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Received: 7 February 2023 | Revised: 17 May 2023 | Accepted: 30 May 2023

DOI: 10.1002/ese3.1500

ORIGINAL ARTICLE

Computational fluid dynamic analysis of hydrogen‐


injected natural gas for mixing and transportation
behaviors in pipeline structures

Shuangjie Yan1 | Guanwei Jia1 | Weiqing Xu2,3 | Rui Li4 |


YangHui Lu5 | Maolin Cai2,3
1
School of Physics and Electronics, Henan University, Kaifeng, China
2
School of Automation Science and Electrical Engineering, Beihang University, Beijing, China
3
Pneumatic and Thermodynamic Energy Storage and Supply Beijing Key Laboratory, Beijing, China
4
General Institute of Science and Technology of National Petroleum and Natural Gas Pipeline Network Group Co., Ltd, Langfang, Hebei, China
5
State Power Investment Corporation Research Institute Co., Ltd, Beijing, China

Correspondence
Guanwei Jia, School of Physics and Abstract
Electronics, Henan University, Kaifeng The transportation of hydrogen is a weak link in the large‐scale development
475004, China.
Email: jiaguanwei@henu.edu.cn
of the hydrogen energy industry. Injecting hydrogen into the natural gas
pipeline network for transportation is an efficient way to achieve the large‐
Funding information scale, long‐distance, and low‐cost transportation of hydrogen. Hydrogen can
Science and Technology Research Project
of Pipechina, Grant/Award Number:
lead to hydrogen embrittlement in natural gas pipelines and cause safety
WZXGL202104; Science and Technology incidents if hydrogen and natural gas are not mixed uniformly. Therefore, it is
Development Project of Henan Province, necessary to study the blending process and blending uniformity of hydrogen
Grant/Award Number: 222102220090; The
Fundamental Research Funds for the and natural gas. In this study, a three‐dimensional model of the hydrogen‐
Central Universities, injected natural gas pipeline was constructed. The effects of hydrogen
Grant/Award Number: YWF‐21‐BJ‐J‐613;
injection inlet and turbulator configuration on the mixing process of hydrogen
State Power Investment Corporation
scientific research project, and natural gas were investigated using a computational fluid dynamics
Grant/Award Number: B1‐ approach. The results show that increasing the number of hydrogen injection
KYB12022QN02; The Beijing Outstanding
inlets shortens the distance L98% of uniform mixing of hydrogen and natural
Young Scientists Program,
Grant/Award Number: gas. Increasing the radial distance r from the initial hydrogen mixing positions
BJJWZYJH01201910006021; The China to the center of the pipeline will shorten the distance for uniform gas mixing
Postdoctoral Science Foundation,
Grant/Award Number: 2021M701096;
in the pipeline. The addition of turbulator configurations in the pipeline
National Natural Science Foundation of significantly reduces the distance to uniform gas mixing. Changing the
China, Grant/Award Number: 51875012 distance Lturb from the turbulator to the initial mixing position further
shortens the distance between hydrogen and natural gas mixing uniformly.
The results of this study provide a reference for the structural design of the
hydrogen–natural gas mixing pipeline and the gas distribution state during the
mixing process.

This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided
the original work is properly cited.
© 2023 The Authors. Energy Science & Engineering published by Society of Chemical Industry and John Wiley & Sons Ltd.

Energy Sci. Eng. 2023;1–17. wileyonlinelibrary.com/journal/ese3 | 1


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2 | YAN ET AL.

KEYWORDS
computational fluid dynamics, hydrogen distribution, hydrogen‐injected natural gas,
pipeline structure

