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Department of Mechanical Engineering, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia
Received 10 October 2002; received in revised form 10 April 2003; accepted 22 October 2003
Communicated by: Associate Editor William Duff
Abstract
This paper describes a relatively simple model for the preliminary design of an air dehumidification process
occurring in a packed bed using liquid desiccant through dimensionless vapor pressure and temperature difference
ratios. An expression is derived using the aforementioned ratios to predict the water condensation rate from the air to
the desiccant solution in terms of known operating parameters. The model predictions were compared against a reliable
set of experimental data available in the literature, with very good agreement. The effects of the cooling water inlet
temperature and the desiccant-to-water heat exchanger effectiveness on the performance of the dehumidifier are also
studied and the results are presented in this paper.
2003 Elsevier Ltd. All rights reserved.
Nomenclature
the use of a numerical solution to handle the iterative literature as performance parameters. Elsayed et al.
calculations. (1993) used the finite difference model to calculate the
In this paper, dimensionless vapor pressure and humidity effectiveness and the enthalpy effectiveness. The
temperature difference ratios, suitable for air dehumid- results are presented in the form of charts. Martin and
ification using a liquid desiccant, are defined. Further- Goswami (2000) used a large body of previously reported
more, a closed-form analytical solution is obtained to experimental data in deriving closed-form performance
predict the mass flow rate of water condensed (rate of correlations to incorporate the design variables that
moisture removal) from the humid air to the desiccant influence the humidity effectiveness and the enthalpy
solution in terms of the heat capacity rates of the fluids, effectiveness in a packed bed dehumidifier/regenerator.
a dimensionless temperature difference ratio and other Six constants used in the correlations were found
known inlet temperature of the air, desiccant solution through fitting the correlation to experimental data via
and the cooling water. regression. The correlations are valid for limited ranges
of the nondimensional variables. Elsayed et al. as well as
Martin and Goswami used the effectiveness to predict the
2. Dimensionless vapor pressure and temperature differ- outlet conditions of air and the solution.
ence ratios for air dehumidification processes In the present study two dimensionless ratios, which
are not the fitting parameters, are defined. Assuming
During an air dehumidification process, the water constant values of these ratios, an expression is derived
vapor from the humid air transfers to the desiccant to predict the water condensation rate in a packed bed
solution whereas the water vapor is removed from the dehumidifier operating with liquid desiccant. If the
solution during the regeneration process. In the regen- specific heat of the fluids is assumed to be constant, then
eration process, a high solution inlet temperature or a the temperature difference ratio can be used instead of
low desiccant concentration results in more moisture the enthalpy effectiveness. Hence, in order to fully
being removed from the solution to the regeneration air. characterize the dehumidification process, two charac-
Hence, a dimensionless moisture difference ratio, suit- teristic parameters relating to the heat and mass transfer
able for the regeneration process in a packed bed is as dimensionless ratios, one for the difference in mois-
defined as the ratio of the actual change in moisture ture content and the other for the temperature differ-
content of the regeneration air in the unit to the maxi- ence, must be specified. A dimensionless moisture
mum possible change in moisture content under given difference ratio, commonly known as air moisture re-
operating conditions (Gandhidasan, 1990). A similar moval effectiveness, for the air dehumidification process
approach can be implemented for a typical packed bed is defined in terms of the moisture content as
dehumidification system to estimate the mass flow rate Wi Wo
of water condensed from the process air and absorbed a¼ ð1Þ
Wi Wo;min
by the desiccant solution.
