Solid State 2.

29

Exercise - 1
Objective Problems | JEE Main
CrYstalline & amorphous solids, 9. Which is covalent solid-
of crystalline solids (B) Diamond
Classification (A) Fe,O3
compound LiAg crystallizes in (D) All
The intermetallic (C) Graphite
in which both lithium and silver have
cubic lattice The arrangement ABC ABC
is referred
number of eight. The crystal class is 10. ******'.
coordination
(A) Simple cubic to as-

centred cubic
(A) Octahedral close packing
(B) Body (B) Hexagonal close packing
centred cubic
(C) Face (C) Tetrahedral close packing
(D) None
(D) Cubic close packing
is called pseudo solid have
one
(Cu, Ag, Au)
-

Which 11. The most malleable metals

(A) CaF2 (B) Glass
close packing of the type
(C) NaCI (D) All (A) Hexagonal close packing
(B) Cubic close packing
Graphite is an example of (C)Body centred cubic packing.
3. of
(A) lonic solid
(D) Malleability is not related to type packing
(B) Covalent solid
available volume
(C) Vander waal's crystal 12. The maximum percentage of
(D) Metallic crystal that can be filled in a face centred cubic system
by an atom is-
(A) 74% (B) 68%
Amorphous solids
(C) 34% D) 26%
(A) Possess sharp melting points
when cut with knife
(B) Undergo clean cleavage
Types of cubic unit cell
(C) Do not undergo clean cleavage when
cut
SCC, BCC, FCC
with knife
13. The rank (effective atoms per unit cell) of a

(D) Possess orderly arrangement over long

cubic unit cell is 4. The type of cell as-
distances (B) Face centred
(A) Body centred
(C) Primitive (D) None of these
5. Wax is an example of -

(A) lonic crystal 14. An element occurring in the BCC structure has
(B) Covalent crystal 12.08 x 1023 unit cells. The total number of atoms
(C) Molecular crystal of the element in these cell will be-
(D) Metallic crystal (A) 1023
24.16 x (B) 36.18 x 1023
(C) 6.04 x 1023 (D) 12.08 x 1023
. Crystals which are good conductor of electricity
and heat are known as -
15 The space occupied by B.C.C. arrangement is
(A) lonic crystals approx -

(B) Covalence crystals (A) 50% (B) 68%

(C) Metallic crystals (C) 74% (D) 56%
(D) Molecular crystals
1.
lodine crystals are 16. Transition metals, when they form interstitial

(A) Metallic solid (B) lonic solid compounds, the non-metals (H, B, C, N) are

(C) Molecular solid (D) Covalent solid accomodated in-

(A) Voids or holes in cubic -

packed structure
8 (B) Tetrahedral voids
Which among the following will show anisotropy-
(A) Glass (B) Barium chloride (C) Octahedral voids

(C) Wood (D) All of these

(D) Paper
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 2.30 Theory and Exercise Book

17. If a is the length of unit cel, then which one is 25. A binary solid (A" B ) has a
correct relationship- theedge length is 400 pm and rock salt .
(A) For simple cubic lattice, Radius of metal pm the radius of anion is - radius ofe,
a (A) 100 pm
ation is75
atom=F 2 (C) 250 pm
(B) 125 pm
(B) For bcc lattice, Radius of metal (D) 325 pm
atom=F 3 4a Voids in close
packing
(C) For fec
26. The tetrahedral
voids formed
by ccp
lattice,Radius of metal of Cl ions in rock salt
a
(A) Occupied by Na* ions
structure are arrangemeni
atom=
2/2 (B) Occupied by Ch ions
(D) All
(C) Occupied by either Na' or
C ions
(D) Vacant
18. The number of atoms present in a simple cubic
unit cell are-
27. Each unit cell of NaCI consists of 4
(A) 4 (B) 3 (C) 2 (D) 1 and -
chloride ion
(A) 13 Na atoms (B) 4 Na ions
19. The number of atoms/molecules contained in one (C) 6 Na atoms (D) 8 Na atoms
face centred cubic unit cell of a monoatomic
substance is-
Structure of Ionic compounds,
(A) 4 (B) 6 (C) 8 (D) 12 radius ratio rule
28. In the unit cell of NaCl lattice there
20. In are
a body centred cubic arrangement, the number (A) 3Na ions (B) 6Nat ions
of atoms per unit cell is-
(C) 6C1 ions (D) 4 NaCl units
(A) 8 (B) (C) 1 (D) 4

29. TiCl has structure similar to CsCI, the

21. The fraction of total volume co-
occupied by the
ordination number of Ti* is-
atoms in a simple cube is -
(A) 4 (B) 6 (C)10 (D) 8

A)(B)2(C)2(D)
(A)
30. For tetrahedral co-ordination the radius ratio
(r
22. 6:6 of NaCl coordination changes to
/should be
(A) 0.414 0.732 (B)>0.732
8 8 coordination on -
(C) 0.156 0.225 (D) 0.225 - 0.414
(A) applying high P
(B) increase in temperature
31. The ratio of cations to anion in a closed pac
(C) both (A) and (B)
(D) no effect on coordination
tetrahedral is-
(A) 0.414 (B) 0.225
23. The C.N. of M4* in (C) 0.02 (D) None
a
MX, is 8. Hence, C.N.
of X is -

