DISTRICT LEVEL PREPARATORY EXAMINATION 2023

Max. Marks : 70
Time :3-15 Hrs. I PUC Chemistry (34)
Instructions:
i. The question paper has four parts. All the four parts are compulsory
PART-A carries 20 marks, each question carries one mark.
PART- B carries 8 marks. Each question carrles two marks
marks
PART-C carries12 marks. Each question carries three
PART-D carries 30 marks. Each question carries five marks
wherever necessary Use log table and
ii. Write balanced chemical equations and draw diagrams
simple calculators if necessary (use of scientific calculator is not allowed)

PART-A
1x15 15
ISelect the correct option from the given choices.
1. Solid in which all the domains are aligned in same direction is
a) Ferromagnetic b) Ferrimagnetic c)Anti-ferromagnetic d) Diamagnetic
2. Solubility of gas in liquid increases with
a) Increase in temperature b) decrease in temperature c) decrease in pressure d) none of these
3. 10mL of liquid A is mixed with 10OmL of liquid B. If it shows negative deviation from Raoult's law then
the volume of resultant solution after mixing A and B is
a) 20 mlL c) 20.2 mL
b) 20.1 mL d) 19.9 mL
4. How much Faraday of electricity is required to deposit one mole of Siiver from Silver chloride?
a) 3F b) 1F c) 3F d) 4F
5. The order of reaction in which the unit for both rate constant and rate of reactions are same is
a) Zero b) First c) Second d) Third
6. In the coagulation of negative sol, among the following ions one having highest flocculating power is
a) Ba2 b) Na1 c) Al3 d) K1
7. The refining method for semiconductors is
a) Electrolytic refining b) Zone refining c) Liquation d) Vapour phase refining
8. The noble gas which can diffuse through rubber and glass is
a) Radon b) Helium c) Xenon d) Krypton
The element which has maximum unpaired electrons in ground state is
9
a) Sc b) V c)Cr d) Mn
10. Denticity of EDTA is
a) 6 b) 2 c) 4 d) 3
11. 3° alkyl halides are practically inert to substitution by S,2 mechanism because of
(a) insolubility (b) instability (c)inductive effect (d) steric hindrance
12. Reaction of phenol with dilute HNO, gives
(a) ortho and meta nitrophenol (6) trinitrophenol
(c) ortho and para nitrophenol (d) meta and para nitrophenol
13. Aldehydes having no a-hydrogen atoms undergo
(a) Aldol condensation (b) Reimer-Tiemann reaction (c) Cannizzaro's reaction (d) none of the above
14. Aniline is - basic than methylamine

(a) more (b) less (c) equally (d) none

15. The number of -

CONH- bonds presents in a tripeptide is

(a) one (b) three (c) two (d) four

Chemistry
 brackets:
from those given In the
by choosing the appropriate word 1x5-5
F l in the blanks

[second, natural gas, shrink, Aspirin, C,H NC] solution containing

more than 0.9% NaCl solution
placed in an aqueous
16. The size of blood cell when
the reaction is
will-- s- then the order of
2.3 X10-mol-L
17. The rate constant k ofa reaction is =

source of Helium.
18. The main commercial
forms
19. Ethyl chloride on heating with AgCN
both analgesics and antipyretic.
20. acts as
PART-B 4x 2=8
two marks.
Each question carrles
Il Answer any four of the following.
of FCC
21. Calculate the number of particles conductivity?
on conductivity and molar
22. decreasing concentration
What is the effect on
for effective collision.
23. Write any 2 factors responsible
24. Give reason
state
) Actinoids show variable Oxidation
(i) Zr and Hf have almost identical radii
25. How is methoxy ethane prepared by Williamson's ether synthesis?
26. Explain Clemmensen reduction with example .

