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adhesion
The Trade Journal for Industrial Adhesives and Sealants
ADHESIVES +
SEALANTS
Pretreatment of Surfaces
Cleanliness in
Submicrometer and
Atomic Percent Range
Digital, interactive, mobile:
the new adhesion eMagazine
New and free of charge in addition to the printed version – exclusively for subscribers
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2 I 2022 Volume 19
adhesion
The Trade Journal for Industrial Adhesives and Sealants
www.adhaesion.com
ADHESIVES +
SEALANTS 2 I 22
Trends Adhesives and Sealants Applications
Adhesives from UV-Moisture-Curing Silicone-Based Thermal
Plastic Bags Adhesive Systems Interface Materials
14 18 22
Pretreatment of Surfaces
Cleanliness in
Submicrometer and
Atomic Percent Range
adhesion 2 I 22 3
Trends and Events
Around 50 material combinations Components made of a combination of thermoplastic and thermosetting elastomers.
already validated
4 adhesion 2 I 22
Manufacturing Gaskets and Molded
ity management process, these data are then combined with pro-
duction data. According to Tec-Joint, the data allow correspond-
ing solutions to be developed more easily and cases of damage
to be analyzed quickly. Companies with ISO 9001 and ISO 14001
certification that are familiar with the quality requirements of
their industry and supply high-quality products can also provide
end-to-end documentation of the processes. //
Quality management and documentation along the entire value chain Contact and further information:
is a key feature of modern development projects and services. Richard Gisler, Tec-Joint, r.gisler@tec-joint.ch, www.tec-joint.ch
5
Trends and Events
Low optical interaction, high strength this is offset by lower strength, slower curing, and, in some cases,
strong outgassing. What is more, they emit particles to their sur-
A precondition for high component quality is, in particular, low roundings during curing. Due to the potential impact on adjacent
optical interaction between the adhesive and the photopolymer. manufacturing processes, many automotive suppliers are striving
For that reason, the adhesives are chemically adapted in such a to achieve silicone-free production. According to the companies,
way that they do not shift the absorption into other wavelength the Photobond UV acrylates tested by Delo and Covestro show a
ranges when they are combined with the photopolymer. They highly improved outgassing behavior compared to silicones and
must therefore ensure color fidelity under all conditions. reach their full strength within seconds under UV light. //
Until now, mainly silicones have been used to fix the film layers. Contact and further information:
Silicones are versatile and high-performance materials. However, Susanne Friedel, Covestro, susanne.friedel@covestro.com
6 adhesion 2 I 22
Adhesive from Plastic Bags
On January 1, 2022, a ban was introduced in Germany on disposable plastic carrier bags with a thickness of less than
50 micrometers. However, very thin bags less than 15 micrometers thick are still permitted. An innovative research
approach may allow them to be turned into high-quality adhesive.
and most of them are thrown away and in- groups would improve the adhesion of the
© Filmbetrachter on Pixabay / IVK
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Trends and Events
The many advantages of plastic packaging for replacing multilayer films are already
have contributed to its widespread use in being offered on the market for selected
recent decades and have made it an indis- applications.
pensable part of everyday life. At the same
time, however, packaging waste also con- Customized product properties
tributes significantly to the accumulation
© Fraunhofer IVV
of plastics in the environment. If waste is The recycling of plastic packaging, also in
not properly disposed of, its long persis- the sense of the circular economy and an
tence will hide the risk of accumulation associated equivalent use as the original
of the corresponding materials in the en- product, is therefore also the focus of a pro-
vironment, with negative effects on wild- ject currently being carried out by the Ger- Among other things, the monomaterials films
life and even humans. man Fraunhofer Society. The consortium combine stability and a barrier effect.
Single-grade disposables can be easi- consists of the Fraunhofer Institutes for Or-
ly separated and recycled, provided they ganic Electronics, Electron Beam and Plas- The central idea of the project is to sep-
are disposed of correctly. More problem- ma Technology FEP in Dresden, for Silicate arate the property profile of the polymer
atic are so-called multilayer films, which Research ISC in Würzburg, for Process En- granulate to be extruded from the lat-
are made up of several polymer layers that gineering and Packaging IVV in Freising, er product properties of the film by spe-
are practically inseparable from each oth- and for Environmental, Safety and Ener- cifically modifying the film material af-
er. Due to their outstanding properties, gy Technology UMSICHT in Oberhausen. terwards. Compared to the solutions al-
such composite films are mainly used for Under the coordination of the Fraunhofer ready available, it is possible to increase
packaging in the food sector. IVV, these four institutes are researching the stiffness as required and thus save ma-
For these materials, the only practical op- to develop a completely recyclable mono- terial. For this purpose, technologies are
tion at the end of the product life cycle material film that meets all the require- used that can be applied in-line to the film
is thermal recycling, which, however, is ments of the packaging industry. These in- extrusion. According to the project part-
not an ecologically desirable solution, al- clude mechanical properties, for example ners, this enables the production of recy-
though it is preferable to disposal in sim- to ensure the stability of stand-up pouch- clable films while still maintaining the
ple landfills or even shipping abroad. The es, as well as requirements for the barri- previous production costs. //
focus of current developments is therefore er effect with regard to gases, vapors, and Further information:
on monomaterials. The first approaches aromatic substances. www.ivv.fraunhofer.de
The Goliath manufacturing system, which sign freedom. By adapting the binders and
has been newly developed by the Ger- materials used, the product properties can
man start-up Teu2tec in Gütersloh, ena- also be flexibly adjusted. All products to
bles fast 3D printing of large-format ob- be manufactured can therefore be made to
jects from any type of granulate using the cure either elastically or firmly, the com-
paste extrusion modeling process (PEM). pany adds.
For this purpose, the system uses clas-
© Teu2tec
8 adhesion 2 I 22
speeds of up to 300 mm/s and a mass flow of up to head during the active printing process. The pro-
100 g/s can be achieved. The layer height can be ad- cess technology used makes it possible to interrupt
justed from 3 mm to 12 mm, which not only enables the extrusion during the additive process and to re-
®
fast printing processes, but also – due to the low position the printing head without further printing
layer height – makes it possible to produce optical- paste leaking from the nozzle.
ly complex components. At 2200 x 2200 x 2000 mm, The company says that, since the beginning of
the volume is large enough to be used, for example, 2022, the first printing tests under water have been PRECISE DOSING
to design furniture or complete playground equip- completed. It is already becoming clear that, with
ment for urban development. appropriate binder systems, the process will enable OF SMALLEST
In an initial test series, the team already succeed- the printing of components under water. // QUANTITIES
ed in setting down and repositioning the print More information: https://teu2tec.de
Cleanliness in
Submicrometer and
Atomic Percent Range
Particulate and filmic component cleanliness must be achieved reliably and efficiently in series
production, especially when manufacturing, joining and coating technologies change. In parallel,
requirements are growing due to ever stricter regulatory specifications. In addition to cleaning and
drying processes designed to meet specific requirements and suitable technology, the software and
the cleaning environment must also be adapted accordingly.
Whether production equipment for the bility are extremely high. This not only manufacturing processes is an essential
semi-inductor industry, biotechnology, leads to high demands in terms of pro- criterion due to regulatory specifications.
laser and sensor technology, devices for duction precision of the parts, but also Moreover, there is a trend for miniaturisa-
measuring and analysis technology, com- their cleanliness. For medical technol- tion and functional integration with ever
ponents for accumulators and fuel cells, ogy products such as implants, instru- smaller and more complex components.
optical systems or metal cutting tools, the ments, cannulae and endoscopes, partic- These developments entail that particu-
requirements for performance and relia- ulate and film-type contamination from late cleanliness specifications in the mi-
Figure 1 > The various treatment stations of this individually designed ultrasonic ultrafine cleaning system can be flexibly accessed.
10 adhesion 2 I 22
trum of precision and ultra-fine cleaning
(Figure 1). This enables them to adapt
cleaning processes, their control software
as well as the machinery and ambient con-
ditions to the requirements and applica-
tions on hand.
