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Keywords: The present work aims to enhance the performance of a solar energy-driven HDH desalination system. An
Renewable energy experimental apparatus consisting of a novel closed-loop pulsating heat pipe (CLPHP) assisted by a bubble basin
Desalination HDH system was investigated. To evaluate the productivity of the fresh water, tests have been properly designed
Humidification/dehumidification
and conducted in outdoor and indoor modes during June and July of 2020, under local weather conditions of
Closed-loop pulsating heat pipe
Bubble basin
Mashhad, Iran. A closed air-heated configuration is introduced into the HDH desalination system, to recover the
condensation latent heat. The air leaving the dehumidifier is pre-heated and pre-humidified using CLPHP before
entering the humidifier of the desalination unit. Also, an air injection system is used to enhance the mass and
heat transfer rate by generating bubbles. In the experiments, the influence of the operating conditions such as
radiation and air mass flow rate on the performance of the desalination unit was investigated. Furthermore, a
comparison between the bubble basin and bubble column types was carried out. Based on the results, the bubble
basin type presented a higher yield compared to the bubble column type that was obtained as 0.83 and 0.70 (kg/
(hr.m2)), respectively. Besides, it was observed that by increasing the radiation and air mass flow rate, pro
ductivity is improved. The maximum obtained yield of the proposed system was achieved as 8.7 L/(day.m2).
Desalinating seawater and brackish water is becoming a necessity for Closed cycles of water/air improve energy recovery since the input
the sustainable development of many regions in the world. It is predicted energy used for water/air heating is preserved in the process. CA-OW air
that in two decades, solar energy will become the cheapest desalination heated cycle usually surpasses OA-OW [9–12].
technology with a price of 0.00045 $/L of treated water [1]. Various HDH units have three main sections: humidifier, dehumidifier, and
methods have been studied on water desalination such as multi-effect heat source. A humidifier can be a wetted wall column, packed bed
desalination (MED) [2], multi-stage flashing (MSF) [3], reverse containing different packings, spray tower, or bubble column. Bubble
osmosis (RO) [4,5], solar stills [6,7], humidification/dehumidification column humidifiers (BCH) are promising for HDH, offering higher heat
processes (HDH) [8], etc. HDH desalination system is a promising and mass transfer rates by direct mixing of air with water at low cost and
technology to address water scarcity issues in rural regions and is known have low maintenance requirements [9,12,13].
as an appealing process for small and medium scales, and high-salinity The ultimate purpose of an HDH desalination unit is to obtain a
water desalination [9]. HDH process due to its wide range of advan higher rate of fresh water. To enhance productivity, various bubble HDH
tages such as moderate working pressure and temperature, easy system arrangements have been investigated in the literature. A summary of the
construction using low-cost materials, and effortless system operation is conducted works has been provided.
considered as the most effective method for desalination process [10]. Fallahzadeh et al. [14] introduced a modified pyramid-shaped solar
HDH systems can be classified under two broad categories [11]:
* Corresponding author.
E-mail address: v.madadi@yu.ac.ir (V. Madadi Avargani).
https://doi.org/10.1016/j.enconman.2020.113694
Received 7 September 2020; Received in revised form 21 November 2020; Accepted 23 November 2020
Available online 2 December 2020
0196-8904/© 2020 Elsevier Ltd. All rights reserved.
L. Aref et al. Energy Conversion and Management 228 (2021) 113694
still (MPSS) integrated with a heat pipe solar collector. Two different increased by about 56% with an increase in superficial air velocity.