1 | INTRODUCTION However, injecting hydrogen into natural gas changes


the flow state and thermodynamic properties of the
The increase in fossil energy consumption has led to a original gas in the pipeline and affects the gas delivery
global ecological crisis.1 It is imperative to improve the state. Nonuniform mixing of hydrogen and natural gas in
energy mix and replace fossil fuels with noncarbon fuels the pipeline increases the probability of hydrogen embrit-
to achieve carbon neutrality. The Paris Agreement tlement. The effect of hydrogen embrittlement on the
provides direction and plans for a carbon‐free future whole equipment of the hydrogen mixing natural gas
and carbon neutrality. China,2 the United States,3 the transmission system, such as compressors,13 pipelines,14
European Union,4 and the Intergovernmental Panel on welds,15 valves,16 storage,17 and so on. Eames et al.18
Climate Change5 are promoting the development of investigated the effect of T‐joint geometry (diameter ratio,
global renewable energy to reduce carbon emissions. direction of hydrogen injection) and hydrogen injection
Hydrogen energy is a potential energy carrier for the rate on the mixing process of natural gas and hydrogen.
“power‐to‐gas” conversion of renewable energy sources The results showed that high hydrogen concentration on
and a bridge between fossil and renewable energy the pipeline wall significantly increases the risk of
sources.6 It is expected that hydrogen will account for hydrogen embrittlement and pipeline rupture. Hydrogen
more than 19% of final energy demand by 2050.7 injection from the bottom side of the pipeline facilitates
However, the higher transportation cost of hydrogen hydrogen and natural gas mixing. Baowei and colleagues19
energy leading to lower utilization is currently an investigated the mixing distribution of hydrogen and
important factor limiting its development. According to natural gas in the chamber with low‐, medium‐, and high‐
the analysis, the transportation cost of hydrogen pressure injection modes. Villuendas et al.20 used CFD
accounts for 30%–40% of the final hydrogen selling methods to simulate the mixing and transport behavior of
price.8 The use of pipelines for the transport of pure natural gas and hydrogen. The gases were well mixed at
hydrogen allows for low transport costs and high speed, 20D–30D pipe lengths at the mixing station. The transport
allowing for the massive transport of hydrogen. However, behavior of the gas in pipes of different diameters was also
each mile of a pure hydrogen pipeline cost is three times investigated. Zhou et al.21 took 33 h for the ratio to regain
more expensive to build than a natural gas pipeline.9 The stability in the pipeline network by changing the hydrogen
current global mileage of natural gas pipelines in service mixing ratio (HMR) at the inlet of the pipeline in a natural
has exceeded 1.35 × 106 km. The total mileage of trunk gas pipeline system. The propagation rate of the hydrogen
gas pipelines in China has reached 1.16 × 105 km,10 concentration is much lower than the pressure and flow
accounting for 8.6% of the global total. It provides the rate. Kuczyński et al.22 concluded that the content of
basis for the large‐scale and long‐distance pipeline hydrogen should not exceed 15%–20% for long‐distance
network transportation and distribution of hydrogen. transport. Dz et al.23 studied the relatively small energy
Mixing hydrogen with natural gas in a certain volume loss to the natural gas pipeline system caused by the input
fraction and using existing natural gas pipelines to of hydrogen mixed with natural gas at the outlet location
transport hydrogen is the best method.11 In 2017, the of the natural gas pipeline network. Kong et al.24 studied
“HyDeploy” project in the United Kingdom was put the effect of the structure of a Kenics static mixer
into operation, enabling the small‐scale provision of (KSM) static mixer on the mixing process of hydrogen
hydrogen‐blended natural gas.12 In 2019, Germany's and natural gas. The distribution and number of mixer
Avacon increased the volume fraction of hydrogen in arrangements were optimized based on the results of the
the natural gas pipeline network to 20%. The 2021 project study. Dell'Isola et al.25 injected hydrogen into natural gas
“Key Technology Research and Application Demonstra- and analyzed the effect of hydrogen injection on the flow
tion of Natural Gas Hydrogen Mixing,” in which the rate, relative density, specific heat, and speed of sound of
State Power Investment Group is involved, is expected to the gas. Li et al.26 investigated the physical properties
deliver 4.4 × 106 m3 of hydrogen to Zhangjiakou city of hydrogen mixed with natural gas. To ensure the
annually. These small‐scale demonstration projects stability of the physical properties of the mixtures of
provide technical and practical experience for the large‐ hydrogen–natural gas, the HMR should be controlled
scale application of hydrogen‐injected natural gas. within 30%. Guandalini et al.27 studied the effect of
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YAN ET AL. | 3

hydrogen injection on the components, density, velocity of processes. There is a lack of studies on the mixing process
fluid, and pressure distribution of natural gas. Hydrogen and mixing uniformity of hydrogen and natural gas.
injection enhances the gas perturbation in the pipeline The physical properties of natural gas and hydrogen are
network and the density of the gas decreases. The effect of different, and the mixing process is complicated. Further
hydrogen injection on the pressure drops in the pipeline study of the mixing process and mixing uniformity of
network is negligible (the difference is less than 0.1%). hydrogen and natural gas can provide data reference and
Abd et al.28 studied the effect of different HMRs on the guidance for natural gas–hydrogen mixing projects. The
transport properties of natural gas. Hydrogen mixing number of hydrogen inlets, the initial mixing positions of
reduces the density of natural gas; a 10% HMR records an hydrogen, and the installation positions of turbulators
11.78% reduction in the density of natural gas. Hydrogen in the pipeline were changed. The effect of the pipeline
mixing increases the pressure loss on the transport structure on the mixing process and mixing uniformity of
pipeline; a 10% HMR leads to a 5.39% increase in the hydrogen and natural gas was investigated. Shortening the
pressure drop of the gas. Zhang et al.29 investigated the distance for uniform mixing of hydrogen and natural
effect of different HMRs on the natural gas transmission gas can reduce hydrogen aggregation during hydrogen‐
process. The results showed that hydrogen mixing can blended natural gas delivery.
reduce the frictional resistance of the pipeline. The higher
the HMR, the higher the volume flow rate at the outlet.
The pressure drop of the pipeline increases with the 2 | GEOMETRIC M ODEL
increase of the HMR. Liu et al.30 compared and analyzed
the mixing effect of KSM‐type static mixer, S‐shaped static To study the influence of pipeline structure on the mixing
mixer, orifice plate static mixer, and venturi static mixer process of hydrogen and natural gas, two types of mixing
on different gas sources of natural gas. The best mixing pipeline models are constructed. The structural configura-
effect had been found in the KSM‐type static mixer. Kong tion of the pipeline is shown in Figure 1. Type A adjusts the
et al.31 showed that the addition of an SK‐type static mixer number of hydrogen injection inlets (NHIIs) and the initial
in the manifold can significantly reduce the distance of mixing positions of hydrogen; Type B is to add turbulators
uniform gas mixing. The addition of a mixer improved the on the basis of Type A and adjusts its installation position
mixing efficiency of natural gas. Most studies on hydrogen accordingly. Hydrogen is injected into the natural gas
mixing with natural gas have focused on the effects pipeline through a 90° bend pipeline. When the NHII = 1,
of hydrogen mixing on gas properties and transport the initial mixing position of hydrogen is set at the center of

FIGURE 1 Hydrogen injection pipeline structure configuration. NHII, number of hydrogen injection inlet.
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4 | YAN ET AL.