For selection of the suitable cleaning sys-
tem for a specific task, the first thing
looked at is whether the system is to be
used for pre-cleaning, intermediate clean-
ing or final cleaning. Depending on the
use and cleanliness specifications to be
achieved, the solution may be chamber
or multi-tank immersion machine, a flex-
© Ecoclean
ible ultrasonic multitank machine based
on standardized modules, or a customized
Figure 2 > By combining wet chemical and low-pressure plasma cleaning methods for ultrafine ultrasonics-based ultrafine cleaning sys-
degreasing in a single machine, the surface characteristics required for downstream coating or tem. The cleaning chemicals as well as
bonding are efficiently achieved. the optimal process technologies are also
specifically chosen for the application and
the contaminants to be eliminated. Pro-
cess technologies that may be considered
crometer and even nanometer ranges as of these miniaturized components there include, for example, spraying, high-pres-
well as very stringent requirements re- is also an evolution towards ever larger sure, immersion, ultrasonic or megasonic
garding residual film-like contaminations integrated manufacturing modules. This and plasma cleaning (Figure 2), injection
must be met by more and more industry also creates new challenges for the clean- flood washing, Pulsated Pressure Clean-
sectors. Depending on components and/ ing processes and the machine systems re- ing (PPC) and passivation/preservation,
or applications, outgassing rates for or- quired to implement them. if required.
ganic substances and residual moisture
may also have to be met. The same ap- Plant concepts for cleaning Cleaning processes and systems for
plies in the area of of surface analyses for ultra-high cleanliness
residues of prohibited substances, whose For component cleaning, this results in
limit values are partly in the atomic per- very demanding tasks, which cover the The design of customized ultrasonic mul-
cent range. atomic percent range when it entire production chain. chain. As a full- ti-chamber systems and processes for ul-
comes to surface analyses for residues of range supplier, the companies of the SBS trafine cleaning applications are the core
prohibited substances. For the production Ecoclean Group cover the entire spec- competence of the Switzerland-based com-
© UCM / Gebr. Brasseler
11
Cover Story I Ultra-Fine Cleaning
© Zeiss
Figure 4 > In the immersion/spray rinse tanks specifically developed for ultrafine cleaning processes, the parts are sprayed off as they exit the
bath which enhances the rinsing result.
pany UCM. Key factors to be considered are cy and intensity to the requirements of sures among other things that the speci-
the material and geometry of the parts to different parts to be cleaned. With parts fied dwell times in wash and rinse tanks
be cleaned, the type and quantity of con- that present complex geometries, capillary are precisely observed, and that prior-
taminants, the particulate or film-type structures or porous surfaces, such as for itized sequences – e.g. for very fragile
cleanliness specifications and, where ap- example sintered metal components or ad- parts – can be programmed.
plicable, permitted outgassing rates and ditive manufactured components, the PPC The optimal system and process solu-
maximum acceptable residues of prohib- method comes into play. Features such as tion from a cleanliness and economic ef-
ited substances in the atomic percentage multi-side overflow in all wash and rinse ficiency point of view can be determined
rate. In addition, attention is paid to the tanks as well as the immersion/spray through cleaning trials with original parts
selection of suitable cleaning chemicals rinse technology specially developed for in Ecoclean’s and UCM’s precision clean-
and media supply, for example the use of ultrafine cleaning systems contribute to ing technology centres. //
the use of osmosis or demineralized water. the reliable meeting of very severe clean-
The materials and manufacturing methods liness specifications (Figure 4).
used to build the cleaning system and au- The decision which parts are taken to
tomatic transport system are also select- which wash and rinse tanks as well the
ed with the prevention of dirt build-up, re- part-specific process parameters such as
contamination and cross-contamination al- temperatures, ultrasonic output and fre-
ready in mind. Outfitting with clean room- quency, intensity of PPC, dwell time in
grade components and interfacing with the various wash and rinse tanks, are
clean rooms are also possible (Figure 3). defined during the process development
phase. Depending on the complexity and Contact
Requirements for the process heat absorption capacity of the parts, dry-
development ing is mostly done using infrared or vacu- Ecoclean GmbH
um technology. The resulting part-specif- Monschau (Germany)
Standard equipment installed in precision ic cleaning programs are stored in the ma- Kathrin Gross, Marketing
and ultrafine cleaning systems are mul- chine controller. The software-controlled kathrin.gross@ecoclean-group.net
tifrequency ultrasonic systems that offer implementation of the cleaning sequence www.ecoclean-group.net
flexible adjustment of ultrasonic frequen- plays a decisive role in this context. It en- www.ucm-ag.com
12 adhesion 2 I 22
CREATING TOMORROW’S SOLUTIONS
KEEPING COOL
WITH TIM
How can you keep temperatures in xEV battery applications reliably under control? Gap fillers based on silicones
are the material of choice. Especially for high-volume automotive applications, WACKER now offers a new
generation of gap fillers: they combine the advantages of a cost-effective lightweight gap filler with maximal
thermal conductivity, while their high-level dispensing performance is well suited for use in an automotive
production environment. No matter what challenges e-mobility may bring in the future, keep cool with WACKER
thermal interface materials (TIM).
Adhesive formulations catalysts. The recycling of used adhesives, Product design suitable for the
on the other hand, is as sensible as the re- circular economy
The 'adhesive' itself can also contribute cycling of printing ink in paper recovery,
to resource efficiency. In terms of circu- which is why the adhesive should have During the disassembly of adhesively
lar economy-friendly adhesive formula- little effect on the joined part after sep- bonded products, cohesion-related influ-
tions, recyclates can be suitable raw ma- aration. ences are preferred [2]. These are par-
terials for adhesives. Since adhesives are ticularly targeted on the basis of local
typically needed in medium quantities, re- Renewable raw materials stimuli such as heating and mechanical
cyclates made from polyethylene tereph- overloading. With chemically curing ad-
thalate (PET) from bottles, polyamide (PA) Furthermore, bio-based adhesives are al- hesives, softening of the polymer adhe-
from used textiles or polyurethanes (PUR) ready being used today in certain mass sive layer can also be achieved by swell-
from mattresses or car upholstery, for ex- applications [1]. However, many of the ing. Another possibility is the degrada-
ample, can be partially chemically reac- necessary property profiles of synthet- tion of the polymer network. The user of
ted with polyols. Oligomers with alcohol ic adhesives cannot yet be reproduced the adhesively bonded product and the
end groups are formed in the process. If by bio-based adhesives, which still lim- recycler must be aware of the disassem-
necessary, even the 'stickies' can be used its their applicability. Nevertheless, ad- bly option provided by the manufacturer
here, which are produced during paper re- hesives are an ideal product group for (Figure 1). This also applies analogously
cycling and partly come from paper adhe- the use of renewable raw materials. The to repair processes. Digital information
sives. These can be used as raw materials moderate quantities are sufficient so that sources make it technically possible to
for various adhesives such as reactive and the raw material synthesis could be eco- pass on these specifications. In the me-
non-reactive polyurethanes, hot-melt ad- nomically feasible and the ecological im- chanical recycling of plastic parts, it is
hesives, epoxy resins, especially cationic pact large enough. The development of helpful if the adhesive is as compatible as
curing ones, or polyacrylates. renewable raw materials for widespread possible with the plastics. As a necessary
Consistent raw material quality is an es- utilisation in adhesives is well on its way, supplement to mechanical recycling and
sential prerequisite here. Alternatively, but also requires enormous research to as a preferred alternative to purely en-
plastic waste can be used to produce a reach the level of fully synthetic adhe- ergetic recycling, chemical (raw materi-
powder that can be used as a lightweight sives. Degradable adhesives based on al) recycling opens up a forward-looking
filler for adhesives instead of mineral com- various renewable materials such as perspective for adhesively bonded joints
ponents such as chalk or quartz powder. starch, cellulose or proteins have long with plastic joining partners – including
The binding of CO 2 under mild condi- been used industrially, for example in those that may still be contaminated with
tions would be made possible by suitable food labelling. adhesive and paint [3].
14 adhesion 2 I 22
Disassembly processes of
adhesively bonded products
© Fraunhofer IFAM
account in this early phase of product de-
velopment. In the case of a high number
of variants, small dimensions and high
quantities, dismantling (shredding) can
be a variant of the disassembly process, Figure 1 > Process steps and players in the disassembly of sustainably adhesively bonded
which enables sorting by material type. structures
Large component dimensions with a high
dead weight of the sorted components fa-
vour the use of mechanical loosening of struction: On the one hand, it contrib- struction feasible. Consistent lightweight
adhesively bonded joints. Accessibility for utes to constructive lightweight construc- construction enables material savings and
disassembly aids must be ensured by de- tion through adhesive bonding technolo- increased resource efficiency in all phases
sign. Power-intensive processes can be gy realisation of targeted structures, e.g., of the product life cycle.
