MOLE CONCEPT Motion DPP-1 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION 1, INGLE CORRECT QUESTION: If the mass of 0.25 moles of an element X is 2.25 g, the mass of one atom of X is about (A) 1.5 x 104 g (8) 2.5x 10739 (15x10 9 (0) 2.5.x 10-% g From 392 mg of H,SO,, 1.204 x 10% molecules of HS, are removed. How many moles of H,SO, are left: (A) 2x 103 (8) 1.2 x 103 (©4103 (0) 1.5 x 10%, If-all the O-atoms from 4.4 g CO,, 6.022 x 10 molecules of N,0,, 0.2 moles of CO and 1.12 L of SO, gas at NTP are removed and combifted to\form O, gas, then the resulting gas occupies a volume of ..... at NTP. (A) 2.4L (8) 44.8 (©) 3.6L (Dane ‘The mass of half molé oF electrons is about : (Given : Mass of electfOn, = 9.109 x 10* 9) (A) 0.548 mg (80.274 mg (©) 1.096 mg (0) 9.109:ma 39.4 kg Of gold was recovered from a smuggler The number of atoms of goldyrecovered are (A) 200 (B) 112044 x 10% (©) 6.022 x 10% (0) 4.2044 x 10% ‘The mass of Magnesium that contains the same number 6flatom$ as are present in 2g of Calcium Is: (A129 (8) 249 (06g (0) 1.8.9 ‘The number of gram-atoms present in 288g(0F sulphur is (A) 18 (B) 9 (C) 4.5 (D) 13.5 MULTIPLE TYPE QUESTIONS 124 amu of P, will contain : (At. mass of P = 31) (A) 4N,, atoms of phosphorus (B) 4 atoms of phosphorus (C) 1 molecule of phosphorus (0) N, molecules of phosphorus In which of the following pairs do 1 g of each have an equal number of molecules (A) NO and co (B) N, and C,0, (ON, and co (D) N,O and Co, Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588FILL IN THE BLANK 10. Fill the blanks in the table (where N, is Avogadro number) ware Fo oj ol ofatom] Mase removes | tot | Atoms T"e cum aon, pee |) eee Howsotl catia | hem en | mmeres| mere oF amr present Eosinno] ‘Sime [tem tone | te te 2 | ane a a | eee Trae clam Ste = | son hoo alga we | mer Re Corparate Office: tion Elucation PVCU, 354 Rajeev Gand Nagar Kota BOOIBISEBEMOLE CONCEPT Motion DPP - 2 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION SINGLE CORRECT QUESTIONS 1. 1.5 x 10” atoms of an element weigh 0.9 g. The atomic mass of the element (in amu) is (a) 36 (®) 18 (©) 54 (0) 72 2. The ratio of mass of a Titanium atom to the mass of a Carbon atom is 4: 1. Then, the molar mass of Titanium is (a) 39 (©) 489 (129 (0) 249 3. Ahypothetical element Z exists In nature as two Isotopes 2* and 2° with thelr relative abundances 25% and 75% respectively. Then, the average atomic mass (in u) of element Z is = (A) 65.5 (8) 66 (0.66.25 (0) 66.5 4, The mass of a molecule of water is: (A) 3x 10% kg (B) 3x 105K (C) SX HDR KG (D) 2.5 x 107 kg 5. The weight of 1x10 moleaiiles of MgSO,.7H.0.is (a 4.t9 (e419 () 4109) (0)0.419 6. Among the followiig samples, the largest: number of molecules is in : (A) 28 g of CO’ (B) 46.9 OF CH.OH (C)36.G.0f 4,0. (D) 54g of NO, 7. 124g OF Py will contain which of the follewing (1) 4 atoms of Phosphorus (2) 4N, atoms of Phosphorus (3) N, molecules 6fPhospharus (4) 4 molecule of Phosphorus (A) Land 4 (@),2 ana 3 (©) Lands (0)2and 4 8. Number of gold atoms in 300)mg of a gold ring of 20 carat. g6ld (pure gold is 24 carat) are (A) 4.5 * 10 (B) 6.8 * 10%, (C) 7.6 x 1020 (D) 9.5 x 10° MATCH THE COLUMN 9. Column - 1 Column - 11 (A) 49.9 H,S0, (p) 0.5 mole of given unit (8) 20g NaOH (4) 1.5N, atoms (©) 11.2 LofCo, at STP () 0.5 Ny molecules (D) 6.022 x 107? atoms of Oxygen (s) 2 mole of ‘0’ atom INTEGER TYPE 10. How many atoms are present in '64 amu’ of oxygen. Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588MOLE CONCEPT Motion DPP - 3 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION SINGLE CORRECT QUESTIONS 1. From container having 64 g Oxygen, 11.2 L Oxygen gas at $.T.P. and 6.022 x 1023 Oxygen atoms are removed. Find the mass of the oxygen gas left (A) zero (8) 329 (©) 169 (0) none 2. If a sample of Ferric sulphate Fe,(SO,), contains 7.2 moles of O-atoms, then the number of S- atoms in the given sample are : (A) 1.8N, (8) 1.2 N, (1.6, (0) L4 Ny 3. 