the natural gas pipeline; When NHII ≥ 2, the initial mixing natural gas. The calculation formula of the density ρ of
positions of the hydrogen are uniformly distributed in a the mixed hydrogen and natural gas is
circle around the center of the pipeline. The initial mixing
position of the hydrogen is adjusted by adjusting the radial Pop + P
RT i Mi
distance r from the hydrogen pipeline to the center of the ρ= Y
, (1)
natural gas pipeline. Each hydrogen injection port corre- i

sponds to a circular cylinder, and the three turbulator


models designed are shown in Type B in Figure 1. The where ρ is the density of mixed gas, kg/m3; Pop is the
installation position of the turbulators is adjusted by working pressure of the mixed hydrogen gas, Pa; P is
changing the distance Lturb from the turbulator to the initial the local relative pressure with respect to Pop, Pa; R is the
mixing position. The hydrogen injection into the pipeline is molar gas constant, J/(mol K); T is the gas temperature,
mainly concentrated in the area 0–150 mm from the initial K; Yi is the mass fraction of gas i, and Mi is the relative
mixing position. The turbulator was adjusted to vary molecular mass of gas i.
between Lturb = 50 and Lturb = 150 mm from the initial The compression factor z of the gas mixture is
mixing position. To mix the hydrogen and natural gas calculated as
sufficiently, the length of the pipeline is set to 22D, where D
is the diameter of the natural gas pipeline. The diameter of Pr Vr
z = Zc , (2)
the single hydrogen injection inlet is d1 = 80 mm, and Tr
the diameter of the turbulator is D1 = 40 mm. The HMR in
the pipeline is controlled by adjusting the diameter d of the where z is the compression factor of the gas mixture, Zc is
hydrogen injection inlet. The diameter of the hydrogen the critical compression factor, Pr is the comparison
injection inlet is dn = (1/n)1/2 × d1, where n is the NHIIs. pressure, Vr is the comparison volume, and Tr is the
Lmix indicates the mixing distance between hydrogen and comparison temperature.
natural gas in the pipeline; L98% represents the distance to The viscosity of the gas mixture μ is calculated as

iM=1 x i μi M 1/2
98% uniformity of mixing of hydrogen and natural gas in the

iM=1 x i M 1/2
pipeline. The specific parameters of the pipeline structures i
μ= , (3)
are shown in Table 1. A total of 21 monitoring cross‐sections i
were taken at 1D millimeter intervals in the pipeline from
the initial mixing position. Thirty‐three monitoring points where μi is the kinetic viscosity of gas i, N s/m2; and xi is
are set up within each cross‐section, which are uniformly the volume fraction of gas i.
distributed around the center of the pipe (the black dots in Component transport equation:
the section are the monitoring points).
 (ρYi ) 
+ div(ρ u Yi ) = div(Di grad Yi ), (4)
t
3 | COMPUTATIONAL M ODEL
where Di is the diffusion coefficient of component i,

3.1 | Mathematical equation s/m2; and u is the vector velocity of the fluid, m/s.
The distribution of hydrogen and natural gas in the
When hydrogen and natural gas are mixed, the volume of pipeline is predicted by solving the component transport
the mixed gas is the sum of the volumes of hydrogen and equation.

TABLE 1 Model parameters.


Species Parameter NHII: one NHII: two NHII: four NHII: eight
Natural gas pipeline Pipeline diameter(D/mm) 300
Hydrogen injection inlet configuration Inlet diameter (d/mm) 80 56.6 40 28.3
Radial distance (r/mm) 0 40, 70, 90, 110
Turbulator configuration Turbulator diameter (D1/mm) 40
Distance to initial mixing position 50, 100, 150
(Lturb/mm)
Abbreviation: NHII, number of hydrogen injection inlet.
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YAN ET AL. | 5

The flow of mixed hydrogen and natural gas in the  (ρT )  (ρvi T )  (ρνj T )  (ρvk T )
+ + +
t x y z
   
pipeline follows the continuity equation, momentum
  k  T    k  T 
  +  
   y  c p  y 
equation, and energy equation. The expression is as follows:
x  cp x 
The continuity equation is the equation of mass = (8)

  k  T 
conservation. Any fluid problem must satisfy the law of
  + ST ,
 z  c p  z 
conservation of mass. The sum of the masses flowing
+
out per unit time is equal to the masses reduced within
the control body due to density change at the same
time interval. The velocity and density within the flow where k is the heat transfer coefficient of the gas,
are solved by the continuity equation. Continuity w/(m2 k); cp is the specific heat capacity of the gas
equation: mixture, J/(kg K); T is the temperature, K; ST is the
internal heat source of the fluid, w/m3.
ρ  (ρvi )  (ρvj )  (ρvk ) The velocity values and HMRs of the gases at
+ + + = 0, (5)
t x y z different positions in the pipeline are counted through
33 monitoring points. The velocity COV32 is the ratio of
where x is the distance from the initial mixing position, the standard deviation to the mean value, which reflects
m; vi, vj, and vk are the components of the velocity vector the flow distribution of the mixed gases in the pipeline,
in the x, y, and z directions. and the formula is