(A) 8 (B) 6
32. The radius of the Nat is 95 pm and that or
C) 4 (D) 2 mber
1onis 181 pm. Predict the co-ordination nu
24. In the cubic close of Nat
packing, the unit cell has
(A) 4 (B) 6
(A) 4 tetrahedral voids each of which is shared
by (C)8 (D) Unpredictable
four adjacent unit cells.
2.16
(B) 4 tetrahedral voids within the unit cell 33. The ionic radii of Rb and I are 1.46 and
exhibited

(C) 8 tetyrahedral voids each of the which is shared A. The most

probable type of structure
by four adjacent unit cells. by it is-
(D) 8 tetrahedral voids within the unit cells. (A) CsCI type (B) NaC type
(C) ZnS type (D) CaF2 type
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 Solid State 2.31

ong the following is an example of 38. nature

One The yellow colour of ZnO and conducting
ferroelectric compound
s4. produced in heating is due to-
(A) Quartz (B) Lead chromate (A) Metal excess defects due to
interstitial cation
(C) Barium titanate (D) Tourmaline (B) Extra positive ions present in an interstitialT
site
Certain crystals produce electric signals on (C) Trapped electrons
35. of pressure. his phenomenon is (D) All
plication
called 39. In antiflourite structure, the negative 1ons
(A) Pyro electricity (B) Ferroelectricity
tetrahedral voids
(C) Piezoelectricity (D) Ferrielectricity (A) Occupy
(B) Occupy octahedral voids
here represents
Structure shown (C) Are arranged in ccp
36.
(D) Are arrange in hcp
Cation
of-
Anion 40. A silicon solar battery makes use

(A) n-Type semiconductor

(B) p-Type semiconductor
defect (B) Frenkel defect with As and
(A) Schottky (C) Combination of Si doped
excess defect
(C) metal (D) p-njunction
these
(D) none of
Ferrimagnetism 1S in
41.
Defects in solids & (B) T t
(A) 11 t t
property of solids (D) of these
C) t t none

if lowers
Which of the following defect, present,
the density of the crystal-
(A) Frenkel

(B) Schottky
(C) Edge dislocation
F-centres.
(D) Constitution of

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2.32 Theory and Exercise Book

Exercise 2 (Level-I) Objective Problems | JEE

Crystalline & amorphous solids, 9. A solid is made of two
Main
Classification of crystalline solids atoms Z are in C.C.P.
elements X and
1. Which is/are amorphous solids- X occupy all the arrangement whiwhitle 7.aloms
(A) Rubber (B) Plastics formula of the
rahedral sites. What
compound- is the
C) Glass (D) All (A) XZ
(B) XZ,
C) XZ (D) Unpreictable
2. LiF is a/an-
(A) lonic crystal (B) Metallic crystal 10. Close packing is maximum in the crystal.
(C) Covalent crystal (D) Molecular crystal
(A) Simple cubic (B) Face centred
3. A solid having no definite shape is called- (C) Body centred (D) None of these
(A) Amorphous solid (B) Crystalline solid 11. In a body centred cubic cell an
C) Anisotropic solid (D) None of these atom at the ho
of centre is shared by-
4. How many number of atoms (A) I unit cell (B) 4 unit cells
there in a cube
are

based unit cell having one atom on each corner C) 3 unit cells (D) 2 unit cells
and two atoms on each body diagonal of cube-
12. In face centred cubic lattice the
a
(A) 8 (B) 6 C) 4 D) 9 number of
nearest neighbour for a given lattice
point are
5 An alloy of copper, silver and gold is found to (A) 6 ) 8 (C)12 (D) 14
have copper constituting the C.C.P. lattice. If
silver atoms occupy the 13. For the structure given below the site marked
edge centres and gold
is present at body centre, the alloy has a formula- as S is a-

(A) CuAgAu (B) CuAgAu

C) Cu,AgAu (D) CuAgAu
6. The number of
atoms/molecules contained in
face centred cubic unit cell of a mono atomic
one
.'
substance is-
(A) (B) 2 C) 4 (D) 6
(A) Tetrahedral void (B) Cubic void
1. In a face centred cubic
arrangement ofA & B (C) Octahedral void (D) None of these
atoms whose A atoms are at the corner of the
unit cell & B atoms at the face centres. One of 14. A solid has a structure in which W atoms are locatu
the A atom is missing from one corner in unit at the corners of a cubic lattice, O atom at the cente
cell. Thesimplest formula of compound is- and Na atom at centre of the
of the edges cuD
(A) A,B3 B) AB The formula for the compound is
(C) A,B24 (D) A78 B3 (A)NaWO, (B) NaWO,
(C) Na,WO, (D) NaWO,
Types of cubic unit cell
sCC, BCC, FCC 15. Which one of the following schemes of
ordering

8. In a face centred cubic cell, an atom at the face

closed packed sheets ofequal sized spheres
centre is shared by- generate close packed lattice.
(A) 4 unit cells (B) 2 unit cells (B) ABACABAC
(A) ABCABC
(C) I unit cell (D) 6 unit cells (D) ABCBCABCBC
(C) ABBAABBA

