) [increases No change In brewing alcohol, fermentation involves (A) enzymes building up the alcohol from the sugars (B) _yeastcells providing energy for the ‘breakdown of sugars to alcohol (C)__ enzymes using the sugars to obtain energy while producing alcohol QW y225t cells providing enzymes for the breakdown of sugars to alcoho! Which of the following is NOT manufac- tured using ammonia? (A) Dyes Ethanol (C) Explosives (D) _Livestock feed Cracking is a process used to break down large hydrocarbons into smaller molecules, Which of the following is a balanced equation forthe eracking of dodeeane into nonane and propene? 34. CyHay ? CyHye * Co, (A) @) CyHy, 7 CHa CoH G@® 6H, CHa + CH D) Cy 2G Ha + He What is the product of the following (unbalanced) equation? 35. A1,0,,H,0 (s) + H,0 (1) + OH" (ag) + A) @®) © A1,H,0(; 1) ALOH),6) Al, OF),6) @® 10-00 36. Which of the following is a MAJOR component of biomass? (A) Oil (B) Ethanol G@DP Cellulose (D) Natural gas GO ON TO THE NEXT PAGE,f , | i tem 37 refers to the following schematic 39, ‘From the reaction given below, 4 high diagram. pressure would give the best yield, but in Nitrogen industry, a moderate pressure is used fixation N, tat wa ightning = 2NH,(8) IDenitrifying N,(g) + 3H,(8) (8) — [rece Why is a moderate pressure used in industry | rather than high pressure? w fe Dest] Organic |q_ Plants (y @@{yp Its too expensive to produce high 7 pressure =<“ | (B) The reaction would be uncontrol- Bacteria lably fast. - Bester (©) Thereaction would be too slow to generate adequate NH, 37. Wwould MOST likely be (D) _Itiseasier to remove the NH, from the reaction container. (A) nitrates (B) nitrites (C)__ nitric (V) acid @) ammonium salts 40. A sample of crude oil contains mainly C,H, In which erude oil fraction would you expect to find this sample? 38. During an earthquake, household water ® Blumen sas is MOST Ii efinery supply is MOST likely to become polluted ©) gee el - @®) Neptha and gasoline broken sewage mains entering the water supply (B) landslides occurring in the countryside (©) dumping of industrial waste imo rivers and streams (D) drainage of chemical fertilizer and 1 pesticides into the soil 41. Chlorine can be produced by the diaphragm method and mercury cell electrolysis. ‘Which of the following statements is/are true regarding the diaphragm cell method? |. _ It is less energy efficient. Il. _Itis more energy efficient. IIL, Itislessharmful to the environment. (A) Lonly (B) — tonly ' (C) and Ilonly @) Wend I onlyof the atmosphere j.\ ack tae 43, Jn whieh tovotal to human health ang 42. Chlorofiuerocarbons undergo homolytic ne detrimental fission by being exposed to ultraviolet light aaeton? in the stratosphere. (A) Mesosphere Which radical could result from ses : G@) Tropes CHFCF,CI? me sale @ = ciyrecr; (D) —Thermosphere FCF, (8) °CH,CF,CI (©) ‘CHFCF,CI @) = CHF 'CFCI Item 44 refers to the following diagram which is a simplified version of the nitrogen cycle with four components labelled L, M, N and O. Atmospheric nitrogen Death and decay Aanmonium ions in the soil 44. Which of the following options represents L. M,N. and 0? L M N oO G@P Reduction Nitrogen-Fixing Bacteria Nitrogen Oxides __Denitvifying Bacteria (B) Oxidation —_Denitrifying Bacteria ‘Nitrogen Oxides Nitrogen-Fixing Bacteria (C) Reduction ing Bacteria. Ammonia Nitrogen-Fixing Bact (D) Oxidation Nitrifying Bacteria Ammonia Fixing Bacteria45. Dissolved O, (DO) in water is very ina body of water fluctuates daily. fluctuation? -12- important for aquatic organisms. However, the dissolved 0, Which of the following factors and its effects accounts for this Factor Effect ‘a Changing temperature During the day more O, is dissolved than at night so DO is higher during the day. (B) | Changing light Plants release more O, at night so DO is increased at night. (C)_| Number of organisms in the water [DO decreases during the day as organisms respire. Pollution NO, and PO.* runoff are food for algae which decreases the DO content. END OF TEST IF YOU FINISH BEFORE TIME IS CALLED, CHECK YOUR WORK ON THIS TEST.