10 moles of CO, do not contain (A) 120 9 of C (8) 6.022 x 10* atoms of © (C) 10 N, molecules of CO, (D) 20 gram-atoms of O. 4. —_Acompound has the molecular formula x{O,. If. g of X,0, has 6.2 9 of X, then atomic mass of Xis (A) 31 amu (8) 37 amu (©) 42 amu (0) 98 amu 5. A sample of CaCO, has Caf 40%, C = 12%,and.0 = 48%)by mass. If the law of constant Proportions is true, then\the mass of Ca in 5 g of CaCO, from another source will be: (29 (0.29 (0.02.9 (0) 20.9 6. In compound,Af. 9 nitrogen combine with 0.57 Goxygen. In compound B, 2ig nitrogen combine with 2.28 g®xygen and in compound C, 3 g nitrogen combine with 5.13 g oxygen. These results obey thellaw of: (A) multiple proportions (6) constant proportions (C) mixed proportions (O) none of these 7. The respective ratio Of, weight of oxygen in samples of pure CuO@nd Cu,0, if both samples contain the same mass oficopper, Is : (ayi:2 (8) 124 c2it (D) none of these 8. The density of air at STP is 0.001287 g mL. Its vapourdensity is (a) 143 (6) 14.3 (©) 1.43 (0) 0.143 [Hint : Divide with the density of hydregen at STP, f., 0.00009 g ml!) MATCH THE COLUMN Column-I Column-11 (A) 32 g each of 0, and Ss (p) 2 moles of Fe (B) 2 gram-molecules of K,{Fe(CN),] (q) 3 moles of ozone molecule (C) 144 9 of Oxygen atom (F) one mole of given unit (D) From 168 g of iron, 6.022 x 10% atoms _(s) 12 moles of carbon atoms of iron are removed, then the iron left INTEGER TYPE 10, Find the relative density of SO, gas with respect to methane. Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588MOLE CONCEPT Motion DPP-4 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION ‘A sample of a compound contains 9.75 g Zn, 1.8 x 10 atoms of Cr and 0.6 gram-atoms of O. What is empirical formula of compound ? (Atomic Mass Zn = 65) (A) zncro, (B) Zncr,0, (© zn,cro, (0) zncr,0, 2. An organic compound on analysis was found to contain 0.032% of sulphur by mass. The molecular mass of the compound, if its one molecule contains two sulphur atoms, is : (a) 100000 uw (8) 10000 u (©) 20000 u (©) 200000 u 3. 0.1 mole of a carbohydrate with empirical formula CH,O contains 1 of hydrogen. What is its molecular formula? (A) CH 095 (B) CoH 205 (C) CyH,0,, (B) CsH_03 4, The number of moles of oxygen obtained by the electrolytic decomposition of 90 g water is (2H0 55 2H, + 0.) (25 5 zs (0) 10 5. Ina gaseous reaction of type xA(a) + yB(a) —+ pC(a) + go(Q) where x, ¥, p and q are stoichiometric Coefficients Which of the following statements is not correct (A) At STP, x litre of A combine with y litre of B to-give C andiD (B) x mole of A combine,with y mole of 8 to give € and D (C) xg of A combine with y 9 of B to give C and D. (0) x molecules of Aleombine with y molecules of B to give C and D, 6. A.compound of Mig contains 6%/6FIMG)bylMaSS!lIf the minimum molar maBS.of the compound is 1n x 10° g/mol then determine value of ‘nt (A) 2. (B)5 o4 (0) 3 7. Sulphur trioxide is prepared by the following two reactions S,(S#9B0.(9) > 8SOx(Q)y 250,(a) + 0.(a) > 250,() How many grams of SO, are produced from 1 mole of S, (a) 1280 (8.640 (© 960 (oyS20 8.3L of N, gas are mixed with, 6L of H, gas to form NH,"Gas, What volume of NH, gas can be Produced, if all volumes are measured under same temperature and pressure conditions : fa) ot (6) a (3 (2 ONE OR MORE OPTIONS MAY BE CORRECT 9. 11.2 Lof a gas at STP weighs 14 g The gas couldbe (ano (8) NO, (ON, (0) co MATCH THE COLUMN 10. Column - Column - 11 (A) A compound containing 5 g°S’ and 5g oxygen _(p) Empirical formula is CH, (©) hydrocarbon containing £8 % °C by mass (@) Molecular formula is CH, ‘ng 2 (C) A compound containing a % of *C’ (r) Empirical formula is SO, and 225 of 0" by mass (0) A hydrocarbon containing 12296 (5) Empl formulas C0, by mass (Molecular mass = 28) Corporate Office : Motion Education Pvt. Ltd, 383 Rajeev Gandhi Nagar, Kota © 8003899588 | Pages IMOLE CONCEPT Motion DPP-5 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION SINGLE CORRECT QUESTIONS 1. Zinc and hydrochloric acid react according to the reaction : 2n(s) + 2HCKaq.) —>_ZnCh,(aq.) + H, 1f 0.30 mole of Zn are added to hydrochioric acid containing 0.52 mole HCI, how many moles of H, are produced: (A) 0.26 (8) 0.52 (0.14 (0) 0.30 3.68 g of a mixture of CaCO, and MgCO, is heated to liberate 0.04 mole of CO,. The mole % of CaCO, and MgCO, in the mixture is respectively : (A) 50%, 50% (B) 60%, 40% — (C) 40%, 60% — (D) 30%, 70% 120 g Mg was burnt in alr to give a mixture of MgO and Mg.N,. The mixture is now dissolved in HCI to form MgCl, and NH,CI. If 107 grams NH,CI is produced, then determine the moles of MgCl, formed. (Az (B)6 o-4 (0) 5 What volume of a 0.8 M solution contains 100 millimoles of the solute (A) 100 mt. (B) 125 ml (©) 500 mt: () 62.5 mt. ‘The molarity of the KOH sollition which is 2.89%@\(mass/volume) solution is (a) M/10 (Byn/2 (Ms, am 75 mi of H,SO, (specific gravity = 1,18) containing 49% H,SO, by maSs.is diluted to 590 ml Calculate molarity of the diluted solution : (07M (8)7.5M (075m (0) 0.25 M Calculate the volume in litre of 1M soldtion 6FHCI, which contains 36.5 9 HCI at (84 (2 (0)3 ‘The atomic weight 6fan element isa’. If this element occurs in naturé as a triatomic gas, then the correct formula forthe number of moles of gas in.jts 'w' g Is : wy ow (©) 3wa ©) 5 ONE OR MORE OPTIONS MAY BE CORRECT 9. 