Answer Key & Solution Explanation, JEE Advanced Paper - 1 Star Batch

JEE ADVANCED PAPER – 1
APNI KAKSHA STAR BATCH
Time : 3 Hours Maximum Marks : 180

ANSWER KEY
&
SOLUTION WITH EXPLANATION
Solution Sheet Available Only for 24 Hours

PART – 1 : MATHEMATICS
Section-I (Maximum Marks : 24)

• This section contains SIX (06) questions having four options each.
• ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
Full Marks : +4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are
chosen, both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen
and it is a correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : -𝟐 In all other cases.
1 1 1 1 1 1
1. If A = 1 cot −1 (1) + 2 cot −1 (2) + 3 cot −1 (3) and B = 1cot −1 1 + 2cot −1 2 + 3cot −1 3 then
aπ c
|B − A| = + d cot −1 (3) where a, b, c, d ∈ N and are in their lowest form. Then which of the
b
following statement(s) is/are correct

(A) a = c (B) b = 4d (C) a + b + c + d = 42 (D) ac − b = 1
Ans. (ABD)
2. Which of the following are correct:

−sin−1 x; x ∈ [−1,0)
(A)cos−1 √1 − x 2 = [
sin−1 x; x ∈ [0,1]
1+x
(B) tan−1 x + tan−1 1 = π + tan−1 (1−x) ⇒ x ∈ (−∞, −1)
1
(C) cos−1 (4x 3 − 3x) = 3cos −1 x If x ∈ [0, 2]
3x−x3 −1 1
(D)tan−1 ( ) = 3tan−1 x If x ∈ ( , )
1−3x2 √3 √3
Ans. (AD)
APNI KAKSHA 1
π
3. If the equation sin−1 (x 2 + x + 1) + cos −1 (ax + 1) = has exactly two distinct solutions then a
2
cannot have the integral value

(A) −1 (B) 0 (C) 1 (D) 2
Ans. (ACD)
2 π
4. If tan−1 (sin2 θ + 2sin θ + 2) + cot −1 (4sec ϕ
+ 1) = has solution for some θ and ϕ then
2
(A) sin θ = −1 (B) sin θ = 1 (C) cos ϕ = 1 (D) cos ϕ = −1

Ans. (BC)
5. Which of the following is a rational number

1 π 3
(A) sin (tan−1 3 + tan−1 3) (B) cos ( 2 − sin−1 4)
1 √63 1 √5
(C) log 2 (sin (4 sin−1 )) (D) tan (2 cos−1 )
8 3
Ans. (ABC)
1 n
6. Consider the binomial expansion of (√x + 4 ) ; n ∈ N where the terms of the expansion are
2 √x
written in decreasing power of x. If the co-efficients of the first three terms form an arithmetic
progression then the statement(s) which hold good is/are
(A) Total number of terms in the binomial expansion is 8 .
(B) Number of terms in the expansion with integral power of x is 3 .
(C) There is no term in the expansion which is independent of x.
(D) Fourth and fifth are the middle terms of the expansion.
Ans. (BC)
Section-II (Maximum Marks : 18)

• This section contains TWO (02) paragraphs. Based on each paragraph, there are THREE (03)
questions having four options each.
• ONLY ONE of these four options is the correct answer.
• For each question, choose the option corresponding to the correct answer.
Full Marks : +𝟑 If ONLY the correct option is chosen;
Negative Marks : −𝟏 In all other cases.
APNI KAKSHA 2
Paragraph 1 (Q.7 to Q.9)
n 1
x
Let f(x) = limn→∞ (cos √n) , g(x) = limn→∞ (1 − x + x en )n. Now, consider the function y =
h(x), where h(x) = tan−1 (g −1 f −1 (x))

ℓn(f(x))
7. limx→0 ℓn(g(x)) is equal to
1 1
(A) − 2 (B) 0 (C) 2 (D) 1
Ans. (A)
8. Domain of the function y = h(x) is

(A) (0, ∞) (B) R (C) (0,1) (D) [0,1]
Ans. (C)
9. Range of the function y = h(x) is