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 Solid State 2.33

Cations
solid has a B.C.C. structure. If the distance 24. In a solid, oxide ions are arranged in CCP.
A
voids and
approach ween the two atoms is A occupy one-sixth of the tetrahedral
of closest
length of the cell is- the octahedral
1.73 A. The edge
73 cations B occupy one-third of
is -

voids. The formula of the compound

(A) 200 pm (B) V2 Pm
(B) AB0
(A) ABO
(C) 142.2 pm (D) 2 pm (C) ABO3 (D) A,B03
simple cubic
25. A certain metal crystallises in a
of KCI is 1.9893 g cms and the
The density structure. At a certain temperature, it arranges
length of a side unit cell is 6.29082 A as
to give
a centred structure. In this transition,
body
determined by X-Rays diffraction. The value of the density of the metal-
avogadro's number calculated from these data is-
(A) Decreases (B) Increases
6.017 x 1023 (B) 6.023 x 1023
(A) (C) Remain unchanged
1023 (D) 6.017 x 1019]
(C) 6.03
x
without definite pattern
(D) Changes a

sodium crystallizes in a 26. The tetrahedral voids formed by ccp arrangement

At room temperature,
8. of Cl ions in rock salt structure are
body centred cubic lattice with a 4.24 A. The =

theoretical density of sodium (At. wt. of (A) Occupied by Na ions

Na =23) is- (B) Occupied by Cl ions
(B) 2.002 g cms (C) Occupied by either Na* or Cl ions
(A) 1.002 g ems
C) 3.002 g cm (D) None of these (D) Vacant

27. A solid is formed and it has three types ofatoms X,

19. The number of next nearest neighbours around each
Y, Z, X forms a FCC lattice with Y atoms occupying
particle in face-centred cubic lattice is
all the tetrahedral voids and Z atoms occupying half
(A) 4 (B) 6 (C)8 (D) 12
the octrahedral voids. The formula of the solid is

Voids in close packing (A) X,Y,Z (B) XY.Z,

20. The interstitial hole is called tetrahedral because (C) X,Y,Z D)X, YZ,
(A) It is formed by four spheres
Structure of Ionic compounds,
(B) Partly same and partly different.
radius ratio rule
(C)It is formed by four spheres the centres of which
28. A solid XY has NaCl structure. If radius of X*
form a regular tetrahedron.
is 100 pm. What is the radius of Y ion-
(D) None of the above three.
(A) 120 pm (B) 136.6 to 241.6 pm
21. lf the anions (A) form hexagonal closest packing and (C) 280 pm (D) Unpredictable
cations (C) occupy only 2/3 octahedral voids in it, then
29. A solid AB has rock salt structure. If the edge
the general formula of the compound is
length is 520 pm and radius of At is 80
(A) CA (B) CA pm, the radius of anion B would be
-

(C) CA (D) C,A, (A) 440 pm (B) 220 pm

2. (C) 360 pm (D) 180 pm
in a close packed array of N spheres, the number
of
tetrahedral holes are- 30. The structure of MgO is similar to NaCI. The
co-ordination number of Mg is
N
(B) 4N (A) 2 (B) 6 (C) 4 (D) 8

(C) 2N (D) N 3 In Each unit cell of NaCl chlorine atom are

present at 14 lattice points then at how many
The vacant space in B.C.C. unit cell is- lattice point, 'Na' will be present
(A) 32%
(B) 10% (A) 13 Na atoms (B) 14 Na atoms
C) 23%
(D) 46% (C) 6 Na atoms (D) 8 Na atoms
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2.34 Theory and Exercise Book

32. The structure of sodium chloride crystal is- 42. How many atoms are there
in a
(A) Body centred cubic lattice which forms hexagona unit cell
(B) Face centred cubic lattice face-centred atom crystals,
each end ofthere
Ma
and 3
in
the bengcel
unit
(C) Octahedral completely enclosed atoms within
D) Square planar cell- thin the uni
(A) 4 (B)6
33. The coordination number of cation and anion in (C) 12
Fluorite and CsCl
(D)8
CaF, are respectively 43. The intermetallic compound
(A)8:4and 6:3 LiAg crystallizs
(B)6:3and 4:4 cubic lattice in which both lithiu
and
(C)8:4 and 8:8 (D)4:2 and 2:4 coordination number of eight. The crystalsilver hav
have
classis
34. A
(A) Simple cubic (B) Body
compound XY crystallizes in BCC lattice with
unit cell edge length of 480 (C) Face centred cubic (D) None centred cubie
pm. If the radius ofY
is 225 pm, then the radius of X* is
44. The mass of a unit cell of CsCI
(A) 127.5 pm (B) 190.68 pm corresponds to
(A) 1 Cs and 1 C (B) 1 Cs and 6 C
(C) 225 pm (D) 255 pm
(C) 4 Cs and 4 C (D) 8 Cs and 1 C
35. In the closest
packing of atoms A (radius: r), the 45. Which of the
radius of atom B that can be fitted into tetrahedral following is incorrect about
NaC
voids is structure?
(A) 0.155 r (A) Nearest neighbours of Na' ion is six C ion
(B)0.225 r (B) Na ion make fcc lattice
C)0414r, (D) 0.732 r
(C) C ion pack in cubic close packed
36. An ionic arrangement
compound AB has ZnS type structure. If (D) There are eight next nearest neighbours of
the radius A' is 22.5 pm, then the ideal Na' ion
radius of B
would be
(A) 54.35 pm (B) 100 pm Defects in solids &
(C) 145.16 pm 46.
property of solids
(D) none of these Schottky defect is noticed in-
37.
(A) NaCl B) KCI
The unit cell cube length for LiCl
(just like NaCl (C) CsCI (D) All
structure) is 5.14 A. Assuming anion-anion
contact, the ionic radius for chloride ion is- 47.
(A) 1.815 Å
NHCI crystallizes in a body-centered cubic type
(B) 2.8 A lattice with a unit cell
(C) 3.8 ÅA (D) 4.815 Å
edge length of 387 pm. The
distance between the oppositively charged ions m
38. A binary solid (A B) has a zinc
thelatticeis
structure with B ions
blende (A) 335.1 pm (B) 83.77 pm
and AT ions
constituting the lattice (C)274.46 pm (D) 137.23 pm
occupying 25% tetrahedral holes.
The formula of solid is-
48. Which of the following will show schottky defect
(A) AB
(B) AB
(C) AB, (A) CaF, (B) ZnS
(D) AB (C) AgC (D) CSCI
39. ZnS is-
(A) lonic crystal 49. Give the correct order ofinitials T (true) orF (raalse)
(B) Covalent crystal for following statements.
(C) Metallic crystal
(D) Vander Waals' crystal .In an anti-fluorite structure anions form.FCC
lattice and cations all tetrahedral voids.
40. The mass of a unit cell of CsCl II. If the radius of occupy a r e 0.2 A
an
corresponds cations
0.95 A then coordinate number anions
to- and
(A) 8Cs* and 1CI (B) 1Cs and 6CI ofcation in the crySt
(C) 1Cs* and 1CI (D) 4Cs* and 4CI Is4
III. An atom/ion is transferred from a lattice site to