10. ‘3 moles of gas C,H, are mixed with 60 9 Ofithis.gas and 2.4 x 10 molecules of the gas are then removed. The left over gas is burnt in the présence of excess oxygen. Then : (N, = 6 x 10%) (Density of water = 19/mL) (A) 2 moles of CH, are left for combustion. (B) Volume of CO, at S.T-P. produced after combustion is 44.8 litre, (©) Volume of liquid water produced is 54 mL. (D) None of these Amongst the following, select the false statements (A) Limiting reagent must have the least moles among all the reactants available in a chemical reaction. (B) If equal masses of aluminium and oxygen are made to combine to produce Al,0,, then aluminium will be the limiting reagent. (©) A2: 3 molar ratio mixture of Na,CO, and MgCO, produces 0.3 mole of CO, per mole of the Initial mixture upon strong heating, (0) All of these Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588MOLE CONCEPT Motion DPP - 6 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION SINGLE CORRECT QUESTIONS 1. ‘The number of molecules of water in 333 9 of Al,(SO,),- 18H,0 is (A) 18.0 x 6,02 x10 (B) 9.0 x 6.02 x10” (©) 18.0 (0) 36.0 Which of the following have largest number of atoms? (A) 4 gm oxygen (B) 16 gm sulphur (©) 35.5 gm chlorine (D) 14 gm lithium Number of oxygen molecules having weight equal to weight of 20 molecules of SO, (a) 100 (8) 50 (O15 (os ‘The weight of 3.2 x 10° atoms of an element 88.0 x10- gm. the atomic weight of the element should be about, (A) 2.5 x10? (8) 15 (15 (0) 150 ‘The number of neutrons present in 9 mg of O* is (a) 10 (8) 5 (C),g1005,N, (0) 0.0005 N, 26.8 gm of Na,SO,«fiH,0 contains 12.6 gm water: The value of n wt (B) 10: oe (0)? The motafifatio of Fe:* to Fe in a mixture of FeSO, and Fe,(SO,), having equal number of sulphate fon. in both ferrous and ferric Suiphatells (ayi:2 (8) 352 (2: 3 (0) 2:3 (One mol mixture of FeO and Fe,0, contain equal moles of each on reaétion with excess 0, gives ‘n’ moles of Fe,0, ‘Alsip wt (82 (923 (0) None of these ONE OR MORE OPTIONS MAY BE CORRECT 9. 10. The true statement out of the following is/are (A) The mole is the amount of substanee tontainiig the same number of chemical units as there are atoms in exactly 12 gms of #C. (B) Avogadro's number is the number of units in a mole, (©) The wt. of one gm-atom of an element means its atomic -weight in gms. (D) One gm-atom of each element contains the same number of atoms Which of the following contain same number of total atoms. (A) 9.9m CH, (B) 18.0 9m C.H,,0, (©) 9.8 gmH,50, (0) 48 gm So, Corporate Offi Motion Education Pvt Ltd,, 394- Rajeev Gandhi Nagar, Kota © 8003899588MOLE CONCEPT Motion DPP -7 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION SINGLE CORRECT QUESTIONS 1. The molar ratio of Ha,** to Hg* in a mixture of Hg,Cl, and HgCl, having equal no. of Cr ions in both mercurous chloride and mercuric chloride is: (Ait (B)1:2 (2:4 (0) None of these ‘The no. of electrons present in 448 ml of O, at STP is (a) 16 (B) 320 N, (© 18x10 (0) 640 N,, ‘The no. of water molecules x mol of CuSO,. SH,O are n,. The no. of water molecules in 2x mol of FeSO,. 7H,0 are (A) 144, (B) less than 3n, (C) 1.41, (D) None of these In the reaction 4A + 2B + 3C + A,B,C, thea6)Jof moles of product formed starting from one mol of A, 0.6 mol of B, 0.72 mol of C (A) 0.25 (8) 0.3 (© 0.24 (D) 2.32 Consider reactions: 2A 3B, B->2C, 3C 4.4, The no. of moles of ‘Diformed starting 4 moles of A are as (B) 16 oa (0) None ‘The ratio of nl of hydrogen atoms in 2 molecule of H,O.to,no. of oxygen atomiin 1.5 mol of H,0, Is: (ay 4/3 (8) 4NJ3 (O4K3N,) (0) 2/3 4 mol NH, on complete dissociation gives : (A) 1 mol N, (8) 0.6 mo! N, (©) 8 moles of (N, +H) (D) 3 mol of H, 4.6 x 10% atoms of an element weight 13.8 gm. Thetam atomic mass of the element (A) 120 am (B) 180 gm (©) 35.5.0m. (0) 108 gm ONE OR MORE OPTIONS MAY BE CORRECT. 