π π π π
(A) (0, 2 ) (B) (− 2 , 0) (C) R (D) (− 2 , 2 )
Ans. (D)
Paragraph 1 (Q.10 to Q.12)
[x] ; −2 ≤ x ≤ −1 [x] ; −π ≤ x < 0

Consider two function f(x) = { and g(x) = {
|x| + 1; −1 < x ≤ 2 sin x ;0 ≤ x ≤ π
where [.] denotes greatest integer function.
10. Number of integers in the Domain of g(f(x)) is

(A) 3 (B) 4 (C) 5 (D) 6
Ans. (C)
11. Number of integers in the range of g(f(x)) is

(A) 3 (B) 4 (C) 5 (D) 6
Ans. (A)
12. Number of integers in the range of f(g(x)) is

(A) 3 (B) 4 (C) 5 (D) 6
Ans. (B)
APNI KAKSHA 3
Section-III (Maximum Marks : 18)

• This section contains SIX (06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER.
• For each question, enter the correct integer corresponding to the answer in the place
designated to enter the answer.
Full Marks : +3 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
13. The centre of a circle lies on the line 2x − 2y + 9 = 0. The circle cuts x 2 + y 2 = 4 orthogonally.
This circle passes through two fixed points (a, b) and (c, d) then find the value of
(a + b + c + d)
Ans. (0)
14. In how many ways 27 identical oranges can be distributed among 3 persons so that the sum of
number of oranges received by any two persons should exceed the number of oranges received
by third person.
Ans. (91)
cos(x+4θ)−4 cos(x+3θ)+6 cos(x+2θ)−4 cos(x+θ)+cosx

15. Let f(x) = Limθ→0 then find the absolute value of
θ4
difference between maximum and minimum value of f(x).

Ans. (2)
x−1−√x2 −5
√2x+3−x x2−5x+6 a√b
16. If Limx→3 ( ) can be expressed in the form where a, b, c ∈ N, then find the
√x+1−x+1 c
least value of (a2 + b2 + c 2 ).

Ans. (29)
17. Find the sum of an infinite geometric series whose first term is the limit of the function
9 7 tan x−sin x
f(x) = (1−x9 − 1−x7) as x → 1 and the common ratio is the limit of function g(x) = as
ℓn3 (1+x)
x → 0.
Ans. (2)
18. Number of real values of x, satisfying the equation [x]2 − 5[x] + 6 − sin x = 0, [⋅] denoting the
greatest integer function is.
Ans. (1)
APNI KAKSHA 4
PART – 2 : PHYSICS

19. The following figure shows a block of mass m suspended from a fixed point by means of a
vertical spring. The block is oscillating simple harmonically and carries a charge q. There also
exists a uniform electric field in the region. Consider four different cases. The electric field is
mg mg 2mg
zero, in case – 1, downward in case – 2, upward and in case – 3, downward in
q q q
case – 4. The speed at mean position is same in all cases.
Select the correct alternatives(s).

(A) Time periods of oscillation are equal in case – 1 and case - 3
(B) Amplitudes of displacement are same in case – 2 and case – 3
(C) The maximum elongation (increment in length from natural length) is maximum in case – 4
(D) Time periods of oscillation are equal in case – 2 and case – 4
Ans. (ABCD)
APNI KAKSHA 5
Sol. (A) For spring block system only equilibrium position changes.
m
Time period remains same T = 2
k
1 2 1 2
(B) kx = m
2 2
  at mean position is same amplitude will be same
3mg
(C) In case – 4, equilibrium position x 0 =
k
20. An ideal dipole of dipole moment P is placed in front of an uncharged conducting sphere of
radius R as shown.
KP
(A) the potential at point A is
(r − R )
2
KP
(B) The potential at point A is
r2
KP
(C) the potential due to dipole at point B is
(r + R )
2
KP
(D) The potential due to dipole at point B is
r2
Ans. (BC)
Sol. Potential at centre due to induced charges on the conductor is zero (by symmetry), and net
 KP 
potential at each point of conductor is same as that at centre, i.e.,  2 
 r 
KP KP
Potential due to dipole at A is and at B is
(r − R ) (r + R )
2 2
APNI KAKSHA 6
21. Three equal point changes (Q) are kept at the three corners of an equilateral triangle ABC of side
a. P is a point having equal distance a from A, B and C. If E is the magnitude of electric field and V
is the potential at point P, then
3Q 6Q 3Q 3 6Q
(A) E= (B) E = (C) V = (D) V =
40a 2 4 0a 2 40a 4 0a
Ans. (BC)
Sol. Let the point charges have the coordinate
 a   a 
P   + ,0,0  , Q   − ,0,0 
 2   2 
 3 
and R   0, a,0 
 2 
 a 2 
 Coordinate of point O at which E has to be calculated   0, , a
 2 3 3 
Also we know
1 Q
E= r
40 r 3
 E net = E1 + E 2 + E 3
 E net =
1 Q
40 a 3
(
PO + QO + RO )
Q  2 ˆ 6Q ˆ
 E net = . 3 a k =
3 
k
40a  3  40a 2
3Q
And the potential is V =
40a
APNI KAKSHA 7
22. In front of an earthed conductor a point charge +q is placed as shown in figure
(A) On the surface of conductor the net charge is always negative

