() Find the correlation time (Te) for each temperatare in the given range of

temperatures.
(a) For the high temperature side of TImin, the formula for Te is given by

for Tc 1S given by
(b For the low temperature side of TImin, the formula

CTI 2
Do
in
Draw straight lines joining the points
(iv) Plot In(T) as a function of 1000/T. and
regions) independently
three regions ( high, jatemedtate and low temperature

find the slopes of hese-tmee straight lines from

ihree regións using corresponding slopes
Calculate Activation energies in
the formula
Kcal/mol
0.2389 x Kx Nox Slope
Ea
where
and
= 6.02 x 104 mol
Avagadro Number,',No
JK
1.38 x *104
constant; K
=

Boltzman

factor
the pre-exponential
extrapolation, which gives
Find the 'y' intercept by

(Teo) calculate numerical factor C

of relaxation constant C,
From the observed value
(v)
using the relation given by

C 4
in
infer the type
/nature of molecular mbtion occurring
From the estimated yalue of Ci,
(NH4CI).
the given diamagnetic solid
 Pan -B
1 NMR SLR time (Ti) data as a function of temperatureof NH,CI (300K).

Sl.No.
Temperature (K) SLRtime, Ti (sec
379.82953 2.57
358.48718 1.87
341.88034 1.26
321.67787 0.899
298.74824 0.523
289.9223 0.333
277.8318 0.2377 HT
9 267.19393 0.171
256.96372 0.132
254.25884 0.0963
2 251.67996 0.0657
13 250.83402 0.0398
4 246.19627 0.0337
15
240.94818 0.0249
16 235.54906 0.015
17
225.09848 0.00714
18
220.37596 0.00572
19
215.48009 0.0044
20
211.14865 0.00305
205.27558 0.00231.
200.5294 0.00189
194.41447 0.00172
189.38318 0.00181
184.18992
25
0.00197
178.58737 0.00262
26 173.7227
27
168.73394
0.00341 L M
0.00476
28
29
163.30263 0.00832
158.71756 0.0123
30
153.40011 0.0202
148.08058 0.0345
32
142.27787 0.0602
 Datn
PART-A
Experiment NMR 1H NMR SLR time (T1) calculations for the
sample MAPF6 at 247K (21 MHz)
H2fs 280 K
delay time (t) in ms Magnetization (Mo) in mv
-176
3 -163
-147
7
9
-122
-96
1
12 -78
1 -43
17 32
20
21
22 24
25 33
30 68
85 97
40 119
45 127
50 146
60 173
75 193 '

100 208
211
150
200 212
300
216

.
 aytime ( Moms (Y ) |
-81| Coiaimd Aamnon iu HenaPlu
3
4

.T14* \*2oy (yins 2F

37.2 m
28) H - Pvm
30 5.5
3 12.5 luwihe
3 18
22
40 27.
45
50
32.
T 280 K eguenty: a 334 MM
36
20 60 47.
70 58.
22 80
100 7
125 80
25 150
6 2001.

v mvevAi m Recwwy
T 38.18 0.333 X
0.8

Ma
M * - g*est(

T14* T.
Ma
F1D

MVFIpuvh
Tin