27. What are artificial sweetening agents? Give an example.

28. What are cationic detergents? Give an example.
PART-C
4 x 3 12
following. Each question carries three marks
V Answer any four of the
29. In the extraction of Aluminium by electrolysis

) Give the composition of electrolyte

(ii) Write over all reaction (3)
(Gii) Mention the role of Cryolite (3)
30. Write the balanced equations
for the manufacture of HNO, by Ostwald's process.
anomalous behavior of Oxygen.
31. a) Mention any two for the
reasons
(2+1)
is in H,O not in H,S.
b) Give reason. Hydrogen bonding
32. Complete the following equations.
() 2 NaOH+C NaCl+ +HO
(i) Na SO, +2 HCI 2 NaCl+H,O+
-

(3)
(ii) Br,+3 F- transition metals
of number of complexes by
33. (a) Give 2 reasons for the formation large
(b) Write formula to calculate spin only magnetic
moment (2+1)
manufactured by chromite ore? (3)
34 How is pure potassium dichromate and magnetic property of the complex
35. On the basis of valence bond theory, explain hybridization, shape
(3)
COF Werner's theory.
36. (a) Write any two postulates of
(b) Write IUPAC name of [Pt{NH,),(H,0) Ci]. (2+1)
PART-D
Each question carries five marks. 3x5 15
V Answer any three of the following.
37. a) Calculate the packing efficiency
of face centered cubic lattice. (3)
stoichiometric defect is shown by the following solids?
b)Which type of
() AgCIi) KCI (2)
 38. a) 1.00g of a non -electrolyte solute is dissolved in 50 g of benzene lowers thefreezing point of benzene
Find the molar mass of
by 0.4 K.The freezing point depression constant for benzene is 5.12 K Kg mol.
solute. (3)
b) State Henry's law (1)
76.48 K bar and 88.84 K bar
C) The Ky Values for Nitrogen gas (N.) at 293K and 303K are
Nitrogen gas is more
respectively. Among these two given temperatures, at which temperature
soluble in water? (1)
39. a) Calculate the EMF of the cell reaction
Mg(s)+Cu(0.0001 M) Mg:*(0.001M) +Cu(s). (3)
Given E Mg/Mg) -2.37 V. E°(Cu"ICu = 0.34 V)
b) Write the equation for cathodic and anodic reactions of lead storage battery. (2)
rate equation for the rate constant of a
first order reaction. (3)
40. a) Derive the integrated
b) Explain the effect of catalyst on activation energy of reaction with grapn. (2)
41. a) Give any two differences between Ilyophilic and lyophobic colloids. (2)
Name the Zeolite catalyst used to convert alcohols to gasoline
b) What is shape selective catalysis ?
in petroleum industry (2)
for Freundlich adsorption isotherm. (1)
c) Write the expression
V Answer any three of the following. each question carries five marks 3 x 5= 15
a) Write equation for the conversion of tertiary butyl bromide into tertiary butyl alcohol in S1
42
mechanism. (2)
b) Mention the major product in the following

i) CHBr +Mg D oH
(i) 2- Bromopentane (2)
c) Haloarenes are less reactive towards nucleophilic substitution reaction than halo alkanes. Give
one reason. (1)
43. a) Write 3 steps of mechanism of acid catalysed dehydration of ethanol to ethene 3)
b) Among alcohols and phenols which is more acidic ? Why? (2)
44. a) Write the equation for the reaction between benzaldehyde and concentrated
NaOH solution. Name the reaction. (2)
b) Explain the preparation of carboxylic acids from
Grignard's reagent (2)
c) Name the product formed when Benzoic acid is heated with ammonia. (1)
45. a) Explain Hoffmann's bromamide degradation for the preparation of Methanamine. (2)
b) What is Hinsberg reagent ? Write general formula of diazonium salt (2)
c) Give the lUPAC name of CH,NHCH,CH, (1)
46. a) Write the Haworth structure of Maltose (2)
b) What is meant by denaturation of proteins? Which level of structure remains intact during
denaturation of proteins? (2)
c) Deficiency of which vitamin causes the disease pernicious anaemia? (1)
47. a) How is Neoprene prepared? Write the equation. (2)
b) What are condensation polymers? Give an example. (2)
c) What is vulcanization of rubber? (1)