Signature of invigilator

PART TEST-3
Class : XII (All)
Time : 1 Hr. Max. Marks : 90

CHEMISTRY
INSTRUCTIONS
1. The question paper contains 30 questions. All Questions carry 3 marks each. All of them are
compulsory.
2. Each question contains four alternatives out of which only ONE is correct.
3. There is NEGATIVE marking. For each wrong answer 1 mark will be deducted.
4. For Assertion–Reason type questions
Mark A: If Assertion is True and Reason is False.
Mark B: If Assertion is False but Reason is True.
Mark C: If both Assertion and Reason are True and the Reason correctly explains the Assertion.
Mark D: If both Assertion and Reason are True but Reason is not the correct explaination of
Assertion.
5. Indicate the correct answer for each question by filling appropriate bubble in your answer sheet.
6. Use only HB pencil for darkening the bubble.
7. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.
8. The answer(s) of the questions must be marked by shading the circles against the question by
dark
HB pencil only. For example if only 'B' choice is correct
then, the correct method for filling the bubble is
A B C D

the wrong method for filling the bubble are

(i) A B C D

(ii) A B C D

(iii) A B C D

(iv) A B C D
The answer of the questions in wrong or any other manner will be treated as wrong.
Q1. Which of the following statements is incorrect?
(A) cis–2–butene on bromination gives meso–2, 3–dibromobutane.
(B) cis–2–butene with cold alkaline aqueous KMnO4 gives meso-glycol.
(C) cis–2–butene with peroxyformic acid gives racemic glycol.
(D) cis–2–butene on reaction with Br2 in presence of a chloride (salt) yields vic–bromochloro–
alkane.
For problem Q2. to Q3.
Two elements Aand B form compounds having formulaAB2 and AB4. When dissolved in 20g of
benzene,
1.0g of AB2 lowers the freezing point by 2.3 0 C, whereas 1.0g of AB lowers the freezing point by
4
1.30C. The molal freezing point depression constant of benzene is 5.10C (Assume no dissociation
of
AB2 and AB4).
Q2. Atomic weight of Ais
(A) 42.64 (B) 21.32 (C) 25.59 (D) 12.80
Q3. Atomic weight of B is
(A) 21.32 (B) 42.64 (C) 12.80 (D) 25.59
Q4. A: As EN difference increases Polar covalent nature increases and thus ionic nature increases.
R: As EN difference increases polarity of partial charges increases.
Q5. Identify the compound (Z), of molecular formula C12H18 which gives only two products of molecular
formula C4H6O and C4H6O2 on ozonolysis and both the products are oxidised to C 4H6O2 and
C4H6O4 with H2O2. The product C4H6O4 on heating gives anhydride.

(A) (B)

(C) (D)

Q6. Li forms a BCC unit cell. If the edge length of the lattice is 3.5 × 1010m and the observed density is
5.3 × 102 kg m3, the % occupancy of lattice point by Li  atom is 
(A) 98% (B) 52% (C) 68% (D) 74%

ROUGHWORK
Q7. A: As per Hanny Smyth Equation NaCl is more ionic lesser covalent.
R: A compound is said to be more ionic lesser covalent when EN difference is above 1.7/2.1.
Q8. For a binary volatile liquid mixture p 0 > p 0 . x and x
A B A
represents the molefraction of Aand B in the
B
liquid phase whereas and represents mole  fraction of A and B in the vapour phase. Hence
yA yB
YA XB YA YB YA YB YA YB
(A) = (B) = (C) < (D) >
YB XA XA XB XA XB XA XB

Q9. A: M-O-H will show acidic charc. in water as EN>1.4 for M-O bond.
R: As polar covalent nature increases B.str. also increases.

Q10. CCl3–COOH
NaOH    B “ C ” is
A

O O
|| ||
(A) CCl3–CH2–CH3 CH
(B) 3  CH2  C  C  OH

(C) (D) none of the above

Q11. A: With the increasing +ve oxidation state of central atom M, B.str. of M-O bond increases
whereas thermal stability of its crystal increases.
R: With the increasing ionic nature crystal becomes more stronger.
Q12. In a cubic, cations (A) are present at the corners and anions (B) are present at the face centred
positions.
The formula of the compound is -
(A) AB (B) A4B3 (C) AB3 (D) AB4
Q13. The vapour pressure of a solution of a non volatile solute (B) in a solvent (A) is 95% of the vapour
pressure of the solvent at the same temperature. If the molecular weight of the solvent is 0.3
times the molecular weight of the solute, what is the ratio of weight of solvent to solute?
(A) 0.15 (B) 5.70 (C) 0.23 (D) none of these
ROUGHWORK
Q14. A certain liquid hydrocarbon, ‘A’ of vapour density = 46, fails to react with Br2 in the dark
unless powdered iron is added. ‘A’ reacts with Etard’s reagent to yield an aldehyde. What
product would be obtained when ‘A’ reacts with excess of chlorine in presence of light?