(B) On the surface of conductor at some points charges are negative and at some points charges
may be positive distributed non uniformly
(C) Inside the conductor electric field due to point charge is non zero
(D) None of the above
Ans. (ABC)
Sol. Charge is distributed over the surface of conductor in such a way that net field due to this charge
and outside charge q is zero inside. Field due to only q is non – zero.
23. Two infinite, parallel, non – conducting sheets carry equal positive charge denstiy  . One is
placed in the yz plane and the other at distance x = a. take potential V = 0 at x = 0
(A) For 0  x  a , potential Vx = 0


(B) For x  a , potential Vx = − (x − a)
0

(C) For x  a , potential Vx = (x − a)
0

(D) For x  0 , potential Vx = x
0
Ans. (ABD)
 x 
Sol. 0  x  a : Vx =  −  E x dx  + V( 0 ) = 0 (as Ex = 0 )
 a 
x
 x   
x  a : Vx = −  E x dx + V( a ) =  −  dx  + V( a ) = − ( x − a )
a  a 0  0
x
   
x  0 : Vx = −  E x dx + V( 0 ) = −  − .x  + V( 0 ) = .x
0  0  0
APNI KAKSHA 8
24. The electric field produced by a positively charged particle, placed in an xy – plane is
7.2 ( 4i + 3j) N / C at the point ( 3cm,3cm ) and 100iˆ N / C at the point ( 2cm,0 )
(A) The x – coordinate of the charged particle is -2cm
(B) The charged particle is placed on the x – axis
−12
(C) The charge of the particle is 10  10 C
(D) The electric potential at the origin due to the charge is 3V
Ans. (BC)
Sol. At point (2cm, 0), field is along x – axis. It is possible only when the particle is situated on x –
axis. Its position is located by extending electric field direction from point (3cm, 3cm). the point
at which this extension intersects x – axis, is the location of the charge. That is (-1cm, 0)
For point (2cm, 0). r = 3cm, E = 100

kQ
Using, E =
r2
 Q = 10  10 −12 C
kQ
Potential at origin =
r
r = 1cm , Q = 10  10 −12 C = V = 9V

APNI KAKSHA 9
Comprehension (1)
A region in space contains a total positive charge Q that is distributed spherically such that the
volume charge density  ( r ) is given by :
R
 ( r ) =  for r 
2
 r R
 ( r ) = 2 1 −  for  r  R
 R 2
 ( r ) = 0 for r  R
Here  is a positive constant having units of c / m .

3
25. Mark the correct option(s).

8Q
(A) Value of  is
5R 3
4Q
(B) Value of  is
5R 3
R  R3
(C) Charge enclosed in region r  is
2 6
R 11  R 3
(D) Charge enclosed in region  r  R is
2 24
Ans. (ACD)