It should be noted that the dimensionless moisture The vapor pressure of the relatively warm and weak
difference ratio suitable for a dehumidification process is solution at the outlet of the dehumidifier is higher than
different from that of regeneration process, since the that of the cool and strong solution at the inlet. As long
objective of the dehumidification process is to transfer as the partial pressure of the water vapor in the air is
the water vapor from the process air to the desiccant higher than the solution vapor pressure, dehumidifica-
solution. Many design variables affect the performance tion can take place. Hence, the solution inlet conditions
of the dehumidification process. The driving force for the set a theoretical limit on the minimum humidity ratio
mass transfer between the liquid desiccant solution and that air can reach. Since the air humidity ratio (kg of
the air is the difference between the vapor pressure of the water vapor per kg of dry air) is a function of the partial
desiccant and the partial pressure of water vapor in the pressure of water vapor in the air, this can be written
air. The desiccant solution vapor pressure is a function of accordingly as
its concentration and temperature whereas the partial
pa;o;min ¼ ps;i ð2Þ
pressure of water vapor in the air is a function of the air
humidity ratio. Analogous to the heat exchanger effec- Eq. (1) can be rewritten in terms of the vapor pressure
tiveness used in heat transfer studies, the concept of difference ratio as
effectiveness can be applied to the packed bed dehu- pa;i pa;o
midification process which involves simultaneous heat a¼ ð3Þ
pa;i ps;i
and mass transfer (Martin and Goswami, 2000). The air
moisture removal effectiveness (Ullah et al., 1988; Oberg In order to make the air dehumidification process
and Goswami, 1998b) and the enthalpy effectiveness effective, the strong desiccant solution leaving the
(Elsayed et al., 1993; Khan, 1994, 1996) suitable for regenerator passes through heat exchangers, so that the
dehumidification process are very well defined in the cool and strong desiccant solution absorbs a maximum
412 P. Gandhidasan / Solar Energy 76 (2004) 409–416
amount of water vapor from the air due to the high 5. The warm ðts;o Þ, weak desiccant ðno Þ leaving the dehu-
potential for mass transfer. As expected, the value of pa;o midifier is reconcentrated in the regenerator to the re-
is greater than ps;i . Hence, the value of a is always po- quired concentration ðni Þ and it is cooled to the
sitive and less than 1. temperature of ðts;o Þ before it enters the desiccant-
In summer, it is expected that the temperature of the to-water heat exchanger.
ambient humid air that enters the dehumidifier is higher
than the solution inlet temperature. Hence, in addition Eq. (5) can be written as
to moisture transfer, heat transfer will also occur due to Gs
the temperature difference. The primary objective of the cp;a ðta;i ta;o Þ þ yðpa;i pa;o Þ ¼ cp;s ðts;o ts;i Þ ð6Þ
Ga
dehumidification process is the transfer of water vapor
where y ¼ MMwa Pkb for small vapor pressures. Eq. (6) can be
from the ambient humid air, and hence the temperature
written in terms of dimensionless vapor pressure and
difference ratio can be defined in accordance with the
temperature difference ratios as
dimensionless vapor pressure difference ratio as given by
Eq. (3), to obtain a simple relationship. Accordingly, Gs
cp;a bðta;i ts;i Þ þ yaðpa;i ps;i Þ ¼ cp;s ðts;o ts;i Þ ð7Þ
this can be defined as Ga
