Mock Test-1

The correct statement about B2H6 is:

A All B–H–B angles are of 120°.

B Its fragment, BH3, behaves as a Lewis base.

C Terminal B–H bonds have less p-character when compared to

bridging bonds.

D The two B–H–B bonds are not of same length.

Consider the above reaction, the product ‘X’ and ‘Y’ respectively
are :

A B

C D
Match List-I with List-II :
List-I List-II
(Process) (Catalyst)
(a) Deacon’s process (i) ZSM-5
(b) Contact process (ii) CuCl2
(c) Cracking of hydrocarbons (iii) Particles ’Ni’
(d) Hydrogenation of vegetables oils (iv) V2O5
Choose the most appropriate answer from the option given below:

A (a)-(i), (b)-(iii), (c)-(ii), (d)-(iv)

B (a)-(iv), (b)-(ii), (c)-(i), (d)-(iii)

C (a)-(ii), (b)-(iv), (c)-(i), (d)-(iii)

D (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)

The correct order of conductivity of ions in water is:

A Cs+>Rb+> K+> Na+

B K+> Na+> Cs+>Rb+

C Rb+> Na+> K+>Li+

D Na+> K+>Rb+> Cs+

The addition of silica during the extraction of copper from its
sulphide ore :-

A converts copper sulphide into copper silicate

B converts iron oxide into iron silicate

C reduces copper sulphide into metallic copper

D reduces the melting point of the reaction mixture

Which among the following is the strongest acid ?

A CH3CH2CH2CH3 B

C D
The secondary valency and the number of hydrogen bonded
water molecule(s) in CuSO4.5H2O, respectively, are :

A 6 and 4

B 4 and 1

C 5 and 1

D 6 and 5
Which statement is correct?

A Buna-S is a synthetic and linear thermosetting polymer

B Neoprene is addition copolymer used in plastic bucket

manufacturing

C Synthesis of Buna-S needs nascent oxygen

D Buna-N is a natural polymer

The plots of radial distribution functions for various orbitals of
hydrogen atom against 'r' are given below:
The correct plot for 3s orbital is:

D
Which of the glycosidic linkage galactose and glucose is present in
lactose?

A C-1 of glucose and C-6 of galactose

B C-1 of galactose and C-4 of glucose

C C-1 of glucose and C-4 of galactose

D C-1 of galactose and C-6 of glucose

The hybridization and magnetic nature of [Mn(CN)6]4– and
[Fe(CN)6]3–, respectively are:

A d2sp3 and paramagnetic

B sp3d2 and paramagnetic

C d2sp3 and diamagnetic

D sp3d2 and diamagnetic

Given below are two statements: One is labelled as Assertion A and the other is
labeled as Reason R:
Assertion A:During the boiling of water having temporary hardness,
Mg(HCO3)2 is converted to MgCO3.
Reason R: The solubility product of Mg(OH)2 is greater than that of MgCO3.
In the light of the above statements, choose the most appropriate answer
from the options given below.

A A is false but R is true

B Both A and R are true and R is the correct explanation of A.

C Both A and R are true but R is NOT the correct explanation of A

D A is true but R is false.

The parameters of the unit cell of a substance are
a = 2.5, b = 3.0, c = 4.0, 𝞪 = 90°, 𝜷 = 120° 𝜸 = 90°.
The crystal system of the substance is :

A Hexagonal

B Orthorhombic

C Monoclinic

D Triclinic
 Considering the above chemical
reaction, identity the product “X” :

A B

C D
Consider the above chemical reaction and identity product “A”
:

A B

C D
Compound(s) which will liberate carbon dioxide with sodium
bicarbonate solution is/are:

A B and C only

B B only

C A and B only

D C only
Main Products formed during a reaction of 1-methoxy
naphthalene with hydroiodic acid are :

A B

C D
The solubility of AgCN in a buffer solution of pH = 3 is x. The value of
x is:
[Assume: No cyano complex is formed; Ksp(AgCN) = 2.2 × 10–16 and Ka
(HCN) = 6.2 × 10–10]

A 0.625 × 10–6

B 1.6 × 10–6

C 2.2 × 10–16

D 1.9 × 10–5
The correct order of stability of given carbocation is :

A A>C>B>D B D >B > C > A

C D>B>A>C D C>A>D>B
Given below are two statements : One is labelled as Assertion A and the
other labelled as Reason R.
Assertion A : Lithium halides are some what covalent in nature.
Reason R : Lithium possess high polarisation capability.
In the light of the above statements, choose the most appropriate answer
from the options given below:

A A is true but R is false

B A is false but R is true

C Both A and R are true but R is NOT the correct explanation of A

D Both A and R are true and R is the correct explanation of A

The density of NaOH solution is 1.2 g cm–3. The molality of this
solution is ________ m.
(Round off to the Nearest Integer)
[Use : Atomic masses : Na : 23.0 u O : 16.0 u H : 1.0 u Density
of H2O : 1.0 g cm–3]
CO2 gas adsorbs on charcoal following Freundlich adsorption
isotherm. For a given amount of charcoal, the mass of CO22
adsorbed becomes 64 times when the pressure of CO2 is
doubled.
The value of n in the Freundlich isotherm equation is _____
× 10–2. (Round off to the Nearest Integer)
The conductivity of a weak acid HA of concentration 0.001 mol
L–2 is 2.0 × 10-5 S cm-1. If Amo(HA) 190 S cm2 mol-1, the
ionization constant (Ka) of HA is equal to _____ × 10-6.
(Round off to the Nearest integer)
An organic compound is subjected to chlorination to get
compound A using 5.0 g of chlorine. When 0.5 g of compound
A is reacted with AgNO3 [Carius Method], the percentage of
chlorine in compound A is _______ when it forms 0.3849 g
of AgCl. (Round off to the Nearest Integer)
(Atomic masses of Ag and Cl are 107.87 and 35.5
respectively)
The number of geometrical isomers possible in
triamminetrinitrocobalt (III) is X and in trioxalatochromate
(III) is Y. Then the value of X + Y is _______.
Solutions
The correct statement about B2H6 is:

A All B–H–B angles are of 120°.

B Its fragment, BH3, behaves as a Lewis base.

C Terminal B–H bonds have less p-character when compared to

bridging bonds.

D The two B–H–B bonds are not of same length.

Solution: Terminal bond angle is greater than that of bridge bond angle
Consider the above reaction, the product ‘X’ and ‘Y’ respectively
are :

A B

C D
Solution :
Match List-I with List-II :
List-I List-II
(Process) (Catalyst)
(a) Deacon’s process (i) ZSM-5
(b) Contact process (ii) CuCl2
(c) Cracking of hydrocarbons (iii) Particles ’Ni’
(d) Hydrogenation of vegetables oils (iv) V2O5
Choose the most appropriate answer from the option given below:

A (a)-(i), (b)-(iii), (c)-(ii), (d)-(iv)

B (a)-(iv), (b)-(ii), (c)-(i), (d)-(iii)

C (a)-(ii), (b)-(iv), (c)-(i), (d)-(iii)

D (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)

The correct order of conductivity of ions in water is:

A Cs+>Rb+> K+> Na+

B K+> Na+> Cs+>Rb+

C Rb+> Na+> K+>Li+

D Na+> K+>Rb+> Cs+

Sol.
Csaq+ has lower hydrated radius so its electrical

conductivity is higher.
The addition of silica during the extraction of copper from its
sulphide ore :-

A converts copper sulphide into copper silicate

B converts iron oxide into iron silicate

C reduces copper sulphide into metallic copper

D reduces the melting point of the reaction mixture

Solution:

Silica is used to remove FeO impurity from the ore

of copper
FeO + SiO2 → FeSiO3
iron silicate
(Slag)
Which among the following is the strongest acid ?

A CH3CH2CH2CH3 B

C D
The secondary valency and the number of hydrogen bounded
water molecule(s) in CuSO4.5H2O, respectively, are :

A 6 and 4

B 4 and 1

C 5 and 1

D 6 and 5
Solution :
Which statement is correct?

A Buna-S is a synthetic and linear thermosetting polymer

B Neoprene is addition copolymer used in plastic bucket

manufacturing

C Synthesis of Buna-S needs nascent oxygen

D Buna-N is a natural polymer

Solution: Synthesis of Buna-S needs nascent oxygen.
The plots of radial distribution functions for various orbitals of
hydrogen atom against 'r' are given below:
The correct plot for 3s orbital is:

D
Solution: 3s orbital
Number of radial nodes = n – l – 1
For 3s orbital n = 3 , l = 0
Number of radial nodes = 3 – 0 – 1 = 2
It is correctly represented in graph of option D
Which of the glycosidic linkage galactose and glucose is present in
lactose?