R 8Qr
(A) Electric field in the region r  is
2 150 R 3
(B) Electric field inside the entire spherical volume is linearly dependent on r
Q
(C) Electric field in the region r  R is
40 r 2
Q
(D) Electric field in the region r  R is
40 R 2
Ans. (AC)
APNI KAKSHA 10
R
(A) If an electron is released in the region r  it will execute periodic and oscillatory motion
2
R
(B) If an electron is released in region r  it will execute simple harmonic motion
2
(C) For points at r  R the electric field of given charge distribution is identical to a point
charge
(D) Electric field at the centre of given spherical charge distribution is zero
Ans. (ABCD)
Sol. The charge in a spherical shell of radius r and thickness dr is dQ =  ( r ) 4 r 2 dr . Let Q i the
R R
charge in the region r  and let Q 0 be the charge in the region where  r  R.
2 2
3
R
4  
 2   R3
The total charge is Q = Qi + Q0 , where Qi =  = and
3 6
  3 R3   4 R4  
 R −   R − 16  
R
 2 r3    8     11  R 3
Q 0 = 4 ( 2 ) =   r −  dr = 8   − =
R /2 
R  3 4R  24
 
 
15   R 3 8Q
Therefore, Q = and  =
24 5 R3
R  4 r 3 r 8Qr
For r  , Gauss’s law gives E4 r = and E = =
2
.
2 3 0 30 150 R 3
R
For  r  R.
2
  3 R3    
R4
  r −  4
−   
 8   r
E4 r 2 = i + 8    
Q 1 16
−
0 0   3  4R   
  
    
  R3   r 
2
r
4
 kQ   r 3  r 
4

and E =   
64 − 48   − 1 = 2 
64   − 48   − 1
240 ( 4 r 2 )   R  R  15r   R  R 
APNI KAKSHA 11
(
For r  R, E 4 r 2 =) Q
0
and E =
Q
40 r 3
R 8eQ
For r  , Fr = − eE = − r , so the restoring force depends upon displacement to the
r 15R 3
first power, and we have simple harmonic motion.
8eQ
Comparing to F = − kr, k = .
15 R 3
k 8eQ 2 150 R 3m e
Then  = = and T = = 2
me 15 0 R 3m e  8eQ
R
If the amplitude of oscillation is greater than , the force is no longer linear in r, and is thus no
2
longer simple harmonic.
Comprehension (2)
A charged particle is suspended at the centre of two thin concentric spherical charged shells,
made of non conducting material. Figure A shows cross-section of the arrangement. Figure B
gives the net flux  through a Gaussian sphere centered on the particle, as a function of the
radius r of the sphere.
28. What is the charge on the central particle?

(A) 0.2 C (B) 2 C (C) 1.77 C (D) 3.4 C
Ans. (C)
q 40
Sol. = 2  105  q = 20  105 = 2   105
0 4
2  105 2  10−4 2  10 −4
= = = C
36  109 36  36 
= 2  0.884 C = 1.77 C
APNI KAKSHA 12
29. What is the charge on shell A?
−6 −6 −6 −6
(A) 5.31 10 C (B) −5.31 10 C (C) −3.54  10 C (D) −1.77 10 C
Ans. (B)
q + qA
Sol. = − 4  105
0
q qA
+ = − 4  105
0 0
qA
 2  105 + = − 4  105
0
qA
 = − 6  105
0
 q A = −5.31 C
30. In which range of the values of r is the electric field zero?

(A) 0 to rA
(B) rA to rB
(C) For r  rB
(D) For no range of r, electric field is zero

Ans. (D)
Sol. Since  never zero at any Gaussian sphere of any radius.

APNI KAKSHA 13
31. A small particle of mass m and charge –q is placed at point P on the axis of uniformly charged
ring and released. If R > > x, the particle will undergo oscillations along the axis of symmetry
Qq
with an angular frequency that is equal to . Find  +  + 
 0 R  m
Ans. (8)
KQx
Sol. E p =
(R + x2 )
2 3/2
1 Qqx
FR = −q E = −
40 ( R 2 + x 2 )3/2
Since R  x
1 Qq
So, FR = − .x
40 R 3
Comparing with FR = − kx
Qq
k=
40 R 3
k
=
m
Qq
=
4 0 R 3m
APNI KAKSHA 14
32. In space, a horizontal electric field E (E = (mg)/q) exists as shown in figure and a mass m
attached at the end of a light rod. If mass m is released from the position shown in figure, the
g
angular velocity of the rod when it passes through the bottom most position is . Find

 +.
Ans. (3)
Sol. From conservation of energy
1 2
Work done by electric field + work done by gravitational field = I
2
1
q.E. sin 45 + mg (1 − cos 45 ) = m 22
2
mg  1  1 2 2 2g
q + mg 1 − = 2m  =
q 2  2
33. The ratio of the time periods of small oscillations of the insulated spring and mass system before
and after charging the masses is
Ans. (1)
APNI KAKSHA 15
1 q2
Sol. In equilibrium of the charged small bodies, . = kx 0 , where x 0 is the elongation
40 ( 0 + x0 )
2
in the spring in equilibrium.