 (vi − v¯)2 ,
The flow velocity and turbulence intensity in the fluid
n
domain are predicted analytically by solving the conser- s 1 1
COV = = (9)
vation of momentum equation. Momentum conservation v¯ v¯ n − 1 i =1
equation:
where n is the number of monitoring points selected in
 (ρvi ) p the cross‐section, vi is the velocity of the monitoring
t
+ div(ρvi v¯i ) = div(μ grad vi ) − x
+ Si,
point, m/s; v is the average value of the velocity over the
 (ρvj ) p
t
+ div(ρvj v¯j ) = div(μ grad vj ) − y
+ Sj, monitored section, m/s.
 (ρvk ) p The mixing uniformity is used to evaluate the
t
+ div(ρvk v¯k ) = div(μ grad vk ) − z
+ Sk ,
mixing of hydrogen and natural gas in the pipeline.
(6)
The greater the mixing uniformity, the more uniformly
the hydrogen and natural gas are mixed. Celik et al.33
where v¯i, v¯j, and v¯k are the fluid velocity vectors, m/s; were the first to propose the use of mixing uniformity
vi, vj, and vk are the components of velocity in the x, y, (mixing index) to evaluate the degree of mixing of a
and z directions, m/s; Si, Sj, and Sk are the generalized mixture. Montante et al.34 and Zhuang et al.35 used a
source terms for momentum conservation, N/m3, mixing uniformity greater than 95% to determine
whether the gas in the vessel was well mixed. With
 vj
Si = Fx +

x (μ ) + ( μ ) + (μ )
 vi
x

y x

x
 vk
x
reference to industry standards, it is considered that the
gas is well mixed with a uniformity of mixing U ≥ 95%.
 
+ x
(λ div( v )), Therefore, the mixing uniformity U ≥ 98% is used in
 vj this study to determine whether the hydrogen and
Sj = Fy +

x (μ ) + ( μ ) + ( μ )
 vi
x

y y

x
 vk
y natural gas are uniformly mixed in the pipeline. The
(7)
  gas mixing uniformity U is calculated by the following
+ y
(λ div( v )),
formula:
 vj
Sk = Fz +

(μ ) + ( μ ) + (μ )
 vi    vk

 
1 n  ci − c¯ 2
x z y z x z

 ,

n i =1  c¯ 

+ z
(λ div( v )), U=1− (10)

where Fx, Fy, and Fz are the components of the volume force
in the x, y, and z directions, and λ is the second viscosity. where ci the HMR at the monitoring points, and c is
The mixed transport of hydrogen and natural gas the average value of the HMR at the monitoring cross‐
obeys the equation of conservation of energy sections.
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6 | YAN ET AL.

3.2 | Boundary conditions The effects of four turbulence models (standard k−ε
model, renormalization group k–epsilon model, standard
Methane accounts for more than 90% of all components k−ω model, and shear stress transfer k–omega model) on
of natural gas.36 As far as the work in this manuscript is the simulation results are investigated with other
concerned, it is possible to use methane instead of boundary conditions unchanged. Taking the model with
natural gas for the analytical study. Methane is injected HMR = 10% and NHII = 2 as an example, Table 3
at the natural gas inlet. The inlet of hydrogen and natural presents simulation results obtained using different
gas was set to the velocity inlet, and the outlet was set to turbulence models. From Table 3, it can be seen that
the outlet flow boundary. The natural gas pipeline inlet the errors of the simulated values of the HMR at the
velocity is set to 8 m/s (flow rate: 1891.0 m3/h). The HMR outlet position are less than 5% using different turbu-
was adjusted by controlling the velocity of the hydrogen lence models. When utilizing the standard k–ε model, the
inlet. The specific values are shown in Table 2. The initial HMR at the pipeline outlet is 9.87%, exhibiting a
turbulence parameters at the inlet of the natural gas deviation of merely 1.3% from theoretical values and
pipeline and the hydrogen injection pipeline are the thus possessing minimal error. The turbulence model is a
same. The inlet turbulence intensity is set to 5% and standard k–ε turbulence model suitable for gas mixing
the turbulence viscosity ratio is set to 10. The turbulence calculations, which reduces the computational effort
intensity of the return flow at the outlet is 5% and the while maintaining the accuracy of the calculation.
turbulence viscosity ratio of the return flow is 10. Consequently, the standard k–ε model is chosen as the
The turbulator surface and natural gas pipeline walls final turbulence model.
were set to be smooth, adiabatic, and with nonslip
standard walls. The initial temperature of the wall is set
to 300 K. The heat flux of the wall and the heat exchange 3.3 | Mesh irrelevance testing
coefficient of the wall are both 0. The temperature of
both hydrogen and natural gas is set to 300 K. During the The quantity and quality of mesh partitioning are crucial
mixing of hydrogen and natural gas, the flow field of the to the simulation calculation process. The mesh division
gas in the pipeline changes in a complex way. Simulation not only determines the accuracy and convergence of
of the mixing process is computationally complex and the calculation results but also places a demand on the
large. The geometry of the model and the computed fluid hardware performance of the computer. There will be
domain have mirror symmetry. Setting the boundary of errors in the simulation, resulting in a slightly lower
the natural gas pipeline as a symmetric wall boundary HMR at the exit position compared to the theoretical
can reduce the computational effort. Using the compo- calculation value. The accuracy of the calculation, the
nent transport model, the calculation was solved using turbulence model, and the solution algorithm will cause
the Simplec algorithm. The pipeline was set up and filled errors. But the quality of mesh division is the main cause
with methane before hydrogen injection. Hybrid initial- of error. The tetrahedral and hexahedral meshing
ization was used to assign initial values to the computed methods were chosen for meshing the calculation area.
fields before starting the calculation. A sufficient number The walls of the model and the area around the turbulent
of iterations was set to bring the calculation to a flow device were locally meshed to provide a relatively
steady state. accurate calculation of the flow processes at the
boundaries. The mesh division of the pipeline is shown
in Figure 2.
TABLE 2 Boundary condition parameters. It is generally believed that the smaller the mesh size
Name Numerical value and the more meshes there are, the more accurate the
Operating pressure (Pa) 101,325
TABLE 3 Simulative results of different turbulence models.
3
Natural gas flow (m /h) 1891.0
Simulated Theoretical
Natural gas inlet 8 Turbulence models value value Error (%)
velocity (m/s)
Standard k−ε model 0.0987 0.1 1.3
Hydrogen flow (m3/h) 99.52 (5%); 210.11 (10%); 472.75
RNG k−ε model 0.0969 3.1
(20%); 810.42 (30%)
Standard k−ω model 0.0986 1.4
Hydrogen inlet velocity 5.5 (5%); 11.6 (10%); 26.1 (20%);
(m/s) 44.8 (30%) SST k−ω model 0.0977 2.3
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YAN ET AL. | 7

FIGURE 2 Mesh division.