ta;i ta;o The effect of desiccant flow rate on the rate of conden-
b¼ ð4Þ sation of water is given in terms of the desiccant con-
ta;i ts;i
centration at the inlet and outlet of the dehumidifier as
The air outlet temperature is expected to be lower than (Kim et al., 1997)
that of the inlet air due to the contact of the air stream
1 1 m
with the cool and strong desiccant solution. This is ¼ 1þ ð8Þ
no ni Gs
confirmed with the experimental data given by Chung
et al. (1993). If the desiccant inlet temperature is higher The mass flow rate of water condensed from the humid air
than the air inlet temperature, then it is expected that the and absorbed by the strong desiccant solution is given by
air outlet temperature is higher than that of the inlet, as Ga y
shown by Chung and Wu (1998). In both cases b is m¼ ðpa;i pa;o Þ ð9Þ
k
positive. However, the air outlet temperature depends
on the heat capacity rate as well as the inlet conditions of The partial pressure of water vapor in the desiccant
both the air and the desiccant solution. Hence, rarely the solution at the inlet of the dehumidifier is given in terms
value of b may be less than zero (Fumo and Goswami, of the water vapor pressure in the humid air entering the
2002) but still Eq. (4) can be used in the analysis. In this dehumidifier by combining Eqs. (3) and (9) as
paper, these two dimensionless difference ratios are mk
combined with the energy balance equation to obtain a ps;i ¼ pa;i ð10Þ
Ga ya
simple expression to predict the mass rate of water vapor
condensed from the humid air to the desiccant solution In order to obtain the desiccant solution temperature at
in terms of known inlet temperatures and heat capacity the outlet of the dehumidifier in terms of the known
rates of the fluids. solution temperature at the inlet, the effectiveness of the
heat exchanger is defined as
ts;o ts;i
3. System analysis eHE ¼ ð11Þ
ts;o tc;i
The overall energy balance for the dehumidifier can The desiccant outlet temperature in terms of the inlet
be written as temperature is given by
Ga ha;i þ Gs hs;i ¼ Ga ha;o þ Gs hs;o ð5Þ ts;i eHE tc;i
ts;o ¼ ð12Þ
ð1 eHE Þ
The following assumptions are made for the analysis:
By substituting the values for ps;i and ts;o from Eqs. (10)
1. The water condensation rate is negligible compared and (12), respectively, in Eq. (7), the mass flow rate of
to the flow rate of fluids. water condensed from the humid air to the desiccant
2. The specific heat of the fluids with respect to the tem- solution can be obtained. Accordingly, this is given by,
perature is constant.
1 Cs eHE
3. The latent heat of condensation is constant with re- m¼ ðts;i tc;i Þ Ca bðta;i ts;i Þ ð13Þ
k ð1 eHE Þ
spect to the temperature and concentration of the
desiccant encountered in the system. where Cs ¼ Gs cp;s and Ca ¼ Ga cp;a . It is to be noted that
4. The desiccant inlet temperature is different from the the dimensionless vapor pressure difference ratio, a is
inlet temperature of air. not directly involved in estimating m. However, in using
P. Gandhidasan / Solar Energy 76 (2004) 409–416 413
Table 1
Comparison of experimental results (Fumo and Goswami, 2002) with the present study
Experimental results Present study with % difference
2 2
Case (1) Ga ¼ 1:18 kg/m s, ta;i ¼ 30:1 C, Wi ¼ 0:0181 kg water vapor/kg dry air, Gs ¼ 6:227 kg/m s, ts;i ¼ 30:3 C, ni ¼ 34:7% by
mass, b ¼ 10:5
tc;i ¼ 29:6 C
no (% by mass) 34.6 34.65 0.14
ts;o (C) 32.6 31.35 3.83
m (g/s) 0.40 0.372 7.00
