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THECHEMISTRYOFDECAFFEINATEDCOFFEE

SOLVENTDECAFFEINATION CO,DECAFFEINATION WATERDECAFFEINATION

Solventdecaffeinationusessolvents Solventdecaffeinationremoves 'Swisswaterdecaffeination'soaks


toselectivelyremovecaffeine. caffeinebutcanalsoremoveother beansinhotwatertoremove
Commonsolventsaremethylene flavourcompoundsorprecursors. caffeineandflavourcompounds.
chlorideandethylacetate. Carbondioxideismoreselective. Caffeineisremovedfromthewater
byfiltrationbutflavourcompounds
remain.Theflavour-saturatedwater
WATER
removescaffeinefromfurtherbean
cIv
WATER batcheswithoutflavourloss.
H=C "CH3

Methylenechloride(left)andethylacetate(right)
COFFEE&CAFFEINE
WATER CARBON
SOLVENT FILTER
Temp. WATER WATER
Atypicalcupofcoffeecontains COz -FLAVOUE BIRATEETTE

between70to140milligramsof
caffeine.Caffeinecaninfluence
thecentralnervoussystem,and
Indirectsolventextraction(above) Flavour-chargedwaterusedtoremove
canleadtosleepproblems,
beansaresteamed,thensoakedin 65 caffeinefromnewbatchofcoffeebeans
restlessnessanddiscomfort.
solventtoremovecaffeine,before Pressure
beingsteamed,dried,androasted. 'Frenchwaterdecaffeination'soaks
beansinhotwaterfor24hours.
CHz Thebeansareremovedanddried,
H;C. WATER WATER andthewaterisfilteredtoremove
CAFFEINE SOLVENT
caffeine.Thecaffeine-freewateris
WATER 300atm BEANS WATER
CAFFEINE addedtothedriedbeanssothat
CH; theyreabsorbflavourcompounds.

Inindirectsolventextraction(above) Athighpressurecarbondioxide
Thereareseveralprocessesused beansaresoakedinhotwater.The dissolvescaffeine.Thecaffeineis WATER DRY
todecaffeinatecoffee.IntheU.S. wateristhenmixedwithasolventto removedfromthecarbondioxide
CARBON
decaffeinationmustremove97% removecaffeine,beforeflavoursin withwatersoitcanberecirculated. WATER FILTER WATER
oftheoriginalcaffeinecontent. thewaterarereturnedtothebeans. Theprocesslastsforupto12hours. CAPEREITERSTIC

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