working fluids (water and ethanol) were used at three different filling Furthermore, system productivity is increased by around 29% with an
ratios (FRs). The best amount of FR was found as 40% for both working increase in liquid height. Behnam and Shafii [19] experimentally
fluids. The MPSS offered the best possible performance and the accu investigated the performance of an HDH solar desalination system
mulated yield was achieved over 6000 mL/m2. Rajaseenivasan and equipped with a heat pipe, an evacuated tube collector, and an air
Srithar [15] investigated a bubble column HDH desalination system bubble column humidifier. The effects of various parameters including
powered by biomass energy. The highest distillate of 6.1 kg/hr and air flow rate into the humidifier and initial depth of water in the hu
3.5 kg/hr is collected for the HDH desalination system with pre-heated midifier were investigated. Khalil et al. [20] studied the effect of water
air and direct air supply, respectively. Rajaseenivasan et al. [12] stud temperature, air flow rate, water height, and sieve’s hole diameter on
ied the performance of an HDH desalination system by using a bubble desalination performance using an air bubble column humidifier and an
column system with a solar air heater, a solar air heater with turbulators, evacuated tube solar collector. The results showed that daily produc
and a dual-purpose solar collector with turbulators. The maximum tivity and efficiency are 21 kg and 63%, respectively.
gained output ratio and overall efficiency of 3.3 and 78% were obtained The present work aims to reduce the cost and improve the perfor
with a dual-purpose solar collector containing turbulators and solar air mance of an HDH system using:
heater containing turbulators, respectively. Fallahzadeh et al. [16]
experimentally investigated an active bubble basin solar still to evaluate 1. Humidifier: Bubble basin (BB) integrated with a pulsating heat pipe
the effect of a CLPHP and a bubble injection system. This study focuses solar collector (PHPSC)
on using a CLPHP to enhance the heat transfer and minimize the heat 2. Dehumidifier: Dual-purpose pulsating heat pipe dehumidifier
loss of vapor condensation. Liu and Sharqawy [17] investigated the (PHPDH), i.e. as a condenser and a heat recovery apparatus.
performance of bubble column humidifier and dehumidifier experi
mentally under sub-atmospheric pressures. The results showed that By using the BB, solar energy is absorbed via the PHPSC and is
operating the bubble column humidifier at sub-atmospheric pressure directly transferred to the water. Therefore, unlike other common solar
enhances the total heat transfer by about 35% and the effectiveness by HDH processes that use pumps to circulate water to collectors [19], by
about 7.1%. Eder and Preißinger [18] investigated the humidification of removal of the pump, a lower desalinated water cost is predicted.
air in a bubble column and concluded that the system productivity is In most HDH systems, the shell and tube (ST) heat exchanger and
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L. Aref et al. Energy Conversion and Management 228 (2021) 113694
Fig. 1. Schematic of the proposed HDH desalination unit. (Dimensions are not to scale).
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L. Aref et al. Energy Conversion and Management 228 (2021) 113694
best angle for the collector to absorb the maximum radiation is settling
in the same latitude of the experimentation site [26]. The inclination of
the PHPSC was 35◦ to the horizon which is approximately the same as
the latitude of Mashhad.
0.004 m and 0.005 m, respectively, which is put onto the bottom plate of
the collector and fastened by glue.
The CLPHP comprises 9 turns with a bending radius of 0.05 m. The
evaporation, adiabatic, and condensation sections of the CLPHP are 1 m,
0.07 m, and 0.3 m long, respectively. On the surface of the CLPHP, an
aluminum sheet with a thickness of 0.001 m is placed which is painted in
black to maximize the solar absorption. The received radiation at the
evaporation section is transferred to the condensation section, where it
is cooled by the basin water. To connect the CLPHP to the basin, 10 holes
with a diameter equal to the OD of the capillary tubes are drilled on the
wall of the basin. To prepare the CLPHP for operation, initially, the
CLPHP is evacuated to a certain low pressure and then partially filled by
distilled water with the FR of 40% using a filling/vacuum system. The Fig. 4. Schematic of the BBH.
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L. Aref et al. Energy Conversion and Management 228 (2021) 113694
water molecules and carries them as it flows upward into the PHPDH ( 2 )0.5
through a plastic duct with a diameter of 0.1 m. However, some amount u(B,x) =
ax
(1)
of humidified air in the BBH is condensed on the glass cover owing to the 3
temperature difference between the glazed aperture and the air. A gutter
is used to collect this distilled water and direct it to a collecting jar. where, ax is the accuracy of the measuring device.