Case (2) Ga ¼ 1:513 kg/m2 s, ta;i ¼ 30:2 C, Wi ¼ 0:0181 kg water vapor/kg dry air, Gs ¼ 6:113 kg/m2 s, ts;i ¼ 30:0 C, ni ¼ 34:3% by
mass, b ¼ 10:0
tc;i ¼ 29:1 C
no (% by mass) 34.1 34.24 0.41
ts;o (C) 32.7 31.38 4.04
m (g/s) 0.52 0.476 8.46
Case (3) Ga ¼ 1:189 kg/m2 s, ta;i ¼ 35:5 C, Wi ¼ 0:0188 kg water vapor/kg dry air, Gs ¼ 6:29 kg/m2 s, ts;i ¼ 30:3 C, ni ¼ 34:5% by
mass, b ¼ 0:52
tc;i ¼ 29:3 C
no (% by mass) 33.7 34.45 2.20
ts;o (C) 32.6 31.73 2.67
m (g/s) 0.42 0.389 7.38
Case (4) Ga ¼ 1:183 kg/m2 s, ta;i ¼ 40:1 C, Wi ¼ 0:018 kg water vapor/kg dry air, Gs ¼ 6:287 kg/m2 s, ts;i ¼ 30:5 C, ni ¼ 34:4% by
mass, b ¼ 0:73
tc;i ¼ 29:5 C
no (% by mass) 34.3 34.36 0.17
ts;o (C) 32.9 32.05 2.58
m (g/s) 0.36 0.332 7.78
Case (5) Ga ¼ 1:214 kg/m2 s, ta;i ¼ 30:3 C, Wi ¼ 0:0142 kg water vapor/kg dry air, Gs ¼ 6:273 kg/m2 s, ts;i ¼ 30:1 C, ni ¼ 33:9% by
mass, b ¼ 4:0
tc;i ¼ 29:7 C
no (% by mass) 33.8 33.88 0.24
ts;o (C) 31.5 30.70 2.54
m (g/s) 0.23 0.206 10.4
Case (6) Ga ¼ 1:187 kg/m2 s, ta;i ¼ 29:9 C, Wi ¼ 0:0215 kg water vapor/kg dry air, Gs ¼ 6:272 kg/m2 s, ts;i ¼ 30:3 C, ni ¼ 33:9% by
mass, b ¼ 8:75
tc;i ¼ 29:4 C
no (% by mass) 33.7 33.84 0.41
ts;o (C) 33.1 31.60 4.53
m (g/s) 0.53 0.483 8.87
Case (7) Ga ¼ 1:19 kg/m2 s, ta;i ¼ 30:1 C, Wi ¼ 0:018 kg water vapor/kg dry air, Gs ¼ 5:019 kg/m2 s, ts;i ¼ 30:2 C, ni ¼ 34:4% by
mass, b ¼ 21
tc;i ¼ 29:4 C
no (% by mass) 34.2 34.35 0.44
ts;o (C) 32.7 31.39 4.01
m (g/s) 0.38 0.344 9.47
Case (8) Ga ¼ 1:198 kg/m2 s, ta;i ¼ 29:9 C, Wi ¼ 0:0177 kg water vapor/kg dry air, Gs ¼ 6:269 kg/m2 s, ts;i ¼ 25:0 C, ni ¼ 34:7% by
mass, b ¼ 0:35
tc;i ¼ 23:9 C
no (% by mass) 34.5 34.64 0.40
ts;o (C) 28.4 26.62 6.27
m (g/s) 0.50 0.466 6.80
Case (9) Ga ¼ 1:176 kg/m2 s, ta;i ¼ 29:9 C, Wi ¼ 0:0178 kg water vapor/kg dry air, Gs ¼ 6:309 kg/m2 s, ts;i ¼ 35:2 C, ni ¼ 34:9% by
mass, b ¼ 1:1
tc;i ¼ 35:06 C
no (% by mass) 34.8 34.88 0.23
ts;o (C) 36.2 35.41 2.18
(continued on next page)
414 P. Gandhidasan / Solar Energy 76 (2004) 409–416
Table 1 (continued)
Experimental results Present study with % difference
m (g/s) 0.21 0.192 8.57
2 2
Case (10) Ga ¼ 1:182 kg/m s, ta;i ¼ 29:9 C, Wi ¼ 0:0179 kg water vapor/kg dry air, Gs ¼ 6:164 kg/m s, ts;i ¼ 30:1 C, ni ¼ 33:1% by
mass, b ¼ 12:5
tc;i ¼ 29:5 C
no (% by mass) 33.0 33.06 0.18
ts;o (C) 32.2 31.00 3.73
m (g/s) 0.36 0.331 8.06
Case (11) Ga ¼ 1:192 kg/m2 s, ta;i ¼ 29:9 C, Wi ¼ 0:0179 kg water vapor/kg dry air, Gs ¼ 6:267 kg/m2 s, ts;i ¼ 30:2 C, ni ¼ 33:8% by
mass, b ¼ 8:67
tc;i ¼ 29:6 C
no (% by mass) 33.7 33.76 0.18
ts;o (C) 32.6 31.12 4.54
m (g/s) 0.38 0.344 9.47
Case (12) Ga ¼ 1:176 kg/m2 s, ta;i ¼ 30:0 C, Wi ¼ 0:0181 kg water vapor/kg dry air, Gs ¼ 6:206 kg/m2 s, ts;i ¼ 30:2 C, ni ¼ 34:8% by
mass, b ¼ 10:0
tc;i ¼ 29:5 C
no (% by mass) 34.7 34.75 0.14
ts;o (C) 32.5 31.29 3.72
m (g/s) 0.41 0.376 8.29
Eq. (13), care should be exercised in accordance to the experimental results are used to calculate the dimen-
following: sionless temperature difference ratio ðbÞ. It may be noted
that two values of b are less than zero. The cooling water
• The value of b and the cooling water inlet tempera- inlet temperature is adjusted to obtain the same air
ture must be selected so that pa;o is always greater humidity ratio at the outlet of the dehumidifier. The la-
than ps;i . tent heat of condensation is assumed as constant at
• The desiccant inlet temperature to the dehumidifier 2430.0 kJ/kg. According to the results given in Table 1,
may be either lower or higher than the air inlet tem- there is a very good agreement between the experimental
