78. Which of the following polyhalogen compounds is 80.

IUPAC name of DDT is

mainly responsible for ozone layer depletion? (a) 1,1-bis (4-chlorophenyl)-2,2,2-trichloroethane
(a) DDT (b) 1,2-bis (4-chlorophenyl)-1,1,1-trichloroethane
(b) Freons (c) 2,2-bis (4-chlorophenyl)-1,1,1-trichloroethane
(c) lodoform (d) 2,1-bis (4-chlorophenyl)-1,
(d) Carbontetrachloride 1,1-trichloroethane
79. Natural ozone layer is unbalanced due to 81. Toxicity of DDT towards fish is due to
(a) cloudiness of poisonous gases (a) chemical stability of DDT
6) presence of rain in the atmosphere (b) it is deposited and stored in fatty acid
(c) initiation of radical chain by freon (c) fats solubility of DDT
(d) All of the above (d) All of the above

Special Format Questions

I More Than One Correct
Option
82. Choose the correct alternatives from the following. Ch/FeCly
(a) Me B r is more reactive than
85.
AI
A Na/ether B
II

Me Choose the correct options

towards Sy lreaction
Br
reaction.
regarding above
Me
(a) A is chlorobenzene
b) Br
is more reactive than
(b) B is biphenyl
Me towards S 1reaction (c) Step-I is aromatic electrophilic substitution reaction
Br (d) Step-Il is eliminatiion reaction
(c) Benzyl bromide is more stable than allyl bromide
II. Statement Based
d) tert-butyl bromide on treatment with
elimination product
KOHalc. gives Questions
83.
CH3 Fe
Grignard reagent is a very versatile initiating compound 86. + X2
for the variety of organic reactions. Dark
Choose the correct
options regarding Grignard reagent.
(a) It is prepared by treating alkyl halide with CH3 CHh
metal in dry ether magnesium
b) The carbon atom inGrignard reagent is more
electronegative than Mg-atom
(C) Grignard reagent reacts with ethyl alcohol to For the above reaction
give
corresponding alkene as a
major product I.X =C; ortho
(d) C-Mg bond in Grignard reagent is non-polar and and para-isomers can be separate
out
ionic
II. X =
; reaction does not occur due to high
84. Choose the correct alternatives from the reactivity of iodine
following.
(a) Benzyl chloride undergoes rapid solvolysis than IIL. X ; reaction with fluorine is reversibie.
=

chlorobenzene Select the most

(b) 2-phenyl-1-chloroethane undergoes slower solvolysis appropriate option with respe ct to
correct statements.
than chlorobenzene
(c) Allyl chloride is more rapid than butyl chloride (a) Only II
towards (b) Only II
solvolysis
(d) Order of solvolysis of various halogen containing ()OnlyIII
Compounds (d) All of the above
 A r T t R 10 Haloalkanes and Halodren

ler the following haloarenes,

Consider.
I. Assertion-Reason Type Questions
CI CI CI
C Directions (Q. Nos. 91-109) Inthe following
questions a stulement of Assertion (A) folloued by a
CI statement of Reason (R) is given. Choose the correct
CI answer out of the following choices.
I (a) Both A and R are correct; R i_ the correct
explanation of A
b p ofI
is more than that ofI1 correct
(6) Both A and R are correct; R is not the
()bp
of. is least among the given explanation of A
(i)
ofIl is highest among the given (c) A is correct; R is incorrect
is greater than that ofII
mp ofl (d) R is correct; A is incorrect
option. halides from
Choose
the correct
91. Assertion (A) In the preparation of alkyl other
(a)OnlyI (b) II, III and IV alcohols, thionyl chloride preferred
is over

(c)Only IV (d) Both I and IV reagents.

during
the following alkyl halides Reason (R) The other two products produced
Consider the reaction except alkyl halide, are escapable
gases.
C.H C,H;Cl, CH,Br, CH,F
II Assertion (A) H,PO, is used during
the reaction of
TV 92.

Undergoes faster dehydrohalogenation than alcohol with KI.