mechanised or supported by automatic stiffening elements such as ribs. On the The design of a product consisting of sev-
machines or robots. In this context, how- other hand, by joining different materi- eral components that can be separated
ever, the construction of product-specific als that are used according to the specif- from each other again in the so-called dif-
disassembly lines is largely untested. De- ic requirements in the component, adhe- ferential construction method has further
taching by heat input is a means of dis- sive bonding in multi-material construc- advantages in addition to the lightweight
mantling adhesively bonded products, tion can make material lightweight con- construction potential: In terms of repa-
both in combination with mechanical de-
taching and independently. Disassembly
through media influence is particularly
suitable for water-based adhesive disper- Disassembly option Type of components Comment
sions and is already being used success-
fully both in the handicraft sector (e.g. Dismemberment Wide range of different Suitable for series
component geometries production, in use
dissolving wallpaper) and for mass-pro-
duced products (e.g. removing labels from
Small component
deposit bottles). dimensions
Adhesive bonding technology has long
been an indispensable, eco-balance-rel- High numbers of pieces
evant factor for the realisation of light- Mechanical separation / Large component Need for research:
weight construction through multi-mate- disassembly of the dimensions automation in large-scale
rial design. In the future, adhesive bond- adhesively bonded joint production
ing technology will also be a key to en- High dead weight of the
suring that products can be repaired and single-material
components
recycled. Accordingly, adhesive bonding
does not prevent the disassembly of prod- Separation / disassembly by Stand-alone disassembly
ucts, but offers a promising possibility for heat input tool, but can also be
combined with mechanical
detaching the joined parts [4].
separation / disassembly
Separation / disassembly Can also be combined with
Product designs
through targeted media mechanical separation /
influence disassembly
Adhesive bonding technology can be © Fraunhofer IFAM
seen as an 'enabler' of lightweight con- Table 1 > Disassembly processes of adhesively bonded products
15
Studies and Analyses I Green Deal and Adhesives Industry
© Fraunhofer IFAM
© Fraunhofer IFAM
Figure 2 > Use of digitalisation in the development of Figure 3 > The product-related translation in the interplay of the players in
adhesively bonded products the adhesive bonding technology life cycle
rability, should an element of the product surface treatment processes can be used for twins, for example, enable the selection
be damaged during the product use phase, this, which specifically adjust or improve of an optimally suitable disassembly pro-
it can be replaced without having to re- the adhesion between the surfaces of the cess. Adhesively bonded products can be
place the entirety of the product. Design joined parts and the adhesive [2]. Know- fitted with an RFID chip, via which all
adjustments, even minor ones such as cus- ledge of the optimised properties can then data on the materials and adhesives can
tomising products according to customer in turn be taken into account in the design. be retrieved for disassembly. The high ex-
requirements, can be made in the exist- After precise knowledge of the load cas- perimental verification effort required for
ing process chain without having to build es as well as the surface properties of the the process integration of adhesive bond-
a completely new product line with the parts to be joined, the next logical step is ing technology into a production process
corresponding infrastructure. Combined an application technique that is adapted can also be reduced with the help of suit-
with an increasing degree of digitalisa- to the adhesive used and the specific re- ably calibrated, digital material and com-
tion, adhesive bonding technology will en- quirements of the product, such as process ponent models. Verifiable lifetime predic-
able modern, future-proof process chains times, geometry, etc. If optimised applica- tions that reduce maintenance costs, lead
and products. tion techniques are used to apply exactly to a more resource-efficient replacement
the required amount of adhesive only at of wear parts and significantly increase
Dimensioning and adhesive points defined by the design, the amount the safety gain require the development of
application of adhesive used can be reduced and op- structural health monitoring (SHM) sys-
timally utilised. This results in material tems [6] [7]. The necessary sensor technol-
In the product development process, the and weight savings and also increases re- ogy and the ways in which this informa-
amount of resources used must always be source efficiency. tion can be stored and read are the subject
critically questioned. This concerns the of current research activities.
question of which quantity of which ma- Digitisation and adhesive bonding In addition to their material properties, ma-
terial is actually needed for the product to technology terials are used in adhesively bonded joints
fulfil its function safely. The definition of in conjunction with their data and espe-
realistic requirement profiles is decisive Digitalisation supports decisions in the cially metadata. In terms of a holistic view,
for this. To prevent overdimensioning of use of adhesive bonding technology. Digi- this makes the inclusion of 'end of life' pro-
adhesively bonded joints, the requirement tal tools (Figure 2) and the availability of cedures already visible in the product life
profiles on which the design of an adhe- material and process-related data along cycles 'development' and 'manufactur-
sively bonded joint is based must be de- the entirety of the process chain within ing'. Communication of FAIR (meta) data
fined realistically, i.e., adapted to the load the framework of FAIR data concepts [5] (Figure 3) across generations is ensured by
cases that actually occur. will in future allow developers of adhesive- the standardised summary of textual-con-
The use of adhesive bonding technology ly bonded joints to identify environmental- ceptual and spatial-pictorial information in
can contribute to increasing the longevity ly friendly optima in terms of material, cost ontologies, which also include the temporal
of products, i.e. the extension of the prod- and energy efficiency across the entire life dimension. In contrast to the past, histor-
uct life cycle phase 'utilisation'. This can cycle as part of a holistic approach. ically developed material or actor-related
also be achieved by developing adhesive- Cyberphysical systems digitise prod- information will be transmitted digitally in
ly bonded products with optimised ageing uct and process information and pass it the future. Whereas materials have been in
resistance. Among other things, optimised on along production processes. Digital the foreground up to now, their inseparable
16 adhesion 2 I 22
linkage with data for all product life cycle hesively bonded products will form future Fraunhofer IFAM, Fraunhofer Verlag, Stuttgart
phases will gain in importance in the fu- value creation cycles. The holistic consid- (2020), 258 – 263, Circular economy appropriate
ture. Not only the ecological value, but also eration of adhesively bonded products product design, DOI 10.24406/ifam-n-603186,
the economic value of these connections with regard to ecological improvements https://www.ifam.fraunhofer.de/Press_releases/
far exceeds the material value, especially along value chains or cycles is made pos- Circular economy and adhesive bonding tech-
in the adhesive bonding technology sense. sible by the life cycle assessment (LCA) as nology (Access December 02, 2021)
currently the most comprehensive assess- [5] Turning FAIR into reality, Final Report and
Outlook ment method for environmental impacts. Action Plan from the European Commission
The view 'from the material to the safe Expert Group on FAIR Data, European Commis-
The circular economy and life cycle as- product' combines the aspects of safety sion Expert Group on FAIR Data, Directorate-
sessment are already implicit in adhesive- and long-term stability with the require- General for Research and Innovation. European
ly bonded products today. In the future, ments of circular economy and eco-bal- Commission (2018)
it will be interactively experienced by ance effectiveness in the sense of sustain- [6] www.dgzfp.de/Fachaussch%C3%BCsse/
the respective actor – be it in production, ability of products. In this area of conflict, Zustands%C3%BCberwachung (access: April
in application, in repair or in the careful adhesive bonding technology has the nec- 30, 2020)
disposal of adhesively bonded joints – in essary technological and ecological per- [7] A. Trilaksono, N. Watanabe, H. Hoshi, A. Kon-
the aspects relevant to him and made ac- formance capacity and thus offers the po- do, Y. Iwahori, S.-I. Takeda: Continuous Dam-
cessible for comparative considerations. tential to become the leading joining tech- age Monitoring of a Thin Composite Structural
In this way, the view of sustainable ad- nology of the 21st century. Adhesive bond- with Mismatched Stiffener in a Combined Joint
hesive bonding technology includes the ing technology, the circular economy and Using Fiber Bragg Grating under Tension and
three equally supporting pillars of sus- life cycle assessment are therefore not con- Three-Point Loading. OJCM 03 (03) 2013, 63 –
tainability: Economic, ecological and so- tradictory. On the contrary: they comple- 87, doi: 10.4236/ojcm.2013.33008
cial aspects come into play in sustainable ment each other. //
products in a holistic life cycle approach.