The uncertainty associated with each of the variables (x) used in
2.1.3. Pulsating heat pipe dehumidifier (PHPDH) determining the overall efficiency is given by the square root of the sum
A schematic of the detailed structure and geometry of the PHPDH is of the variances of the statistical distributions of each component (i)
shown in Fig. 5. The corresponding dimensions of the outer acrylic involved in the process, namely,
plastic enclosure are 0.5 × 0.2 m2 with a height of 0.4 m. Insulation of (
n ( ) )0.5
∑ ∂y 2 2
PVC with a thickness of 0.02 m is covered on the outer surface of the uy = uxi (2)
enclosure to minimize heat loss. A CLPHP is utilized to dehumidify the i=1
∂xi
entering air and to pre-heat the recycled air. The CLPHP is a copper Hence, the combined uncertainty of the daily overall efficiency (ηd )
capillary tube with ID and OD of 0.004 m and 0.005 m, respectively, is:
which is divided into two parts by a separating sheet. The CLPHP
⎡ ( ) ⎤0.5
comprises 23 turns with a bending radius of 0.04 m. The evaporation u2G A2PHPSC + A2g
u2v
section and condensation section of the CLPHP are 0.17 m and 0.15 m ⎣
Uηd = ηd 2 + ( ( ) )2 ⎦ (3)
v
long, respectively. To prepare the CLPHP it is filled by distilled water G APHPSC + Ag + WB
with the FR of 40% using the filling/vacuum system. The received latent
The calculated maximum combined uncertainty for daily overall
heat of vapor at the bottom part of the PHPDH is transferred to the upper
efficiency is 0.004%.
part of the PHPDH to pre-heat the recycled air.
The carried-out experiments were screened by some instrumental
devices and all of the important variables were measured and recorded
2.2. Uncertainty analysis and instruments during the experimental tests, which include:
Uncertainty of measurement implies the parameter related to the 1. Solar and IR radiation
result of a measurement characterizing the scattering of the values that 2. The temperature of the ambient air
seem sensibly be credited to the measurand. The purpose of measure 3. The temperature of the water basin
ment is the estimation of the true value of a measurand. If the mea 4. The temperature of the air
surement is perfect, the true value could be obtained which is the ideal 5. The relative humidity of the air
result. A real measurement is influenced by errors. Even, if all the errors 6. The flow rate of the circulating air
could be assessed and corrected, uncertainty about the result of the
measurement there still exists [27]. According to GUM the imprecision The corresponding devices measuring these parameters are listed in
which is derived from data sheets of the measuring device is a type B Table 1 with their accuracies and ranges. Also, three blowers with tag
standard uncertainty, which is calculated by [28]: numbers of B1, B2, and B3 were utilized to circulate the air in the system
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Fig. 10. Schematic of the psychrometric chart (dimensions are not to scale).
Fig. 11. Effect of radiation heat flux on yield and overall efficiency.
Fig. 12. Effect of radiation heat flux on the humidifier efficiency and dehu
radiation. By increasing the radiation, Tw has been raised denoting the midifier effectiveness.
better performance of the PHPSC. At a higher Tw, the heat and mass
transfer rates rise from hot water to the air bubbles, so that boosted difference between the BBH outlet air and the bottom part of PHPDH
humidity of air at the BBH exit is achieved. Consequently, the produc outlet air (w1 − w2 ) is heightened. According to Eq. (6), although a
tion of fresh water gets enhanced. Besides, the overall efficiency is higher humidity in the BBH outlet (w1 ) is obtained at the higher radi
improved by the amplification of the radiation. The reason behind this ation, the efficiency is increased.