A.
() and (TV). Reason (R) H,PO, is a non-oxidising agent.
B. ( ) Undergoes lower dehydrohalogenation halide which is formned
than ().
93. Assertion (A) Yield of an alkyl is low.
C. TV) has least ability to undergo
by the free radical halogenation
lead to
Reason (R) Free radical halogenation
dehydrohalogenation. formation of mixture of isomeric
mono and

Choose the correct option. polyhaloalkanes.

a Only A (6) A,B and C
94. Assertion (A) Bromides and iodides develop colour
and C (d) Only C
(c) Both B when exposed to light.
following reaction, colourless when pure.
89. Look at the Reason(R) Alkyl halides are
hv bromides
2CHCl+O2 2cOCl,+2HCl 95. Assertion (A) Boiling points of chlorides,
considered to bethan higher
A B and iodides are

I. Bis phosgene gas and is poisonous. hydrocarbons.

IL A is stored in closed dark coloured
bottle. Reason (R) Due to greater polarity and higher
molecular mass, the intermolecular
forces of attraction
the freon refrigerant
II A is used for the production of derivative as compared to
R-22.
are weaker in halogen
Choose the correct option.
hydrocarbon.
soluble in
(a) Both I and II b) Both II and II
96. Assertion (A) Haloalkanes are very slightly
(d) All of these water.
c) Only II
for intermolecular attraction between
0. Which of the following statements is/are correct Reason (R) Newsolvent molecules have much more
haloalkanes and
DDT?
the mosquito that spreads strength than intermolecular attraction between
. It is very effective against haloalkanes molecules.
malaria. 97. Assertion (A) SN 2 mechanism is accompanied by
animals.
I It is easily metabolised by
racemisation.
I. It is highly toxic forfish.
Reason (R) Nucleophile attaches itself on
Choose the correct option.
(b) Both II and
II the side opposite to one where halogen atom is
(a) Both I and II
(d) Both I
and III present.
(c) Only II
 98. Assertion (A) Sl reaction is accompanied by 108. Assertion (A) Chloroform is replaced by eth
racemisation. anaesthetic.

Reason (R) Carbocation is formed in this reaction, Reason (R) Inhaling chloroform vapours denra
and attack of nucleophile can be from either side of the central nervous system.
the leaving group. 109. Assertion (A) Exposure of ultraviolet rays te
of
99. Assertion (A)
haloarene.
Snl mechanism is nuled out in case
causes the skin cancer, disorder and
immune system.
IUman,
disrupt the
Reason (R) Phenyl cation is formed as a result of self Reason (R) Carbon tetrachloride deplets t
ionisation which is not stabilised by resonance.
layer.
deplets the ozo
100. Assertion (A) Me 0 Cl reacts faster with
IV. Matching Type Questions
water than Me Cl 110. Match the following Column I (statement) to
Reason (R)-1-cffect of Me ois Column II (corresponding halide) and choose the
correct option from the codes given below,
more than that of Me ^a
Column II
101. Assertion (A) It is necessary to avoid traces of
Column II
A. Halogen atom is bonded to an 1. Aryl halide
moisture from Grignard reagent. sp-hybridised carbon atom next to an
Reason (R) Grignard reagent reacts with water and aromatic ring.
forms hydrocarbon. B. Halogen atom is bonded to an 2 Vinylic halide
sp-hybridised carbon atom of
102. Assertion (A) tert-butylbromide undergoes carbon-carbon double bond.
Wurtz reaction to give 2, 2, 3, 3-tetramethylbutane.
C. Halogen atom is bonded to 3. Benzylic
Reason (R) In Wurtz reaction, alkyl halides react
sp -hybridised carbon atom of an halide
with sodium in dry ether to give hydrocarbon aromatic ring.
containing double the carbon atoms that present in the
halide. Codes
A B
103. Assertion (A) Bond cleavage in haloarene is difficult
(a) 1
than haloalkane.
6) 3
Reason (R) Phenyl carbocation is more stable. c) 3 2
104. Assertion (A) Presence of nitro group at ortho or (d) 1 2 3
para position increases the reactivity of haloarene 111. Match the following common name in Column Io e
towards nucleophilic substitution. IUPAC name in Column II and choose the corect
Reason (R) Nitro group being an electron option from the codes given below.
withdrawing group decreases the electron density
over the benzene ring Column I Column I

A. Bromoform 1. 1-bromo-2,2-dimethyl propane

105. Assertion (A) Electrophilic substitution reactions in
haloarene occur slowly and under drastic conditions. B. Vinyl chloride 2. Chlorophenylmethane
Reason (R) Haloarene are activated as compared to C. Benzyl chloride 3. Tribromomethane
benzene. D. Chloroform 4. Chloroethene
106. Assertion (A) Nitration of chlorobenzene leads to the E. neo-pentylbromide 5. Trichloromethane
formation of ortho and paranitro chloro benzene.
Reason Codes
(R)-NO, group is a o, p-directing group A B C D E
107. Assertion (A) Chlorine is an ortho-para (a) 3 4 5 2
directing
group in electrophilic aromatic substitution reaction. (b) 2
(c) 3 4 2
Reason (R) Chlorine is an electron withdrawing
group. (d) 1 2
 M a t c h
t n e
a l

kyl halide reactin with

k y .