perature, but the cooling water inlet temperature must data of Fumo and Goswami and the theoretical results of
always be lower than the desiccant inlet temperature. this study for the desiccant outlet temperature and the
• The desiccant flow rate cannot be increased beyond water condensation rate. In all cases, the predicted values
the flooding velocity and the minimum desiccant flow for the above parameters are lower than the experimental
rate must be sufficiently high enough to ensure wet- data and the maximum difference is less than 10.5%. An
ting of the packing. attempt was also made to perform a sensitivity analysis,
with respect to the heat exchanger effectiveness. Accord-
ingly, its value was increased to 0.8 and it was found that
4. Results and discussion the same results were obtained with higher cooling water
inlet temperatures of 30.0, 29.7, 29.9, 30.1, 30.0, 30.0,
In order to use Eq. (13) with confidence for predicting 30.0, 24.6, 35.15, 29.9, 30.0, and 29.9 C, respectively for
the mass flow rate of water condensed from the air to the the same 12 cases presented in Table 1. Based on this
liquid desiccant during the dehumidification process, preliminary comparison, it is believed that the simplified
validation is needed. A comparison was made between model described herein gives good predictions and added
the predicted values acquired from the above equation confidence that this model may be used to make a first
and experimental values available in literature. Reliable estimate of the water condensation rate.
sets of experimental data for dehumidification of air Fumo and Goswami (2002) studied the effects of
using lithium chloride (LiCl) as the liquid desiccant are various design variables such as air flow rate, humidity
presented by Fumo and Goswami (2002). A comparison ratio, inlet air temperature, desiccant flow rate, desiccant
of typical experimental results for twelve cases as pre- concentration, and inlet desiccant temperature on the
sented by Fumo and Goswami, with the results obtained performance of the dehumidifier in detail. Hence, in this
from the current study, is given in Table 1. Since Fumo paper, the effects of cooling water inlet temperature and
and Goswami provide no information about the heat the heat exchanger effectiveness are investigated using
exchanger used in their experimental facility, the effec- Eq. (13). The parameters that have been kept constant
tiveness of the heat exchanger is assumed as 0.6. The are listed in Table 2.
P. Gandhidasan / Solar Energy 76 (2004) 409–416 415
Table 2 14
Dehumidifier parameters for the parametric investigation
Desiccant Lithium chloride
εHE = 0.6
12 εHE = 0.65
o
tc,i = 29.5 C in the literature. It is found that the lower cooling water
10
inlet temperature and the higher heat exchanger effec-
tiveness increase the rate of moisture removal. The effect
8
of changing the desiccant flow rate on the water con-
6
densation rate is more pronounced at low cooling water
inlet temperature than at high tc;i . For preliminary de-
4
sign purposes, the simple expression derived in this pa-
per can be used to estimate the water condensation rate.
2
0 Acknowledgement
3 3.5 4 4.5 5 5.5 6 6.5
Desiccant flow rate, kg/m2s
The author is grateful for the financial support and
Fig. 2. Influence of cooling water inlet temperature on con- facilities provided by the King Fahd University of
densation rate. Petroleum and Minerals for this research.
416 P. Gandhidasan / Solar Energy 76 (2004) 409–416