11/06/2023, 05:13 Scientists see the light on microsupercapacitors

Scientists see the light on microsupercapacitors

MIKE WILLIAMS – DECEMBER 3, 2015
POSTED IN: NEWS RELEASES

Editor’s note: Links to a video and images for download appear at the end of this release.

David Ruth
713-348-6327
david@rice.edu
Mike Williams
713-348-6728
mikewilliams@rice.edu

Scientists see the light on microsupercapacitors

Rice University’s laser-induced graphene makes simple, powerful
energy storage possible 
HOUSTON – (Dec. 3, 2015) – Rice University researchers who pioneered the development of laser-induced graphene
have configured their discovery into flexible, solid-state microsupercapacitors that rival the best available for
energy storage and delivery.

Rice University's laser-induced graphene makes simple, powerful e…

e…

The devices developed in the lab of Rice chemist James Tour are geared toward electronics and apparel. They are
the subject of a new paper in the journal Advanced Materials.
Microsupercapacitors are not batteries, but inch closer to them as the technology improves. Traditional capacitors
store energy and release it quickly (as in a camera flash), unlike common lithium-ion batteries that take a long time
to charge and release their energy as needed.
Rice’s microsupercapacitors charge 50 times faster than batteries, discharge more slowly than traditional
capacitors and match commercial supercapacitors for both the amount of energy stored and power delivered.
The devices are manufactured by burning electrode patterns with a commercial laser into plastic sheets in room-
temperature air, eliminating the complex fabrication conditions that have limited the widespread application of
microsupercapacitors. The researchers see a path toward cost-effective, roll-to-roll manufacturing.

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11/06/2023, 05:13 Scientists see the light on microsupercapacitors
“It’s a pain in the neck to build microsupercapacitors now,” Tour said. “They require a lot of lithographic steps. But
these we can make in minutes: We burn the patterns, add electrolyte and cover them.”
Their capacitance of 934 millifarads per square centimeter and energy density of 3.2 milliwatts per cubic
centimeter rival commercial lithium thin-film batteries, with a power density two orders of magnitude higher than
batteries, the researchers claimed. The devices displayed long life and mechanical stability when repeatedly bent
10,000 times.
Their energy density is due to the nature of laser-induced graphene (LIG). Tour and his group discovered last year
that heating a commercial polyimide plastic sheet with a laser burned everything but the carbon from the top layer,
leaving a form of graphene. But rather than a flat sheet of hexagonal rings of atoms, the laser left a spongy array of
graphene flakes attached to the polyimide, with high surface area.
The researchers treated their LIG patterns — interdigitated like folded hands — with manganese dioxide, ferric
oxyhydroxide or polyaniline through electrodeposition and turned the resulting composites into positive and
negative electrodes. The composites could then be formed into solid-state microsupercapacitors with no need for
current collectors, binders or separators.
Tour is convinced the day is coming when supercapacitors replace batteries entirely, as energy storage systems will
charge in minutes rather than hours. “We’re not quite there yet, but we’re getting closer all the time,” he said. “In
the interim, they’re able to supplement batteries with high power. What we have now is as good as some
commercial supercapacitors. And they’re just plastic.”
Rice graduate students Lei Li and Jibo Zhang and alumnus Zhiwei Peng are lead authors of the paper. Co-authors
are Rice postdoctoral researchers Yongsung Ji, Nam Dong Kim, Gedeng Ruan and Yang Yang and graduate students
Yilun Li, Ruquan Ye and Huilong Fei; Caitian Gao, a visiting graduate student at Rice from Lanzhou University,
China; and Qifeng Zhong, a visiting graduate student at Rice from Southeast University, Nanjing, China.
Tour is the T.T. and W.F. Chao Chair in Chemistry as well as a professor of materials science and nanoengineering
and of computer science.
The Air Force Office of Scientific Research and its Multidisciplinary University Research Initiative and the Chinese
Scholarship Council supported the research.
-30-
Read the abstract at http://onlinelibrary.wiley.com/doi/10.1002/adma.201503333/abstract
This news release can be found online at https://news2.rice.edu/2015/12/03/scientists-see-the-light-on-
microsupercapacitors/
Follow Rice News and Media Relations via Twitter @RiceUNews
Related Materials:

Tour Group: www.jmtour.com

Wiess School of Natural Sciences: http://naturalsciences.rice.edu
Video:

 
 
 
 
https://youtu.be/NqIa5j0Oo9E

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11/06/2023, 05:13 Scientists see the light on microsupercapacitors
Images for download:

 
 
 
 
 
https://news2.rice.edu/files/2015/10/1102_LIG-1-WEB.jpg
Treating laser-induced graphene created at Rice University with manganese dioxide turns the material into a
microsupercapacitor that rivals any on the market today, according to the researchers. The flexible material in this
electron microscope image shows promise for electronics and apparel. (Credit: Tour Group/Rice University)
 
 
 
 
 
https://news2.rice.edu/files/2015/10/1102_LIG-2-WEB.jpg
Rice University scientists are making small, flexible microsupercapacitors in a room-temperature process they
claim shows promise for manufacturing in bulk. The technique is based on their method to burn patterns of
spongy graphene into plastic sheets with a commercial laser. (Credit: Tour Group/Rice University)
Located on a 300-acre forested campus in Houston, Rice University is consistently ranked among the nation’s top
20 universities by U.S. News & World Report. Rice has highly respected schools of Architecture, Business,
Continuing Studies, Engineering, Humanities, Music, Natural Sciences and Social Sciences and is home to the Baker
Institute for Public Policy. With 3,910 undergraduates and 2,809 graduate students, Rice’s undergraduate student-
to-faculty ratio is 6-to-1. Its residential college system builds close-knit communities and lifelong friendships, just
one reason why Rice is ranked No. 1 for best quality of life and for lots of race/class interaction by the Princeton
Review. Rice is also rated as a best value among private universities by Kiplinger’s Personal Finance. To read “What
they’re saying about Rice,” go to http://tinyurl.com/AboutRiceUniversity.

TAGS: Natural Sciences

About Mike Williams

Mike Williams is a senior media relations specialist in Rice University's Office of Public Affairs.

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