Let a further small elongation of x is given to the spring.
Then, net restoring force on any of the charged particle is given by,
 1 q2 
F = − k ( x 0 − x ) − 2
 40 ( 0 + x 0 + x ) 
Since x is very small so, x is neglected in second term = − kx
2k mm m
a =− x [As F = r where reduced mass  = = ]
m m+m 2
 a = −2 x
2k m
Hence,  =  T = 2
m 2k
m
In absence of charge, T0 = 2
2k
T
Therefore, =1
T0
 Hence (D) is correct
Alternate: For small oscillation force due to their charges does not change so we can assume it
to be constant. And in presence of constant force, time period does not change for spring block
system.
34. A point charge q is placed at a point on the axis of a non – conducting circular plate of radius r at
qr 
a distance R (  r ) from its centre. The electric flux associated with the plate is . Find
40 R 
 +?
Ans. (4)
Sol. As the point is very far.
Kq
So we can assume that electric field at every point on plate  E =
R2
qr 2
 = EA = 2 ( r ) =
Kq 2
R 4 0 R 2
APNI KAKSHA 16
2
35. A small ball of mass 1kg and charge C is placed at the centre of a uniformly charged sphere of
3
1
radius 1m and charge mC . A narrow smooth groove is made in the sphere from centre to
3
surface as shown in figure. The sphere is made to rotate about its vertical diameter at a constant
1
rate of revolutions per second. Find the speed (in m/s) w.r.t. ground with which the ball
2
slides out from the groove. Neglect any magnetic force acting on ball.
Ans. (2)
 3 KQq KQq  KQq m2 R 2

R
1
R  0
Sol. m r =  −  + m xdx = +
2 2
2 2 R 2R 2
Substituting values, we get  2r = 2 + 1 = 3
 t = r = 1
 net = Vr2 + Vt2 = 3 + 1 = 2 m / sec
36. A positive charge +Q is fixed at a point A. Another positively charged particle of mass m and
charge +q is projected from a point B with velocity u as shown in the figure. The point B is at
large distance from A and at distance ‘d’ from the line AC. The initial velocity is parallel to the line
AC. The point C is at very large distance from A. Find the minimum distance (in meters) of +q
from +Q during the motion.
Take Qq = 40mu 2d and d = ( )

2 − 1 meter
APNI KAKSHA 17
Ans. (1)
Sol. The path of the particle will be as shown in the figure. At the point of minimum distance (D) the
velocity of the particle will be perpendicular to its position vector w.r.t. +Q.
Now by conservation of energy
1 2 1 KQq
mu + 0 = m 2 + ...(1)
2 2 rmin
Torque on q about Q is zero hence angular momentum about Q will be conserved
 m  rmin = mud ...( 2 )
By equation (2) in (1), we get
2
1 1  ud  KQq
 mu 2 = m   +
2 2  rmin  rmin
2 d 2  mu 2d
1
 mu  1 − 2  =  KQq = mu 2d ( given )
2  rmin  rmin
 rmin
2
− 2rmin d − d 2 = 0
2d  4d 2 + 4d 2
 rmin =
2
(
= d 1 2 )
Distance cannot be negative
(
 rmin = d 1 + 2 )
APNI KAKSHA 18
PART – 3 : CHEMISTRY

37. In FCC unit cell shown which of the following statements are correct –
(A) sphere 11 & 14 touch each other

(B) sphere 10 & 14 touch each other
(C) sphere 10 & 12 are at a distance of 2 2 r
(D) There are six planes in the FCC unit cell having such arrangement of atoms
Ans. (ABCD)
(D) There are six planes of this type.
38. Select the correct statement(s):

