Paper: Chemistry HSSC-II Test: 05 Session: RNT_FEB 2022

Name: Pre-Engg. / Pre-

Roll No.
_________________________________________ Med.
Time: 15 Min Total Marks: 13 Date: 21-03-2022

SECTION – A (Marks 13)

Q.1 Encircle the correct option i.e. A / B / C / D. Each part carries one mark.
(1×13=13)
i) Which of the alkyl halide is quickly forms Grignard’s Reagent?
⒜ CH3 – F ⒝ CH3 – Cl ⒞ CH3 – Br ⒟ CH3 – I
◯ ◯ ◯ ◯
ii) All aldehydes except formaldehyde react with Grignard’s Reagent to form ______
alcohols;
⒜ Primary ⒝ Secondary ⒞ ⒟ Quaternary ◯
Tertiary ◯
◯ ◯
iii) Which one of the following reactions is most likely to occur through SN1 mechanism?
NaOH / CCl4 ◯
⒜ (CH3)2CH Cl (CH3)2CH OH
NaOH / H2O ◯
⒝ H3C CH2 Cl H3C CH2 OH
NaOH / H2O
⒞ (CH3)3C Cl (CH3)3C OH ◯
NaOH / CCl4
⒟ (CH3)3C Cl (CH3)3C OH ◯
iv) Which of the diazonium ion is most stable?

⒜ H3C CH2 N N ◯ ⒞ H3C N N

◯

⒝ Cl CH2 CH2 N N ◯ ⒟ O2N N N

◯
v) 100 % inversion of configuration takes place in;
⒜ SN1 mechanism ◯ ⒞ SN1 mechanism in polar solvent ◯
⒝ SN2 mechanism ◯ ⒟ SN2 mechanism in polar solvent ◯
vi) Reaction between alkyl amines and alkyl halides proceed via;
⒜ Nucleophilic Substitution Reaction ◯
⒝ Nucleophile Addition Reaction ◯
⒞ Nucleophilic Acyl Substitution Reaction ◯
⒟ Electrophilic Addition Reaction ◯
vii) In a nucleophilic substitution reaction, the rate of substitution doubled with the
increased concentration of nucleophile while concentration of alkyl halides kept
constant. Indicate the type of reaction mechanism.

Hard Work and Determination is the Key to Success

 ⒜ SN1 mechanism ◯ ⒞ Both SN1 & SN2 mechanism
◯
⒝ SN2 mechanism ◯ ⒟ Nothing can be said ◯

viii) Which of the following is a secondary amine?

⒜ 2-Methylaminopropane ◯ ⒞ 3-Amino-3-methylpentane ◯
⒝ Iso-Propyl Amine ◯ ⒟ Sec-Butyl Amine ◯
ix) Double bond is formed as a result of;
⒜ Substitution Reactions ◯ ⒞ Addition Reactions ◯
⒝ Elimination Reactions ◯ ⒟ Rearrangement Reactions ◯
x) Which of the following is CORRECT?
⒜ SN2 and E2 are one step reactions ◯
⒝ E1 and E2 are one step reactions ◯
⒞ SN1 and SN2 are one step reactions ◯
⒟ SN1 and E1 are one step reactions ◯
xi) Strong base favours the;
⒜ Substitution Reaction ◯
⒝ Elimination Reaction ◯
⒞ Substitution followed by Elimination ◯
⒟ Elimination followed by Substitution ◯
xii) The nucleophilicity of amine is due;
⒜ –R attached to – NH2 group ◯ ⒞ Presence of lone pair of N atom ◯
⒝ Hydrogen atoms of – NH2 group ◯ ⒟ Electronegativity of N atom ◯
xiii) Which is NOT true about β-Elimination Reaction?
⒜ It results in the formation of Pi-Bond ◯
⒝ Presence of β-H is necessary ◯
⒞ It favours in polar molecules ◯
⒟ It occurs through by SN1 and SN2 mechanism ◯

Hard Work and Determination is the Key to Success

Paper: Chemistry HSSC-II Test: 05 Session: RNT_FEB 2022
Name: Pre-Engg. / Pre-
Roll No.
_________________________________________ Med.
Time: 1 Hr. 15 Min Total Marks: 37 Date: 21-03-2022

SECTION – B (Marks 24)

Q. Answered Briefly and Precisely FOLLOWING Parts; all carry equal marks.
2 (3×8=24)
i) Convert the following;
⒜ 3-Methylaniline into 3-Nitrotoluene ⒞ Methyl Bromide into ethanoic acid
⒝ Aniline into 1,3,5-Tribromoaniline
ii) How ethyl amine reacts with the following reagents?
⒜ Nitrous acid in 0 °C ⒞ Acetyl chloride
⒝ Acetaldehyde
iii) Why ethylamine is soluble in water whereas aniline is not despite both can form
Hydrogen Bonding?
iv) Write three isomeric amines corresponding to the molecular formula, C4H11N.
⒜ Write IUPAC names of all the isomers.
⒝ What type of isomerism is exhibited by different pairs of amines?
v) Grignard’s Reagent is one of the organometallic compounds capable of forming
carboxylic acids upon reacting with carbondioxide followed by acid hydrolysis.
Prepare following carboxylic acid from Grignard’s Reagent;
CH3O
H3C C C OH
CH3
vi) Why Iso-Propyl Bromide react differently with alcoholic KOH and Aqueous KOH?
Write the reaction that explain the difference.
vii) How it is possible that a secondary alcohol is prepare by the reaction of Grignard’s
Reagent with ester? Explain with the help of reaction(s).
viii) Why alkyl fluoride is least reactive as compare to alkyl iodide despite C – F bond is
highly polarized compare to C – I?

SECTION – C (Marks 13)

Attempt FOLLOWING question in detailed. [13 × 1
= 13]
Q. a) How methyl magnesium bromide reacts with the following;
3 [1+2+1+1]
i) Methyl Bromide iii) Ammonia
ii) Acetaldehyde iv) Water
b) How secondary carbocation is stabilized for conducting S N1 or E1 mechanism for
Substitution Reactions or Elimination Reactions respectively? [4]
c) Compare the Chemical Kinetic of E1 and E2 Mechanism for Elimination
Reaction keeping the following point in view.

Hard Work and Determination is the Key to Success

 [4]
i) Rate Equation ii) Order of Reaction iii) Molecularity

Hard Work and Determination is the Key to Success