Single Correct questions

Q-1

The major product is

A B

C D
Q-

The major product is

A B

C D
Q-2

(i) Zn
(ii) H2O/Δ

The major product is

A B

C D
Q-

(i) Zn
(ii) H2O/Δ

The major product is

A B

C D
Q- 3

(i) Zn
(ii) H3O+

The major product is

A B

C D
Q-

(i) Zn
(ii) H3O+

The major product is

A B

C D
 ⊕
Q- 4 N≡N
Cl⊝

CH = CH — CN
.
Cu2+

The major product is

A B

C D
 ⊕
Q- N≡N
Cl⊝

CH = CH — CN
Cu2+

The major product is

A B

C D
 ⊕
N≡N
Q- 5 Cl⊝

Cu2+

The major product is

A B

C D
 ⊕
N≡N
Q- Cl⊝

Cu2+

The major product is

A B

C D
Q-6

(i) NaH/Δ
(ii) H3O+/Δ

The major product would be

A B

C D
Q-

(i) NaH/Δ
(ii) H3O+/Δ

The major product would be

A B

C D
Q-7

A B

C D
Q-

A B

C D
Solution:
Q- 8: Aniline react with mixed acid (conc. HNO 3) and conc. H2SO4 at 288 K to
give P (51%), Q(47%) and R(2%). The major product(s) of the following
reaction sequence is (are)

A B

C D
Q- Aniline react with mixed acid (conc. HNO 3) and conc. H2SO4 at 288 K to
give P (51%), Q(47%) and R(2%). The major product(s) of the following
reaction sequence is (are)

A B

C D
Solution:
Q-9: C4H4O4 represent dicarboxylic acid with degree of unsaturation is 3. It
can show G.I. and its geometrical isomer are P & Q. P forms anhydride (R)
on heating.
Major product of following reaction is:

A Meso

B Pair of diastereomer

C Pair of enantiomers

D Pair of G.I.
Q- C4H4O4 represent dicarboxylic acid with degree of unsaturation is 3. It
can show G.I. and its geometrical isomer are P & Q. P forms anhydride (R)
on heating.
Major product of following reaction is:

A Meso

B Pair of diastereomer

C Pair of enantiomers

D Pair of G.I.
Solution:

pK1 of maleic acid is smaller than fumaric acid and reverse is true for pK 2 due to intermolecular hydrogen bonding in
conjugate base of maleic acid.
Multiple Correct questions
Q- 10 O
||
R — C — CH2
|
Br
The correct statement/s regarding the above reaction is

A Rate Limiting is the formation of enol

B Rate limiting is the attack on x 2 that is, the formation of -C-X bond.

C Rate α [ketone] [acid]

D The rates of bromination, iodination, deuterium exchange and

racemisation are identical
Q- O
||
R — C — CH2
|
Br
The correct statement/s regarding the above reaction is

A Rate Limiting is the formation of enol

B Rate limiting is the attack on x 2 that is, the formation of -C-X bond.

C Rate α [ketone] [acid]

D The rates of bromination, iodination, deuterium exchange and

racemisation are identical
Q-11: Which one of the following carboxylic acids does not undergo
decarboxylation easily?

A B

C D
Q- Which one of the following carboxylic acids does not undergo
decarboxylation easily?

A B

C D
Q- 12: Considering the reaction sequence given below, the correct
statement(s) is(are)

A P can be reduced to a primary alcohol using NaBH 4

B Treating P with conc. NH4OH solution followed by acidification gives Q.

C Treating Q with a solution of NaNO 2 in aq. HCl liberates N2

D P is more acidic than CH3CH2COOH

Q- Considering the reaction sequence given below, the correct
statement(s) is(are)

A P can be reduced to a primary alcohol using NaBH 4

B Treating P with conc. NH4OH solution followed by acidification gives Q.

C Treating Q with a solution of NaNO 2 in aq. HCl liberates N2

D P is more acidic than CH3CH2COOH

Solution:
Q- 13: Correct option(s) for the following sequence of reaction is(are)

A Q = KNO2, W = LiAlH4

B R = benzenamine, V = KCN

C Q = AgNO2, R = phenylmethanamine

D W = LiAlH4, V = AgCN
Q- Correct option(s) for the following sequence of reaction is(are)

A Q = KNO2, W = LiAlH4

B R = benzenamine, V = KCN

C Q = AgNO2, R = phenylmethanamine

D W = LiAlH4, V = AgCN
Solution:
Q- 14: Which of the following acid on heating gives geometrical isomers as a
product?

A B

C D None of these
Q- Which of the following acid on heating gives geometrical isomers as a
product?