(A) Solubility of alkali metal's chlorate decreases down the group
(B) Solubility of alkali metal's perchlorate decreases down the group
(C) Solubility of alkali metal's nitrate decreases down the group
(D) Solubility of alkali earth metal's sulphate increases down the group
APNI KAKSHA 19
Ans. (A,B,C)
Sol. Solubility of alkali earth metal's sulphate decrease down the group:
BeSO4 > MgSO4 > CaSO4 > SrSO4 > BaSO4
39. Statement I: Produces as major enol in basic medium
Statement II: major enol form in acid medium.
Correct option is/are :

(A) Statement I is Correct
(B) Statement II is Correct
(C) Statement I is correct but Statement II is incorrect
(D) Statement II is correct but statement I is incorrect
Ans. (A, B)
Sol. The molecule has 2αH atoms which can involve in enolisation. In basic medium-the most acidic
H atom is transferred to oxygen during enolisation. H on C1 is more acidic and it is involved in
enolisation. In acid medium-the more stable alkene is formed.
40. In a compound, A atoms are at FCC lattice positions, B atoms are in all tetrahedral voids and C
atoms are in all octahedral voids of this lattice. Assume B and C are of appropriate size so that
there is no distortion in FCC lattice. Find correct statement (s)
(A) formula of the compound is AB2 C
(B) In this compound B atoms will be touching the C atoms.
(C) if atomic masses of A, B and C are 20, 30, and 40 respectively, then mass of unit cell is 480 amu
(D) if radius of A atoms is 200 pm edge length of unit cell is 4 2 Å

Ans. (ACD)
41. Which of the fallowing oxides are amphoteric?

(A) HgO (B) ZnO
(C) PbO2 (D) SnO2
Ans. (B,C,D)
APNI KAKSHA 20
42. Which mixture of structure in each beaker would rotate plane polarized light?
(A) (B)
(C) (D)
Ans. (ABC)

Paragraph for 1 to 3
In solids, the constituent particles are closed packed, leaving the minimum vacant space. The
constituent particles are identical hard spheres and they build the three-dimensional structure.
In ionic solids normally the bigger anions occupy the void spaces, depending on their relative
size.
APNI KAKSHA 21
43. An ionic solid has some point defect but its experimental density is equal to its theoretical
density. The type of defect is
(A) Schottky defect (B) Frenkel defect
(C)Metal excess defect (D) Metal deficient defect
Ans. (B)
 r 2+ 
44. The radius ration of P2+ and Q– ions  p  is 0.8. The unit cell of this ionic solid is
r – 
 Q 
(A) Simple cubic for Q– ions and P2+ ions occupy all the cubic voids
(B) Face centred cubic for Q– ions and P2+ ions occupy all the tetrahedral voids.
(C) Face centred cubic for P2+ ions and Q– ions occupy all the tetrahedral voids.
(D) Face centred cubic for Q– ions and P2+ ions occupy 50% of octahedral voids.
Ans. (C)
45. An ionic solid PQ crystallises in rock salt structure with density 4.0 gm/cm3. If the radius of
cation and anion is 83 and 167 pm respectively, then the molar mass of solid is
[NA = 6 × 1023]
(A) 75 gm/cm3 (B) 50 gm/cm3 (C) 25 gm/cm3 (D) 150 gm/cm3
Ans. (A)
Paragraph for 4 to 6
Keto-Enol tautomerism arises when an αH atom on an α saturated carbon of an aldehyde or
ketone migrates on to carbonyl oxygen The two isomers differ in
the position of a H atom as well as double bond. These two forms are inter changeable. (acid or
alkali medium catalyse). They exist in equilibrium.
46. Which of the following does not exhibit tautomerism?
(A) (B) (C) (D)
Ans. (C)
Sol. It has no H atom on a saturated carbon.
APNI KAKSHA 22
47. Which has maximum enol content among the following?
(A) (B)
(C) (D)
Ans. (D)
Sol. is more stable due
to intramolecular H bonding and extensive conjugation. This compound will have higher enol
content.
48. Aceto acetic ester which exists in keto and enol forms.
It's properties are

(A) Decolorises Br2
(B) It forms a colors with neutral FeCl3 .
(C) It is reduced to sec alcoholic ester with NaBH4 .
(D) All
Ans. (D)
Sol. It exhibits the properties Ketone, alcohol unsaturated compound, phenol