Adhesive technology has the potential to
meet these new requirements with tech-
nical innovations. In the future, value The Authors
chains of adhesively bonded products References
must be considered holistically in the [1] B. Mayer, A. Groß (Hrsg.): In Kreis- Prof. Dr. Andreas Groß
product life cycles 'manufacture', 'utili- laufwirtschaft und Klebtechnik – eine Studie Head of the department “Workforce Training
sation' and 'end-of-life'. This includes, in des Fraunhofer IFAM, Fraunhofer Verlag, Stutt- and Technology Transfer”
particular, making the 'end-of-life' con- gart (2020) 240 – 249, Nutzung nachwachsend- – corresponding author –
cept of adhesively bonded products an er Rohstoffe in Klebstoffen (andreas.gross@ifam.fraunhofer.de)
integral part of product development as [2] A. Groß, B. Mayer, K. Haag: Circular Economy
early as the product planning and de- and Adhesive Bonding Technology, Part 2. ad- Prof. Dr. Bernd Mayer
sign phase. These new challenges result- häsion KLEBEN+DICHTEN 19 (2022) [1] 16 – 20 Director of the institute “Adhesive Bonding
ing from closed-loop thinking therefore [3] U. Tillmann: Nachhaltigkeit braucht mehr Technology and Surfaces”
require even more intensive communi- Chemie, nicht weniger (2018), www.vci.de/
cation and cooperation in the future and themen/energie-klima-rohstoffe/klimaschutz/ Dr. Katharina Haag
thus even closer networking of all play- vci-hauptgeschaeftsfuehrer-utz-tillmann- Group Manager in the department “Polymeric
ers along value chains. Raw materials auf-presskonferenz-eroeffnung-achema- Materials and Mechanical Engineering”
and adhesive manufacturers, adhesive us- 2018-nachhaltigkeit-braucht-mehr-chemie-
ers, product manufacturers, end custom- nicht-weniger.jsp (access: April 30, 2020) Fraunhofer Institute for Manufacturing
ers and recyclers as part of the 'adhesive [4] B. Mayer, A. Gross (Ed.), Circular Economy Technology and Advanced Materials IFAM,
bonding' system along the life cycle of ad- and Adhesive Bonding Technology – a study by Bremen (Germany)
Adhesives and Sealants I UV Polymerization
UV-Moisture-Curing
Adhesive Systems for
the Automotive and
Electronics Industries
UV adhesives cure in seconds and achieve high initial adhesion directly after crosslinking.
This makes them particularly interesting for high-volume applications. However, not every
component geometry allows pure UV polymerization. New possibilities are opening up with
UV-moisture-curing acrylic systems that do not require any thermal post-treatment.
Adhesives are becoming increasingly pop- vent-free, one-component adhesives. The ture post-curing can be influenced by the
ular in all industrial sectors, serving a chemical reaction of the adhesive can be relative humidity.
wide range of applications from large-vol- divided into two functional principles.
ume potting applications to micro-dosed The primary crosslinking of these spe- Technical properties and resulting
bonding. For products and manufacturing cially formulated UV adhesives is based process possibilities
concepts requiring high speed curing to on free-radical crosslinking polymeri-
accommodate large production volumes, zation, which is started by excitation of In order to highlight the areas of applica-
UV adhesives are typically used because the photoinitiator with a curing light of tion of dual-curing acrylate systems in the
they cure in seconds. This adhesive tech- the appropriate wavelength and intensity. next section, it is first necessary to take a
nology is in demand due to the nature of In the system addressed here, the use of closer look at the physical properties in the
the adhesives’ cured and uncured physi- LED wavelengths of 365 nm, 405 nm or the liquid and solid state. The modifiable vis-
cal properties. High adhesion is achieved UV-A spectrum is the appropriate process cosity range of these UV acrylates can ex-
immediately after polymerization. UV ad- parameter for targeted curing. This pho- tend from low-viscosity products to stable,
hesives can provide controlled flow and toinitiator, acting as a starter molecule in- gel-like formulations. Low-viscosity, New-
dispensing precision. However, not eve- corporated into the adhesive formulation, tonian-behavior products, for example,
ry component geometry allows pure UV initiates radical crosslinking of mono- are shear rate-independent here and can
polymerization. In areas shadowed from mers and the acrylate groups of the iso- be used with consistent viscosity ranges.
UV light, a secondary curing step is re- cyanate acrylates with the acrylate base This is particularly important for the user
quired to ensure complete crosslinking within seconds, forming a polymer struc- to know if he has to change process pa-
of the adhesive. This article discusses ture. As a result, an initial bond strength rameters without affecting the viscosity
the properties and functional principles is built up. and thus the flow behavior of the adhesive.
of UV-moisture-curing acrylate adhesive The isocyanate groups of the isocyanate Structural viscous, shear-thinning adhe-
systems. They offer a secondary curing acrylates can then be further crosslinked sives have the advantage that the user of
option without the need for downstream in the secondary mechanism, without fur- these systems can, for example, signifi-
thermal processes. ther energy input, by the humidity in the cantly influence the flow properties with
air. As shown in the table (Table 1), the the parameters of temperature and shear
How UV-moisture-curing acrylate final bond strength can be achieved af- rate (pressure, metered volume, needle di-
systems work ter a few days by this secondary mecha- ameter, etc.). For example, it is possible to
nism. Thus, UV-curing systems can fully meter a stable adhesive with a high thixot-
Dual-cure acrylate systems with second- cure even without direct irradiation in the ropy index specifically through its shear-
ary moisture curing capability are sol- shadow zones. The curing speed of mois- thinning properties as an edge bonder
18 adhesion 2 I 22
Hardness shore D Bond strength (N/Chip)*
tion at break and E modulus, they can be
After UV-curing** 15 22 used in a wide range of applications. Flex-
+1 day moisture-curing*** 22 37 ible systems with high elongation at break
+2 day moisture-curing 40 96 are used especially for films or shock-re-
+3 day moisture-curing 50 102 sistant applications. Stiffer systems with
high bond strength and low elongation
+4 day moisture-curing 56 122
at break, on the other hand, are suitable
+5 day moisture-curing 60 131
for strong connections between structur-
+6 day moisture-curing 63 140 al components. Dielectric strength of over
+7 day moisture-curing 64 143 25 kV/mm in some cases and good com-
+8 day moisture-curing 64 142 patibility with flux residues are further ad-
*Ceramic resistor chip 1206 (3.2 x 1.6 mm). The chip, which has no light transmission, is vantages of these systems when used in
attached to the PCB with adhesive, UV radiation only hardens the adhesive on the edge and the automotive and electronics industries.
fixes the chip. The adhesive under the mold is cured by moisture over time. The electronics-compatible formulation of
**UV-curing: UVA lamp, Fe-doped, 60 mW/cm2, 30 s the systems brings with it an electronic
***Moisture-curing : 25 °C, 50 % relative humidity grade ion content, which prevents the ad-
© Panacol hesive from causing corrosion effects on
Table 1 > Progression of moisture-curing over time – bond strength and hardness plateau after metallic surfaces.
7 days indicating cure is complete.
Areas of application in the
automotive and electronics
for capacitors on printed circuit boards markers is possible, which can be excited industries
(Figure 1). with short-wave light. As a further alter-
The rapid achievement of stability af- native, it is possible to add a color addi- Components are becoming smaller and
ter the dispensing process then prevents tive to the UV moisture post-crosslinking smaller. The number of electronic com-
the adhesive from flowing away horizon- acrylate systems. However, this has an in- ponents is increasing and the demands on
tally. The adhesive can then be cured in fluence on the absorption behavior of the adhesive systems are becoming greater.
seconds in an inline process using UV intensity used, which is reflected in the Dual-curing UV acrylates with the capa-
light. Uncured monomers in shadow are- depth of cure and curing speed. bility of moisture post-curing have a ma-
as between and below the condensers are The isocyanate acrylates are specially de- jor advantage here. They enable the pro-
crosslinked downstream stress-free by veloped for high adhesive strengths on duction of high quantities per hour (unit
moisture post-curing. For optical control, plastics, metal and glass. Due to the dif- per hour) without downstream oven pro-
the additional incorporation of fluorescent ferent properties in terms of CTE, elonga- cesses and thermal stress effects.
© Panacol
19
Adhesives and Sealants I UV Polymerization
Figure 3 > Corrosion protection with Vitralit UD8050 MV F on welds between aluminum support and copper strand
20 adhesion 2 I 22
sist environmental effects. This can af- ple, they can provide corrosion protection speed and the ability to run a fully auto-
ford maximum protection for capacitors, as encapsulation compounds for welds on mated, in-line process. This opens many
connectors and pins. UV/moisture curing cell contact systems, or as strand protec- possibilities for creative bonding process-
acrylate adhesives are available in formu- tion or stiffening (Figure 3). Since shadow es and process designs. The versatile UV/
lation options that differ in terms of flex- zones often occur here due to the opaque moisture curing acrylate systems meet a
ibility, modulus of elasticity and tear re- metal substrates, dual-curing acrylate wide range of applications and industries,
sistance. They offer a broad based spec- technology is a very good bonding meth- particularly automotive, consumer and in-
trum of properties for the optimal pairing od for fast manufacturing processes and dustrial electronics. //
of adhesive and performance. inline quality control.
