ZAMIL SHIPYARDS

COSHH ASSESSMENT HSE-CA-000

Substance used: EP4920 Polyester Catalyst

Manufacturer: Eager Polymers
Description of product: Methyl Ethyl Ketone Peroxide

Emergency telephone number Zamil: 0138696465 Manufacturer: 773-807-4314

Location of process Composite Workshops
Activity being carried out?
Employees Contractors Public
Identify the persons at risk:
(Including trainees) x x x
Describe the activity or work process.
(Include how long and how often this is
carried out and the quantity of substance
used.
Classification under CHIP/CLP

Corrosive Environment Explosive Flammable Long Harmful/ Oxidising Toxic Pressurised

Hazard Term irritant Container
Hazard

Hazard Type
Gas Vapour Mist Fume Dust Liquid Solid Other

Route of Exposure
Inhalation Absorption Ingestion Injection

Workplace Exposure Limits (WELs) please indicate n/a where not applicable
Long-term exposure level (8hrTWA): Short-term exposure level (15 mins):

State the Risks to Health from Identified Hazards

Skin Absorption: Severe skin irritant, causes redness, blistering, and oedema.
Eye Contact: Eye contact causes severe corrosion and may cause blindness.
Ingestion: Human systemic effects by ingestion: changes in structure or function of oesophagus, nausea, or vomiting, and other
gastrointestinal effects.
Inhalation: Moderately toxic by inhalation.
EFFECTS OF OVEREXPOSURE
Prolonged inhalation of vapours may cause mucous membrane irritation and vertigo. There are no known medical conditions,
which are recognized as being aggravated by exposure.
Control Measures: (for example extraction, ventilation, training, supervision). Take account of those substances that are
produced from activities undertaken by another employer’s employees.
Eyes – Immediately flood the eye with plenty of water for at least 15 minutes and get medical attention.
Ingested – Wash out mouth with water. Do not induce vomiting. Keep warm and at rest. Get medical attention urgently.
Skin – Remove contaminated clothing and wash skin thoroughly with water. If irritation persists, get medical advice.
Inhalation – Remove from exposure. Keep warm and at rest and get medical attention.
Personal Protective Equipment
Personal Protective Equipment (state type and standard)

chemical goggles or face shield

Dust mask Visor

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COSHH ASSESSMENT HSE-CA-000

If airborne concentrations are expected to

exceed acceptable levels wear a
IOSH/MSHA approved air-purifying Safety goggles recommended. Permanent eyewash is
Respirator espirator with an organic vapor cartridge Goggles highly recommended.
or canister. When using respirators refer to
OSHA’s 29CFR 1910.134.
Protective gloves recommended, solvent
resistant, such as butyl rubber, nitrile or
neoprene.
Gloves Overalls

Footwear Other

First Aid Measures

Description of first aid measures
Skin: Immediately remove any contaminated clothing. Wash contaminated area thoroughly with soap and copious amounts of
water for at least 15 minutes. If irritation or adverse symptoms develop seek medical attention.
Eyes: Remove any contact lenses at once. Flush eyes with water for at least 15 minutes. Ensure adequate flushing by separating
the eyelids with fingers. If irritation or adverse symptoms develop seek medical attention.
Ingestion: Contact a physician, hospital, or Poison Control Center at once. DO NOT INDUCE VOMITING.
Inhalation: Remove to fresh air, if coughing, breathing becomes laboured, irritation develops or other symptoms
develop, seek medical attention at once, even if symptoms develop several hours after the exposure.
Storage & Handling
HANDLING AND STORING:
Keep containers closed to prevent contamination. Rotate stock using the oldest material first. The activity and stability of MEKP is
directly related to the shipping and storage temperature history. Cool storage at 80°F or below is recommended for longer shelf
life and stability. Prolonged storage at elevated temperatures of 100°F and higher will cause product degradation, gassing and
potential container rupture which can result in a fire and/or explosion.

OTHER PRECAUTIONS:
MEKP should never be added to hot solvents or monomers as a violent decomposition and/or reaction may result. When using
spray equipment, never spray raw MEKP onto curing or into raw resin or flues. Keep MEKP in its original container.
DO NOT STORE WITH FOOD OR DRINK. DO NOT USE NEAR FOOD OR DRINK.
Disposal of Substances & Contaminated Containers
Prevent material from entering drains, sewers, streams, etc. Immediately dispose of waste material at a approved hazardous
waste management facility in accordance with state and local regulations.

Fire Fighting Measures

Water from a safe distance – preferably with a fog nozzle. In case of very small fires, other means such as carbon dioxide, foam or
dry chemical extinguishers may be effective. Dry chemical combined with MEKP formulations may re-ignite. Light water additives
may be particularly effective at extinguishing MEKP fires.
Water X AAAF X CO2 X Dry Powder

This assessment must be shown to all operatives working with this substance

Is exposure adequately controlled? Yes x No

Risk Rating Following Control Measures

High Medium Low

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COSHH ASSESSMENT HSE-CA-000

Date of Assessment Review Date Assessed by Approved by Authorised by

Revision 1.0 Issue Date 06/08/2020 Page 3

This copy is controlled.