(A) (B) (C) (D)

Q15. A: M2+OH will preferably produce MO and H+ whereas M4+OH will more prone to produce
M4+ and OH ions in polar solvent if both produce solvated ions.
R: B.str. of M2+ --O is greater than that of M4+ --O.

Q16. An alkyne, A, on treatment with hydrogen in presence of catalyst followed by ozonolysis gives
only one product, B.A, on treatment with sodium in liquid ammonia forms C, which with a
peracid gives
D. With Baeyer’s reagent, C gives E. Indicate the correct statement.
(A) D is a mesodiol (B) both D & E are racemix mixtures
(C) E is a mesodiol (D) Reaction of D or E with HIO4 give different products
Q17. A: AlCl3 is more hydrolysed than PCl5 in aqueous solution.
R: Al in AlCl3 has more positive charge polarity than P in PCl5 in all phases.
Q18. Indicate among the following the reaction not correctly formulated
+SO 2C l2
(A) CH = CH–CH     CH Cl–CHCl–CH
2 3 UV or peroxide 2 3

(B) HC  CH + CH 2N 2

(C) (CH3)3CH + Cl

p ho to
  (CH3)3C–Cl

2 ha log
ROUGHWORK
enation
 (D) CH –C  C–CH –CH –CH Na 
3 2 2 3 in NH3 (liq)

Q19. A: If both M2+OH and M4+OH behave as covalent molecules even in polar solvents then on
heating up the solution finally the most probable species obtained are M2+ , OH , M4+O and H +
.
R: B.str. of M2+ --O is greater than that of M4+ --O.
Q20. Point out the wrong statement
 
(A) Wittig’s reaction involves a phosphorous ylide : 3 P C H2

(B) forms a salt with HClO4

(C) C6H5–CO–(CH2)3–Cl K OH , C H 3 O H
      

(D) b a se
 

Q21. A: In aqueous solutions SiCl4 is less hydrolysed than PCl5 .

R: Partial positive charge polarity is more on P in PCl5 than on Si in SiCl4.

ROUGHWORK
 CH3 CNH2
||
Q22. M g / dry eth er O .
     

The structures of and respectively are

(A) X = ;Y=

(B) X = ;Y=

(C) X = ;Y=

(D) X = ;Y=

For problem Q23. to Q26.

The molar volume of liquid (A) (M.wt. = 80 g mol–1, density = 0.9 g ml–1) increases by a factor
of 2800 as it vaporises at 270C and that of liquid (B) (M.wt. = 100 g mol–1, density = 0.8 g ml–1)
increases by a factor of 7000 at 270C. A solution of (A) and (B) at 200C has a vapour pressure
of 50 mm Hg.
Q23. The vapour pressure of pure (A) i.e. pA 0 is
(A) 7.52 mm Hg (B) 75.21 mm Hg (C) 752.1 mm Hg (D) 760 mm Hg
Q24. The vapour pressure of pure (B) i.e. pB 0 is
(A) 75.21 mm Hg (B) 7.52 mm Hg (C) 21.40 mm Hg (D) 760 mm Hg
Q25. The mole fraction of (A) in the vapour phase above the
solution is (A) 0.78 (B) 0.22 (C) 0.53 (D) 0.47
Q26. The mole fraction of (B) in the vapour phase above the
solution is (A) 0.53 (B) 0.22 (C) 0.78 (D) 0.47

ROUGHWORK
Q27. (styrene) on hydroboration – oxidation gives

(A) (B)

(C) (D)

Q28. A: SiO2 is a weakly acidic oxide.

R: SiO2 Cannot react with any of the acids.

Q29. For MeCH=CH2 NBS

       (C)
B r / CC l 4 N a / eth er
  2
(C) may be: (A)
(B)

(A) (B) CH2=CH–CH=CHCH = CH2

(C) (D) all are correct

Q30. A: A neutral oxide cannot react with an acid or base.

R: Aneutral oxide when dissolved in water produces a solution with pH=7 at room temp.

ROUGHWORK