The use of isocyanate acrylates also of- The potting process of assembled PCBs
fers advantages when potting electronic and housing materials for interior sen-
boards into housings, as well as plugs and sors must be fast due to the high vol-
connectors (Figure 2). Faster cycle times umes being produced. The combination
can be achieved, as conventional potting of a jet dispense process and the UV/mois-
compounds rely on slower room tempera- ture curing acrylate adhesives is the per-
ture curing or a combination of room tem- fect solution for high speed potting. With
perature cure and thermal curing for bet- the appropriate LED curing light, the ad-
ter crosslinking. hesives will cure in one to two seconds The Authors
In the field of electromobility, there are and create resilient bonds between PCBs
more and more interfaces to electronic and popular package materials, such as Eike Leipold
applications, as the number of sensors, PC, PBT and PA. – corresponding author –
controllers and electronic connections is (eike.leipold@panacol.de)
multiplying immensely. Assembly of in- Conclusions and outlook Katharina Jörg
dividual components is being replaced by Heiko Fauser
integration of modular sub-assemblies. Fast curing, process-reliable solutions
Moisture-curing acrylate systems are also are achievable with UV/moisture curing Panacol-Elosol GmbH
used in new battery technology. For exam- acrylate adhesives. These adhesives offer Steinbach / Taunus (Germany)
ZSK EXTRUDERS.
CONTINUOUS PRODUCTION
OF ADHESIVES.
+ Broad application range
+ Consistently high product quality
+ Optimal throughput rates
+ Maximum efficiency
Continuous production of hot melt and pressure sensitive adhesives. Coperion’s ZSK twin screw extruders allow
the use of a wide range of different recipe components and ensures consistently high product quality without
batch-to-batch variations. www.coperion.com/adhesives
Applications I Thermally Conductive Adhesives
Silicone-Based Thermal
Interface Materials for
Electric Vehicles
Efficient thermal management is needed for traction batteries, electric motors and power electronics
in electric vehicles. Silicone-based thermal interface materials are particularly suitable in that role,
since they are extremely long-lasting, and their shore hardness values and flow properties are
customizable.
Peter Walter
After a tentative start, electromobility is electronics generate heat as well. To avoid filler loads well in excess of 90 %. The fill-
taking off. According to a current study heat-related damage or failure, the ther- ers are typically metal oxides, such as alu-
from Pricewaterhouse Coopers, more than mal energy released needs to be dissipat- minum oxide, which ensures that the TIM
twice as many electric cars were sold in ed quickly and effectively. remains electrically insulating, a proper-
2021 than in the previous year, with three Thermally conductive gap fillers play a ty which is essential for use in close prox-
million electrically powered vehicles new- key role in dissipating excess heat, fill- imity to live components.
ly approved for use in China alone. Sales ing the space between the assembly that Silicone-based TIMs, i.e., heat-conducting
figures rose in Europe as well: by 76 % needs to be temperature-controlled and materials comprising a matrix of cured or
in England and by a full 83 % in Germa- the heat exchanger or heat sink, and thus uncured silicones, have a long, success-
ny [1]. Analysts estimate that every oth- lowering the thermal transfer resistance. ful track record in power electronics as-
er small car will be electric by 2026. By In so doing, they enhance thermal cou- semblies. Silicones are widely known for
2035, electrically driven cars may have fi- pling between the components (Figure 1). their aging resistance – even upon expo-
nally unseated those powered by combus- Thermal interface materials (TIMs) are sure to high or low temperatures. Unlike
tion engines [2]. therefore becoming increasingly attrac- organic polymers, they undergo very little
Efforts in the automotive industry to take tive to car makers as they develop elec- change in physical or technical properties
electromobility to the next level have tric vehicles for mass production. over the temperature range -45 to +180 °C
shifted into high gear. A few hurdles have and above. They are also more flame-re-
to be overcome on road to mass produc- Thermally conductive silicone sistant than organic polymers. A further
tion of electric vehicles, however. One ma- products characteristic of silicones is their low sur-
jor challenge is how to effectively dissi- face energy. Liquid silicones, for instance,
pate the heat generated in the many com- The choice of TIM and its type of product will wet nearly all solid surfaces.
ponents while the battery is being charged – whether paste, curable gap filler, adhe- This makes silicone-based thermal gap
and when the vehicle is on the road. sive, prefabricated pad – depends on the fillers easier to work with, because they
This kind of thermal management is espe- application and the prospective operating will fill even the tiniest irregularities in
cially critical for the battery serving as the conditions. the substrate surfaces. Aging resistance
power source. Lithium-ion batteries only TIMs can be commonly made from poly- and flame resistance are also the main ar-
deliver their best performance at temper- mers containing a considerable amount of guments in favor of using thermally con-
atures between 20 and 35 °C. Consequent- thermally conductive inorganic substanc- ductive silicone products in vehicles fitted
ly, to ensure acceptable performance and es as filler. The base polymer may be an with all-electric drives – even for assem-
life span, they need to be prevented from organic polymer or a silicone. Achieving blies operating at temperatures which do
overheating. The electric motor and power the desired thermal conductivity requires not necessarily require silicone.
22 adhesion 2 I 22
Easy application
© Wacker
thermal coupling between the parts, but
also bond them together. Silicone pastes
maintain their consistency after appli- Figure 1 > Gap fillers are used to replace the air – a poor heat conductor – in the gap between
cation. In practice, their applications are the heat source and heat sink, creating a thermally conductive connection.
© Wacker
Figure 2 > A bead of silicone-based gap filler is applied onto a power electronics module during the dispensing process.
23
Applications I Thermally Conductive Adhesives
© Wacker
Figure 3 > If the thermally
conductive silicone resin Silres
H 68 TC is heated to the
encapsulating temperature of
60 °C usually employed in the
electric motor sector, its viscosity
drops to values below
10,000 mPa·s – at this
temperature trickle application is
possible.
limited to small substrates and thin film cope with high-speed, highly automated veloped gap fillers from the Semicosil 96x
thicknesses. Thicknesses after pressing car production processes. The relevant pa- TC series, which can be dispensed rapidly
should not exceed 100 to 150 µm. rameters are the molecular chain lengths and permit short cycle times, even where
Silicone-based gap fillers and silicone ad- and the type of liquid silicone polymers, large substrates are mass produced.
hesives undergo a change of consistency as well as the size and shape of the filler A further source of heat in electric vehi-
as a result of a platinum-catalyzed, addi- particles. Wacker has conducted extensive cles is the power electronics. Their task is
tion-curing reaction. This yields a relative- tests to characterize the functionality of to transform and regulate the electric cur-
ly soft, elastically deformable pad in the the products in its TIM portfolio – and has rent. Inverters, for example, convert direct
gap that fills out the contours of the sur- fine-tuned their workability in collabora- current into alternating current and vice
faces exactly. Such gap fillers can even tion with major equipment makers. versa, while voltage converters change the
out surfaces with roughness values in the The highly loaded silicone systems are level of the voltage. Power module com-
millimeter range, which occur especial- much more resistant to sedimentation ponents such as IGBTs (integrated gate bi-
ly with large substrates. This distinguish- than conventional products and can be polar transistors) can reach temperatures
es them from prefabricated pads, which supplied in 200-liter drums. They can be greater than 100 °C in operation. The pow-
have a specific thickness and are therefore readily conveyed over long distances on er losses can exceed 100 W/cm² – more
unable to accommodate large tolerances. suitable handling equipment, can be dis- than the surface heating power density
Pourable, thermally conductive potting pensed at high rates (up to 50 ml/s) and of a stovetop turned to high. Overheating
compounds are used for complex surfac- support a rapid, automated assembly at may damage the sensitive semiconductor
es, where they transport the heat to the low, reproducible pressure. The result is structures and so lead to aging and even-
heat sink and, at the same time, protect the a throughput rate of up to 6 kg material tually to component failure.
surfaces from environmental factors. Such per minute. Such failures can be prevented by active-
products are applied by dipping or trickling. ly cooling the printed board and IGBT as-
Applications in electric cars sembly. At operating temperatures above
Optimized for electromobility 150 °C, silicone-based TIMs are the mate-
Electric vehicles currently use lithium-ion rials of choice for thermal coupling, be-
The Wacker chemical group has taken batteries as energy storage. These are usu- cause organic polymers would be unable
products with a successful track record ally installed below the passenger com- to withstand the heat. Depending on the
in power electronics assemblies and has partment, where they occupy most of the design, effective component cooling can
used them to develop numerous silicone- floor space. be achieved with thermally conductive
based TIMs for the electromobility sec- A thermally conductive gap filler is needed gap fillers from the Semicosil 96xx TC se-
tor. The company is continually optimiz- to provide thermal coupling between the ries or heat-sink pastes, e.g., Semicosil
ing these products, and especially their battery modules and the heat-dissipation Paste 40 TC.