9. 10. Select the incorrect statement(s): (A) Mass of 6.022 x 10° molecule of SO, is 8 kg (B) Number of oxygen atoms in 4.8 gm of O, are 18.06 x 102 (©) Mass of 22.7 ml of C,H, at 1 bar pressure & 273 K Is 30 gm (0) Volume of 51 mg of NH, at 1 bar pressure & 273 K is 68.1 1 1 mol of ,* N-¥ions contains (A)7N,electrons (B)7N,protons (C) 7 N,neutrons__(D) 14 N, protons Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588MOLE CONCEPT Motion DPP-8 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION How much pure KMnO, should be heated with H,SO, to produce 48 gm 0,7 KMnO, +H,SO, > K,SO, + MnSO, + H,0 + 0, (A) 189.6 gm (B) 122.5 gm (0) 158 gm (D) 316 gm How many water molecules will be lost on completely dehydrating 0.342 gm of sucrose, C,,.H,,0,, (A) 6.622 x 10" (B) 6.02 x 10 (C) 7.224 x 10% (D) 1.324 x 10" ‘Ametal oxide has the formula M,0,. It can be reduced by hydrogen to give free metal and water. 0.1596 g of the metal oxide required 6 mg of hydrogen for complete reduction. The atomic weight of the metal is (a) 27.90 (B) 159.60 (© 79.80 (0) 5.80 Large quantities of ammonia are burned in the presence of a platinum catalyst to give nitric oxide, as the first step in the preparatigh of nitric acid, NH,(9)+0.(g) > NO(Q)+H,0(a) (unbalanced). Suppose a vessel contains@.12 mole NH, and 0.14 mol O,. How many moles of NO may be obtained? (A) 0.120 (B) 0.112 (C) 0.140 (D) 0.070 1.0 x10 mol of Ag* and 1.06% 10° mol of CrOz~ react togetiner to form solid Ag,CrO,. What is the amount of Ag,CrO, formed? (Molecular weightof Ag,CrO, =)332 ) (A) 0.268 gm (B) 0.166 gm (C) 6.212 om (O))1.65 am ‘An unknown compound contains 8% sulphur by mass. The least molecularweight of the compound and if one mole contain 4 atoms of S: (A) 200, 400 (B) 300, 400 (©) 400, 1600 (©) 400, 1200) ‘The sample(s) containing same no. of \Nalatbifilas there are ‘Na’ atoms in 5.3 gm of Na,CO, , is/ are (A) 4 am of NaOH (B) 5.85 om of Nacl (©) 0.25 mole oF NSO, (0) 5.6 gm of Na.PO, ‘A mixture of gas "X" (ml, wt. 16) and gas Y (mol. Wtn28) in thé mole ratio a: b has a mean molecular weight 20. What Would be mean molecular welght if the gases are mixed in the ratio b: a under identical conditions (gases are non reacting). (a) 24 (B) 20 (©) 26 (0) 40 QNE OR MORE OPTIONS MAY BE CORRECT 10. ‘A piece of plumber's solder weighing 3.0 gm-was dissolved in dilute nitric acid, then treated with dilute H,SO,,. This percipitated the lead as PbSO,, which after washing and drying weighed 2.93 gm. The solution was then neutralized to precipitate stannic acid, which was decomposed by heating, Yielding 1.27 gm SnO,. What is the analysis of the solder. (Pb = 207.2 amu, Sn = 118.7 amu) (A) 66.7 % Pb, 33.3 % Sn (B) 33.3 % Pb, 66.7 % Sn (©) 1 gm Pb, 2 gm Sn (0) 2.gm Pb, 1 gm Sn. Which of the following pairs do not contain equal number of atoms ? (volume of gas is taken at 1 atm, 0°C) (A) 11.2 mi of N, and 0.0159 of NO (B) 22.4 litres of N,O and 22.4 litres of NO (C) 1 millimole of FCI and 0.5 millimole of H, (0) 1 mole of H,0, and 1 mole of N,O, Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588MOLE CONCEPT Motion DPP-9 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION SINGLE CORRECT QUESTIONS 1. Density of ry ar containing eny Nand 0, =225 gmt t 760 mm and 300K. Whats % composition of N, by weight in the air. (A) 78% (B) 82% (© 73.47% (0) 72.42% A given sample of pure compound contains 9.81 gm of Zn, 1.8 x10" atoms of chromium and 0,60 mol of oxygen atoms. What is the simplest formula, (A) 2nCr,0, (B) 2nCr,0, (© 2ncro, () zncro, If two elements X and Y combine to form two compounds XY, and X,Y, when 0.05 mole of XY, weighs § gm while 3.011 x10® molecules of, X,Y, weighs 90g. The atomic masses of X and Y will be (A) X = 20, ¥ = 30 (B) X = 30, Y = 20% (C) B40, Y= 30 (0) x = 30,¥ 0 1.44 gram of Titanlum (Ti) reacted with excess of O, and)produced x gram of non-stoichiometric compound Ti, ,,0. The value of x will be (A) 2.779 (8) 39790 (Org (0) 3.09 A sample of impure éuprite Cu,0 contains 66.6 % by mass copper. Th@\% of pure Cu,O by mass of Cu,0 will be (A) 25% (B) 50% (© 75% (0) 95% 8 gm‘sulphur are burnt to form SOswhichiis then oxidised by chlorine to silphate. The solution Is now. treated with BaCl, solution. The amount of BaSO, precipitated Inmol will be (A) 0.25 mol (B) 0.30 mol (0.50 mot (0) 0.75,mot A drug marijuana owes)its activity of tetrahydrocannabinol, which contains 70% as many C atoms as H atoms and 15 times as many hydrogen atomisias oxygen atoms. The number of mole ina gm of it is 0.00318. The molecular formula will be (A) CagH 50. (8) C,H) (C) C,H, 0. (0) C,,0,,0, A mixture of NH,NO, & (NH,),HPO, showed the mass percent of nitrogen to be 30.40%, The mass ratio of the two components in the mixturé)willibe: (2st (B) 1:2 (1:3 (O34 ONE OR MORE OPTIONS MAY BE CORRECT 9. 