fact is that, although, the enhancement of the radiation has a negative
effect on efficiency due to the improved received energy, but at the same 3.1.3. Effect of air flow rate
time increases the yield, too. So ultimately, according to Eq. (4), the sum Fig. 13 demonstrates the effect of air mass flow rate on temperature
of these effects leads to an increase in overall efficiency. and relative humidity. Although the temperatures of Tw, Ta1, Ta2, and
Fig. 12 illustrates the effect of the radiation on the BBH and PHPDH Ta3 have an increasing trend with the enhancement of air flow, their
efficiency. The results revealed that the radiation has a direct relation variations are not considerable. Air flow is inserted into the BBH and
ship with both parameters. It is clear that by enhancing the radiation, PHPDH through a bubble pipe to generate bubbles. Since increasing the
the collector absorbs more thermal energy leading to increased Tw. Also, air flow rate improves the velocity of up going bubbles, the possibility
as mentioned before the higher the Tw the greater is Ta1. Hence, as and the quantity of the bubble collisions heightens. This fact leads to the
discussed before, Ta3 would be higher. On the other hand, RH1 is very transformation of the kinetic energy of bubbles to thermal energy to
close to saturation. So, based on Fig. 10, the corresponding specific some extent. Hence, the temperatures of the Tw, Ta1, Ta2, and Ta3 are
humidity at these temperatures would be higher providing a higher increased lightly. Also, by raising the air flow rate, the temperature
specific humidity difference. By increasing the radiation further, the difference between Ta2 and Ta3 is grown. This is due to the enhanced
humidifier efficiency remains constant. This is due to the PHPSC’s po collision of the bubbles in the water bath.
tential in transferring the thermal energy. At certain radiation intensity, As can be seen in Fig. 13, by increasing the air flow rate, RH1 has an
the PHPSC reaches its maximum heat transfer efficiency. Hence, the increasing trend. The air flow rate enhancement increases the mixing
humidifier efficiency remains constant and reaches a steady operation. rate and coalescence of the bubbles, making the system turbulent. The
These facts are in exact accordance with Eq. (5). turbulency of the system improves the mass transfer rate of the basin
According to Fig. 12, PHPDH efficiency is increased with radiation water molecules into the air. Substantially, increasing the flow rate of
enhancement. As shown in Fig. 10, by raising the radiation, the humidity the air means that the air as a carrier is capable of transferring more
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L. Aref et al. Energy Conversion and Management 228 (2021) 113694
Fig. 15. Effect of the mass flow rate of air on humidifier efficiency and
dehumidifier effectiveness.
Fig. 13. Effect of the mass flow rate of air on temperature and rela
enhancement of specific humidity of humidifier outlet air (w1). Hence,
tive humidity. based on Eq. (5) the humidifier efficiency is raised. Also, the variation of
Ta2 is almost constant and RH2 has a descending trend concluding a
reduction in specific humidity of the dehumidifier bottom part outlet air
water molecules from the BBH. As a result, the relative humidity of the
(w1). According to Eq. (6), dehumidifier’s efficiency is increased.
air leaving the BBH (RH1) rises. Moreover, RH2 has experienced a
descending trend with increasing the mass flow rate of the air. This fact
can be explained by the increased condensation in the PHPDH. When the
3.2. Outdoor mode
condensation occurs, the water content of the leaving air is reduced
leading to a reduction of the relative humidity of the leaving air.
Fig. 16 shows the measured hourly variation of solar irradiance
Additionally, RH3 is almost saturated at any air flow rate because the
received by the HDH system concerning the local time for three days
leaving air from the upper part of the PHPDH has come into contact with
(6.2.2020, 6.18.2020, and 7.6.2020). Although climate factors such as
the water bath.
clouds, humidity, dust, etc., would affect the amount of solar radiation
Fig. 14 clarifies that the yield and overall efficiency is proportional to
received by the earth’s surface day by day, the average deviation be
the air flow rate. By increasing the air flow rate, the number of bubbles
tween the solar radiations for the tested days is within 10%. The
existing in the medium is rose leading to enhancement of the surface
maximum solar irradiance was received on the third day (July 6) among
contact area between the bubbles and the water. Also, the collisions of
the three test days followed by the second day (June 18) and the first day
the bubbles are raised. All of these events result in the improved mass
(June 2). The radiation variations range between 307 and 997 W/m2.