workability, to meet the requirements of system. It must be aging-resistant to pre-
mass production. vent premature battery failure and must Silicones also cool electric motors
The primary requirement here has been lend itself to rapid application to large sur-
to adjust the rheological properties of the faces, making workability key for this fill- In conventional vehicles, the necessary
paste-like compounds so that they can er. For such applications, Wacker has de- torque is provided by a combustion en-
24 adhesion 2 I 22
gine, but in electric vehicles the power is H 68 TC. This product has such a low vis- electronics and electric motors, function re-
delivered by a compact, high-performance cosity at 60 °C that it can easily be trick- liably for long periods of time. //
three-phase motor. Heat is again generat- led into the gap between hairpins and sta-
ed and needs to be dissipated for various tor laminations (Figure 3). Tests are also
reasons: on the one hand, the wire enam- being conducted to establish whether the
els coated onto the stator windings need heat can be transported along the copper
to be protected against heat-induced ag- hairpins to the heat sinks via a thermally References
ing and, on the other, permanent-mag- conductive silicone encapsulant such as [1] PricewaterhouseCoopers: Electric Vehicle
net synchronous motors contain magnet- Elastosil RT 7xxx TC. Sales Review Full Year 2021, online: www.strate-
ic materials made from rare earth metals gyand.pwc.com/de/en/industries/automotive/
and can lose their magnetization at tem- Conclusions and outlook electric-vehicle-sales-review-full-year-2021.ht-
peratures above 130 °C. The heat dissipat- ml, access: 17.02.2022
ed from the electric motor can be readily A number of development and testing ap- [2] Boston Consulting Group, Why Electric Cars
deployed elsewhere – to heat the passen- proaches are being applied to thermal man- Can’t Come Fast Enough (April 2021), p. 1
ger compartment and the windshield, for agement in electric cars. It will be some
instance. This not only protects the bat- time before standards have been accepted
tery, but also enables longer driving rang- and technical solutions established once
es, especially in winter. Manufacturers of and for all. However, it is already apparent
electric motors are currently working on that silicone-based thermal interface mate- The Author
different heat-dissipation concepts. It is rials will play a key role in future thermal
still unclear which one will prevail. regulation, as they can be readily adapted Peter Walter
However, it is clear that thermally conduc- to a wide variety of processing and manu- (peter.walter@wacker.com)
tive silicone products can play a key role. facturing methods, making them the TIM Senior Marketing Manager
One solution, for example, could be to dis- of choice for future mass production of Industrial Solutions
sipate the stator’s waste heat via the mo- electric vehicles. Silicones thus go a long
tor laminations with the aid of thermally way toward ensuring that key components Wacker Chemie AG
conductive silicone resins such as Silres of electromobility, such as batteries, power Munich (Germany)
25
Products
© Scheugenpflug GmbH
to 20 ml and two-component materials from 0.1 to 40 ml up to ten
times more quickly than comparable solutions on the market. Pow-
erful servo drives ensure high dispensing speeds and an optimized
power transfer. This makes the dispenser, which works without a
diaphragm and is particularly pressure stable, suitable for highly
automated production lines. To achieve the high dispensing speeds Highest dispensing speeds even with highly abrasive materials
even with high-viscosity thermally conductive heat transfer adhe-
sives, the DosP DP2001 is fitted with a special static mixing tube
that can withstand the highest dispensing pressures without plas-
tic deformation. 4 ml. This high dispensing accuracy with fast cycle times is made
possible by a new displacement-free valve system, which is also
Highly precise dispensing of even the smallest volumes suitable for the use of abrasive materials due to its robustness. Both
dispensing solutions from Scheugenpflug feature process monitor-
The low-volume dispenser DosPL DPL2001 has been specially de- ing and access to relevant process parameters. The sensor technol-
veloped for the smaller and smaller dispensing quantities that are ogy and software continuously monitor the dispensing pressure
required due to the ongoing miniaturization of electronic compo- for each component. //
nents. The dispensing quantity includes one-component materials
from 0.003 ml to 2 ml and two-component materials from 0.006 to More information: www.scheugenpflug-dispensing.com
More information:
www.loctiteAM.com
www.henkel.de
26 adhesion 2 I 22
New Structural Bonding Adhesive for Electric
Vehicle Batteries
Dymax has presented its latest adhesive for the assembly of elec-
tric vehicle batteries. The extremely low-shrinkage UV adhesive
called Dymax 9501-F has been specially designed for fixing cy-
lindrical battery cells to plastic bases and holders and, according
to the manufacturer, has excellent bond strength to common sub-
strates such as PC, PC/ABS, nickel-plated steel, and aluminum.
It cures tack-free in seconds when exposed to UV or visible light
and is also LED curable at a wavelength of 385 nm. As Dymax
points out, the fast curing time allows assembled components to
27
Products
color of the material can be dyed in other color shades for the
greatest possible visual design freedom. //
Further information: www.remmers.com Application of the product MB FL 2K as a tile adhesive
More information:
Addibond polymer helps replace screws, bolts or rivets. www.solvay.com
28 adhesion 2 I 22
w w w.ad h aesi on.c om
IndustryContacts
CONNECTING MATERIALS 2022
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TABLE OF CONTENTS
TITLE
Driven by a strong pioneering spirit and
w w w.ad h aesi on .c om
with a well-founded process know-how the
IndustryContacts Scheugenpflug company evolved from a
manufacturer of casting resin technology to a
CONNECTING MATERIALS 2022
world leading provider of premium adhesive
bonding, dispensing and potting solutions
over the past 30 years. The product portfolio
ranges from compact but efficient manual
work stations to custom-tailored, modular
production lines for automotive and industrial
electronics, medical technology and consumer Scheugenpflug GmbH
applications. As part of the Atlas Copco Group Gewerbepark 23
the company is able to provide technical service 93333 Neustadt/Donau
and after sales support to its customers with a Germany
global footprint. Scheugenpflug strives for
innovation forged by collaborative efforts with Phone +49 9445 9564 0
a broad network of material manufacturers Fax +49 9445 9564 40
and partners to maximum production quality, www.scheugenpflug-dispensing.com
cycle time and process reliability. sales.de@scheugenpflug-dispensing.com
www.adhaesion.com 3
adhesion IndustryContacts Connecting Materials