Iwiththeirrespective reagent given in

Column
gen
n Colum
amn.
substituted
Il and choose the product Codes
A
cormect option C
the
codes given below. (a) 2 3
(b) 1
Column I
Column I1 (c) 2
(Reagent)
.
(Substituted product) (d) 1
RH i
16.
following conditions given in Column
KCN

Match the
2. RCN
B ApCN

with Column II and choose the correct option tron

C KNO
3. RNC the codes given below.
4. R-0-N-O Column I1I
D . LiAIH, Column II
5. R-NO, OH
E AgNO

1. NaOH,
Wes

C 443 K, H
B
3 5
2
4
NO2 NO2
3 41 5
2 4 5 CI OH
d3
NO
stch the following columnr I which represents
M a t c h

statements to the Column II representing B. 2. NaOH,

368 K, H
nTesponding compounds.

Column I
NO2 NO2
Column II

A. The cormpounds that rotates the 1. Enantiomers OH

plane polarised light to the right, i.e. NO2 0N NO;
clockwise. ON Warm

R The compounds that rotate the plane 2. Dextrorotatory

C. O - O 3. HO

light to the left, i.e.

polarised
anti-clockwise. NO NO2
C. The stereoisomers related to each 3. Leavorotatory
oher as non-superimposable mirror Codes
images A B C
(a) 3 1
Codes 3
(b)
A B C 2
2
(c)
(a)3 1
0)1 2 3
(d)3 2

116. Match the reactions given in Column I with the types

c)2 3 1
(02 1 3 of reactions given in Column II and choose the
the correct option fom the codes given below.
AMatch the Column I representing alkyl halide with
the correct
Salement given in Column II and choose Column I Column II
opion from the codes given below. OH
Column II
Column I
I. Sy2orelimination +NaOH
A. 1. Electrophilic
Primary alkyl halide of
depending upon strength addition
base/ nucleophile
NO2 NO2
B. 2. Prefer Sy 2 reaction ****

Decondary alkyl halide B. CH-CH=CH, +HBr- 2. Electrophilic

3. S y l o r elimination aromatic
C.Tertiaryalkyl halide depending upon
stability of CH-CH-CH substitution
carbocation o r more
Br
substituted alkene.
 Column L Column I Directions (Q. Nos. 119-120)In the quess
the compounds in increasing
orderng
C. CH3-CH-I CH3-CH-OH 3. Saytzeff arrange of rate o
elimination reaction towards nucleophilic substitution.

OH CI CI ÇI
O,N O)NO
119. (O O
Fe/Cl2
NO2 NO2
4. Nucleophilic B C
D. aromatic (a) C< B<A
-C CI
substitution (b) B< C <A
(c) A < C <B
(d) A <B<C

C CI CI
E. CHCH, ÇHCH,ale KOH, 5. Nucleophilic CH
substitution (Sy 1) 120.
Br

CH,CH-CHCH
Codes CH3 CH
A B C
A B C D E
(a) 2 5 4 (a) A <B <C
4 2 3 (b) B<A<C
()2 5 1 4 3 (c)C<B<A
(d) A < C<B
(d) 2 1 4 S 3

Directions (Q. Nos. 121-122) Answerthe

V. Passage Based Questionss questions based on the paragraph given below.
Directions (Q. Nos. 117-118) Answer the questions Many polyhalogen compounds have many
on the basis of the following reaction. applications in industry and agriculture. Among
these compounds some compounds have many
CH3 harmful effects also.
OH+ H.C Br (CH), C-OH +B Such as higher levels of methylene chloride in air
cause dizziness, nausea, tingling and numbness in
CH3 the fingers and toes.
117. Which of the following statements is/are correct about 121. Name the compound which is employed as a
the mechanism of this reaction? solvent for fats, alkaloids, iodine and other
(a) Carbocation will be formed as an intermediate in the substances.
reaction (a) Dichloromethanee
(b) Step I is slowest and reversible (b) Trichloromethane
(c) Rate of reaction depends upon concentration of only
(c) Triiodomethane
alkyl halide
(d) Tetrachloromethane
(d) All of the above
122. Which of the following compound is used as an
118. Which ofthe following statements is/are correct about organic insecticide?
the reaction? (a) Chloroform
(a) It is an Sy 2reaction
b) Freon-12
b) Tertiary alkyl halide undergo Sn lreaction very fast
(c) Carbon tetrachloride
(c) Order ofreactivity for Sy Ireaction 1> 2°> 3*
(d) DDT
(d) None of the above