transfer between the water and the air. Consequently, the air carries
The observation showed that the solar radiation profile seems to be the
more water molecules and leaves the BBH with higher relative humidity.
same on the experimental days. The amount of total solar radiation
So, productivity would be increased.
incident on the system depends on the time of the day. The solar radi
Results revealed that the HDH system exhibits a higher efficiency at
ation varies along the hours after sunrise until a maximum value at
elevated air flow rates which is illustrated in Fig. 14. This fact could be
midday then decreases in the afternoon. These solar radiation data are
interpreted according to Eq. (4); the higher the productivity, the greater
used to calculate the overall efficiency.
is the overall efficiency.
Fig. 17 shows the hourly yield of the HDH system on experimented
Based on Fig. 15, by increasing the air flow rate the efficiencies of the
days. The yield of the HDH system follows the solar radiation intensity
humidifier and dehumidifier are slightly enhanced. According to Fig. 13,
trend, except the maximum yield has occurred at 1 PM. The change in
by increasing the air mass flow rate, Ta1 remains approximately con
water temperature lags behind the solar irradiance change for about an
stant, but there is a considerable improvement in RH1 which leads to
hour. Due to the high specific heat of water, the water temperature tends
Fig. 16. Measured hourly variation of the solar irradiance received by the HDH
Fig. 14. Effect of the mass flow rate of air on the yield and overall efficiency. system on three different days (June 2nd, June 18th, and July 6th of 2020).
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L. Aref et al. Energy Conversion and Management 228 (2021) 113694
Table 2
Manufacturing costs of the HDH system.
Components Cost ($)
PHPSC Glass 2
Black paint 1.5
Aluminum cover 0.25
Copper tube 16
Aluminum frame 15
PVC insulation 4
Polycarbonate two-layer sheet 25
BBH Plastic duct 0.7
Inlet & outlet tubes 0.1
Galvanized sheet 6.3
Glass 1
PVC insulation 2
PHPDH PVC insulation 3
Acrylic plastic 12
Copper tube 8
Fig. 17. The hourly yield of the HDH system on three different days (June 2nd, Inlet & outlet tubes 0.1
June 18th, and July 6th of 2020). Other devices Wooden structure 10
Feed tank 0.2
Brine tank 0.2
to increase even when the solar intensity is reduced. As a result, the
Three Valves 37.5
evaporated mass tends to increase leading to enhancement of the yield. Blower #1 22
The maximum hourly yield of the HDH system for the third, second, and Blower #2 15
the first day, is 1.42, 1.34, and 1.27 kg/(hr.m2), respectively. It can be Blower #3 13
seen that the production rate is low in the morning hours due to the high Capital cost 194.85 $
thermal mass of water inside the humidifier and its lower temperature.
As the water temperature increases, the hourly production increases as (n = 10) and annual cost (AC) are the main calculation parameters
well. used in the cost analysis of the desalination unit. Finally, the cost of
Daily water productivity and overall efficiency are illustrated in distilled water per liter (CPL) can be calculated by dividing the net
Fig. 18. The accumulated yield for the third (July 6), second (June 18), annualized cost of the system (AC) by the annual yield of the HDH
and the first day (June 2) reached 8.7, 8.4, and 7.9 kg/(day.m2), system (M). The above-mentioned calculation parameters are expressed
respectively. These deferent values on the accumulated yield are due to in Table 3.
the variation of climatic conditions especially the total solar radiation. Due to the significant decline of the performance of the HDH in the
For the third day, the solar irradiance is the highest among the three test seasons with less solar radiation, the average daily yield of the HDH
days which led to a high accumulated freshwater yield. The HDH system system throughout a year is considered 75% of the maximum daily yield
efficiency for the three test days remains approximately constant. on a typical summer day (8.7 kg/m2). The cost of distilled water per liter
(CPL) can be calculated by dividing the net annualized cost of the system
(AC) by the annual yield of the HDH system (M = the operational time ×
3.3. Economic analysis the average yield). The cost of the distilled water varies depending on
operational time (Fig. 19).