TABLE 4 Verification of mesh irrelevance (HMR = 10%).


Average skew Average quality
Mesh Number of Number of factor of factor of HMR at the
Type characteristics nodes units the mesh the mesh outlet (%)
Eight NHII Sparse 49,161 189,752 0.21379 0.76382 9.86
Medium 102,061 384,984 0.20926 0.75607 9.85
Dense 211,286 816,936 0.20616 0.76165 9.85
Eight Sparse 167,506 818,685 0.22543 0.82467 9.85
NHII + turbulator
Medium 322,189 1,635,790 0.22371 0.83309 9.86
Dense 676,889 3,537,757 0.22102 0.83886 9.90
Abbreviations: HMR, hydrogen mixing ratio; NHII, number of hydrogen injection inlet.

results of simulation calculations. However, an excessive 4 | R ES ULT S AN D DI S C US S I ON


number of meshes leads to little improvement in
computational accuracy and also reduces the efficiency 4.1 | Effect of hydrogen injection inlet
of the computer. It is important to balance the configuration on mixing uniformity
computational accuracy with the number of meshes. A
pipeline model with a 10% HMR was chosen as a The hydrogen and natural gas in the pipeline were
representative. The mesh irrelevance was verified for subjected to turbulence and concentration differences for
three meshing methods: sparse, medium, and dense. The diffusion and eventual uniform mixing. In the mixing
results are shown in Table 4. Increasing the number of process of hydrogen and natural gas, the pipeline
meshes has little effect on the outlet HMR. The error structure is the main factor that affects the mixing
between the simulated and theoretical values of the HMR process. Changing the number of hydrogen inlets and the
is within 1.5%, which is in accordance with the standard. initial mixing positions of hydrogen, the HMRs were 5%
The evaluation coefficients are in the range of 0–1. The (A), 10% (B), 20% (C), and 30% (D). The variation of the
closer the skew factor is to 0, the better the quality of distance L98% for uniform mixing of hydrogen and
the mesh. The closer the quality factor is to 1, the higher natural gas in the pipeline is shown in Figure 3. When
the quality of the mesh. The skewness and mesh quality the initial mixing positions of hydrogen are close to the
were evaluated for the meshes. All three specifications center of the pipeline (r = 40 and 70 mm), the distance
met the requirements, and the mesh irrelevance was L98% of gas mixing uniformly in the pipeline decreases
verified. In this study, meshes of medium size were and then increases with the increase of the number of
selected. For the model of Type A, the mesh size was set hydrogen inlets. As the NHII increases, the effect of
to 20 mm. For the model of Type B, the mesh size was set mixing with multiple inlets is similar to that of blending
to 10 mm, and local mesh encryption was carried out on with a single inlet. Therefore, by continuing to increase
the turbulent part. the NHIIs, the distance L98% for uniform mixing of
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8 | YAN ET AL.

F I G U R E 3 Influence of hydrogen inlet configuration on the distance of gas mixing uniformity. (A) HMR: 5%, (B) HMR: 10%, (C) HMR:
20%, and (D) HMR: 30%. HMR, hydrogen mixing ratio; NHII, number of hydrogen injection inlet.

hydrogen and natural gas increases instead. When the Increasing the radial distance r can shorten the distance
initial mixing positions of hydrogen are far from the of uniform mixing of hydrogen and natural gas in the
center of the pipeline (r = 90 and 110 mm), the distance pipeline. The radial distance r increases and the distance
of gas mixing uniformity first decreases and then between the hydrogen pipe to the wall of the natural gas
gradually smooths out with the increase of the number pipeline becomes smaller. The injection of hydrogen into
of hydrogen inlets. Increasing the proportion of blended the natural gas pipeline increases the probability of
hydrogen, the distance L98% required for uniform contact between the hydrogen and the wall of the
blending of hydrogen and natural gas increases. In pipeline. The collision of hydrogen with the wall of the
general, the distance L98% for uniform gas mixing is natural gas pipeline increases the disturbance of gas in
effectively reduced by appropriately increasing the the pipeline. The increased perturbation facilitates faster
number of hydrogen inlets compared to single‐inlet and more uniform mixing of hydrogen and natural gas.
hydrogen injection. Therefore, with the increase of radial distance r, the
The initial mixing position of hydrogen is an distance between hydrogen and natural gas mixing
important factor affecting the mixing process of hydro- uniformly in the pipeline gradually decreases. The
gen and natural gas in the pipeline. The variation of the shortest distance to achieve uniform mixing of hydrogen
distance of gas mixing uniformly in the pipeline at and natural gas in the pipeline is achieved when the
different inlets of hydrogen injection for r = 40, 70, 90, radial distance r = 110 mm. At four HMRs, the distance
and 110 mm is investigated. At r = 40 mm, the distance to achieve uniform mixing of hydrogen and natural gas
for uniform gas mixing in the pipeline increases when in the pipeline is relatively short for NHII = 8 and the
the number of hydrogen inlets exceeds five or six. radial distance r = 110 mm. With the increase of HMR,
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YAN ET AL. | 9