41. The density of CaF, (fluorite an

interstitial position in Frenkel defect.
structure) is 3.18 g/
cm. The length of the side of the unit cell is .
Density of crystal always increases
due
to

(A) 253 pm (B) 344 pm substitutinal impurity defect.

(C) 546 pm (D) 273 pm (A) TFFF (B) FTTF
(C) TFFT (D) TFTF

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 Solid State 2.35

ercise -2 (Level-II) JEE Advanced

Multiple Correct |
The
compound having general formula M2+ Answer the following questions
called as dimension is
Fe,04 are 5. Empty space left in HCP in three
(B) Spinels (D) 26%
(A) Ferrite
(A) 76% (B) 74% (C)68%
C) Ferrimagnetic substance
of no. of atoms to no. of tetrahedral
(D) Zeolite 6. In ccp, ratio

wWhich of the following statement is/are incorrect

void is-
0.5 3
in the rock-salt structure if an ionic compounds?
(A) (B) C) (D)
A) cOordination number of cation is four where
anion is six.
as that of 7. Size order of octahedral,
tetrahedral & cubic void
number of cation is six where
(B) coordination as
is -
thatof anion is four. octahedral void
tetrahedral void <
number of each cation and anion (A) cubic <
C) coordination tetrahedral void > octahedral void
is four.
(B) cubic >
tetrahedral void = octahedral void
number of each cation and anion (C) cubic =

D) coordination octahedral void > tetrahedral void

is SIX.
(D) cubic >

HCP
statements are correct 8. In certain metallic oxide, metal M occupy
3.
Which of the following
(A) The
coordination number of each type of ion in 2
of octahedral void,
CsCl is 8.
lattice & 0 occupy 3 rd
in BCC structure has
(B) A metal that crystallises formula of crystal is -

a coordination
number 12.
(A) M,O, (B) MO, (C) M,O, (D) M,0,
C) A unit cell of an
ionic crystal shares some of its
ions with other unit cells STATEMENT TYPE QUESTIONS
NaCl is 552 pm.
(D) The length of the unit cell in Each of the questions given below
consist of

II. Use the

a-95pm r
= 181 pm] Statement - I and Statement
to choose the appropriate answer.
following Key
Statement- II are true,
Select write statement (s) (A) If both Statement- I and
4.
and Statement II is the
correct explanation
occupy the second nearest neighbour
-

(A)8 Cs' ions

of Statement- I.
locations ofa Cs' ion
are true
by six voids
surrounded
in two
If both Statement -
I and Statement - II
(B) Each sphere is (B) explanation
d1mensional hexagonal close packed layer but Statement
-
II is not the correct

anions are 0.3 A of Statement I.

(C) If the radius of cations and is
of cation of the I is true but Statement - II
and 0.4 A then coordinate number (C) IfStatement
crystal is 6. false.
Statement - II is
from its lattice If Statement I is false but
(D) In AgCl, the silver ion is displaced
-

(D)
pOSition to an interstitial position
such a defect is true.
the density
called a frenkel defect. Statement -
I. Due to Frenkel defect
9.
of solid decrease.
ASSAGE BASED QUESTIONS: II. In Frenkel defect
cation or anion

Passagen two dimension, there are square close packing Statement -

lattice sites
is present at interstitial site leaving

dimension, vacant.
Hexagonal close packing. In three
and CCP
how threre are HCP, BCC the temperature
in packing 1s
10. Statement - I. By increasing
ngement. Unoccupied space from 8 8 to 6 6.
Anown as void which may be octahedral, C.N. of CsCl changes influences the
Temnperature also
tetrahedral or cubic void and formation
of void Statement - II.
in crystal. C.N. of solid.
depend on atomic 1onic arrangment
or
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11. Statement 1. Solid having more F-centers have 17. Increase in pressure in ionic solids
intense color. co-ordination No. may
mas.

