PARAS PUBLIC SCHOOL

ANNUAL EXAMINATION (2023-24)

SUBJECT:- CHEMISTRY

CLASS:- XI
Max. Marks: 70 Time Allowed: 3 hours

Read the following instructions carefully.

a. There are 34 questions in this question paper.
b. SECTION A consists of 18 multiple-choice questions carrying I mark
c. SECTION B consists of 7 very short answer questions carrying 2 marks
each.
d. SECTION C consists of 5 short answer questions carrying 3 marks
e. SECTION D consists of case-based questions carrying 8 marks
f. SECTION E consists of 3 long answer questions carrying 5 marks
g. All questions are compulsory.

SECTION -A (18*1=18)
1. LPG mainly contains ,
a) ethane b)butane c)methane d)ethyne

2. The oxidation number of S in Na2SO4 is

a) +6 b)-6 c)-5/2 d)+2/3
3. The IUPAC name of

a)n-hexane b)Cyclohexane (c) Cyclopentane d) benzene

4. Which of the following will exhibit cis-tans isomerism?
a)Butanol b)2-butyne c)ethyne d)2-butene
5. Which of the following cannot be prepared using wurtz reaction?
a) Methane b)ethane c)butane d)hexane
6. Which of the following has highest boiling point?
a) n-octane b)iso-octane
c)2,2 di methyl pentane d) All have equal
7. The number of significant figures in 0.01051 is,
a) 4 b)26 c)3 d)2
8. The I.U.P.A.C. name of
a)3-methyl-2-methyl benzene b)1,2,4 tri methyl benzene
c)Toluene d)4-methyl isopropyl benzene
9. Which of the following have identical electronic configuration?
a) CI and Ar b) Na and K
+ +
c)Li and He d)F+ and Ne
10. Which of the following is an electrophile?
a)H2O b) NH3 c) Br d)NO2+
11. The number of neutrons in 37 CI17 is,
a)37 b)20 c)30 d)17
12.Which of the following is correct order of the size of iodine
species?
a)I>1->I+ b)I>I+>I- c)I+>I->I d)I->I>I+

13. The enthalpies of all elements in their in their standard states

are equal to:
a)Unity b)zero c) <0 d)different for each element

14. If QZ=KC , the reaction proceeds in the

a)forward reaction b)backward reaction
c) at equilibrium d) none of these

15. Aromaticity of a compound and is determined by,

a)(4n+2) π electron rule b)(4n+3) π electron rule
c)(5n+2) π electron rule d) none of the above

16. Which of the following is used in Friedel Crafts alkylation

reaction?
a) Anhydrous AICb b)HCI c)H2SO4 d)Zn(Hg)-HCI
17.Heterolytic Fission leads to the formation of-
a)ions b)neutral species c)Free radical d) all of the above
18. How many sigma(σ ) and pi ( π ) bonds are there in ?
A) σ =3; π = 2 B) σ =6; π = 3 c) σ =12; π =3 d)σ =3; π =5
 SECTION-B (7*2=14)
19. Draw the Sawhorse projection of Ethane ,(Both eclipsed and
staggered conformations)
20.Chlorophyll present in green leaves of plants absorbs light at
4.620 x 1014 Hz. Calculate the wavelength of radiation .
21.What is the difference between the terms orbit and orbital?
22.State Markovnikov rule
23. Explain why (CH3)3C-is less stable than CH3CH2- ?
24. Show the resonance in Aniline.
25. Draw the condensed structural formula and write the I.U.P.A.C
name of the given compound.

SECTION-C (5*3=15)
26. Write the products of Ozonolysis of Pent-2-ene. Draw the
structure of Chlorobenzene. (2+1)
27.Draw the structures of the geometric isomers of 2-butene.Which
isomer has Zero dipole moment?
28. Write the IUPAC names of the following. (1+1+1)
a)
b)

c)

29.In the reaction 2A+ 4B →3C+4D, when 5 moles of A react with 6

moles of B then, Which is the limiting reagent? Define molarity.(2+1)
30.Balance the given equation using oxidation number method.
MnO4- (aq)+SO2(g) → Mn2+(aq) +HSO4-(aq) (in acidic solution)

SECTON -D (8)
Read the passage and answer the following –
From unsaturated hydrocarbon Dihydrogen(H2) gas adds to alkenes
and alkynes in the presence of finely divided catalysts like
platinum ,palladium or nickel to form alkanes. This process is called
hydrogenation .These metals absorb dihydrogen gas on their surfaces
and activate the hydrogen-hydrogen bond. Platinum and palladium
catalyse the reaction at room temperature but relatively higher
temperature and pressure are required the nickel catalysts. Halogens
also adds to alkene and alkene and alkynes via addition reaction in the
same way.
Alkyl halides on treatment with sodium metal in dry either(free from
moisture) solution give higher alkanes .This reaction is known as
Wurtz reaction and is used for the preparation of higher alkanes
containing even number of carbon atoms.
a.Which of the following catalyst is used for hydrogenation reaction?
a) platinum b) palladium c) nickel d)All the above (1)
b. What happens when Ethene reacts with H2in presence of Nickel
(catalyst) ? (2)
c. Write the product of the reaction. :
Dry
CH3Br + CH3CH3Br + 2Na E ther >¿ (2)
d. What happen when CH3+CH=CH2 reacts with Br2 in presence of
CCI2?
(2)
e. Which alkyl halide should be taken for the preparation in butane via
wurtz reaction? (1)

SECTON -E (3*5=15)
32. Assign oxidation number to the underlined elements in each of the
following species: (5)
a) K2MnO4 b)H2SO4 c)K2Cr2O7 d)H2S3O8 e)KNO3

33. a.What happens when 3,4 - Di methyl-hept-3-ene undergoes

ozonolysis reaction? (2)
b.What happens when CH4 reacts with CI2 in presence of Sun
light? (2)
c. What is peroxide effect? (1)
34. i)Write the structures of the products formed in the given
reaction.(3)

ii) Find the structure of “A”. (2)