the radial distance r becomes the main factor affecting gas. The radial distance r = 110 mm from the initial
the distance L98% of gas mixing uniformity. Selecting a mixing position of hydrogen to the center of the natural
suitable NHII and increasing the distance r from the gas pipeline is the relatively shortest distance for
hydrogen pipeline to the center of the natural gas uniform mixing of gas. At r = 110 mm, the NHIIs in
pipeline can be very effective in shortening the distance the pipeline and the installation position of the
between hydrogen and natural gas mixing uniformly in turbulators are adjusted. The variation of the distance
the pipeline. L98% required for uniform mixing of hydrogen and
natural gas for HMRs of 5% (A), 10% (B), 20% (C), and
30% (D) is shown in Figure 4. With the addition of the
4.2 | Effect of turbulator configuration turbulator, the disturbance of the gas in the pipeline is
on the distance of mixing uniformity enhanced compared to the absence of the turbulator.
The distance between hydrogen and natural gas
During the mixing of hydrogen and natural gas, the uniformly mixed in the pipeline is significantly reduced
hydrogen is mainly concentrated in the area between 0 with the installation of turbulators. By changing the
and 150 mm from the initial mixing position. To further installation position of the turbulator in the pipeline,
reduce the mixing distance between hydrogen and the distance between hydrogen and natural gas can be
natural gas, turbulators were added in the pipeline at further reduced.
Lturb = 50, 100, and 150 mm. The turbulator enhances As seen in Figure 4, with the addition of a turbulator,
the turbulence intensity of the gas in the pipeline and the distance between hydrogen and natural gas mixing is
enhances the mixing efficiency of hydrogen and natural significantly reduced. However, when the NHII is 1, if

F I G U R E 4 Influence of turbulator configuration on the distance of gas mixing uniformity. (A) HMR: 5%, (B) HMR: 10%, (C) HMR: 20%,
and (D) HMR: 30%. HMR, hydrogen mixing ratio; NHII, number of hydrogen injection inlet.
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10 | YAN ET AL.

the turbulator is installed in an inappropriate position, 4.3 | Hydrogen‐injected natural gas


it will increase the distance for uniform mixing of pipeline
hydrogen and natural gas. With an HMR of 5% and
turbulators set to Lturb = 50 and 50 mm, the hydrogen 4.3.1 | Visualization
and natural gas mix uniformly over a longer distance
than without turbulators. The distances of gas mixing To visualize the mixing process of hydrogen and natural
uniformly are 19.4D and 20D, respectively. The distance gas in the pipeline, the mixing process with an HMR of
of gas mixing uniformly without the turbulator is 16.9D. 10%, four‐inlet hydrogen injection and eight‐inlet hydro-
However, with the addition of turbulators at a distance of gen injection is taken as an example. The distribution of
100 mm from the initial mixing position, the distance of hydrogen gas inside the pipeline with different structures
uniform gas mixing was 58.8% of the distance without is shown in Figure 5. As can be seen in Figure 5A,C, the
the addition of turbulators. At NHII = 1, HMR is 10%, distance of uniform mixing of hydrogen and natural gas
turbulators are added at 50 mm from the initial mixing in the pipeline is shortening as the radial distance r
position, and the distance of uniform gas mixing is 19D. increases from 40 to 110 mm. At the radial distance
The distance of uniform gas mixing without the r = 110 mm, the distance L98% of the hydrogen and
turbulator is 16.4D. The distance of uniform hydrogen natural gas mixing uniformly is the shortest. For four‐
and natural gas mixing is slightly farther than that inlet hydrogen injection, the shortest distance for
without the turbulator. The turbulator was added under uniform gas mixing is 9.83D. For eight‐inlet hydrogen
the above three conditions, the distance between the injection, the shortest distance for uniform gas mixing is
hydrogen and the natural gas is mixed uniformly is 7.02D. Figure 5B,D indicates that the distance for
slightly further than without the turbulator, and the uniform gas blending is significantly reduced by the
turbulator caused very little disturbance to the flow of addition of the turbulator. Adjusting the distance Lturb
hydrogen in the pipeline. The gas flows through the from the turbulator to the initial mixing position, the
turbulator and there is no significant turbulence of the distance L98% for uniform mixing of hydrogen and
gas in the pipeline. Due to the pressure and inertia forces, natural gas is changing. With four‐inlet hydrogen
the hydrogen gas flows through the turbulator and injection, the turbulator has the shortest distance for
continues to flow forward at a greater velocity. The uniform gas mixing at Lturb = 50 mm, which is 2.95D.
hydrogen in the pipeline slowly spreads from the center With eight‐inlet hydrogen injection, the turbulator is set
of the pipe to the surrounding area. Due to the low to Lturb = 125 mm and the shortest distance for uniform
turbulence intensity of the gas in the pipeline, the mixing gas mixing is 1.99D. The distance over which the uniform
of hydrogen and natural gas in the pipeline is slow. mixing of hydrogen and natural gas mix uniformly is
Therefore, the distance between hydrogen and natural longer with eight hydrogen injection inlets compared to
gas mixing uniformly is slightly farther than when the four. The addition of the turbulator creates a more
turbulator is not added. With mixing ratios of 20% and intense disturbance of the gas in the pipeline with eight‐
30%, the addition of turbulators reduces the distance for inlet hydrogen injection. As a result, the distance
uniform mixing of hydrogen and natural gas. At NHII = required for uniform gas mixing during eight‐inlet
1, the addition of turbulator shortens the distance of gas hydrogen injection is shorter.
mixing uniformity. When the turbulators are set at
Lturb = 150 mm and Lturb = 50 mm, respectively, the gas
mixing uniformity distance is the shortest. At NHII = 2, 4.3.2 | Distribution of blending uniformity
the turbulator was set at Lturb = 150 and 50 mm, the
shortest distance for uniform gas mixing. At NHII = 8, the effect of radial distance r and turbulator
In single‐pipe hydrogen injection mixing, changing position variation on the distance L98% of gas uniform
the position of the turbulator has the greatest effect on mixing is shown in Figure 6. As can be seen in Figure 6A,
the mixing of hydrogen and natural gas. As the NHIIs the distance r from the turbulator to the initial mixing
increase, the distance between the uniform mixing of position increases and the distance between hydrogen
hydrogen and natural gas decreases. The influence of the and natural gas mixing uniformly decreases. The
turbulator installation position on the mixing process of distance L98% between the hydrogen and natural gas
hydrogen and natural gas is reduced. By choosing the mixed uniformly in the pipeline increases with the
suitable number of hydrogen inlets and the installation increase of the HMR. From Figure 6B, it can be seen that
positions of the turbulator, the distance between the at HMR = 5%, 10%, and 20%, the distance L98% of uniform
hydrogen and natural gas mixing uniformly in the gas mixing first decreases, then increases, and then
pipeline can be effectively shortened. decreases with the increase of Lturb. When HMR = 30%,
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YAN ET AL. | 11