Statement Il. Excess of Nat in NaCl solid decrease

having F-centers make it appears to pink. 18. The amorphous solids are an
isotropic
12. Statement - I. Close packing of atoms in cubic COLUMN MATCHING
structure is in order of: fcc> bec > sc Match the following columns
Statement II. Packing density
19. ColumnI Column II
vol.of sphere in an unit cell |
A. Rock salt P.
a Face centred
cubic, anion in
13. Statement I. Pure NaCl is diamagnetic in nature.
-

B. Fluorite tetrahedral void

Statement II. In NaCl, Nat occupy octahedral Face centred
voids cubic, cation in
C. Agl, ZnS
octahedral void
TRUE/ FALSE R. Face centred
State whether the following statements are cubic, cation in
True or False alternate
tetrahedral void
14. Coluor of LiCl due to metal excess
D. Na,o S. Face centred
defect is
pink. cubic, cation in
tetrahedral void
15. The imperfection in crystal increases with increases T. 6{all the digits in
in temperature.
)show co-ordination
16. FCC structure possesses the
number
most close packing U Cation (8), anion (4)
of atoms in it.
V. Cation (4), anion (8)
W. Cation (4), anion (4)

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Exercise 3
cubic solid is made up of two elements A and B.
A
Atoms B are at the orners of the cube and A at
1 edge length of unit cell of AgCl is
t h e b o d y c e n t r e . What is the formula of
compound.
compound alloy ofgold and copper crystallizes in
A lattice
a cubic.lattice in hich gold occupy that lattice point
at Comers of the cube and copper atom occupy the
ontres of each of the cube faces. What is the
compound.
formula of this
A Cubic solid is made by atoms A forming close
pack arrangement,
B occupying one. Fourth of
tetrahedral void and C occupying half of the
octahedral voids. What is the formula ofcompound.
What is the percent by mass of titanium in rutile, a
mineral that contain 1itanium and oxygen, ifstructure
can be described as a closet packed array of oxide
in one half
ions, with titanium ofthe octahedral holes.
What is the oxidation number of titanium?
Spinel important class of oxides consisting of
is a gold= 197 amu.
two types ofmetal ions with the oxide ions arranged
in CCP pattern. The normal spinel has one-eight of
the tetrahedral holes occupied by one type of metal
ion and one half of the octahedral hole occupied by
another type of metal ion. Such a spinel is formed
by Zn, Al* and O, with Zn2* in the tetrahedral
holes. Give the formulae of spinel.
Iron occurs as bcc as well as fcc unit cell. If the
effective radius of an atom of iron is 124 pm.
Compute the density ofiron in both these structures.
A closed packed structure of uniform spheres has
the edge length of 534 pm. Calculate the radius of
sphere, if it exist in
(A) simple cubic lattice
(B) BCC lattice
(C) FCC lattice
Calculate the density of diamond from the fact that it
has face centered cubic structure with two atoms
per lattice point and unit cell edge length of3.569 A.
An element crystallizes into a structure which may
Dedescribed by a cubic type of unit cell having one
aom on each corner of the cube and two atoms on
e of24its body diagonals. If the volume of this unit
cel is
x
1024 cm and density of element is 7.2
Cm, calculate the number of atoms present in
200 g of
element.
Silverh
ofan
silver
atomic radius of 144 pmand the density
is 10.6 g cm. To which type of cubic
crystal, silver belongs?
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of NaCI. The
AgCl has the same structure as that
11.
found to be 555
Find
pm and the density of AgCI
is 5.561 g cm'.
the percentage of sites that are unoccupied.
12. Xenon crystallises in the face-centred cubic
the
and the edge of the unit cell is 620 pm. What is
nearest neighbour distance and what is the radius
of xenon atom ?
The two ions At and B- have radii 88 and 200 pm
13.
respectively. In the closed packed crystal of compound
AB, predict the co-ordination number of A*".
14. CsCl has the bec arrangement and its unit cell edge
length is 400 pm. Calculate the interionic distance
in CsCI.
1 Gold crystallizes in a face centered cubic lattice. If
the length of the edge of the unit cell is 407 pm,
calculate the density of gold as well as its atomic
radius assuming it to be spherical. Atomic mass of
16. The density of KBr is 2.75 g cms, The length of
the edge of the unit cell is 654 pm. Show that KBr
has face centered cubic structure.
(N=6.023 x 1023 mol, At. mass K=39, Br = 80)
17. An element crystallizes in a structure having FCC
unit cell of an edge 200 pm. Calculate the density, if
200 g ofthis element contains 24 x 10 atoms.
18. The effective radius of the iron atom is 1.42 . If has
FCC structure. Calculate its density (Fe = 56 amu)
19. A crystal of lead (I) sulphide has NaCI structure.
In this crystal the shortest distance between Pb2
ion and S* ion is 297 pm. What is the length of the
edge ofthe unit cell in lead suiphide ?Also calculate
the unit cell volume.
20. If the length of the body diagonal for CsCl which
crystallises into a cubic structure with C ions at
the corners and Cs* ions at the centre of the unit
cells is 7 Å and the radius of the Cs* ion is 1.69 A,
what is the radii of CH ion ?
21. In a cubic closed packed strueture of mixed oxides
the lattice is made up of oxide ions, one eighth of
tetrahedral voids are occupied by divalent ions (A2*)
while one half of the octahedral voids occupied
trivalent ions (B"). What is the formula of the oxide?
22. A solid A" and B has NaCl type closed packed
structure. If the anion has a radius of 250 pm, what
should be the ideal radius of the cation ? Can a
cation C having a radius of 180 pm be slipped into
the tetrahedral site of the crystal of A'B? Give
reasons for your answer
394 Rajeev Gandhi Nagar, Kota
2.38 Theory and Exercise Book