10. Which of the following statement(s) is/are correct for water ? (A) Hand O are in 2:1 atomic ratio (B) H and O are in 2:1 weight ratio (©) Hand 0 are in 1:8 weight ratio (0) H and O are in 1:8 volume ratio Three isotopes of an element have mass numbers M, (M+1) and (M+2). If the mean mass number is (M++0.5), then which of the following ratio(s) may be accepted for M, (M+1) and (M+2) In the order (Ayiraea (B)4rai2 (96:1 (O)2:as4 Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588MOLE CONCEPT Motion DPP - 10 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION SINGLE CORRECT QUESTIONS 1. '5 moles of A, 6 moles of Z and mixed with sufficient amount of C to produce final product 'F’. ‘Then find the maximum moles of 'F' which can be produced. Assuming that the product formed can also be reused, Reactions are A+2Z58 BHCoZ+F (A) 3 moles (8) 4.5 moles (© 5 moles (0) 6 moles FeSO, undergoes decomposition as 2FeSO,(s) ~ Fe,0,(s) + $0,(g) + $0,(9) At STP if (7.6 gm) FeSO, Is taken then The volume occupied by the gases at STP (a) 22.4 lit (B) 11.2 Hit (©) rede (0) 2.24 lit FeSO, undergoes decomposition 2FeSO,(s) > Fe,0,(s) + $0,(g) +0,(9) At STP if (7.6 gm) FeSO, is taken then the avefag@lmolar mass GFthe gaseous mixture. (a) 72 (6) 36 (48 (o)j50 Calculate the affiount of ZnO preduced (in|Gi))iwhen 195 gm of ZnS reats with 89.6 / 0, at 1 atm and 273K 2nS #0} + 2n0 + SO, (a) 1729 (8) 1639 (©) 1489 (0) 1509 A certain metal M forms an Insoluble oxalate complex M,0,(C,0,),.12H,0. If 3.38 gm of the complex are formed from, gm of oxalic acid, what is.the atomic weight of M? (A) 80.23 (8) 70:20 (©) 96.15 (0) 68.23 Decreasing order (first having highest & then others following it ) of mass of pure NaOH in each of the aqueous solution. (i) 50gm of 40% (w/w) NaOH (ii) 0g of 50% (w/v) NaOH [d,.=1.29m/mil (ii) 50 gm of 20 M NaOH[d.,, = dom/mi} (4) (0, (i), 8) (i), @, (C) ii), Gi), (D) All contain same wt. of NaOH Methyl benzoate is prepared by the reaction between benzoic acid and methanol, according to the equation C,H,COOH + CH,OH ->C,H,COOCH, + H,0 Benzoic acid Methanol Methyl benzoate In an experiment 24.4 gm of benzoic acid were reacted with 70.0 mL of CH,OH. The density of CH,OH is 0.79 g mL. The methyl benzoate produced has a mass of 21.6 g. What was the percentage yield of product? (A) 91.7% (B) 79.4 % (C715 % (0) 21.7 % Corporate Office : Motion Education Pvt. Ltd, 383 Rajeev Gandhi Nagar, Kota © 8003899588 | Pages ICOMPREHENSION QUESTIONS ‘Comprehension (Q.8 to Q.10) 10. Just like unitversal gas constant R, another constant "Boltzman constant" is also frequently used R & is defined as jj = K. Using this information & the fact that only gases follow the equation PV = nT, answer the following questions. FY gives the value of (A) number of moles of gas (B) mass of gas (©) number of molecules of gas (D) molar mass of the gas Which of the following gas has maximum number of atoms. (A) 44.8 lit. O, at 1 atm, 273 kK (B) 49.26 lit. of H, at 1 atm, 300 K (C) 22.4 lit. of O, at 2 atm, 546 K 2s (0) 11.2 lit. of laughing gas (N,0) at’ atm, If value of R = 0.0821 atmalit-/K mole, then whatiwill be its approximate value in Pa-m?/K mole units. (a) 0.08921 (8) 8.31 (¢) 1.98 (0) 8.314 x 107 Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588MOLE CONCEPT Motion DPP - 11 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION ‘The air contains 78% N, & 22% O, by volume. The volume occupied by 40 gm air at 20°C & 745 mm Hg pressure approximately. (a) 34 Mit, (8) 34 mi (© 3.4K. lit. (D) 3.4 lit 0.5 gm of fuming sulphuric acid was dissolved in water. The solution required 30 ml of 0.4 M NaOH solution for complete neutralisation. Calculate the % of free SO, in the sample. (A) 78.24 % (B) 50.2 % (© 60.4 % (0) 64'5% Arrange in increasing order of Molarity of solute in following solutions considering water as solvent Show your calculations, (i) 224 gm/lit. KOH (ii) 11.2% w/v KOH (ii) 5m KOH (d = 0.64 g/ml) Ad) < Gi) Fe,0,(s) + 0X9) het the percentage bir mass ofFe,0, in oiginal sample. (3) 80% (6) 20% (ga (0) 3088 32.2 am of Glauber’s salt (Na,SO,. 