Category overview
Fillers and pigments 6 Manual application systems for 2K adhesives and sealants 16
4 www.adhaesion.com
adhesion IndustryContacts Connecting Materials
Categories A-Z
foil coating 10 Fully automatic application systems for 1K adhesives and sealants 15
www.adhaesion.com 5
adhesion IndustryContacts Connecting Materials
Company index
RAW MATERIALS
Polymers
6 www.adhaesion.com
adhesion IndustryContacts Connecting Materials
Company index
www.adhaesion.com 7
adhesion IndustryContacts Connecting Materials
Company index
Jowat SE
Ernst-Hilker-Str. 10-14 E. Epple & Co. GmbH
D-32758 Detmold Dichtstoffe//Klebstoffe//Gießharz
Phone: +49 5231 7 49-0 Sealants//Adhesives//Cast resins
Fax: +49 5231 7 49-105 Hertzstr. 8
info@jowat.de D-71083 Herrenberg
www.jowat.de Phone: +49 7032 9771 0
Panacol-Elosol GmbH
Stierstädter Str. 4 Fax: +49 7032 9771 60
D-61449 Steinbach/Taunus info@epple-chemie.de
Dr. Detlef Heindl www.epple-chemie.de
Phone: +49 6171 6202 0
Fax: +49 6171 6202 590
info@panacol.de
www.panacol.de
merz + benteli ag
Freiburgstr. 616
CH-3172 Niederwangen/Bern
Simon Bienz
Phone: +41 31 980 4848 Panacol-Elosol GmbH
Fax: +41 31 980 4849 Stierstädter Str. 4
info@merz-benteli.ch D-61449 Steinbach/Taunus
Sika Deutschland GmbH www.merz-benteli.ch Dr. Detlef Heindl
Kleben und Dichten Industrie Phone: +49 6171 6202 0
Stuttgarter Str. 139 Fax: +49 6171 6202 590
D-72574 Bad Urach info@panacol.de
Phone: +49 7125 940 7692 www.panacol.de
verkauf.industry@de.sika.com
www.sika.de/industrie
8 www.adhaesion.com
adhesion IndustryContacts Connecting Materials
Company index
Polyurethane adhesives
Jowat SE
Ernst-Hilker-Str. 10-14
D-32758 Detmold Panacol-Elosol GmbH
Phone: +49 5231 7 49-0 Stierstädter Str. 4
Fax: +49 5231 7 49-105 D-61449 Steinbach/Taunus
info@jowat.de Dr. Detlef Heindl
www.jowat.de Phone: +49 6171 6202 0
Fax: +49 6171 6202 590
ATP adhesive systems AG info@panacol.de
Sihleggstr. 23 www.panacol.de
CH-8832 Wollerau Kömmerling Chemische Fabrik GmbH
Daniel Heini Zweibrücker Str. 200
Phone: +41 43 888 15 15 D-66954 Pirmasens
Fax: +41 43 888 15 10 Dr. Gert Heckmann
info@atp-ag.com Phone: +49 6331 56 2337
www.atp-ag.com Fax: +49 6331 56 1999
info@koe-chemie.de
www.koe-chemie.de Sika Deutschland GmbH
Kleben und Dichten Industrie
Stuttgarter Str. 139
Bodo Möller Chemie GmbH D-72574 Bad Urach
Senefelderstr. 176 Phone: +49 7125 940 7692
D-63069 Offenbach am Main verkauf.industry@de.sika.com
Phone: +49 69 8383 26 0 www.sika.de/industrie
Fax: +49 69 8383 26 199
info@bm-chemie.de Sika Deutschland GmbH Hot-melt adhesives
www.bm-chemie.de Kleben und Dichten Industrie
Stuttgarter Str. 139
D-72574 Bad Urach
Phone: +49 7125 940 7692
verkauf.industry@de.sika.com
Bühnen GmbH & Co. KG www.sika.de/industrie Bodo Möller Chemie GmbH
Hinterm Sielhof 25 Senefelderstr. 176
D-28277 Bremen D-63069 Offenbach am Main
Phone: +49 421 5120 0 Acrylic adhesives
Phone: +49 69 8383 26 0
Fax: +49 421 5120 260 Fax: +49 69 8383 26 199
info@buehnen.de info@bm-chemie.de
www.buehnen.de www.bm-chemie.de
www.adhaesion.com 9
adhesion IndustryContacts Connecting Materials
Company index
merz + benteli ag
Freiburgstr. 616
Kömmerling Chemische Fabrik GmbH CH-3172 Niederwangen/Bern
Zweibrücker Str. 200 Simon Bienz
D-66954 Pirmasens Phone: +41 31 980 4848
Dr. Gert Heckmann Fax: +41 31 980 4849
Phone: +49 6331 56 2337 info@merz-benteli.ch IMCD Deutschland GmbH
Fax: +49 6331 56 1999 www.merz-benteli.ch Konrad-Adenauer-Ufer 41-45
info@koe-chemie.de D-50668 Köln
www.koe-chemie.de Dr. Heinz-J. Küppers
Phone: +49 2835 444 244
Fax: +49 2835 444 245
heinz.kueppers@imcd.de
www.imcdgroup.com/adhesives
Wakol GmbH
Bottenbacher Str. 30 ADHESIVES FOR BONDING GLASS/
D-66954 Pirmasens CERAMICS
Phone: +49 6331 8001 131
Sika Deutschland GmbH Fax: +49 6331 8001 890
Kleben und Dichten Industrie Epoxy resin adhesives
info@wakol.de
Stuttgarter Str. 139 www.wakol.de
D-72574 Bad Urach
Phone: +49 7125 940 7692
verkauf.industry@de.sika.com technical adhesive foils
www.sika.de/industrie
Dispersion adhesives
MS polymer adhesives
10 www.adhaesion.com
adhesion IndustryContacts Connecting Materials
Company index
Panacol-Elosol GmbH
Polyurethane adhesives Stierstädter Str. 4
D-61449 Steinbach/Taunus
Dr. Detlef Heindl
Phone: +49 6171 6202 0 Bodo Möller Chemie GmbH
Fax: +49 6171 6202 590 Senefelderstr. 176
Bühnen GmbH & Co. KG info@panacol.de D-63069 Offenbach am Main
Hinterm Sielhof 25 www.panacol.de Phone: +49 69 8383 26 0
D-28277 Bremen Fax: +49 69 8383 26 199
Phone: +49 421 5120 0 info@bm-chemie.de
Fax: +49 421 5120 260 Silicones www.bm-chemie.de
info@buehnen.de
www.buehnen.de Acrylic adhesives
www.adhaesion.com 11
adhesion IndustryContacts Connecting Materials
Company index
Panacol-Elosol GmbH
Stierstädter Str. 4
D-61449 Steinbach/Taunus
Dr. Detlef Heindl
Phone: +49 6171 6202 0
Fax: +49 6171 6202 590 Wakol GmbH
info@panacol.de Bottenbacher Str. 30
www.panacol.de Kaneka Belgium D-66954 Pirmasens
Nijverheidsstraat 16 Phone: +49 6331 8001 131
B-2260 Westerlo Fax: +49 6331 8001 890
Jo Indesteege info@wakol.de
Phone: +32 14 25 45 20 www.wakol.de
jo.indesteege@kaneka.be
www.kaneka.be/products/liquid-polymers
for application in the packaging and
graphic industry
Sika Deutschland GmbH
Kleben und Dichten Industrie
Stuttgarter Str. 139
D-72574 Bad Urach
Phone: +49 7125 940 7692
verkauf.industry@de.sika.com Lohmann GmbH & Co. KG
www.sika.de/industrie Irlicher Str. 55
D-56567 Neuwied
OTHER ADHESIVES Phone: +49 2631 34 0 ATP adhesive systems AG
Fax: +49 2631 34 6661 Sihleggstr. 23
for general application in the info@lohmann-tapes.com CH-8832 Wollerau
transport, automotive industry and www.lohmann-tapes.com Daniel Heini
its suppliers, as well as in machine Phone: +41 43 888 15 15
Fax: +41 43 888 15 10
and equipment building info@atp-ag.com
www.atp-ag.com
Jowat SE
Ernst-Hilker-Str. 10-14
D-32758 Detmold
Phone: +49 5231 7 49-0
Fax: +49 5231 7 49-105
info@jowat.de
www.jowat.de
12 www.adhaesion.com
adhesion IndustryContacts Connecting Materials
Company index
OTHER ADHESIVES
for application in the packaging and
graphic industry Bodo Möller Chemie GmbH
Senefelderstr. 176
D-63069 Offenbach am Main
Phone: +49 69 8383 26 0
Kaneka Belgium Fax: +49 69 8383 26 199
Nijverheidsstraat 16 info@bm-chemie.de
B-2260 Westerlo www.bm-chemie.de
Jo Indesteege
Lohmann GmbH & Co. KG Phone: +32 14 25 45 20
Irlicher Str. 55 jo.indesteege@kaneka.be
D-56567 Neuwied www.kaneka.be/products/liquid-polymers
Phone: +49 2631 34 0 Bühnen GmbH & Co. KG
Fax: +49 2631 34 6661 Hinterm Sielhof 25
info@lohmann-tapes.com D-28277 Bremen
www.lohmann-tapes.com Phone: +49 421 5120 0
Fax: +49 421 5120 260
info@buehnen.de
www.buehnen.de
Lohmann GmbH & Co. KG
Irlicher Str. 55
D-56567 Neuwied
Phone: +49 2631 34 0
Fax: +49 2631 34 6661
info@lohmann-tapes.com
Soudal NV www.lohmann-tapes.com
Everdongenlaan 18-20 Jowat SE
B-2300 Turnhout Ernst-Hilker-Str. 10-14
Phone: +32 14 42 42 31 D-32758 Detmold
info@soudal.com Phone: +49 5231 7 49-0
www.soudal.com Fax: +49 5231 7 49-105
info@jowat.de
www.jowat.de
Soudal NV
Everdongenlaan 18-20
