RARE ACADEMY OF MYSORE

II PUC CHEMISTRY
Model Paper - 2
Time : 3hrs 15 min] Sunday, 04th February 2024r 2017 [Max. Marks: 70

PART – A
I Select the correct option from the given choices 15 x 1 = 15
1. If the solute associates in solution, Van’t Hoff factor is
a) >1 b) <1
c) =1 d) 0 YRR

2. SI unit of molar conductivity is

a) 𝑆𝑐𝑚2 𝑚𝑜𝑙−1 b) 𝑆 𝑐𝑚 𝑚𝑜𝑙−1
c) 𝑆 𝑚2 𝑚𝑜𝑙−1 d) 𝑆 −1 𝑚2 𝑚𝑜𝑙−1

3. Three faradays of electricity passed through molten Al2O3, aqueous solution

of CuSO4 and molten NaCl. The amount of Al, Cu and Na deposited at the
cathode will be in the ratio
a) 1mol: 2 mol : 3 mol b) 1.5 mol : 2 mol : 3 mol
c) 1 mol : 1.5 mol : 3 mol d) 1 mol : 3 mol : 2 mol

4. The thermal decomposition of HI on the surface of gold is an example of

a) 2nd order b) 1st order
c) Pseudo 1st order d) Zero order

5. Colour of transition metal ions are due to absorption of some wavelength.

This results in
a) d – s transition b) s – s transition
c) d – d transition d) s – d transition

6. The correct IUPAC name of [Pt(NH3)2Cl2] is

a) diaminedichlorido platinum (IV) b) diamminedichlorido platinum(II)
c) diamminedichlorido platinum(0) d) dichloridodiammine platinum(II)

7. The compound used in the treatment of malaria is

a) halothane b) chloroquine
c) chloramphenicol d) cis – platin
 8. Pyrogallol is an example of
a) monohydric phenol b) dihydric phenol
c) trihydric phenol d) tetrahydric phenol

9. Which of the following unsymmetrical ether ?

a) C2H5 – O – C2H5 b) CH3 – O – CH3
c) C3H7 – O – C3H7 d) C2H5 – O – C3H7

10. Which among the following will not answer Fehling’s test ?
a) formaldehyde b) acetaldehyde
c) benzaldehyde d) propanaldehyde

11. Vinegar is
a) 4% methanoic acid b) 14% ethanoic acid
c) 14% methanoic acid d) 4% ethanoic acid

12. The correct order of basic character among the followings in aqueous
solution is
(i) NH3 (ii) CH3 – NH2 (iii) (CH3)2 – NH (iv) (CH3)3 – N
a) i < iv < ii < iii b) iv < i < ii < iii
c) iv < ii < i < iii d) i < ii < iii < iv

13. The colour of p – hydroxyazobenzene is ?

a) orange b) yellow
c) green d) violet

14. The optically inactive amino acid is

a) lysine b) aspargine c) Leucine d) glycine

15. Pernicious anaemia is due to the deficiency of

a) Vitamin A b) Vitamin B12 c) Vitamin B1 d) Vitamin B6

II. Fill in the blanks by choosing the appropriate word from those given in the
brackets : (Na, Hinsberg’s reagent, whole number, Lucas reagent, +5, +3) 5 x 1 = 5
16. Van’t Hoff factor of aluminium sulphate is _______
17. Molecularity of a reaction is always a _____
18. Most common oxidation state of lanthanoids is _____
 19. Fittig’s reaction involves the reaction of aryl halide with _____
20. The reagent used to distinguish between 10, 20 and t30 amine is ____

PART – B
III. Answer any three of the following. Each question carries 2 marks 3 x 2=6
21. (a) State Henry’s law. (b) N2 is more soluble than He in water. Which among
them have higher KH value ?
22. Show that for a first order reaction, half – life period is independent of initial
concentration.
23. Define ionisation isomerism. Give an example.
24. Explain Finkelstein’s reaction with an example. Give equation.
25. How is acetaldehyde prepared by Stephen’s reaction ? Give equation.
26. Write the Haworth’s projection formula of maltose.