Table 2 exhibits the cost estimation for different components used in
the fabricated HDH system. The capital cost (P) was 194.85 $. The
capital recovery factor (CRF), the fixed annual cost (FAC), the sinking 3.4. Water quality analysis
fund factor (SFF), the annual salvage value (ASV), annual maintenance
cost (AMC), current cost (CC) (0.005 $/KWh), cost of power used in the To evaluate the system performance on the quality of the produced
system (ACC), the interest per year (i = 12%), the number of life-years water, the brackish water and obtained distilled water was subject to
Fig. 18. Daily water productivity and efficiency for three different days (June 2nd, June 18th, and July 6th of 2020).
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L. Aref et al. Energy Conversion and Management 228 (2021) 113694
Table 3 are not enforced. They are guidelines for water treatment plant opera
Economic analysis. tors and state governments attempting to provide communities with the
Parameter Value Unit best quality water possible [29]. The values of these parameters are
compared with the standard values subscribed to drinking water by
P 194.85 $
S = 0.2P 38.97 $ WHO, and the results have been tabulated in Table 4.
n 10 year Table 5 compares the performance of the presented system with the
i 12 % results of the previous studies. The distillate of this work is comparable
CRF =
i(1 + i) n
0.175 – with the previous results and gives better overall efficiency. It reveals
(1 + i)n − 1 that the proposed system provides a notable improvement in the
FAC = P × CRF 34.10 $
i
distillate of the humidification-dehumidification desalination system.
0.057 –
SFF =
(1 + i)n − 1
AMC = 0.15FAC 5.12 $ 4. Conclusion
CC 0.005 $/Kwh
( )
E = 0.001 × Wblower,1 + Wblower,2 + Wblower,3 × t 0.432 Kwh This work presents the effect of using CLPHP as an energy source and
ACC = CC × E 0.002 $ also a dual-purpose device for distillation and recovering the conden
ASV = SFF × S 2.22 $ sation latent heat instantaneously. The air is driven into the BBH and
AC = FAC + AMC + ACC − ASV 37.002 $ PHPDH in the form of bubbles and the effects of air flow rate and ra
M 3175.5 L diation on its performance have been investigated and the following
AC 0.012 $/L
CPL = results were concluded:
M
5. Future work
Fig. 19. Changes of the CPL with operational time.
This research is focused on the PHPDH-assisted bubble basin of the
various tests for determining the Secondary Standards, and physical HDH desalination system. In future work, the dispersion of nano-sized
quantities like pH, electrical conductivity, TDS, hardness, turbidity, particles in the working fluid could be the better choice for enhancing
Iron, Manganese, Aluminum, and Free residual chlorine. Secondary the heat transfer capability of PHPDH. Moreover, it could be recom
Standards regulate contaminants that cause offensive taste, odor, color, mended to use a combination of the HDH system and solar air heater for
corrosivity, foaming, and staining. The concentration limit is called the improving productivity.
Secondary Maximum Contaminant Level (SMCL). Secondary Standards
Table 4
Water quality analysis.
Parameter Secondary Maximum Contaminant Level (SMCL)* Brackish water Distilled water
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L. Aref et al. Energy Conversion and Management 228 (2021) 113694
Table 5
The comparison of different HDHs and the present study.
Author System Overall efficiency Productivity
CRediT authorship contribution statement [15] Rajaseenivasan T, Srithar K. An investigation into a laboratory scale bubble column
humidification dehumidification desalination system powered by biomass energy.
Energy Convers Manage 2017;139:232–44. https://doi.org/10.1016/j.
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analysis, Investigation, Writing - original draft, Writing - review & [16] Fallahzadeh R, Aref L, Madadi Avargani V, Gholamiarjenaki N. An experimental
editing, Visualization, Funding acquisition. Rasoul Fallahzadeh: investigation on the performance of a new portable active bubble basin solar still.
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Vahid Madadi Avargani: Supervision, Conceptualization, Methodol dehumidifier under varying pressure. Int J Heat Mass Transf 2016;93:934–44.
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