10H,0) is dissolvediinjWater to prepare 2ilit. solution. The molarityiof Na* ion is x and molality of S02" 1s y. The values of x and y are: (A) 0.1, 0,05 (8) 0.2, 0.1 (©)0.05, 0.05 (0) None of these 300 ml 0.4 M PB{NO,), soluti@n is fixed with 50 m| 0.6 M Ba,(PO,),. The Pb# aon-centration after the precipitation, of Pb,(PO,). Is : (A) (9/35) M (B)0 (© 35) (D)flone of these ‘The molarity of pure water is (a) 18 (B) 55.55) (© 5.55 () 100 MATRIX MATCH QUESTIONS 9. 10. ‘Two substance C & O, are allowed to reactcompletely to form CO & CO, mixture, leaving none of the reactants. It is known that when 1 mole of carbon reacts with 1 moles of O, to give 1 mole of CO,, 100 kcal of energy is released & when‘ mole of carbon reacts with 0.5 moles of O, to give 1 mole of CO, 25 kcal is liberated. Using this information match column I with column II Column- 1 Column-I1 (Amount of reactants) (Energy released) (A) 36.9 C & 800, (P) 125 keal (8) 129C&24g0, (Q) 225 kcal (©) 24g C& 4890, (R) 150 kcal (0) 36gC.& 6490, (S) 62.5 keal Match the column: Column-T Column-11 (No. of moles of ) (A) Oxygen atom in. 0.5 mol Ca,(PO,), (P)8 (B) Carbon atom in 112 lit. CH, at 1 atm & 273K. (Q)4 (C) Sulphur in 192 gm of SO, @S5 (0) ‘Cr"in 24.088 * 10 molecule C10 (8)3 Corporate Office : Motion Education Pvt. Ltd, 383 Rajeev Gandhi Nagar, Kota © 8003899588 | Pages IMOLE CONCEPT Motion DPP - 12 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION C,H,OH (9) + 0, (9) —> CO, (9) + H,0 (/) Magnitude of volume change if 30 mi of C,H.OH (9) is burnt with excess amount of oxygen, is (A) 30 mi (B) 60 mi (C) 20 mi (D) 10 ml 410 ml of a compound containing 'N' and 'O' is mixed with 30 ml of H, to produce H,0 (/) and 10, mi of N, (g). Molecular formula of compound if both reactants reacts completely, is ) NO (B) No, (C)N,0, (0) NO, Similar to the ®% labelling of oleum, a mixture of H,PO, and P,O,9 is labelled as (100 + x) % where x is the maximum mass of water which can react with P,O,, present in 100 gm mixture of H,PO, and P,O,o. If such a mixture Is labelled as 127 %. Mass of P,O,, in 100 gm of mixture, is () 7i gm (8) 47 gm (© 83 gm (0) 38'gm Mass of sucrose C,,H,,0,, produced by fixing 84 gm of carbon, 12 gm of hydrogen and 56 lit. O, at STP according to given reaction, Is C(s) + H,(G) + , (9) —> Cite, 1(5) (a) 138.5 (8) 155.5 (Q 172.5 (0) 199.5 1f 50. gm oleum sample rated/as 118% is mixed with 18 gm Water, then the correct option is (A) The resulting solution contains 18 gm of water and 118 gm H,SO, (B) The resulting solution contains 9 gm water and 9 gm H,S0, (C) The resulting solution contains only 118 gm pure H,SO, (0) The resulting solution contains 68,qmiof pure H,S0, An experiment is conducted in mass spectrometry taking sequentially 10;, SO} and He** one by one. Ifallithe ions are accelerated by same potential difference then the ratiOlof radil of all the ions undergoing circular motionwhen same magnetic field is applied in direction perpendicular to the motion of fonspare (A) 5y3:4V6:V2-—(B) SV F:4V3-V2 (©) STAY i (Oy SN3-4V6:1 In the quantitative determination of nitrogen using Duma’s method, N, gas liberated from 0.42 gm of a sample of organic compound was collected over water. If the volume of N, gas collected 100 was —— ml at total pressure 860 mim Hg at 250/K, % by mass of nitrogen in the organic 7 compound is [Aq. tension at 250 K is 24 pimHg and R = 0.08 L atm molt K-! ] 0 5 20 100 “ase (8) 5% oO7% oO>% Consider the following set of reactions cH, cue 0-H 9 \ , cH—C—o-H | Total ntimes + AgNO; —S | (excess) i 9 | ilver Salt — White residue g CH—C—0-n Corporate Offi Motion Education Pvt Ltd,, 394- Rajeev Gandhi Nagar, Kota © 80038995881F 0.1 moles of silver salt is taken & wt, of residue obtained is 54 gms then what will be the molecular mass of cH, —(CH—CH-~CH) cH, | | I ° Bee Gr ge (a) 495, (B) 309 (© 320 () 204 LONE OR MORE OPTIONS MAY BE CORRECT 9. An aqueous solution consisting of 5 M BaCl,, 58.8% w/v NaCl solution & 2m Na,X has a density