F I G U R E 5 Distribution of hydrogen at 10% HMR in the pipeline. (A) NHII: 4, (B) NHII + NTurb: 4, (C) NHII: 8, and NHII + NTurb: 8.
HMR, hydrogen mixing ratio; NHII, number of hydrogen injection inlet.

F I G U R E 6 Influence of pipeline configuration on gas mixing uniformity distance. (A) NHII: 8 and (B) NHII + NTurb: 8. HMR,
hydrogen mixing ratio; NHII, number of hydrogen injection inlet.

the distance L98% for uniform mixing of hydrogen and 4.3.3 | Distribution of hydrogen
natural gas decreases and then increases with the
increase of Lturb. Increasing the HMR in the pipeline, Setting the NHIIs as 8, r = 110 mm, and HMRs as 5% (A),
the distance between even hydrogen and natural gas 10% (B), 20% (C), and 30% (D). Changing the distance Lturb
mixing increases. from the turbulator to the starting mixing position, the
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12 | YAN ET AL.

relationship between the hydrogen distribution in the theoretical values calculated from the simulations in this
pipeline and the cross‐sectional position is shown in study are less than 2%. The simulation results are within
Figure 7. Because of the presence of the turbulator, the the error tolerance. Increasing the HMR, the inlet velocity
flow velocity and direction of the gas in the pipeline are of hydrogen increases, and the disturbance of the gas when
disturbed when the gas hits the turbulator. The HMR in it hits the turbulator is more violent. As the HMR
the pipeline changes drastically near the turbulator. As the increases, the HMR in the pipeline needs longer distances
blending distance Lmix increases, the HMR in the pipeline to stabilize.
gradually stabilizes around the initially set mixing ratio.
During the gas mixing process, the HMR in the pipeline
has been stabilized, but the gas has not been mixed 4.3.4 | Changes in turbulent dissipation rate
uniformly at this location. The HMR in the pipeline in
Figure 7A reaches 5% at Lmix = 2D. The mixing uniformity The turbulence intensity of the gas mixture in the pipeline
of the gas at Lmix = 2D is 96.8% (Lturb = 50 mm), 95.7% can be expressed in terms of the turbulent dissipation rate.
(Lturb = 100 mm), and 98% (Lturb = 150 mm), respectively. Setting the NHIIs as 8, r = 110 mm, changing the HMR in
The mixing uniformity of hydrogen and natural gas the pipeline to 5% (A), 10% (B), 20%(D), and 30% (D),
reaches 98% at 2.75D (Lturb = 50 mm), 2.76D (Lturb = 100 respectively. The relationship between the turbulent
mm), and 1.98D (Lturb = 150 mm). In the simulation dissipation rate and the location of the monitored cross‐
process, the HMR in the simulated pipeline is slightly section is shown in Figure 8. With the addition of a
smaller than the theoretically calculated value of the HMR turbulator in the pipeline, the original flow rate and
because of the error. The errors between the HMR and the direction of the gas are disturbed. Due to the disturbance of

F I G U R E 7 Distribution of hydrogen in the pipeline. (A) HMR: 5%, (B) HMR: 10%, (C) HMR: 20%, and (D) HMR: 30%. HMR, hydrogen
mixing ratio; NHII, number of hydrogen injection inlet.
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YAN ET AL. | 13

F I G U R E 8 Turbulent dissipation rate in the hydrogen mixing pipeline. (A) HMR: 5%, (B) HMR: 10%, (C) HMR: 20%, and (D) HMR:
30%. HMR, hydrogen mixing ratio; NHII, number of hydrogen injection inlet.