23. If the radius of Mg ion, Cs' ion, O ion, S ion 35. NaH crystallizes in the same
and Cl ion are 0.65 Å, 1.69 A, 1.40 Å, 1.84 Ä, and
structure as tthat c NaCl
The edge length of the cubic unit
cell of
of H, NaH is 488 A.
1.81 A respectively. Calculate the co-ordination (a) Calculate the ionic radius
numbers of the cations in the crystals of Mgs, MgO
and CsCl.
ionic radius of Na' is 0.95 A.
(b) Calculate the density of NaH
provided the
24. A unit cell of
sodium chloride has four formula units. 36. Metallic gold crystallises in fcc
The edge oflength ofthe unit cell is 0.564 nm. What of the cubic unit cell is a 4.07 lattice. The 1
is the density of sodium chloride. (a) What is the closest distance
=

A length
(b) How many "nearest neighbours"between gold
25 In cubic
a
crystal of CsCI (density =3.97 gm/cm) atom have at the distance does each
the eight corners are
occupied by C ions with Cs (c) What is the density of gold ? calculated
in (a). gold
1ons at the centre. Calculate the distance between
the neighbouring (d) Prove that the packing fraction of
Cs and Cl ions. 37.
gold is 0,74
26 Ice crystallizes in a
Calculate the value of Avogadro's number from the
following data : hexagonal lattice. At the
low temperature at which
Density of NaCl 2.165 cm
=

the
Distance between Na and structure was
C in NaCl 281 pm. =

determined, the lattice

27. KCI crystallizes in the same
constants were a 4.53 A, and b
type of lattice as does =

figure). How many molecules are 7.60 A (Cea

=

NaCl. Given that Na0.5 and Na =

CI
0.7 given unit cell ? [densityice) 0.92contained in a
=

Calculate K 38. gm/cm'|

(a) The ratio of the sides of unit cell for
Using the data given below, find the
KCIto that lattice to which the type of cubie
for NaCl and crystal belongs.
Fe V
(b) The ratio of densities of NaCl to that a in pm Pd
for KCi 286 301
28. An element A p in gm cm 388
(Atomic weight 100) having bcc
= 7.86 5.96 12.16
structure has unit cell 39.
edge length 400 pm. Calculate Potassium crystallizes in
the density ofA and
number of unit cells and number lattice with edge length, a5.2 A
a
body-centered cubic
of atoms in 10 =

gm of A. (a) What is the distance between

29. nearest neighbours?
Prove that the void (b) What is the distance
space percentage in zinc blende between next-nearest
structure is 25% neighbours?
30. The (c) How many nearest
composition of a sample of wustite is atom have? neighbours does each K
0,What percentage of iron is present in the Fe:
0.93
form (d) How many next-nearest
of Fe(lII) ?
K atom have? neighbours does each
31.
BaTiO, crystallizes in the
prevoskite structure. This (e) What is the calculated
structure may be described as a cubic potassium? density of crystaline
barium ions lattice with
Oxide ions
occupying the corner of the unit
cell,
40. Prove that void
space in fluorite structure per
occupying face-centers and
the volume of unit cell is unt
ion
occupying the center of the unit cell. titanium 41.
0.243.
(a) If titanium is described Acompound formed by elements X & Y,
BaO lattice, what
as
occupying holes in
type of holes does it
in a cubic structure,
where X is at
Crystalli2zs
corners Or
(b) What fraction of occupy? the cube and Y is at six face centers.theWhat
32.
this type hole does it occupy? 1ormula of the is
tne
Rbl
crystallizes in bcc structure in which each estimate the
compound ? If side length is DA.
is Rb density of the
surrounded by
2.17 A. Find the eight iodide ions each of radius
weight of X and Y as 60 andsolid assuming ato
length of one side of Rbl unit cel. 42. 90
he mineral hawleyite, one form ofCds,
respectively
33
If NaCl dopped with 10 mol %
is in one of the cubic crystallizes
the numbers of SrCl,, what is A. The lattices, with edge lengtn .0
34.
cation vacancies ? density of
) In which cubic hawleyite is 4.63 g
Find the size of lattice does llize?
hawleyite
octahedral void in anlargest sphere that will fit in
ideal FCC crystal as a 43.
(i) Find the
Schottky defect in g cm crysta
of atomic radius 'r'.
The function Diamond structure can be considered as. 18 ZnS
void does not distort insertion of this sphere into (Zinc blend) structure
the FCC lattice. in which each Zn'
packing fraction of FCC lattice Calculate the allernate tetrahedral
void and S2 in cubic
octahedral voids are filled when all the arrangement is close
by this sphere. C-C replaced by one carbon ator1.5 A.
covalent
the edge bond length in diamond
wnat is
:info@motion.ac.in, url : www.motignac in
is
length of diamond unit cell z =8).
 Solid State 2.39