A B

C D None of these
Solution:
Q-15: In which of the following reactions, correct major product is
mentioned?

D
Q- In which of the following reactions, correct major product is mentioned?

D
 Solution:

a and c are hydrolysis of ester reaction. In c stereochemistry of chiral carbon

is not affected.
b and d is esterification reaction where, nucleophile is phenolic OH while in d
isopropyl alcohol is a nucleophile
Q- 16: An ester A (C4H8O2) on treatment with excess CH3MgBr followed by
treatment with H+ gives an alcohol B as the only product. Which of the
following statements is/are true?

A A on basic hydrolysis gives formate ion as one of the products

B Alcohol B gives a positive iodoform test

C A on acidic hydrolysis gives acetic acid as one of the products

D Alcohol B gives precipitate with Lucas reagent immediately

Q- An ester A (C4H8O2) on treatment with excess CH3MgBr followed by
treatment with H+ gives an alcohol B as the only product. Which of the
following statements is/are true?

A A on basic hydrolysis gives formate ion as one of the products

B Alcohol B gives a positive iodoform test

C A on acidic hydrolysis gives acetic acid as one of the products

D Alcohol B gives precipitate with Lucas reagent immediately

Solution:

O OH
CH3 ⊝ O
(i) CH3MgBr OH/I2 ⊝
C H C CH3 CHI3 + CH3 C O
H O CH3 (excess)
(C4H8O2) (ii) H3O+
CH3
⊝ H+/H2O Lucas reagent
OH/H2O (B)

O H [5-10 min 2°-alcohol]

⊝ O
H C O + CH3 C OH
H C OH
CH3

+
(CH3)2- CHOH
Q-17: Identify the products X, Y and Z in the given reactions;

A B

C D Reaction involves 1,4-addition

Q- Identify the products X, Y and Z in the given reactions;

A B

C D Reaction involves 1,4-addition

Solution:
Integer Correct questions
Q-18: Consider the reaction sequence from P to Q shown below. The
overall yield of the major product Q from P is 75%. What is the amount in
grams of Q obtained from 9.3 mL of P? (Use density of P = 1.00 g mL -1; Molar
mass of C = 12.0, H = 1.0, O =16.0 and N = 14.0 g mol -1)
Solution:
Q- 19: Total number of enol possible for the compound formed during given
reaction will be (including stereoisomer)
Q- Total number of enol possible for the compound formed during given
reaction will be (including stereoisomer)

Ans : 3
Solution:
Q-20

(Y) is including stereoisomers. Value of (X + Y) will be

Q-

(Y) is including stereoisomers. Value of (X + Y) will be

Ans : 8
Solution:
Q-21: How many of the following reactions can produce ethane?
(i) CH2 — COOH
Δ
|
CH2 — COOH
NaOH & CaO
(ii) CH3— COONa Δ
Δ
(iii) (CH3COO)2Ca
NaOH & CaO
(iv) CH3CH2COONa Δ
COOH
Δ
(v) CH3CH
COOH
Q- How many of the following reactions can produce ethane?
(i) CH2 — COOH
| Δ
CH2 — COOH
NaOH & CaO
(ii) CH3— COONa Δ
Δ
(iii) (CH3COO)2Ca
NaOH & CaO
(iv) CH3CH2COONa Δ

COOH
Δ
(v) CH3CH
COOH

Ans : 1
Solution:
Q- 22: Malonic acid (X) when heated with P 4O10 undergoes dehydration to
produce compound (A) which is a bad smelling gas. (A) when heated at
200°C decomposes into gas (B) leaving behind a black residue (C).
Hydrolysis of compound (A) reproduces (X). The completely neutralized
salt of (X) with NaOH when subjected to dry distillation with soda lime
produce a gas (Y). What is the sum of total number of atoms in each of
one molecules of gas (B) & (Y)?
Q- Malonic acid (X) when heated with P 4O10 undergoes dehydration to
produce compound (A) which is a bad smelling gas. (A) when heated at
200°C decomposes into gas (B) leaving behind a black residue (C).
Hydrolysis of compound (A) reproduces (X). The completely neutralized
salt of (X) with NaOH when subjected to dry distillation with soda lime
produce a gas (Y). What is the sum of total number of atoms in each of
one molecules of gas (B) & (Y)?

Ans: 8.00
Solution:

200 °C
Δ

Δ
CaO
You can contact me

Beastchemist

Beastchemist

@BEASTCHEMIST
Mohit Ryan Sir
Join Vedantu JEE
Telegram
channel NOW!
Assignments
Notes
Daily Update

https://vdnt.in/JEEVedantu