APNI KAKSHA 23
49. An unknown solution [mol. wt. of solute = 250] is 20% (w/w). Molarity of solution is.
[Given dsolution = 1.25 g/ml]
Ans. (1)
n solute
Sol. Molarity =  1000
Vol. of solution (in ml)
20 / 250
= 1000 = 1
100 /1.25
50. Find the number of parent acid formed from complete hydrolysis of P4 O10 .
Ans. (4)
Sol. P4 O10 + 6H2 O ⟶ 4H3 PO4
51. (i) (ii)

Sum of number of stereoisomer (C) & Degree of unsaturations in (D).
Ans. (5)
52. Calculate % volume occupied by atoms in CsCl type structure assuming anion-anion contact.
r+
[Given = 0.7;  = 3 ; 3 = 1.7]
r–
Ans. (67.15)
4 3 4 3
r+ + r–
  r+  
3
Sol. 3 3  =  +  100 = 67.15

100   1
(2r −)3 6  r–  

53. Find the ratio of bond order of N22+ to N22− .

Ans. (1)
54. How many structural isomer are possible for C4 H10 O.

Ans. (7)
APNI KAKSHA 24

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JEE ADVANCED PAPER – 1

APNI KAKSHA STAR BATCH

Time : 3 Hours Maximum Marks : 180

Solution Sheet Available Only for 24 Hours

Section-I (Maximum Marks : 24)

following statement(s) is/are correct

2. Which of the following are correct:

cannot have the integral value

(A) sin θ = −1 (B) sin θ = 1 (C) cos ϕ = 1 (D) cos ϕ = −1

5. Which of the following is a rational number

Section-II (Maximum Marks : 18)

h(x), where h(x) = tan−1 (g −1 f −1 (x))

8. Domain of the function y = h(x) is

9. Range of the function y = h(x) is

Paragraph 1 (Q.10 to Q.12)

[x] ; −2 ≤ x ≤ −1 [x] ; −π ≤ x < 0

10. Number of integers in the Domain of g(f(x)) is

11. Number of integers in the range of g(f(x)) is

12. Number of integers in the range of f(g(x)) is

Section-III (Maximum Marks : 18)

cos(x+4θ)−4 cos(x+3θ)+6 cos(x+2θ)−4 cos(x+θ)+cosx

difference between maximum and minimum value of f(x).

least value of (a2 + b2 + c 2 ).

Section-I (Maximum Marks : 24)

Select the correct alternatives(s).

(A) On the surface of conductor the net charge is always negative

(A) For 0  x  a , potential Vx = 0

For point (2cm, 0). r = 3cm, E = 100

Section-II (Maximum Marks : 18)

volume charge density  ( r ) is given by :

Here  is a positive constant having units of c / m .

25. Mark the correct option(s).

26. Mark the correct option(s).

28. What is the charge on the central particle?

30. In which range of the values of r is the electric field zero?

(D) For no range of r, electric field is zero

Section-III (Maximum Marks : 18)

in the spring in equilibrium.

 3 KQq KQq  KQq m2 R 2

Substituting values, we get  2r = 2 + 1 = 3

 net = Vr2 + Vt2 = 3 + 1 = 2 m / sec

Take Qq = 40mu 2d and d = ( )

Now by conservation of energy

Section-I (Maximum Marks : 24)

(A) sphere 11 & 14 touch each other

(C) sphere 10 & 12 are at a distance of 2 2 r

(D) There are six planes of this type.

38. Select the correct statement(s):

39. Statement I: Produces as major enol in basic medium

Statement II: major enol form in acid medium.

Correct option is/are :

(D) if radius of A atoms is 200 pm edge length of unit cell is 4 2 Å

41. Which of the fallowing oxides are amphoteric?

Section-II (Maximum Marks : 18)

ketone migrates on to carbonyl oxygen The two isomers differ in

46. Which of the following does not exhibit tautomerism?

(A) (B) (C) (D)

Sol. is more stable due

It's properties are

Section-III (Maximum Marks : 18)

51. (i) (ii)

Sol. 3 3  =  +  100 = 67.15

53. Find the ratio of bond order of N22+ to N22− .