Exercis
- 4 |Level-I Previous Year | JEE Main

has a unit cell consisting of A 6. cubic lattice. If 'a'

An i o n i c c o m p o u n d
CsCl crystallises in body centred
the corners of a cube and B ions on the is its edge length then which of the following
ans at
on
of the faces of the cube. The empirical expressions is correct ? JEE Main 2014]
centres

would be [AIEEE-20051
formula for this compound (A) e +e a (B) c +c 3a
(A) A,B
(C) AB (C) A,B (D) AB 3a
(C) es +
Tc= 3a (D) c +Fer 2
Total volume of atoms present in a face-centred
ctbic unit cell of a metal is (r is atomic radius) in body centred cubicc
7. Sodium metal crystallizes a

of
AIEEE 2006| lattice with a unit cell edge of 4.29 Å. The radius
sodium atom is approximately: 1JEE Main 2015]
24
(A)r (B) r (A) 5.72 A (B) 0.93 A
(C) 1.86 A (D) 3.22 A

16 20
C)r3 D)r 8. A metal crystallises in a face centred cubic struc-
the
ture. If the edge length of its unit cell is 'a',
atoms of element Y form ccp lattice closest approach between two atoms in metallic
In a compound,
JEE Main 2017]
and those of element X occupy 2/3rd of tetrahedral crystal willbe:
voids. The formula of the compound will be (B) 2a
-

(A) 2W2a
[AIEEE 2008]

(A) X,Y (B) X,Y

C) X,Y4 (D) X,Y, C (D) 2a

Copper crystallises in fcc with a unity cell length of 9. Which type of 'defect' has the presence cations in

361 pm. What is the radius of copper atom ? the interstitial sites ? JEE Main 2018]
[AIEEE-2009] Metal deficiency defect
(A)
(A) 108 pm (B) 127 pm (B) Schottky defect

C)157 pm (D) 181 pm (C) Vacancy defect

(D) Frenkel defect
Which of the following exists as covalent crystals
in the solid state ? JEE Main 2013]
(A) Sulphur (B) Phosphorus
C)lodine (D) Silicon

can visit
For 2019 & 2020 year questions you
www.onlinetestseries.motion.ac.in

Kota
Corporate Office: Motion Education Pvt. Ltd., 394 Rajeev Gandhi Nagar,
2.40 Theory and Exercise Book

Exercise - 4 | Level-II Previous Year | JEE

Advan
1.
ed
An element crystallises in FCC lattice having edge surrounded in the same plane by six
identical Snhe
length 400 pm. Calculate the maximum diameter as closely as
possible. Three spheres are then pheres
which can be placed in interstital sites without over the first layer so that
plaeaced
they
each.touch
disturbing the structure. JEE 2005 and represent the second layer. Each one of other
2.
three spheres touches three these
th.
spheres of the bot
Which of the following FCC structure contains
layer. Finally, the second layer is ttom
cations in alternate tetrahedral voids? |JEE 2005] covered with .

third layer that is identical to the

(A) NaC1 (B) ZnS bottom layer
(C) Na,O
relative position. Assume radius of every sphere
(D) CaF be 'r'.
te
to

3. The edge length of unit cell of a metal having atomic 120

weight 75 g/mol is 5Å which crystallizes in cubic 120°
lattice. If the density is 2 g/cc then find the radius
of metal atom. (N =6 x 103). Give the answer in
pm. JEE 2006]
c/2
4. Match the crystal system / unit cells mentioned in
ColumnI with their characteristic features mentioned
D
in Column II. Indicate your answer by
darkening
the appropriate bubbles
of the 4 x 4 matrix
given in 5. The number of atoms in this HCP unit cells is
the ORS. JEE 20071
ColumnI
JEE 2008
(A) 4 (B) 6
(A) simple cubic and face-centred cubic
(B) cubic and rhombohedral
(C)12 (D) 17

(C) cubic and tetragonal 6. The volume of this HCP unit cell is JEE 2008|
(D) hexagonal and monoclinic (A) 24/2 r3 (B) 16/2r3
Column II
(P) have these cell parameters a = b = c and
(C) 12/2r3 (D) 3643
aB=Y 1. The empty space in this HCP unit cell is
(Q) are two crystal systems
JEE 2008)
(R) have only two crystallographic angles of 90°
(A) 74 % (B) 47.6%
(S) belong to same crystal system.
C) 32% (D) 26%

Paragraph for Question No. 5 to 7

8. The packing eficiency of the -dimensional squ
In hexagonal systems of crystals, a
frequently unit cell shown below is JEE 2010
encountered arrangement of atoms is described as
a hexagonal prism. Here, the top and bottom of the
cell are regular hexagons and three atoms are
sandwiched in between them. A space-filling model
-L
of this structure, called hexagonal close-packed (A) 39.27% (B) 68.02%
(HCP), is constituted of a sphere on a flat surface
(C) 74.05% (D) 78.54%

:info@motion.ac.in, url: wwW.motion.ac.in, : 1800-212-1799,8003899588

 Solid State 2.41

hexagonal
The number ofh faces that are present in 14. A crystalline solid of a pure substance has a face
centred cubic structure with a cell edge of 400 pm.
truncated
octahedron is JEE 20111 is
a If the density of the substance in the crystal
in 256 g
A
ompound M,X, has cubicclose packing (ccp)
8g cm', then the number of atoms present
N is.
. arrangement
of X. Its unit cell structure is shown ofthe crystal in Nx 1024, The value of
JEE Adv. 2017
pirical formula of the compound is
below. The
JEE Adv. - 2012]
15. Consider an ionic solid MX with NaCl structur.
Construct a new structure (Z)
whose unit cell is
M= 0
from the unit cell of MX following
the
X =O constructed
below. Neglect fthe
sequential instruction given
charge balance.