Wakol GmbH B-2300 Turnhout
Bottenbacher Str. 30 Phone: +32 14 42 42 31
D-66954 Pirmasens info@soudal.com
Phone: +49 6331 8001 131 www.soudal.com Lohmann GmbH & Co. KG
Fax: +49 6331 8001 890 Irlicher Str. 55
info@wakol.de D-56567 Neuwied
www.wakol.de Phone: +49 2631 34 0
Fax: +49 2631 34 6661
for application in the building info@lohmann-tapes.com
www.lohmann-tapes.com
industry Wakol GmbH
Bottenbacher Str. 30
D-66954 Pirmasens
Phone: +49 6331 8001 131
Fax: +49 6331 8001 890
info@wakol.de
www.wakol.de
www.adhaesion.com 13
adhesion IndustryContacts Connecting Materials
Company index
Soudal NV
Everdongenlaan 18-20
B-2300 Turnhout
Phone: +32 14 42 42 31 Wakol GmbH
info@soudal.com Bottenbacher Str. 30
www.soudal.com Soudal NV D-66954 Pirmasens
Everdongenlaan 18-20 Phone: +49 6331 8001 131
Butyl sealants B-2300 Turnhout Fax: +49 6331 8001 890
Phone: +32 14 42 42 31 info@wakol.de
info@soudal.com www.wakol.de
www.soudal.com
Silicones
Silane terminated sealants
Bodo Möller Chemie GmbH
Senefelderstr. 176
D-63069 Offenbach am Main
Phone: +49 69 8383 26 0 Kömmerling Chemische Fabrik GmbH
Fax: +49 69 8383 26 199 Zweibrücker Str. 200
info@bm-chemie.de D-66954 Pirmasens
www.bm-chemie.de Dr. Gert Heckmann
Phone: +49 6331 56 2337
Fax: +49 6331 56 1999
Kaneka Belgium info@koe-chemie.de
Kömmerling Chemische Fabrik GmbH Nijverheidsstraat 16 www.koe-chemie.de
Zweibrücker Str. 200 B-2260 Westerlo
D-66954 Pirmasens Jo Indesteege
Dr. Gert Heckmann Phone: +32 14 25 45 20
Phone: +49 6331 56 2337 jo.indesteege@kaneka.be
Fax: +49 6331 56 1999 www.kaneka.be/products/liquid-polymers
info@koe-chemie.de
www.koe-chemie.de
Sika Deutschland GmbH
Kleben und Dichten Industrie
Polysulphide sealants Stuttgarter Str. 139
D-72574 Bad Urach
Phone: +49 7125 940 7692
verkauf.industry@de.sika.com
Kömmerling Chemische Fabrik GmbH merz + benteli ag www.sika.de/industrie
Zweibrücker Str. 200 Freiburgstr. 616
D-66954 Pirmasens CH-3172 Niederwangen/Bern
Dr. Gert Heckmann Simon Bienz
Phone: +49 6331 56 2337 Phone: +41 31 980 4848
Fax: +49 6331 56 1999 Fax: +41 31 980 4849
info@koe-chemie.de info@merz-benteli.ch
www.koe-chemie.de www.merz-benteli.ch
14 www.adhaesion.com
adhesion IndustryContacts Connecting Materials
Company index
SEALANTS
Silicones
Scheugenpflug GmbH
Gewerbepark 23
Panacol-Elosol GmbH D-93333 Neustadt a.d. Donau
Stierstädter Str. 4 Phone: +49 9445 9564 0
D-61449 Steinbach/Taunus Fax: +49 9445 9564 40
Dr. Detlef Heindl sales.de@scheugenpflug-dispensing.com
Phone: +49 6171 6202 0 www.scheugenpflug-dispensing.com
Soudal NV
Everdongenlaan 18-20 Fax: +49 6171 6202 590
B-2300 Turnhout info@panacol.de
Phone: +32 14 42 42 31 www.panacol.de
info@soudal.com
www.soudal.com
Unitechnologies SA – mta®
APPLICATION SYSTEMS Bernstr. 5
Manual application systems for 1K CH-3238 Gals
WIWA Wilhelm Wagner GmbH & Co. KG Stefan Eidam
adhesives and sealants Gewerbestr. 1-3 Phone: +41 32 338 80 80
D-35633 Lahnau info@unitechnologies.com
Robert Lischke www.unitechnologies.com
Phone: +49 176 1695 1131
info@wiwa.de
www.wiwa.com
www.adhaesion.com 15
adhesion IndustryContacts Connecting Materials
Company index
Unitechnologies SA – mta®
Bernstr. 5
CH-3238 Gals
Sulzer Mixpac AG Industry, Stefan Eidam
Construction, Meter Mixing Phone: +41 32 338 80 80
Ruetistr. 7 info@unitechnologies.com
CH-9496 Haag www.unitechnologies.com
Phone: +41 81 772 20 00
Fax: +41 81 772 20 01
H&H Maschinenbau GmbH sales.industry@medmix.com
Industrieweg 6 www.medmix.swiss
D-32457 Porta Westfalica
Toni Hausdorf
Phone: +49 571 798 77 0
Fax: +49 571 798 77 19
sales@hh-klebetechnologie.de
www.hh-klebetechnologie.de ViscoTec Pumpen- u. Dosiertechnik
WIWA Wilhelm Wagner GmbH & Co. KG
Gewerbestr. 1-3 GmbH
D-35633 Lahnau Amperstr. 13
Robert Lischke D-84513 Töging a. Inn
Phone: +49 176 1695 1131 Phone: +49 8631 9274 0
info@wiwa.de Fax: +49 8631 9274 300
www.wiwa.com mail@viscotec.de
Scheugenpflug GmbH www.viscotec.de
Gewerbepark 23
D-93333 Neustadt a.d. Donau Semi-automatic application systems
Adhesive application robots
Phone: +49 9445 9564 0 for 2K adhesives and sealants
Fax: +49 9445 9564 40
sales.de@scheugenpflug-dispensing.com
www.scheugenpflug-dispensing.com
Balti AG
Unitechnologies SA – mta® Sihlbruggstr. 3
Bernstr. 5 CH-6340 Baar
CH-3238 Gals Urs Sachs
Unitechnologies SA – mta® Stefan Eidam Phone: +41 41 560 1180
Bernstr. 5 Phone: +41 32 338 80 80 Fax: +41 41 560 1190
CH-3238 Gals info@unitechnologies.com info@balti.ch
Stefan Eidam www.unitechnologies.com www.balti.ch
Phone: +41 32 338 80 80
info@unitechnologies.com
www.unitechnologies.com
Scheugenpflug GmbH
Gewerbepark 23
D-93333 Neustadt a.d. Donau
ViscoTec Pumpen- u. Dosiertechnik Phone: +49 9445 9564 0
GmbH Fax: +49 9445 9564 40
Amperstr. 13 sales.de@scheugenpflug-dispensing.com
ViscoTec Pumpen- u. Dosiertechnik D-84513 Töging a. Inn www.scheugenpflug-dispensing.com
GmbH Phone: +49 8631 9274 0
Amperstr. 13 Fax: +49 8631 9274 300
D-84513 Töging a. Inn mail@viscotec.de EQUIPMENT FOR MATERIAL
Phone: +49 8631 9274 0 www.viscotec.de TRANSFER, MIXING AND METERING
Fax: +49 8631 9274 300
mail@viscotec.de Pumps
www.viscotec.de Fully automatic application systems
for 2K adhesives and sealants
Scheugenpflug GmbH
Gewerbepark 23 ViscoTec Pumpen- u. Dosiertechnik
D-93333 Neustadt a.d. Donau GmbH
Phone: +49 9445 9564 0 Amperstr. 13
Fax: +49 9445 9564 40 D-84513 Töging a. Inn
sales.de@scheugenpflug-dispensing.com Phone: +49 8631 9274 0
www.scheugenpflug-dispensing.com Fax: +49 8631 9274 300
mail@viscotec.de
www.viscotec.de
16 www.adhaesion.com
adhesion IndustryContacts Connecting Materials
Company index
www.adhaesion.com 17
adhesion IndustryContacts Connecting Materials
Company index
Fraunhofer-Institut für
Fertigungstechnik und Angewandte
Materialforschung IFAM
E. Epple & Co. GmbH Klebtechnik und Oberflächen
Dichtstoffe//Klebstoffe//Gießharz Weiterbildungszentrum Klebtechnik
Sealants//Adhesives//Cast resins Wiener Str. 12
Hertzstr. 8 D-28359 Bremen
D-71083 Herrenberg Phone: +49 421 2246 402
Dr. Hönle AG – UV-Technology Phone: +49 7032 9771 0 Fax: +49 421 2246 605
Head of Hönle Group Fax: +49 7032 9771 60 kleben-lernen@ifam.fraunhofer.
Lochhamer Schlag 1 info@epple-chemie.de www.kleben-in-bremen.de
D-82166 Gräfelfing www.epple-chemie.de www.bremen-bonding.com
Florian Diermeier
Phone: +49 89 85 60 80
Fax: +49 89 85 60 8148 Quality management Construction and calculation
uv@hoenle.de
www.hoenle.de
18 www.adhaesion.com
adhesion IndustryContacts Connecting Materials
Companies A-Z
A F I
www.adhaesion.com 19
adhesion IndustryContacts Connecting Materials
Companies A-Z
K P U
Unitechnologies SA – mta®
Bernstr. 5
Panacol-Elosol GmbH CH-3238 Gals
Krahn Chemie Deutschland GmbH Stefan Eidam
Grimm 10 Stierstädter Str. 4
D-61449 Steinbach/Taunus Phone: +41 32 338 80 80
D-20457 Hamburg info@unitechnologies.com
Marcus Wedemann Dr. Detlef Heindl
Phone: +49 6171 6202 0 www.unitechnologies.com
Phone: +49 17 153 72 490
marcus.wedemann@krahn.eu Fax: +49 6171 6202 590
www.krahn.eu info@panacol.de V
www.panacol.de
L
S
20 www.adhaesion.com
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