PART – C
IV. Answer any three of the following. Each question carries 3 marks. 3x3=9
27. How is potassium permanganate prepared ? Give equation.
28. Give any three reasons for the catalytic properties of d block elements.
29. What is lanthanoid contraction ? What is the effect of it and what is the reason for
it ?
30. Using VBT, explain the formation, geometry and magnetic property of
[𝑁𝑖(𝐶𝑁)4 ]2−.
31. Give any three postulates of Werner’s theory.
32. Give the IUPAC name of (a) [Co(NH3)3(H2O)3]3+ (b) K3[Cr(C2O4)3] (c)
[Fe(CO)5]

V. Answer any two of the following. Each question carries 3 marks. 2x3=6
33. (a) What are ideal solutions ? Give an example.
(b) Plot the graph of vapour pressure against mole fraction for an ideal solution.
34. Write a note on hydrogen – oxygen fuel cell.
35. (a) State (i) Kohlrausch law (ii) Faraday’s first law of electrolysis
(b) Write Nernst equation for Daniel cell. (2+1)
36. Deduce integrated rate equation for a zero order reaction.
PART – D
VI. Answer any four of the following. Each question carries 5 marks. 4 x 5 = 20
1
37. (a) Explain SN mechanism for the hydrolysis of tertiary butyl bromide.
(b) What are entiaomers ? Give an example. (3+2)
 38. (a) How does propene undergoes hydroboration – oxidation reaction ? Give
equation.
(b) How is aspirin prepared from salicylic acid ? Give equation.
(c) Name the major product formed when sodium phenate reacts with methyl
iodide ? (2+2+1)
39. (a) Explain Lucas reagent test.
(b) Explain Reimer - Tiemann reaction. (3+2)
40. (a) How does acetone reacts with 2,4 – DNP. Give equation.
(b) How does acetone undergoes Clemenson’s reduction ? Give equation.
(c) What is Tollen’s reagent ? (2+2+1)
41. (a) Explain decarboxylation reaction with an example. Give equation.
(b) How does ethanoic acid undergoes esterification reaction ? Give equation.
(c) Which is more acidic among methanoic acid and ethanoic acid ? (2+2+1)
42. (a) Explain Hoffmann bromamide reaction. Give equation.
(b) How is aniline converted into 4 – bromoaniline ? Give equation.
(c) Name the reagent used in Gatterman reaction. (2+2+1)
43. (a) Give any three differences between DNA and RNA.
(b) What is peptida e linkage ? Write the general formula of a dipeptide. (3+2)
PART – E
VII. Answer any three of the following. Each question carries 3 marks. 3 x 3 = 9
44. Calculate the mole fraction of ethylene glycol (C2H6O2) in a solution
containing 20% of C2H6O2 by mass.
45. The vapour pressure of water is 12.3 kPa at 300 K. Calculate the vapour
pressure of 1 molal solution of a non volatile solute in it.

46. The resistance of 1 M salt solution occupying a volume between two platinum
electrodes 1.8 cm apart 5.4 cm2 in area was found to be 32 Ω. Calculate the
conductivity of the solution.
47. Calculate the EMF of the cell in which the following reaction takes place.
0
𝑁𝑖(𝑠) + 2 𝐴𝑔 + 0.002𝑀 → 𝑁𝑖 +2 0.16𝑀 + 2 𝐴𝑔 𝑠 ; 𝐸𝑐𝑒𝑙𝑙 = 1.05 𝑉
48. Time taken for 25% completion of a first order reaction is 30 minutes. Calculate
the time taken for 70% completion of the reaction.
49. Rate of a reaction quadruples when the temperature is increased from 300 K to
320 K. Calculate the energy of activation.

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