of 1.949 gm/mi. Mark the option(s) which represent correct molarity (M) of the specified ion, [Assume 100% dissociation of each salt and molecular mass of X* Is 96] (A) [Cr] = 204 (B) [Nav] = 11M (C) [Total anions] = 20.5 M (0) [Total cations} 15M 10, A mixture of 100 ml of CO, CO, and 0, was sparked. When the resulting gaseous mixture was passed through KOH solution, contraction in volume was found to be 80 ml, the composition of initial mixture may be (in the same order) (A) 30 mi, 60 mi, 10 mi (B) 30 mi, 50 mi, 20 mi (©) 50 ml, 30 mi, 20 mi (D),30 ml, 40 mi, 30 mi Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588MOLE CONCEPT Motion DPP - 13 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION SINGLE CORRECT QUESTIONS 1. 40 gm of a carbonate of an alkali metal or alkaline earth metal containing some inert impurities was made to react with excess HCI solution. The liberated CO, occupied 12.315 lit. at 1 atm & 300 K, The correct option is (A) Mass of impurity is 1 gm and metal is Be (B) Mass of impurity is 3 gm and metal is Li (©) Mass of impurity is 5 gm and metal is Be (D) Mass of impurity is 2 gm and metal is Mg The percentage by mole of NO, in a mixture of NO,(q) and NO(a) having average molecular mass 34is: (A) 25% (B) 20% (©) 40% (0) 75% The minimum mass of mixture ofA, and B, required tolproduce at least 1 kg of each product is (Given At. mass of ‘A’ = 10 At, mass of 'B' = 120) 5A, + 2B, —>2AB, + 44,8 (A) 2120 gm (B) 1060 gm (©) 560.gm (©) 1660. 9m ‘The mass of €O, produced from 620 gm mixture of GJHj0)& O., prepared to produce maximum energy is (A) 413.33. gm. (B) 593,04. gm / (C) 440 gm (0) 320 om, ‘Assuming complete precipitation of AgCI, calculate the sum of the molar concentration ofall the ions if2 lit of 2M Ag,SOjiis mixed with 4 lt of 1 M NaCl solution is = (a) at (6) 2M (3m (D)25™ 12.59m of fuming H,SO, (labelled 112%) is mixed\With 100 lit water. Molar concentration of H* in resultant solution is [Note : Assume that H,SO, dissociate completély and there is no change in volume on mixing] 3 3 350 ©) 700 2 A a9 (8) 700 «© 350 74 gm of a sample on complete combustion gives 132 gm CO, and 54 gm of H,0. The molecular formula of the compound may be A) GH (8) CyH,00 (©) Chg (0) ¢,H,0, ‘The % by volume of C,H, in a gaseous mixture of C,Hy., CH, and CO is 40. When 200 ml of the mixture Is burnt in excess of O,. Find volume (in ml) of CO, produced. (A) 220, (B) 340 (¢) 440, (0) 560 Corporate Office : Motion Education Pvt. Ltd, 383 Rajeev Gandhi Nagar, Kota © 8003899588 | Pages IONE OR MORE OPTIONS MAY BE CORRECT 9. 10. Given following series of reactions () NH, +0,—>NO+H,0 (1) NO+0,—>No, (I) NO, +H,0—+HNO,+HNO, (IV) HNO, —> HNO, + NO + H,0 Select the correct option(s): (A) Moles of HNO, obtained is half of moles of Ammonia used if HNO, is not used to produce HNO, by reation (IV) 100 (8) ~;- % more HNO, will be produced if HNO, Is used to produce HNO, by reaction (IV) than if HNO, Is not used to produce HNO; by reaction (IV) L (©) If HNO, Is used to produce HNO, then -;* of total HNO, Is produced by reaction (IV) (0) Moles of NO produced in reaction (1vy/is 50% of moles of total HNO, produced Solution(s) containing 40 gm,NSOH is/are (A) 50 gm of 80% (w/w) NaOH (B) 50 gm of 80% (w/v) NaOH [4,a, = 1.2 den/mil] (C) 50 gm of 20 MiNaOH [4,.,,, = 1 g/ml] (0) 50 gm of Sef NaOH Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588 | Page: 2MOLE CONCEPT Motion DPP - 14 urtring potent trough eaacation JEE [MAIN + ADV.] DIVISION 1. ‘The pair of species having same percentage (mass) of carbon Is: (A) CH,COOH and C,H,,0, (B) CH,COOH and C,H,OH (C) HCOOCH, and C.3H;.0,5 (0) C,H,205 and C,3H,203, 200 ml of a gaseous mixture containing CO, CO, and N, on complete combustion in just sufficient amount of 0, showed contraction of 40 ml when the resulting gases were passed through KOH solution it reduces by 50 % then calculate the volume ratio of Vig, : Veo : Vy, in original mixture, (4ari:s (B)2:3:5 (14:5 (o)1:3:5 What volumes should you mix of 0.2 M NaCl and 0.1 M CaCl, solution so that in resulting solution the concentration of positive ion is 40% lesser.than concentration of negative ion. Assuming total volume of solution 1000 mi. (A) 400 mi NaCI , 600 ml CaCl, (B) 600)m! Naci, 400 mi CaCl, (C) 800 mi NaC,’ 200 mi CaCl, (D) None of these ‘An iodized salt contains 