the turbulator, a low flow velocity zone is formed behind 4.3.5 | Velocity COV distribution
the turbulator. Therefore, the turbulent dissipation rate
of the gas in the vicinity of the turbulator increases rapidly Velocity COV reflects the state of change of the gas
and then decreases rapidly. There is a small fluctuation velocity in the pipeline; the larger the value of velocity
between 1D and 2D from the mixing center that finally COV, the more chaotic the distribution of velocity in the
stabilizes around 1000 m2/s3. The closer the turbulator is to pipeline. Setting the NHIIs as 8, r = 110 mm, changing
the initial mixing position, the greater the turbulent the HMR in the pipeline to 5% (A), 10% (B), 20% (C), and
dissipation rate of the gas near the turbulator. In this 30% (D), respectively. The relationship between the
study, the HMR in the pipeline was adjusted by increasing velocity COV and the position of the cross‐section is
the inlet velocity of the hydrogen. Therefore, by increasing shown in Figure 9. As the gas in the pipeline flows
the HMR, the flow rate of the gas in the pipeline increases, through the turbulator, the flow field of the gas in the
and the fluctuation of the turbulent dissipation rate caused pipeline is disturbed. The velocity change of the gas in
by the turbulent flow device increases. The inclusion of the pipeline is complicated, the turbulence intensity of
turbulators in the pipeline disturbs the flow rate and the gas is increased, which improves the diffusion mixing
direction of flow of the gas in the pipeline. The addition of efficiency of hydrogen and natural gas. The gas flows
turbulators enhances the turbulence intensity of the through the turbulator, a low flow velocity region is
gas in the pipeline and improves the mixing efficiency formed in the area of 1D–2D behind the turbulator. The
of hydrogen and natural gas. The distance between disturbed gases converge behind the turbulator and
hydrogen and natural gas mixing uniformly is significantly continue to flow forward at a higher velocity. The
reduced. velocity COV first decreases between 1D–3D and then
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14 | YAN ET AL.

F I G U R E 9 Sampling cross‐section velocity COV. (A) HMR: 5%, (B) HMR: 10%, (C) HMR: 20%, and (D) HMR: 30%. COV, ratio of the
standard deviation to the mean value; HMR, hydrogen mixing ratio; NHII, number of hydrogen injection inlet.

increases rapidly. The velocity COV does not decrease as pressure is formed behind the turbulators, and the pressure
the mixing distance increases because the velocity of the drop in the pipeline at the turbulators increases. The gases
gas in the pipe is disturbed by the turbulator. The final converge behind the turbulator, the pressure of the gas
velocity COV fluctuates at a higher level. in the pipeline increases, and the pressure drop in the
pipeline decreases. As the mixing distance increases,
the pressure of the gases in the pipeline decreases,
4.3.6 | Pressure drop analysis and the pressure drop increases. The pressure drop of
the gas in the pipeline is smallest when the HMR is 5% and
The flow of gas in the pipeline is influenced by the the distance Lturb = 50 mm from the turbulator to the
structure of the pipeline, the roughness of the pipeline initial mixing position is set. The pressure drop of the gas
wall, temperature changes, flow rate changes, and so on. in the pipeline is highest when the turbulator is 150 mm
The pressure of the gas in the pipeline decreases as the from the initial mixing position. At an HMR of 10%, the
mixing distance increases. With a hydrogen injection inlet turbulator is set to Lturb = 150 mm, and the pressure drop
number of eight and r = 110 mm, the difference between in the pipe is minimal. The maximum pressure drop in the
the average pressure in the monitored section and the inlet pipe is achieved when the turbulator is set to Lturb = 100
pressure in the pipeline is calculated. Changing the HMR mm. The pressure drops in the pipeline with an HMR of
in the pipeline to 5% (A), 10% (B), 20% (C), and 30% (D), 20% are the opposite of that with an HMR of 10%; with the
respectively. The pressure drop in the pipeline versus the turbulator at Lturb = 100 mm, the pressure drop in the
blending distance is shown in Figure 10. Because of the pipeline is minimal. At Lturb = 150 mm, the pressure drops
disturbance of the turbulators, a zone of relatively low in the pipeline are at maximum. At an HMR of 30%, the
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YAN ET AL. | 15

F I G U R E 10 Pressure drops in the hydrogen mixing pipeline. (A) HMR: 5%, (B) HMR: 10%, (C) HMR: 20%, and (D) HMR: 30%. COV,
ratio of the standard deviation to the mean value; HMR, hydrogen mixing ratio; NHII, number of hydrogen injection inlet.

pressure drop in the pipeline is similar for turbulators at 5 | CONCLUSIONS


Lturb = 50 and 100 mm. At Lturb = 150 mm, the pressure
drop in the pipeline is the highest. The effect of different pipeline structures on the mixing
When the gas flows through the turbulator, the flow rate process of hydrogen and natural gas is investigated.
and flow direction of the gas in the pipeline changes. Under Changing the NHIIs, the initial mixing position of
the influence of the turbulator, the gas in the pipeline forms hydrogen, and the installation position of turbulator,
a low flow velocity and low‐pressure region behind the pipeline models of different structures were constructed
turbulator. Because of the restriction of the pipe wall, the for simulation. The mixing process of hydrogen and
gas in the pipeline continues to flow forward after natural gas in the pipeline, the distribution, and the
converging on the other side of the turbulator. The turbulent change of mixing uniformity were obtained. The details
dissipation rate of the gas in the pipeline increases rapidly in are as follows:
the vicinity of the turbulator. The velocity of the gas
decreases in the region between 1D and 2D from the initial 1. Increasing the NHIIs shortens the distance L98% of
mixing position. The gas flow continues at a higher velocity hydrogen and natural gas mixing uniformly in the
after convergence behind the turbulator. As a consequence, pipeline. After increasing the NHIIs to a certain
the velocity COV increases rapidly around the distance 3D number, further increases do not significantly shorten
from the initial mixing position. The pressure drop of the the distance of hydrogen and natural gas blending
gas at the turbulator position increases and the pressure evenly. The distance of uniform mixing of gas in the
drop of the gas in the pipeline after the gas convergence pipeline grows with the increase of HMR.
decreases. The pressure loss in the pipeline gradually 2. The radial distance r from the initial hydrogen mixing
increases as the mixing distance increases. positions to the center of the natural gas pipeline is an
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16 | YAN ET AL.

important factor affecting the uniformity of the 4. Cuevas F, Zhang J, Latroche M. The vision of France,
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