1) Remove all the anions (X) except the central

(A) MX (B) MX,
one

C) M,X (D) MX,4 (ii) Replace all the face centered cations (M) by
anions (X)
of X" 10ins around A' ion in solid
1
The arrangement i ) Remove all the corner cations (M)
with cation (M)
AX is given in
the figure (not drawn to scale). If
iv) Replace the central anion (X)
the radius of Xis
250 pm, the radius of A* is (number of anions)
in Z is
JEE Adv. 2013 The value of
(number of cations)
JEE Adv. 2018]
(A) 104 pm

(B) 125 pmm

C
(C)183pm
D) 57 pmn

If the unit cell of a mineral has cubic close packed

12
fraction of
(ccp) array of oxygen atoms with m

octahedral holes occupied by aluminium ions and n

fraction of tetrahedral holes occupied by magne-

SIum ions, m and n, respectively, are

JEE Adv. 2015]

1
() 28 B) 14

(D) 4'8

h e CORRECT statement(s) for cubic close packed

(cep) three dimensional structure is(are)
JEE Adv. 2016]
(A) The number of the nearest neighbours of an
atom present in the topmost layer is 12

8) The efficiency of atom packing is 74%

The number of octahedral and tetrahedral voids
per atom are and 2, respectively

The unit cell edge length is 22 times the

radius of the atom

Kota
Corporate Office Motion Education Pvt. Ltd., 394 Rajeev Gandhi Nagar,
 2.42 Theory and Exercise Book

ANSWERKEYS
Exercise - 1 Obiective Problems | JEE
B
n
B 4. 5.
. C C 8. B 9. D C
11 D 10. D
12. 13. B 14. A
16. D 15. B
17. D 18. D 19. A
21. D 22.
20. B
26. D
A 23. C 24 D
25. B
27. B 28. D 29. D
31. B 32. B 33. B 34.
30 D
36. A 37.
35. C
B 38. D 39.
41. C 40 C

Exercise 2 (Level-I)
1 D
Objective Problems| JEE Main
2 A 3 A
8 4. D 5. C 6. C 7.
B 9 C C
10. B 11. A 12.
15. C 13 14.
16. B
22 18. A 19. B 20. C
23. A 24. C
25. B
2 D 30. B 31.
26 D 27 28 B
32. B 33.
36. B
37 A 38
34 B 35 B
39 A 40 41. B
43. B 44 A 42 B
45. D 46. D 47 A 48. D 49 D
Exercise 2
(Level-II)
-

1
Multiple Correct | JEE Advanced
ABC 2 ABC
6 3. ACD 4. BD
C 7. D D
8 D 9. D
11. C 12. 10. A
A 13. B
16. True 14. True 15.
17. False 18. True
False 19. A-QT B-PVQ ;C-RW D-Sv
Exercise 3 |
1. -B 2.
Subjective | JEE Advanced
6. 7.887
AuCu, 3 A,B,C, 59.95%, +4
g/cc, 8.59 gm/cm* 7. 267 5
ZnALO
9 3.472x 10* atoms pm, 231.2 pm, 188.8 pm
10. 8. 3.5 g cm
12. FCC 11.
438.5 pm, 219.25
pm 13 6
0.24%
15. 19.4 g/cm, 143.9 14. 346.4 pm
pm 16. FCC
19. a=
5.94 x 10 cm, V 17. 41.67 g cm3
=2.096 x 1022 cm 18. 5.74 g em
22. 103.4 pm, No 23.
4 20. 1.81 Å
26. 6.01x103 27
6, 8
(a) 1.143, B1.172 24. 2.16 gm/cm
21.
25.
AB,O
35
3.57 A
28 5.188 gm/cm*, 6.023x 1022 atoms of A, 3.0115
30 15.053
x 102 unit cells
31. a) octahedral, B 1/4
33 6.02x10 mol- 32.
34. 4.34 Å
36. (a) 2.88 A, B 12, C 19.4 g/c 0.414 79.3 % 35.
r.

38. for Fe is bec, for V is 37. 4 molecules of (a) 1.49 Å, B 1.37

g/cm
bcc, for Pd is face centered H,OO
41. XY, 4.38 g/cm 39
42. (i) 3.90, (ii) 0.120 g/cc (a)4.5 A, B 52 Å, C8, D6, (e)0.92 glar
43. 3.46 A
Exercise - 4 | Level-I
D
Previous Year | JEE Main
8. C 9.
C
D
3 D 4 B 5. D 6. A 7. C

Exercise -4 | Level-II
Previous Year | JEE
5.
117.1 pm
B 6.
B 3. 216.5 pm 4.
Advanc
T1. A 12. A 7. D 8. D
9. (A)-P, S;(B)- P,Q:(C)-Q:(D)Q.
8
13. B, C, D 10. B
14.
15. 3
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