0.5 % of Naf. A person consumes\3,gm of salt everyday. The number of iodide ions going into his body everyday is (a) 10 (B),602«10-7 — (C)y6I0Z)x 10° —(D) 6.02 x 102 ‘The mass of P,O,, produced if 440 gm of P,S, is mixed with 384 gm BFO, is P,S, +:Os—=>1Pj0ig-+SO, (A) 568 gm. (8) 426 gm (©) 284.4m. (0) 396 gm \Volurfte Of water which must be addedito 8M HCI to make 2 lit. of 7.3% w/v HEl)Solution is (a) 1.5 Tt (8) 0.5 iit (© ii, (0) 2 it. Molarity of aqueolis NaOH solution will be, if mole fraction of NaOH in the solution is 0.5. [Given : density of pure NaOH = 4 gm/ml] (A) 76.92 (8) 35.71 (©) 68.96 () 26.46 Calculate percentage change iiM,.,, of the mixture, if PClyindergo 50% decomposition. PCI, —> PCI, + Cl, (A) 50% (B) 66.66 % (©) 33.33% (0) Zero SUBJECTIVE QUESTIONS 9. 10. Calculate the volume of a 20% (w/w) HCI solution of density 2.5 gm/mil required to prepare 363, Gm of ASCI, according to the following equations. 2KMnO, + 16 HC|—> 2KCI + 2MnCl, + SCI, + 8H,0 2As + 3Cl, —> 2AsCl, Given that the yield of IF and 11" reaction are 60% and 80% respectively and sufficient amount of "As" and KMnO, is present. [As = 75, Cl = 35.5] ‘A mixture containing N, and H, in 2 : 3 by mole is partially converted into NH,. The NH, formed is completely neutralized by 200 ml of 2.5 M H,PO,, Calculate the vapour density of frst mixture (containing W,, H, and NH,) If NH, Is not consumed in Il reaction. Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588MOLE CONCEPT Motion DPP - 15 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION SINGLE CORRECT QUESTIONS 1. For which of the following solution, minimum amount of NaOH is required for complete neutralisation. [Assume complete dissociation of acid ] (A) 50 ml H,SO, solution [basicity = 2] (dyauzuon = 2.am/ml) , % w/w (B) 50 mi HPO, solution [basicity = 3] (deouion = 2.9m/ml) , % w/w (C) 100 mi FICI solution (basicity (0) 100 ml HNO, solution [basicity 98 = 1] (eucon = 1.5.9m/ml) , % w/w = 36.5 1.5 gm/ml)’, % w/w 6.5 '2V' ml of 1 M Na,SO, is mixed with 'V' ml of 2M Ba(NO,), solution, (A) Molarity of Na* ion in final solution can’t be calculated as V is not known, 2 (®) Molarity of 8280, in final solution is = Mi 4 (©) Molarity of NO; in Final solutigf is 5 M. 2 (0) Molarity of NO; is final solution is M. 500 ml of a H,Oy6lution ongomplete,decomposition produces 2 moles 6fH,0. Volume strength of H,O, solution is [Given : Volume of O, is measured at 1atm and 273K] 12 w (8) 22.4 (©) 5.6V (0) 44.8 ‘A gaseous Féaction, 3A > 28 is carried out Im a)0.0821 litre closed containeh initially containing/1 mole of gas A. After sufficient time a curve of, P (atm) vs T (K) is plotted and the angle with x-axis was found to be 42.95°. The degree of assOtiation of gas A is n 42.95 = 0.8] (8) 06 (os (0) 0.8 100 ml of 0.1 M Na,SO, is mixed with 100 ml of 0.2M NaCI solution, Molarity of Na* ion in final solution. If final solution has density 1.2. gm/milt (A) 0.4 (8) 0.2 (Qos (0) 0.15 Number of moles of NH, produced if 140 gm of N, reacts with 40 gm of hydrogen. [Given % yield of reaction is 50%) (a) 12 (B) 10 (os (oye 1 litre of a gaseous organic compound C,H,0 is completely burnt in an excess of oxygen, The contraction in volume in litre is (assume water get condensed out). (142-22) 5 (1-22 “” Ce o GaSe [PF Molarity of aqueous solution of NaOH having mole fraction 0.2 and density 1 gm / ml. (a) 13.8 (8) 8.9 (© 12.2 (D) 10.1 Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588SUBJECTIVE QUESTIONS 9. 2AgNO,(aq) + Fe(s) —> Fe(NO,),(aq) + 2Ag(s). 100 ml solution of AgNO, was mixed with 11.2 gm Fe. The mass of the total solid at the completion of reaction was found to be 35.2 gm. Calculate molarity of AgNO, in the solution and the remaining mass of Fe. 10. Platinum rods are known for the "adsorption tendencies" for hydrogen gas. H, molecules get attached to the surface of platinum forming a monolayer. Each molecule can be considered as a sphere of radius V7<10""?m, covering a surface area of xr?, One gram of platinum (surface area = 22 m?) is dipped in 1 litre of 0.2 M H, solution. (i) 16,02 % of surface area of platinum is covered by monolayer of H, gas calculate number of molecules of H, attached.. (ii) Assuming no change in volume of solution what would be final molarity of H, solution, Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588