A C-1 of glucose and C-6 of galactose

B C-1 of galactose and C-4 of glucose

C C-1 of glucose and C-4 of galactose

D C-1 of galactose and C-6 of glucose

Solution:
The hybridization and magnetic nature of [Mn(CN)6]4– and
[Fe(CN)6]3–, respectively are:

A d2sp3 and paramagnetic

B sp3d2 and paramagnetic

C d2sp3 and diamagnetic

D sp3d2 and diamagnetic

Solution:
Given below are two statements: One is labelled as Assertion A and
the other is labeled as Reason R:
Assertion A:During the boiling of water having temporary hardness,
Mg(HCO3)2 is converted to MgCO3.
Reason R: The solubility product of Mg(OH)2 is greater than that of
MgCO3.
In the light of the above statements, choose the most appropriate
answer from the options given below.

A A is false but R is true

B Both A and R are true and R is the correct explanation of A.

C Both A and R are true but R is NOT the correct explanation of A

D A is true but R is false.

Solution :
The parameters of the unit cell of a substance are
a = 2.5, b = 3.0, c = 4.0, 𝞪 = 90°, 𝜷 = 120° 𝜸 = 90°.
The crystal system of the substance is :

A Hexagonal

B Orthorhombic

C Monoclinic

D Triclinic
Solution:

a ≠ b ≠ c and 𝞪 = 𝜸 = 90º ≠ 𝜷
are parameters of monoclinic unit cell.
 Considering the above chemical
reaction, identity the product “X” :

A B

C D
Solution :
Consider the above chemical reaction and identity product “A”
:

A B

C D
Solution :
Compound(s) which will liberate carbon dioxide with sodium
bicarbonate solution is/are:

A B and C only

B B only

C A and B only

D C only
Solution: Compounds which are more acidic then H2CO3, gives CO2
gas on reaction with NaHCO3.
Compound B i.e. Benzoic acid and compound C i.e. picric
acid both are more acidic than H2CO3.
Main Products formed during a reaction of 1-methoxy
naphthalene with hydroiodic acid are :

A B

C D
Solution :
The solubility of AgCN in a buffer solution of pH = 3 is x. The value of
x is:
[Assume: No cyano complex is formed; Ksp(AgCN) = 2.2 × 10–16 and Ka
(HCN) = 6.2 × 10–10]

A 0.625 × 10–6

B 1.6 × 10–6

C 2.2 × 10–16

D 1.9 × 10–5
Solution:
The correct order of stability of given carbocation is :

A A>C>B>D B D >B > C > A

C D>B>A>C D C>A>D>B
Solution:
Given below are two statements : One is labelled as Assertion A and the
other labelled as Reason R.
Assertion A : Lithium halides are some what covalent in nature.
Reason R : Lithium possess high polarisation capability.
In the light of the above statements, choose the most appropriate answer
from the options given below:

A A is true but R is false

B A is false but R is true

C Both A and R are true but R is NOT the correct explanation of A

D Both A and R are true and R is the correct explanation of A

Solution:

Lithium due to small size has very high polarization capability

and thus increases covalent nature in Halides.
The density of NaOH solution is 1.2 g cm–3. The molality of this
solution is ________ m.
(Round off to the Nearest Integer)
[Use : Atomic masses : Na : 23.0 u O : 16.0 u H : 1.0 u Density
of H2O : 1.0 g cm–3]

5
Solution:
CO2 gas adsorbs on charcoal following Freundlich adsorption
isotherm. For a given amount of charcoal, the mass of CO22
adsorbed becomes 64 times when the pressure of CO2 is
doubled.
The value of n in the Freundlich isotherm equation is _____
× 10–2. (Round off to the Nearest Integer)

17
Solution:
The conductivity of a weak acid HA of concentration 0.001 mol
L–2 is 2.0 × 10-5 S cm-1. If Amo(HA) 190 S cm2 mol-1, the
ionization constant (Ka) of HA is equal to _____ × 10-6.
(Round off to the Nearest integer)

12
Solution:
An organic compound is subjected to chlorination to get
compound A using 5.0 g of chlorine. When 0.5 g of compound
A is reacted with AgNO3 [Carius Method], the percentage of
chlorine in compound A is _______ when it forms 0.3849 g
of AgCl. (Round off to the Nearest Integer)
(Atomic masses of Ag and Cl are 107.87 and 35.5
respectively)

19
Solution:
The number of geometrical isomers possible in
triamminetrinitrocobalt (III) is X and in trioxalatochromate
(III) is Y. Then the value of X + Y is _______.

2
Solution:
Solution:
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